JPH03124496A - Thermal transfer recording medium with receiving paper and manufacture thereof - Google Patents
Thermal transfer recording medium with receiving paper and manufacture thereofInfo
- Publication number
- JPH03124496A JPH03124496A JP1260176A JP26017689A JPH03124496A JP H03124496 A JPH03124496 A JP H03124496A JP 1260176 A JP1260176 A JP 1260176A JP 26017689 A JP26017689 A JP 26017689A JP H03124496 A JPH03124496 A JP H03124496A
- Authority
- JP
- Japan
- Prior art keywords
- thermal transfer
- receiving paper
- laminating agent
- transfer sheet
- hot laminating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 238000010030 laminating Methods 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 23
- 238000004781 supercooling Methods 0.000 claims abstract description 17
- 230000008018 melting Effects 0.000 claims abstract description 11
- 238000002844 melting Methods 0.000 claims abstract description 11
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000012964 benzotriazole Substances 0.000 claims abstract description 3
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 claims description 6
- 229960001413 acetanilide Drugs 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000012943 hotmelt Substances 0.000 abstract description 2
- 239000002985 plastic film Substances 0.000 abstract description 2
- 229920006255 plastic film Polymers 0.000 abstract description 2
- 238000003475 lamination Methods 0.000 description 6
- 239000000945 filler Substances 0.000 description 4
- 230000008014 freezing Effects 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 239000004203 carnauba wax Substances 0.000 description 3
- 235000013869 carnauba wax Nutrition 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 238000009816 wet lamination Methods 0.000 description 1
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
良又上辺上」土1
本発明は感熱転写シートと受け紙とのラミネートによる
セットタイプの記録媒体に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a set type recording medium formed by laminating a thermal transfer sheet and a receiving paper.
従じLの1E術
受け紙付感熱転写カーボンセットに関しては従来種々の
ラミネート方法およびセットの形状についての提案かさ
れている。従来のうミネート方法については感熱転写シ
ートへのラミネート剤の塗工によりセットする方法で、
ドライラミネートによる方法、ウェットラミネートによ
る方法かある。Various laminating methods and various shapes of the set have been proposed regarding the heat-sensitive transfer carbon set with 1E paper of standard L. The conventional lamination method involves applying a laminating agent to a heat-sensitive transfer sheet.
There are two methods: dry lamination and wet lamination.
か じよ−と ろ 古
これら従来の方法ては印字の鮮明性の点から、ラミネー
ト剤の塗布にとして1g7m2以下か9ましく、逆にこ
の塗布量てはサーマルヘッドによる感熱転写シートのつ
き現象(受け紙から感熱転写シートかはかれる現象)を
解決することは困難てあった。From the viewpoint of print clarity, these conventional methods recommend applying a laminating agent of 1g7m2 or less, but conversely, this amount of application is limited by the sticking phenomenon of the thermal transfer sheet caused by the thermal head. It was difficult to solve the problem (the phenomenon of the thermal transfer sheet being peeled off from the receiving paper).
更に、転写後に転写シートを剥離した受け紙の表面のベ
タつきも問題であった。Furthermore, there was also a problem of stickiness on the surface of the receiving paper from which the transfer sheet was peeled off after the transfer.
占 るための
本発明者はこのような問題点について種々検討の結果、
次のような構成の受け紙付感熱転写記録媒体とすること
により、それを解決てきることを見出した。即ち、本発
明は感熱転写インキ層を有する感熱転写シートと、過冷
却性材料を含有するホットラミネート剤層を右する受け
紙とからなり、該感熱転写インキ層と該ホットラミネー
ト剤層とか対向接合してなることを41F徴とする受け
紙付感熱転写記録媒体を提供するものである。As a result of various studies on these problems, the inventor of the present invention has found that
It has been found that this problem can be solved by providing a thermal transfer recording medium with receiving paper having the following structure. That is, the present invention consists of a heat-sensitive transfer sheet having a heat-sensitive transfer ink layer and a receiving paper holding a hot laminating agent layer containing a supercooling material, and the heat-sensitive transfer ink layer and the hot laminating agent layer are bonded facing each other. The present invention provides a thermal transfer recording medium with receiving paper having a 41F characteristic.
更に、本発明は受け紙ヒに設けられた過冷却性材料を含
有するホットラミネート剤層に、ホットラミネート剤が
流動性を有している状態下において、感熱転写シートの
感熱転写インキ層を密着させることを特徴とする受け紙
付感熱転写記録媒体の製法を提供するものである。この
流動性を有する状yミ5はホットラミネート剤が過冷却
状態である場合も含むものである。Furthermore, the present invention is capable of adhering a thermal transfer ink layer of a thermal transfer sheet to a hot laminating agent layer containing a supercooling material provided on a receiving paper in a state where the hot laminating agent has fluidity. The present invention provides a method for producing a thermal transfer recording medium with receiving paper, which is characterized in that: This state of fluidity 5 also includes the case where the hot laminating agent is in a supercooled state.
過冷却状態とは過冷却性材料又はそれを含イiする組成
物、例えば、ここで用いるホットラミネート剤の融点以
下で凝固点以上の温度における流動性のある状態をいう
。The supercooled state refers to a fluid state at a temperature below the melting point and above the freezing point of the supercoolable material or a composition containing the same, for example, the hot laminating agent used here.
未発明に用いる感熱転写シートは従来から知られている
ものを用いることが出来る。例えば、ホットメルト系イ
ンキまたは溶剤系(ソルベント、エマルジョン)インキ
てもよく、これを基材、例えば、プラスチック・フィル
ム上に塗着して成るものでよい。フィルムの厚さは、例
えば、感度の点からは4〜6μか好ましいが、これに限
定されるものではない。Conventionally known heat-sensitive transfer sheets can be used for the present invention. For example, it may be a hot-melt ink or a solvent-based (solvent, emulsion) ink, which may be applied onto a substrate such as a plastic film. The thickness of the film is, for example, preferably 4 to 6 μm from the viewpoint of sensitivity, but is not limited thereto.
受け紙としては、一般に感熱転写用として使用されてい
るものを用いることがてきる。As the receiving paper, those generally used for thermal transfer can be used.
印字鮮明性、ラミネート性の点からはベック平滑度(J
IS P8119−1976) 100 sec/cc
以りのものか好ましい。Bekk smoothness (J
IS P8119-1976) 100 sec/cc
The following are preferred.
受け紙と感熱転写シートとをホットラミネートにより接
合せしめるホットラミネート剤としては過冷却性材料を
用いる。A supercooling material is used as a hot laminating agent for bonding the receiving paper and the heat-sensitive transfer sheet by hot lamination.
過冷却性材料とは、その融点と凝固点との間に巾広い温
度領域かあり、この過冷却温度領域内ては、融点以上の
温度で溶融した後は、その凝固点まで温度か下からない
限り固化せず、流動性を保ち、また凝固点以下の温度で
固化した後は、再びその融点に達しない限り、溶融しな
い材料である。過冷却性材料の例としては、ジシクロへ
キシルフタレート、ベンゾトリアゾール、アセトアニリ
ドポリエチレンクリコール等がある。Supercooled materials have a wide temperature range between their melting point and freezing point, and within this supercooled temperature range, after melting at a temperature above the melting point, the material will not melt unless the temperature drops to the freezing point. It is a material that does not solidify, maintains fluidity, and, after solidifying at a temperature below its freezing point, does not melt unless it reaches its melting point again. Examples of supercooling materials include dicyclohexyl phthalate, benzotriazole, acetanilide polyethylene glycol, and the like.
過冷却性材料としては融点か50°C以」二のものか好
ましく、特に好ましくは700°C以1−である。融点
か50℃より低い場合には、使用条件にもよるが印字後
の受け紙のベトつきか大きく、実用的てない。The supercooling material preferably has a melting point of 50°C or higher, particularly preferably 700°C or higher. If the melting point is lower than 50° C., depending on the conditions of use, the receiving paper may become sticky after printing, making it impractical.
過冷却性材料は70°Cにおける溶融粘度か300セン
チボイズ以上のものか好ましい。The supercooling material preferably has a melt viscosity of 300 centivoise or more at 70°C.
300センチボイス未満のものはホットラミネートした
詩に紙へ浸透し易く、旨くラミネートできない。If the voice is less than 300 cm, it will easily penetrate into the hot laminated paper and cannot be laminated well.
必要に応じ、過冷却性材料に充填剤を混して用いること
がてきる。充填剤は印字の13明性を高め、受け紙のベ
トッキを減し、月つ筆記性を改良するために用いる。充
填剤としてはクレー、軽質炭酸カルシウム、沈降性バリ
ウム、シリカなどを用いることかできる。過冷却性材料
と充填剤の重量比率は70〜95:5〜30か好ましい
。If necessary, a filler may be mixed with the supercooling material. The filler is used to increase the clarity of the print, reduce stickiness on the receiving paper, and improve the writing quality. As the filler, clay, light calcium carbonate, precipitated barium, silica, etc. can be used. The weight ratio of supercooling material and filler is preferably 70-95:5-30.
更に必要に応じ、溶融粘度調整剤としてはワックス例え
ば、マイクロクリスタリンワックス及びパラフィンワッ
クス、ミソスチン酸セレシン等を、粘着性付4剤として
はロジン、軟化剤、例えば、ポリブテン、流動パラフィ
ンなどを用いてもよい。Furthermore, if necessary, wax such as microcrystalline wax, paraffin wax, ceresin misostate, etc. may be used as the melt viscosity modifier, and rosin, softener, such as polybutene, liquid paraffin, etc. may be used as the tackifier. good.
ホットラミネート剤の使用iBとしては感熱転写シート
のつき現象防止、印字の鮮明性の点から見て、 1.0
〜7.119/II’か好ましく、3.0〜4.09/
rm2か特に好ましい。The use of hot laminating agent iB is 1.0 from the viewpoint of prevention of sticking phenomenon of heat-sensitive transfer sheet and clarity of printing.
~7.119/II' or preferably 3.0-4.09/
rm2 is particularly preferred.
なお、従来技術におけるホットラミネート剤はその使用
量を多くすると受け紙のベトフきか生ずるので、その塗
布量は1.Off/112未満か望ましかったが、この
ような少量では、“うき”現象を解決てきなかった。ホ
ットラミネートを行う温度としては感熱転写インキの融
点以ドて行うのか栄ましく、且つ、ホットラミネート剤
の溶融粘度か少なくとも300センチボイズ以上になる
温度て行うことか望ましい。これより高い温度でホット
ラミネー1−を行うと、ホットラミネート剤の受け紙へ
の浸透が大きくなり、十分なラミネート強度か得られな
い。In addition, if the amount of hot laminating agent used in the prior art is increased, the receiving paper will become sticky, so the amount of hot laminating agent applied should be 1. It was desirable that the amount was less than Off/112, but such a small amount did not solve the "floating" phenomenon. The temperature at which hot lamination is carried out is preferably at a temperature below the melting point of the thermal transfer ink, and preferably at a temperature at which the melt viscosity of the hot laminating agent is at least 300 centivoise or higher. If hot lamination 1- is performed at a temperature higher than this, the hot laminating agent will penetrate into the receiving paper to a large extent, and sufficient lamination strength will not be obtained.
火五A」
(イ)感熱転写シートを次のようにして作成する。シリ
コン樹脂を用いて耐熱処理を施したポリエステルフィル
ム(6μ厚)にカルナバワックスを1μ厚に塗布して剥
離層とする。``Fire 5 A'' (a) Create a thermal transfer sheet as follows. Carnauba wax is applied to a thickness of 1 μm on a polyester film (6 μm thick) that has been heat-resistant treated with silicone resin to form a release layer.
次に下記の配合のインキを2.5μ厚(固形分)に塗布
して感熱転写インキ層をつくり、感熱転写シートとした
。Next, an ink having the following composition was applied to a thickness of 2.5 μm (solid content) to form a heat-sensitive transfer ink layer, and a heat-sensitive transfer sheet was prepared.
カーボンブラック 6重ψ部ポリアミド樹脂
6重量部カルナバワックスパウダー
8屯4)部IPA 80重量部(
ロ)次に受け紙として純白ロール(紀州製紙はまゆう)
を用い、下記のホットラミネート剤て70°Cの温度で
、 3.5り7m2の塗布量て塗布し、この上へL記イ
ンキ層を密着させ、ホットラミネートにより接合した。Carbon black 6 parts polyamide resin 6 parts by weight Carnauba wax powder
8 tons 4) parts IPA 80 parts by weight (
b) Next, a pure white roll (Kishu Paper Hamayuu) as receiving paper.
Using the following hot laminating agent, the following hot laminating agent was applied at a temperature of 70° C. in a coating amount of 3.5 x 7 m 2 , and the ink layer L was adhered thereon and bonded by hot lamination.
ホラ1−ラミネートのスピードはlO■/分以−ヒか密
着性の点から望ましく、 40m/分て行なった。ま
た紙も予熱するのかよく、400Cに予熱してホットラ
ミネートした。The laminating speed was preferably 10 m/min or less from the viewpoint of adhesion, and the laminating speed was 40 m/min. I also preheated the paper to 400C and hot laminated it.
ホットラミネート剤:
マイクロクリスタリン
ワックス 20重液部
ジシクロへキシルフタ
レート 75改!j部軽質炭醜カル
シウム 51聞部
このようにしてつくられた受け紙付感熱転写シートをサ
ーマルプリンターで印字した所、サーマルヘッドによろ
うき現象はなく、感熱転写シートと受け紙との剥離性も
スムースであり、受け紙のベトっきもなかった。また、
受け紙への水性ペンののりも良好であった。Hot laminating agent: Microcrystalline wax 20 heavy liquid parts dicyclohexyl phthalate 75 reform! Part J: Light carbon-based calcium Part 51: When the heat-sensitive transfer sheet with receiving paper made in this way was printed with a thermal printer, there was no waxing phenomenon caused by the thermal head, and there was no peeling property between the heat-sensitive transfer sheet and the receiving paper. It was smooth and the receiving paper was not sticky. Also,
The water-based pen adhered well to the receiving paper.
実j自1又
(イ)感熱転写シートは次のようにして作成される。耐
熱処理をほどこしたポリエステルフィルム(5μ厚)に
下記配合のインキを2.5〜3.5μ厚く固形分)に塗
布して感熱転写シートとした。(a) The thermal transfer sheet is prepared as follows. A heat-sensitive transfer sheet was prepared by coating a heat-resistant polyester film (5μ thick) with the following ink to a thickness of 2.5 to 3.5μ (solid content).
カーボンブラック 15重液部カルナバワック
ス 55重量部パラフィンワックス 1
5重縫部EVA I O重量部ボ
リフテン 5重ψ部(【1)次に受け
紙としてTRW7 (十条製紙熱転写用紙)を用い、次
のホットラミネート剤を70°Cの温度で、 3.59
/m2の塗布量で塗布し、前記インキ層とホットラミネ
ートした。Carbon black 15 parts by weight Carnauba wax 55 parts by weight Paraffin wax 1
5-ply seam EVA IO weight part Boriften 5-ply ψ part ([1] Next, using TRW7 (Jujo Paper Thermal Transfer Paper) as the receiving paper, apply the following hot laminating agent at a temperature of 70°C, 3.59
/m2 and hot laminated with the ink layer.
ミリスチン酸 20重量部アセトアニリド
70重量一部クレー
l卸h)部このようにしてつくられた受け紙付感熱転写
シートをサーマルプリンターで印字した所、サーマルヘ
ッドによるつき現象はなく、感熱転写シートと受け紙と
の剥離性もスムースであり、受け紙のベトつきもなかっ
た。また受け紙への印鑑ののりも良好であった。Myristic acid 20 parts by weight Acetanilide 70 parts by weight Clay
When the thermal transfer sheet with receiving paper produced in this way was printed using a thermal printer, there was no sticking phenomenon due to the thermal head, and the peelability between the thermal transfer sheet and the receiving paper was smooth, and the receiving paper was printed on. There was no sticky feeling from the paper either. The seal also adhered well to the receiving paper.
仇−沫
(イ)サーマルヘッドによる感熱転写シートのうき現象
かなくなった。(a) The phenomenon of scratching of the heat-sensitive transfer sheet caused by the thermal head has disappeared.
(ロ)感熱転写シートと受け紙との剥離性か非常にスム
ースになりだ。(b) The peelability between the thermal transfer sheet and the receiving paper is very smooth.
(ハ)印字の鮮明性か良好である。(c) The clarity of printing is good.
(ニ)ホットラミネート剤に起因する受け紙のベトつき
かなくなった。(d) The stickyness of the receiving paper caused by the hot laminating agent has disappeared.
(ネ)受け紙への筆記性(水性ペン、印鑑)か良好とな
った。(n) Writing on paper (water-based pen, seal) was good.
Claims (1)
却性材料を含有するホットラミネート剤層を有する受け
紙とからなり、該感熱転写インキ層と該ホットラミネー
ト剤層とが対向接合してなることを特徴とする受け紙付
感熱転写記録媒体。 2、過冷却性材料が、融点50℃以上である請求項1記
載の媒体。 3、過冷却性材料が融点70℃以上である請求項1記載
の媒体。 4、過冷却性材料がジシクロヘキシルフタレート、ベン
ゾトリアゾール、アセトアニリド、ポリエチレングリコ
ールからなる群から選ばれた一種である請求項1記載の
媒体。 5、受け紙上に設けられた過冷却性材料を含有するホッ
トラミネート剤層に、ホットラミネート剤が流動性を有
している状態下において、感熱転写シートの感熱転写イ
ンキ層を密着させることを特徴とする受け紙付感熱転写
記録媒体の製法。 6、受け紙上に設けられた過冷却性材料を含有するホッ
トラミネート剤層に、ホットラミネート剤の過冷却状態
下において、感熱転写シートの感熱転写インキ層を密着
させる請求項5記載の受け紙付感熱転写記録媒体の製法[Claims] 1. Consisting of a heat-sensitive transfer sheet having a heat-sensitive transfer ink layer and a receiving paper having a hot laminating agent layer containing a supercooling material, the heat-sensitive transfer ink layer and the hot laminating agent layer 1. A thermal transfer recording medium with receiving paper, characterized in that these are bonded facing each other. 2. The medium according to claim 1, wherein the supercooling material has a melting point of 50°C or higher. 3. The medium according to claim 1, wherein the supercooling material has a melting point of 70°C or higher. 4. The medium according to claim 1, wherein the supercooling material is one selected from the group consisting of dicyclohexyl phthalate, benzotriazole, acetanilide, and polyethylene glycol. 5. The thermal transfer ink layer of the thermal transfer sheet is brought into close contact with the hot laminating agent layer containing a supercooling material provided on the receiving paper while the hot laminating agent has fluidity. A method for producing a thermal transfer recording medium with receiving paper. 6. The receiving paper according to claim 5, wherein the thermal transfer ink layer of the thermal transfer sheet is brought into close contact with the hot laminating agent layer containing a supercooling material provided on the receiving paper while the hot laminating agent is in a supercooled state. Manufacturing method for thermal transfer recording media
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1260176A JPH0825343B2 (en) | 1989-10-06 | 1989-10-06 | Thermal transfer recording medium with receiving paper and manufacturing method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1260176A JPH0825343B2 (en) | 1989-10-06 | 1989-10-06 | Thermal transfer recording medium with receiving paper and manufacturing method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH03124496A true JPH03124496A (en) | 1991-05-28 |
JPH0825343B2 JPH0825343B2 (en) | 1996-03-13 |
Family
ID=17344380
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1260176A Expired - Fee Related JPH0825343B2 (en) | 1989-10-06 | 1989-10-06 | Thermal transfer recording medium with receiving paper and manufacturing method thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0825343B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04182194A (en) * | 1990-11-16 | 1992-06-29 | General Kk | Thermal transfer recording medium having receiving paper and preparation thereof |
-
1989
- 1989-10-06 JP JP1260176A patent/JPH0825343B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04182194A (en) * | 1990-11-16 | 1992-06-29 | General Kk | Thermal transfer recording medium having receiving paper and preparation thereof |
Also Published As
Publication number | Publication date |
---|---|
JPH0825343B2 (en) | 1996-03-13 |
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