JPH0445560B2 - - Google Patents

Info

Publication number: JPH0445560B2
Authority: JP; Japan
Prior art keywords: weight; sodium; water; beads; zeolite
Prior art date: 1981-02-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP57030478A

Other languages

English (en)

Japanese (ja)

Other versions

JPS57159898A (en

Inventor

Jeroomu Guretsukusetsuku Jon

Uiruson Jorudaano Suu

Gurei Seimooru

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Colgate Palmolive Co

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-02-26

Filing date

1982-02-26

Publication date

1992-07-27

1982-02-26 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1982-10-02 Publication of JPS57159898A publication Critical patent/JPS57159898A/ja

1992-07-27 Publication of JPH0445560B2 publication Critical patent/JPH0445560B2/ja

Status Granted legal-status Critical Current

Links

239000003599 detergent Substances 0.000 claims description 179
239000011324 bead Substances 0.000 claims description 145
239000010457 zeolite Substances 0.000 claims description 125
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 124
229910001868 water Inorganic materials 0.000 claims description 119
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 118
239000000203 mixture Substances 0.000 claims description 118
229910021536 Zeolite Inorganic materials 0.000 claims description 91
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 88
239000000047 product Substances 0.000 claims description 80
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 64
229920000058 polyacrylate Polymers 0.000 claims description 64
239000000440 bentonite Substances 0.000 claims description 61
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 61
239000011734 sodium Substances 0.000 claims description 61
229910000278 bentonite Inorganic materials 0.000 claims description 60
239000000463 material Substances 0.000 claims description 49
229910000029 sodium carbonate Inorganic materials 0.000 claims description 44
239000000758 substrate Substances 0.000 claims description 42
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 34
239000004115 Sodium Silicate Substances 0.000 claims description 32
235000017557 sodium bicarbonate Nutrition 0.000 claims description 32
229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 32
229910052911 sodium silicate Inorganic materials 0.000 claims description 32
229910052708 sodium Inorganic materials 0.000 claims description 28
239000007787 solid Substances 0.000 claims description 27
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
229910000323 aluminium silicate Inorganic materials 0.000 claims description 26
239000007788 liquid Substances 0.000 claims description 24
238000001694 spray drying Methods 0.000 claims description 24
230000036571 hydration Effects 0.000 claims description 23
238000006703 hydration reaction Methods 0.000 claims description 23
238000004519 manufacturing process Methods 0.000 claims description 21
239000007921 spray Substances 0.000 claims description 21
102000004190 Enzymes Human genes 0.000 claims description 20
108090000790 Enzymes Proteins 0.000 claims description 20
239000002245 particle Substances 0.000 claims description 20
229920002125 Sokalan® Polymers 0.000 claims description 19
150000003839 salts Chemical class 0.000 claims description 18
239000002002 slurry Substances 0.000 claims description 17
230000003287 optical effect Effects 0.000 claims description 16
229910001424 calcium ion Inorganic materials 0.000 claims description 15
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 14
IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 14
238000000034 method Methods 0.000 claims description 14
229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 14
235000013799 ultramarine blue Nutrition 0.000 claims description 14
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 13
229910052681 coesite Inorganic materials 0.000 claims description 11
229910052906 cristobalite Inorganic materials 0.000 claims description 11
239000000377 silicon dioxide Substances 0.000 claims description 11
235000012239 silicon dioxide Nutrition 0.000 claims description 11
229910052682 stishovite Inorganic materials 0.000 claims description 11
229910052905 tridymite Inorganic materials 0.000 claims description 11
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 9
239000004927 clay Substances 0.000 claims description 9
238000005342 ion exchange Methods 0.000 claims description 9
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
238000000354 decomposition reaction Methods 0.000 claims description 8
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
230000008961 swelling Effects 0.000 claims description 7
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
150000002191 fatty alcohols Chemical class 0.000 claims description 6
230000009467 reduction Effects 0.000 claims description 6
239000012736 aqueous medium Substances 0.000 claims description 5
239000007859 condensation product Substances 0.000 claims description 5
239000004584 polyacrylic acid Substances 0.000 claims description 5
229920000728 polyester Polymers 0.000 claims description 5
229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
238000001879 gelation Methods 0.000 claims description 4
230000008569 process Effects 0.000 claims description 4
229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
235000019341 magnesium sulphate Nutrition 0.000 claims description 3
241000047703 Nonion Species 0.000 claims description 2
JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 claims description 2
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 3
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
239000001509 sodium citrate Substances 0.000 claims 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims 1
235000012216 bentonite Nutrition 0.000 description 48
229940092782 bentonite Drugs 0.000 description 42
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 38
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 36
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 31
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 27
239000002585 base Substances 0.000 description 25
235000017550 sodium carbonate Nutrition 0.000 description 23
238000002156 mixing Methods 0.000 description 20
239000006057 Non-nutritive feed additive Substances 0.000 description 19
229940088598 enzyme Drugs 0.000 description 19
239000004615 ingredient Substances 0.000 description 19
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 18
239000012467 final product Substances 0.000 description 17
150000004760 silicates Chemical class 0.000 description 17
238000012360 testing method Methods 0.000 description 16
239000003205 fragrance Substances 0.000 description 15
239000000843 powder Substances 0.000 description 15
239000002671 adjuvant Substances 0.000 description 14
238000009472 formulation Methods 0.000 description 14
238000005406 washing Methods 0.000 description 14
239000007864 aqueous solution Substances 0.000 description 13
235000015165 citric acid Nutrition 0.000 description 13
-1 alkali metal salts Chemical class 0.000 description 12
238000004140 cleaning Methods 0.000 description 11
230000000694 effects Effects 0.000 description 11
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 9
239000011521 glass Substances 0.000 description 9
229920000742 Cotton Polymers 0.000 description 8
238000001035 drying Methods 0.000 description 8
239000002609 medium Substances 0.000 description 8
239000000126 substance Substances 0.000 description 8
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 7
239000000654 additive Substances 0.000 description 7
239000002808 molecular sieve Substances 0.000 description 7
239000000049 pigment Substances 0.000 description 7
230000002829 reductive effect Effects 0.000 description 7
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 7
102000005158 Subtilisins Human genes 0.000 description 6
108010056079 Subtilisins Proteins 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
239000012530 fluid Substances 0.000 description 6
239000002250 absorbent Substances 0.000 description 5
230000002745 absorbent Effects 0.000 description 5
239000003086 colorant Substances 0.000 description 5
238000005260 corrosion Methods 0.000 description 5
239000013078 crystal Substances 0.000 description 5
239000008367 deionised water Substances 0.000 description 5
229910021641 deionized water Inorganic materials 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
239000004744 fabric Substances 0.000 description 5
238000012545 processing Methods 0.000 description 5
239000002689 soil Substances 0.000 description 5
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical group C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 4
108091005804 Peptidases Proteins 0.000 description 4
102000035195 Peptidases Human genes 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
150000004649 carbonic acid derivatives Chemical class 0.000 description 4
230000007797 corrosion Effects 0.000 description 4
230000008021 deposition Effects 0.000 description 4
239000008233 hard water Substances 0.000 description 4
239000011159 matrix material Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000004480 active ingredient Substances 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
230000008901 benefit Effects 0.000 description 3
238000004364 calculation method Methods 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
238000002425 crystallisation Methods 0.000 description 3
230000008025 crystallization Effects 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
239000000945 filler Substances 0.000 description 3
RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 3
238000005507 spraying Methods 0.000 description 3
108091005658 Basic proteases Proteins 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
239000004677 Nylon Substances 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
230000002411 adverse Effects 0.000 description 2
238000013019 agitation Methods 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
230000000844 anti-bacterial effect Effects 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
230000008859 change Effects 0.000 description 2
150000001860 citric acid derivatives Chemical class 0.000 description 2
230000007423 decrease Effects 0.000 description 2
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
239000000975 dye Substances 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
239000000796 flavoring agent Substances 0.000 description 2
235000019634 flavors Nutrition 0.000 description 2
238000000227 grinding Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
150000004677 hydrates Chemical class 0.000 description 2
230000006872 improvement Effects 0.000 description 2
230000002401 inhibitory effect Effects 0.000 description 2
229910010272 inorganic material Inorganic materials 0.000 description 2
239000011147 inorganic material Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000011068 loading method Methods 0.000 description 2
229910001425 magnesium ion Inorganic materials 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
229910052901 montmorillonite Inorganic materials 0.000 description 2
229920001778 nylon Polymers 0.000 description 2
RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical group [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000004576 sand Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
XCMDVRAWAIYDEE-UHFFFAOYSA-N 1,2-diphenyl-3h-pyrazole Chemical class C1C=CN(C=2C=CC=CC=2)N1C1=CC=CC=C1 XCMDVRAWAIYDEE-UHFFFAOYSA-N 0.000 description 1
QWZHDKGQKYEBKK-UHFFFAOYSA-N 3-aminochromen-2-one Chemical class C1=CC=C2OC(=O)C(N)=CC2=C1 QWZHDKGQKYEBKK-UHFFFAOYSA-N 0.000 description 1
MPIFMUARWKUNQZ-UHFFFAOYSA-N 4-[2-(2-phenylethenyl)phenyl]-2h-benzo[e]benzotriazole Chemical class C=1C=CC=C(C=2C=3N=NNC=3C3=CC=CC=C3C=2)C=1C=CC1=CC=CC=C1 MPIFMUARWKUNQZ-UHFFFAOYSA-N 0.000 description 1
FUXZRRZSHWQAAA-UHFFFAOYSA-N 5,5-dioxodibenzothiophene-3,7-diamine Chemical compound C1=C(N)C=C2S(=O)(=O)C3=CC(N)=CC=C3C2=C1 FUXZRRZSHWQAAA-UHFFFAOYSA-N 0.000 description 1
PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
229920004934 Dacron® Polymers 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
125000003158 alcohol group Chemical group 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
102000004139 alpha-Amylases Human genes 0.000 description 1
108090000637 alpha-Amylases Proteins 0.000 description 1
229940024171 alpha-amylase Drugs 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
230000003625 amylolytic effect Effects 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
238000005282 brightening Methods 0.000 description 1
238000001354 calcination Methods 0.000 description 1
235000010216 calcium carbonate Nutrition 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000004040 coloring Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000006071 cream Substances 0.000 description 1
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
229910052675 erionite Inorganic materials 0.000 description 1
239000003925 fat Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
230000006870 function Effects 0.000 description 1
239000007789 gas Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910017053 inorganic salt Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
239000005416 organic matter Substances 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000002304 perfume Substances 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000867 polyelectrolyte Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
230000002335 preservative effect Effects 0.000 description 1
230000002265 prevention Effects 0.000 description 1
238000003672 processing method Methods 0.000 description 1
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
238000012958 reprocessing Methods 0.000 description 1
210000002374 sebum Anatomy 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
238000004513 sizing Methods 0.000 description 1
239000000344 soap Substances 0.000 description 1
229940080314 sodium bentonite Drugs 0.000 description 1
229910000280 sodium bentonite Inorganic materials 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
229910000144 sodium(I) superoxide Inorganic materials 0.000 description 1
QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical class [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000004758 synthetic textile Substances 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
230000009974 thixotropic effect Effects 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
239000003981 vehicle Substances 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Biochemistry (AREA)
Detergent Compositions (AREA)

JP57030478A 1981-02-26 1982-02-26 Detergent composition and base beads therefor Granted JPS57159898A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US23861981A	1981-02-26	1981-02-26

Publications (2)

Publication Number	Publication Date
JPS57159898A JPS57159898A (en)	1982-10-02
JPH0445560B2 true JPH0445560B2 (xx)	1992-07-27

Family

ID=22898657

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
JP57030478A Granted JPS57159898A (en)	1981-02-26	1982-02-26	Detergent composition and base beads therefor
JP57030479A Granted JPS57173000A (en)	1981-02-26	1982-02-26	Detergent composition and base beads therefor

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
JP57030479A Granted JPS57173000A (en)	1981-02-26	1982-02-26	Detergent composition and base beads therefor

Country Status (5)

Country	Link
JP (2)	JPS57159898A (xx)
BE (2)	BE892282A (xx)
IN (1)	IN161821B (xx)
ZA (2)	ZA82937B (xx)
ZM (1)	ZM1082A1 (xx)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4404128A (en) *	1981-05-29	1983-09-13	The Procter & Gamble Company	Enzyme detergent composition
ATE20476T1 (de) *	1983-04-08	1986-07-15	Procter & Gamble	Granulierte detergenszusammensetzungen, welche ein gemischtes polymerzusatzsystem enthalten.
JPS59203722A (ja) *	1983-05-04	1984-11-17	Nippon Chem Ind Co Ltd:The	懸濁安定性のよい濃厚ゼオライトスラリ−
US4510066A (en) *	1983-07-06	1985-04-09	Colgate-Palmolive Company	Retarding setting of crutcher slurry for manufacturing base beads for detergent compositions
JPS6084397A (ja) *	1983-10-17	1985-05-13	花王株式会社	洗浄剤組成物
FR2568790B1 (fr) *	1984-08-10	1990-01-12	Rhone Poulenc Chim Base	Procede d'obtention d'une suspension aqueuse stable et pompable de zeolite et suspension ainsi obtenue
US4609473A (en) *	1984-11-26	1986-09-02	Colgate Palmolive Company	Bentonite-sulfate fabric softening particulate agglomerate, processes for manufacture and use thereof, and detergent compositions containing it
CA1297376C (en) *	1985-11-01	1992-03-17	David Philip Jones	Detergent compositions, components therefor, and processes for theirpreparation
GB8526999D0 (en) *	1985-11-01	1985-12-04	Unilever Plc	Detergent compositions
CA1286563C (en) *	1986-04-04	1991-07-23	Jan Hendrik Eertink	Detergent powders and processes for preparing them
GB8626082D0 (en) *	1986-10-31	1986-12-03	Unilever Plc	Detergent powders
DE3702764A1 (de) *	1987-01-30	1988-08-11	Degussa	Waschmittelbuilder
DE3855170T2 (de) *	1987-04-14	1996-10-17	Northrop Grumman Corp	Herstellungssystem unter Verwendung von dreidimensionalen graphischen Modellen
GB8709057D0 (en) *	1987-04-15	1987-05-20	Unilever Plc	Composition for softening fabrics
DE69922783T2 (de)	1998-10-16	2005-12-08	Kao Corp.	Verfahren zur herstellung von detergentteilchen
JP3359591B2 (ja) *	1999-05-10	2002-12-24	花王株式会社	界面活性剤担持用顆粒群の製法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS52112610A (en) *	1976-03-19	1977-09-21	Mizusawa Industrial Chem	Detergent builder composition
JPS52138508A (en) *	1976-03-25	1977-11-18	Procter & Gamble	Detergent composition
JPS555947A (en) *	1978-06-29	1980-01-17	Lion Fat Oil Co Ltd	Detergent composition

1982
- 1982-02-10 IN IN107/DEL/82A patent/IN161821B/en unknown
- 1982-02-12 ZA ZA82937A patent/ZA82937B/xx unknown
- 1982-02-12 ZA ZA82938A patent/ZA82938B/xx unknown
- 1982-02-23 ZM ZM10/82A patent/ZM1082A1/xx unknown
- 1982-02-25 BE BE0/207414A patent/BE892282A/fr not_active IP Right Cessation
- 1982-02-25 BE BE0/207415A patent/BE892283A/fr not_active IP Right Cessation
- 1982-02-26 JP JP57030478A patent/JPS57159898A/ja active Granted
- 1982-02-26 JP JP57030479A patent/JPS57173000A/ja active Granted

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS52112610A (en) *	1976-03-19	1977-09-21	Mizusawa Industrial Chem	Detergent builder composition
JPS52138508A (en) *	1976-03-25	1977-11-18	Procter & Gamble	Detergent composition
JPS555947A (en) *	1978-06-29	1980-01-17	Lion Fat Oil Co Ltd	Detergent composition

Also Published As

Publication number	Publication date
ZM1082A1 (en)	1983-11-21
JPS57173000A (en)	1982-10-25
BE892283A (fr)	1982-08-25
JPS57159898A (en)	1982-10-02
BE892282A (fr)	1982-08-25
ZA82938B (en)	1983-09-28
JPH046760B2 (xx)	1992-02-06
ZA82937B (en)	1983-09-28
IN161821B (xx)	1988-02-06

Publication	Publication Date	Title
US4414130A (en)	1983-11-08	Readily disintegrable agglomerates of insoluble detergent builders and detergent compositions containing them
CA1174935A (en)	1984-09-25	Spray dried base beads and detergent compositions
US4347152A (en)	1982-08-31	Phosphate-free concentrated particulate heavy duty laundry detergent
SE452773B (sv)	1987-12-14	Friflytande, spraytorkat perlmaterial och uppslamning for dess framstellning
US4368134A (en)	1983-01-11	Method for retarding gelation of bicarbonate-carbonate-zeolite-silicate crutcher slurries
US4260651A (en)	1981-04-07	Phosphate-free concentrated particulate heavy duty laundry detergent
US4488972A (en)	1984-12-18	Bentonite agglomerates
US4666740A (en)	1987-05-19	Phosphate-free concentrated particulate heavy duty laundry detergent
US4411809A (en)	1983-10-25	Concentrated heavy duty particulate laundry detergent
JPH0445560B2 (xx)	1992-07-27
SE435729B (sv)	1984-10-15	Fririnnande, partikelformig, stark eller hogverkande tvettdetergent
US4510066A (en)	1985-04-09	Retarding setting of crutcher slurry for manufacturing base beads for detergent compositions
IE48186B1 (en)	1984-10-31	Detergent compositions
US5080820A (en)	1992-01-14	Spray dried base beads for detergent compositions containing zeolite, bentonite and polyphosphate
US5024778A (en)	1991-06-18	Spray dried base beads for detergent compositions containing zeolite, bentonite and polyphosphate
US4427567A (en)	1984-01-24	Method for reconditioning of poorly flowing or caked detergent powders
US4851137A (en)	1989-07-25	Process for manufacturing bentonite agglomerates
CA1080575A (en)	1980-07-01	Method for reconditioning detergent powders
US4666738A (en)	1987-05-19	Method for making a phosphate containing concentrated heavy duty particulate laundry detergent
JPS60262896A (ja)	1985-12-26	ビルダー入り粒状非イオン性洗剤組成物
US4767546A (en)	1988-08-30	Fabric softening bentonite agglomerates for use in laundry detergents
GB2106482A (en)	1983-04-13	Method for retarding gelation of bicarbonate-carbonate-zeolite- silicate crutcher slurries
US4664950A (en)	1987-05-12	Concentrated heavy duty particulate laundry detergent
US4663194A (en)	1987-05-05	Phosphate-free concentrated particulate heavy duty laundry detergent
US4746445A (en)	1988-05-24	Process for manufacturing bentonite agglomerates