JPH04179464A - Disoxidant having strengthened bacteriostatic effect - Google Patents
Disoxidant having strengthened bacteriostatic effectInfo
- Publication number
- JPH04179464A JPH04179464A JP30644390A JP30644390A JPH04179464A JP H04179464 A JPH04179464 A JP H04179464A JP 30644390 A JP30644390 A JP 30644390A JP 30644390 A JP30644390 A JP 30644390A JP H04179464 A JPH04179464 A JP H04179464A
- Authority
- JP
- Japan
- Prior art keywords
- disoxidant
- bag
- bacteriostatic effect
- allyl isothiocyanate
- cyclodextrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003385 bacteriostatic effect Effects 0.000 title claims description 10
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000016720 allyl isothiocyanate Nutrition 0.000 claims abstract description 8
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010457 zeolite Substances 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000006096 absorbing agent Substances 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 2
- 235000013305 food Nutrition 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract description 3
- 229940079593 drug Drugs 0.000 abstract description 2
- GBCAVSYHPPARHX-UHFFFAOYSA-M n'-cyclohexyl-n-[2-(4-methylmorpholin-4-ium-4-yl)ethyl]methanediimine;4-methylbenzenesulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.C1CCCCC1N=C=NCC[N+]1(C)CCOCC1 GBCAVSYHPPARHX-UHFFFAOYSA-M 0.000 abstract description 2
- 239000004113 Sepiolite Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 229910052624 sepiolite Inorganic materials 0.000 abstract 1
- 235000019355 sepiolite Nutrition 0.000 abstract 1
- 229940123973 Oxygen scavenger Drugs 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 241001148470 aerobic bacillus Species 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 241001293164 Eutrema japonicum Species 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920001007 Nylon 4 Polymers 0.000 description 1
- 235000000760 Wasabia japonica Nutrition 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001146 hypoxic effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000012794 white bread Nutrition 0.000 description 1
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明は、静菌効果を強化した脱酸素剤に関するもの
である。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to an oxygen scavenger with enhanced bacteriostatic effect.
（従来の技術）
従来１食品、医薬品、飼料などの鮮度保持剤として、脱
酸素剤があった。(Prior Art) Oxygen scavengers have conventionally been used as freshness-preserving agents for foods, medicines, feeds, and the like.
（発明が解決しようとする［［ これは次のような欠点があった。(The invention seeks to solve [[ This had the following drawbacks.
（イ）嫌気性菌に対しては静菌効果がなかった。(b) It had no bacteriostatic effect against anaerobic bacteria.
（ロ）食品、医薬品、ＮＦｌなどの包装を完全密閉状態
にしなければならず、密閉状態が不完全な場合や、簡易
包装での長期保存には、十分な効果がなかった。(b) Packaging for foods, pharmaceuticals, NF1, etc. must be completely sealed, and it has not been sufficiently effective when the seal is incomplete or for long-term storage in simple packaging.
本発明は、これらの欠点を除くためになされたものであ
る。The present invention has been made to eliminate these drawbacks.
（課題を解決するための手ト
イソチオシアン酸アリルは、わさびの−成分として好気
性および嫌気性菌に対する静菌効果や、防黴効果は広く
知られている。(To solve the problem, allyl isothiocyanate is a component of wasabi and is widely known for its bacteriostatic effect against aerobic and anaerobic bacteria and its antifungal effect.
： ′″ｔ″″″５″１°＠９ｕ、４ Ｖ＋ｌｒ＞７＞
１１１７リルを粒状あるいは、粉状のサイクロデキスト
リン。: ′″t″″″5″1°@9u, 4 V+lr>7>
1117 Ril is granular or powdered cyclodextrin.
ＣＭＣ，シリカ、アルミナ、ゼオライト、セとオライド
などの有機あるいは無機担体に担持させた静菌剤（１）
を脱酸素剤（２）に混入させ、ガス透過性袋（３）に封
入する。 本発明は、以上の構成よりなる静菌効果を
強化した脱酸素剤である。Bacteriostatic agent supported on organic or inorganic carriers such as CMC, silica, alumina, zeolite, and ceolide (1)
is mixed into an oxygen absorber (2) and sealed in a gas permeable bag (3). The present invention is an oxygen absorber having an enhanced bacteriostatic effect and having the above structure.
（作用）
イソチオシアン酸アリルを粒状あるいは粉状のサイクロ
デキストリン、ＣＭ Ｃ、ンリカ、アルミす、ゼオライ
ト、セビオライトなどの有機あるいは無機担体に担持さ
せた静菌剤（１）を脱酸素剤（２）に混入させ、ガス透
過性袋（３）に封入する。(Function) A bacteriostatic agent (1) in which allyl isothiocyanate is supported on a granular or powdery organic or inorganic carrier such as cyclodextrin, CMC, phosphoric acid, aluminum, zeolite, or Seviolite is used as an oxygen scavenger (2). Mix and seal in a gas permeable bag (3).
以上の構成よりなる静菌効果を強化した脱酸素剤（６）
をナイロンなどの気密性のあるフィルムで作られた袋（
４）に食品（５）と共に入れて、袋（４）の開口部をシ
ールする。Oxygen absorber with enhanced bacteriostatic effect consisting of the above composition (6)
Bags made of airtight film such as nylon (
4) with the food (5) and seal the opening of the bag (4).
袋（４）の内部では、封入された空気の酸素が脱酸素剤
（２）により奪われて低酸素あるいは、無酸素状態にな
ると共に、イソチオシアン酸アリルは蒸散して、袋（４
）の内部に滞留する。Inside the bag (4), oxygen is removed from the sealed air by the oxygen scavenger (2), resulting in a hypoxic or anoxic state, and allyl isothiocyanate evaporates, leaving the air inside the bag (4).
) stays inside.
この時、イソチオシアン酸アリルの蒸気は、その静菌効
果により、嫌気性菌の増殖を抑制する。At this time, the vapor of allyl isothiocyanate suppresses the growth of anaerobic bacteria due to its bacteriostatic effect.
また、袋（４）内部の残留酸素や、長期保存時の袋（４
）内部への空気の浸透による好気性菌や黴の増殖も抑制
する。In addition, residual oxygen inside the bag (4) and bag (4) during long-term storage
) It also suppresses the growth of aerobic bacteria and mold due to the infiltration of air inside.
（実施例） 以下１本発明の実施例について説明する。(Example) An embodiment of the present invention will be described below.
（イ）粒状のサイクロデキストリン５ｇにイソチオシア
ン酸アリル０．０３ｃｃを担持させたちの（１１と逼元
鉄を主成分とする市販の脱酸＃８削（２１５ｇとを混ぜ
合わせ、ガス透過性フィルムで作られた袋（３）に封入
する。(a) Mix 5 g of granular cyclodextrin with 0.03 cc of allyl isothiocyanate (11) and 215 g of commercially available deoxidized #8, which is mainly composed of iron and iron, and use a gas-permeable film to Enclose it in the made bag (3).
担体としては、ＣＭ Ｃ、ンリカ、アルミナ、ゼオライ
ト、セとオライドなどの有機または無機担体も使用でき
る。As the carrier, organic or inorganic carriers such as CMC, alumina, alumina, zeolite, and ceolide can also be used.
（ロ）これを、食品（５）として食パン５０ｇと共に。(b) Use this with 50g of white bread as food (5).
気密性のある袋（４）として２５ｅ＋＊ Ｘ ３０ｃｍ
の透明−なナイロン製袋に入れて、開口部を熱シールし
、試料Ａとした。25e+* x 30cm as airtight bag (4)
The sample was placed in a transparent nylon bag, and the opening was heat-sealed to obtain Sample A.
比較のために、脱酸素ｆ１５ｇのみを使用した試料をＢ
とした。For comparison, a sample using only 15 g of deoxidized f
And so.
（ハ）試料ＡとＢを室温（摂氏２５度）で放置したとこ
ろ、試ＦＩＢは１５日日目黴の発生が認められ、２０日
日目は腐敗により食用に供し得なかった。一方、試料Ａ
は３０日Ｉｒも、黴の発生および腐敗は認められず５食
用に供し得た。(c) When Samples A and B were left at room temperature (25 degrees Celsius), the sample FIB developed mold on the 15th day, and could not be used for consumption on the 20th day due to decomposition. On the other hand, sample A
After irradiation for 30 days, no mold growth or decomposition was observed and the product could be used for 5 meals.
（発明の効果） 従来の脱酸素剤と比較して、静菌効果が向上した。(Effect of the invention) Improved bacteriostatic effect compared to conventional oxygen scavengers.
第１図は本発明の断面図
第２図は本発明の実施例を示す斜視図
（１）は静菌剤 （２）は脱酸素剤 （３）はガス透過
性袋 （４）は気密性袋 （５）は食品 （６）は静
菌効果を強化した脱酸素剤本体Figure 1 is a sectional view of the present invention Figure 2 is a perspective view showing an embodiment of the present invention (1) is a bacteriostatic agent (2) is an oxygen absorber (3) is a gas permeable bag (4) is an airtight bag Bag (5) is food (6) is oxygen absorber with enhanced bacteriostatic effect
Claims (1)
キストリン、ＣＭＣ（カルボキシメチルセルロース）、
シリカ、アルミナ、ゼオライト、セビオライトなどの有
機または無機担体にイソチオシアン酸アリルを担持させ
た静菌剤（１）を混入し、ガス透過性袋（３）に封入し
てなる、静菌効果を強化した脱酸素剤。1. Oxygen absorber (2), granular or powdered cyclodextrin, CMC (carboxymethyl cellulose),
A bacteriostatic agent (1) in which allyl isothiocyanate is supported on an organic or inorganic carrier such as silica, alumina, zeolite, or Seviolite is mixed and sealed in a gas permeable bag (3) to enhance the bacteriostatic effect. Oxygen absorber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30644390A JPH04179464A (en) | 1990-11-13 | 1990-11-13 | Disoxidant having strengthened bacteriostatic effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30644390A JPH04179464A (en) | 1990-11-13 | 1990-11-13 | Disoxidant having strengthened bacteriostatic effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04179464A true JPH04179464A (en) | 1992-06-26 |
Family
ID=17957066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30644390A Pending JPH04179464A (en) | 1990-11-13 | 1990-11-13 | Disoxidant having strengthened bacteriostatic effect |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04179464A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04124099U (en) * | 1991-04-30 | 1992-11-11 | 積水樹脂株式会社 | Antibacterial pack material |
| AU694163B2 (en) * | 1994-07-14 | 1998-07-16 | Kyodo Printing Co., Ltd. | Antimicrobial laminate and bag, container, and shaped cup using same |
-
1990
- 1990-11-13 JP JP30644390A patent/JPH04179464A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04124099U (en) * | 1991-04-30 | 1992-11-11 | 積水樹脂株式会社 | Antibacterial pack material |
| AU694163B2 (en) * | 1994-07-14 | 1998-07-16 | Kyodo Printing Co., Ltd. | Antimicrobial laminate and bag, container, and shaped cup using same |
| US6150004A (en) * | 1994-07-14 | 2000-11-21 | Kyodo Printing Co., Ltd. | Antimicrobial laminate and bag, container, and shaped cup using same |
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