JPH04103339A - Method for forming three-dimensional objects - Google Patents
Method for forming three-dimensional objectsInfo
- Publication number
- JPH04103339A JPH04103339A JP22204290A JP22204290A JPH04103339A JP H04103339 A JPH04103339 A JP H04103339A JP 22204290 A JP22204290 A JP 22204290A JP 22204290 A JP22204290 A JP 22204290A JP H04103339 A JPH04103339 A JP H04103339A
- Authority
- JP
- Japan
- Prior art keywords
- dimensional object
- photocurable resin
- forming
- slice
- piece
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
Abstract
Description
【発明の詳細な説明】
〔概 要〕
光硬化性樹脂を層状に積層して立体形状物を形成する立
体形状物の形成方法に関し、
滑らかな表面を有する立体形状物を短時間で形成するこ
とを可能にする立体形状物の形成方法の捷供を目的とし
、
硬化させた光硬化性樹脂の表面に未硬化で液状の光硬化
性樹脂の被着と、
未硬化の光硬化性樹脂の光の照射による硬化とを交互に
操り返し、
光硬化性樹脂を層状に積層して立体形状物を形成する立
体形状物の形成方法において、立体形状物の表層領域の
積層密度は、その中実領域の積層密度より高くするよう
に構成する。[Detailed Description of the Invention] [Summary] A method for forming a three-dimensional object in which a three-dimensional object is formed by laminating photocurable resins in layers, the object of which is to form a three-dimensional object with a smooth surface in a short time. The aim is to develop a method for forming three-dimensional objects that enables the formation of three-dimensional objects, by depositing an uncured liquid photocurable resin on the surface of a cured photocurable resin, and by exposing the uncured photocurable resin to light. In a method for forming a three-dimensional object in which a three-dimensional object is formed by laminating photocurable resin in layers, the lamination density of the surface layer region of the three-dimensional object is equal to that of the solid area. The stacking density is higher than that of .
本発明は、光硬化性樹脂を層状に積層して立体形状物を
形成する立体形状物の形成方法、特に滑らかな表面を有
する立体形状物を短時間で形成できる立体形状物の形成
方法に関する。The present invention relates to a method for forming a three-dimensional object by laminating layers of photocurable resin to form a three-dimensional object, and particularly to a method for forming a three-dimensional object by which a three-dimensional object having a smooth surface can be formed in a short time.
近年の商品開発期間の短縮、商品デザインの多様化等の
要求から、商品開発段階において数多くの商品モデルを
短期間で作成することが益々重要となっている。2. Description of the Related Art Due to recent demands for shortening product development periods, diversifying product designs, etc., it has become increasingly important to create a large number of product models in a short period of time at the product development stage.
このような商品モデルを形成するための方法として、硬
化させた光硬化性樹脂の表面に、例えば0.1〜0.5
mm程度の厚さで未硬化で液状の光硬化性樹脂の被着と
、
光軸に垂直な断面の直径が0.1〜5mm程度のビーム
状の光、例えばレーザ光を未硬化の光硬化性樹脂に照射
して硬化することを交互に複数回、例えば何百回も繰り
返し、光硬化性樹脂を何百層にも積層して立体形状物を
形成する立体形状物の形成方法がある。As a method for forming such a product model, for example, 0.1 to 0.5
Deposition of uncured liquid photocurable resin with a thickness of approximately 1.0 mm, and photocuring of uncured resin using a beam of light, such as a laser beam, with a cross-sectional diameter of approximately 0.1 to 5 mm perpendicular to the optical axis. There is a method for forming a three-dimensional object in which the process of irradiating and curing a photocurable resin is alternately repeated multiple times, for example, hundreds of times, and hundreds of layers of photocurable resin are laminated to form a three-dimensional object.
尚、未硬化の光硬化性樹脂へのレーザ光の照射領域は、
三次元CAD (computer−aided de
sign)により得られた三次元座標データの商品モデ
ルを高さ方向に所定間隔、例えば0.1〜0.5mm程
度の厚さでスライスした際に、それぞれのスライス片の
輪郭線内、即ち商品モデルの中実部と対応するものであ
る。The irradiation area of the laser beam on the uncured photocurable resin is as follows:
Three-dimensional CAD (computer-aided design)
When slicing the product model of the three-dimensional coordinate data obtained by ``sign'' in the height direction at predetermined intervals, for example, at a thickness of about 0.1 to 0.5 mm, the product model within the contour line of each slice, that is, the product This corresponds to the solid part of the model.
〔従来の技術〕
次に、従来の立体形状物の形成方法にフいて、第2図を
参照しながら説明する。[Prior Art] Next, a conventional method for forming a three-dimensional object will be explained with reference to FIG.
第2図は、従来の立体形状物の形成方法を説明するため
の図で、同図(a)は工程順側断面図、同図(b)はB
−B線断面図、同図(c)と同図(e)は側断面の側面
輪郭線が直線となる立体形状物の部分側断面図、同図(
d)は側断面の側面輪車3線が曲線となる立体形状物の
部分側断面図である。FIG. 2 is a diagram for explaining a conventional method for forming a three-dimensional object.
-B sectional view, the same figure (c) and the same figure (e) are partial side sectional views of the three-dimensional object whose side profile line of the side cross section is a straight line, the same figure (
d) is a partial side sectional view of a three-dimensional object in which the three lines of the side wheels in the side section are curved.
尚、同じ部品・材料に対しては全図を通して同じ記号を
付与しである。Note that the same symbols are given to the same parts and materials throughout the drawings.
同図(a)に示すように従来の゛′立体形状物の形成方
法゛により光硬化性樹脂よりなるスライス片Sl、 S
2. ・・、Snを積層するが如(して立体形状物1
1を形成するには、
まず、同図(a)の(イ)に示すように、先端にテーブ
ル13を水平にして固定したプランジャー15を矢印り
方向、すなわち垂直下方に突き出し、容器12に貯蔵し
た未硬化で液状の光硬化性樹脂10の中にテーブル13
をゆっくりと沈める。As shown in the same figure (a), slice pieces Sl and S made of photocurable resin are made by the conventional ``method of forming three-dimensional objects''.
2. . . . As if Sn were laminated (thus, three-dimensional object 1
1, first, as shown in (a) of FIG. A table 13 is placed in the stored uncured liquid photocurable resin 10.
Slowly sink.
そして、テーブル13の表面と光硬化性樹脂10の液面
10aとの間の距離がΔZ、例えば0.5 m mにな
ったところでプランジャー15の突き出しを一時的に停
止する。Then, when the distance between the surface of the table 13 and the liquid level 10a of the photocurable resin 10 reaches ΔZ, for example, 0.5 mm, the thrusting of the plunger 15 is temporarily stopped.
次いで、光硬化性樹脂10を短時間で硬化する紫外HM
SN域の光を含んだ光、例えば325ナノメータの波
長の光を含むHe−Cdレーザ発振器(図示せず)が発
生するレーザ光線14を同図(b)の点線で示す領域A
内を隈無く照射すると、この領域A内の光硬化性樹脂1
0が硬化し、光硬化性樹脂10゛よりなる厚さΔ2のス
ライス片S、がテーブル13上に形成される。Next, ultraviolet HM cures the photocurable resin 10 in a short time.
A laser beam 14 generated by a He-Cd laser oscillator (not shown) containing light in the SN range, for example, light with a wavelength of 325 nanometers, is shown in area A by the dotted line in FIG.
When the inside is irradiated thoroughly, the photocurable resin 1 in this area A
0 is cured, and a slice piece S having a thickness of Δ2 made of photocurable resin 10° is formed on the table 13.
この後、再びプランジャー15を更にΔZだけ垂直下方
に突き出し、前記した要領にしたがってレーザ光線14
により光硬化性樹脂10を硬化すると、スライス片SI
上に厚さΔZのスライス片S2が積層された状態で形成
される。After this, the plunger 15 is further projected vertically downward by ΔZ again, and the laser beam 14 is
When the photocurable resin 10 is cured by
A slice piece S2 having a thickness of ΔZ is stacked thereon.
かかるプランジャー15の垂直下方へのΔZ単位の突き
出しとレーザ光線14の光硬化性樹脂10への照射とを
交互にn回繰り返すことにより、立体形状物11が形成
されることとなる。The three-dimensional object 11 is formed by alternately repeating the vertical downward protrusion of the plunger 15 by ΔZ units and the irradiation of the laser beam 14 onto the photocurable resin 10 n times.
第2図の(c)図及び(d)図において二点鎖線で示す
ように、立体形状物11の本来の側断面の側面輪郭線は
滑らかである。As shown by the two-dot chain line in FIGS. 2(c) and 2(d), the side profile of the original side cross section of the three-dimensional object 11 is smooth.
ところが、立体形状物11は、同図(c)〜同図(d)
に示すように厚さがΔ2で端面が垂直に切り立ったスラ
イス片Sl+ S2.・・、Snを積層して形成してい
る。However, the three-dimensional object 11 is
As shown in , the slice piece Sl+ S2. has a thickness of Δ2 and has a vertical end face. ..., formed by laminating Sn.
このため、立体形状物11の側断面の側面輪郭線は、同
図(c)〜同図(d)に示すように階段状となって、立
体形状物11の本来の側断面の側面輪郭線とは大きく相
違していた。Therefore, the side profile of the side cross section of the three-dimensional object 11 becomes step-like, as shown in FIGS. It was very different from that.
このような立体形状物11の側断面の階段状の側面輪郭
線を、立体形状物11の本来の側断面の側面輪郭線に近
づけるには、同図(c)〜同図(d)のスライス片SI
+ S2.・・、Snよりも薄いスライス片TI+ T
t、・・、Tw (スライス片Sl、St、・・、Sn
のそれぞれの厚さはΔYであり、ΔYくΔZ)を積層密
度を高くして積層すれば良いことは自明である。In order to bring the step-like side profile of the side cross section of the three-dimensional object 11 closer to the side profile of the original side cross section of the three-dimensional object 11, the slices shown in FIGS. Single SI
+S2. ..., slice piece thinner than Sn TI+T
t,..., Tw (slice pieces Sl, St,..., Sn
The thickness of each layer is ΔY, and it is obvious that ΔY×ΔZ) can be laminated with a high lamination density.
しかしながら、このような方法で立体形状物11を形成
するには、その形成のための時間が非常に長くなるとい
う問題があった。However, forming the three-dimensional object 11 using such a method has a problem in that it takes a very long time to form.
本発明は、かかる問題を解消するためになされたもので
、その目的は滑らかな表面を有する立体形状物を短時間
で形成することを可能にする立体形状物の形成方法の提
供にある。The present invention has been made to solve this problem, and its purpose is to provide a method for forming a three-dimensional object that makes it possible to form a three-dimensional object with a smooth surface in a short time.
[課題を解決するための手段]
前記目的は、第1図に示すように硬化させた光硬化性樹
脂の表面に未硬化で液状の光硬化性樹脂の被着と、
未硬化の前記光硬化性樹脂の光の照射による硬化とを交
互に繰り返し、
光硬化性樹脂を層状に積層した立体形状物を形成する立
体形状物の形成方法において、立体形状物11の表層領
域11aの積層密度は、その中実領域11bの積層密度
より高くすることを特徴とする立体形状物の形成方法で
達成される。[Means for Solving the Problems] The object is to deposit an uncured liquid photocurable resin on the surface of a cured photocurable resin as shown in FIG. In the method for forming a three-dimensional object in which a three-dimensional object is formed by laminating photo-curable resin in layers by repeating alternately curing the photo-curable resin by irradiation with light, the lamination density of the surface region 11a of the three-dimensional object 11 is as follows: This is achieved by a method for forming a three-dimensional object characterized by making the stacking density higher than that of the solid region 11b.
本発明の立体形状物の形成方法においては、立体形状物
11の表層領域11aの積層密度だけを、その中実領域
11bの積層密度より高くしている。In the method for forming a three-dimensional object of the present invention, only the layer density of the surface layer region 11a of the three-dimensional object 11 is made higher than the layer density of the solid region 11b.
従って、本発明は、滑らかな表面を有する立体形状物を
短時間で形成することを可能にする。Therefore, the present invention makes it possible to form a three-dimensional object with a smooth surface in a short time.
以下、本発明の一実施例の立体形状物の形成方法につい
て第1図を参照しながら説明する。Hereinafter, a method for forming a three-dimensional object according to an embodiment of the present invention will be described with reference to FIG.
第1図は、本発明の一実施例の立体形状物の形成方法を
説明するための図で、同図(a)は立体形状物の形成工
程順を示す要部概略側断面図、同図(b)は立体形状物
の模式的側断面図である。FIG. 1 is a diagram for explaining a method for forming a three-dimensional object according to an embodiment of the present invention, and FIG. (b) is a schematic side sectional view of a three-dimensional object.
本発明の一実施例の立体形状物の形成方法は、光硬化性
樹脂としてはエポキシ系の光硬化性樹脂を、またこの光
硬化性樹脂を感光して硬化する光としては紫外線領域の
光、例えば波長が325ナノメータの光を含んだレーザ
光線14を使用し、同図(b)に示す如く表層領域11
aの積層密度が中実領域11bの積層密度より高い立体
形状物11を従来の方法よりも短時間で効率良く形成で
きるように構成したものである。In the method for forming a three-dimensional object according to an embodiment of the present invention, an epoxy-based photocurable resin is used as the photocurable resin, and light in the ultraviolet region is used as the light for exposing and curing the photocurable resin. For example, by using a laser beam 14 containing light with a wavelength of 325 nanometers, as shown in FIG.
The structure is such that a three-dimensional object 11 in which the stacking density of a is higher than the stacking density of the solid region 11b can be formed more efficiently in a shorter time than with conventional methods.
すなわち、本発明の一実施例は、テーブル13上に中実
領域11bとなるスライス片S、を形成してから、表層
領域11aとなるサブスライス片SII+ Sl□。That is, in one embodiment of the present invention, after forming the slice piece S that will become the solid region 11b on the table 13, the sub-slice piece SII+Sl□ that will become the surface layer region 11a.
StSをこの順にスライス片SLの外周に固着して形成
し、次いでスライス片S、上に中実領域11bとなるス
ライス片S2を積層した状態で形成してから、表層領域
11aとなるサブスライス片Sz+、 Szz、 St
、をこの順にスライス片S2の外周に固着させて形成し
、同図(b)に示すような光硬化性樹脂を積層した立体
形状物を完成するものである。StS is formed by fixing it to the outer periphery of the slice piece SL in this order, and then the slice piece S is formed with the slice piece S2 which becomes the solid region 11b stacked thereon, and then the sub-slice piece which becomes the surface layer region 11a is formed. Sz+, Szz, St
are fixed to the outer periphery of the sliced piece S2 in this order to complete a three-dimensional object laminated with photocurable resin as shown in FIG. 2(b).
次に、本発明の立体形状物の形成方法について、同図(
a)及び同図(b)を参照しながら詳細に説明する。Next, the method for forming a three-dimensional object according to the present invention will be explained in the same figure (
This will be explained in detail with reference to a) and FIG.
まず、テーブル13上に立体形状物11のスライス片S
Iを形成するために、容器12内に収納したテーブル1
30表面に下端面を固着したプランジャー15を矢印り
方向に垂直に突き出し、テーブル13の表面と容器12
内の光硬化性樹脂10の液面10aとの間の距離がスラ
イス片S、の厚さに相当するΔZ1例えは0.4mmに
なったらところでプランジャー15の突き出しを一時的
に停止する((イ)図参照))。First, a slice S of the three-dimensional object 11 is placed on the table 13.
Table 1 housed in container 12 to form I
The plunger 15 with its lower end fixed to the surface of the table 13 and the container 12 are projected vertically in the direction of the arrow.
When the distance between the liquid surface 10a of the photocurable resin 10 and the liquid surface 10a becomes ΔZ1, which corresponds to the thickness of the slice piece S, for example, 0.4 mm, the thrusting of the plunger 15 is temporarily stopped (( b) See figure)).
この後、レーザ光線14を第1図の(b)図に示す如く
スライス片S、となる光硬化性樹脂lOの表面に照射し
、スライス片S+を形成する。Thereafter, as shown in FIG. 1(b), a laser beam 14 is irradiated onto the surface of the photocurable resin lO, which will become the slice piece S, to form a slice piece S+.
次いで、プランジャー15を矢印りと逆方向、即ち矢印
D゛方向引き込み、テーブル13の表面と光硬化性樹脂
10の液面10aとの間の距離がΔY、例えばΔY=0
.1mmになったらところでプランジャー15の引き込
みを一時的に停止する((ロ)図参照))。Next, the plunger 15 is pulled in the direction opposite to the arrow mark, that is, in the direction of the arrow D', until the distance between the surface of the table 13 and the liquid level 10a of the photocurable resin 10 is ΔY, for example, ΔY=0.
.. When it reaches 1 mm, the retraction of the plunger 15 is temporarily stopped (see figure (b))).
しかる後、前述した如く同図(b)の立体形状物11の
表層領域11aを構成するサブスライス片S目となる領
域に該当する光硬化性樹脂lOの表面に、レーザ光線1
4を照射し、スライス片Slの周囲に固着したサブスラ
イス片Sllを形成する。Thereafter, as described above, a laser beam 1 is applied to the surface of the photocurable resin lO corresponding to the area corresponding to the Sth sub-slice piece constituting the surface area 11a of the three-dimensional object 11 shown in FIG.
4 to form a sub-slice piece Sll fixed around the slice piece Sl.
かかる方法を繰り返して実行することによりスライス片
S1の周囲に固着したサブスライス片S、1゜SIl+
Sl!が形成されることとなる((ハ)及び(ニ)図
参照)。By repeatedly performing this method, the sub-slice piece S fixed around the slice piece S1, 1° SIl+
Sl! will be formed (see figures (c) and (d)).
次いで、スライス片S2を形成するために、プランジャ
ー15を再び矢印り方向に垂直に突き出し、スライス片
SIの表面と光硬化性樹脂10の液面10aとの間の距
離がΔZになったところでプランジャー15の突き出し
を一時的に停止し、スライス片S1を形成した上記要領
に従ってスライス片S2を形成する((ホ)参照)。Next, in order to form the slice piece S2, the plunger 15 is again projected perpendicularly in the direction of the arrow, and when the distance between the surface of the slice piece SI and the liquid level 10a of the photocurable resin 10 becomes ΔZ, The protrusion of the plunger 15 is temporarily stopped, and a slice S2 is formed according to the procedure described above for forming the slice S1 (see (e)).
この後、サブスライス片5IIJIL 513の形成を
した上記要領により、スライス片S2の周囲にサブスラ
イス片Sz++ S!!、 Stsを形成すると同図(
b)の立体形状物11が完成する。Thereafter, by the above procedure for forming the sub-slice piece 5IIJIL 513, a sub-slice piece Sz++ S! is formed around the slice piece S2. ! , the same figure (
The three-dimensional object 11 of b) is completed.
前述したように本発明の立体形状物の形成方法は、サブ
スライス片を積層してなる表層領域の積層密度を高く、
スライス片を積層してなる中実領域の積層密度は低くし
て立体形状物を形成するものである。As mentioned above, the method for forming a three-dimensional object of the present invention increases the lamination density of the surface layer region formed by laminating subslice pieces,
The stacking density of the solid region formed by stacking slice pieces is made low to form a three-dimensional object.
従って、本発明の立体形状物の形成方法は、滑らかな表
面を有する立体形状物を短時間で形成することを可能に
することとなる。Therefore, the method for forming a three-dimensional object of the present invention makes it possible to form a three-dimensional object with a smooth surface in a short time.
[発明の効果〕
以上の説明から明らかなように本発明によれば、滑らか
な表面を有する立体形状物を短時間で形成することを可
能にすることとなる。[Effects of the Invention] As is clear from the above description, according to the present invention, it becomes possible to form a three-dimensional object having a smooth surface in a short time.
第1図は、本発明の一実施例の立体形状物の形成方法を
説明するための図、
第2図は、従来の立体形状物の形成方法を説明するため
の図である。
図において、
10は未硬化の光硬化性樹脂、
lO′は硬化法の光硬化性樹脂、
11は立体形状物、
11aは立体形状物の表層領域、
11bは立体形状物の中実領域、
12は容器、
13はテーブル、
14はレーザ光線、
15はプランジャーをそれぞれ示す。FIG. 1 is a diagram for explaining a method for forming a three-dimensional object according to an embodiment of the present invention, and FIG. 2 is a diagram for explaining a conventional method for forming a three-dimensional object. In the figure, 10 is an uncured photocurable resin, lO' is a photocurable resin in a curing method, 11 is a three-dimensional object, 11a is a surface region of the three-dimensional object, 11b is a solid region of the three-dimensional object, 12 13 is a container, 14 is a laser beam, and 15 is a plunger.
Claims (1)
性樹脂の被着と、 未硬化の前記光硬化性樹脂の光の照射による硬化とを交
互に繰り返し、 光硬化性樹脂を層状に積層した立体形状物を形成する立
体形状物の形成方法において、 前記立体形状物の表層領域の積層密度は、その中実領域
の積層密度より高くすることを特徴とする立体形状物の
形成方法。[Claims] Alternately repeating the deposition of an uncured liquid photocurable resin on the surface of the cured photocurable resin and the curing of the uncured photocurable resin by irradiation with light, A method for forming a three-dimensional object in which a three-dimensional object is formed by laminating photocurable resin in layers, characterized in that the lamination density of the surface region of the three-dimensional object is higher than the lamination density of the solid region thereof. A method for forming three-dimensional objects.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22204290A JPH04103339A (en) | 1990-08-22 | 1990-08-22 | Method for forming three-dimensional objects |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22204290A JPH04103339A (en) | 1990-08-22 | 1990-08-22 | Method for forming three-dimensional objects |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04103339A true JPH04103339A (en) | 1992-04-06 |
Family
ID=16776180
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22204290A Pending JPH04103339A (en) | 1990-08-22 | 1990-08-22 | Method for forming three-dimensional objects |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04103339A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05169550A (en) * | 1991-12-26 | 1993-07-09 | Sony Corp | Optically molding method |
EP0604738A1 (en) * | 1992-12-29 | 1994-07-06 | Kimberly-Clark Corporation | Laminating method and products made thereby |
JPH09286058A (en) * | 1996-04-23 | 1997-11-04 | Matsushita Electric Works Ltd | Formation of three-dimensional shape |
WO2003016031A1 (en) * | 2001-08-16 | 2003-02-27 | Riken | Rapid prototyping method and device using v-cad data |
CN104149241A (en) * | 2014-07-31 | 2014-11-19 | 苏州市华宁机械制造有限公司 | Photo-curing molding device |
WO2017126094A1 (en) * | 2016-01-22 | 2017-07-27 | 株式会社日立製作所 | Laminated shaped object and device including same, and shaping method |
-
1990
- 1990-08-22 JP JP22204290A patent/JPH04103339A/en active Pending
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05169550A (en) * | 1991-12-26 | 1993-07-09 | Sony Corp | Optically molding method |
EP0604738A1 (en) * | 1992-12-29 | 1994-07-06 | Kimberly-Clark Corporation | Laminating method and products made thereby |
US5455074A (en) * | 1992-12-29 | 1995-10-03 | Kimberly-Clark Corporation | Laminating method and products made thereby |
US5578369A (en) * | 1992-12-29 | 1996-11-26 | Kimberly-Clark Corporation | Laminating method and products made thereby |
JPH09286058A (en) * | 1996-04-23 | 1997-11-04 | Matsushita Electric Works Ltd | Formation of three-dimensional shape |
WO2003016031A1 (en) * | 2001-08-16 | 2003-02-27 | Riken | Rapid prototyping method and device using v-cad data |
CN104149241A (en) * | 2014-07-31 | 2014-11-19 | 苏州市华宁机械制造有限公司 | Photo-curing molding device |
WO2017126094A1 (en) * | 2016-01-22 | 2017-07-27 | 株式会社日立製作所 | Laminated shaped object and device including same, and shaping method |
JPWO2017126094A1 (en) * | 2016-01-22 | 2018-01-25 | 株式会社日立製作所 | Laminated shaped article, apparatus having the same, and shaping method |
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