JPH0148059B2 - - Google Patents
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- Publication number
- JPH0148059B2 JPH0148059B2 JP57062007A JP6200782A JPH0148059B2 JP H0148059 B2 JPH0148059 B2 JP H0148059B2 JP 57062007 A JP57062007 A JP 57062007A JP 6200782 A JP6200782 A JP 6200782A JP H0148059 B2 JPH0148059 B2 JP H0148059B2
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- Japan
- Prior art keywords
- tablet
- concrete
- expanding
- crushing
- expanding agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- Working Measures On Existing Buildindgs (AREA)
- Disintegrating Or Milling (AREA)
Description
本発明は、硬焼生石灰と水硬性物質を主成分と
する膨張剤(以下膨張剤という)の水和エネルギ
ーを利用して、コンクリート等を静的に破砕する
方法およびそれに用いる膨張錠剤に関するもので
ある。
コンクリート等の被破砕物に装填孔を穿設し、
この装填孔中に膨張剤を充填し、膨張剤の水和エ
ネルギーを利用してコンクリート等を静的に破砕
する方法が実用化されている。しかしながら一般
に市販されている膨張剤によるコンクリート等の
静的な破砕において膨張剤の適用温度範囲の上限
を越えて使用した場合(例えば商品名がプライス
ター200の場合、適用範囲が5〜15℃であるが、
15℃以上の温度で使用した場合)、また適用温度
範囲以内で使用したとしても、装填孔径が50mmφ
以上の場合には、水和エネルギーの内の熱エネル
ギーが装填孔内に充填された膨張剤内部に蓄積さ
れ、その熱エネルギーにより膨張剤内の水分の一
部が水蒸気化し、装填孔内の水蒸気圧が高まり、
充填された膨張剤が装填孔外に爆発的に突出し
(以下突出現象という)破砕効果が得られなくな
るばかりでなく、作業上非常に危険であるという
欠点がある。また膨張剤の水和反応は温度に非常
に大きく影響されるため、一品種の膨張剤の適用
温度範囲を大きくすることは困難で、年間を通じ
て気温変化の大きい国内においては、多品種の膨
張剤が必要となり(例えば商品面がブライスター
の場合、−5〜30℃の気温により四種類を使い分
ける)、このため生産、在庫、および使用上の管
理がしにくく、またコストが高くなるという欠点
がある。また品種の適用温度範囲の上限付近の気
温で使用していた場合、気温の変化の大きいとき
に適用温度範囲を越えて使用してしまうため、膨
張剤の突出現象を引き起こすことがしばしば起こ
り、このため破砕効果が得られないばかりでな
く、作業上非常に危険な状態になるという欠点が
ある。
このため突出現象を防止する方法として、特開
昭48−25337号、特開昭49−21924号に装填孔に膨
張剤を充填後、その上部に当たる部分にモルタル
または器具類によつて密栓をする方法が提案され
ているが、これらの方法では作業性が悪く、また
コストも高くなる欠点がある。
このほか、例えば特公昭49−43416号公報には、
生石灰に結合剤等を混合し加圧成形した円柱形
(径は孔径より小さく中心部にケーシングパイプ
挿入孔がある)の成形体を装填孔に挿入し、水お
よび水和反応遅延剤を注入し、さらに中心部に挿
入したケーシングパイプ内に電熱器を装置して通
電し、水和反応を起こさしめる破砕工法が提案さ
れている。この方法は成形体とすることにより、
膨張剤の充填の作業性が向上するが、電熱器の装
着、過熱等作業が繁雑で注水の作業性も悪かつ
た。
本発明は、このような欠点を改良し、膨張剤の
水和エネルギーを利用してコンクリート等の静的
破砕を有効かつ安全に行わせる方法とそれに用い
る膨張剤を提供するものであり、その特徴とする
ところは、硬焼生石灰と水硬性物質を主成分と
し、CaO成分を30〜98%含有する膨張剤を容積
0.05cm3〜10cm3で、かつ嵩比重2.3〜3.2に圧縮成形
してなる立体形の膨張錠剤を装填孔に充填した
後、水を注入することある。
次に本発明の実施態様を図面に従つて詳述す
る。第1図において、1はコンクリート等の被破
砕物であり、これに一定の間隔をおいて、一定の
長さで、一定の孔径の装填孔2を穿設し、その装
填孔2に膨張錠剤3を充填した後、装填孔2の孔
口4から水を注入して膨張錠剤3を水和膨張させ
て被破砕物1を破砕する。膨張錠剤3には硬焼生
石灰と水硬性物質を主成分としてCaO成分が30〜
98%の粉末状の膨張剤を原料とする。CaO成分が
30%以下では被破砕物を破砕するに必要な膨張圧
は得られず、またCaO成分が98%以上では突出現
象が発生する場合がある。
膨張錠剤3はあらかじめ粉末状の膨張剤をその
まま打錠機等で圧縮成形させることにより得られ
るが、特に成形性を良くするためには打錠成型助
剤(離型剤)等の潤たく剤を粉末状の膨張剤に混
合させることが望ましい。圧縮成形後、大きさ形
状を調整して用いてもよい。
膨張錠剤3の形状は装填孔2の孔口4から注入
する水が装填孔2の孔底5まで浸透分散しやす
く、また充填された膨張錠剤3が水の注入によつ
て始まる水和膨張反応で生じる水蒸気ガスを膨張
錠剤3が結晶成長する前に各々の膨張錠剤3の粒
子間の隙間を通つて、大気中に放出しやすいもの
が好ましく、例えば円柱体、長方体、円盤体およ
び多面体またはこれらのものの角のとれたものお
よび球体が良く、特に球体は表面積が最も小さい
ので各粒子間の空間が小さくとれるので、膨張錠
剤3の膨張圧を有効に利用でき最も望ましい。
膨張錠剤3は、装填孔2に充填する際の装填の
しやすさ、および装填孔2に充填された後の水和
膨張反応による膨張圧の関係および装填孔2の孔
径(一般に30〜100mmφ)等に条件が組み合わさ
れ最も破砕効果をあげるためには、膨張錠剤の容
積は0.05〜10cm3でなくてはならない。
粒子の大きさを0.05cm3以下にすると、突出現象
が起こりやすく、また10cm3以上にすると突出現象
は発生しないが、破砕効果が減少することにな
り、更に破砕時間も遅れがちとなる。
膨張錠剤3は取り扱うとき粒子が壊れにくい硬
さで、かつ装填孔2に充填された後、水を注入し
て水和膨張反応が始まり、初期の反応で生じた水
蒸気を膨張錠剤3の粒子間を通つて大気中に放出
されるまで、膨張錠剤3の形がこわれない硬さが
必要であり、このためには膨張錠剤3は嵩比重
2.3〜3.2でなくてはならない。膨張錠剤3の嵩比
重が2.3以下の場合には、取り扱い中に粒子がこ
われたり水和膨張の際の膨張圧が不足して、破砕
物1が完全に破砕されない。嵩比重が3.2以上の
場合は、膨張錠剤の製造および水の吸水性より好
ましくない。
本発明の方法によると被破砕物に充填された膨
張錠剤が、水和膨張時に発生する水蒸気を膨張錠
剤間の隙間を通つて大気中に放出することによ
り、膨張剤内部の水蒸気が増大することを防止
し、装填孔を50mmφ以上としても、また膨張剤の
適用温度範囲の上限を越えて使用したとしても、
充填された膨張剤が孔外に突出することがなく、
膨張剤の水和膨張エネルギーを有効に利用でき、
また従来の膨張剤のようにあらかじめ、膨張剤と
水を容器内で混合し、これを速やかに装填孔に充
填する作業がなくなり、水のみを装填孔に充填さ
れた膨張錠剤に注入すれば良いので、作業の効率
化および経済効果の大きい破砕作業が可能とな
り、かつ突出による危険を防止することができる
ため、作業上の安全性をより高める効果があり、
また破砕作業において、装填孔径50mmφ以上の大
きな孔径で膨張剤が使用できるため、一孔当たり
の膨張剤の充填量をより多く使用することがで
き、このため破砕力が増大するために孔の間隔を
大きく取れるので破砕に必要な孔数の削減が可能
となり、破砕作業を効率的かつ経済的にする効果
がある。また、膨張剤の適用範囲外の温度で使用
しても突出減少がなく破砕効果が得られるので、
一品種の膨張剤でより広い範囲の温度で使用でき
るため、多品種のものを容易する必要がなく、膨
張剤の生産、在庫および使用に当たつての管理が
効率的かつ経済的である。
以下実施例について説明を説明する。
実施例 1
無筋コンクリートブロツクに抵抗線の長さ60
cm、装填孔径60mmφ、さく孔長100cmを穿設した
ものを供試体とした。これに第1図a,b,cに
示す形状、サイズの実施例1、2、3の膨張錠剤
を装填孔に充填した後、水を膨張剤(膨張剤成分
は硬焼生石灰60%、水硬性物質40%)の重量比
で、20%注入し、膨張剤の突出現象およびコンク
リートの破砕状況を観察した。なお、比較のため
に膨張錠剤のサイズ、容積、嵩比重をかえた比較
例1、2、3、4、5および粉末状の膨張剤をあ
らかじめ容器内で水と混合した(重量比30%)比
較例6、粉末状の膨張剤、か粒状の膨張剤を装填
孔に直接充填した後、水を重量比で20%注入した
比較例7、8を行ない観察した。
その結果、膨張錠剤の形状、容積、嵩比重が突
出現象および%に与える効果が大きいことが判明
した。
The present invention relates to a method for statically crushing concrete, etc., using the hydration energy of an expanding agent (hereinafter referred to as an expanding agent) whose main components are hard calcined quicklime and a hydraulic substance, and an expanding tablet used therein. be. A loading hole is drilled into the material to be crushed such as concrete,
A method has been put into practical use in which the loading hole is filled with an expanding agent and the hydration energy of the expanding agent is used to statically crush concrete or the like. However, if a commercially available expanding agent is used for static crushing of concrete, etc., at temperatures exceeding the upper limit of the applicable temperature range of the expanding agent (for example, if the product name is Plaister 200, the applicable range is 5 to 15 degrees Celsius). Yes, but
(when used at temperatures above 15℃), and even when used within the applicable temperature range, the loading hole diameter is 50mmφ
In the above case, the thermal energy of the hydration energy is accumulated inside the expanding agent filled in the loading hole, and this thermal energy converts some of the water in the expanding agent into water vapor, causing water vapor in the loading hole. The pressure increases,
The filling expansion agent explosively protrudes outside the loading hole (hereinafter referred to as protrusion phenomenon), which not only makes it impossible to obtain a crushing effect, but also has the disadvantage that it is extremely dangerous to work with. Furthermore, since the hydration reaction of expanding agents is greatly affected by temperature, it is difficult to widen the applicable temperature range for one type of expanding agent. (For example, if the product is Blister, four types are used depending on the temperature from -5 to 30℃), which makes it difficult to manage production, inventory, and usage, and increases costs. be. In addition, if the product is used at temperatures near the upper limit of the applicable temperature range, it will be used beyond the applicable temperature range when there is a large change in temperature, which often causes the swelling agent to protrude. This has the disadvantage that not only is the crushing effect not achieved, but it is also extremely dangerous to work with. For this reason, as a method to prevent the protrusion phenomenon, after filling the loading hole with an expanding agent, the upper part of the loading hole is tightly plugged with mortar or instruments, as disclosed in Japanese Patent Application Laid-open Nos. 48-25337 and 49-21924. Although methods have been proposed, these methods have the drawbacks of poor workability and high costs. In addition, for example, in Japanese Patent Publication No. 49-43416,
A cylindrical shaped body (the diameter is smaller than the hole diameter and there is a casing pipe insertion hole in the center) made by mixing quicklime with a binder, etc. under pressure is inserted into the loading hole, and water and a hydration reaction retarder are injected. Furthermore, a crushing method has been proposed in which an electric heater is installed inside the casing pipe inserted into the center and electricity is applied to cause a hydration reaction. In this method, by forming a molded body,
Although the workability of filling the expansion agent was improved, work such as installing an electric heater and heating was complicated, and the workability of pouring water was also poor. The present invention aims to improve such drawbacks and provide a method for effectively and safely performing static crushing of concrete, etc. by utilizing the hydration energy of an expanding agent, and an expanding agent used therein. The main components are hard calcined quicklime and hydraulic substances, and an expanding agent containing 30 to 98% CaO component is added by volume.
After filling a loading hole with a three-dimensional expanded tablet formed by compression molding to a size of 0.05 cm 3 to 10 cm 3 and a bulk specific gravity of 2.3 to 3.2, water may be injected. Next, embodiments of the present invention will be described in detail with reference to the drawings. In Fig. 1, reference numeral 1 denotes a material to be crushed such as concrete, into which loading holes 2 of a constant length and diameter are bored at regular intervals, and expanded tablets are inserted into the loading holes 2. 3, water is injected from the opening 4 of the loading hole 2 to hydrate and expand the expandable tablet 3, thereby crushing the object 1 to be crushed. Expandable tablet 3 contains hard calcined lime and hydraulic substances as main components, and CaO content is 30 to 30%.
The raw material is 98% powdered swelling agent. CaO component
If the CaO content is less than 30%, the expansion pressure necessary to crush the object to be crushed cannot be obtained, and if the CaO content is more than 98%, a protrusion phenomenon may occur. Expandable tablet 3 can be obtained by compression-molding a powdered expanding agent as it is in a tablet machine, etc., but in order to particularly improve the moldability, a moistening agent such as a tablet-forming aid (mold release agent) is added. It is desirable to mix the powder with the expanding agent. After compression molding, the size and shape may be adjusted before use. The shape of the expandable tablet 3 is such that water injected from the opening 4 of the loading hole 2 can easily permeate and disperse to the bottom 5 of the loading hole 2, and the filled expandable tablet 3 undergoes a hydration expansion reaction that starts when water is injected. It is preferable that the water vapor gas generated in the expansion tablet 3 can be easily released into the atmosphere through the gaps between the particles of each expansion tablet 3 before the expansion tablet 3 undergoes crystal growth, such as a cylinder, a rectangle, a disk, and a polyhedron. Or, of these, rounded corners and spheres are preferable; in particular, spheres have the smallest surface area, so the space between each particle can be kept small, and the expansion pressure of the expansion tablet 3 can be effectively used, which is most desirable. The expandable tablet 3 is characterized by the ease of loading when filling the loading hole 2, the relationship between the expansion pressure due to the hydration expansion reaction after being filled into the loading hole 2, and the hole diameter of the loading hole 2 (generally 30 to 100 mmφ). In order to obtain the best crushing effect by combining these conditions, the volume of the expanded tablet must be 0.05 to 10 cm 3 . If the particle size is 0.05 cm 3 or less, the protrusion phenomenon tends to occur, and if the particle size is 10 cm 3 or more, the protrusion phenomenon will not occur, but the crushing effect will be reduced and the crushing time will also tend to be delayed. The expanding tablet 3 has a hardness that makes the particles difficult to break when handled, and after filling the loading hole 2, water is injected to start the hydration expansion reaction, and the water vapor generated in the initial reaction is transferred between the particles of the expanding tablet 3. It is necessary that the expandable tablet 3 has a hardness that does not break its shape until it is released into the atmosphere.
Must be between 2.3 and 3.2. If the bulk specific gravity of the expanded tablet 3 is 2.3 or less, the particles may break during handling or the expansion pressure during hydration expansion may be insufficient, and the crushed product 1 will not be completely crushed. If the bulk specific gravity is 3.2 or more, it is not preferable for the production of expanded tablets and for water absorption. According to the method of the present invention, the expanded tablets filled in the material to be crushed release the water vapor generated during hydration and expansion into the atmosphere through the gaps between the expanded tablets, thereby increasing the water vapor inside the expanding agent. Even if the loading hole is 50mmφ or more, or if the expanding agent is used beyond the upper limit of the applicable temperature range,
The filled swelling agent does not protrude outside the hole,
The hydration expansion energy of the swelling agent can be used effectively,
In addition, unlike conventional expanding agents, there is no need to mix the expanding agent and water in a container in advance and immediately fill the loading hole with the mixture; instead, only water can be injected into the expanding tablet filled in the loading hole. Therefore, it is possible to perform crushing work with greater work efficiency and economical effects, and it is also possible to prevent dangers due to protrusion, which has the effect of further increasing work safety.
In addition, during crushing work, because the expanding agent can be used in large holes with a charging hole diameter of 50 mm or more, it is possible to use a larger amount of expanding agent per hole, which increases the crushing force and increases the distance between the holes. Since it is possible to obtain a large number of holes, it is possible to reduce the number of holes required for crushing, which has the effect of making crushing work efficient and economical. In addition, even when used at temperatures outside the applicable range of the expansion agent, there is no reduction in protrusion and a crushing effect is obtained.
Since one type of expanding agent can be used in a wider temperature range, there is no need to use multiple types of expanding agents, and the management of the production, inventory, and use of the expanding agent is efficient and economical. Examples will be explained below. Example 1 Resistance wire length 60 on unreinforced concrete block
The specimen was made with a hole diameter of 60 mmφ, a hole length of 100 cm, and a hole diameter of 60 mm. After filling the loading holes with expanded tablets of Examples 1, 2, and 3 having the shapes and sizes shown in Figure 1 a, b, and c, water was added as an expanding agent (expanding agent components were 60% hard calcined lime, water 20% hard material (40%) was injected by weight, and the protrusion phenomenon of the expanding agent and the crushing condition of the concrete were observed. For comparison, Comparative Examples 1, 2, 3, 4, and 5 in which the size, volume, and bulk specific gravity of the expanding tablets were changed, and a powdered expanding agent were mixed with water in a container in advance (weight ratio 30%). Comparative Example 6, Comparative Examples 7 and 8 were carried out and observed in which a powdered swelling agent or a granular swelling agent was directly filled into the loading hole, and then water was injected at 20% by weight. As a result, it was found that the shape, volume, and bulk specific gravity of the expanded tablet had a large effect on the protrusion phenomenon and percentage.
【表】
※2:粉末の膨張剤の装填孔に直接充填した後、水
を注入したもの。
※3:か粒状の膨張剤を装填孔に直接充填した後、
水を注入したもの。
実施例 2
無筋コンクリートに抵抗線の長さ65mm、装填孔
径60mmφ、さく孔長90cmを穿設したものを供試体
とした。これに表2に示す膨張錠剤(形状:円柱
体、容積6.0cm3、嵩比重:2.8)を装填孔に充填し
た後、水を膨張錠剤の重量比で20%注入し、膨張
錠剤の硬焼生石灰と水硬性物質との成分比と膨張
錠剤の突出現象およびコンクリートの破砕状況を
観察した(実施例4、5、6)。同時に硬焼生石
灰100%、および硬焼生石灰と水硬性物質比が
25/75の膨張錠剤を用いた比較例9、10を行ない
観察した。その結果、膨張錠剤の成分の硬焼生石
灰および水硬性物質が突出防止およびコンクリー
トの破砕に与える効果が大きいことが判つた。[Table] *2: Powdered swelling agent is directly filled into the loading hole and then water is injected.
*3: After filling the granular expansion agent directly into the loading hole,
Injected with water.
Example 2 A test specimen was prepared by drilling a resistance wire length of 65 mm, a loading hole diameter of 60 mmφ, and a drilling hole length of 90 cm in unreinforced concrete. After filling the loading hole with the expanded tablet shown in Table 2 (shape: cylindrical, volume 6.0 cm 3 , bulk specific gravity: 2.8), water was injected at 20% by weight of the expanded tablet, and the expanded tablet was hard-burned. The component ratio of quicklime and hydraulic substance, the protrusion phenomenon of expanded tablets, and the crushing condition of concrete were observed (Examples 4, 5, and 6). At the same time, 100% hard-burned quicklime, and the ratio of hard-burnt quicklime to hydraulic substances is
Comparative Examples 9 and 10 using 25/75 expanded tablets were conducted and observed. As a result, it was found that the components of the expanded tablet, hard calcined lime and hydraulic substances, had a great effect on preventing extrusion and crushing concrete.
【表】【table】
第1図は本発明に係るコンクリート等の静的破
砕方法の一実施態様の断面図、第2図a,b,c
はそれぞれ実施例の円柱体、円盤体、球体形態の
膨張錠剤の平面図、側面図である。
1……コンクリート等の被破砕物、2……装填
孔、3……膨張錠剤、4……装填孔2の孔口、5
……装填孔2の孔底。
Fig. 1 is a sectional view of an embodiment of the static crushing method for concrete, etc. according to the present invention, Fig. 2 a, b, c
These are a plan view and a side view of expansible tablets in the form of cylinders, discs, and spheres, respectively, according to Examples. 1... Material to be crushed such as concrete, 2... Loading hole, 3... Expandable tablet, 4... Hole opening of loading hole 2, 5
...Bottom of loading hole 2.
Claims (1)
ート等の被破砕物を静的に破砕するにあたり、硬
焼生石灰と水硬性物質を主成分とし、CaO成分を
30〜98%含有する膨張剤を容積0.05cm3〜10cm3で、
かつ嵩比重2.3〜3.2に圧縮成形してなる立体形の
膨張錠剤を装填孔に充填した後、水を注入するこ
とを特徴とするコンクリート等の静的破砕方法。 2 硬焼石灰と水硬性物質を主成分とし、CaO成
分を30〜98%含有する膨張剤を容積0.05cm3〜10cm3
で、かつ嵩比重2.3〜3.2の立体形に圧縮成形して
なるコンクリート等の静的破砕用膨張錠剤。 3 該膨張錠剤の形状が円柱体、長方体、円盤体
および多面体またはこれらのものの角のとれたも
の、および球体からなることを特徴とする特許請
求の範囲第2項記載の静的破砕用膨張錠剤。[Scope of Claims] 1. When statically crushing objects such as concrete using the hydration energy of an expanding agent, the main components are hard calcined quicklime and a hydraulic substance, and the CaO component is
A volume of 0.05 cm 3 to 10 cm 3 of swelling agent containing 30 to 98%,
A method for static crushing of concrete, etc., characterized by filling a loading hole with a three-dimensional expanded tablet formed by compression molding and having a bulk specific gravity of 2.3 to 3.2, and then injecting water. 2 A volume of 0.05 cm 3 to 10 cm 3 of an expanding agent whose main components are hard calcined lime and hydraulic substances and contains 30 to 98% CaO component.
Expandable tablets for static crushing of concrete, etc., which are compression-molded into a three-dimensional shape with a bulk specific gravity of 2.3 to 3.2. 3. For static crushing according to claim 2, wherein the shape of the expandable tablet is a cylinder, a rectangle, a disc, a polyhedron, or one of these with rounded corners, and a sphere. Expanding tablets.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6200782A JPS58180245A (en) | 1982-04-14 | 1982-04-14 | Static crushing of concrete and expanding tablet |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6200782A JPS58180245A (en) | 1982-04-14 | 1982-04-14 | Static crushing of concrete and expanding tablet |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS58180245A JPS58180245A (en) | 1983-10-21 |
JPH0148059B2 true JPH0148059B2 (en) | 1989-10-17 |
Family
ID=13187662
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6200782A Granted JPS58180245A (en) | 1982-04-14 | 1982-04-14 | Static crushing of concrete and expanding tablet |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS58180245A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5945379A (en) * | 1982-09-07 | 1984-03-14 | Denki Kagaku Kogyo Kk | Agent for disintegrating brittle material, and method for disintegration using the same |
JPS6013172A (en) * | 1983-07-04 | 1985-01-23 | 旭化成株式会社 | Static destruction of concrete and expansion tablet |
JPS62195074A (en) * | 1986-02-21 | 1987-08-27 | Ube Ind Ltd | Static crushing agent and its manufacturing method |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4943416A (en) * | 1972-08-31 | 1974-04-24 | ||
JPS5667059A (en) * | 1979-11-01 | 1981-06-05 | Onoda Cement Co Ltd | Destroying agent for brittle matter |
-
1982
- 1982-04-14 JP JP6200782A patent/JPS58180245A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4943416A (en) * | 1972-08-31 | 1974-04-24 | ||
JPS5667059A (en) * | 1979-11-01 | 1981-06-05 | Onoda Cement Co Ltd | Destroying agent for brittle matter |
Also Published As
Publication number | Publication date |
---|---|
JPS58180245A (en) | 1983-10-21 |
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