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JPH02124703A - Ozonizer - Google Patents

Ozonizer

Info

Publication number
JPH02124703A
JPH02124703A JP27531888A JP27531888A JPH02124703A JP H02124703 A JPH02124703 A JP H02124703A JP 27531888 A JP27531888 A JP 27531888A JP 27531888 A JP27531888 A JP 27531888A JP H02124703 A JPH02124703 A JP H02124703A
Authority
JP
Japan
Prior art keywords
electrode
electrodes
center
discharge
ceramic tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP27531888A
Other languages
Japanese (ja)
Inventor
Takeshi Yamazaki
剛 山崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Energy Support Corp
Original Assignee
Energy Support Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Energy Support Corp filed Critical Energy Support Corp
Priority to JP27531888A priority Critical patent/JPH02124703A/en
Publication of JPH02124703A publication Critical patent/JPH02124703A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10Preparation of ozone
    • C01B13/11Preparation of ozone by electric discharge
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/10Dischargers used for production of ozone
    • C01B2201/14Concentric/tubular dischargers
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/20Electrodes used for obtaining electrical discharge
    • C01B2201/22Constructional details of the electrodes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/30Dielectrics used in the electrical dischargers
    • C01B2201/32Constructional details of the dielectrics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

PURPOSE:To facilitate dimensional precision control of the title ozonizer and to improve the ozone generating efficiency by inserting a central electrode into the center of an insulating ceramic pipe pierced with many small holes in parallel, providing a peripheral electrode on the periphery, and arranging an intermediate electrode between both electrodes. CONSTITUTION:The cylindrical ceramic pipe 1 is pierced with the plural parallel small holes 2 in the axial direction. The central electrode 4 is inserted into the small hole 2 at the center of the pipe 1, and the peripheral electrode 5 is closely mounted on the center of the periphery of the pipe 1 at a distance of L from both ends and grounded. The intermediate electrodes 6 having the length almost equivalent to the length of the peripheral electrode 5 in the axial direction are inserted into the small holes 2 between both electrodes 4 and 5. When an AC voltage is impressed between both electrodes 4 and 5, a silent discharge is generated between the small hole 2 of the ceramic pipe 1 and each intermediate electrode 6, and the oxygen in the air in the discharge is converted to ozone.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、オゾン発生装置に関するものである。[Detailed description of the invention] [Industrial application field] The present invention relates to an ozone generator.

[従来の技術] 従来、オゾン発生装置としては第4図に示すように、一
対の平行平板型1i10.11の一方の電f!11に無
声放電を得るための誘電体12をtn置し、この平行平
板型4f1.10.11に交番電圧を印加する。すると
、他方の電極11と誘電体12との空間S内で無声放電
が発生し、この放電の作用によってオゾンが発生ずる。
[Prior Art] Conventionally, as shown in FIG. 4, an ozone generator uses one of a pair of parallel plate type 1i10.11 electric f! A dielectric 12 for obtaining a silent discharge is placed on the parallel plate type 4f1.10.11, and an alternating voltage is applied to the parallel plate type 4f1.10.11. Then, a silent discharge occurs in the space S between the other electrode 11 and the dielectric 12, and ozone is generated by the action of this discharge.

[発明が解決しようとする課題」 ところが、一対の電filo、11に傾きが生じると電
極10.11間距離の短いところに電界が集中し、そこ
に部分放電が発生してしまうため、均等放電を持続させ
ることができない、そのため、オゾンを効率よく発生さ
せることができないという問題がある。また、空間Sは
数mイであるため寸法精度を高度に管理することは難し
かった。
[Problem to be Solved by the Invention] However, if the pair of electrodes 10 and 11 are tilted, the electric field will be concentrated in the short distance between the electrodes 10 and 11, and a partial discharge will occur there. Therefore, there is a problem that ozone cannot be efficiently generated. Furthermore, since the space S is several meters wide, it is difficult to control the dimensional accuracy to a high degree.

本発明の目的は5.F記の問題を解決するために寸法精
度管理を容易にし、さらにオゾンを効率よく発生させる
オゾン発生装置を提供することにある。
The purpose of the present invention is 5. In order to solve the problem described in F, it is an object of the present invention to provide an ozone generator that facilitates dimensional accuracy control and also efficiently generates ozone.

し課題を解決するための手段〕 上記の目的を解決するために、本発明は、複数の細孔が
互いに並設して貫設された絶縁性セラミンク管と、同絶
縁性セラミック管のほぼ中央部の細孔に挿入された中央
部電極と、同絶縁性セラミック管の外周部に配設され前
記中央部電極との間で交番電圧が印加される外周電極と
、前記両電極間に介在する細孔に遊挿配設した中間電極
群とから構成したことをその要旨とする。
Means for Solving the Problem] In order to solve the above object, the present invention provides an insulating ceramic tube in which a plurality of pores are arranged in parallel with each other and penetrating through the insulating ceramic tube; a central electrode inserted into the pore of the insulating ceramic tube; an outer peripheral electrode disposed on the outer periphery of the insulating ceramic tube to which an alternating voltage is applied between the central electrode; Its gist is that it is composed of a group of intermediate electrodes loosely inserted into the pores.

「作用] したがって、中央部電極電極および外周電極間に交番電
圧を印加すると絶縁性セラミック間の細孔と各中間電極
との間で無声放電が発生する。そして、細孔と中間電極
との間に介在する空気中の酸素が無声放電の作用により
オゾンに変換される。
"Operation" Therefore, when an alternating voltage is applied between the center electrode and the outer electrode, a silent discharge occurs between the pores between the insulating ceramics and each intermediate electrode. Oxygen present in the air is converted to ozone by the action of silent discharge.

L実施例] 以下、本発明を具体化した一実施例を第1.2図に基づ
いて説明する。
L Embodiment] Hereinafter, an embodiment embodying the present invention will be described based on FIG. 1.2.

絶縁性を備えたアルミナ磁器製のセラミック管1は円筒
形状に形成されるとともに、その軸心方向に対して複数
の角形状の細孔2が互いに並設して貫設されている。そ
して、細孔2が互いに隣接する絶縁壁3の全体はセラミ
ック管1の横断面に対し格子状となるように形成されて
いる。
An insulating ceramic tube 1 made of alumina porcelain is formed into a cylindrical shape, and has a plurality of square-shaped pores 2 extending in parallel with each other in the axial direction thereof. The entire insulating wall 3 in which the pores 2 are adjacent to each other is formed in a lattice shape with respect to the cross section of the ceramic tube 1.

前記セラミック管lの中央部の細孔2には中央部’IR
Mi4 (本実施例においては4本)が挿入されるとと
もに、セラミック管1の外周部にはその両端から沿面距
1111Lを備えた中央部に対し、筒状の外周電極5が
密着して嵌合されている。なお、この外周部[5はアー
ス接地されている。
The pore 2 in the center of the ceramic tube l has a center part 'IR'.
Mi4 (four in this example) is inserted, and a cylindrical outer electrode 5 is fitted tightly to the center of the ceramic tube 1 with a creepage distance of 1111L from both ends to the outer circumference of the ceramic tube 1. has been done. Note that this outer peripheral portion [5 is grounded.

前記画電極4.5間に介在する細孔2には外部電極5の
軸心方向長さにほぼ等しいステンレス製の中間電極6が
外部電極5と対応する位置に遊嵌配設されている。その
ため、この中間電極66両電極4.5に対して沿面距i
ll L iJ’ Bけられている。
An intermediate electrode 6 made of stainless steel and having approximately the same length in the axial direction as the external electrode 5 is loosely fitted into the hole 2 interposed between the picture electrodes 4 and 5 at a position corresponding to the external electrode 5. Therefore, the creepage distance i with respect to this intermediate electrode 66 and both electrodes 4.5 is
ll L iJ' B is kicked out.

なお、前記中間電極6はその両端が図示しない細孔2に
対し、細い絶縁支持部材6aにて支持され、細孔2に対
し遊挿状態にて保持されている(第1図においては一部
のみ図示)。
The intermediate electrode 6 is supported by a thin insulating support member 6a at both ends of the pore 2 (not shown), and is held loosely inserted into the pore 2 (partially shown in FIG. 1). (only shown).

次に、上記のように構成されたオゾン発生装置の作用に
ついて説明する。
Next, the operation of the ozone generator configured as described above will be explained.

中央都電4f14および外周電極5に交番電圧を印加す
ると、外周電極5はアース接地されているため、常に零
電位に保たれている。よって、外周部[i5の零電位に
対して中央部電極4が正の電位またはnの電位が印加さ
れる。
When an alternating voltage is applied to the Chuo Toden 4f14 and the outer electrode 5, the outer electrode 5 is always kept at zero potential because it is grounded. Therefore, a positive potential or a potential of n is applied to the central electrode 4 with respect to the zero potential of the outer peripheral part [i5.

第3図に示すように、中央部電極4の、優性が正の電位
となった場合、絶縁壁3の中央部電極・1側の表面には
分極作用により負の電荷が集まる。
As shown in FIG. 3, when the central electrode 4 has a dominantly positive potential, negative charges gather on the surface of the insulating wall 3 on the central electrode 1 side due to polarization.

方、その絶縁壁3の外周な極5側の表面には正の電荷が
集まる。また、これに伴って細孔2内に遊挿配設された
中間゛電極6の中央部電極4側の表面には負の電荷が集
まり、外周電J#!5側の表面には正の電荷が集まる。
On the other hand, positive charges gather on the outer circumferential surface of the insulating wall 3 on the pole 5 side. In addition, along with this, negative charges gather on the surface of the intermediate electrode 6 that is loosely inserted into the pore 2 on the center electrode 4 side, and the outer circumferential charge J#! Positive charges gather on the surface on the 5 side.

中央部′S極4の慢性が負の電位に変化したとき、中間
電極6は無声放電を行う。
When the potential of the central S pole 4 changes to a negative potential, the intermediate electrode 6 produces a silent discharge.

そして、中央部8極71の極性が負の電位となった場合
、各絶縁壁3および中間電極6は1lij記とは逆の分
極作用となり、中央部Z@t4の極性が正の電位に変化
したとき、中間電極6は無声放電を行う。
Then, when the polarity of the center 8 poles 71 becomes a negative potential, each insulating wall 3 and the intermediate electrode 6 have a polarization action opposite to that in 1lij, and the polarity of the center Z@t4 changes to a positive potential. At this time, the intermediate electrode 6 produces a silent discharge.

この無声放電の作用によって細孔2内の空気中の酸素が
オゾンに変換される。そのため、第1図に示すように空
気を細孔2内に流し込むことにより、オゾンを大量に発
生させることができる。
Oxygen in the air within the pores 2 is converted into ozone by the action of this silent discharge. Therefore, by flowing air into the pores 2 as shown in FIG. 1, a large amount of ozone can be generated.

オゾン発生装置の放電電力の90%以上が熱となるが、
セラミック管1を利用したことにより耐熱性が優れ、熱
の放射率もよく、熱によるセラミックの熱収縮率も極め
て小さいため、細孔2内の寸法精度を高度に保つことが
できる。その結果、寸法変化による電界の集中がなくな
るため、部分放電の発生を防止し、さらに、セラミック
管1によって放電熱が放出されるため、均等放電を持続
することができ、オゾンを効率よく発生させることがで
きる。
More than 90% of the discharge power of an ozone generator becomes heat,
By using the ceramic tube 1, it has excellent heat resistance, good heat emissivity, and the thermal shrinkage rate of ceramic due to heat is extremely small, so that a high degree of dimensional accuracy within the pores 2 can be maintained. As a result, there is no concentration of electric field due to dimensional changes, which prevents the occurrence of partial discharge.Furthermore, since discharge heat is released by the ceramic tube 1, uniform discharge can be sustained, and ozone can be generated efficiently. be able to.

また、中央都電I#!4をセラミック管lの中央のml
孔2に挿入したことにより、外周電極5に対し電界分布
が均一になるため、中間電極6群の無声放電を均一に発
生させることができ、オゾンを効率よく発生させること
ができる。そして、外周部[l!5、中間電極61¥に
それぞれ沿面距MLを設けたことにより、沿面放電が発
生して両型4124.5と中間型4Ii6群との短絡を
防止することができる。
Also, Chuo Toden I#! 4 to ml in the center of the ceramic tube l
By inserting it into the hole 2, the electric field distribution becomes uniform with respect to the outer peripheral electrode 5, so that silent discharge can be uniformly generated in the group of intermediate electrodes 6, and ozone can be generated efficiently. And the outer periphery [l! 5. By providing the creepage distance ML for each of the intermediate electrodes 61\, it is possible to prevent creepage discharge from occurring and shorting between the two molds 4124.5 and the intermediate molds 4Ii6 group.

絶縁壁3の厚さをできるだけ薄くすることにより、広い
放電面積を小さい空間に収めることができ、画電極4,
5間の距離か接近する。その結果、静電容量が増加し放
電電圧が高くなるため、効率よくオゾンを発生させるこ
とができる。しかも、セラミックの加工は近年椹めて容
易であるため、上記の要求を満たすことができる。
By making the thickness of the insulating wall 3 as thin as possible, a wide discharge area can be contained in a small space, and the picture electrodes 4,
Get close or within 5 degrees. As a result, the capacitance increases and the discharge voltage becomes higher, so that ozone can be efficiently generated. Moreover, since processing of ceramics has become easier in recent years, the above requirements can be met.

本実施例では、アルミナ磁器製のセラミック管lを使用
したが、無気孔タイプのセラミックでかつ、絶縁性の優
れたものであればよい、さらに、ステンレスを中間電極
6群に使用したが、無声放電による発熱に耐える導体で
あればよい。
In this example, a ceramic tube l made of alumina porcelain was used, but any material that is non-porous type ceramic and has excellent insulating properties may be used.Furthermore, stainless steel was used for the six groups of intermediate electrodes, but there was no sound. Any conductor that can withstand heat generated by discharge may be used.

なお、セラミック管1内に流し込む空気はできるだけ水
分含有量の少ない乾燥したものがよい。
Note that it is preferable that the air flowed into the ceramic tube 1 be dry with as little moisture content as possible.

また、空気の代わりに酸素を流し込むことも可能である
It is also possible to flow oxygen instead of air.

また、細孔2を角形状の形成したが、丸または多角形状
にすることも可能である。
Further, although the pores 2 are formed in a rectangular shape, they can also be formed in a round or polygonal shape.

なお、この発明は前記実施例に限定されるものではなく
、この発明の趣旨から逸脱しない範囲内で任意に変更す
ることも可能である。
It should be noted that the present invention is not limited to the above-mentioned embodiments, and may be modified as desired without departing from the spirit of the present invention.

[発明の効果コ 以上、訂述したように、絶縁性セラミック管を誘電体に
使用したことにより、放電熱によるセラミック管の熱収
縮率が極めて小さく、細孔内の寸法精度を高度に保つこ
とができ、電界の集中による部分放電を防止することが
できる。その結果、均等放電を持続せることかでき、オ
ゾンを人足に効率よく発生させることができるという効
果がある。
[Effects of the invention] As detailed above, by using an insulating ceramic tube as a dielectric material, the thermal contraction rate of the ceramic tube due to discharge heat is extremely small, and the dimensional accuracy within the pores can be maintained at a high level. This makes it possible to prevent partial discharge due to electric field concentration. As a result, uniform discharge can be sustained and ozone can be efficiently generated in the human foot.

【図面の簡単な説明】[Brief explanation of drawings]

第1〜3図は本発明を具体化した一実施例を示し、第1
図はオゾン発生装置の原理構成を示す一部切り欠き側面
図、第2図は第1図のA−A線断面図、第3図は中央部
電極の極性が正の電位となったときの絶縁壁および中間
電極群の分極作用を示す一部拡大図、第4図は従来例を
示す原理構成図である。 1・・・セラミック管、2・・・細孔、4・・・中央部
電極、5・・・外周電極、6・・・中間電極。 特許出願人   工ナジ〜サポート株式会社代 理 人
   弁理士    恩1)博宣+ 1位
1 to 3 show an embodiment embodying the present invention.
The figure is a partially cutaway side view showing the principle configuration of the ozone generator, Figure 2 is a cross-sectional view taken along the line A-A in Figure 1, and Figure 3 is a cross-sectional view taken along the line A-A in Figure 1. FIG. 4 is a partially enlarged view showing the polarization effect of the insulating wall and the intermediate electrode group, and is a diagram showing the principle configuration of a conventional example. DESCRIPTION OF SYMBOLS 1... Ceramic tube, 2... Pore, 4... Center electrode, 5... Outer electrode, 6... Intermediate electrode. Patent applicant Kounaji~Support Co., Ltd. Agent Patent attorney On 1) Hironobu + 1st place

Claims (1)

【特許請求の範囲】 1、複数の細孔が互いに並設して貫設された絶縁性セラ
ミック管と、 同絶縁性セラミック管のほぼ中央部の細孔に挿入された
中央部電極と、 同絶縁性セラミック管の外周部に配設され前記中央部電
極との間で交番電圧が印加される外周電極と、 前記両電極間に介在する細孔に遊挿配設した中間電極群
と から構成したことを特徴とするオゾン発生装置。
[Claims] 1. An insulating ceramic tube having a plurality of pores arranged in parallel with each other and a central electrode inserted into the pore approximately in the center of the insulating ceramic tube; Consisting of an outer electrode arranged on the outer periphery of the insulating ceramic tube and to which an alternating voltage is applied between it and the central electrode, and a group of intermediate electrodes loosely inserted into the pores interposed between the two electrodes. An ozone generator characterized by:
JP27531888A 1988-10-31 1988-10-31 Ozonizer Pending JPH02124703A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27531888A JPH02124703A (en) 1988-10-31 1988-10-31 Ozonizer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27531888A JPH02124703A (en) 1988-10-31 1988-10-31 Ozonizer

Publications (1)

Publication Number Publication Date
JPH02124703A true JPH02124703A (en) 1990-05-14

Family

ID=17553777

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27531888A Pending JPH02124703A (en) 1988-10-31 1988-10-31 Ozonizer

Country Status (1)

Country Link
JP (1) JPH02124703A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103693625A (en) * 2014-01-03 2014-04-02 袁良雄 Efficient and energy-saving ozone generator
WO2014156409A1 (en) * 2013-03-26 2014-10-02 日本碍子株式会社 Dielectric porcelain composition and composite ceramic structural body

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014156409A1 (en) * 2013-03-26 2014-10-02 日本碍子株式会社 Dielectric porcelain composition and composite ceramic structural body
JPWO2014156409A1 (en) * 2013-03-26 2017-02-16 日本碍子株式会社 Dielectric porcelain composition and composite ceramic structure
US9573851B2 (en) 2013-03-26 2017-02-21 Ngk Insulators, Ltd. Dielectric ceramic composition and composite ceramic structure
CN103693625A (en) * 2014-01-03 2014-04-02 袁良雄 Efficient and energy-saving ozone generator

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