JPH0343745A - Pressure sensitive transfer film - Google Patents
Pressure sensitive transfer filmInfo
- Publication number
- JPH0343745A JPH0343745A JP1178819A JP17881989A JPH0343745A JP H0343745 A JPH0343745 A JP H0343745A JP 1178819 A JP1178819 A JP 1178819A JP 17881989 A JP17881989 A JP 17881989A JP H0343745 A JPH0343745 A JP H0343745A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- film
- toner
- adhesive layer
- copying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010410 layer Substances 0.000 claims abstract description 44
- 239000012790 adhesive layer Substances 0.000 claims abstract description 31
- 239000011241 protective layer Substances 0.000 claims abstract description 12
- 239000002985 plastic film Substances 0.000 claims abstract description 9
- 229920006255 plastic film Polymers 0.000 claims abstract description 9
- 230000001070 adhesive effect Effects 0.000 abstract description 10
- 239000000853 adhesive Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 229920002799 BoPET Polymers 0.000 description 8
- 239000002904 solvent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000007740 vapor deposition Methods 0.000 description 4
- 239000000123 paper Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 210000004905 finger nail Anatomy 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 241000220150 Eucryphia lucida Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Landscapes
- Fixing For Electrophotography (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明はトナー転写システムに関する感圧転写フィル
ムに係るものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a pressure sensitive transfer film related to a toner transfer system.
（従来の技術）
トナーにより複写をするいわゆる乾式コピーには、コピ
ー用紙として各種の紙類が使用されている。しかし、極
薄紙や厚紙、凹凸のあるレザー木材、金属、ガラス、プ
ラスチック板等には直接にコピー出来ないところから、
いわゆるトナー転写システムが採用されている。それは
、予め離型層を形成したＰＥＴフィルムにコピーをして
トナーが付着した複写フィルムを得、この複写フィルム
のトナー面にスプレーで粘着剤を塗布して感圧転写フィ
ルムを得、この感圧転写フィルｌ、をＰＥＴフィルム側
からこすって目的とする被転写体にトナーの部分だけを
転写するというものである。(Prior Art) Various types of paper are used as copy paper in so-called dry copying in which copies are made using toner. However, since it cannot be copied directly to ultra-thin paper, cardboard, uneven leather wood, metal, glass, plastic boards, etc.
A so-called toner transfer system is employed. It involves copying onto a PET film on which a release layer has been formed in advance to obtain a copy film with toner attached, and then spraying an adhesive onto the toner side of the copy film to obtain a pressure-sensitive transfer film. The transfer film 1 is rubbed from the PET film side to transfer only the toner portion to the target transfer object.
（発明が解決しようとする課題）
しかし、上記した従来の感圧転写フィルムは、スプレー
での粘着剤の塗布や乾燥の工程で非常な手間がかかシ、
粘着剤もこれを均一な厚さに塗布することは非常に困難
である。また、粘着剤の溶解に有機溶剤を使用する場合
は、溶剤の蒸発に伴う環境汚染の問題がある。この発明
はかかる多くの課題を解決した感圧転写フィルムを提供
するものである。(Problem to be Solved by the Invention) However, the above-mentioned conventional pressure-sensitive transfer film requires a lot of time and effort in the process of applying the adhesive by spraying and drying.
It is also very difficult to apply adhesive to a uniform thickness. Furthermore, when an organic solvent is used to dissolve the adhesive, there is a problem of environmental pollution due to evaporation of the solvent. The present invention provides a pressure-sensitive transfer film that solves many of these problems.
（課題を解決するための手段）
すなわちこの発明は、離型層を形成したプラスチックフ
ィルムの離型層上に乾式コピーをしてトナーが付着した
複写フィルムを得、一方、アンカ層を順次設けた層を前
記した複写フィルムのトナーの上にのみ熱ロール等で転
写して得たことを特徴とする、感圧転写フィルムである
。(Means for Solving the Problems) That is, in this invention, dry copying is performed on the release layer of a plastic film on which a release layer has been formed to obtain a copy film to which toner is attached, and on the other hand, an anchor layer is sequentially provided. This is a pressure-sensitive transfer film characterized in that the layer is transferred only onto the toner of the copying film described above using a hot roll or the like.
プラスチックフィルムとしては、ＰＥＴフィルム等の各
種のプラスチックフィルムが使用できる。As the plastic film, various plastic films such as PET film can be used.
複写フィルムを得るには、プラスチックフィルムの表面
に適宜の樹脂によシ離型層を形成してかき、その離型層
上に、トナーにより複写をするいわゆる乾式コピーをす
ればよい。In order to obtain a copy film, a release layer may be formed on the surface of a plastic film using a suitable resin, and a so-called dry copying process in which copies are made using toner may be performed on the release layer.
積層フィルムのアンカーコート層は、プラスチックフィ
ルムと粘着層との離型性を向上させるためのものであシ
、適宜の樹脂によシ形成すればよい。The anchor coat layer of the laminated film is for improving the releasability between the plastic film and the adhesive layer, and may be formed from an appropriate resin.
粘着層は、常温で粘着性のある樹脂によシ形成し、樹脂
中には無機粉末粒子を均一に分散させる。The adhesive layer is formed from a resin that is sticky at room temperature, and inorganic powder particles are uniformly dispersed in the resin.
粘着層は平常では非粘着性であるが、圧力を加えると粘
着性を示す。The adhesive layer is normally non-adhesive, but becomes tacky when pressure is applied.
粘着層の樹脂としては、アクリル樹脂、合成ゴム、ポリ
ビニルエーテル、ポリビニルブチラール、ネオブレン等
が、無機粉末おｌ子としては二酸化ケイ素等が夫々使用
出来る。As the resin for the adhesive layer, acrylic resin, synthetic rubber, polyvinyl ether, polyvinyl butyral, neorene, etc. can be used, and as the inorganic powder, silicon dioxide, etc. can be used.
粘着層中の無機粉末粒子は、樹脂固形分に対して重量比
で５０〜８０％が好嘘しい。無機粉末粒子が５０％よシ
少ないと、積層フィルムに転写したときに複写フィルム
のトナ一部以外の部分へも粘着層が転写されて汚れが目
立ち、また、８０％よυ多いと感圧転写フィルムとして
の接着性が弱くなる。The inorganic powder particles in the adhesive layer preferably have a weight ratio of 50 to 80% based on the resin solid content. If the amount of inorganic powder particles is less than 50%, the adhesive layer will be transferred to areas other than the toner part of the copying film when transferred to a laminated film, making stains noticeable, and if the amount is more than 80%, pressure sensitive transfer will be difficult. The adhesiveness of the film becomes weak.
保護層は蒸着適性をもたすためのものであシ、軟化点が
９０℃ 以上の樹脂が好ましい。例えば、ＭＭＡＱＩ脂
、スチレンマレイン酸樹脂、エポキシ系、メラミン系、
二液硬化型ウレタン系、アミノアルキッド系の熱硬化タ
イプ樹脂等が使用できる。The protective layer is intended to provide vapor deposition suitability, and is preferably a resin having a softening point of 90° C. or higher. For example, MMAQI resin, styrene maleic acid resin, epoxy type, melamine type,
Two-component urethane-based thermosetting resins, aminoalkyd-based thermosetting resins, etc. can be used.
Ａｌ蒸着層は、トナーがカラーである場合に隠蔽性を付
与し、メタリック外観をもたらすためのものである。The Al vapor-deposited layer is for providing hiding properties and giving a metallic appearance when the toner is a color toner.
積層フィルムの粘着層又は粘着層、保護層、及びＡｌ蒸
着層を順次設けた層は、熱ロール等で、複写フィルムの
トナー面のトナーの上に転写する。The adhesive layer of the laminated film or the layer in which the adhesive layer, the protective layer, and the Al vapor deposition layer are sequentially provided is transferred onto the toner on the toner side of the copying film using a hot roll or the like.
この場合、トナーが熱によシ接着性を有するようになる
ことから、粘着層、保護層、及びＡｌ蒸着層を順次設け
た層でも転写できるものである〇（実施例）
この発明の感圧転写フィルムを製造する工程等を示す図
面を参照しつつ、この発明の詳細な説明する。In this case, since the toner becomes adhesive due to heat, it is possible to transfer even a layer in which an adhesive layer, a protective layer, and an Al vapor deposition layer are sequentially provided.〇(Example) Pressure sensitive of this invention The present invention will be described in detail with reference to drawings showing the steps of manufacturing a transfer film.
実施例 １゜
厚す７５μｍ０ＰＥＴフイルム１上に下記の組成からな
る塗料をＷｅシ０ 、６９／ｄとなるようグラビアコー
トし、オープンで１５０℃、３０ Ｓｅｅ乾燥して離型
層２を形成した。次いでその離型層２上に所望の図案を
乾式コピーして、第１図に示すような、トナー３が付着
した複写フィルムＡを得た。Example 1 A coating material having the following composition was gravure coated on a PET film 1 having a thickness of 75 .mu.m as shown below so as to give a wetness of 0.69/d, and was dried in the open at 150.degree. C. and 30 See to form a release layer 2. Next, a desired design was dry-copied onto the release layer 2 to obtain a copying film A to which toner 3 was adhered as shown in FIG.
シリコン系離型剤、非接着剤・・・０．１重量部（信越
化学社製ＫＳ７７４）
触 媒 ・・・０．０１
／／溶 剤 ・・・１０．０
／／一方、厚さ２５μｍのＰＥＴフィルム１上に
、筐ず次の組成からなる塗料をｗｅｔ、０．６ｇ／ａ！
となるようグラビアコートし、オーブンで１５０℃、３
０ＳｅＣ乾燥して、アンカーコート層４を形成した。Silicone mold release agent, non-adhesive agent...0.1 part by weight (KS774 manufactured by Shin-Etsu Chemical Co., Ltd.) Catalyst...0.01
//Solvent...10.0
//Meanwhile, on the PET film 1 with a thickness of 25 μm, a paint consisting of the following composition was wet, 0.6 g/a!
Gravure coat it so that
An anchor coat layer 4 was formed by drying at 0SeC.
シリコン系離型剤、非接着剤・・・０．１１部（信越化
学社製ＫＳ７７４）
触 媒 ・・・０．０１ ７
／溶 剤 ・・・１ｏ、ｏ
０次に、アンカーコート層４上に、下記の組成から
なる塗料をリバースコートし、オーブンで１３０で、３
ｏｓｅｃ乾燥して３．０μｍの厚さの粘着層５を形成し
て、第２図に示すような、積層フィルムＢを得た。Silicone mold release agent, non-adhesive agent...0.11 part (KS774 manufactured by Shin-Etsu Chemical Co., Ltd.) Catalyst...0.01 7
/Solvent...1o,o
0 Next, on the anchor coat layer 4, a paint consisting of the following composition was reverse coated and heated in an oven at 130° C.
Osec drying was performed to form an adhesive layer 5 having a thickness of 3.0 μm, thereby obtaining a laminated film B as shown in FIG.
ゴム系粘着剤 ・・・ ２．０重量部（コニシボ
ンド社製ＫＨ５０５−２０）Ｓｊ−０２・・・ ０．６
′
溶 剤 ・・・ １０．Ｑ ／
／次に、複写フィルムＡのトナー５面と積層フィルムＢ
の粘着層５面が接するようにして、複写フィルムＡと積
層フィルムＢを１２０〜１４０１：の熱ロール間に通し
、第３図に示すように熱融着して転写した後、複写フィ
ルムＡと積層フィルムＢを剥がすと、第４図に示すよう
に積層フィルムＢの粘着層５は複写フィルムＡのトナー
５０部分にのみ転写され、この発明の感圧転写フィルム
を得ることができた。Rubber adhesive: 2.0 parts by weight (KH505-20 manufactured by Konishi Bond) Sj-02: 0.6
' Solvent... 10. Q/
/Next, 5 toner sides of copying film A and laminated film B
Copy film A and laminated film B are passed between 120 to 1401 heat rolls so that the 5 sides of the adhesive layer of When the laminated film B was peeled off, the adhesive layer 5 of the laminated film B was transferred only to the toner 50 portion of the copying film A, as shown in FIG. 4, and a pressure-sensitive transfer film of the present invention could be obtained.
この様にして得られた感圧転写フィルムを第５図に示す
ように、被転写体６の上に置き、ＰＥＴフィルム１の上
から爪でこすると、トナー５及び粘着層５が被転写体乙
の上にきれいに転写出来た。As shown in FIG. 5, the pressure-sensitive transfer film obtained in this manner is placed on the transfer target 6 and rubbed with a fingernail from above the PET film 1, so that the toner 5 and the adhesive layer 5 are transferred to the transfer target. I was able to transfer it neatly onto the original.
実施例 ２゜
実施例１と同様にして複写フィルムＡと積層フィルムＢ
を得、積層フィルムＢは宮らに粘着層５上に下記の組成
からなる保ｉｍ＃７（ドライで１．ｒＪｐｍ厚）ｋよび
ＡＲＭ着層８ （５５０１１ｍ厚）を順次形成し、第６
図に示すような積層フィルムＣを得た。Example 2゜ Copy film A and laminated film B were prepared in the same manner as in Example 1.
Laminated film B was prepared by sequentially forming adhesive layer #7 (1.rJpm thick in dry form) and ARM adhesive layer 8 (55011 m thick) having the following composition on adhesive layer 5.
A laminated film C as shown in the figure was obtained.
アクリル樹脂 ・・・５．０重量部（日立化成
社製ヒタロイド５００４）
イソシアネート系硬化剤 ・・・ ４．ｏ 〃（日
本ポリウレタン社製コロネート２０３０）ＮＯ１／１６
・・−０，５／を溶 剤
・・・ ３゜ｏ 〃次に、複写フィルムＡ
のトナー３面と積層フィルムＣのＡｌ蒸着層８面とが接
するようにして、実施例１と同様にして積層フィルムＣ
の粘着ＮＩ５、保護層７、及びＡｌ！蒸着層８を複写フ
ィルムＡのトナー３０部分にのみ転写し、この発明の感
圧転写フィルムを得た。Acrylic resin: 5.0 parts by weight (Hitaroid 5004, manufactured by Hitachi Chemical) Isocyanate curing agent: 4. o (Coronate 2030 manufactured by Nippon Polyurethane Co., Ltd.) NO1/16
...-0,5/ as solvent
... 3゜o〃Next, copy film A
Laminated film C was prepared in the same manner as in Example 1, with the 3 toner surfaces of Laminated Film C in contact with the 8 Al vapor-deposited layers of Laminated Film C.
adhesive NI5, protective layer 7, and Al! The vapor deposited layer 8 was transferred only to the toner 30 portion of the copying film A to obtain a pressure-sensitive transfer film of the present invention.
この様にして得られた感圧転写フィルムを被転写体の上
に置き、ＰＥＴ フィルム１の上から爪でこすると、ト
ｆ−５、粘着層５、保護層７、及びＡＪ蒸着層８がきれ
いに転写出来た。When the pressure-sensitive transfer film obtained in this manner is placed on the object to be transferred and rubbed with a fingernail from above the PET film 1, the adhesive layer 5, the adhesive layer 5, the protective layer 7, and the AJ vapor deposition layer 8 are removed. I was able to transfer it cleanly.
（発明の効果）
この発明の感圧転写フィルムは上記のように構成したか
ら、従来のようにスプレーで粘着剤を塗布し乾燥すると
いう非常に手間のかかる工程を経る事がなく、簡易に得
ることが出来る０また、粘着剤は従来のスプレーで塗布
した場合のように不均一な厚とになることはなく、容易
に均一な厚さに塗布できるから、この発明の感圧転写フ
ィルムは、均一な厚さの粘着層を形成することができ、
従って被転写体に転写すれば、均一な色彩と光沢とで非
常に美Ｒな模様、文字、図柄等を付与することが出来る
ものである。(Effects of the Invention) Since the pressure-sensitive transfer film of the present invention is configured as described above, it can be easily obtained without going through the extremely time-consuming process of spraying an adhesive and drying it as in the past. In addition, the pressure-sensitive transfer film of the present invention can be easily applied to a uniform thickness, rather than being unevenly thick as when applied by conventional spraying. Can form an adhesive layer of uniform thickness,
Therefore, when transferred onto an object, it is possible to impart very beautiful patterns, letters, designs, etc. with uniform color and gloss.
図面はこの発明の感圧転写フィルムを製造する工程を示
す一部拡大断面図である。第１図は複写ルムを複写フィ
ルムに転写した後に得られるこの発明の感圧転写フィル
ム、第５図はこの発明の感圧転写フィルムを被転写体に
転写した時の状態である。第６図は鴇４フィルムの他の
例を示す。
Ａ・・・・・複写フィルム
Ｂ・・・・・積層フィルム
Ｃ・・・・・積層フィルム
ト・・・・ＰＥＴフィルム
２・・・・・離型層
３・・・・・トナー
４ ・・・・・アンカーコート層
５・・・・・粘着層
６・・・・・被転写体
７・・・・・保護層
８・・・・・Ａｌ蒸着層The drawings are partially enlarged cross-sectional views showing the process of manufacturing the pressure-sensitive transfer film of the present invention. FIG. 1 shows the pressure-sensitive transfer film of this invention obtained after transferring a copying lume to a copying film, and FIG. 5 shows the state when the pressure-sensitive transfer film of this invention is transferred to an object to be transferred. FIG. 6 shows another example of the Toshi 4 film. A... Copy film B... Laminated film C... Laminated film... PET film 2... Release layer 3... Toner 4... ... Anchor coat layer 5 ... Adhesive layer 6 ... Transferred object 7 ... Protective layer 8 ... Al vapor deposited layer
Claims (1)
式コピーをしてトナーが付着した複写フィルムを得、一
方、アンカーコート層を形成したプラスチックフィルム
のアンカーコート層上に粘着層を又は粘着層、保護層、
及びＡｌ蒸着層を順次設けた層を形成した積層フィルム
を得、この積層フィルムの粘着層又は粘着層、保護層、
及びＡｌ蒸着層を順次設けた層を前記した複写フィルム
のトナーの上にのみ熱ロール等で転写して得たことを特
徴とする、感圧転写フィルム。Dry copying is performed on the release layer of the plastic film on which the release layer has been formed to obtain a copy film to which the toner is attached, and on the other hand, an adhesive layer or adhesive layer is applied on the anchor coat layer of the plastic film on which the anchor coat layer has been formed. , protective layer,
A laminated film is obtained in which layers are sequentially provided with and Al vapor-deposited layers, and the adhesive layer or adhesive layer of this laminated film, the protective layer,
A pressure-sensitive transfer film, which is obtained by transferring a layer including a vapor-deposited Al layer and an Al vapor-deposited layer in sequence only onto the toner of the above-mentioned copying film using a hot roll or the like.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1178819A JPH0343745A (en) | 1989-07-11 | 1989-07-11 | Pressure sensitive transfer film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1178819A JPH0343745A (en) | 1989-07-11 | 1989-07-11 | Pressure sensitive transfer film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0343745A true JPH0343745A (en) | 1991-02-25 |
Family
ID=16055216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1178819A Pending JPH0343745A (en) | 1989-07-11 | 1989-07-11 | Pressure sensitive transfer film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0343745A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004074422A (en) * | 2002-08-09 | 2004-03-11 | Mitsubishi Pencil Co Ltd | Transfer foil |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59178468A (en) * | 1983-03-30 | 1984-10-09 | Dainippon Printing Co Ltd | Manufacture of id card by electrophotography |
| JPS6135858B2 (en) * | 1978-12-21 | 1986-08-15 | Matsushita Electric Ind Co Ltd | |
| JPS63100485A (en) * | 1986-10-16 | 1988-05-02 | Sharp Corp | Coloring image forming device |
-
1989
- 1989-07-11 JP JP1178819A patent/JPH0343745A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6135858B2 (en) * | 1978-12-21 | 1986-08-15 | Matsushita Electric Ind Co Ltd | |
| JPS59178468A (en) * | 1983-03-30 | 1984-10-09 | Dainippon Printing Co Ltd | Manufacture of id card by electrophotography |
| JPS63100485A (en) * | 1986-10-16 | 1988-05-02 | Sharp Corp | Coloring image forming device |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004074422A (en) * | 2002-08-09 | 2004-03-11 | Mitsubishi Pencil Co Ltd | Transfer foil |
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