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JPH02252667A - Production of gate pier or the like by utilizing waste - Google Patents

Production of gate pier or the like by utilizing waste

Info

Publication number
JPH02252667A
JPH02252667A JP33498588A JP33498588A JPH02252667A JP H02252667 A JPH02252667 A JP H02252667A JP 33498588 A JP33498588 A JP 33498588A JP 33498588 A JP33498588 A JP 33498588A JP H02252667 A JPH02252667 A JP H02252667A
Authority
JP
Japan
Prior art keywords
waste
slag
marble
powdery
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP33498588A
Other languages
Japanese (ja)
Inventor
Takeo Kidai
木代 武雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Trading Corp
Furukawa Sangyo Kaisha Ltd
Original Assignee
Mitsubishi Materials Trading Corp
Furukawa Sangyo Kaisha Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Trading Corp, Furukawa Sangyo Kaisha Ltd filed Critical Mitsubishi Materials Trading Corp
Priority to JP33498588A priority Critical patent/JPH02252667A/en
Publication of JPH02252667A publication Critical patent/JPH02252667A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4826Polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Finishing Walls (AREA)

Abstract

PURPOSE:To improve the added value by melting and kneading a powdery waste, such as slag, with a synthetic resin waste, forming a core material part, then mixing powdery decorative stone with a polyester resin and forming a surface member on the periphery thereof. CONSTITUTION:Powdered wastes, such as slag, sludge or cinders, are mixed and a hot-melt resin waste, such as PE or PS, in an amount of >=10% based on the above-mentioned mixture is added, thermally melted, injected into a mold of a prescribed shape, cooled and then cured to provide a core material part, which is subsequently placed in the center of a mold form shaped into a prescribed form and a mixture prepared by mixing decorative stone, such as marble, granite or brick, in a powdery or granular form with a polyester resin at about 9/1 ratio is filled in the periphery thereof, cured and hardened to form a surface member and afford a formed product, such as decorated gate pier.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、工場排水からでる汚泥、鋳物製造過程からで
る鉱砂等の産業廃棄物及び自治体から出る燃え殻等の一
般廃棄物の処理方法に間する。
Detailed Description of the Invention (Industrial Application Field) The present invention is applicable to a method for treating industrial waste such as sludge from factory wastewater, ore sand from the foundry manufacturing process, and general waste such as cinders from local governments. Pause.

(従来の技術) 上記産業及び一般廃棄物の処理法については、「廃棄物
処理法」によって一定の処理基準が定められ、生活環境
の保全と公衆衛生の維持が図られようとしている。
(Prior Art) Regarding the above-mentioned industrial and general waste treatment methods, certain treatment standards have been established by the "Waste Disposal Law," and efforts are being made to preserve the living environment and maintain public health.

しかし、多様な廃棄物が°膨大に排出され、且つ、新し
い処理場建設には地域住民の反対が強い等の現状にあっ
て、処理体制がこれに伴わず、処理能力の不足が慢性化
している状況にある。
However, given the current situation where a huge amount of diverse waste is being generated and the construction of a new treatment plant is strongly opposed by local residents, the treatment system has not been able to keep up with this, and the lack of treatment capacity has become chronic. I am in a situation where I am.

この為、山や砂利穴等に不法投棄される例は枚挙にいと
まがなく、しかし、−度この様に不法投棄がなされると
、雨水と共に有害物質が地中深く浸透して地下水中に混
入し、この結果、一般住民の健康や生活環境に弊害をも
たらすという重大な問題を抱えている。
For this reason, there are countless examples of illegal dumping in mountains, gravel pits, etc. However, when illegal dumping occurs in this way, toxic substances permeate deep into the ground along with rainwater and enter the groundwater. This poses a serious problem in that it causes harm to the health and living environment of the general population.

(発明の解決しようとする!!H) そこで、本発明者はこれら廃棄物の処理に対する研究を
重た結果、廃棄物の特性に着目し、ボリエチレン、ポリ
スチレン等の熱溶融性合成樹脂の粘結性を利用して廃棄
物に適切な固化処理を施し、門柱や敷石ブロック等の有
効物質を得ることに成功したものであり、上記問題点を
一掃する;とに主たる狙いがある。
(The invention attempts to solve the problem! The main aim is to eliminate the above-mentioned problems by applying appropriate solidification treatment to waste by utilizing its properties, and successfully obtaining useful materials for gateposts, paving blocks, etc.

(課題を解決しようとする手段) 本廃棄物利用による門柱等の製造方法は、先ず、粉状と
した鉱滓、汚泥、燃え殻等の廃棄物を集め、これをミキ
サー等で混合する。そして、該混合物に熱溶融性合成樹
脂廃棄物を1割以上投入し、加熱下で溶融混練し、これ
を一定の形の型材に投入して放冷硬化させて芯材部を形
成する。
(Means for Solving the Problems) In this method of manufacturing gateposts, etc. using waste, first, wastes such as powdered slag, sludge, cinders, etc. are collected and mixed in a mixer or the like. Then, 10% or more of hot-melt synthetic resin waste is added to the mixture, melted and kneaded under heating, and then put into a mold of a certain shape and allowed to cool and harden to form a core part.

次いで、この芯材部の周囲に、粉状又は粒状の大理石、
御影石、レンガ等の装飾性石材にポリエステル樹脂を混
合させた混練物を囲撓させて表面部材を成形し、大理石
、御影石、レンガ等の処理の表出された門柱、敷石ブロ
ック等の成形品を得ることを特徴として構成される。
Next, powdered or granular marble,
A kneaded mixture of decorative stones such as granite and bricks mixed with polyester resin is molded into surface members to form molded products such as gateposts and paving stone blocks that are made of marble, granite, bricks, etc. It is structured with the characteristic of obtaining.

(作用) 粉状の鉱滓、汚泥、燃え殻等に対し熱溶融性の合成樹脂
廃棄物が加熱で溶融して粘結性を発揮し、廃棄物相互を
結合させ、他の硬化剤を要することなく廃棄物自体で一
定の形の芯材部を形成するように働く。
(Function) Heat-melting synthetic resin waste melts powdered slag, sludge, cinders, etc. by heating and exhibits caking properties, bonding the wastes together and eliminating the need for other hardening agents. The waste itself acts to form a core of a certain shape.

又、粉状又は粒状の大理石とポリエステ樹脂中の表面部
材は、この芯材部を覆い隠すと共に、それ自体大理石の
処理を表化し、綺麗に装飾された門柱、敷石ブロック等
を形成するように働く。
In addition, the powdered or granular marble and the surface material in the polyester resin not only cover up this core material but also reveal the processing of the marble, forming beautifully decorated gateposts, paving stone blocks, etc. work.

又、このポリエステル樹脂は紫外線に強く、耐候性を向
上させる。
Additionally, this polyester resin is resistant to ultraviolet rays and improves weather resistance.

(結果) 以上の構成に基づく本発明は、従来廃棄されていた鉱滓
、汚泥、燃え殻等の廃棄物を同化処理できるので、今ま
で必要とした廃棄の為の膨大な広さの処理場が必要なく
、慢性的に能力不足に陥っていた廃棄物処理の問題を解
決する重要な手段となる。そして、莫大なi!a* *
用を要する管理型の廃棄物に対する従来の処理法と比較
するとその経済的メリットが極めて大きい。
(Results) The present invention based on the above configuration can assimilate waste materials such as mine slag, sludge, and cinders that were conventionally disposed of, so a hugely large treatment plant for disposal is not required. This will be an important means of solving the problem of waste disposal, which has been suffering from a chronic lack of capacity. And huge i! a* *
The economic benefits are extremely large compared to conventional treatment methods for controlled waste that requires use.

その際、ポリエチレン等合成樹脂廃棄物の熱溶敵性を利
用しで粘結させたので、廃棄物自体で固化させることが
でき、硬化剤等を要さず経済的である。
At this time, since the heat-melting property of the waste synthetic resin such as polyethylene was used for caking, the waste itself can be solidified, which is economical since no curing agent or the like is required.

更に、廃棄物が積極的に門柱等の有用物質に活用される
ので、リサイクルの過程に軟り、天然資源の有効利用に
つながり、且つ、それが大理石、御影石等の処理による
装飾効果を兼ね備えたものなので付加価値の高い製品を
得ることができる。
Furthermore, since waste is actively used to make useful materials such as gateposts, the recycling process becomes flexible, leading to the effective use of natural resources, and it also has a decorative effect by processing marble, granite, etc. Because it is a product, it is possible to obtain products with high added value.

(実施例) 缶詰工場からの脱水汚泥400kgと、I!鋼工場から
の鉱滓200kgと、自治体からの建築廃材の燃殻10
0kgとを集め、且つ、ポリエチレン100kg%ナイ
ロン100kg、ポリスチレン100kgを破砕機にか
けて5X5X5mmのベレットに粉砕し、これをミキサ
ーに掛けて約5分程度混合した0次いで、この混合物を
加熱装置を備えた押出機に投入して、約200℃に加熱
しつつ混練した。すると、樹脂分が溶融しつつ、汚泥、
鉱滓壽の廃棄物と混り合い均一化した。そして、これを
30X30X140cmの角柱型の成形枠に充填し、上
から油圧プレスで押圧し密度を高めた後、乾燥状態の室
で24時間放置した。この結果、冷却に従って、均一混
合した樹脂分が廃棄物相互を結合して固化し、相当強度
の芯材部を得た。
(Example) 400 kg of dehydrated sludge from a cannery and I! 200 kg of slag from a steel factory and 10 husk of construction waste from local government
Then, 100 kg of polyethylene, 100 kg of nylon, and 100 kg of polystyrene were crushed into 5 x 5 x 5 mm pellets using a crusher, and mixed in a mixer for about 5 minutes.Next, this mixture was extruded using a heating device. The mixture was put into a machine and kneaded while being heated to about 200°C. Then, while the resin content melts, sludge,
It mixed with the waste from the slag and became homogenized. Then, this was filled into a 30 x 30 x 140 cm prismatic molding frame, pressed from above with a hydraulic press to increase density, and then left in a dry chamber for 24 hours. As a result, as the resin was cooled, the uniformly mixed resin bonded the waste materials and solidified, yielding a core material portion with considerable strength.

次いで、この芯材部の下に予め固めた粉状大理石の板を
敷き、その周囲を門柱の形に型とった成形枠で囲撓し、
中に粉状大理石とポリエステルとを9:lの割合で混合
した混練物を、バイブレーダーで空気抜きをしながら充
填し、これを30分放置し、養生固化して表面部材を得
た。
Next, a board of pre-hardened powdered marble was laid under this core material, and a molded frame shaped like a gatepost was placed around it.
A kneaded mixture of powdered marble and polyester in a ratio of 9:1 was filled into the container while removing air using a vibrader, and the mixture was left to stand for 30 minutes to cure and harden to obtain a surface member.

同化完了後、表面をサウンドベーパーで研摩仕上げした
ところ、大理石の処理が表われ、綺麗に装飾された門柱
が得られた。
After the assimilation was completed, the surface was polished with sound vapor, and the marble treatment was revealed, resulting in a beautifully decorated gatepost.

(実施例2) アルミニ場からの鉱滓350kgと、ポリエチレン50
kg、ナイロン50kg、ポリスチレン50kgを破砕
機にかけて5X5X5rnmのペレットに粉砕し、これ
をミキサーに掛けて約5分程度混合した0次いで、この
混合物を加熱H置を儂えた押出機に投入して、約200
℃に加熱しつつ混練すると、樹脂分が溶融しつつ、鉱滓
の廃棄物と混り合い均一化した。そして、これを30×
30X5cmの角型の道路用敷石ブロック成形枠に充填
し、上から油圧プレスで押圧し密度を高めた後、乾燥状
態の室で24時間放置し、冷却に従フて、均一混合した
樹脂分が廃棄物相互を結合して固化した。
(Example 2) 350 kg of slag from an aluminum field and 50 kg of polyethylene
kg, 50 kg of nylon, and 50 kg of polystyrene were crushed into pellets of 5 x 5 x 5 nm using a crusher, and mixed in a mixer for about 5 minutes.Next, this mixture was put into an extruder with a heating H setting, and the pellets were crushed into pellets of about 5 x 5 x 5 nm. 200
When kneaded while heating to ℃, the resin content melted and mixed with the slag waste to homogenize it. And this is 30x
It was filled into a 30 x 5 cm square road paving stone block molding frame, pressed from above with a hydraulic press to increase the density, left in a dry room for 24 hours, and allowed to cool until the uniformly mixed resin content was mixed. The wastes were combined and solidified.

次いで、この敷石ブロックの表面に、粉状の御影石とポ
リエステルとを9:lの割合で混合した混練物をバイブ
レータ−で空気抜きしながら充填、養生固化し、5mm
の厚みの表面層とした。
Next, the surface of this paving stone block was filled with a kneaded mixture of powdered granite and polyester in a ratio of 9:1 while removing air with a vibrator, and cured and solidified to a thickness of 5 mm.
The surface layer had a thickness of .

この結果、成型枠に刻んだ幾何学模様が現われ整美な敷
石ブロックが得られた。
As a result, the geometric patterns engraved on the molding frame appeared and a beautiful paving stone block was obtained.

Claims (1)

【特許請求の範囲】 1)粉状とした鉱滓、汚泥、燃え殻等の廃棄物に対し1
割を越える割合で熱溶融性の合成樹脂廃棄物を混合し、
該混合物を加熱下で溶融混練し、更に一定の形の型材に
投入して放冷硬化させて芯材部を形成し、 次いで、該芯材部の周囲に、粉状又は粒状の大理石、御
影石等の装飾性石材にポリエステル樹脂を混合させた混
練物を囲撓させて表面部材を形成し、 その表面に大理石、御影石等の処理の表出された門柱、
敷石ブロック等の成形品を得ることを特徴とする廃棄物
利用による門柱等の製造方法。
[Claims] 1) 1 for waste such as powdered slag, sludge, cinders, etc.
Mixing heat-melting synthetic resin waste at a ratio exceeding 10%,
The mixture is melted and kneaded under heating, then put into a mold of a certain shape and left to cool and harden to form a core part. Next, powdered or granular marble or granite is placed around the core part. The surface member is formed by surrounding a kneaded mixture of decorative stone materials such as polyester resin, etc., and the gatepost has a surface treated with marble, granite, etc.
A method for manufacturing gateposts, etc. by using waste, characterized by obtaining molded products such as paving stone blocks.
JP33498588A 1988-12-30 1988-12-30 Production of gate pier or the like by utilizing waste Pending JPH02252667A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33498588A JPH02252667A (en) 1988-12-30 1988-12-30 Production of gate pier or the like by utilizing waste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33498588A JPH02252667A (en) 1988-12-30 1988-12-30 Production of gate pier or the like by utilizing waste

Publications (1)

Publication Number Publication Date
JPH02252667A true JPH02252667A (en) 1990-10-11

Family

ID=18283431

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33498588A Pending JPH02252667A (en) 1988-12-30 1988-12-30 Production of gate pier or the like by utilizing waste

Country Status (1)

Country Link
JP (1) JPH02252667A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010047686A (en) * 1999-11-22 2001-06-15 김성열 Marble manufacturing method by using scrapped materials
CN106699125A (en) * 2017-03-02 2017-05-24 陈炳响 Sintered brick and preparation method thereof
CN106747315A (en) * 2017-03-02 2017-05-31 陈炳响 A kind of fired brick and preparation method thereof
CN106882953A (en) * 2017-03-02 2017-06-23 陈炳响 A kind of fired brick and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4929609A (en) * 1972-07-10 1974-03-16
JPS60429U (en) * 1983-06-17 1985-01-05 石川島播磨重工業株式会社 Radial gate anchorage

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4929609A (en) * 1972-07-10 1974-03-16
JPS60429U (en) * 1983-06-17 1985-01-05 石川島播磨重工業株式会社 Radial gate anchorage

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010047686A (en) * 1999-11-22 2001-06-15 김성열 Marble manufacturing method by using scrapped materials
CN106699125A (en) * 2017-03-02 2017-05-24 陈炳响 Sintered brick and preparation method thereof
CN106747315A (en) * 2017-03-02 2017-05-31 陈炳响 A kind of fired brick and preparation method thereof
CN106882953A (en) * 2017-03-02 2017-06-23 陈炳响 A kind of fired brick and preparation method thereof

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