JPH0330902A - Inorganically treated ply wood - Google Patents
Inorganically treated ply woodInfo
- Publication number
- JPH0330902A JPH0330902A JP16772589A JP16772589A JPH0330902A JP H0330902 A JPH0330902 A JP H0330902A JP 16772589 A JP16772589 A JP 16772589A JP 16772589 A JP16772589 A JP 16772589A JP H0330902 A JPH0330902 A JP H0330902A
- Authority
- JP
- Japan
- Prior art keywords
- inorganic
- veneer
- impregnation
- wood
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011120 plywood Substances 0.000 title claims abstract description 15
- 238000005470 impregnation Methods 0.000 claims abstract description 22
- 239000002023 wood Substances 0.000 claims abstract description 19
- 150000001449 anionic compounds Chemical class 0.000 claims abstract description 8
- 150000001767 cationic compounds Chemical class 0.000 claims abstract description 8
- 229910001412 inorganic anion Inorganic materials 0.000 claims abstract description 8
- 229910001411 inorganic cation Inorganic materials 0.000 claims abstract description 8
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000002344 surface layer Substances 0.000 claims description 4
- 238000011282 treatment Methods 0.000 abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- -1 Al<2+> Chemical class 0.000 abstract description 4
- 238000007654 immersion Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000010875 treated wood Substances 0.000 description 3
- 239000004566 building material Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000011121 hardwood Substances 0.000 description 2
- 229910001410 inorganic ion Inorganic materials 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Finished Plywoods (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、防火戸、防火パーティション、防火パネル
建材等に使用される防火性の必要な各種無機処理合板に
関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to various inorganic treated plywoods that require fire retardancy and are used for fire doors, fire retardant partitions, fire retardant panel building materials, etc.
防火性の必要な各種の建材はそのほとんどが金属材料や
無機材料またはこれらの複合体から作られていたが、木
材特有のやわらかさ、あたたかさに欠けることから木材
の内部に不溶性無機物を定着させ、木質感を残した状態
で難燃性、耐腐食性を付与した無機処理木材が提案され
ている。Most of the various building materials that require fire retardancy were made from metal materials, inorganic materials, or composites of these materials, but since they lacked the softness and warmth characteristic of wood, it was necessary to fix insoluble inorganic substances inside the wood. , inorganic treated wood has been proposed that has flame retardancy and corrosion resistance while retaining its wood texture.
しかしながら無機処理することにより、木質系材料の欠
点である難燃性、耐腐食性は向上するが寸法安定性に対
しては十分ではない、また防火性を高めるために無機物
の含浸率が高められており割れやすく、加工性に欠は歩
留が悪いという問題を有していた。However, although inorganic treatment improves flame retardancy and corrosion resistance, which are disadvantages of wood-based materials, it is not sufficient to improve dimensional stability, and in order to improve fire resistance, the impregnation rate of inorganic substances is increased. It has the problem of being easily cracked, lacking workability, and resulting in poor yield.
この発明の目的は、難燃性、耐腐食性、を備えたまま寸
法安定性、加工性を改良した無機処理合板を提供するこ
とである。An object of the present invention is to provide an inorganically treated plywood with improved dimensional stability and workability while maintaining flame retardancy and corrosion resistance.
この発明の無機処理合板は、木材単板に無機陽イオン水
溶液と無機陰イオン水溶液とを順次含浸させて、木材単
板の内部に不溶性の無機塩を形成して無機処理単板とし
、この無機処理単板の複数枚を積層接着した無機処理合
板において、表面層の無機処理単板を他の部位の無機処
理単板よりも低含浸率としたことを特徴とする。The inorganic treated plywood of the present invention is produced by impregnating a wood veneer with an aqueous inorganic cation solution and an aqueous inorganic anion solution in order to form an insoluble inorganic salt inside the wood veneer to obtain an inorganic treated veneer. An inorganically treated plywood made by laminating and bonding a plurality of treated veneers, characterized in that the inorganically treated veneer in the surface layer has a lower impregnation rate than the inorganically treated veneers in other parts.
第１図は、この発明の木材単板ｌへの無機処理の工程を
示す工程説明図である。木材単板ｌを温水３に浸漬し、
飽水処理を行う。この飽水処理は減圧下でおこなっても
良く、あるいは水を沸騰させて行っても良い。つぎに無
機陽イオン（例えばＡＩ”、Ｍｇ”″ ’ｌ、 ｎ ｔ
＋ 、 Ｃａ ｔ ＋ 、 Ｂａ ｔ ’の少な
くとも１！Ｉを含む）水溶液４中に浸漬しく１１含浸）
、ついで無機陰イオン（例えばＨＰＯ，”ＣＯ，”−、
Ｓｏ、”−、ＢＯ，’−の少なくとも１種を含む）水溶
ｉ５中に浸漬する（２液含浸）。この含浸処理ににおい
て水溶液濃度、処理温度は高くなるほど、また処理時間
は長くなるほど含浸率が高くなり、無機陽イオン水溶１
４と無機陰イオン水溶液５への浸漬処理を交互に数回繰
り返すことにより含浸率を高めることができ、これらの
条件を変えて組み合わせることにより含浸率をコントロ
ールすることができる。つぎに木材単板１から未反応の
無機イオンを除去するために水６に浸漬し乾燥させて無
機処理を終わる。このようにして得られた無機処理した
木材単板１から合板１０を製造する。FIG. 1 is a process explanatory diagram showing the process of inorganic treatment of a wood veneer l according to the present invention. Soak the wood veneer l in warm water 3,
Perform water saturation treatment. This water saturation treatment may be carried out under reduced pressure or by boiling the water. Next, inorganic cations (e.g. AI", Mg""'l, nt
At least one of +, Cat +, Bat'! Immersion in aqueous solution 4 (containing I); 11 impregnation)
, followed by inorganic anions (e.g. HPO, “CO,”-,
So, "-, BO, '-)) is immersed in aqueous i5 (two-liquid impregnation). In this impregnation treatment, the higher the aqueous solution concentration and treatment temperature, and the longer the treatment time, the higher the impregnation rate. becomes high, and inorganic cation water-soluble 1
The impregnation rate can be increased by alternately repeating the immersion treatment in 4 and the inorganic anion aqueous solution 5 several times, and the impregnation rate can be controlled by changing and combining these conditions. Next, in order to remove unreacted inorganic ions from the wood veneer 1, it is immersed in water 6 and dried to complete the inorganic treatment. Plywood 10 is manufactured from the inorganically treated wood veneer 1 thus obtained.
第２図に無機処理した木材単板１を用いた合板１０を示
す。木材種としては針葉樹が広葉樹よりも無機イオン水
溶液が含浸しやすく、コア単＋Ｆｉ１２としては針葉樹
、表面層となるフェース単板、裏面層となるバンク単板
としては広葉樹を木材種とすることが望ましい。含浸率
１００重量％以上で無機処理した厚さ１．０〜３．０
ｍの木材単板ｌを、望ましくは繊維方向が直交する方向
に複数枚積層したコア単板１２と、木材単板ｌに含浸率
３０〜８０重量％で無機処理した厚さ０．５〜１．５
ｌｌｌＩｎのフェース単板１１およびバック単板１３と
をそれぞれ接着剤を介して張り合わせたものである。な
お接着剤としてはフェノール系やユリアーメラミン系な
どの耐熱性の優れたもので、ポリリン酸塩など難燃剤を
添加したものが望ましい。なお裏面が隠れる使い方をす
る場合は、バック単板１３は高含浸率であっても良い。FIG. 2 shows a plywood 10 using an inorganically treated wood veneer 1. As for the wood species, softwood is more easily impregnated with inorganic ion aqueous solution than hardwood, and it is desirable to use softwood for the core single + Fi12, hardwood for the face veneer that will be the surface layer, and the bank veneer that will be the back layer. . Thickness 1.0-3.0 treated with inorganic material with an impregnation rate of 100% by weight or more
The core veneer 12 is made by laminating a plurality of wood veneers l, preferably in a direction perpendicular to the fiber direction, and the wood veneer l is inorganically treated with an impregnation rate of 30 to 80% by weight to a thickness of 0.5 to 1. .5
A face veneer 11 and a back veneer 13 of lllIn are laminated together using an adhesive. The adhesive should preferably be one with excellent heat resistance, such as a phenolic or urea-melamine adhesive, with a flame retardant such as polyphosphate added thereto. Note that if the back veneer 13 is to be used so that the back surface is hidden, the back veneer 13 may have a high impregnation rate.
〔作用］
この発明の構成によれば、木質系材料に無機陽イオン水
溶液と無機陰イオン水溶液を含浸させ、コア単板内部に
は高含浸率で無機塩を形成することができ、フェース単
板にはコア単板に比べて低含浸率で＠機塩を形成するこ
とができる。[Function] According to the structure of the present invention, it is possible to impregnate the wood-based material with an inorganic cation aqueous solution and an inorganic anion aqueous solution, and form an inorganic salt inside the core veneer at a high impregnation rate. It is possible to form @machine salt with a lower impregnation rate than core veneer.
〔実施例］ この発明の実施例とその特性を下記に示す。〔Example] Examples of this invention and their characteristics are shown below.
以下余白
〔発明の効果〕
この発明の無機処理合板は、合板を構成するコア単板内
部には高含浸率で無機塩を形成し、表面層の単板にはコ
ア単板に比べて低含浸率で無機塩を形成したので、難燃
性および耐腐食性を有することはもちろんのこと、寸法
安定性が向上し、８すれにくく、加工性も向上し歩留が
良くなり、木質感もｔ員なわない。The following margins [Effects of the Invention] The inorganic treated plywood of this invention forms inorganic salts at a high impregnation rate inside the core veneer constituting the plywood, and has a lower impregnation rate in the surface layer veneer than the core veneer. Since it forms an inorganic salt at a high rate, it not only has flame retardancy and corrosion resistance, but also improves dimensional stability, scratch resistance, improves workability, and improves yield, and has a wood texture. Not a member.
第１図はこの発明の一実施例の無機処理合板の製造工程
説明図、第２図は無機処理合板の縦断面図である。
１・・・木材単板、４・・・無機陽イオン水溶液、５・
・・無機陰イオン水溶液、１０・・・合板、１１・・・
フェース単板、１２・・・コア単板、１３・・・バンク
単板、第
図
１１フエース輩扱
／
入
１３バック単級FIG. 1 is an explanatory diagram of the manufacturing process of inorganic treated plywood according to an embodiment of the present invention, and FIG. 2 is a longitudinal sectional view of the inorganic treated plywood. 1... Wood veneer, 4... Inorganic cation aqueous solution, 5...
...Inorganic anion aqueous solution, 10...Plywood, 11...
Face veneer, 12...Core veneer, 13...Bank veneer, Figure 11 Face veneer/Enter 13 Back veneer grade
Claims (1)
を順次含浸させて、木材単板の内部に不溶性の無機塩を
形成して無機処理単板とし、この無機処理単板の複数枚
を積層接着した無機処理合板において、表面層の無機処
理単板を他の部位の無機処理単板よりも低含浸率とした
ことを特徴とする無機処理合板。A wood veneer is sequentially impregnated with an inorganic cation aqueous solution and an inorganic anion aqueous solution to form an insoluble inorganic salt inside the wood veneer to form an inorganic treated veneer, and multiple pieces of this inorganic treated veneer are laminated. 1. An inorganically treated plywood bonded together, characterized in that the inorganically treated veneer in the surface layer has a lower impregnation rate than the inorganically treated veneer in other parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16772589A JPH0330902A (en) | 1989-06-27 | 1989-06-27 | Inorganically treated ply wood |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16772589A JPH0330902A (en) | 1989-06-27 | 1989-06-27 | Inorganically treated ply wood |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0330902A true JPH0330902A (en) | 1991-02-08 |
Family
ID=15855010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16772589A Pending JPH0330902A (en) | 1989-06-27 | 1989-06-27 | Inorganically treated ply wood |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0330902A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2801066A1 (en) * | 1999-11-12 | 2001-05-18 | Schreinerei Schneider Ag | FIRE RESISTANT SANDWICH PANEL |
| US6386781B1 (en) | 1997-04-15 | 2002-05-14 | L'oreal | Unit for packaging and applying a liquid product |
| JP2006102319A (en) * | 2004-10-07 | 2006-04-20 | Mitsubishi Pencil Co Ltd | Applicator for hair, and makeup substance container having the applicator |
-
1989
- 1989-06-27 JP JP16772589A patent/JPH0330902A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6386781B1 (en) | 1997-04-15 | 2002-05-14 | L'oreal | Unit for packaging and applying a liquid product |
| US6692173B2 (en) | 1997-04-15 | 2004-02-17 | L'oreal | Unit for packaging and applying a liquid product |
| FR2801066A1 (en) * | 1999-11-12 | 2001-05-18 | Schreinerei Schneider Ag | FIRE RESISTANT SANDWICH PANEL |
| GB2356649B (en) * | 1999-11-12 | 2004-01-21 | Schreinerel Schneider Ag | Fire-resistant sandwich plate |
| JP2006102319A (en) * | 2004-10-07 | 2006-04-20 | Mitsubishi Pencil Co Ltd | Applicator for hair, and makeup substance container having the applicator |
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