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JPH0273009A - Composition, applied onto keratinous substance and skin and having deodorizing effect - Google Patents

Composition, applied onto keratinous substance and skin and having deodorizing effect

Info

Publication number
JPH0273009A
JPH0273009A JP22679688A JP22679688A JPH0273009A JP H0273009 A JPH0273009 A JP H0273009A JP 22679688 A JP22679688 A JP 22679688A JP 22679688 A JP22679688 A JP 22679688A JP H0273009 A JPH0273009 A JP H0273009A
Authority
JP
Japan
Prior art keywords
composition
deodorizing effect
silica gel
zinc oxide
dispersant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22679688A
Other languages
Japanese (ja)
Inventor
Takahisa Higuchi
樋口 尚央
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP22679688A priority Critical patent/JPH0273009A/en
Publication of JPH0273009A publication Critical patent/JPH0273009A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27Zinc; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00Anti-perspirants or body deodorants

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

PURPOSE:To obtain the subject composition, containing fine white powder consisting of zinc oxide and silica gel and having high safety with excellent deodorizing effects. CONSTITUTION:A composition, containing 0.1-60wt.% fine white powder consisting of zinc oxide and silica gel [at a molar ratio within the range of (1:9)-(9:1)] and 0.1-30wt.% dispersant having <=150 pigment dispersibility index for improving the dispersibility of the fine white powder and applied onto keratinous substances and skin. A dermal drug for external use capable of safely deodorizing bad smelling ingredients, such as ammonia or sulfur-based smell, generating from human bodies or hair and body hair treating agents.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は人体より発生、又は毛髪、体毛処理剤により発
生するアンモニア、硫黄系臭などの悪臭成分を安全に脱
臭する方法として、酸化亜鉛(ZnO)とシリカゲル(
S i O。
Detailed Description of the Invention (Field of Industrial Application) The present invention is a method for safely deodorizing malodor components such as ammonia and sulfur odor generated from the human body or from hair and body hair treatment agents. ZnO) and silica gel (
S i O.

nH,o)からなる白色微粉末及び顔料分散性指数(流
動点−湿潤点)が150以下の成分を含有することを特
徴とする安全性の高いケラチン質物質上に適用する組成
物及び酸化亜鉛(Z n O)とシリカゲル(SiO,
nH,0)からなる白色微粉末及び上記の顔料分散剤製
配合した皮膚外用剤を提供するものである。
Zinc oxide and a highly safe composition to be applied on keratinous materials, characterized by containing a white fine powder consisting of nH, o) and a component having a pigment dispersibility index (pour point - wet point) of 150 or less (Z n O) and silica gel (SiO,
The present invention provides an external skin preparation containing a white fine powder consisting of nH, 0) and the above-mentioned pigment dispersant.

ここで言う顔料分散性指数とは以下の方法により得られ
る特性値である。
The pigment dispersibility index referred to here is a characteristic value obtained by the following method.

〔顔料分散性指数測定法〕[Pigment dispersibility index measurement method]

二酸化チタン100gをビーカーにとり、これに試料2
0gを加え、充分に混合する。その後流動パラフィン#
7oを滴下し、二酸化チタンが均一にぬれたときの流動
パラフィンの量(g)を湿潤点とする0次に流動パラフ
ィンをさらに加え混合し、ビーカーを傾ける時、流動す
る迄に加えた流動パラフィンの量(g)を流動点とする
Take 100g of titanium dioxide in a beaker and add sample 2 to it.
Add 0g and mix thoroughly. Then liquid paraffin #
The amount of liquid paraffin (g) when the titanium dioxide is uniformly wetted is the wetting point. When the beaker is tilted, liquid paraffin is added until it becomes fluid. The amount (g) is taken as the pour point.

顔料分散性指数=流動点(g)−湿潤点(g)(従来技
術及びその欠点) 従来より毛髪及び体毛処理組成物及び皮膚外用剤の脱臭
方法の一つとして、悪臭成分をマスキングするような香
料を添加し香料具により悪臭を目立たなくする方法が行
われてきた。
Pigment dispersibility index = Pour point (g) - Wet point (g) (Prior art and its drawbacks) Conventionally, as a method of deodorizing hair and body hair treatment compositions and external skin preparations, methods for masking malodorous components have been used. Methods have been used to make bad odors less noticeable by adding fragrances and using perfume tools.

しかし、近年、生活環境の変化により微香性の商品が好
まれるようになり、香料を多量に使用するマスキング方
法は好まれなくなってきている。又、香料の多くが皮膚
刺激性を示す事実も香料によるマスキングを困難にして
いる。
However, in recent years, due to changes in the living environment, slightly scented products have come to be preferred, and masking methods that use large amounts of perfume are no longer preferred. Additionally, the fact that many fragrances are irritating to the skin also makes masking with fragrances difficult.

又、悪臭は、汗腺より分泌する汗が細菌により分解され
発生する。従って、これらの細菌の繁殖を防止するため
にヘキサミン、過酸化亜鉛などの殺菌剤の添加も行われ
ている。
In addition, bad odors are generated when sweat secreted from sweat glands is decomposed by bacteria. Therefore, in order to prevent the proliferation of these bacteria, disinfectants such as hexamine and zinc peroxide are also added.

さらに汗の発生を抑制するため、アルミニウムクロロハ
イドレート、エチルアルコールの様な収れん剤の添加が
行われている。しかし、これら薬剤の安全性にも問題が
あり、これらの方法に代わる安全性が高く優れた脱臭効
果を持つ組成物、化粧料の開発が待たれていた。
Furthermore, astringents such as aluminum chlorohydrate and ethyl alcohol are added to suppress sweat generation. However, there are also problems with the safety of these drugs, and the development of compositions and cosmetics that are highly safe and have excellent deodorizing effects in place of these methods has been awaited.

又、ケラチン質物質の毛髪又は体毛処理剤であるコール
ドウェーブローション、ヘアストレイトナー、脱色剤、
及び脱毛剤に用いられる原料の多くはアンモニア臭など
の悪臭を持ち、処理中及び処理後にも不快臭を発生する
ことが多い、これについても同様の香料によるマスキン
グが行われているが、これに代わる安全性の高い解決法
の開発が待たれていた。
In addition, cold wave lotions, hair straighteners, bleaching agents, which are keratinous hair or body hair treatment agents,
Many of the raw materials used in depilatory products and depilatory products have bad odors such as ammonia odor, and often generate unpleasant odors during and after treatment. The development of an alternative, highly secure solution has been awaited.

(解決手段) 本願の発明者は、上記の欠点を解決すべく、種々の脱臭
剤を検討した結果、酸化亜鉛(Z n O)とシリカゲ
ル(S i O,・n H,O)からなる白色微粉末を
ケラチン質物買上に適用する組成物及び皮膚外用剤に0
.1〜60重量%及び白色微粉末の分散性を良くするた
めに顔料分散性指数が150以下の分散剤0.1〜30
重量%を配合することにより優れた脱臭効果が得られる
ことを発見し1本発明を完成した。
(Solution Means) In order to solve the above-mentioned drawbacks, the inventor of the present application investigated various deodorizing agents, and as a result, developed a white deodorizing agent made of zinc oxide (Z n O) and silica gel (S i O,·n H, O). 0 for compositions and skin external preparations in which fine powder is applied to keratin products.
.. 1 to 60% by weight and a dispersant with a pigment dispersibility index of 150 or less to improve the dispersibility of white fine powder 0.1 to 30
It was discovered that an excellent deodorizing effect could be obtained by blending in a proportion by weight, and the present invention was completed.

(発明の構成) 本発明は、酸化亜鉛とシリカゲル(モル比で1対9から
9対1の範囲)からなる白色微粉末を0.1〜60重量
%及び白色微粉末の分散性を良くするために顔料分散性
指数が150以下の分散剤0.1〜30重量%を含有す
るケラチン質物質上及び皮膚上に適用する組成物から成
るが、本明細書でいう組成物とはケラチン質物買上及び
皮膚上に使用される外用剤で、薬事法に言う化粧品、医
薬部外品及び医薬品にかかわらず、脱臭を目的とするす
べての組成物を含む。
(Structure of the Invention) The present invention uses 0.1 to 60% by weight of white fine powder consisting of zinc oxide and silica gel (molar ratio in the range of 1:9 to 9:1) and improves the dispersibility of the white fine powder. This composition consists of a composition applied to keratinous materials and skin containing 0.1 to 30% by weight of a dispersant with a pigment dispersibility index of 150 or less. and external preparations used on the skin, including all compositions for the purpose of deodorization, regardless of whether they are cosmetics, quasi-drugs, or pharmaceuticals as defined in the Pharmaceutical Affairs Law.

又、リップスティックやファンデーションの様に脱臭を
目的としない化粧料に対し、本願発明にある組成物を配
合すれば、当該化粧料に脱臭効果を持たせることも可能
である。
Furthermore, by blending the composition of the present invention into cosmetics such as lipsticks and foundations that are not intended for deodorization, it is possible to impart a deodorizing effect to the cosmetics.

以下にこの発明の実施例を示すことによってこの発明の
効果をより一層明確なものとするしかし、本発明はこの
実施例によって限定されるものではない。
The effects of this invention will be made clearer by showing examples of the invention below, but the invention is not limited to these examples.

又、この発明で使える酸化亜鉛とシリカゲルからなる白
色微粉末の具体例としては、チタン工業株式会社製の5
Z−100というものがある。
Further, as a specific example of the white fine powder made of zinc oxide and silica gel that can be used in this invention, 5 manufactured by Titan Kogyo Co., Ltd.
There is something called Z-100.

実施例1 酸化亜鉛とシリカゲルからなる白色微粉末及び顔料分散
性指数が150以下の分散剤を用いて表−1の制汗剤処
方で棒状製品をS造し、20人のパネラ−にて、使用時
の脱臭効果について評価した。比較として、白色微粉末
又は顔料分散性指数が150以下の分散剤及びその両方
を配合しないで同様の棒状製品を製造し評価した。結果
は、表−2の通りである。
Example 1 A bar-shaped product was manufactured using the antiperspirant formulation shown in Table 1 using white fine powder consisting of zinc oxide and silica gel and a dispersant with a pigment dispersibility index of 150 or less, and 20 panelists conducted the following tests. The deodorizing effect during use was evaluated. For comparison, similar rod-shaped products were produced and evaluated without blending white fine powder, a dispersant with a pigment dispersibility index of 150 or less, or both. The results are shown in Table-2.

表−2の結果から明らかなように酸化亜鉛とシリカゲル
からなる白色微粉末及び分散剤を配合した実施例1は、
比較例1及び2に比べ使用時の脱臭効果が大きくなって
いる。
As is clear from the results in Table 2, Example 1, in which white fine powder made of zinc oxide and silica gel and a dispersant were blended,
Compared to Comparative Examples 1 and 2, the deodorizing effect during use is greater.

実施例2 酸化亜鉛とシリカゲルからなる白色微粉末及び顔料分散
性指数が150以下の分散剤を用いて表−3の制汗剤処
方でポンプ用剤を製造し、20人のパネラ−にて、使用
時の脱臭効果について評価した。比較として、白色微粉
末又は顔料分散性指数が150以下の分散剤及びその両
方を配合しないで同様のポンプ用剤を製造して評価した
。結果は1表−4の通りである。
Example 2 A pump agent was manufactured according to the antiperspirant formulation shown in Table 3 using a fine white powder consisting of zinc oxide and silica gel and a dispersant with a pigment dispersibility index of 150 or less, and 20 panelists tested it. The deodorizing effect during use was evaluated. For comparison, similar pump agents were prepared and evaluated without incorporating white fine powder, a dispersant having a pigment dispersibility index of 150 or less, or both. The results are shown in Table 1-4.

は顔料分散性指数が150以下の分散剤及びその両方を
配合しないで同様のクリームを製造して評価した。結果
は、表−6の通りである。
produced and evaluated a similar cream without incorporating a dispersant with a pigment dispersibility index of 150 or less, and without both. The results are shown in Table-6.

表−4の結果から明らかなように酸化亜鉛とシリカゲル
からなる白色微粉末及び分゛散剤を配合した実施例2は
、比較例3及び4に比べ使用時の脱臭効果が大きくなっ
ている。
As is clear from the results in Table 4, Example 2, in which white fine powder consisting of zinc oxide and silica gel and a dispersant were blended, had a greater deodorizing effect during use than Comparative Examples 3 and 4.

実施例3 酸化亜鉛とシリカゲルからなる白色微粉末及び顔料分散
性指数が150以下の分散剤を用いて表−5の脱毛剤処
方でクリームを製造し。
Example 3 A cream was produced according to the depilatory formulation shown in Table 5 using a fine white powder consisting of zinc oxide and silica gel and a dispersant having a pigment dispersibility index of 150 or less.

20人のパネラ−にて、使用時の脱臭効果について評価
した。比較として、白色微粉末又表−6の結果から明ら
かなように酸化亜鉛とシリカゲルからなる白色微粉末及
び分散剤を配合した実施例3は、比較例5及び6に比べ
使用時の脱臭効果が大ききくなっている。
A panel of 20 people evaluated the deodorizing effect during use. As a comparison, as is clear from the results of white fine powder and Table 6, Example 3, in which a white fine powder consisting of zinc oxide and silica gel and a dispersant were blended, had a better deodorizing effect during use than Comparative Examples 5 and 6. It's getting bigger.

きくなっている。It's getting louder.

実施例4 酸化亜鉛とシリカゲルからなる白色微粉末及び顔料分散
性指数が150以下の分散剤を用いて表−7のデオドラ
ント剤処方で無水クリムを製造し、20人のパネラ−に
て、使用1時間後の脱臭効果について評価した。比較と
して、酸化亜鉛を配合したもの、又は白色微粉末又は顔
料分散性指数が150以下の分散剤を配合しないで同様
の無水クリームを製造して評価した。結果は、表−8の
通りである。
Example 4 Anhydrous cream was produced according to the deodorant formulation shown in Table 7 using white fine powder consisting of zinc oxide and silica gel and a dispersant with a pigment dispersibility index of 150 or less. The deodorizing effect after a period of time was evaluated. For comparison, similar anhydrous creams were prepared and evaluated without incorporating zinc oxide, white fine powder, or a dispersant having a pigment dispersibility index of 150 or less. The results are shown in Table-8.

表−8の結果から明らかなように酸化亜鉛とシリカゲル
からなる白色微粉末及び分散剤を配合した実施例4は、
比較例7及び8に比べ使用1時間後の脱臭効果が大きく
なっている。
As is clear from the results in Table 8, Example 4, in which white fine powder consisting of zinc oxide and silica gel and a dispersant were blended,
Compared to Comparative Examples 7 and 8, the deodorizing effect after 1 hour of use is greater.

実施例5 酸化亜鉛とシリカゲルからなる白色微粉末及び顔料分散
性指数が150以下の分散剤を用いて表−9のコールド
ウェーブI液剤の処方でローションを製造し、20人の
パネラ−にて、使用処理中の脱臭効果について評価した
Example 5 A lotion was manufactured according to the Cold Wave I liquid formulation shown in Table 9 using white fine powder consisting of zinc oxide and silica gel and a dispersant with a pigment dispersibility index of 150 or less. The deodorizing effect during use was evaluated.

比較として、白色微粉末又は顔料分散性指数が150以
下の分散剤及びその両方を配合しないで同様のローショ
ンを製造して評価した。
For comparison, a similar lotion was prepared and evaluated without incorporating white fine powder, a dispersant having a pigment dispersibility index of 150 or less, or both.

結果は、表−10の通りである。The results are shown in Table-10.

ト剤の処方で乳液状物を製造し、20人のパネラ−にて
、コールドウェーブローション■液の前後で使用し評価
した。比較として、自白色微粉末又は顔料分散性指数が
150以下の分散剤及び両方を配合しないで同様の乳液
状物を製造して評価した。結果は、表−12の通りであ
る。
A milky lotion was prepared using the formulation of the liquid and evaluated by 20 panelists who used it before and after cold wave lotion (1). For comparison, a similar emulsion was prepared and evaluated without incorporating a white fine powder or a dispersant with a pigment dispersibility index of 150 or less, and neither of them. The results are shown in Table-12.

表−10の結果から明らかなように酸化亜鉛とシリカゲ
ルからなる白色微粉末及び分散剤を配合した実施例5は
、比較例9及び10に比べ使用処理中の脱臭効果が大き
くなっている。
As is clear from the results in Table 10, Example 5, in which the fine white powder of zinc oxide and silica gel and a dispersant were blended, had a greater deodorizing effect during use than Comparative Examples 9 and 10.

実施例6 酸化亜鉛とシリカゲルからなる白色微粉末及び顔料分散
性指数が150以下の分散剤を用いて表−11のパーマ
処理後のトリートメン表−12の結果から明らかなよう
に酸化亜鉛とシリカゲルからなる白色微粉末及び分散剤
を配合した実施例6は、比較例11及び12に比ベコー
ルドウェーブローション■液の前手続補正IF(自発) 後のどちらの使用においても脱臭効果が太きくなってい
る。
Example 6 Treatment after permanent treatment shown in Table 11 using white fine powder consisting of zinc oxide and silica gel and a dispersant having a pigment dispersibility index of 150 or less.As is clear from the results in Table 12, zinc oxide and silica gel were used. Example 6, in which white fine powder and dispersant were blended, was compared to Comparative Examples 11 and 12.The deodorizing effect was stronger in both cases of use after the Cold Wave Lotion ■ Pre-procedure correction IF (spontaneous) of the liquid. ing.

以上 昭和63年12月乙、−白that's all December 1988 - White

Claims (4)

【特許請求の範囲】[Claims] (1)酸化亜鉛とシリカゲル(モル比で1対9から9対
1の範囲)からなる白色微粉末を0.1〜60重量%含
有する事を特徴とする、ケラチン質物質、特に毛髪もし
くは体毛処理、及び処理後に適用する脱臭効果を有する
組成物。
(1) Keratinous substances, especially hair or body hair, characterized by containing 0.1 to 60% by weight of white fine powder consisting of zinc oxide and silica gel (molar ratio in the range of 1:9 to 9:1) A composition having a deodorizing effect that is applied during treatment and after treatment.
(2)上記第1項に規定のごとき組成物を含有すること
により脱臭効果を有する、特に発汗に関する処理のため
の組成物。
(2) A composition, particularly for treating perspiration, which has a deodorizing effect by containing a composition as defined in item 1 above.
(3)上記第1項に規定のごとき組成物を含有すること
により脱臭効果を有することを特徴とする皮膚外用剤。
(3) A skin preparation for external use, characterized in that it has a deodorizing effect by containing a composition as defined in item 1 above.
(4)液体、クリーム、乳濁液、ゲル、粉末、濃ちょう
化ローション、スティックの形に成型されるか、もしく
は泡、又は粉体の形にエアロゾルによって調整されて、
脱臭効果を有することを特徴とする、上記第1ないし第
2ないし第3項のいづれかの組成物。
(4) formed into the form of a liquid, cream, emulsion, gel, powder, thickened lotion, stick, or formulated by aerosol into the form of a foam or powder;
The composition according to any one of items 1, 2, and 3 above, which is characterized by having a deodorizing effect.
JP22679688A 1988-09-09 1988-09-09 Composition, applied onto keratinous substance and skin and having deodorizing effect Pending JPH0273009A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22679688A JPH0273009A (en) 1988-09-09 1988-09-09 Composition, applied onto keratinous substance and skin and having deodorizing effect

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22679688A JPH0273009A (en) 1988-09-09 1988-09-09 Composition, applied onto keratinous substance and skin and having deodorizing effect

Publications (1)

Publication Number Publication Date
JPH0273009A true JPH0273009A (en) 1990-03-13

Family

ID=16850751

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22679688A Pending JPH0273009A (en) 1988-09-09 1988-09-09 Composition, applied onto keratinous substance and skin and having deodorizing effect

Country Status (1)

Country Link
JP (1) JPH0273009A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999016411A1 (en) * 1997-09-26 1999-04-08 Shiseido Company, Ltd. Dermatologic preparation
JP2020014656A (en) * 2018-07-25 2020-01-30 東洋製罐グループホールディングス株式会社 Deodorant composition for permanent wave-treated hair, manufacturing method of deodorant composition, and deodorizing method of hair

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999016411A1 (en) * 1997-09-26 1999-04-08 Shiseido Company, Ltd. Dermatologic preparation
JP2020014656A (en) * 2018-07-25 2020-01-30 東洋製罐グループホールディングス株式会社 Deodorant composition for permanent wave-treated hair, manufacturing method of deodorant composition, and deodorizing method of hair

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