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JPH0270051A - Formation of wear resistant structure of sliding part for injection molding machine - Google Patents

Formation of wear resistant structure of sliding part for injection molding machine

Info

Publication number
JPH0270051A
JPH0270051A JP63222699A JP22269988A JPH0270051A JP H0270051 A JPH0270051 A JP H0270051A JP 63222699 A JP63222699 A JP 63222699A JP 22269988 A JP22269988 A JP 22269988A JP H0270051 A JPH0270051 A JP H0270051A
Authority
JP
Japan
Prior art keywords
base
wear
layer
sliding part
welding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63222699A
Other languages
Japanese (ja)
Other versions
JP2520382B2 (en
Inventor
Kenichi Maede
前出 憲一
Hironori Koyama
洋典 小山
Junichi Tanaka
順一 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Meiki Seisakusho KK
Original Assignee
Meiki Seisakusho KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Meiki Seisakusho KK filed Critical Meiki Seisakusho KK
Priority to JP63222699A priority Critical patent/JP2520382B2/en
Publication of JPH0270051A publication Critical patent/JPH0270051A/en
Application granted granted Critical
Publication of JP2520382B2 publication Critical patent/JP2520382B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/46Means for plasticising or homogenising the moulding material or forcing it into the mould
    • B29C45/58Details
    • B29C45/60Screws
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/46Means for plasticising or homogenising the moulding material or forcing it into the mould
    • B29C45/47Means for plasticising or homogenising the moulding material or forcing it into the mould using screws
    • B29C45/50Axially movable screw
    • B29C45/52Non-return devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/505Screws
    • B29C48/507Screws characterised by the material or their manufacturing process
    • B29C48/509Materials, coating or lining therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/46Means for plasticising or homogenising the moulding material or forcing it into the mould
    • B29C45/47Means for plasticising or homogenising the moulding material or forcing it into the mould using screws
    • B29C45/50Axially movable screw
    • B29C45/52Non-return devices
    • B29C2045/526Abrasion resistant means in the screw head or non-return device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

PURPOSE:To obtain the wear resistant structure having excellent strength, wear resistance and durability by mixing and welding an Ni base and WC to the surface of the base material of the sliding part and welding the WC to the resultant base body layer, thereby forming the wear resistant layer nearly uniformly dispersed with the Ni base and the WC. CONSTITUTION:Powders of the Ni base and the WC are mixed and are welded by a plasma welding device 50 to the surface of the base material S of the sliding part such as ring valve of an injection molding machine to form the base body layer 10A. The mixing ratio of the Ni base and the WC of the above-mentioned powder is adequately about 7:3 by volume. The WC 15 sinks to the lower part and the upper part consists mostly of only the Ni base 14 in the base body layer 10A obtd. in such a manner by the difference in sp. gs. The WC is then plasma-welded to the above- mentioned base body layer 10A. The amt. of the WC to be welded at this time is preferably made equal to the amt. of the WC to be welded to the above-mentioned base body layer 10A. The WC is intruded into the above-mentioned Ni base 14 by this welding of the WC. The wear resistant layer 10 in which the WC 15 is nearly uniformly dispersed in the Ni base 14 as a whole is thus easily and surely formed.

Description

【発明の詳細な説明】 (産業上の利用分野) この発明は、射出成形装置において摩耗の生じやすい摺
動部における耐摩耗構造の形成方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for forming a wear-resistant structure in a sliding part that is prone to wear in an injection molding apparatus.

(従来の技術) 射出成形装置においては、例えば、成形材料のチャージ
時にリンクハルツの前端面とスクリュヘット後端面か接
触しかつ前記スクリュヘットか回転しているため摺動し
、両者の摺動面には摩擦による摩耗か生ずる。特に、成
形材料かセラミック等の硬質材料である場合あるいはガ
ラスフィラー等を混入した場合には、両部品の摺動部に
おける摩耗は著しく、そのためスクリュの寿命が極端に
短かくなるという問題を生している。
(Prior Art) In an injection molding device, for example, when charging the molding material, the front end face of the link heart and the rear end face of the screw head come into contact with each other, and since the screw head is rotating, they slide, and the sliding surfaces of both contact. wear due to friction occurs. In particular, if the molding material is a hard material such as ceramic, or if it contains glass filler, etc., the sliding parts of both parts will wear significantly, resulting in an extremely shortened screw life. ing.

このような問題を解決する手段として、例えば特開昭6
2−68703号公報に開示されたように、両部品の接
触面に硬質粉粒体であるタングステンカーバイドを適量
溶射することによって摩耗防止を図る構造か提案されて
いる。
As a means to solve such problems, for example,
As disclosed in Japanese Patent No. 2-68703, a structure has been proposed in which wear is prevented by thermally spraying an appropriate amount of tungsten carbide, which is a hard powder, on the contact surfaces of both parts.

ところて1このタングステンカーバイドは、耐熱、耐摩
耗性を有するニッケル基合金とともにフラズマ溶射法に
よって溶射されるのか好ましい。
Now, it is preferable that the tungsten carbide is thermally sprayed together with a nickel-based alloy having heat resistance and wear resistance by a plasma spraying method.

しかしなから、これらの金属バラタ−を混合溶射した場
合には、次のような問題か生ずることか明らかになった
However, it has become clear that when these metal balata are mixed and thermally sprayed, the following problems occur.

すなわち、タンクステンンカーへイトおよびニッケル基
合金の金属バラタ−を混合溶射した場合、両金属の比重
かタングステンカーバイド15.8、ニッケル基は8.
9と大きく異なるために、第3図に示した溶着層40の
拡大断面図から明らかなように、比重の大きいタングス
テンカーバイド41がニッケル基42中に沈み込んて被
溶射体である母材43表面側に集中し、溶着層上部にタ
ングステンカーバイドかほとんど存在せず均一な溶着層
が得られないのである。従って、このような溶着層40
にあっては層の上部と下部とで硬度か異なり所定の強度
の耐摩耗層か得られない。
That is, when a metal balater of tank sten carbide and a nickel-based alloy is mixed and sprayed, the specific gravity of both metals is 15.8 for tungsten carbide and 8.8 for nickel-based alloy.
9, as is clear from the enlarged cross-sectional view of the welding layer 40 shown in FIG. The tungsten carbide concentrates on the sides, and there is almost no tungsten carbide on the top of the weld layer, making it impossible to obtain a uniform weld layer. Therefore, such a welding layer 40
In this case, the upper and lower parts of the layer have different hardnesses, making it impossible to obtain a wear-resistant layer with a predetermined strength.

(発明が解決しようとする課題) そこてこの発明は上のような状況に鑑みて、層の上部と
下部とて硬度等の物性か異なることかなく、所定の混合
比に基づく強度を有し、耐摩耗性、耐久性に優れた耐摩
耗構造を確実に形成する方法を提供することを目的とす
るものである。
(Problems to be Solved by the Invention) Therefore, in view of the above situation, the present invention has been developed to provide a material that has strength based on a predetermined mixing ratio without having physical properties such as hardness different between the upper and lower parts of the layer. The object of the present invention is to provide a method for reliably forming a wear-resistant structure with excellent wear resistance and durability.

(課題を解決するための手段) すなわち、この発明は、耐摩耗構造の形成方法に係り、
この方法は、摺動部の母材表面に、ニッケル基とタング
ステンカーバイドを混合溶着して基体層を形成する工程
と、前記基体層にタングステンカーバイドを溶着してニ
ッケル基とタンクステンカーハイ1〜がほぼ均一な状態
て分散された耐摩耗層を形成する工程とからなることを
特徴とする。
(Means for solving the problem) That is, the present invention relates to a method of forming a wear-resistant structure,
This method includes the steps of forming a base layer by welding a mixture of nickel base and tungsten carbide on the base material surface of the sliding part, and welding tungsten carbide to the base layer to form a nickel base and tank sten carbide layer. forming a wear-resistant layer in which the wear-resistant layers are almost uniformly dispersed.

(実施例) 以下添付の図面に従ってこの発明の詳細な説明すると、
第1図はスクリュヘットとリンクハルツの摺動部に耐摩
耗層を形成した射出成形装置の要部断面図、第2図は第
1図の耐摩耗層の拡大断面図、第3図は従来の溶着層の
拡大断面図、第4図はこの発明方法の基体層の形成工程
を示す断面図、第5図は同しく耐摩耗層の形成工程を示
す断面図である。
(Example) The present invention will be described in detail below with reference to the attached drawings.
Figure 1 is a cross-sectional view of the main parts of an injection molding machine in which a wear-resistant layer is formed on the sliding parts of the screw head and link heart, Figure 2 is an enlarged cross-sectional view of the wear-resistant layer in Figure 1, and Figure 3 is a conventional FIG. 4 is a sectional view showing the step of forming the base layer in the method of the present invention, and FIG. 5 is a sectional view showing the step of forming the wear-resistant layer.

第1図に図示したように射出成形装置の加熱筒ll内に
はスクリュ12か回転自在に挿入され、このスクリュ先
端にはウェアプレート13を介してスクリュヘッド20
が螺着されている。スクリュヘット20は溶融した成形
材料を通過させるための切欠通路23か設けられた大径
部21およびスクリュに螺着される細軸部22を有する
。また細軸部22の外周には加熱筒11内面に当接する
リンクハルツ30か嵌挿され、該リンクバルブ内周面3
1と前記細軸部22との間には樹脂通路Pとなる間隙か
形成される。
As shown in FIG. 1, a screw 12 is rotatably inserted into the heating cylinder 11 of the injection molding apparatus, and a screw head 20 is connected to the tip of the screw via a wear plate 13.
is screwed on. The screw head 20 has a large diameter portion 21 provided with a cutout passage 23 through which molten molding material passes, and a thin shaft portion 22 that is screwed onto the screw. Further, a link hartz 30 that comes into contact with the inner surface of the heating cylinder 11 is fitted onto the outer periphery of the thin shaft portion 22, and the link valve inner peripheral surface 3
1 and the thin shaft portion 22, a gap serving as a resin passage P is formed.

そして溶融樹脂のチャージ(充填)時には、樹脂の送入
圧によってリンクハルツ30か前方に押されて該リング
ハルツ後端部32と前記ウェアフレートの前端部13a
の間に隙間か形成され、樹脂通路Pが開かれて切欠通路
23と連通する。
When charging (filling) with molten resin, the link hartz 30 is pushed forward by the resin feeding pressure, and the rear end 32 of the ring hartz and the front end 13a of the wear plate are pushed forward.
A gap is formed between them, and the resin passage P is opened and communicates with the notch passage 23.

このとき前記リンクハルツの前端部33とスクリュヘッ
トの大径部後端面21aは接触しており、同時にスクリ
ュ12か回転しているのてこれらの摺動部における摩耗
は極めて大きいものとなる。
At this time, the front end 33 of the link heart and the rear end surface 21a of the large diameter part of the screw head are in contact with each other, and since the screw 12 is rotating at the same time, the wear on these sliding parts becomes extremely large.

しかるに、この射出成形装置においては、摺動部となる
スクリュヘット大径部の後端面21aおよびリンクハル
ツの前端面33に、それぞれ耐摩耗層10.10か形成
されている。
However, in this injection molding apparatus, wear-resistant layers 10 and 10 are formed on the rear end surface 21a of the large diameter portion of the screw head, which serves as a sliding portion, and on the front end surface 33 of the link heart, respectively.

この耐摩耗層重0の厚さは約4mmて、ニッケル基とタ
ングステンカーバイドの金属パラターのプラズマ溶着層
からなる。
This wear-resistant layer has a thickness of about 4 mm and is composed of a plasma-welded layer of metal parametries of nickel base and tungsten carbide.

そしてこの耐摩耗層10は、第2図の拡大断面図から理
解されるように、スクリュヘットまたはりンクへルフを
構成する母材S表面に、ニッケル基14とタングステン
カーバイド15がほぼ均一に分散された状態て溶着形成
されている。
In this wear-resistant layer 10, as can be seen from the enlarged cross-sectional view in FIG. It is welded and formed.

第3図は従来の耐摩耗構造における断面図であるか、前
述したように、従来構造にあっては両金属パウダーの比
重の違いにより比重の大きいタングステンカーバイド4
1は比重の小さいニッケル基42の下部に沈み込み、均
一な分散混合状態か得られない。
Figure 3 is a cross-sectional view of a conventional wear-resistant structure.
1 sinks below the nickel base 42, which has a low specific gravity, and a uniformly dispersed and mixed state cannot be obtained.

この耐摩耗層10は以下に述べる方法によって形成され
る。
This wear-resistant layer 10 is formed by the method described below.

まず、第4図に図示したように、摺動部となるリンクバ
ルブの前端面またはスクリュヘット大径部の後端面等の
母材Sの表面に、ニッケル基Niとタングステンカーバ
イドWCのパラターを、混合比、例えば体積比て[ニッ
ケル基]7対Fタンクステンカーハイト]3の割合て公
知のプラズマ溶着装置50より混合溶着して、基体層1
0Aか形成される。なおこの実施例ては、ニッケル基は
rNimonic80AJ (商品名)を用いた。
First, as shown in Fig. 4, a parata of nickel-based Ni and tungsten carbide WC is applied to the surface of the base material S, such as the front end face of the link valve that becomes the sliding part or the rear end face of the large diameter part of the screw head. The base layer 1 is mixed and welded using a known plasma welding apparatus 50 at a mixing ratio of 7 [nickel base] to 3 F tank stenker height (volume ratio).
0A is formed. In this example, rNimonic80AJ (trade name) was used as the nickel group.

ここで形成される基体層10Aては、図示のように、比
重の相違により、タングステンカーバイドエ5は基体層
10A下部に沈みこみ、上部はほとんどニッケル基14
のみの層となっている。これは、第3図に図示した従来
の溶着層40と同様である。
As shown in the figure, in the base layer 10A formed here, due to the difference in specific gravity, the tungsten carbide 5 sinks into the lower part of the base layer 10A, and the upper part is almost nickel-based 14.
There are only two layers. This is similar to the conventional weld layer 40 illustrated in FIG.

次に、この発明方法においては、第5図に図示したよう
に、前記工程で形成された基体!l OAにタングステ
ンカーバイドWCか前記と同様プラズマ溶着装置50に
よって溶着される。このときのタングステンカーバイド
の溶着量は、前記基体層の形成工程て溶着されたタング
ステンカーバイドと同量で行うことが望ましい。
Next, in the method of this invention, as shown in FIG. 5, the substrate formed in the above process! 1 Tungsten carbide WC is welded to the OA using the plasma welding device 50 as described above. The amount of tungsten carbide deposited at this time is preferably the same as the amount of tungsten carbide deposited in the step of forming the base layer.

この工程によって、図示のように、タングステンカーバ
イド15は前記基体層10Aの上部、すなわちタングス
テンカーバイドかほとんど存在していなかったニッケル
基14中にも入り込み、全体としてタングステンカーバ
イド15かニッケル基14中にほぼ均一な状態て分散さ
れた耐摩耗層10か形成される。
Through this step, as shown in the figure, tungsten carbide 15 also enters the upper part of the base layer 10A, that is, into the nickel base 14 where almost no tungsten carbide was present, and as a whole, almost all tungsten carbide 15 or nickel base 14 is present. A uniformly distributed wear-resistant layer 10 is formed.

(効果) 以上図示説明したようにこの発明によれば、射出成形装
置の摺動部の母材表面にニッケル基とタングステンカー
バイドがほぼ均一な状態て分散された耐摩耗層を簡単か
つ確実に溶着形成することか可能となった。従って層全
体に所定の混合比よりなる金属層か形成され、所期の硬
度を有し、かつ耐摩耗性、耐久性等の物性を安定して備
えた耐摩耗層を形成することかてき、この発明のもたら
す効果は実際」二極めて大きいものがある。
(Effects) As illustrated and explained above, according to the present invention, a wear-resistant layer in which nickel base and tungsten carbide are almost uniformly dispersed is easily and reliably welded to the surface of the base material of the sliding part of an injection molding device. It became possible to form. Therefore, a metal layer having a predetermined mixing ratio is formed over the entire layer, and a wear-resistant layer having desired hardness and stable physical properties such as wear resistance and durability can be formed. The effects of this invention are actually quite large.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はスクリュヘットとリンクハルツの摺動部に耐摩
耗層を形成した射出成形装置の要部断面図、第2図は第
1図の耐摩耗層の拡大断面図、第3図は従、来の溶着層
の拡大断面図、第4図はこの発明方法の基体層の形成工
程を示す断面図、第5図は同しく耐摩耗層の形成工程を
示す断面図である。 10・・・耐摩耗層、IOA・・・基体層、14・・・
ニッケル基、15・・・タングステンカーバイド、20
・・・スクリュヘッド、21a・・・大径部後端面、3
0・・・リングハルツ、33・・・リンクハルツ前端面
Figure 1 is a cross-sectional view of the main parts of an injection molding machine in which a wear-resistant layer is formed on the sliding parts of the screw head and link heart, Figure 2 is an enlarged cross-sectional view of the wear-resistant layer in Figure 1, and Figure 3 is a , FIG. 4 is a sectional view showing the step of forming the base layer in the method of the present invention, and FIG. 5 is a sectional view showing the step of forming the wear-resistant layer. 10... Wear-resistant layer, IOA... Base layer, 14...
Nickel base, 15...Tungsten carbide, 20
...Screw head, 21a...Large diameter portion rear end surface, 3
0... Ring Harz, 33... Link Harz front end surface.

Claims (1)

【特許請求の範囲】 1、摺動部の母材表面に、ニッケル基とタングステンカ
ーバイドを混合溶着して基体層を形成する工程と、前記
基体層にタングステンカーバイドを溶着してニッケル基
とタングステンカーバイドがほぼ均一な状態で分散され
た耐摩耗層を形成する工程とからなることを特徴とする
射出成形装置の摺動部における耐摩耗構造の形成方法。 2、基体層形成工程におけるニッケル基とタングステン
カーバイドの混合比が体積比で約7対3の割合である請
求項第1項記載の射出成形装置の摺動部における耐摩耗
構造の形成方法。
[Claims] 1. A step of forming a base layer by welding a mixture of nickel base and tungsten carbide on the base material surface of the sliding part, and a step of welding tungsten carbide to the base layer to form the nickel base and tungsten carbide. 1. A method for forming a wear-resistant structure in a sliding part of an injection molding device, the method comprising the step of forming a wear-resistant layer in which a wear-resistant layer is almost uniformly dispersed. 2. The method for forming a wear-resistant structure in a sliding part of an injection molding apparatus according to claim 1, wherein the mixing ratio of nickel base and tungsten carbide in the base layer forming step is about 7:3 by volume.
JP63222699A 1988-09-06 1988-09-06 Method of forming wear resistant structure in sliding part of injection molding machine Expired - Lifetime JP2520382B2 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0636824U (en) * 1992-10-23 1994-05-17 株式会社名機製作所 Screw head structure of injection device
JPH0860334A (en) * 1995-08-03 1996-03-05 Meiki Co Ltd Manufacture of nozzle tip of injection molding machine
EP1961550A4 (en) * 2005-12-15 2010-12-08 Sumitomo Heavy Industries SNAIL, SPRAYER AND PRESSURE MEMBER
EP2455207A1 (en) * 2010-11-18 2012-05-23 Sumitomo Heavy Industries, Ltd. Screw and manufacturing method thereof
CN114855159A (en) * 2022-04-15 2022-08-05 潜江市江汉钻具有限公司 Wear-resistant double-layer composite drill bit based on plasma fusion and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0636824U (en) * 1992-10-23 1994-05-17 株式会社名機製作所 Screw head structure of injection device
JPH0860334A (en) * 1995-08-03 1996-03-05 Meiki Co Ltd Manufacture of nozzle tip of injection molding machine
EP1961550A4 (en) * 2005-12-15 2010-12-08 Sumitomo Heavy Industries SNAIL, SPRAYER AND PRESSURE MEMBER
US7934923B2 (en) 2005-12-15 2011-05-03 Sumitomo Heavy Industries, Ltd. Screw, injection apparatus, and pressure member
EP2455207A1 (en) * 2010-11-18 2012-05-23 Sumitomo Heavy Industries, Ltd. Screw and manufacturing method thereof
CN114855159A (en) * 2022-04-15 2022-08-05 潜江市江汉钻具有限公司 Wear-resistant double-layer composite drill bit based on plasma fusion and preparation method thereof

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