JPH03209241A - Silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To obtain a sensitive material inhibiting the growth of mold on the image surface of a print and having superior preservable property of a color image by incorporating a specified yellow coupler and an antibacterial and antimold agent. CONSTITUTION:At least one kind of yellow coupler represented by formula I and at least one kind of antibacterial and antimold agent are incorporated in combination. In the formula I, R1 is aryl or tert. alkyl, R2 is F, alkyl, aryl, etc., R3 is a group substitutable on the benzene ring, X is H or a group releasable by a coupling reaction with the oxidized body of an arom. prim. amine developing agent, l is an integer of 0-4, and when l is >=2, R3's may be different from each other. A sensitive material inhibiting the growth of mold on the image surface of a print and having superior preservable property of a yellow dyestuff image is obtd.

Description

DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a silver halide photographic material, and more particularly to a photographic material with improved image stability.

More specifically, the present invention relates to a photographic material with improved mold resistance and color image fastness of photographic images.

(Prior art) When photographic images are stored under high humidity conditions, mold may grow on the surface, and in some cases, the acid secreted by the mold can discolor or fade the colored image, significantly deteriorating the image quality. There was a problem.

In order to solve this problem, several proposals have been made to apply antibacterial and antifungal agents to silver halide photographic materials. For example, a method for suppressing the growth of mold on images by adding an antibacterial and antifungal agent to a processing solution for silver halide photographic light-sensitive materials is disclosed in JP-A-59-126533 and JP-A-60-260952.
, 58-105145, 61-39047, 61
-75354, Special Publication No. 62-62334, West German Patent 34
36862A, and R, D, 20526, etc., but in these cases, a new treatment bath containing an antibacterial and antifungal agent (antibacterial and antifungal bath, stable bath) is installed in the current treatment process. However, there are problems such as the necessity to modify the equipment and the fact that the antibacterial and fungicidal agent has poor solubility in water, causing it to precipitate in the processing bath and adhere to the surface of the photographic material. Furthermore, since a large amount of waste liquid is generated, there is also a problem in terms of environmental conservation.

On the other hand, a method has been proposed in which an antibacterial and antifungal agent is added to the silver halide photographic material itself in advance to suppress the growth of mold on images. It is also possible to suppress the growth of mold on unprocessed photographic materials. This method is described in Japanese Patent Application Laid-Open No. 60-263
938, 59-84237, 58-166343,
60-114239, etc.

However, even with the above-mentioned method, the amount of antibacterial and fungicidal agent that can be introduced into photographic materials is limited, so if the image surface becomes extremely dirty with hand grime or the like during storage or if storage conditions are poor, mold and mildew may occur. may occur. Therefore, in addition to taking measures to prevent the growth of mold, we also take measures to prevent the color image from discoloring or fading even if mold occurs. It becomes necessary.

The main cause of discoloration or fading of color images due to mold growth is organic acids (acetic acid, citric acid, tartaric acid, gluconic acid, etc.) secreted by mold, and cyan and yellow pigments are discolored by these acids ( acid fading).

Regarding yellow dye images, the use of cyclic ether compounds or epoxy group-containing compounds is disclosed in JP-A-64-50048, JP-A-64-50049, and JP-A-61-4041. Although the compound was found to be effective to some extent in improving acid fading, it was still not a sufficient improvement. Also, US Patent 3. 26
5. No. 506 discloses a yellow coupler with improved color image fastness, but it was not very effective against acid fading.

(Problems to be Solved by the Invention) An object of the present invention is to suppress the growth of mold on the image surface of prints obtained by processing color photographic materials, and to provide silver halide photographic materials with excellent color image storage properties. Our goal is to provide the following. More specifically, it is an object of the present invention to provide a reflective silver halide color photographic material in which yellow dye images are prevented from fading due to acid.

(Means for Solving the Problems) As a result of intensive research, the present inventor has found that by containing a combination of at least one yellow coupler represented by the following general formula (I) and at least one antibacterial and fungicidal agent, This problem has been solved by suppressing the occurrence of mold and also improving the acid fading that would occur if mold were to occur.

General formula (I) [wherein, R represents an aryl group or a tertiary alkyl group,
1 is a fluorine atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a dialkylamine group, an alkylthio group, or an arylthio group, R1 is a group that can be substituted on the benzene ring, and X is a hydrogen atom or an aromatic group. l represents a group that can be separated by a coupling reaction with an oxidized product of a primary amine developer, and l represents an integer of 0 to 4, respectively. However, when l is plural, the plural R3s may be the same or different. ] Compound (I) used in the present invention will be explained in more detail.

In general formula (I), R3 preferably has 6 carbon atoms
~24 aryl groups (e.g. phenyl, p-)lyl, o
-tolyl, 4-methoxyphenyl, 2-methoxyphenyl, 4-butoxyphenyl, 4-octyloxyphenyl, 4-hexadecyloxyphenyl, l-naphthyl)
or a tertiary alkyl group having 4 to 24 carbon atoms (for example, t
-butyl, t-pentyl, t-hexyl, 1. l,
3. 3-tetramethylbutyl, ■-adamantyl, l,1-dimethyl-2-chloroethyl, 2-phenoxy-2-propyl, bicyclo(2,2,2)octane-
1-yl).

In general formula (I), R2 is preferably a fluorine atom,
Alkyl groups having 1 to 24 carbon atoms (e.g. methyl, ethyl, isopropyl, t-butyl, cyclopentyl, n-
octyl, n-hexadecyl, benzyl), C6-C24 aryl groups (e.g. phenyl, p-tolyl,
O-)lyl, 4-methoxyphenyl), from 1 carbon atom
24 alkoxy groups (e.g. methoxy, nidoxy, butoxy, n-octyloxine, n-tetradecyloxy,
benzyloxy, methoxyethoxy), carbon atoms 6~
24 aryloxy groups (e.g. phenoxy, I)-)
-lyloxy, o-1lyloxy, p-methoxyphenoxy, p-dimethylaminophenoxy, m-pentadecylphenoxy), dialkylamino groups having 2 to 24 carbon atoms (e.g. dimethylamino, diethylamino, pyrrolidino, piperidino, morpholino), Number of carbon atoms: 1-24
alkylthio groups (e.g. methylthio, butylthio, n
-octylthio, n-hexadecylthio) or arylthio groups having 6 to 24 carbon atoms (e.g. phenylthio,
4-methoxyphenylthio, 4-[-butylphenylthio, 4-dodecylphenylthio).

In general formula CI), R1 is preferably a halogen atom (fluorine atom, chlorine atom, bromine atom, iodine atom), an alkyl group having 1 to 24 carbon atoms (e.g. methyl, t-butyl, n-dodecyl), a carbon atom Aryl groups having 6 to 24 carbon atoms (e.g. phenyl, p-tolyl, p-dodecyloxyphenyl), alkoxy groups having 1 to 24 carbon atoms (e.g. methoxy, n-butoxy, n-octyloxy, n-tetradecyloxy, benzyloxy, methoxyethoxy), aryloxy groups having 6 to 24 carbon atoms (e.g. phenoxy, pt-butylphenoxy, 4-butoxyphenoxy), alkoxycarbonyl groups having 2 to 24 carbon atoms [e.g. ethoxycarbonyl, dodecyl oxycarbonyl, 1-(dodecyloxycarbonyl)ethoxycarbonyl], aryloxycarbonyl group having 7 to 24 carbon atoms (e.g. phenoxycarbonyl, 4-octylphenoxycarbonyl, 2,4-di-t-pentylphenoxycarbonyl), Carbonamide groups having 1 to 24 carbon atoms [e.g. acetamido, pivaloylamino, benzamide, 2-ethylhexanamide, tetradecanamide, l(2,4-di-t-pentylphenoxy)butanamide, 3-(2,4-di-t-pentylphenoxy)butanamide, -t-pentylphenoxy)butanamide, 3-dodecylsulfonyl-2-methylpropanamide], a sulfonamide group having 1 to 24 carbon atoms (e.g. methanesulfonamide, p-)luenesulfonamide, hensabcansulfonamide), Carbamoyl group having 1 to 24 carbon atoms (e.g. N-methylcarbamoyl, N-tetradecylcarbamoyl, N,N-dihexylcarbamoyl, N-octadecyl-N-methylcarbamoyl, N-phenylcarbamoyl), carbon number O to 24 sulfamoyl groups (e.g. N-methylsulfamoyl, N-phenylsulfamoyl, N-acetylsulfamoyl, N-propanoylsulfamoyl,
N-hexadecylsulfamoyl, N,N-dioctylsulfamoyl), alkylsulfonyl groups having 1 to 24 carbon atoms (e.g. methylsulfonyl, benzylsulfonyl, hexadecylsulfonyl), arylsulfonyl having 6 to 24 carbon atoms groups (e.g. phenylsulfonyl, I
)-) Lylsulfonyl, p-dodecylsulfonyl, p-
methoxysulfonyl), ureido groups having 1 to 24 carbon atoms (e.g. 3-methylureido, 3-phenylureido, 3,3-dimethylamino, 3-tetradecylureido), sulfamoylamino having 0 to 24 carbon atoms groups (e.g. N, N-dimethylsulfamoylamino), alkoxycarbonylamino groups having 2 to 24 carbon atoms (e.g. methoxycarbonylamino, isobutoxycarbonylamino, dodecyloxycarbonylamino), nitro groups, 1 to 24 carbon atoms 24 heterocyclic groups (e.g. 4-pyridyl, 2-thienyl, phthalimide, octadecylsuccinimide), cyano groups, acyl groups having 1 to 24 carbon atoms (
(e.g. acetyl, benzoyl, dodecanoyl), acyloxy groups having 1 to 24 carbon atoms (e.g. acetoxy, benzoyloxy, dodecanoyloxy), 1 carbon atom
~24 alkylsulfonyloxy groups (e.g. methylsulfonyloxy, heisubylsulfonyloxy) or arylsulfonyloxy groups having 6 to 24 carbon atoms (
For example, p-1 luenesulfonyloxy, p-dodecylphenylsulfonyloxy).

In general formula (I), l is preferably an integer of 1 or 2.

In the general formula (I), , bromine, iodine), 1 to 24 carbon atoms
a heterocyclic group bonded to the coupling active position at the nitrogen atom of
Aryloxy group having 6 to 24 carbon atoms, 6 carbon atoms
~24 arylthio groups (e.g. phenylthio, p-butylphenylthio, p-chlorophenylthio, p-
carboxyphenylthio), acyloxy groups having 1 to 24 carbon atoms (e.g. acetoxy, benzoyloxy, dodecanoyloxy), alkylsulfonyloxy groups having 1 to 24 carbon atoms (e.g. methylsulfonyloxy, butylsulfonyluoquine, dodecylsulfonyl) Oxy),
Arylsulfonyloxy groups having 6 to 24 carbon atoms (e.g. benzenesulfonyloxy, p-chlorophenylsulfonyloxy) or heterocyclic oxy groups having 1 to 24 carbon atoms (e.g. 3-pyridyloxy, l-phenyl-1
, 2,3,4-tetrazol-5=yloxy), and more preferably a heterocyclic group or aryloxy group bonded to the coupling active position through a nitrogen atom.

When X represents a nitrogen ring group bonded to the coupling active position with a nitrogen atom, X may contain a petero atom selected from oxygen, sulfur, nitrogen, phosphorus, selenium, and tellurium in addition to the nitrogen atom. A 5- to 7-membered optionally substituted monocyclic or fused heterocycle, examples of which include succinimide, maleimide, phthalimide, diglycolimide, pyrrole, pyrazole, imidazole,
l.

2.4-triazole, tetrazole, indole, benzopyrazole, benzimidazole, benzotriazole, imidazolidine-2,4-dione, oxazolidine-2,4-dione, thiazolidine-2,4-dione,
imidazolidin-2-one, oxazolin-2-one,
Thiazolin-2-one, benzimidacillin-2-one, benzoxazolin-2-one, benzothiazolin-2-one
2=one, 2-virolin-5-one, 2-imidacillin-5-one, indoline-2,3-dione, 2,6-cyoxypurine, parabanic acid, 1,2゜4-triacylidine-3,5-dione , 2-pyridone, 4-pyridone, 2
-pyrimidone, 6-pyridazone, 2-pyrazone, etc., and these heterocyclic groups may be substituted. Examples of substituents include hydroxyl group, carboxyl group, sulfo group, amino group (e.g. amino, N-methylamino, N.

In addition to N-dimethylamino, N,N-diethylamino, anilino, pyrrolidino, piperidino, morpholino), there are substituents listed as examples of R1 above.

When X represents an aryloxy group, X has 6 carbon atoms
-24 aryloxy groups, and when X is a heterocyclic group, it may be substituted with a group selected from the above-mentioned substituent groups. Substituents include carboxyl group, sulfo group,
Preferred are a cyano group, a nitro group, an alkoxycarbonyl group, a halogen atom, a carbonamide group, a sulfonamide group, a carbamoyl group, a sulfamoyl group, an alkyl group, an alkylsulfonyl group, an arylsulfonyl group, or an acyl group.

Next, examples of particularly preferably used substituents in the present invention will be described for each of the above-mentioned substituents R, R1, Rs, and X.

In general formula [I], R1 is particularly preferably a 2- or 4-alkoxyaryl group (e.g. 4-methoxyphenyl, 4-butoxyphenyl, 2-methoxyphenyl) or a t-butyl group, most preferably a t-butyl group. preferable.

In general formula CI), R2 is particularly preferably a methyl, ethyl, alkoxy, aryloxy or dialkylamine group, most preferably a methyl, ethyl, alkoxy, aryloxy or dimethylamino group.

In the general formula CI), R1 is particularly preferably an alkoxy group, a carbonamide group or a sulfonamide group.

In general formula (I), X is particularly preferably a heterocyclic group or an aryloxy group bonded to the coupling active position via a nitrogen atom.

When X represents the above-mentioned heterocyclic group, X is preferably represented by the following general formula (II).

General formula [I[) -2,- R1 In general formula (II), Z is -0-C5 R1 R1 R, R5 R,R.

It represents a xycarbonyl group, and Rlo and R1 represent a hydrogen atom, an alkyl group or an aryl group.

R4° and R11 may be bonded to each other to form a benzene ring. R4 and Rs, Ri and R, , R, and R1 or R
1 and R1 may be bonded to each other to form a ring (eg, cyclobutane, cyclohexane, cyclohebutane, cyclohexene, pyrrolidine, piperidine).

Among the heterocyclic groups represented by the general formula (II), particularly preferred ones are those in which Z is R4R+ [was]. Here, R,, R,, R, and R1 are hydrogen atoms,
represents an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group, or an amino group, R and R7 are a hydrogen atom, an alkyl group, an aryl group, an alkylsulfonyl group, It is an arylsulfonyl group or an alkyl heterocyclic group.

The total number of carbon atoms in the heterocyclic group represented by the general formula [■] is 2
~24, preferably 4-20, more preferably 5-1
It is 6. Examples of the heterocyclic group represented by general formula [II] are succinimide group, maleimide group, phthalimide group, ■-methylimidazolidine-2,4-dione-3
-yl group, 1benzylimidazolidine-2,4-dione-3-yl group, 5,5-dimethyloxazolidine-2°4-dione-3-yl group, 5-methyl-5-propyloxazolidine-2,4 -dione-3-yl group, 5,5-
dimethylthiazolidine-2,4-dione-3-yl group,
5,5-dimethylimidazolidine-2,4-dione-3
-yl group, 3-methylimidazolidinetrione-1-yl group, 1,2゜4-triacylidine-3,5-dione-
4-yl group, l-methyl-2-phenyl-1,2,4-
triacylidin-3,5-dione-4-yl group, 1-benzyl-2-phenyl-1,2,4-triacylidin-
3,5-dione-4-yl group, 5-hexyloxy-1
-methylimidazolidine-2゜4-dione-3-yl group, l-benzyl-5-ethoxyimidazolidine-2,4
-dione-3-yl group and ■-benzyl-5-dodecyloxyimidazolidine-2,4-dione-3-yl group.

Among the above heterocyclic groups, imidazolidine-2,4-dione-3-yl group (e.g. 1-benzyl-imidazolidine-
2,4-dione-3-yl group) is the most preferred group.

When X represents an aryloxy group, 4-carboxyphenoxy group, 4-methylsulfonylphenoxy group, 4-
(4-benzyloxyphenylsulfonyl) phenoxy group, 4-(4-hydroxyphenylsulfonyl) phenoxy group, 2-chloro-4-(3-chloro-4-hydroxyphenylsulfonyl) phenoxy group, 4-methoxycarbonylphenoxy group, 2-chloro-4-methoxycarbonylphenoxy group, 2-acetamido-4-methoxycarbonylphenoxy group, 4-isopropoxycarbonylphenoxy group, 4-cyanophenoxy group, 2-[N
-(2-hydroxyethyl)carbamoyl]phenoquine group, 4-nitrophenoxy group, 2,5-dichlorophenoxy group, 2,3゜5-trichlorophenoxy group, 4-methoxycarbonyl-2-methoxyphenoxy group, 4-(
3carboxypropanamide) phenoxy group is the most preferred example.

The coupler represented by the general formula (K) may form a dimer or a multimer of more than two molecules bonded to each other via the substituent R8, the general formula (I[l] 2 or a divalent or higher valence group). In this case, the number of carbon atoms in each substituent group may be outside the range specified above.

When the coupler represented by the general formula CI) forms a multimer, a typical example is a single or copolymer of an addition polymer ethylenically unsaturated compound (yellow color-forming monomer) having a yellow dye-forming coupler residue. In this case, the multimer contains repeating units of the general formula (III), and one or more types of yellow coloring repeating units represented by the general formula CI[Il may be contained in the multimer, and non-containing as a copolymer component. It may also be a copolymer containing one or more color-forming ethylene type monomers.

In the formula, R represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or a chlorine atom, A represents -CONH--COO- or a substituted or unsubstituted phenylene group, and B represents a substituted or unsubstituted alkylene group. , represents a phenylene group or an aralkylene group, and L is -CONH--NHCONH- -NHCOO--NHCO--0CONHNH--CO
O--0CO--CO- -O--9--8O, --NH8O, - or -3O,
Represents NH-. a, b, and c represent 0 or l. Q represents a combined yellow coupler residue represented by the general formula (Il).

As the multimer, a copolymer of a yellow color-forming monomer represented by a coupler unit of the general formula [[[] and the following non-color-forming ethylene-like monomer is preferred.

Examples of non-color-forming ethylene monomers that do not couple with the oxidation products of aromatic-grade amine developers include acrylic acid,
α-Chloroacrylic acid, α-alkylacrylic acid (e.g. methacrylic acid, etc.) Amides or esters derived from these acrylic acids (e.g. acrylamide, methacrylamide, n-butylacrylamide, t-
Butyl acrylamide, diacetone acrylamide, methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, a-butyl acrylate, 1so-butyl acrylate, 2-ethylhexyl acrylate, n-octyl acrylate, lauryl acrylate, methyl methacrylate , ethyl methacrylate, n-butyl methacrylate and β-hydroxy methacrylate), vinyl esters (e.g. vinyl acetate, vinyl propionate and vinyl laurate), acrylonitrile, methacrylatrile,
Aromatic vinyl compounds (e.g. styrene and its derivatives, e.g. vinyltoluene, divinylbenzene, vinylacetophenone and sulfostyrene), itaconic acid, citraconic acid, crotonic acid, vinylidene chloride, vinyl alkyl ethers (e.g. vinyl ethyl ether),
Maleic acid ester, N-vinyl-2-pyrrolidone, N
-vinylpyridine and 2- and -4-vinylpyridine.

Particularly preferred are acrylic esters, methacrylic esters, and maleic esters. Two or more kinds of the non-color-forming ethylene monomers used here can also be used together. For example, methyl acrylate and butyl acrylate, butyl acrylate and styrene, butyl methacrylate and methacrylic acid, methyl acrylate and diacetone acrylamide, etc. can be used.

As is well known in the field of polymer couplers (the general formula [l11
) The ethylenically unsaturated monomer to be copolymerized with the vinyl monomer corresponding to For example, it can be selected so that its compatibility with gelatin, its flexibility, thermal stability, etc. are favorably influenced.

The yellow polymer coupler used in the present invention is obtained by dissolving a lipophilic polymer coupler obtained by polymerizing a vinyl monomer to give a coupler unit represented by the above general formula [11) in an organic solvent and adding it to an aqueous gelatin solution. It may be made by emulsifying and dispersing it in the form of latex, or it may be made directly by emulsion polymerization.

U.S. Patent No. 3,45 discloses a method for emulsifying and dispersing lipophilic polymer couplers in an aqueous gelatin solution in the form of latex.
No. 1,820, and U.S. Pat. No. 4,08 for emulsion polymerization.
The methods described in No. 0,211 and No. 3,370.952 can be used.

Specific examples of the yellow dye-forming couplers R1 and X represented by the general formula [I] are shown below, but the present invention is not limited thereto.

A specific example of X is shown below.

(1) (2) (9) (11) (12) (13) (5) (6) H (23) (14) (15) (24) (25) A specific example of R1 is shown below.

(17) Hz (18) (20) (21) (22) Hz -CONH(CHz)sOc+! H□ -NHCOCIs)Is+-n (47) (48) General formula (1) The yellow pigment forming force expressed by Specific examples of pullers are shown below.

C1@H*? -NllCOCHzCHCOOC)Is-NH5OzC
l! It! S-n (38) (39) (42) (43) (44) In the table, the numbers in parentheses represent the numbers assigned to the specific examples of X and R8, and the numbers in [ ] represent the numbers on the anilide group. Represents the replacement position.

The coupler of the present invention may be used alone, or may be used in combination of two or several kinds, or may be used in combination with a known yellow dye-forming coupler.

The couplers of the present invention can be used in any layer of the light-sensitive material, but are preferably used in the light-sensitive silver halide emulsion layer or a layer adjacent thereto, most preferably in the light-sensitive silver halide emulsion layer.

The coupler of the present invention can be synthesized by conventionally known synthesis methods.
There is a synthesis method described in the specification of No. 23047.

The amount of the coupler of the present invention used in the light-sensitive material is 1xto-'mol-10-' mol per ld, preferably l
Xl0-' mol to 5XlO-' mol, more preferably 2
x10-'' moles-101 moles.

As the antibacterial and antifungal agent used in the present invention, any generally known agent may be used, such as ``Bacterial and Antifungal Handbook'' edited by the Japanese Society of Antibacterial and Antifungal, ``Chemistry of Antibacterial and Antifungal'' by Hiroshi Horiguchi, Hygiene. Those described in "Sterilization, sterilization, and anti-mold technology of microorganisms" edited by the Technical Society, "Encyclopedia of anti-bacterial and anti-mildew" edited by the Japanese Society of Anti-bacterial and Anti-mold, etc. can be used.

Preferably, compounds represented by the following general formulas (F-I) to (F-VIII) are used.

General formula (F-I) General formula (F-n) R″ General formula (F-II) General formula (F-IV) General formula (F-V) General formula (F-VI) General formula (F-■ ) General formula (F-VIII) (wherein R2, R3, R', R'SR', R'' and R' represent a hydrogen atom, an alkyl group, or an aryl group, and R7 represents a hydrogen atom, an alkyl group, group, aryl group, nitro group, carboxy group, sulfo group, sulfamoyl group, hydroxy group, halogen atom, alkoxy group, or thiazolyl group. RIo represents an alkylene group or arylene group. "represents a halogen atom or an alkyl group, R
11 and R'' represent a hydrogen atom, an alkyl group, an aryl group, or a nitrogen-containing heterocyclic residue.R'' and RI
+ represents a hydrogen atom, an alkyl group, a halogen atom, or an aryl group, and R'' and R'' may be combined to form a benzene ring. R" represents a hydrogen atom or an alkyl group. R" represents an alkyl group or an aryl group.

Y represents a halogen atom, Zl represents a nonmetallic atomic group necessary to form a thiazolyl ring, and Zl represents a nonmetallic atomic group necessary to form a six-membered ring. n represents 0 or 1, and m represents 1 or 2.

) (A-4) Specific examples of compounds represented by formulas (F-r) to (F-VIII) are shown below, but the present invention is not limited thereto.

(A-1) (A-2) (A-3) (A-zl (person-lσ) (^-4) (person-ttl (person-lko) (^-2) (A-/J) (^-1) 1 person-/da) (^-de) IA-it) (A-/≦) (λ-ty) (person-//1 H!ICI!-Group-C→Town (λ- /de) (^-aJ) (^-ko4) (A-17) (person-kot) (person-ko0) (A-J/) (^-koJ) (A-JJ) (A -koda) [A-Jσ) (^-7/) (^-Jko) (A-77) (A-Jda) (A-35) (A-36) (A-37) Mouth (A- 38) (A-39) In addition to the compounds represented by general formulas (F-I) to (F-VIII), methyl-1-(butylcarbamoyl)-2-benzimidazole carbamate, methylbenzimidazole carbamate, 2-pyridinethiol -1-oxide, 10.10'-oxybisphenoxyarsine, N
-dimethyl-N'phenol-N'-(fluorodichloromethylthio)-sulfamide, benzylbromoacetate 1((shortmethyl)sulfonyl)-4-methylbenzene, 2. 3. 5. 6-Chitrachlor 4-(
methylsulfonyl)pyridine, p-chlorophenyl-3
- Iodopropargyl formal, phenylphenol, pentachlorophenol, 4-chloro-3,5-xylenol, phenol, thymol, phenoxyethanol, m-cresol, phenethyl alcohol, p-isopropylphenol, salicylic acid, etc. may be used. .

These antibacterial and antifungal agents may be used alone or in combination of two or more, and any layer may be added. That is, it may be added to any of the silver halide emulsion layer, intermediate layer, protective layer, or ultraviolet absorbing layer, or to a plurality of these layers. The amount added depends on the type of antibacterial and antifungal agent, but is preferably 0.001 to 1. Og/m, more preferably 0.0
It is 5 to 0.5 g/+d.

The antibacterial and fungicidal agent used in the present invention is generally effective against most molds, including molds that grow on silver halide photographic materials. As an example of mold, Asper
gillusniger, Pu1lularia p
ullufans, Chaefomium glob
osun+, Cladosporium resin
ae, Aspergillus flavus, A
spergillus oryzae.

Penicillium citrinum, Pen
icillium Iuteum.

Trichoderma uiride,
Aspergi! Ius restr-clus,
Aspergil [us glaucus, Chry
sosporium.

Aspergillus vesirolor, Eu
rotium rubrum.

Eurotium tonophilum, Arth
rium pestalotia.

There are Paeci lon + yces, etc.

The color photographic light-sensitive material of the present invention can be constructed by coating at least one blue-sensitive silver halide emulsion layer, one edge-sensitive silver halide emulsion layer, and one red-sensitive silver halide emulsion layer on a support. In general color photographic paper, the layers are usually coated on the support in the above order, but they may be applied in a different order. Furthermore, an infrared-sensitive silver halide emulsion layer can be used in place of at least one of the above-mentioned emulsion layers. These photosensitive emulsion layers contain a silver halide emulsion sensitive to each wavelength range, and dyes that are complementary colors to the sensitizing light - yellow for blue, magenta for green, and cyan for red.
By containing a so-called color coupler that forms a color, subtractive color reproduction can be performed. However, the coloring hues of the photosensitive layer and the coupler may not correspond as described above.

As the silver halide emulsion used in the present invention, one consisting of silver chlorobromide or silver chloride that does not substantially contain silver iodide can be preferably used. Here, "substantially free of silver iodide" means that the silver iodide content is 1 mol% or less, preferably 0.2 mol% or less. The halogen composition of the emulsion may be different or the same among the grains, but if an emulsion having the same halogen composition among the grains is used, it is easy to make the properties of each grain uniform. In addition, regarding the halogen composition distribution inside silver halide emulsion grains, there are grains with a so-called uniform structure in which the composition is the same in every part of the silver halide grain, and grains with a core inside the silver halide grain and a shell surrounding it. (shell) [-layer or multiple layers] Particles with a so-called layered structure in which the halogen composition is different, or
Particles with a structure that has parts with different halogen compositions in a non-layered manner inside or on the particle surface (if on the particle surface, parts with different compositions are joined on the edge, corner, or surface of the particle) are appropriately selected and used. be able to. In order to obtain high sensitivity, it is more advantageous to use one of the latter than particles with a uniform structure, and it is also preferable from the viewpoint of pressure resistance. When the silver halide grains have the above structure, the boundaries between the parts that differ in halogen composition are
The boundaries may be clear, or may be unclear due to the formation of mixed crystals due to compositional differences, or may have continuous structural changes.

Regarding the halogen composition of these silver chlorobromide emulsions, any silver bromide/silver chloride ratio can be used. Although this ratio can vary widely depending on the purpose, a silver chloride ratio of 2% or more is preferably used.

Furthermore, so-called high-silver chloride emulsions having a high silver chloride content are preferably used in light-sensitive materials suitable for rapid processing. The silver chloride content of these high silver chloride emulsions is preferably 90 mol% or more,
More preferably 95 mol% or more.

Such a high silver chloride emulsion preferably has a structure in which the localized silver bromide layer is provided inside and/or on the surface of the silver halide grains in a layered or non-layered manner as described above. The halogen composition of the localized layer preferably has a silver bromide content of at least 10 mol%, more preferably more than 20 mol%. These localized layers can be located inside the grains or on the edges, corners, or surfaces of the grain surfaces, and one preferred example is one in which they are epitaxially grown on a part of the corner of the grains.

On the other hand, in order to minimize the decrease in sensitivity when a photosensitive material is subjected to pressure, even in high silver chloride emulsions with a silver chloride content of 90 mol% or more, grains with a uniform structure with a small distribution of halogen composition within the grains are used. It is also preferable to use

Furthermore, it is also effective to further increase the silver chloride content of the silver halide emulsion for the purpose of reducing the amount of replenishment of the development processing solution.

In such cases, the silver chloride content is 98 mol% to 10
Emulsions of almost pure silver chloride, such as 0 mol %, are also preferably used.

Average grain size of the silver halide grains contained in the silver halide emulsion used in the present invention (the grain size is defined as the diameter of a circle equivalent to the projected area of the grain, and the number average thereof is taken)
is preferably 0.1 μ to 2 μ.

In addition, their particle size distribution has a coefficient of variation (standard deviation of particle size distribution divided by average particle size) of 20%.
Hereinafter, a so-called monodisperse material having a content of 15% or less is preferable. At this time, in order to obtain a wide latitude, it is preferable to blend the above-mentioned monodispersed emulsions in the same layer or to apply multilayer coating.

The shape of silver halide grains contained in photographic emulsions is regular (cubic, tetradecahedral, or octahedral).
lar) those with crystal shapes, those with irregular crystal shapes such as spherical, plate-like, etc.
Alternatively, a composite form of these can be used. Moreover, it may be made of a mixture of crystals having various crystal forms. In the present invention, among these particles, it is preferable to contain particles having the above-mentioned regular crystal shape in an amount of 50% or more, preferably 70% or more, and more preferably 90% or more.

In addition to these, the average aspect ratio (yen equivalent diameter/
Emulsions in which the projected area of tabular grains having a thickness of 5 or more, preferably 8 or more, exceeds 50% of the total grains can also be preferably used.

The silver chlorobromide emulsion used in the present invention is P, Glafkid
Chimia at Ph1sique Pho
tographique (Pau1Monte1, 1967), by G. F. Pho
to-graphic Bmulsion Chemi
stry (Focal Press, 1966), V, L, Zelikman et a1, M
making and coating photogra
phic Bmuldion (Focal Pres.
It can be prepared using the method described in J.S. Publishing, 1964). That is, any of the acidic method, neutral method, ammonia method, etc. may be used, and the method for reacting the soluble silver salt with the soluble halogen salt may be any method such as one-sided mixing method, simultaneous mixing method, or a combination thereof. May be used. A method in which particles are formed in an atmosphere containing excess silver ions (so-called back mixing method) can also be used. As one type of simultaneous mixing method, a method in which lllAg in the liquid phase in which silver halide is produced can be kept constant, that is, a so-called Chondral double jet method can also be used. According to this method, a silver halide emulsion having a regular crystal shape and a nearly uniform grain size can be obtained.

Various polyvalent metal ion impurities can be introduced into the silver halide emulsion used in the present invention during the process of emulsion grain formation or physical ripening.

Examples of compounds used include cadmium, zinc, lead,
Salts such as copper and thallium, or iron, which is a group II element,
Examples include salts or complex salts of ruthenium, rhodium, palladium, osmium, iridium, platinum, and the like. In particular, the above-mentioned Group Ⅰ elements can be preferably used. The amount of these compounds added varies over a wide range depending on the purpose, but is preferably from 10@1 to 10@-2 mol relative to silver halide.

The silver halide emulsion used in the present invention is usually subjected to chemical sensitization and spectral sensitization.

Regarding the chemical sensitization method, sulfur sensitization typified by the addition of unstable sulfur compounds, noble metal sensitization typified by gold sensitization, or reduction sensitization can be used alone or in combination. Regarding compounds used for chemical sensitization, see the lower right column on page 18 of the specification of JP-A-62-215272.
Those described in the upper right column of page 22 are preferably used.

Spectral sensitization is carried out for the purpose of imparting spectral sensitivity in a desired light wavelength range to the emulsion of each layer in the light-sensitive material of the present invention. In the present invention, it is preferable to add a dye-spectral sensitizing dye that absorbs light in a wavelength range corresponding to the desired spectral sensitivity. Spectral sensitizing dyes used at this time include, for example, F, M, HarIIler, H.
atarocyclic compounds-Cya
nine dies and rated com
pounds (John Wiley & 5ons
[New York, London), 1964
2013). As specific examples of the compounds, those described in the above-mentioned JP-A-62-215272 specification, page 22, upper right column to page 38, are preferably used.

The silver halide emulsion used in the present invention has the following properties:
Alternatively, various compounds or their precursors can be added for the purpose of stabilizing photographic performance. As specific examples of these compounds, those described on pages 39 to 72 of the specification of JP-A-62-215272 mentioned above are preferably used.

The emulsion used in the present invention may be either a so-called surface latent image type emulsion in which a latent image is mainly formed on the grain surface or a so-called internal latent image type emulsion in which a latent image is mainly formed inside the grain. Although surface latent image type emulsions are preferred.

In the present invention, in addition to the yellow coupler of general formula (I), magenta couplers and cyan couplers, which develop magenta and cyan colors, respectively, by coupling with oxidized products of aromatic primary amine color developing agents are commonly used.

Cyan couplers and magenta couplers preferably used in the present invention have the following general formulas (C-I), (C-
n), (M-1), and (M-II).

General formula (C-1) H General formula (C-11) 0H Y.

General formula (M-I) R1 General formula (M-n) In general formulas (C-1) and (C-11), R8,
R2 and R4 represent a substituted or unsubstituted aliphatic, aromatic or heterocyclic group, R3, R3 and R1 represent a hydrogen atom, halogen atom, aliphatic group, aromatic group or acylamino group, and R5 together with R2 It may also represent a group of nonmetallic atoms forming a nitrogen-containing 5- or 6-membered ring. Yl
, Y2 represents a hydrogen atom or a vine group that is released during the coupling reaction with the oxidized product of the developing agent. n represents 0 or 1.

R3 in general formula (C-IF) is preferably an aliphatic group, such as methyl group, ethyl group, propyl group, butyl group, pentadecyl group, tart-butyl group, cyclohexyl group, cyclohexylmethyl group, phenyl group. Examples include thiomethyl group, dodecyloxyphenylthiomethyl group, butanamidomethyl group, and methoxymethyl group.

Preferred examples of the cyan coupler represented by the general formula (C-■) or (C-II) are as follows.

In general formula (C-I), preferable R1 is an aryl group,
A heterocyclic group, such as a halogen atom, an alkyl group, an alkoxy group, an aryloxy group, an acylamino group, an acyl group,
More preferably, it is an aryl group substituted with a carbamoyl group, a sulfonamide group, a sulfamoyl group, a sulfonyl group, a sulfamide group, an oxycarbonyl group, or a cyano group.

In general formula (C-I), when L and R2 do not form a ring, R3 is preferably a substituted or unsubstituted alkyl group or aryl group, particularly preferably a substituted aryloxy-substituted alkyl group, and R3 is Preferably it is a hydrogen atom.

In the general formula (C-n), R3 is preferably a substituted or unsubstituted alkyl group or aryl group, and particularly preferably a substituted aryloxy-substituted alkyl group.

In general formula (C-II), R3 preferably has 2 to 2 carbon atoms.
It is a methyl group having 15 alkyl groups and a substituent having 1 or more carbon atoms, and the substituent is preferably an arylthio group, an alkylthio group, an acylamino group, an aryloxy group, or an alkyloxy group.

In general formula (Cn), R3 is more preferably an alkyl group having 2 to 15 carbon atoms, particularly preferably an alkyl group having 2 to 4 carbon atoms.

In the general formula (C-Ir), preferred R6 is a hydrogen atom,
A halogen atom, with chlorine and fluorine atoms being particularly preferred. Preferred Y and Y in general formulas (C-I) and (C-m) are a hydrogen atom, a halogen atom, an alkoxy group, an aryloxy group, an acyloxy group, and a sulfonamide group, respectively.

In general formula (M-1), R1 and R1 represent an aryl group, R represents a hydrogen atom, an aliphatic or aromatic acyl group, an aliphatic or aromatic sulfonyl group,
Y represents a hydrogen atom or a leaving group.

Aryl group (preferably phenyl group) of R7 and R9
The substituents allowed for are the same as the substituents allowed for substituent R3, and when there are two or more substituents, they may be the same or different. R is preferably a hydrogen atom, an aliphatic acyl group or a sulfonyl group, particularly preferably a hydrogen atom.

Preferred Y is of the type that leaves off with either a sulfur, oxygen or nitrogen atom, eg US Patent! 4.3
Particularly preferred are the sulfur atom separation types as described in No. 51.897 and International Publication No. W0118104795.

In general formula (M-II), RIG represents a hydrogen atom or a substituent. Y represents a hydrogen atom or a leaving group, and particularly preferably a halogen atom or an arylthio group. Za,
2b and Zc are methine, substituted methine, =N-1;! −
In NH4iL, one of the Za-Zb bond and Zb-Zc bond is a double bond, and the other is a single bond.

The case where the Zb-Zc bond is a carbon-carbon double bond includes the case where it is a part of an aromatic ring. R1° or Y.

When a dimer or more multimer is formed with Za.

When zh or Zc is a substituted methine, it includes the case where the substituted methine forms a dimer or more multimer.

Among the pyrazoloazole couplers represented by the general formula (M-n), imidazo C1,2-C1,2-, which is described in U.S. Pat. b] Pyrazoles are preferred, such as pyrazolo[1,
5-bl[:1,2,4]) riazoles are particularly preferred.

In addition, a branched alkyl group as described in JP-A No. 61-65245 is directly connected to the 2.3 or 6-position of the pyrazolotriazole ring to create a pyrazolotriazole coupler, which is described in JP-A No. 61-65246. pyrazoloazole couplers containing a sulfonamide group in the molecule, pyrazoloazole couplers having an alkoxyphenylsulfonamide ballast group as described in JP-A-61-147254, and European Patent Publication No. 226. It is preferred to use pyrazolotriazole couplers having an alkoxy or aryloxy group in the 6-position, such as those described in No. 849 and No. 294.785.

General formula (C-I), (C-old, (M-I), (M-II)
) Specific examples of couplers represented by °1 are listed below.

(C-1> α (C-4) (C-5> (C-6) (C-7) (C-8) (C-13) (C-14) (C-15) (C-16 ) I I (C-9) (C-10) (C-12) (C-17) (C-18) (C-19) I (C-20) (C-21) (C-22) ( M-4) (M-6) UshiHco (M-1) (M-2) (M-7) (M-8) I CH8 I Above general formulas (C-I) to (1-14) Various known techniques can be applied to the coupler represented by 0.1 to 1.0 mole per mole of silver halide in the silver halide emulsion layer constituting the photosensitive layer. Yes, usually.
It can be added by the oil-in-ice dispersion method known as the oil protection method, and after being dissolved in a solvent, it is emulsified and dispersed in an aqueous gelatin solution containing a surfactant. Alternatively, water or an aqueous gelatin solution may be added to a coupler solution containing a surfactant to form an oil-in-ice droplet dispersion with phase inversion.

Alkali-soluble couplers can also be dispersed by the so-called Fischer dispersion method. From the coupler dispersion,
The low-boiling organic solvent may be removed by distillation, noodle washing, ultrafiltration, or the like, and then mixed with the photographic emulsion.

As a dispersion medium for such a coupler, the dielectric constant (25℃)
2-20. It is preferable to use a high boiling point organic solvent and/or a water-insoluble polymer compound having a refractive index (25° C.) of 1.5 to 1.7.

As the high boiling point organic solvent, preferably the following general formula (A) ~
A high boiling point organic solvent represented by (E) is used.

General formula (A) L M, -0-P=0 General formula (B) L　COOWi General formula (E) W, -0-W.

(In the formula, L, W, and W are each substituted or unsubstituted alkyl group, cycloalkyl group, alkenyl group,
represents an aryl group or a heterocyclic group, L is 111, Ow
1 or S-1, n is an integer from ■ to 5, and when n is 2 or more, 1l14 may be the same or different from each other, and in the general formula (E), L and 6 are fused rings. ).

The high boiling point organic solvent used in the present invention has a melting point of 100°C or less and a boiling point of 140°C, even if other than those of general formula (A) or E).
Any of the above water-immiscible compounds can be used as long as they are good solvents for couplers. The melting point of the high boiling point organic solvent is preferably 8
The temperature is below 0°C. The boiling point of the high boiling point organic solvent is preferably 160°C or higher, more preferably 170°C or higher.

For details on these high boiling point organic solvents, please refer to JP-A-62
-215272 Publication Specification, page 137, lower right column ~ 14
It is written in the upper right column of page 4.

These couplers can also be synthesized with rhodapul latex polymers (
For example, it can be emulsified and dispersed in an aqueous hydrophilic colloid solution by impregnating it with a water-insoluble but organic solvent-soluble polymer.

Preferably, the homopolymers or copolymers described on pages 12 to 30 of International Publication No. W088100723 are used, and acrylamide-based polymers are particularly preferred from the viewpoint of color image stabilization.

The light-sensitive material produced using the present invention may contain a hydroquinone derivative, an aminophenol derivative, a gallic acid derivative, an ascorbic acid derivative, etc. as a color antifoggant.

Various anti-fading agents can be used in the photosensitive material of the present invention. That is, hydroquinones, 6
-Hydroxychromans, 5-hydroxycoumarans,
Spirochromans, p-alkoxyphenols, hindered phenols centered on bisphenols, gallic acid derivatives, methylenedioxybenzenes, aminophenols, hindered amines, and silylation and alkylation of the phenolic hydroxyl groups of these compounds. Typical examples include ether or ester derivatives. Further, metal complexes such as (bissalicylaldoximado)nickel complex and (bis-N,N-dialkyldithiocarbamado)nickel complex can also be used.

Specific examples of organic antifade agents are described in the following patent specifications:

Hydroquinones are U.S. Patent No. 2.360.290,
Same No. 2.41111.613, Same No. 2.700.45
No. 3, No. 2,701, No. 197, No. 2.728.6
No. 59, No. 2.732.300, No. 2.735.
No. 765, No. 3.982.944, No. 4,430
, No. 425, British Patent No. 1.363.921, U.S. Patent No. 2,710.801, U.S. Pat. is U.S. Patent No. 3.432.
No. 300, No. 3.573.050, No. 3.574
．． No. 627, No. 3.698゜909, No. 3.76
4.337, JP-A-52-152225, etc. Spiroindans are described in U.S. Patent No. 4.360.589,
p-Alkoxyphenols are described in U.S. Patent No. 2.735.
No. 765, British Patent No. 2.066, 975, JP-A-5
No. 9-10539, Special Publication No. 57-19765, etc.
Hindered phenols are U.S. Patent No. 3.700.45
No. 5, JP-A No. 52-72224, U.S. Patent No. 4.228
．． Gallic acid derivatives, methylenedioxybenzenes, and aminophenols are disclosed in U.S. Patent No. 3.457.079, U.S. Pat. No. 21144, etc., and hindered amines are disclosed in U.S. Patent No. 3.336.13.
No. 5, No. 4.268.593, British Patent No. 1.32
No. 6.889, No. 1.354.313, No. 1, 4
10.1iA6, Japanese Patent Publication No. 51-1420, Japanese Patent Publication No. 1973
No. 8-114036, No. 59-53846, No. 5
No. 9-78344, etc., and metal complexes are disclosed in U.S. Patent No. 4.0.
50.938, British Patent No. 4.241°155, British Patent No. 2.027.731 (^), etc., respectively. The purpose of these compounds can be achieved by co-emulsifying them with a coupler and adding them to the photosensitive layer, usually in an amount of 5 to 100% by weight based on the corresponding color coupler. In order to prevent the cyan dye image from deteriorating due to heat and especially light, it is more effective to introduce an ultraviolet absorber into the cyan coloring layer and the layers on both sides adjacent to it.

As ultraviolet absorbers, benzotriazole compounds substituted with aryl groups (for example, U.S. Pat. No. 3,533.7
94), 4-thiazolidone compounds (e.g., U.S. Pat. No. 3.314.794, U.S. Pat. No. 3.352;
681), benzophenone compounds (e.g., those described in JP-A No. 46-2784), cinnamic acid ester compounds (e.g., those described in U.S. Pat. ), butadiene compounds (as described in U.S. Pat. No. 4,045,229), or benzoxidole compounds (e.g., U.S. Pat. No. 3,406,070, U.S. Pat. 271.307) can be used. An ultraviolet absorbing coupler (for example, an α-naphthol cyan dye-forming coupler) or an ultraviolet absorbing polymer may be used. These ultraviolet absorbers may be mordanted in specific layers.

Among these, benzotriazole compounds substituted with the aforementioned aryl group are preferred.

In addition to the above-mentioned couplers, it is particularly preferable to use the following compounds. Particularly preferred is the combination with a pyrazoloazole coupler.

That is, a compound (F) that chemically bonds with the aromatic amine developing agent remaining after color development processing to produce a chemically inert and substantially colorless compound and/or an aroma remaining after color development processing. For example, in storage after processing, the compound (G) that chemically bonds with the oxidized form of a group amine color developing agent to produce a chemically inert and substantially colorless compound may be used simultaneously or singly. This is preferable in order to prevent staining and other side effects caused by the formation of coloring dyes due to the reaction between the color developing agent or its oxidized product remaining in the film and the coupler.

A preferable compound (F) has a second-order reaction rate constant with p-anisidine (in trioctyl phosphate at 80°C) of 1.01/mol·sec ~ l x
lo-'! It is a compound that reacts in the range of /mat·sec.

Incidentally, the second-order reaction rate constant can be measured by the method described in JP-A-63-158545.

When k is larger than this range, the compound itself becomes unstable and may react with gelatin or water and decompose. On the other hand, if R2 is smaller than this range, the reaction with the remaining aromatic amine developing agent will be slow, and as a result, side effects of the remaining aromatic amine developing agent may not be prevented.

A more preferable compound (F) can be represented by the following general formula (Fl) or (FI[).

General formula (Fl) R1-(^)1-x General formula (FIr) R, -C=Y In the formula, R1 and R2 each represent an aliphatic group, an aromatic group, or a heterocyclic group. n represents 1 or 0.

A represents a group that reacts with the aromatic amine developer to form a chemical bond, and X represents a group that reacts with the aromatic amine developer and leaves. B represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an acyl group, or a sulfonyl group,
Y represents a group that promotes addition of an aromatic amine developing agent to the compound of general formula (FII). Here R3
and X%Y and R3 or B may be bonded to each other to form a cyclic structure.

Among the methods of chemically bonding with the residual aromatic amine developing agent, the typical ones are substitution reaction and addition reaction.

For specific examples of compounds represented by the general formula (Fl) and (Fl), see JP-A-63-158545 and JP-A-62-28
3338, European Patent Publication No. 298321, European Patent Publication No. 2775
Those described in specifications such as No. 89 are preferred.

On the other hand, a more preferable compound (G) that chemically bonds with the oxidized aromatic amine developing agent remaining after color development processing to produce a chemically inert and colorless compound is the following general formula (GI ).

General formula (GI) -Z In the formula, R represents an aliphatic group, an aromatic group or a heterocyclic group. Z represents a nucleophilic group or a group that decomposes in the photosensitive material to release a nucleophilic group. In the compound represented by the general formula (GI), Z has Paarson's nucleophilicity "CLI value (R
, G., Pearson, et al., J.
.

Chem, Sac, 90.319 (1968)
) is preferably 5 or more, or a group derived therefrom.

For specific examples of compounds represented by the general formula (GI), see European Patent Publication No. 255722, Japanese Patent Application Laid-Open No. 1430-1980
No. 48, No. 62-229145, patent application No. 63-136
No. 724, No. 62-214Ei81, European Patent Publication 2
Those described in No. 98321, No. 277589, etc. are preferred.

Further, details of the combination of the above-mentioned compound (G) and compound (F) are described in European Patent Publication No. 277589.

The photosensitive material produced using the present invention contains a water-soluble dye or a dye that becomes water-soluble through photographic processing as a filter dye in the hydrophilic colloid layer or for various purposes such as preventing irradiation or halation. You can leave it there. Such dyes include oxonol dyes, hemioxonol dyes, styryl dyes, merocyanine dyes, cyanine dyes and azo dyes. Among them, oxonol dyes, hemioxonol dyes and merocyanine dyes are useful.

As the binder or protective colloid that can be used in the emulsion layer of the light-sensitive material of the present invention, it is advantageous to use gelatin, but other hydrophilic colloids can be used alone or together with gelatin.

In the present invention, the gelatin may be either lime-treated or acid-treated. Details of the method for producing gelatin are described in The Macromolecular Chemistry of Gelatin, written by Arthur Vuis (Academic Press, published in 1964).

As the support 17 used in the present invention, a reflective support that is normally used in photographic materials can be used.

The ``reflective support j'' used in the present invention refers to one that enhances the reflectivity and makes the dye image formed in the silver halide emulsion layer clear. Examples include those coated with a hydrophobic resin containing a dispersed light-reflecting substance such as titanium oxide, zinc oxide, calcium carbonate, and calcium sulfate, and those using a hydrophobic resin containing a dispersed light-reflecting substance as a support. For example, baryta paper, polyethylene-coated paper, polypropylene synthetic paper, transparent supports with a reflective layer or a reflective material, such as glass plates, polyester films such as polyethylene terephthalate, cellulose triacetate or cellulose nitrate, polyamide film, polycarbonate film,
Examples include polystyrene film and vinyl chloride resin.

As other reflective supports, supports having a specular reflective or second type diffuse reflective metal surface can be used. The metal surface has a spectral reflectance of 0.0 in the visible wavelength range.
5 or more (and it is better to roughen the metal surface or use metal powder to make it diffusely reflective.The metal should be aluminum, tin, silver, magnesium, or an alloy thereof, and the surface It may be the surface of a metal plate, metal foil, or thin metal layer obtained by rolling, vapor deposition, plating, or the like.

Among these, it is preferable to obtain the metal by vapor-depositing the metal onto another substrate. Preferably, a layer of water-resistant resin, particularly thermoplastic resin, is provided on the metal surface. It is preferable to provide an antistatic layer on the side of the support of the present invention opposite to the side having the metal surface. For details of such a support, see, for example, JP-A-61-210
No. 346, No. 63-24247, No. 63-24251
No. 63-24255, etc.

These supports can be appropriately selected depending on the purpose of use.

As a light-reflecting substance, it is best to thoroughly knead a white pigment in the presence of a surfactant, and also coat the surface of the pigment particles with
It is preferable to use one treated with a tetrahydric alcohol.

The occupied area ratio (%) of white pigment fine particles per defined unit area is calculated by dividing the observed area into adjoining unit areas of 6 μm x 6 μm, and dividing the area of fine particles projected onto that unit area. It can be determined by measuring the occupied area ratio (%) (R,). The coefficient of variation of the occupied area ratio (%) can be determined by the ratio s/R of the standard deviation S of R8 to the average value (R) of R1. The number (n) of target unit areas is preferably 6 or more. Therefore, the coefficient of variation s/R can be determined.

In the present invention, the coefficient of variation of the occupied area ratio (%) of the pigment fine particles is preferably 0.15 or less, particularly 0.12 or less. If it is 0.08 or less, the dispersibility of the particles can be said to be "substantially uniform."

The color developing solution used in the development of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine color developing agent as a main component. Aminophenol compounds are also useful as color developing agents, but p-phenylenediamine compounds are preferably used, typical examples of which include 3-methyl-4-amino-N, N-diethylaniline, 3-diethylaniline, and Methyl-4-amino-N-ethyl-
N-β-hydroxyethylaniline, 3-methyl4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, 3-methyl-4-amino-N-ethyl-N
-β-methoxyethylaniline and their sulfates, hydrochlorides or p-toluenesulfonates.

Two or more of these compounds can be used in combination depending on the purpose.

The color developer may contain pH buffering agents such as alkali metal carbonates or phosphates, development inhibitors or antifoggants such as bromide salts, iodide salts, benzimidazoles, benzothiazoles or mercapto compounds. It is common to include

In addition, if necessary, various preservatives such as hydroxylamine, diethylhydroxylamine, sulfites, hydrazines such as N,N-biscarboxymethylhydrazine, phenyl semicarbazides, triethanolamine, catechol sulfonic acids, ethylene glycol, etc. , organic solvents such as diethylene glycol, development accelerators such as benzyl alcohol, polyethylene glycol, quaternary ammonium salts, amines, dye-forming couplers, competitive couplers, auxiliary developing agents such as l-phenyl-3-pyrazolidone, viscosity. Various chelating agents such as aminopolycarboxylic acid, aminopolyphosphonic acid, alkylphosphonic acid, and phosphonocarboxylic acid, such as ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, Hydroxyethyliminodiacetic acid, l-hydroxyethylidene-
1°l-diphosphonic acid, nitrilo-N,N,N-trimethylenephosphonic acid, ethylenediamine-N,N.

Representative examples include N',N'-tetramethylenephosphonic acid, ethylene glycol (0-hydroxyphenylacetic acid), and salts thereof.

Further, when performing reversal processing, color development is usually performed after black and white development and reversal processing. This black and white developer contains known black and white developing agents such as dihydroxybenzenes such as hydroquinone, 3-pyrazolidones such as 1-phenyl-3-pyrazolidone, or amine phenols such as N-methyl-p-aminophenol. Alternatively, they can be used in combination.

The pH of these color developing solutions and black and white developing solutions is generally 9 to 12. The amount of replenishment of these developing solutions depends on the color photographic light-sensitive material being processed, but is generally 31 or less per square meter of light-sensitive material, and the bromide ion concentration in the replenisher is reduced (possibly 500
It can also be less than i. When reducing the amount of replenishment, it is preferable to prevent evaporation of the liquid and air oxidation by reducing the area of contact with the air in the processing tank. The contact area between the photographic processing solution and air in the processing tank can be expressed by the aperture ratio defined below. That is, aperture ratio=contact area between processing liquid and air (cnf)/capacity of processing liquid (Ci) The above aperture ratio is 0. It is preferably 1 or less, more preferably 0.001-0.05.

As a method for reducing the aperture ratio in this way, in addition to providing a shield such as a floating lid on the surface of the photographic processing solution in the processing tank, methods using a movable lid as described in Japanese Patent Application No. 62-241342, Examples include the slit development method described in Japanese Patent No. 63-216050.

It is preferable to reduce the aperture ratio not only in both color development and black-and-white development, but also in all subsequent steps, such as bleaching, bleach-fixing, fixing, washing, and stabilization.

Furthermore, the amount of replenishment can be reduced by using means for suppressing the accumulation of bromide ions in the developer.

The time for color development processing is usually set between 2 and 5 minutes, but the processing time can be further shortened by using high temperature, high pH, and high concentration of color developing agent.

After color development, the photographic emulsion layer is usually bleached.

The bleaching process may be carried out simultaneously with the fixing process (bleach-fixing process) or separately. Furthermore, in order to speed up the processing, a processing method may be used in which bleaching is followed by bleach-fixing. Furthermore, depending on the purpose, treatment may be carried out in two consecutive bleach-fixing baths, fixing treatment before bleach-fixing treatment, or bleaching treatment after bleach-fixing treatment. As the bleaching agent, for example, a compound of a polyvalent metal such as iron (III) is used. Typical bleaching agents include organic complex salts of iron (III), such as aminopolymer salts such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, chlorohexanediaminetetraacetic acid, methyliminodiacetic acid, l,3-diaminopropanetetraacetic acid, and glycol etheraminetetraacetic acid. Carboxylic acids or citric acid, tartaric acid,
Complex salts such as malic acid can be used. Among these, aminopolycarboxylic acid iron(II[) complex salts including ethylenediaminetetraacetic acid iron([[) complex salts] are preferable from the viewpoint of rapid processing and prevention of environmental pollution. Furthermore, aminopolycarboxylic acid iron(III) complexes are particularly useful in both bleach and bleach-fix solutions. The pH of bleaching solutions or bleach-fixing solutions using these aminopolycarboxylic acid iron (I [ You can also.

A bleach accelerator may be used in the bleaching solution, bleach-fixing solution, and their prebaths, if necessary.

Specific examples of useful bleach accelerators are described in U.S. Pat. No. 3,893.858, German Pat.
, No. 290,812, JP-A-53-95630, Research Disclosure No. 17.129 (197
Compounds having a mercapto group or disulfide bond as described in J. No. 1987 (July 1983); thiazolidine derivatives as described in JP-A No. 140129/1983; U.S. Patent No. 3.706,5
1,000 urea derivatives described in No. 61: JP-A-58-1623
Iodide salt described in No. 5; West German Patent No. 2,748°430
Polyoxyethylene compounds described in No. 1973-
Polyamine compounds described in No. 8836; bromide ions, etc. can be used. Compounds that grow mercapto groups or disulfide groups are preferable from the viewpoint of having a large promoting effect, and are particularly preferred as described in U.S. Pat. The compounds described are preferred. Additionally, U.S. Pat. No. 4,552.
Compounds described in No. 834 are also preferred. These bleach accelerators may be added to the light-sensitive material. These bleach accelerators are particularly effective when bleach-fixing color light-sensitive materials for photography.

Examples of fixing agents include thiosulfates, thiocyanates, thioether compounds, thioureas, and large amounts of iodide salts, but thiosulfates are commonly used, and ammonium 100sulfate is the most common. Can be used widely. Preservatives for bleach-fixing solutions include sulfites, bisulfites, p-
Sulfinic acids such as toluenesulfinic acid or carbonyl bisulfite adducts are preferred.

The silver halide color photographic light-sensitive material of the present invention is generally subjected to water washing and/or stabilization steps after desilvering treatment.

The amount of water used in the washing process varies widely depending on the characteristics of the photosensitive material (for example, depending on the materials used such as couplers), the application, the temperature of the washing water, the number of washing tanks (stages), the replenishment method such as free flow or down flow, and various other conditions. Can be set to . Among these, the relationship between the number of washing tanks and the amount of water in the multistage countercurrent method is
urnalor the 5ociety of
Motion Picture and T
elevision Engineers Volume 64, P.
248-253 (May 1955 issue).

According to the multi-stage countercurrent method described in the above-mentioned literature, the amount of water used for washing can be significantly reduced, but due to the increase in the residence time of water in the tank, bacteria will breed, and the generated suspended matter will adhere to the photosensitive material. The problem arises. In the processing of the color photosensitive material of the present invention, as a solution to such problems,
The method for reducing calcium ions and magnesium ions described in JP-A-62-288838 can be used very effectively. In addition, isothiazolone compounds and thiabendazoles described in JP-A No. 57-8542,
Chlorine-based disinfectants such as chlorinated sodium isocyanurate,
Others, such as benzotriazole, Hiroshi Horiguchi, "Chemistry of antibacterial and antifungal J (1986), Sankyo Publishing, complete edition of sanitary technology, "sterilization of microorganisms, sterilization, antifungal technology J (1982), Society of Industrial Technology, Japan antibacterial and antifungal Academic Line [Encyclopedia of Antibacterial and Antifungal Agents J (1
It is also possible to use the fungicides described in 1986).

The pH of the washing water in the processing of the photosensitive material of the present invention is 4 to 4.
9, preferably 5-8. The washing water temperature and washing time can also be set variously depending on the characteristics of the photosensitive material, its use, etc., but generally it is 20 seconds to 10 minutes at 15 to 45°C, preferably 2
A range of 30 seconds to 5 minutes is selected at 5 to 40°C. Furthermore,
The light-sensitive material of the present invention can also be directly processed with a stabilizing solution instead of washing with water. In such stabilization treatment, Japanese Patent Application Laid-Open Nos. 57-8543 and 58-14834
All known methods described in No. 60-220345 can be used.

Further, following the water washing treatment, a further stabilization treatment may be carried out, such as a stabilizing bath containing formalin and a surfactant, which is used as a final bath for color photosensitive materials for photography. .

It is also possible to add various botanical agents and antifungal agents to this stabilizing bath.

The overflow liquid resulting from the water washing and/or replenishment of the stabilizing liquid can also be reused in processes such as the desilvering process.

The silver halide color light-sensitive material of the present invention may contain a color developing agent for the purpose of simplifying and speeding up processing. In order to incorporate the color developing agent, it is preferable to use various precursors of the color developing agent. For example, U.S. Patent No. 3,342,59
Indoaniline compound described in No. 7, No. 3.342,
No. 599, Research Disclosure 14,850
Ship base-type compounds described in No. and No. 15.159, aldol compounds described in No. 13.924, U.S. Patent No. 3
, 719,492, JP-A-53-13
Examples include urethane compounds described in No. 5628.

The silver halide color light-sensitive material of the present invention may optionally contain various 1-phenyl-3
- Pyrazolidones may be incorporated. Typical compounds are JP-A-56-64339, JP-A-57-144547,
and No. 58-115438.

Various treatment liquids in the present invention are used at 100C to 50C. Normally, the standard temperature is 33°C to 38°C, but higher temperatures can be used to accelerate processing and shorten processing time, or lower temperatures can be used to improve image quality and stability of the processing solution. can do. Further, in order to save silver on the photosensitive material, a treatment using cobalt intensification or hydrogen peroxide intensification as described in German Patent No. 2,226,770 or US Pat. No. 3,674,499 may be carried out.

(Example) The present invention will be described in detail below using Examples, but the present invention is not limited thereto.

Example 1 111 m of the first layer coating solution for a paper support laminated on both sides with polyethylene 19.1 g of yellow coupler (BxY), 4.4 g of color image stabilizer (Cpd-1), and color image stabilizer (Cp
d-7) Add and dissolve 27.2 cc of ethyl acetate and 8.2 g of solvent (Solv-3) to 0.7 g, and dissolve this solution in 3 cc of 10% sodium dodecylbenzenesulfonate.
The mixture was emulsified and dispersed in 185 cc of a 10% aqueous gelatin solution. On the other hand, bulk silver bromide emulsion (cubic, average grain size 0.8
3-near mixture of 8- and 0.70-(silver molar ratio). The coefficient of variation of particle size distribution is 0.08 and 0.08. l
O1 (Each emulsion contains 0.2 mol % of silver bromide locally on the grain surface) and the following blue-sensitive sensitizing dyes were added per mol of silver to 2.0 x 10-' mol of each for large-sized emulsions. , and for small size emulsions, 2.5X1, respectively.
After adding 0-' mole, sulfur sensitization was performed to prepare m.

The above emulsified dispersion and this emulsion were mixed and dissolved to prepare a first coating solution having the composition shown below.

The coating solutions for the second to seventh layers were also prepared in the same manner as the coating solution for the first layer. As the gelatin hardening agent for each layer, 1-year-old xy-3,5-dichloro-9-triazine sodium salt was used.

The following spectral sensitizing dyes were used in each layer.

Blue-sensitive emulsion layer so, e SOJ-N (CJs) Edge-sensitive emulsion layer (per mole of silver halide, 4.0XIO-' moles for large size emulsions, 5.6 for small size emulsions)
x10-' mol) and owe SO-NH(C2)1s) s (2.0 x 10-' mol each for large size emulsions and 2.0 x 10-' mol each for small size emulsions per mole of silver halide). 5X10-'mol) SOs' SO! H-N(C21(S)s (per mole of silver halide, 7.0X10-' mole for large size emulsions and 1 for small size emulsions)
．． 0x10-' mol) red-sensitive emulsion layer CJs (e 5H11 (0.9x10-' mol per mol of silver halide for large size emulsions and 1 for small size emulsions)
．． For the red-sensitive emulsion layer, 2.6X 10-' moles of the following compound were added per mole of silver halide.

8゜5X10-' mol per mole of silveride, 7.7X1
0-' mol, 2.5XlO-' mol was added.

The following dyes were added to the emulsion layer to prevent irradiation.

Furthermore, 1-(5-methylureidophenyl)-5-mercaptotetrazole was used as a halogen for each of the blue-sensitive emulsion layer, green-sensitive emulsion layer, and red-sensitive emulsion layer (layer structure) The composition of each layer is shown below. The numbers represent the coating amount (g/m''). Silver halide emulsions represent the coating amount in terms of silver.

Support polyethylene laminate paper [The polyethylene on the first layer side contains a white pigment (TiO=) and a bluish dye (ulmarine blue)] -th layer (blue-sensitive layer) Said silver chlorobromide emulsion 0.30 Gelatin 1.86 Izo-Coupler (BXY) 0.82 color image stabilizer (
Cpd-1) 0.19 solvent (S
OIV-3) 0.35 Color image stabilizer (Cpd-7) 0.06
Second layer (color mixing prevention layer) Gelatin 0.99 Color mixing prevention agent (Cpd-5>0.08 Solvent (SOIV-1) 0.16
Solvent (Solv-4) 0.
08 Fifth layer (R sensitive layer) Silver chlorobromide emulsion (cubic, 1:3 mixture (^g molar ratio) of one with an average grain size of 0.55 m and one with an average grain size of 0.39 m. Variation in grain size distribution The coefficients are 0.10 and 0.08,
(Each emulsion contained 0.8 mol% of AgBr locally on the grain surface) 0.12 Gelatin
1.24 magenta coupler <BxM
) 0.20 color image stabilizer (CPd-2
) 0.03 color image stabilizer (CPd
-3) 0.15 color image stabilizer (C
pd-4) 0.02 color image stabilizer (Cpd-9) 0.02 solvent (
Solv-2) 0.4
0 Fourth layer (ultraviolet absorption layer) Gelatin 1.58 Ultraviolet absorber (tlV-1) 0.47 Color mixing inhibitor (Cpd-5) 0.0
5 solvent (SOIV-5) 0
．． 24 Fifth layer (red-sensitive layer) Silver chlorobromide emulsion (cubic, 1:4 mixture (hg molar ratio) of one with an average grain size of 0.58 m and one with an average grain size of 0.45 m. The coefficient of variation is 0.09 and 0.11,
(Each emulsion contained 6 mol% of gBrO locally on a part of the grain surface) 0.23 gelatin
1.34 cyan coupler (BxC)
0.32 color image stabilizer (Cpd-6)
0.1.7 Color image stabilizer (Cpd
-7) Color image stabilizer (Cpcl-8) Solvent (Solv-6) Sixth layer (ultraviolet absorption layer) Gelatin ultraviolet absorber (mouth v-1) Color mixing inhibitor (Cpd-5) Solvent (So I v- 5) Seventh layer (protective layer) Gelatin polyvinyl alcohol scum (denaturation degree 17%) Liquid paraffin 0.40 0.04 0.15 0.53 0, 16 0.02 0.08 1.33 Lyle modified copolymer Coalescence 0.17 0.03 1=1 mixture (molar ratio) ([!XM) Magenta coupler (εXY) Yellow coupler 2H5 1:1 mixture (molar ratio) (ToC) Cyan coupler ([:pd-2 ) Color Image Stabilizer α C-QC-Hs R=CJs, C4L, and (Cpd-3) Color Image Stabilizer I Mixture of 2:4:4 by weight, respectively (Cpd-4) Color Image Stabilizer (Cpd- 1) Color image stabilizer (Cpd-5> Color mixture prevention agent (Cpd-6) Color image stabilizer (Cpd-9) Color image stabilizer (V-1) Ultraviolet absorber 2: Mixture (weight ratio) ( Cpd-7) Color image stabilizer Be[:L-CH) -- C0NHC,H, (t) Average molecular weight 60.000 (Cpd-8) 4:4 mixture (weight ratio) of color image stabilizer (Solv- 1) Solv-5 solvent C00C,H,? (CL)・C00CaLt (Solv-2) Solv-6) Solvent 2:1 mixture (volume ratio) (Solv-3) Solv-4) Creation of color photographic paper B-P Color photographic paper A Photographic papers B to P were prepared in exactly the same manner as photographic paper A except that the yellow coupler was replaced with the exemplified compound and the exemplified compound of the antibacterial and fungicidal agent was added. The amount of each coupler added to the photographic papers B to P was set to be equimolar to the amount added to each layer of the photographic paper. The composition of photographic paper BP is shown in Table 1.

First, attach a photosensitive needle (manufactured by Fuji Photo Film Co., Ltd.,
A FWH type (light source color temperature: 3200°K) was used to provide gradation exposure of a three-color separation filter for sensitometry. The exposure at this time was 0. 250 CM with 1 second exposure time
The exposure amount was set to S.

Separately, each sample was exposed uniformly to light through a transparent glass using the photosensitive needle described above.

At this time, the exposure time was 2 seconds and the exposure time was 20. The exposure amount was set to OOOCMS.

The former sample exposed to three-color separation filter and the latter sample exposed to transparent glass were used for acid fading test and mold growth test, respectively, after treatment.

The exposed sample was subjected to continuous processing (running test) using a paper processing machine until twice the color development tank capacity was replenished in the next processing step.

Processing process ■ Concave 1-way color development
35℃ 45 seconds 161m7 17N bleach fixing 3
0~35℃ 45 seconds 215d 171 Rinse ■ 3
0~35℃ 20 seconds -101 rinse■ 30~35
°0 20 seconds -104' rinse■ 30-35℃
20 seconds 350d 101 drying 70-80
The amount of replenishment for 60 seconds was per 1 rrr of photosensitive material (a 3-tank countercurrent force type was used for rinsing ①-②).The composition of each processing solution was as follows.

Standing Dan Second Base Eikiri Mu 1 Kin Plate Charging Water
80 (7! 800d
Ethylenediamine-N.

N, N, N-tetramethylenephosphonic acid 1. ．． 5g 2.0g Potassium bromide 0.015g Triethanolamine Sodium chloride Potassium carbonate N-ethyl-N-(β-methanesulfonamidoethyl)-3 Methyl-4-aminoaniline sulfate N,N-bis(carboxymethyl( Hydrazine optical brightener (W) lITEX4B.

8.0g 12.0g 1.4g 5g 5g 5.0g 7.0g 5.5g 7.0g Add water l000111100O1
ntpH (25°C) 10.05
10.45 Bleach-fix solution (tank solution and replenisher are the same) water
400-Ammonium thiosulfate (70%) 100ml Sodium sulfite 17g Iron(I) ethylenediaminetetraacetate Ammonium 55g Disodium ethylenediaminetetraacetate 5g Add water 1000T! pH (25°C)6.
0 Rinse solution (tank solution and refill solution are the same) Ion exchange water (calcium, magnesium 3pp each
m or less) Acid fading test Each processed sample for acid fading test is added to 1N citric acid solution.
After being immersed for 1 minute, dried at 80° C. 030% or 40° C. 70% for 3 days, the decrease in yellow density from the initial density of 2.0 was measured.

Each sample for mold growth test that has been processed for mold growth test was cut into a size of 35w x 35 pieces, and M40Y medium (glucose, malt extract, yeast extract, and BACT-Agar) was placed in the center of the sample.
15 μl of a suspension of a strain of the genus Aspergillus, Penicillium, or Paec i Iomyces, which occurs on color photographic paper, was added dropwise to a 1/10 diluted solution containing (containing 100% of the total number of microorganisms containing 10% of the total number of microorganisms containing 10% of the total number of microorganisms containing 100% of the total number of microorganisms containing 100% of the total number of microorganisms containing 100% of the total number of microorganisms in the sample). Next, this is heated to 20℃ and relative humidity is 1.
00% condition for 3 weeks, and the state of mold growth was observed. The results are shown in Table 1, where the numerical values indicate the diameter (mm) of the hyphae and the expanded area, and are expressed in the range of 0 to 35. That is, the smaller the value, the better the anti-mold effect, 0 means no mold is generated, and 35 means mold is generated on the entire surface of the sample. At the same time, the degree of discoloration of the mold-infested area was also observed. The results of these tests are shown in Table 1.

/ As is clear from the results in Table 1, the samples of the present invention are excellent in acid fading and have good mold resistance.

It can also be seen that even when mold occurs, yellow fading is better than in the comparative example.

(Effects of the Present Invention) According to the present invention, it is possible to obtain a silver halide color photographic light-sensitive material in which the growth of mold on the image surface is suppressed and the yellow dye image has excellent storage stability.

Procedural amendment spontaneous

Claims (2)

[Claims] (1) A reflective silver halide color photographic material containing at least one yellow coupler represented by the following general formula (I) and at least one antibacterial and antifungal agent. General formula (I) ▲Mathematical formulas, chemical formulas, tables, etc.▼ [In the formula, R_1 is an aryl group or a tertiary alkyl group,
R_2 is a fluorine atom, alkyl group, aryl group, alkoxy group, aryloxy group, dialkylamino group, alkylthio group, or arylthio group, R_3 is a group that can be substituted on the benzene ring, and X is a hydrogen atom or an aromatic group. l represents a group that can be separated by a coupling reaction with an oxidized product of a primary amine developer, and l represents an integer of 0 to 4, respectively. However, when l is plural, the plural R_2 may be the same or different. ] (2) The antibacterial and fungicidal agent has the following general formulas (F-I) to (F-VI
The reflective silver halide color photographic light-sensitive material according to claim (1), which is a compound represented by II). General formula (F-I) ▲ Contains mathematical formulas, chemical formulas, tables, etc. ▼ General formula (F-II) ▲ Contains mathematical formulas, chemical formulas, tables, etc. ▼ General formula (F-III) ▲ Contains mathematical formulas, chemical formulas, tables, etc. ▼ General formula (F-IV) ▲ Contains mathematical formulas, chemical formulas, tables, etc. ▼ General formula (F-V) ▲ Contains mathematical formulas, chemical formulas, tables, etc. ▼ General formula (F-VI) ▲ Contains mathematical formulas, chemical formulas, tables, etc. Yes ▼ General formula (F-VII) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ General formula (F-VIII) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (In the formula, R^2, R^3, R^ 4, R^5, R^6, R
^8 and R^9 represent a hydrogen atom, an alkyl group, or an aryl group, and R^7 represents a hydrogen atom, an alkyl group,
Represents an aryl group, nitro group, carboxy group, sulfo group, sulfamoyl group, hydroxy group, halogen atom, alkoxy group, or thiazolyl group. R^1^0 represents an alkylene group or an arylene group. R^1^1,
R^1^2 and R^1^3 represent a halogen atom or an alkyl group, and R^1^4 and R^1^5 represent a hydrogen atom, an alkyl group, an aryl group, or a nitrogen-containing heterocycle. Represents a residue. R^1^6 and R^1^7 represent a hydrogen atom, an alkyl group, a halogen atom, or an aryl group, and R^1^6 and R^1^7 may be combined to form a benzene ring. . R^1^9 represents a hydrogen atom or an alkyl group. R^1^9 represents an alkyl group or an aryl group. Y represents a halogen atom, Z^1 represents a nonmetallic atomic group necessary to form a thiazolyl ring, and Z^2 represents a nonmetallic atomic group necessary to form a six-membered ring. n represents 0 or 1, and m represents 1 or 2. )