JPH03161053A - Fat and oil oxidation and decomposition catalyst - Google Patents
Fat and oil oxidation and decomposition catalystInfo
- Publication number
- JPH03161053A JPH03161053A JP1300412A JP30041289A JPH03161053A JP H03161053 A JPH03161053 A JP H03161053A JP 1300412 A JP1300412 A JP 1300412A JP 30041289 A JP30041289 A JP 30041289A JP H03161053 A JPH03161053 A JP H03161053A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- aluminum
- porous
- coating
- porous coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 40
- 230000003647 oxidation Effects 0.000 title claims abstract description 11
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 11
- 238000000354 decomposition reaction Methods 0.000 title abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003921 oil Substances 0.000 claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010949 copper Substances 0.000 claims abstract description 4
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052802 copper Inorganic materials 0.000 claims abstract description 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract 3
- 229910017052 cobalt Inorganic materials 0.000 claims abstract 2
- 239000010941 cobalt Substances 0.000 claims abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000006864 oxidative decomposition reaction Methods 0.000 claims description 4
- 238000007743 anodising Methods 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 238000002048 anodisation reaction Methods 0.000 abstract 1
- 238000010030 laminating Methods 0.000 abstract 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 238000009423 ventilation Methods 0.000 abstract 1
- 239000003925 fat Substances 0.000 description 9
- 235000014593 oils and fats Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 240000008415 Lactuca sativa Species 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 235000012045 salad Nutrition 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910003322 NiCu Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、調理器の庫内壁面に適用可能な油脂等の有機
物の酸化分解能力を有する触媒体に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a catalyst having the ability to oxidize and decompose organic substances such as fats and oils and which can be applied to the inner wall surface of a cooking appliance.
従来の技術
従来のこの種の触媒体は、第6図に示すように金属多孔
体1の表面に触媒2と結合剤3からなる!ll底物を塗
布して焼成し、付着した油脂類4を約300℃で分解す
るというものであった(例えば特公昭60−7539号
公報、特公昭59−40062号公報)。2. Prior Art A conventional catalyst body of this type consists of a catalyst 2 and a binder 3 on the surface of a metal porous body 1, as shown in FIG. The method was to apply a 100% polyester resin and bake it, and to decompose the adhering fats and oils 4 at about 300°C (for example, Japanese Patent Publications No. 7539/1983 and Japanese Patent Publication No. 40062/1982).
発明が解決しようとする課題
しかし、上記の構或では、触媒は結合剤のために被膜中
にかくれてしまい、高い酸化能力は得られないという課
題があった。このことは、油脂類の重量減少として評価
するよりは、分解処理後の触媒体表面の外観での評価が
よりはっきりする。Problems to be Solved by the Invention However, in the above structure, there was a problem in that the catalyst was hidden in the coating due to the binder, and high oxidation ability could not be obtained. This is more clearly evaluated based on the appearance of the surface of the catalyst after decomposition treatment, rather than based on the weight loss of fats and oils.
従来、重量減少が大きいとされているものでも、外観は
油脂類の跡が明らかに残っていた。Even products that were traditionally considered to have a large weight loss still had visible traces of oil and fat on their exteriors.
本発明は、上記従来の課題を解決するもので、外観でも
油脂類の100%の分解と判断できるほどの高活性の触
媒体を提供することを目的とする.課題を解決するため
の手段
上記課題を解決するために、本発明はアルミニウム繊維
を積層し、アルξニウムのエキスバンドメタルでサンド
イッチ状にした多孔体と、その表面に陽極酸化法により
形成した酸化珪素(Sing)、酸化アルξニウム(A
tt Os )のうちから選ばれた多孔質被膜と、前記
多孔質被膜の表面にマンガン(Mn),鉄(Fe),:
]バルト(Co),ニソケル(N i ) ,銅(Cu
),セリウム(Ce)のうちから選ばれた1種以上の酸
化物からなる触媒を担持したものである。The present invention solves the above-mentioned conventional problems, and aims to provide a highly active catalyst that can be judged to have 100% decomposition of fats and oils from its appearance. Means for Solving the Problems In order to solve the above problems, the present invention provides a porous body in which aluminum fibers are laminated and sandwiched with aluminum expanded metal, and an oxidized body formed on the surface by an anodizing method. Silicon (Sing), aluminum oxide (A
a porous coating selected from the group consisting of:
] Balt (Co), Nisokel (N i ), Copper (Cu
) and cerium (Ce).
作用
上記した手段により、触媒体の通気性がよくなり、油脂
頻が酸化分解する際、酸素の供給が十分になされるとと
もに、酸化触媒が露出状態で担持されたSiO.,AI
!O.のうちから選ばれた多孔質被膜上に油脂類が付着
すると濡れ性がよくなり、そのため局部に集中すること
なく均一に接触し、酸化触媒とも直接接触するため高活
性となり、外観上100%油脂類を酸化分解することと
なる.
実施例
以下、本発明の実施例を添付図面にもとづいて説明する
.第1図は本発明の触媒体の拡大断面図であり、直径数
10μm〜数100μmのアルミニウム繊維5の表面に
厚さ5〜20μm1気孔率約20%のSin.を主成分
とした多孔質被膜6を陽極酸化法で形成したのち、Mn
,Fe,Co,NiCu,Ceのうちから選ばれた1種
以上の硝酸塩.酢酸塩などの溶液中に浸漬するか、溶液
を吹き付けた後、乾燥し、45゛Cで30分焼戊して触
媒7を露出状態に担持したものである。触媒体表面に付
着した油脂類4はSingを主戒分とした多孔質被膜6
と濡れ性がよいため局所に集中することなく均一に接触
するとともに露出状態に担持した触媒7と直接接触する
.
上記のような触媒7を担持したアルミニウム繊維8を第
2図に示すようにからみあわせて空気の通気孔9を形成
し、第3図に示すように厚さ約1閣に積層し、触媒体の
機械的強度の向上と形状維持のため上下から第4図に示
すようなアル多ニウムエキスパンドlOでサンドイッチ
状に加工すると、第5図に示すような油脂類酸化触媒体
ができる。Effect: By the means described above, the air permeability of the catalyst body is improved, and when the fat and oil is oxidized and decomposed, oxygen is sufficiently supplied, and the SiO. ,AI
! O. When oils and fats adhere to the porous coating selected from among these, the wettability improves, so that they are in uniform contact without being concentrated locally, and they also come into direct contact with the oxidation catalyst, resulting in high activity. This results in the oxidative decomposition of EXAMPLES Hereinafter, examples of the present invention will be explained based on the attached drawings. FIG. 1 is an enlarged sectional view of the catalyst body of the present invention, in which a Sin. After forming a porous film 6 mainly composed of Mn by anodizing method,
, Fe, Co, NiCu, Ce. The catalyst 7 was supported in an exposed state by immersing it in a solution such as acetate or by spraying the solution, then drying and baking at 45°C for 30 minutes. The oils and fats 4 adhering to the surface of the catalyst form a porous film 6 containing Sing as its main ingredient.
Because of its good wettability, it contacts uniformly without being concentrated locally, and also directly contacts the exposed catalyst 7. Aluminum fibers 8 supporting the catalyst 7 as described above are intertwined to form air vents 9 as shown in FIG. In order to improve the mechanical strength and maintain the shape, the oil and fat oxidation catalyst body as shown in FIG. 5 is produced by processing it into a sandwich shape with aluminum expanded lO as shown in FIG. 4 from the top and bottom.
なお本実施例の触媒体は前記の方法とは逆の順序で製造
してもよい。すなわち、最初にアルミニウムで第5図に
示す構造体を製造し、前記構造体全体に陽極酸化法でS
in.を主成分とした多孔賞被膜を形成後、触媒を担持
してもよい.上記の方法で製造した触媒体による油脂類
の酸化分解特性を従来例と比較して次の表に示した。Note that the catalyst body of this example may be manufactured in the reverse order of the above method. That is, the structure shown in FIG. 5 is first manufactured from aluminum, and the entire structure is coated with S by anodic oxidation.
in. A catalyst may be supported after forming a porous coating mainly composed of . The following table shows the oxidative decomposition characteristics of oils and fats by the catalyst produced by the above method in comparison with conventional examples.
(以下余白)
上記の表からわかるように、
バインダ(結合剤)
を用いた場合や繊維状でなく通常のアルミニウム仮を用
いた場合などに分解性能が低い。すなわち、酸素(空気
)の拡散が影響している。また担持する触媒については
Mn,Fe,Co,Ni,Cu+Ceのうち1種以上を
用いるとよい。(Left below) As can be seen from the table above, the decomposition performance is low when a binder is used or when ordinary aluminum temporary rather than fibrous material is used. In other words, it is affected by the diffusion of oxygen (air). As for the supported catalyst, it is preferable to use one or more of Mn, Fe, Co, Ni, and Cu+Ce.
油脂分解の性能評価は、10cmX10cm (厚さ約
1帥)の触媒体にサラダオイルをスボイドで定量滴下し
て行った。その結果、本発明の実施例では表にあるよう
に根跡もなく、サラダオイルの重量減少も100%であ
った。Performance evaluation of fat and oil decomposition was carried out by dropping a fixed amount of salad oil onto a 10 cm x 10 cm (approximately 1 cm thick) catalyst body using a dropper. As a result, as shown in the table, in the examples of the present invention, there were no traces and the weight reduction of salad oil was 100%.
一方、本発明では触媒を直接担持するということから触
媒の剥離が懸念されたが、実施例の触媒体でテープによ
る剥離テストを行ったところ、エキスバンドメタルのエ
ッヂの部分で剥離は認められたが、それ以外では強固な
密着を示した。これは、Singの被膜とアルミニウム
繊維とが電気化学的に強固に結合し、さらにSi02被
膜が非常に多孔質なため、担持した触媒が孔の内部で保
持されていることによると考えられる。On the other hand, in the present invention, since the catalyst is directly supported, there was a concern that the catalyst would peel off, but when a peeling test was performed using a tape on the catalyst body of the example, peeling was observed at the edge of the expanded metal. However, other than that, they showed strong adhesion. This is thought to be due to the fact that the Sing coating and the aluminum fibers are strongly electrochemically bonded, and the Si02 coating is extremely porous, so that the supported catalyst is retained within the pores.
なお、本実施例では多孔質被膜としてSingを主威分
とした例について述べたが、A1203を主威分とする
多孔質被膜を形成した触媒体においても同様の結果が得
られた。In this example, an example in which Sing was used as the main component of the porous coating was described, but similar results were obtained with a catalyst body in which a porous coating was formed with A1203 as the main component.
発明の効果
以上のように本発明の油脂類酸化分解触媒体によれば、
アルミニウム繊維の積層構造とすることにより通気性が
よくなり、油脂類が酸化分解する際酸素の供給が十分に
なされるとともに、触媒が露出状態で担持されたSin
.またはAI20,を主威分とする多孔質被膜上に油脂
類が付着すると濡れ性がよいため局所に集中することな
く均一に接触し、酸化触媒とも直接接触するため高活性
となり、外賎上100%油脂類を酸化分解することがで
きる。Effects of the Invention As described above, the catalyst for oxidative decomposition of fats and oils of the present invention has the following effects:
The laminated structure of aluminum fibers improves air permeability and provides a sufficient supply of oxygen when oils and fats are oxidized and decomposed.
.. Alternatively, when oils and fats adhere to a porous film containing AI20 as its main component, it has good wettability, so it contacts uniformly without concentrating locally, and it also comes into direct contact with the oxidation catalyst, resulting in high activity. % oils and fats can be oxidized and decomposed.
第1図は本発明の実施例のアル兆ニウム繊維とその表面
に形成されたSin.もしくはAI.03を主戒分の多
孔質被膜およびこれに担持した触媒の拡大断面図、第2
図は同じ《アル5ニウム繊維を用いた触媒体の一部拡大
図、第3図は同しくエキスバンドメタルでサンドイッチ
状にした触媒体の一部拡大断面図、第4図は同しくエキ
スバンドメタルの正面図、第5図は本発明による触媒体
の斜視図、第6図は従来の触媒体の一部拡大断面図であ
る.
5・・・・・・アルミニウム繊維、6・・・・・・Si
n2またはAltosを主戒分とした多孔質被膜、7・
・・・・・酸化触媒、lO・・・・・・アルミニウムエ
キスパンドメタル。FIG. 1 shows an aluminum trillionium fiber according to an embodiment of the present invention and a Sin. Or AI. Enlarged cross-sectional view of the porous film containing 03 as the main ingredient and the catalyst supported on it, 2nd
The figure is a partially enlarged view of the catalyst body using the same 5-aluminum fiber, Figure 3 is a partially enlarged sectional view of the catalyst body sandwiched with expanded metal, and Figure 4 is the same expanded band. FIG. 5 is a front view of the metal, FIG. 5 is a perspective view of a catalyst body according to the present invention, and FIG. 6 is a partially enlarged sectional view of a conventional catalyst body. 5... Aluminum fiber, 6... Si
Porous coating with n2 or Altos as main component, 7.
... Oxidation catalyst, lO ... Aluminum expanded metal.
Claims (1)
ドメタルでサンドイッチ状にした多孔体と、その多孔体
の表面に陽極酸化法により形成した酸化珪素または酸化
アルミニウムからなる多孔質被膜と、その多孔質被膜の
表面にマンガン、鉄、コバルト、ニッケル、銅、セリウ
ムのうちから選ばれた1種以上の酸化物からなる酸化触
媒を担持した油脂類酸化分解触媒体。A porous body made of laminated aluminum fibers sandwiched with aluminum expanded metal, a porous coating made of silicon oxide or aluminum oxide formed by anodizing on the surface of the porous body, and manganese on the surface of the porous coating. An oil and fat oxidative decomposition catalyst supporting an oxidation catalyst comprising one or more oxides selected from , iron, cobalt, nickel, copper, and cerium.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1300412A JPH03161053A (en) | 1989-11-17 | 1989-11-17 | Fat and oil oxidation and decomposition catalyst |
US07/612,770 US5094222A (en) | 1989-11-17 | 1990-11-14 | Catalytic composite and a cooker having the same |
AU66630/90A AU620267B2 (en) | 1989-11-17 | 1990-11-15 | A catalytic composite and a cooker having the same |
DE69009944T DE69009944T2 (en) | 1989-11-17 | 1990-11-16 | Catalytic composition and cooking device. |
EP90121981A EP0429994B1 (en) | 1989-11-17 | 1990-11-16 | A catalytic composite and a cooker having the same |
KR1019900018668A KR930002244B1 (en) | 1989-11-17 | 1990-11-17 | Catalyst and apparatus for cooking |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1300412A JPH03161053A (en) | 1989-11-17 | 1989-11-17 | Fat and oil oxidation and decomposition catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03161053A true JPH03161053A (en) | 1991-07-11 |
Family
ID=17884491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1300412A Pending JPH03161053A (en) | 1989-11-17 | 1989-11-17 | Fat and oil oxidation and decomposition catalyst |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03161053A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001037988A1 (en) * | 1999-11-25 | 2001-05-31 | Kawasaki Jukogyo Kabushiki Kaisha | Catalyst for exothermic or endothermic reaction, catalyst for water-gas-shift reaction and catalyst for selective oxidation of carbon monoxide, and plate-fin heat exchange type reformer |
JP2010234278A (en) * | 2009-03-31 | 2010-10-21 | Hitachi Aic Inc | Hydrogen catalyst member |
JP2014514531A (en) * | 2011-04-12 | 2014-06-19 | イー.エム.ダブリュ.エナジー カンパニー リミテッド | Cavity of cooking device, cooking device including the same, and auxiliary appliance for cooking device |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5852699A (en) * | 1981-09-24 | 1983-03-28 | 富士通株式会社 | voice input device |
JPS6420815A (en) * | 1987-07-16 | 1989-01-24 | Matsushita Electric Ind Co Ltd | Heating cooker |
-
1989
- 1989-11-17 JP JP1300412A patent/JPH03161053A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5852699A (en) * | 1981-09-24 | 1983-03-28 | 富士通株式会社 | voice input device |
JPS6420815A (en) * | 1987-07-16 | 1989-01-24 | Matsushita Electric Ind Co Ltd | Heating cooker |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001037988A1 (en) * | 1999-11-25 | 2001-05-31 | Kawasaki Jukogyo Kabushiki Kaisha | Catalyst for exothermic or endothermic reaction, catalyst for water-gas-shift reaction and catalyst for selective oxidation of carbon monoxide, and plate-fin heat exchange type reformer |
JP2010234278A (en) * | 2009-03-31 | 2010-10-21 | Hitachi Aic Inc | Hydrogen catalyst member |
JP2014514531A (en) * | 2011-04-12 | 2014-06-19 | イー.エム.ダブリュ.エナジー カンパニー リミテッド | Cavity of cooking device, cooking device including the same, and auxiliary appliance for cooking device |
EP2698583A4 (en) * | 2011-04-12 | 2016-01-06 | Emw Energy Co Ltd | Cavity for a heat-processing device, a heat-processing device comprising same, and an auxiliary implement for the heat-processing device |
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