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JPH04119839A - Damping and soundproofing material and preparation thereof - Google Patents

Damping and soundproofing material and preparation thereof

Info

Publication number
JPH04119839A
JPH04119839A JP2238970A JP23897090A JPH04119839A JP H04119839 A JPH04119839 A JP H04119839A JP 2238970 A JP2238970 A JP 2238970A JP 23897090 A JP23897090 A JP 23897090A JP H04119839 A JPH04119839 A JP H04119839A
Authority
JP
Japan
Prior art keywords
paperboard
melt adhesive
damping
sound
insulating material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2238970A
Other languages
Japanese (ja)
Other versions
JPH0624815B2 (en
Inventor
Hiroaki Mikamo
弘明 三鴨
Motohiko Ninomiya
二宮 元彦
Hiroaki Tamura
博昭 田村
Kunio Nakamura
中村 邦雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honshu Paper Co Ltd
Original Assignee
Honshu Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honshu Paper Co Ltd filed Critical Honshu Paper Co Ltd
Priority to JP2238970A priority Critical patent/JPH0624815B2/en
Priority to KR1019900021097A priority patent/KR950010584B1/en
Publication of JPH04119839A publication Critical patent/JPH04119839A/en
Publication of JPH0624815B2 publication Critical patent/JPH0624815B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties

Landscapes

  • Laminated Bodies (AREA)
  • Building Environments (AREA)
  • Vibration Prevention Devices (AREA)

Abstract

PURPOSE:To obtain excellent damping and soundproofing effect by using a hot melt adhesive as an adhesive laminating a plurality of cardboards. CONSTITUTION:When a plurality of cardboards are laminated, a hot melt adhesive 12 is used as the adhesive layer between the cardboard layers. As the cardboard, one having relatively large thickness is used and, for example, cardboard with a basis weight of about 250-650g/m<2> is pref. The hot melt adhesive can be used by appropriately compounding a tackifier, a plasticizer, a filler, wax and an oxidation inhibitor with a base polymer such as an ethylene/vinyl acetate copolymer or a styrenic copolymer. Further, a hot melt adhesive wherein loss modulus (G'') in a use temp. region (0-40 deg.C) is 10<4>-10<8> dyne/cm<2>, loss tangent (tandelta) is within the range of 0-40 deg.C and the peak value thereof is 0.3-3.0 is pref. used. By this method, excellent damping and soundproofing effect can be obtained.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、住宅等の建材または住宅の付属設備もしくは
家庭電器、自動車等に用いられる制振、防音用の材料な
らびにその製造法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to vibration damping and soundproofing materials used for building materials such as houses, auxiliary equipment for houses, home appliances, automobiles, etc., and a method for manufacturing the same.

[従来技術とその問題点] 近年、住宅環境の騒音が問題にされ、例えば集合住宅に
おける隣家の間に設けられた隔壁、もしくは上、下階間
に生ずる振動などによる近隣間のトラブルが社会問題化
している。同様な問題は、住宅内で使用される回転機器
を備えた洗濯機、冷蔵庫、電気掃除機などの家庭電化製
品から発する騒音に対しても提起されている。
[Prior art and its problems] In recent years, noise in the residential environment has become a problem, and for example, problems between neighbors due to partition walls installed between neighboring houses in apartment complexes or vibrations between upper and lower floors have become a social problem. It has become Similar issues have been raised regarding the noise emitted by household appliances such as washing machines, refrigerators, and vacuum cleaners with rotating equipment used in homes.

この種の騒音抑止ならびに振動抑1−のための資材とし
て最近、開発されているのものに制振鋼板かあり、二の
ものは、例えば自動車内の居住性を高めるだめの騒音抑
止材または同様な目的で電気洗濯機なとの側板に利用さ
れている。
Damping steel plates have recently been developed as materials for this type of noise suppression and vibration suppression. It is used for the side panels of electric washing machines for various purposes.

一方、木造または軽量コンクリート板製の一般住宅およ
びマンション等の集合住宅にあっては、それら住宅の壁
、天井面なとに使用される石膏ホードまたは合板もしく
は鋼板なとに制振ゴムを貼り合わせたものか知られてい
る。しかし、が5るゴム系制振材にあっては、厚さが厚
いはと制振効果か認められるか価格か高くなり、住宅の
内装用として使用したときに居住空間か狭くなる等の問
題があり、一方、薄くすると急激に剛性がなくなり、建
材に貼り合せても振動を減衰させることができない。ま
た、このほか建材に対しては熱可塑性樹脂シート、不織
布、発泡樹脂シート等を貼り合せたものを知られている
か、前記いずれも満足すべき効果をあげていない。
On the other hand, in the case of general houses and apartment complexes made of wooden or lightweight concrete plates, damping rubber is attached to the plasterboard, plywood, or steel plates used for the walls and ceilings of these houses. What is known? However, when it comes to rubber-based damping materials, they are thicker and more expensive, making it difficult to recognize the vibration-damping effect, and when used for the interior of a house, there are problems such as the living space becomes narrower. On the other hand, when made thinner, the rigidity suddenly decreases, and vibrations cannot be damped even when bonded to building materials. In addition, as building materials, there are also known building materials laminated with thermoplastic resin sheets, non-woven fabrics, foamed resin sheets, etc., but none of the above have produced satisfactory effects.

ところで近年、複数枚の板紙をアクリル系合成ゴム接着
剤なとのエマルション系接着剤で接着、積層して成る制
振防音材の提案も見受けられるが、制振性能を向上させ
るためには、多量にエマルンヨン接着剤を塗布しなけれ
ばならず、その場合には、紙層中に多量の水分か残るの
で「カビ」や「カール」発生の原因となる。さらにまた
、製造時に紙層中に浸み込んた水分を蒸発させる為、多
量の乾燥エネルギーと長い乾燥時間か必要であり、その
ため生産性か悪いなとの種々の問題点かあった。その上
、水分の蒸発か不完全な場合には、残留水分のため制振
材料の拘束層に相当する板紙の剛度か低下してしまい、
その結果、板紙と板紙の間に構成される粘弾性樹脂層に
力が加わらなくなるため、振動起因のスレ剪断力(非拘
束型の場合には伸び変形力)か伝達され難く、粘弾性樹
脂層によるエネルギー吸収が困難となり、制振性能か低
下してしまうという問題があった。具体的に説明すると
、後記の比較例にも示すように高固形分のエマルジョン
系接着剤を使用して、加工前の含有水分が8%の2枚の
板紙を積層させてみても接着剤中の水分か紙層内に拡散
するため、加工後においては前記水分が10〜1596
に増加する。水分8%の板紙の剛度を100とすると、
水分10%では97、水分15%では91と剛度か下が
る。また、水分8%の板紙を用いた板紙/合成樹脂/板
紙の構成からなる板紙系複合シートの損失係数を100
とすると、水分lO%では95、水分15%では88と
著しく減少する。
By the way, in recent years, there have been proposals for vibration-damping and sound-insulating materials made by laminating multiple sheets of paperboard glued together using emulsion-based adhesives such as acrylic synthetic rubber adhesives, but in order to improve vibration-damping performance, a large amount of Emulsion adhesive must be applied to the paper layer, and in that case, a large amount of moisture remains in the paper layer, causing mold and curling. Furthermore, a large amount of drying energy and a long drying time are required in order to evaporate the water that has seeped into the paper layer during manufacturing, resulting in various problems such as poor productivity. Moreover, if the water evaporates incompletely, the stiffness of the paperboard, which is the constraining layer of the damping material, will decrease due to the residual water.
As a result, no force is applied to the viscoelastic resin layer formed between the paperboards, so it is difficult for the vibration-induced shearing force (stretching deformation force in the case of non-constraint type) to be transmitted to the viscoelastic resin layer. There was a problem in that it became difficult to absorb energy due to the vibration damping performance. To be more specific, as shown in the comparative example below, even when two sheets of paperboard with a moisture content of 8% before processing are laminated using an emulsion adhesive with a high solids content, there is no difference in the adhesive content. Because some of the moisture diffuses into the paper layer, after processing, the moisture is 10 to 1596
increases to If the stiffness of paperboard with 8% moisture is 100,
The stiffness decreases to 97 at 10% moisture and 91 at 15% moisture. In addition, the loss coefficient of a paperboard-based composite sheet consisting of paperboard/synthetic resin/paperboard using paperboard with a moisture content of 8% was 100%.
When the moisture content is 10%, it is 95, and when the moisture content is 15%, it is significantly reduced to 88.

[発明の目的および構成] 本発明の目的は、上述の問題点を解消し、制振と防音性
を兼ね備えた制振防音材を提供せんとしたするもので、
本発明による制振防音材は、少なくとも一枚の板紙の表
面に、下記に特定するようなホットメルト系接着剤また
は塗工剤(以下、単に接着剤またはHM接着剤という)
を、同化後の厚みが30μm以上となるように積層させ
て成る非拘束型の制振防音材と、同しく前記のホットメ
ルト系接着剤層を介して複数枚の板紙を貼り合せて成る
拘束型の制振防音材とを含むものである。なお、複数枚
の板紙を積層させる際、それら板紙層の間の接着剤のう
ち、少なくとも1層の接着剤層はこれを前記厚さを有す
るホントメルト系接着剤層とする必要かあるか、それ以
外の接着剤層としては、前記以外のエマルジョン系接着
剤その他の接着剤を用いることかできる。ただし、エマ
ルジョン系接着剤を併用する場合には、制振層としてて
はなく単に板紙相互を接合する目的で使用するものであ
り、その場合にも紙になるべく水分を与えないように、
塗布量を固形分て20μm以下程度工程る必要かある。
[Object and Structure of the Invention] An object of the present invention is to solve the above-mentioned problems and provide a vibration damping and sound insulating material that has both vibration damping and sound insulating properties.
The vibration damping and sound insulating material according to the present invention is applied to the surface of at least one sheet of paperboard using a hot melt adhesive or coating agent (hereinafter simply referred to as adhesive or HM adhesive) specified below.
A non-constraint type vibration damping and sound insulating material made by laminating the above so that the thickness after assimilation is 30 μm or more, and a constraint made by laminating multiple sheets of paperboard together via the hot melt adhesive layer mentioned above. This includes a type of vibration damping and sound insulating material. In addition, when laminating a plurality of paperboards, is it necessary for at least one adhesive layer among the adhesives between the paperboard layers to be a true melt adhesive layer having the above-mentioned thickness? For other adhesive layers, emulsion adhesives and other adhesives other than those mentioned above may be used. However, if an emulsion adhesive is used in conjunction with the adhesive, it will not be used as a vibration damping layer, but simply for the purpose of bonding the paperboards together, and in that case, care should be taken to avoid adding moisture to the paper as much as possible.
It is necessary to reduce the coating amount to about 20 μm or less based on the solid content.

更にまた、本発明は、前記のホットメルト系接着剤が極
めて高粘度であるため、前記制振防音材を製造するに当
っては、好ましくは後記のニーダー・ルーダー(Kne
ader−Ruder )を使用して混練と溶融ならび
に脱水を行った上で、スリットダイから薄膜状に押出し
ながら板紙の表面にラミネートしたり、或いはギヤ・イ
ン・ダイコーターやロールコータ−を用いてラミネート
する等の方法で板紙に適用する。なお、前記のようにホ
ットメルト系接着剤をラミネートした板紙を巻き取るに
当っても板紙の剛度を低下させないように比較的大径の
ドラムに巻き取るか、或いはラミネートした板紙を平版
裁断機で直接、断裁するようになして前記の不具合か生
しないようにする。
Furthermore, in the present invention, since the hot melt adhesive has an extremely high viscosity, when producing the vibration damping and sound insulating material, it is preferable to use a kneader-ruder (Kneider-Ruder) described below.
After kneading, melting, and dehydrating using a slit die and extruding it into a thin film, it is laminated on the surface of paperboard, or it is laminated using a gear-in-die coater or roll coater. Apply to paperboard by such methods as In addition, when winding up paperboard laminated with hot melt adhesive as mentioned above, it is necessary to wind it on a relatively large diameter drum so as not to reduce the rigidity of the paperboard, or to cut the laminated paperboard using a lithographic cutting machine. Cut the material directly to avoid the above-mentioned problems.

本発明に用いられる板紙としては、比較的厚みの大きい
板紙が用いられ、たとえば、坪量か250〜650g/
m2程度のものか好ましい。
The paperboard used in the present invention is relatively thick paperboard, for example, with a basis weight of 250 to 650 g/
It is preferable to have a size of about m2.

接着剤としては、ホットメルト系接着剤か用いられる。As the adhesive, a hot melt adhesive is used.

ホットメルト系接着剤としては、公知のエチレン−酢酸
ビニル共重合体、スチレン系共重合体、ポリエチレン、
ポリアミド、ポリエステル、ポリプロピレン等のベース
ポリマーに、粘着付与剤、可塑剤、充填剤、ワックス類
、酸化防止剤などを適宜配合して用いることかできる。
Examples of hot melt adhesives include known ethylene-vinyl acetate copolymers, styrene copolymers, polyethylene,
A tackifier, plasticizer, filler, wax, antioxidant, etc. can be suitably added to a base polymer such as polyamide, polyester, or polypropylene.

本発明で用いるホットメルト系接着剤は、本発明者等の
検討結果から、使用温度域(0℃〜40℃)ての粘弾性
値である損失弾性率(G”)か10 〜108dyne
/Cm2、損失正接(tanδ)か0℃〜40℃の範囲
において緩やかなピークを有し、かつそのピーク値か0
.3〜30であるホットメルト系接着剤を用いるのかよ
く、このようなホットメルト系接着剤を使用した場合に
は、振動のヒスミを効果的に吸収し得ることか判明した
。上記ベースポリマーの中でも、ベースポリマーとして
スチレンイソプレン−スチレン共重合体、アタクチンク
ポリプロピレンを用いるのかよい。
The hot melt adhesive used in the present invention has a loss modulus (G''), which is a viscoelastic value in the operating temperature range (0°C to 40°C), or 10 to 108 dyne, based on the study results of the present inventors.
/Cm2, the loss tangent (tan δ) has a gentle peak in the range of 0°C to 40°C, and the peak value is 0
.. It has been found that using a hot melt adhesive having a rating of 3 to 30 is effective in absorbing vibration hisses when such a hot melt adhesive is used. Among the base polymers mentioned above, styrene isoprene-styrene copolymer and atactinic polypropylene may be used as the base polymer.

前述のように、本発明の制振防音材に用いるホットメル
ト系接着剤は、そのガラス転移温度(Tg)領域が使用
温度域に合致するように選択するのかよく、さらに損失
弾性率(G”)と損失正接(tanδ)は、使用温度域
内においては鋭いピークかなく、緩やかなピークを描く
ような特性のものを用いるのかよい。けだし、使用温度
域内に転移領域かくるものを用いれば、ホットメルト系
接着剤成分の高分子が、主鎖及び側鎖のマクロ的或いは
ミクロ的な絡み合いをしながら、効果的に振動エネルギ
ーを吸収するからである。また、ホットメルト系接着剤
の使用量は、少なくとも塗工後の厚さを30μm以上と
することか必要である。
As mentioned above, the hot melt adhesive used in the vibration damping and sound insulating material of the present invention should be selected so that its glass transition temperature (Tg) range matches the operating temperature range, and the loss modulus (G'' ) and loss tangent (tan δ) should have characteristics that do not have sharp peaks but have gentle peaks within the operating temperature range. However, if you use one that has a transition region within the operating temperature range, This is because the polymer of the melt adhesive component effectively absorbs vibrational energy through macroscopic or microscopic entanglement of main chains and side chains.Also, the amount of hot melt adhesive used is , it is necessary that the thickness after coating be at least 30 μm.

次に、前記した損失弾性率(G”)と損失正接(tan
δ)ならびに後記データ中の損失係数(η)について説
明する。前記損失係数は、本発明の目的とするような制
振防音材ならびにこれらを貼付して使用する石膏ホード
、珪酸カルシウム板の如き被貼付素材と制振防音材との
複合体を対象とした音の透過損失を示す測定値であるが
、損失弾性率と損失正接は、いずれもホットメルト接着
剤自体を対象とした粘弾性の測定値である。ちなみに、
前記損失弾性率と損失正接は、いずれもエネルギーロス
量を示しており、両者は、次のような関係にある。
Next, the loss modulus (G”) and loss tangent (tan
δ) and the loss coefficient (η) in the data described below will be explained. The above-mentioned loss coefficient is a sound loss coefficient for the vibration-damping and sound-insulating material that is the object of the present invention, as well as the composite material of the vibration-damping and sound-insulating material and the material to which it is attached, such as gypsum hoarding and calcium silicate board. loss modulus and loss tangent are both measured values of viscoelasticity of the hot melt adhesive itself. By the way,
Both the loss modulus and the loss tangent indicate the amount of energy loss, and they have the following relationship.

なお、本発明で使用するホットメルト系接着剤は、エマ
ルジョン系接着剤とは異なり、接着剤塗工後の紙層中へ
の水分の移行かないので、それによる紙の剛度の低下も
なく、したかって、ホットメルト接着剤層の振動エネル
ギー吸収能力と板紙の振動エネルギー吸収能力とを効果
的に発現させることができると考えられる。
Note that unlike emulsion adhesives, the hot melt adhesive used in the present invention does not allow moisture to migrate into the paper layer after the adhesive is applied, so there is no decrease in the stiffness of the paper. It is thought that the vibration energy absorption ability of the hot melt adhesive layer and the vibration energy absorption ability of the paperboard can be effectively expressed.

本発明における制振防音材の層構成としては種々の形態
かあるか、基本的な層構成を列記すると、次のとおりで
ある。
There are various types of layer configurations of the vibration damping and sound insulating material in the present invention, and the basic layer configurations are listed below.

HM/板紙 板紙/HM/板紙 板紙/HM/板紙/EM/板紙/HM/板紙板紙/P 
E/板紙/HM/板紙/P E/板紙板紙/HM/板紙
/HM/板紙/HM/板紙たたし、HM=ホットメルト
系接着接着剤M=エマルジョン系接着接着剤E−ポリエ
チレンフィルムまたはシートを示す。なお、前記PEと
して示す層には、ポリエチレンのほか、ポロプロピレン
、ポリエチレンテレフタレート、ポリメチルペンテンな
との比較的剛性の高いラミネート樹脂またはフィルムな
どを用いることも出来、その場合のPEの厚みは、概ね
15〜40μm程度とするのを可とする。なお、上記に
PEとして表示したラミネート樹脂またはフィルムは防
湿性を有するので、これを併用したときにはGL工法壁
(第11図参照)におけるコンクリートの結露水か石膏
ボード表面に浸み出すことを防止でき、ひいてはカビの
発生を防止するのに有効である。
HM/Paperboard/HM/Paperboard/HM/Paperboard/EM/Paperboard/HM/Paperboard/P
E/Paperboard/HM/Paperboard/P E/Paperboard/HM/Paperboard/HM/Paperboard/HM/Paperboard, HM=Hot melt adhesive M=Emulsion adhesive E-Polyethylene film or sheet shows. In addition to polyethylene, the layer indicated as PE can also be made of a relatively rigid laminate resin or film such as polypropylene, polyethylene terephthalate, or polymethylpentene, and in that case, the thickness of PE is as follows: It is possible to set the thickness to about 15 to 40 μm. Note that the laminate resin or film indicated as PE above has moisture-proof properties, so when used together, it can prevent condensed water from the concrete in the GL method wall (see Figure 11) from seeping into the surface of the gypsum board. It is also effective in preventing the growth of mold.

これら板紙を積層した制振防音材の片面または両面には
、合板、石膏ボード、鋼板などの建材が貼合されて使用
されるか、その−例を添付図面に基づいて具体的に説明
すると、第1図aは、本発明における非拘束型の制振防
音材を模式的に示したもので、符号11は板紙層、同1
2はホットメルト接着剤層、同13は前記構成から成る
制振防音材を貼付した石膏ボードなとの被貼付体(素材
)を示す。同しく第1図すは、前記の制振防音材が振動
源または騒音源からの固体伝搬音または空気伝搬音の影
響を受けて作動した状態で、非拘束型の場合にはHM層
12にのび変形か生することを模式的に示したものであ
る。また、第2図a、bは、同しく拘束型の制振防音材
の挙動を示した断面図であって、前記と同し部材につい
ては、同じ符号を付して示し、拘束型の制振防音材にあ
っては前記HM層にスレせん断変形か生することを模式
的に示した。第3〜4図は、本発明における制振防音材
を石膏ホードなとの被貼付体13に貼り付けた状態を示
す斜視図であって、第3図は片面型、第4図は両面型を
示した。
Building materials such as plywood, gypsum board, and steel plates are laminated to one or both sides of the vibration-damping and sound-insulating material made of paperboard laminated, and examples thereof will be explained in detail based on the attached drawings. FIG. 1a schematically shows a non-restrictive vibration damping and soundproofing material according to the present invention, in which reference numeral 11 denotes a paperboard layer;
Reference numeral 2 indicates a hot-melt adhesive layer, and reference numeral 13 indicates an object (material) to which a vibration damping and sound insulating material having the above structure is attached, such as a gypsum board. Similarly, FIG. 1 shows a state in which the vibration damping and sound insulating material is activated under the influence of solid-borne sound or air-borne sound from a vibration source or a noise source, and in the case of an unrestrained type, the HM layer 12 This is a schematic illustration of the occurrence of stretching deformation. Furthermore, FIGS. 2a and 2b are cross-sectional views showing the behavior of a constraint type vibration damping and sound insulating material, in which the same members as above are denoted by the same reference numerals, and the restraint type control It is schematically shown that shear deformation occurs in the HM layer in the case of vibration and soundproofing materials. Figures 3 and 4 are perspective views showing the state in which the vibration-damping and sound-insulating material of the present invention is attached to a target object 13 such as a gypsum board, with Figure 3 being a single-sided type and Figure 4 being a double-sided type. showed that.

第5〜6図は、前記したニーダ−・ルーダーの一例を示
し、図中、20はフレーム、21はプレミキサ−で、そ
の外殻に加温装置が組み込まれている。
5 and 6 show an example of the kneader/ruder described above, in which 20 is a frame, 21 is a premixer, and a heating device is incorporated in the outer shell.

22は、前記プレミキサ−における攪拌羽根21aを駆
動するモータ、23はニーダ−であり、前記プレミキサ
−21の底部に設けられた配管24を通して該ミキサー
で溶融混練されたホットメルト接着剤(以下、HM接着
剤という)か該ニーダ−内に導かれ、更に均一に混練さ
れてからニーダ−23の下部に配設された加温装置つき
のエクストルーダ25に導入され、その上で、該エクス
トルーダーの側部に取り付けられた供給パイプ25aを
介して押出される。ちなみに、符号23aはニーダ−内
ニ設けられた攪拌翼てあって、その取付軸23bの上端
に付設されたモータ23cにより駆動せしめられる。
22 is a motor that drives the stirring blade 21a in the premixer, 23 is a kneader, and the hot melt adhesive (hereinafter referred to as HM The adhesive (referred to as adhesive) is guided into the kneader, further kneaded uniformly, and then introduced into the extruder 25 equipped with a heating device located at the bottom of the kneader 23. It is extruded through a supply pipe 25a attached to. Incidentally, reference numeral 23a denotes a stirring blade provided inside the kneader, which is driven by a motor 23c attached to the upper end of the mounting shaft 23b.

前記供給パイプ25aを介して供給されたHM接着剤は
、第7〜8図に示すようなスリットダイ方式のラミネー
ター26または27によって板紙11にラミネートされ
る。なお、符号26は横向きに樹脂を押出すラミネータ
ーで、同27は、上向きに樹脂を流出させるファンテン
方式を示す。第9図は符号28で示すロールコータ−に
よって板紙11の表面にHM接着剤をラミネートさせる
事例を示す。
The HM adhesive supplied through the supply pipe 25a is laminated onto the paperboard 11 by a slit die type laminator 26 or 27 as shown in FIGS. Note that the reference numeral 26 indicates a laminator that extrudes the resin sideways, and the reference numeral 27 indicates a fountain system that causes the resin to flow upward. FIG. 9 shows an example in which the HM adhesive is laminated onto the surface of the paperboard 11 using a roll coater 28.

第10図は、同じくロールコータ方式により本発明の制
振防音材を製造する場合の他の実施例を示すもので、符
号30は、加温装置が組み込まれたHM接着剤の貯槽(
Reservoi r)であって、該槽30の底部に開
口させた供給管31と管路途中にに設けた送りポンプ3
2を介して槽30内のHM接着剤をパン33に導く。パ
ン33内においては溶融状態にあるHM接着剤に浸漬し
つつ回転するコーティングロール34と非回転の計量ロ
ール35とが相対峙して配設され、その間のニップによ
って制御された適正量のHM接着剤かコーティングロー
ル34を介してその直上を走行している板紙11に塗布
される。HM接着剤が塗布された積層板は、次段に配設
された上下一対の圧着ロール36a、36bを介して別
の板紙11と重合させられて、2枚の板紙をHM接着剤
で積層させた制振防音材となる。符号37は、積層板紙
の走行を案内する案内ロールである。
FIG. 10 shows another embodiment in which the vibration-damping and sound-insulating material of the present invention is manufactured using the same roll coater method, and reference numeral 30 denotes an HM adhesive storage tank (30) in which a heating device is incorporated.
A supply pipe 31 opened at the bottom of the tank 30 and a feed pump 3 installed in the middle of the pipe.
The HM adhesive in the tank 30 is led to the pan 33 through the pan 33. Inside the pan 33, a coating roll 34 that rotates while immersed in molten HM adhesive and a non-rotating measuring roll 35 are disposed facing each other, and a proper amount of HM adhesive is controlled by the nip between them. The agent is applied via a coating roll 34 to the paperboard 11 running directly above it. The laminate coated with the HM adhesive is polymerized with another paperboard 11 via a pair of upper and lower pressure rolls 36a and 36b disposed in the next stage, and the two paperboards are laminated with the HM adhesive. It becomes a vibration damping and sound insulating material. Reference numeral 37 is a guide roll that guides the running of the laminated paperboard.

なお、図示を省略したが、前記のようにして製造された
積層材は、これを−旦大径の巻取りトラムに巻き取った
上で、さらに別の積層板と重合させたり、或いは製造直
後に巻き取らずに平判断裁機で所定の寸法に裁断するこ
ともある。さらにまた、第7〜9図の装置により製造し
た片面型の積層材において、板紙11の表面に配設した
HM接着剤層12の露出面に別の板紙■1を貼り合せる
こともてき、このようにして任意の積層枚数を有する制
振防音材を製造するのである。
Although not shown in the drawings, the laminated material manufactured as described above may be wound up on a large-diameter winding tram and then polymerized with another laminated board, or immediately after manufacturing. In some cases, the paper is cut to a specified size using a flat cutting machine without being rolled up. Furthermore, in the single-sided laminate manufactured by the apparatus shown in FIGS. 7 to 9, another paperboard 1 can be bonded to the exposed surface of the HM adhesive layer 12 provided on the surface of the paperboard 11. In this way, a vibration damping and sound insulating material having an arbitrary number of laminated layers is manufactured.

[実施態様] 以下に、本発明の実施例を比較例と共に具体的に記述す
る。
[Embodiments] Examples of the present invention will be specifically described below along with comparative examples.

実施例1 坪量300g/m2の板紙2枚を、スチレン−イソプレ
ン−スチレン共重合体樹脂をベースポリマーとするホッ
トメルト接着剤を用い、かつ該接着剤の塗工厚みか60
μmになるように用いて貼合し、別に、同様にして貼合
した2枚の積層板紙を、スチレン−アクリル共重合体系
樹脂エマルジョン(乾燥後の厚さ20μm)で接着して
、合計4枚の板紙を積層させてなる制振防音材を得た。
Example 1 Two sheets of paperboard with a basis weight of 300 g/m2 were coated with a hot melt adhesive having a styrene-isoprene-styrene copolymer resin as the base polymer, and the coating thickness of the adhesive was 60 g/m2.
Two sheets of laminated paperboard, which were laminated in the same manner, were bonded together using a styrene-acrylic copolymer resin emulsion (thickness after drying: 20 μm), for a total of 4 sheets. A vibration damping and sound insulating material made by laminating paperboards was obtained.

この制振防音材の一方の面に厚さ9n+mの合板を、他
方の面には厚さ3mmの合板を、それぞれ接着剤で貼合
した。実施例1て使用したホットメルト接着剤の粘弾性
は、損失弾性率(G”)か5℃て4XIO6dyne/
cIII2.20℃で、8 x 10 ”dyne/c
m ” 、損失正接(tanδ)は、5℃で1.7 、
20℃で067であった。また、ガラス転移温度(Tg
)は、+0.5℃であった。
A 9n+m thick plywood was attached to one side of this vibration damping and sound insulating material, and a 3 mm thick plywood was attached to the other side with an adhesive. The viscoelasticity of the hot melt adhesive used in Example 1 is the loss modulus (G”) or 4XIO6dyne/4XIO6dyne/at 5°C.
cIII2.8 x 10”dyne/c at 20°C
m”, loss tangent (tan δ) is 1.7 at 5°C,
It was 067 at 20°C. In addition, the glass transition temperature (Tg
) was +0.5°C.

比較例1 実施例1において、板紙2枚の貼合をホットメルト接着
剤の代りにスチレン−ブタ/エン共重合体ラテックスエ
マルンヨンを用い、乾燥後の厚みが60μmとなるよう
にしたこと以外は、実施例]と全く同様にして制振防音
材を得た。
Comparative Example 1 Except for Example 1, except that a styrene-buta/ene copolymer latex emulsion was used instead of the hot melt adhesive to bond the two paperboards together, and the thickness after drying was 60 μm. A vibration-damping and sound-insulating material was obtained in exactly the same manner as in Example].

実施例2 実施例1において、坪Ji600 g / m 2の板
紙2枚を用い、2枚の板紙の貼合に用いるホットメルト
接着剤の厚さを120μmとした以外は、実施例1と全
く同様にして本発明の制振防音材を得た。
Example 2 Completely the same as Example 1 except that in Example 1, two sheets of paperboard with a Tsubo Ji of 600 g/m2 were used and the thickness of the hot melt adhesive used to bond the two sheets of paperboard was 120 μm. The vibration damping and sound insulating material of the present invention was obtained.

実施例3 坪量280g/rn2の板紙2枚を、厚さ40μmのポ
リエチレン押出ラミネートにより貼合し、それとは別に
同様にして貼合した2枚の積層板紙をスチレン−イソプ
レン−スチレン共重合体をベースポリマーとしたホット
メルト接着剤を用い、接着剤の塗工厚さか60μmにな
るように、貼合、積層した。次いで、実施例1と同様に
して、前記積層板紙の上面および下面に合板を貼合して
本発明の制振防音材を得た。
Example 3 Two sheets of paperboard with a basis weight of 280 g/rn2 were laminated with a polyethylene extrusion laminate with a thickness of 40 μm, and separately, two sheets of laminated paperboard laminated in the same manner were laminated with a styrene-isoprene-styrene copolymer. Using a hot-melt adhesive with a base polymer, they were laminated and laminated so that the coating thickness of the adhesive was 60 μm. Next, in the same manner as in Example 1, plywood was bonded to the upper and lower surfaces of the laminated paperboard to obtain a vibration damping and sound insulating material of the present invention.

実施例4 坪量800g/m2の板紙2枚を、前記ホットメルト接
着剤を用い、かつこの接着剤層の厚さが60μmになる
ように貼合、積層し、さらに前記実施例1と同様にして
前記積層板紙の上面、下面に合板を貼合し、本発明の制
振防音材を得た。
Example 4 Two sheets of paperboard with a basis weight of 800 g/m2 were bonded and laminated using the hot melt adhesive so that the thickness of the adhesive layer was 60 μm, and the same procedure as in Example 1 was carried out. Then, plywood was laminated on the upper and lower surfaces of the laminated paperboard to obtain the vibration damping and sound insulating material of the present invention.

比較例2 実施例4において、坪JiLBOOg / m 2の板
紙2枚を、ホットメルト接着剤に代えて、ポリアクリル
酸エステルエマルジョン接着剤(乾燥後に厚さ60μm
)を用いて貼合、積層する以外は、実施例4と全く同様
にして、制振防音材を得た。
Comparative Example 2 In Example 4, two sheets of paperboard of tsubo JiLBOOg/m2 were replaced with a polyacrylic acid ester emulsion adhesive (60 μm thick after drying) instead of the hot melt adhesive.
) A vibration-damping and sound-insulating material was obtained in exactly the same manner as in Example 4, except that the materials were laminated and laminated.

実施例5 実施例1において、ホットメルト接着剤として、スチレ
ン−ブチレン−スチレン共重合体樹脂をベースポリマー
とするホットメルト接着剤を用いた以外は、実施例1と
全く同様にして本発明の制振防音材を得た。
Example 5 The control of the present invention was carried out in exactly the same manner as in Example 1, except that a hot melt adhesive having a styrene-butylene-styrene copolymer resin as the base polymer was used as the hot melt adhesive. Vibration and soundproofing material was obtained.

ここで用いたホットメルト接着剤の粘弾性は、損失弾性
率(G”)が5℃で、4.3 xlO6dyne/cm
 ”20℃で9.1 xlOdyne/cm 2、損失
正接(tanδ)は5℃て1.3.20℃で0.5であ
った。また、カラス転移温度(Tg)は、+4.8℃で
あった。
The viscoelasticity of the hot melt adhesive used here has a loss modulus (G”) of 4.3 xlO6dyne/cm at 5°C.
``9.1 xlOdyne/cm2 at 20℃, loss tangent (tanδ) was 1.3 at 5℃, and 0.5 at 20℃. there were.

実施例6 坪量300g/m2の板紙2枚を実施例1と同様に貼合
し、別に同様に貼合した2枚の積層板紙をスチレン−イ
ソプレン−スチレン共重合体をベスポリマーとするホッ
トメルト接着剤を厚さ60μmになるように用いて接着
させて、板紙が4枚構成の制振防音材層となし、これら
4枚の積層板紙の上面に厚さ9mmの石膏ボードを、下
面にも厚さ91石膏ボートを、それぞれ前記ホットメル
ト接着剤(厚さ20μm)で貼合することにより石膏ボ
ードと組み合わせた割振防音材を得た。
Example 6 Two sheets of paperboard with a basis weight of 300 g/m2 were laminated in the same manner as in Example 1, and two laminated paperboards laminated in the same manner were separately laminated to form a hot melt film using a styrene-isoprene-styrene copolymer as the base polymer. A vibration-damping and sound-insulating material layer consisting of four paperboards was created by bonding them together using an adhesive to a thickness of 60 μm, and a 9mm-thick gypsum board was placed on the top surface of these four laminated paperboards, and on the bottom surface as well. A 91-thick gypsum board was laminated with the hot melt adhesive (thickness: 20 μm) to obtain a soundproofing material combined with a gypsum board.

比較例3 実施例6において、ホットメルト接着剤の代りにスチレ
ン−ブタジェン共重合体ラテックスエマルジョンを用い
た以外は、実施例6と全く同様にして制振防音材を得た
Comparative Example 3 A vibration damping and sound insulating material was obtained in exactly the same manner as in Example 6, except that a styrene-butadiene copolymer latex emulsion was used instead of the hot melt adhesive.

実施例7 実施例6と同様の制振材層で、板紙の上面に厚さ8 m
 / mの硅酸カルシウム板を下面にも厚さ8rn /
 mの硅酸カルシウム板をホットメルト接着材20μm
で貼合させ硅酸カルシウム板に貼合した本発明の制振防
音材を得た。
Example 7 A damping material layer similar to Example 6 with a thickness of 8 m on the top surface of the paperboard.
/ m calcium silicate plate with a thickness of 8rn /
m calcium silicate plate with hot melt adhesive 20μm
A vibration damping and sound insulating material of the present invention was obtained by laminating the material to a calcium silicate plate.

比較例4 実施例7において、板紙2枚の貼合をホットメルト接着
剤の代りに、スチレン−ブタジェン共重合体ラテックス
エマルジョンを用いて行った以外は、実施例7と全く同
様にして制振防音材を得た。
Comparative Example 4 Vibration and soundproofing was carried out in exactly the same manner as in Example 7, except that the two sheets of paperboard were bonded together using a styrene-butadiene copolymer latex emulsion instead of the hot melt adhesive. I got the material.

実施例8 実施例6の構成において、裏面の石膏ボードに代えて、
本発明の制振防音材をコンクリート躯体への直貼り工法
壁として利用した例である。すなわち、実施例6で示す
4枚の板紙をホットメルト接着剤(HM)で積層させて
成る制振防音材の裏面側の板紙部分11に、第7図に示
すようにダンゴ状の直貼り用ホント14を所定の間隔て
配設した上でコンクリート躯体13a (150n+m
厚)と接着させた。この場合には、HM層か均一なフィ
ルム状の膜を形成するので、防湿性も良好でコンクリー
ト躯体からの水分や、直貼り用ボンドからの水分の影響
を受けにくく、また制振材全体がカールすることもない
。更にまた施工時において制振材同志のつき合せも、段
差か発生せずに良好であった。
Example 8 In the configuration of Example 6, instead of the plasterboard on the back side,
This is an example in which the vibration damping and sound insulating material of the present invention is used as a wall that is directly attached to a concrete frame. That is, as shown in FIG. 7, a dumpling-shaped paperboard portion 11 on the back side of the vibration-damping and sound-insulating material made by laminating four paperboards with hot melt adhesive (HM) shown in Example 6 is directly pasted. The concrete frame 13a (150n+m
Thickness) and glued together. In this case, the HM layer forms a uniform film-like membrane, so it has good moisture resistance and is less susceptible to moisture from the concrete structure or moisture from the direct bond, and the damping material as a whole is It doesn't curl either. Furthermore, during construction, the damping materials were in good contact with each other, with no steps occurring.

比較例5 実施例8の構成で、HMの代りに比較例3のスチレンブ
タジェン共重合体ラテックスエマルジョンを用いる以外
は、実施例8と全く同様にして制振防音材を得、前記と
同様にしてコンクリート躯体(150mm厚)と接着さ
せた。この場合にはラテックス中の水分が紙層中に残留
し、またラテックスの均一な連続膜を形成することが難
しく、当然、防湿性も低いので、コンクリート躯体から
の水分や直貼り用ボンドからの水分で、制振材全体かカ
ールし易く、施工時に制振材同志をつき合せると段差か
生し、外観不良となった。
Comparative Example 5 A vibration damping and sound insulating material was obtained in the same manner as in Example 8, except that the styrene-butadiene copolymer latex emulsion of Comparative Example 3 was used in place of HM in the same manner as in Example 8. It was then glued to the concrete frame (150mm thick). In this case, the moisture in the latex remains in the paper layer, and it is difficult to form a uniform continuous film of latex. Naturally, the moisture resistance is also low, so moisture from the concrete frame and the bond for direct application are difficult to form. Moisture tends to cause the entire damping material to curl, and when the damping materials are pressed against each other during construction, a step is formed and the appearance is poor.

実施例9 実施例8において、直貼り用ボンド(第7図参照)に最
も近いホットメルト接着剤(HFvl )をポリエチレ
ンフィルム(厚さ40μm)としたこと以外は、実施例
8と全く同様にしてコンクリート躯体13aと接着させ
た。前記PEが良好な防湿性を示すので、前記実施例と
同様に良好な結果を得た。
Example 9 In Example 8, the procedure was exactly the same as in Example 8, except that the hot melt adhesive (HFvl) closest to the direct attachment bond (see Figure 7) was a polyethylene film (thickness: 40 μm). It was bonded to the concrete frame 13a. Since the PE exhibits good moisture resistance, good results were obtained similar to the examples above.

実施例IO 坪!600 g/rt?の板紙表面にホットメルト接着
剤として、スチレン−ブチレン−スチレン共重合体機能
をヘースポリマーとする、粘着型ホットメルト接着剤を
厚さ60μmとなるようにして、剥離紙の易剥離紙面と
貼合した。この板紙の裏面に坪量600 g/rdの板
紙2枚を実施例1の樹脂エマルジョンで接着して制振材
層とし、さらに、次工程で、表面側を被覆している剥離
紙を剥して後、石膏ボードと貼合して、本発明の制振防
音材を得た。
Example IO Tsubo! 600g/rt? An adhesive type hot melt adhesive having a styrene-butylene-styrene copolymer function as a hese polymer was applied to the paperboard surface to a thickness of 60 μm, and the adhesive was laminated to the easily peelable surface of the release paper. . Two sheets of paperboard with a basis weight of 600 g/rd were adhered to the back side of this paperboard using the resin emulsion of Example 1 to form a damping material layer, and in the next step, the release paper covering the front side was peeled off. Thereafter, it was laminated with a gypsum board to obtain the vibration damping and sound insulating material of the present invention.

以上の実施例、比較例で得た制振防音材の制振防音効果
を示す損失係数を測定した結果を、第1表に示す。
Table 1 shows the results of measuring the loss coefficients indicating the vibration and sound insulation effects of the vibration and sound insulation materials obtained in the above Examples and Comparative Examples.

損失係数の試験方法 実施例、比較例で得られた制振防音材について、機械イ
ンピーダンス法により、周波数を変化させて損失係数を
測定した。損失係数の値が大きい方が、制振防音効果が
大きい。損失係数の値の水準は、使用する積層素材や層
構成によって異なる。
Test method for loss coefficient The loss coefficient of the vibration damping and sound insulating materials obtained in Examples and Comparative Examples was measured by changing the frequency by the mechanical impedance method. The larger the value of the loss coefficient, the greater the vibration damping and soundproofing effect. The level of the loss coefficient value varies depending on the laminated materials and layer configuration used.

損失弾性率(G”)および損失正接(tanδ) 、1
lFI定方法ホットメルト系接着剤の塗装膜について、
ダイナミックアナライザーRDA−700(レオメトリ
ックス・ファーイースト株式会社製)を用いて、1H2
の測定周波数、−50℃〜100℃の温度域で測定した
Loss modulus (G”) and loss tangent (tanδ), 1
Regarding the coating film of lFI method hot melt adhesive,
1H2 using a dynamic analyzer RDA-700 (manufactured by Rheometrics Far East Co., Ltd.)
Measurement was performed at a measurement frequency of -50°C to 100°C.

(以下余白) 実施例11 実施例6と同様の制振防音材層で、板紙(300g/コ
)の上面に厚さ4.0mmの合板を、下面には厚さ9關
の石膏ホードを、それぞれホットメルト接着剤20μm
で貼合させた後、前記の石膏ホード而に制振材層と合板
とを重ねて貼り合せて、床用下地材とした。
(Left below) Example 11 The same vibration-damping and sound-insulating material layer as in Example 6, with 4.0 mm thick plywood on the top surface of paperboard (300 g/piece) and 9 mm thick plaster board on the bottom surface. Hot melt adhesive 20μm each
After lamination, the damping material layer and plywood were layered and laminated on the gypsum board to obtain a floor base material.

以下に、前記実施例における層構成を略記すると、次の
とおりである。
The layer structure in the above example is abbreviated as follows.

合板/板紙/HM/板紙/ HM /板紙/HM/**
/板紙/石膏ホード/板紙//HM/板紙/**/HM
/板紙/HM/板紙/合板、 次いて前記の床用下地ヰ(を根太に固定し、下地材の上
に厚さ1.2m/cによる軽量衝撃音レヘルは、低下し
良好な性能を示した。第12図は、前記実施例の制振防
音材を供試体に用いてのJIN衝撃音測定装置の略図で
あって、図中、符号40は、根太41(根太の間隔!−
300mm)の上に固定した供試体であり、42はフロ
ーリング材、43は前記フローリング材の上面に据置し
た振動源たる夕、ソピングマシン、44は受音測定装置
である。同装置を用いての測定結果は、下記第2表なら
びに別紙第13図に示すとおりである。
Plywood/Paperboard/HM/Paperboard/HM/Paperboard/HM/**
/Paperboard/Gypsum board/Paperboard//HM/Paperboard/**/HM
/Paperboard/HM/Paperboard/Plywood Next, the above-mentioned floor base material was fixed to the joists, and the lightweight impact sound level was lowered by placing the base material on the base material with a thickness of 1.2 m/c, showing good performance. Fig. 12 is a schematic diagram of a JIN impact sound measuring device using the vibration damping and sound insulating material of the above-mentioned example as a specimen.
300 mm), 42 is a flooring material, 43 is a vibration source or soaping machine placed on the upper surface of the flooring material, and 44 is a sound receiving measurement device. The measurement results using the same device are shown in Table 2 below and attached Figure 13.

比較例6 比較例3の板紙複合体を用い、合板、石膏ボード、合板
をそれぞれスチレン−ブタジェン共重合体ラテックスエ
マルジョンを用いて貼り合わせる以外は、実施例11と
同様にして軽量衝撃音を測定した。実施例11に較べ、
効果は不良であって、下記第2表ならびに別紙第13図
に示すとおりである。
Comparative Example 6 Light impact sound was measured in the same manner as in Example 11, except that the paperboard composite of Comparative Example 3 was used and plywood, gypsum board, and plywood were laminated using styrene-butadiene copolymer latex emulsion. . Compared to Example 11,
The effects were poor, as shown in Table 2 below and attached Figure 13.

なお、前記比較例の層構成を、以下に略記する。Note that the layer structure of the comparative example is abbreviated below.

合板/板紙/EM/板紙/EM/板紙/EM/**/板
紙/石膏ボード/板紙/EM/板紙/**/EM/板紙
/EM/板紙/合板 比較例7 合板(厚さ4.0 mm) /石膏ボード(厚さ9.0
 mm)7合板(厚さ4.0關) 比較例8 石膏ボート(厚さ21+nm) 第 表 部 表 以上に説明したように、前記の各実施例のうちの実施例
6ならびに実施例11を、比較例3および比較例6〜8
と対照させつつ、制振防音材の軽量衝撃音特性ならびに
音響透過損失を測定した結果を、別紙第13〜14図に
もグラフとして示した。同グラフからも明らかなように
、本発明によれば、従来型と比較して優れた制振防音特
性をか得られる。
Plywood/Paperboard/EM/Paperboard/EM/Paperboard/EM/**/Paperboard/Gypsum Board/Paperboard/EM/Paperboard/**/EM/Paperboard/EM/Paperboard/Plywood Comparative Example 7 Plywood (thickness 4.0 mm) / gypsum board (thickness 9.0
mm) 7 plywood (thickness: 4.0 mm) Comparative Example 8 Gypsum boat (thickness: 21 + nm) As explained above, Example 6 and Example 11 of the above-mentioned examples were Comparative Example 3 and Comparative Examples 6 to 8
In contrast, the results of measuring the lightweight impact sound characteristics and sound transmission loss of the vibration damping and sound insulating material are also shown in graphs in attached figures 13 and 14. As is clear from the same graph, according to the present invention, superior vibration damping and soundproofing characteristics can be obtained compared to the conventional type.

[発明の効果] 第1表に示した結果によれば、複数枚の板紙を積層させ
るに際して、接着剤としてホットメルト接着剤を用いた
制振防音材(前記実施例146.7参照)は、従来のエ
マルジョン接着剤を用いた比較例1. 2. 3.4に
よる制振防音材に比較して、より損失係数が大きく、制
振防音効果がすくれていることかわかる。また、実施例
1のホットメルト接着剤と別のホットメルト接着剤を使
用した実施例5についても、従来のエマルジョン接着剤
を用いた比較例]より、制振防音効果がすぐれているこ
とが明らかになった。
[Effects of the Invention] According to the results shown in Table 1, when laminating multiple sheets of paperboard, the vibration damping and sound insulating material using hot melt adhesive as the adhesive (see Example 146.7 above) has the following effects: Comparative example 1 using conventional emulsion adhesive. 2. It can be seen that the loss coefficient is larger than that of the vibration damping and sound insulating material according to 3.4, and the vibration damping and sound insulating effect is lower. In addition, it is clear that Example 5, which used the hot melt adhesive of Example 1 and another hot melt adhesive, had better vibration damping and soundproofing effects than the comparative example using a conventional emulsion adhesive. Became.

また、板紙及びホットメルト接着剤の各々の厚さを、実
施例1の2倍に厚くした実施例2の損失係数は、実施例
1の2倍以上になり制振防音効果が大幅に向上する。さ
らに、実施例3のように、2枚の板紙の積層にポリエチ
レンを用いても、両積層板紙をホットメルト接着剤で貼
合することにより、すくれた制振防音材を得ることがで
きることか判明した。なお、合板単体の損失係数は、第
1表に示した各周波数域で、いずれも0.002以下で
あったが、本発明の制振防音材を使用したものは、いず
れも良好な損失係数を示している。
In addition, the loss coefficient of Example 2, in which the thickness of each of the paperboard and hot melt adhesive is twice that of Example 1, is more than twice that of Example 1, and the vibration damping and soundproofing effect is greatly improved. . Furthermore, even if polyethylene is used to laminate two paperboards as in Example 3, it is possible to obtain a vibration-damping and sound-insulating material with a low profile by laminating both laminates with hot-melt adhesive. found. The loss coefficient of the plywood alone was 0.002 or less in each frequency range shown in Table 1, but the loss coefficient of the plywood using the vibration damping and sound insulating material of the present invention was good. It shows.

また、石膏ボート(9mm厚み)2枚を、本発明の板紙
制振防音材を用いずに貼合したものは、第1表に示した
周波数域で、いづれも、0.01以下であったが、本発
明の制振防音材を使用したものは、いづれも良好な損失
係数を示しており、硅酸カルシウム板に対しても同様に
良好な損失係数を示す。
Furthermore, when two sheets of plasterboard (9 mm thick) were laminated together without using the paperboard vibration damping and sound insulating material of the present invention, the frequency range shown in Table 1 was 0.01 or less in all cases. However, all of the materials using the vibration-damping and sound-insulating material of the present invention show good loss coefficients, and similarly good loss coefficients are shown for calcium silicate plates.

前述のように、本発明の制振防音材は、複数枚の板紙を
積層する接着剤としてホットメルト系接着剤を用いるこ
とにより、従来の板紙系積層タイプの割振防音材よりも
制振防音効果のすぐれた制振防音材を得ることができる
ことが確認された。
As mentioned above, the vibration-damping and sound-insulating material of the present invention uses a hot-melt adhesive as the adhesive for laminating multiple sheets of paperboard, so it has better vibration-damping and sound-insulating effects than conventional paperboard-based laminated type vibration-damping and sound-insulating materials. It was confirmed that it is possible to obtain an excellent vibration-damping and sound-insulating material.

その結果、従来の制振ゴムなとの制振材料を用いた場合
の問題点も解消されると共に、すくれた制振防音性を兼
ね備えた制振防音材を提供し得、住宅等の建材及びその
他の住宅機器、家庭電化製品、自動車等に用いて有効な
制振防音材料か得られる。
As a result, the problems associated with using conventional vibration damping materials such as damping rubber can be solved, and a vibration damping and sound insulating material with excellent vibration damping and sound insulating properties can be provided. Also, it is possible to obtain vibration-damping and sound-insulating materials that are effective for use in other housing equipment, home appliances, automobiles, etc.

4、4,

【図面の簡単な説明】[Brief explanation of drawings]

第1図aは、本発明における非拘束型の制振防音材を模
式的に示した断面図、第1−図すは、前記制振防音材か
振動源または騒音源からの固体伝搬音または空気伝搬音
の影響を受けて作動した状態を模式的に示した断面図、
第2図a、  bは、同しく拘束型の制振防音材と、そ
のものの挙動を示した模式的断面図、第3〜4図は本発
明における制振防音材を石膏ボードなどの被貼付体13
に貼り付けた状態を示す斜視図であって、第3図は片面
型、第4図は両面型を示す。第5図は本方法を実施する
場合に用いるニーダ−・ルーダーの一例を示す正面図、
第6図は、第5図の■−■線における断面図、第7〜8
図は、HM接着剤を板紙に適用する場合に使用するスリ
ットダイの一例を示す断面図、第9図は同しくロールコ
ータ一方式の一例を示す断面図、第10図は、同じくロ
ールコータ一方式で板紙2枚をホットメルト接着剤で積
層させる装置の骨格的断面図、第11図は本発明の制振
防音材を石膏ボードとコンクリート躯体の間に適用した
場合を示す断面図、第12図は軽量衝撃音測定装置の概
要を示す略図、第13図は軽量衝撃音レベルの測定結果
を示すグラフ、第14図は、音響透過損失について本発
明の制振防音材単板と石膏ボード単板とを比較して示し
たグラフである。 11・・・板紙層、   12・・・ホットメルト接着
剤層、13・・・被貼付体(素材)   14・・・直
貼り用ボンド、20・・・フレーム、21・・・プレミ
キサ22・・・モータ、    21a・・・攪拌羽根
、23・・・ニーダ−124・・・配管、25・・・エ
クストルーダ26、27・・ラミネーター、28・・・
ロールコータ30・・・貯槽、      31・・・
供給管、32・・・送りポンプ、   33・・・パン
、34・・コーティングロール、35・・計量ロール、
36a、36b・・・圧着ロール、 37・・案内ロー
ル、40・・・供試体、 41・・・根太、 42・・
フローリング材、43・・・タッピング、   44・
・・受音測定装置。
FIG. 1a is a cross-sectional view schematically showing the non-restrictive vibration damping and sound insulating material of the present invention, and FIG. A cross-sectional diagram schematically showing a state in which it operates under the influence of airborne sound,
Figures 2a and 2b are schematic cross-sectional views showing the restraint-type vibration-damping and sound-insulating material and its behavior. body 13
FIG. 3 is a perspective view showing a state in which it is pasted on a paper, and FIG. 3 shows a single-sided type, and FIG. 4 shows a double-sided type. FIG. 5 is a front view showing an example of a kneader/ruder used when carrying out this method;
Figure 6 is a sectional view taken along the line ■-■ in Figure 5, and sections 7 to 8.
The figure is a sectional view showing an example of a slit die used when applying HM adhesive to paperboard, FIG. 9 is a sectional view showing an example of a roll coater type, and FIG. Figure 11 is a cross-sectional view of the structure of a device that laminates two sheets of paperboard with hot melt adhesive using a hot melt adhesive method. Fig. 13 is a graph showing the measurement results of the light impact sound level, and Fig. 14 shows the sound transmission loss of the vibration damping and sound insulating material veneer of the present invention and the gypsum board veneer. It is a graph showing a comparison with the board. DESCRIPTION OF SYMBOLS 11... Paperboard layer, 12... Hot melt adhesive layer, 13... Target object (material) 14... Bond for direct attachment, 20... Frame, 21... Premixer 22... - Motor, 21a... Stirring blade, 23... Kneader 124... Piping, 25... Extruder 26, 27... Laminator, 28...
Roll coater 30...storage tank, 31...
Supply pipe, 32...Feeding pump, 33...Bread, 34...Coating roll, 35...Measuring roll,
36a, 36b...Crimping roll, 37...Guide roll, 40...Specimen, 41...Joist, 42...
Flooring material, 43... Tapping, 44.
...Sound measurement device.

Claims (1)

【特許請求の範囲】 1、少なくとも1層の板紙に、少なくとも1層の合成層
を積層した板紙系制振防音材において、合成樹脂層がホ
ットメル塗工剤またはホットメルト接着剤をホットメル
ト塗工により形成されたことを特徴とする制振防音材。 2、坪量が250〜650g/m^2の板紙を、エチレ
ン−酢酸ビニル共重合体、スチレン系共重合体、ポリエ
チレン、ポリアミド、ポリエステル、ポリプロピレン等
のベースポリマーに、粘着付与剤、可塑剤、軟化剤、充
填剤、ワックス類、酸化防止剤などの助剤を適宜配合し
て成るホットメルト系接着剤で、かつ0℃〜40℃の範
囲における該接着剤の損失弾性率(G”)が10^4〜
10^8dyne/cm^2であり、さらに損失正接(
tanδ)のピークが0℃〜40℃の範囲にあって、そ
のピーク値が0.3〜3.0であるホットメルト系接着
剤を用い、かつその工塗厚みが少なくとも30μmとな
るようにして接着させたことを特徴とする制振防音材。 3、複数枚の板紙をホットメルト系接着剤を用いて貼合
、積層したものの片面または両面に合板、石膏ボード、
パーチクルボードを貼合して成る制振防音材。 4、ホットメルト系接着剤をニーダー・ルーダーを使用
して混練と溶融ならびに脱水を行った上で、スリットダ
イから薄膜状に押出しながら板紙の表面にラミネートし
たことを特徴とする制振防音材の製造法。
[Claims] 1. In a paperboard-based vibration damping and sound insulating material in which at least one synthetic layer is laminated on at least one paperboard layer, the synthetic resin layer is hot-melt coated with a hot-melt coating agent or a hot-melt adhesive. A vibration-damping and sound-insulating material characterized by being formed by. 2. Paperboard with a basis weight of 250 to 650 g/m^2 is mixed with a base polymer such as ethylene-vinyl acetate copolymer, styrene copolymer, polyethylene, polyamide, polyester, polypropylene, etc., and a tackifier, plasticizer, A hot-melt adhesive that is appropriately blended with auxiliary agents such as softeners, fillers, waxes, and antioxidants, and whose loss modulus (G'') in the range of 0°C to 40°C 10^4〜
10^8dyne/cm^2, and the loss tangent (
A hot melt adhesive having a peak value of tan δ) in the range of 0°C to 40°C and a peak value of 0.3 to 3.0 is used, and the final coating thickness is at least 30 μm. A vibration-damping and sound-insulating material characterized by being bonded. 3. Plywood, gypsum board, or laminate on one or both sides of multiple sheets of paperboard pasted and laminated using hot melt adhesive.
A vibration-damping and sound-insulating material made by laminating particle boards. 4. A vibration damping and sound insulating material characterized by kneading, melting and dehydrating hot melt adhesive using a kneader/ruder, extruding it into a thin film from a slit die and laminating it on the surface of paperboard. Manufacturing method.
JP2238970A 1990-09-11 1990-09-11 Vibration damping and soundproofing material and its manufacturing method Expired - Fee Related JPH0624815B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2238970A JPH0624815B2 (en) 1990-09-11 1990-09-11 Vibration damping and soundproofing material and its manufacturing method
KR1019900021097A KR950010584B1 (en) 1990-09-11 1990-12-19 Vibration dampening material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2238970A JPH0624815B2 (en) 1990-09-11 1990-09-11 Vibration damping and soundproofing material and its manufacturing method

Publications (2)

Publication Number Publication Date
JPH04119839A true JPH04119839A (en) 1992-04-21
JPH0624815B2 JPH0624815B2 (en) 1994-04-06

Family

ID=17038002

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (2)

Country Link
JP (1) JPH0624815B2 (en)
KR (1) KR950010584B1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998015407A1 (en) * 1996-10-08 1998-04-16 H.B. Fuller Licensing & Financing, Inc. Laminating method and hot melt adhesive
WO2006054481A1 (en) * 2004-11-17 2006-05-26 Japan Tobacco Inc. Cigarette package, wrapping paper for cigarette package, and method and machine for manufacturing wrapping paper
JP2019501983A (en) * 2015-10-30 2019-01-24 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンHenkel AG & Co. KGaA Damping hot melt composition
JP2021523031A (en) * 2018-05-01 2021-09-02 ユナイテッド・ステイツ・ジプサム・カンパニー Methods for making high sound transmission class gypsum boards and gypsum boards made by those methods

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6453661A (en) * 1987-08-24 1989-03-01 Nec Corp Station data and subscriber data control device
JPH03167389A (en) * 1989-11-24 1991-07-19 Nisshin Kogyo Kk Soundproof sheet for use in floor and soundproofing method for floor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6453661A (en) * 1987-08-24 1989-03-01 Nec Corp Station data and subscriber data control device
JPH03167389A (en) * 1989-11-24 1991-07-19 Nisshin Kogyo Kk Soundproof sheet for use in floor and soundproofing method for floor

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998015407A1 (en) * 1996-10-08 1998-04-16 H.B. Fuller Licensing & Financing, Inc. Laminating method and hot melt adhesive
WO2006054481A1 (en) * 2004-11-17 2006-05-26 Japan Tobacco Inc. Cigarette package, wrapping paper for cigarette package, and method and machine for manufacturing wrapping paper
JP2019501983A (en) * 2015-10-30 2019-01-24 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンHenkel AG & Co. KGaA Damping hot melt composition
JP2021523031A (en) * 2018-05-01 2021-09-02 ユナイテッド・ステイツ・ジプサム・カンパニー Methods for making high sound transmission class gypsum boards and gypsum boards made by those methods

Also Published As

Publication number Publication date
JPH0624815B2 (en) 1994-04-06
KR920006114A (en) 1992-04-27
KR950010584B1 (en) 1995-09-20

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