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JPH01225533A - Sandwich fiber-reinforced plastic molded products and automobile parts made of sandwich fiber-reinforced plastics - Google Patents

Sandwich fiber-reinforced plastic molded products and automobile parts made of sandwich fiber-reinforced plastics

Info

Publication number
JPH01225533A
JPH01225533A JP63050784A JP5078488A JPH01225533A JP H01225533 A JPH01225533 A JP H01225533A JP 63050784 A JP63050784 A JP 63050784A JP 5078488 A JP5078488 A JP 5078488A JP H01225533 A JPH01225533 A JP H01225533A
Authority
JP
Japan
Prior art keywords
smc
glass fiber
specific gravity
lightweight filler
fiber reinforcing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63050784A
Other languages
Japanese (ja)
Inventor
Yoshiro Kimura
吉朗 木村
Akiyoshi Yamada
山田 章義
Kiyotaka Nakai
清隆 中井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DIC Corp
Aisin Corp
Original Assignee
Aisin Seiki Co Ltd
Dainippon Ink and Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aisin Seiki Co Ltd, Dainippon Ink and Chemicals Co Ltd filed Critical Aisin Seiki Co Ltd
Priority to JP63050784A priority Critical patent/JPH01225533A/en
Publication of JPH01225533A publication Critical patent/JPH01225533A/en
Pending legal-status Critical Current

Links

Landscapes

  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

PURPOSE:To achieve the wt. reduction of SMC and the enhancement of rigidity thereof, by constituting a surface material of SMC containing a glass fiber reinforcing material while constituting a core material of SMC containing a hollow lightweight filler. CONSTITUTION:Low specific gravity SMC is used as a core material and high strength SMC is used as a surface material to constitute a sandwich structure. The high strength SMC is formed by impregnating a glass fiber reinforcing material with a thermosetting resin and has bending modulus of elasticity of 1200kg/mm<2> or more and contains 30vol.% or more of the glass fiber reinforcing material. When the content of the glass fiber reinforcing material is below 30vol.%, the high strength of a molded product is hardly developed and the content of said glass fiber reinforcing material is pref. set to 35-55vol.%. The low specific gravity SMC is one formed by impregnating the glass fiber reinforcing material with a resin paste wherein a hollow lightweight filler and a thermosetting resin are blended and having specific gravity of 0.8-1.5 and contains 15vol.% or more of the hollow lightweight filler. When the hollow lightweight filler is below 15vol.%, the lowering of the specific gravity of the molded product is hardly developed and the content of said hollow lightweight filler is set to 20-50vol.%.

Description

【発明の詳細な説明】 「産業上の利用分野」 本発明は、表面材がガラス繊維強化材を30体積%以上
含有するシートモールディングコンパウンドで構成され
るとともに、芯材が中空状の軽量充填剤を15体積%以
上含有するシートモールディングコンパウンドで構成さ
れていることを特徴とする軽量・高強度なサンドイッチ
繊維強化プラスチックス成形品およびこのサンドイッチ
繊維強化プラスチックス製の自動車部品に関するもので
ある。
Detailed Description of the Invention "Industrial Application Field" The present invention is a sheet molding compound in which the surface material is composed of a sheet molding compound containing 30% by volume or more of glass fiber reinforcement, and the core material is a hollow lightweight filler. The present invention relates to a lightweight, high-strength sandwich fiber-reinforced plastic molded product characterized by being composed of a sheet molding compound containing 15% by volume or more of

「従来の技術」 周知のように、繊維強化プラスチックス(以下、FRP
と略す)は金属(特に鉄)に比べ、軽量で強度、耐蝕性
に優れる等多くの特徴を有しており、バスタブ、浄化槽
、パイプ、ボート、いす、各種自動車部品等、多岐に亘
って使用されている。FRPの成形方法には多くの種類
があるか、その1つにプレス成形法がある。これは、予
め所定の温度に加熱されたプレス用金型内にFRP材料
を投人し、加圧、硬化させる方法であり、FrjPl料
として、液状樹脂を用いる場合と、バルクモールディン
グコンパウド、シートモールディングコンパウンドC以
下、SMCと略す)等の成形材料を用いる場合とがある
。なかでも、SMC等の成形材料を用いたプレス成形法
は、材料ロスが少ない、生産性が高い、作業環境が良い
等、他のFRP成形注形法べ多くの長所を有し、FII
P成形品の生産に広く用いられている。
``Conventional technology'' As is well known, fiber reinforced plastics (hereinafter referred to as FRP)
) has many characteristics compared to metals (especially iron), such as being lighter, stronger, and more corrosion resistant, and is used in a wide variety of products such as bathtubs, septic tanks, pipes, boats, chairs, and various automobile parts. has been done. There are many types of FRP molding methods, one of which is press molding. This is a method in which the FRP material is poured into a press mold that has been heated to a predetermined temperature, and is then pressurized and hardened.This method is used in cases where liquid resin is used as the FrjPl material, bulk molding compound, and sheet molding. A molding material such as Compound C (hereinafter abbreviated as SMC) may be used. Among these, the press molding method using molding materials such as SMC has many advantages over other FRP molding and casting methods, such as less material loss, high productivity, and a good working environment.
Widely used in the production of P molded products.

「発明が解決しようとする課題」 S M C等の成形材料は、前記の様に多くの長所を有
しているが、アルミニウム等の軽金属よりも比剛性に劣
るため比剛性を要する分野に用いにくく、例えば剛性設
計されている自動車の内、外装部品、例えば、オーバー
フェンダ−、エアスポイラ−等の外装部品、及び、サン
ルーフハウジング、スライディングルーフパネル等の内
装部品のSMC化を図る場合、軽量化メリットがでない
という問題点がある。
``Problem to be solved by the invention'' Molding materials such as SMC have many advantages as mentioned above, but they are inferior in specific rigidity to light metals such as aluminum, so they cannot be used in fields that require specific rigidity. For example, when using SMC for exterior parts such as over fenders and air spoilers, and interior parts such as sunroof housings and sliding roof panels, there is a weight reduction advantage. There is a problem that there is no

そこで、従来より、SMCの軽量化や高剛性化を図り、
比剛性を高める検討がなされている。SMCの軽量化方
法としては、中空状の軽量充填剤を用いる方法が知られ
ているが、この場合、軽量化を図る以上に、機械的特性
(強度、弾性率)の低下が粁しくなるという欠点があり
、アルミニウム並の比剛性を有するまでには至っていな
い。又、このような低比重SMCは、ハジキ、ピンポー
ル、ブリスタ性等の塗装性にも問題があるため、自動車
外装部品への適用は困難である。一方、SMCの高剛性
化には、ガラス繊維強化材含有率を高めろ方法が知られ
ているが、高剛性化を図る以上に比重が高くなるという
欠点があり、これも又、アルミニウム並の比剛性を有す
るまでには至っていない。強化材として、ガラス繊維よ
りら軽量でしかも高張力な、カーボン繊維、アラミド繊
維等を用いれば、アルミニウム以上の比剛性を存するこ
とら可能であるが、価格的実用性に難がある。
Therefore, we have been trying to make SMC lighter and more rigid,
Studies are being conducted to increase the specific stiffness. A known method for reducing the weight of SMC is to use hollow lightweight fillers, but in this case, it is said that mechanical properties (strength, elastic modulus) deteriorate more than the weight reduction. It has some drawbacks and does not have a specific rigidity comparable to that of aluminum. In addition, such low specific gravity SMC has problems in paintability such as repellency, pin-pole and blister properties, so it is difficult to apply it to automobile exterior parts. On the other hand, to increase the rigidity of SMC, there is a known method of increasing the content of glass fiber reinforcement, but this method has the disadvantage that the specific gravity becomes higher than increasing the rigidity. It has not reached the point where it has specific stiffness. It is possible to use carbon fiber, aramid fiber, or the like, which is lighter than glass fiber and has higher tensile strength, as the reinforcing material because it has a specific rigidity higher than that of aluminum, but this is not practical in terms of price.

「課題を解決するための手段」 本発明者等は、この様な状況に鑑み脱色研究した結果、
低比重SMCを芯材とし、高強度S M Cを表面材と
してサントイブチ状に構成するこさ1こより、上記の如
き欠点が解消できることを見い出し、本発明を完成する
に至った。すなわち、本発明は、表面材がガラス繊維強
化材を30体積%以上含有するSMCで構成されるとと
もに、芯材が中空状の軽量充填剤を15体積%以上含有
するSMCで構成されていることを特徴とする軽量でし
かも高強度なサンドイッチFRP成形品を提供するもの
である。
"Means for solving the problem" As a result of research on decolorization in view of the above situation, the present inventors found that
It has been discovered that the above-mentioned drawbacks can be overcome by constructing the product in the form of a sandbar, using low specific gravity SMC as the core material and high-strength SMC as the surface material, leading to the completion of the present invention. That is, in the present invention, the surface material is composed of SMC containing 30% by volume or more of glass fiber reinforcement, and the core material is composed of SMC containing 15% by volume or more of hollow lightweight filler. The present invention provides a lightweight and high-strength sandwich FRP molded product characterized by the following.

本発明で用いる高強度SMCは、ガラス繊維強化材に熱
硬化性樹脂を含浸してなる、好ましくは曲げ弾性率12
00 kg/ mm”以上のもので、ガラス繊維強化材
を30体積%以上含有するものである。この場合、ガラ
ス繊維強化材含有率が30体積形未満のSMCを表面材
として用いた場合、サンドイッチFRP成形品の高強度
化は発現し難く、好ましくは、ガラス繊維強化材含有率
が35〜55体積%のSMCである。
The high-strength SMC used in the present invention is made by impregnating a glass fiber reinforced material with a thermosetting resin, and preferably has a flexural modulus of 12.
00 kg/mm" or more, and contains glass fiber reinforcement of 30% or more by volume. In this case, if SMC with a glass fiber reinforcement content of less than 30% by volume is used as the surface material, the sandwich It is difficult to increase the strength of FRP molded products, and SMC with a glass fiber reinforcement content of 35 to 55% by volume is preferable.

また、本発明で用いる低比重SMCは、ガラス繊維強化
材に中空状の軽量充填剤と熱硬化性樹脂を混合した樹脂
ペーストを含浸してなる、好ましくは比重0.8〜1.
5のもので、中空状の軽量充填剤を!5体積%以上含有
する−ものである。中空状の軽量充填剤15体積%未満
のSMCを芯材として用いた場合、サンドイッチFRP
成形品の低比重化は発現し難<、好ましくは、中空状の
軽量充填剤含有率が20〜50体積%のSMCである。
Further, the low specific gravity SMC used in the present invention is formed by impregnating a glass fiber reinforced material with a resin paste in which a hollow lightweight filler and a thermosetting resin are mixed, and preferably has a specific gravity of 0.8 to 1.
5, a hollow lightweight filler! Contains 5% by volume or more. When SMC with a hollow lightweight filler of less than 15% by volume is used as a core material, sandwich FRP
It is difficult to reduce the specific gravity of the molded product, and preferably SMC has a hollow lightweight filler content of 20 to 50% by volume.

ここで、ガラス繊維強化材とは、チョツプドストランド
マット、ガラスクロス、ロービングクロス等のシート状
の繊維強化材及びチョツプドストランドであり、好まし
くは、繊維長か1/2〜2インチのチョツプドガラスス
トランドである。
Here, the glass fiber reinforced material refers to sheet-like fiber reinforced materials such as chopped strand mats, glass cloth, roving cloth, and chopped strands, and preferably has a fiber length of 1/2 to 2 inches. It is chopped glass strand.

また、中空状の軽量充填剤とは、好ましくは比重0.1
〜0,7の微小なプラスチック、ガラス等の中空体であ
り、好ましくは、100 kg/ cm”以上の耐圧強
度を有するガラス中空体である。
Further, the hollow lightweight filler preferably has a specific gravity of 0.1.
It is a hollow body made of plastic, glass, etc., which has a pressure resistance of 100 kg/cm" or more, preferably a glass hollow body having a pressure resistance of 100 kg/cm" or more.

さらに、熱硬化性樹脂としては、例えば、マトリクス樹
脂として、不飽和ポリエステル樹脂、ビニルエステル樹
脂、エポキシ樹脂、アクリル樹脂、フェノール樹脂等を
用いることができる。また、これら樹脂中には、充填剤
、低収縮化剤、顔料、離型剤、硬化剤、硬化促進剤、増
粘剤及びその他公知の添加剤等を混合することができる
Further, as the thermosetting resin, for example, unsaturated polyester resin, vinyl ester resin, epoxy resin, acrylic resin, phenol resin, etc. can be used as the matrix resin. In addition, fillers, low-shrinkage agents, pigments, mold release agents, curing agents, curing accelerators, thickeners, and other known additives can be mixed into these resins.

本発明で用いるSMCは、従来公知の製造方法で容易に
製造することができる。本発明のサンドイッチFRP成
形品の製造方法としては、例えば所定の寸法に裁断した
SMCを、高強度SMC/低比重SMC/高強度SMC
のように、サンドイッチ状に重ね合わせたものをプレス
成形することにより、容易に得られるものである。プレ
ス成形条件は、通常のSMCプレス成形条件と同様に、
温度が40〜180℃、圧力が10〜200kg/am
”、加圧時間が1〜60分間の範囲であるが、使用する
SMCの配合組成、成形品の形状・大きさ等により適宜
選定できる。
The SMC used in the present invention can be easily manufactured by a conventionally known manufacturing method. As a method for manufacturing the sandwich FRP molded product of the present invention, for example, SMC cut into predetermined dimensions is cut into high strength SMC/low specific gravity SMC/high strength SMC.
It can be easily obtained by press-molding a sandwich-like structure. Press molding conditions are the same as normal SMC press molding conditions,
Temperature is 40~180℃, pressure is 10~200kg/am
"The pressing time is in the range of 1 to 60 minutes, and can be appropriately selected depending on the composition of the SMC used, the shape and size of the molded product, etc.

また、本発明の自動車部品とは、例えばオーバーフェン
ダ−、エアスポイラ−等の外装部品、サンルーフハウジ
ング、スライディングルーフパネル等の内装部品である
。この自動車部品としての性能は、その比剛性がアルミ
ニウムより優れたもの、即ち比剛性3rE/ρ=7.1
5以上であることが望ましい。
Further, the automobile parts of the present invention include, for example, exterior parts such as over fenders and air spoilers, and interior parts such as sunroof housings and sliding roof panels. The performance as an automobile part is that its specific rigidity is superior to that of aluminum, that is, the specific rigidity is 3rE/ρ=7.1
It is desirable that it is 5 or more.

「作用」 前記構成によれば、従来のSMCに比べて軽量性、機械
的特性において大幅な改善がなされており、アルミニウ
ムよりも比剛性及び成形自由性に優れ、自動車の内・外
装部品、さらには住宅用パネル、ハウジング類、工業部
品、レジャー用品、電子・電気機器部品等多岐に亘って
使用することができる。
"Function" According to the above structure, it has been significantly improved in lightness and mechanical properties compared to conventional SMC, and has better specific rigidity and moldability than aluminum, and is suitable for use in interior and exterior parts of automobiles, as well as It can be used in a wide variety of applications such as housing panels, housings, industrial parts, leisure goods, electronic and electrical equipment parts, etc.

「実施例」 以下、実施例に基づいて、本発明を具体的に説明する。"Example" The present invention will be specifically described below based on Examples.

(実施例−1) 表−1に示す高強度S M C(B )と低比重SMC
(E)をそれぞれ250X250mm寸法に切断し、第
1図に示すように、高強度SMC(B)1枚/低比重S
MC(E)2枚/高強度SMC(B)1枚の構成で重ね
合わせたものを、300X300mm平板成形用金型に
投入し、温度140℃、加圧カフ0トン、加圧時間3分
間の条件でプレス成形を行い、厚み約3.5mmの平板
成形品を得た。なお、第1図中、符号Iは高強度SMC
を示し、2は低比重SMCを示すものである。
(Example-1) High strength SMC (B) and low specific gravity SMC shown in Table-1
(E) was cut into 250 x 250 mm dimensions, and as shown in Figure 1, 1 piece of high strength SMC (B) / 1 piece of low specific gravity S
A stack of two MC (E) sheets and one high-strength SMC (B) sheet was put into a 300 x 300 mm flat plate mold, and heated at a temperature of 140°C, a pressure cuff of 0 tons, and a pressure time of 3 minutes. Press molding was performed under the following conditions to obtain a flat plate molded product with a thickness of about 3.5 mm. In addition, in Fig. 1, the symbol I indicates high-strength SMC.
2 indicates low specific gravity SMC.

(実施例−2) 表−1に示す高強度SMC(C)と低比重SMC(F)
を実施例−1と同様にしてプレス成形を行い、厚み約3
.5mmの平板成形品を得た。 ・(実施例−3) 表−1に示す高強度SMC(C)と低比重SMC(F)
を920X490mmの基本寸法に裁断し、実施例−1
と同様の構成で重ね合わせたものを用いて、第2図に平
面図を示す自動車のサンルーフハウジング(一般肉厚3
 mm)を成形した。サンルーフハウジングとは、自動
車用サンルーフの機構部品を取り付けるためのベースに
なる部品であり、軽重で高剛性であることを必要として
いる。この時の成形条件は、金型温度が(上型)146
℃、(下型)142℃、加圧力450トン、加圧時間3
分間、チャージff14.6kgであった。この成形品
の製品重量は、鉄インサート1.6kgを含めて6.2
kgであり、一般SMC(比重1.82)が7 、1 
kgであったのに比べかなり軽量化が図れた。
(Example-2) High strength SMC (C) and low specific gravity SMC (F) shown in Table-1
was press-formed in the same manner as in Example-1, and the thickness was approximately 3 mm.
.. A 5 mm flat plate molded product was obtained.・(Example-3) High strength SMC (C) and low specific gravity SMC (F) shown in Table-1
Example 1 was cut into basic dimensions of 920 x 490 mm.
A car sunroof housing (general wall thickness 3
mm) was molded. A sunroof housing is a component that serves as a base for attaching the mechanical components of an automobile sunroof, and must be light, heavy, and highly rigid. The molding conditions at this time are that the mold temperature (upper mold) is 146
℃, (lower mold) 142℃, pressurizing force 450 tons, pressurizing time 3
The charge ff was 14.6 kg per minute. The product weight of this molded product is 6.2 kg including the iron insert 1.6 kg.
kg, and the general SMC (specific gravity 1.82) is 7,1
The weight was considerably reduced compared to the original weight of 1 kg.

(比較例−1) 表−Iに示す高強度SMC(A)と低比重SMC(E)
を実施例−1と同様にしてプレス成形を行い、厚み約3
.5mmの平板成形品を得た。
(Comparative Example-1) High strength SMC (A) and low specific gravity SMC (E) shown in Table-I
was press-formed in the same manner as in Example-1, and the thickness was approximately 3 mm.
.. A 5 mm flat plate molded product was obtained.

(比較例−2) 表−1に示す高強度S M C(B )と低比重SMC
(D)を実施例−1と同様にしてプレス成形を行い、厚
み約3.5mmの平板成形品を得た。
(Comparative Example-2) High strength SMC (B) and low specific gravity SMC shown in Table-1
(D) was press-molded in the same manner as in Example-1 to obtain a flat plate molded product with a thickness of about 3.5 mm.

(比較例−3) 表−■に示す高4強度SMC(A)と低比重SMC(E
)を920X490II+llの基本寸法に裁断したも
のを用いて、実施例−3と同様にしてサンルーフハウジ
ングを成形した。この成形品の製品重量は、鉄インサー
ト1.6kgを含めて5.9kgであり、−般SMC(
比重1.82)が7 、1 kgであったのに比べ、か
なり軽量化が図れた。しかしながら、成形後に金型から
成形品を脱型した際、すでに割れ欠け等の欠陥か発生し
ており非常にこわれ易いものであった。
(Comparative Example-3) High 4 strength SMC (A) and low specific gravity SMC (E
) was cut into basic dimensions of 920 x 490 II+ll, and a sunroof housing was molded in the same manner as in Example-3. The product weight of this molded product is 5.9 kg including the iron insert of 1.6 kg.
Compared to the 7.1 kg specific gravity (1.82), the weight was considerably reduced. However, when the molded product was removed from the mold after molding, defects such as cracking and chipping had already occurred, making it extremely fragile.

〈物性試験〉 次に、前記実施例−■、−2、−3及び比較例−1、−
2、−3の成形品より、25X60mmのテストピース
を、平板成形品の場合は端部50mmを除く中央部から
、10個切り出し、サンルーフハウジングの場合は第2
図に示す位置から17個切り出して、曲げ強さ、曲げ弾
性率(flS  K−7203に準拠)と比重(JIS
  K−7112に帛拠)を測定した。その各平均値を
表2に示したか、本発明のサンドイッチFRP成形品は
、これまでのFRP成形品の軽量性、機賊的特性におけ
る欠点を大幅に改善しており、アルミニウムよりら比強
度、比剛性に優れているものであった。
<Physical property test> Next, the above Examples -■, -2, -3 and Comparative Examples -1, -
From the molded product 2 and -3, cut out 10 test pieces of 25 x 60 mm from the center excluding 50 mm of the edges in the case of a flat molded product.
Cut out 17 pieces from the positions shown in the figure, and measure their bending strength, bending modulus (based on flS K-7203), and specific gravity (JIS
(based on K-7112) was measured. The average values of each are shown in Table 2. The sandwich FRP molded product of the present invention has significantly improved the drawbacks of conventional FRP molded products in terms of lightness and mechanical properties, and has a higher specific strength and strength than aluminum. It had excellent specific rigidity.

「発明の効果」 本発明のサンドイッチF、RP成形品はこれまでの方法
の経用性、機械的特性における欠点を大幅に改善してお
り、アルミニウムよりも比剛性及び成形自由性に優れ、
自動車の内・外装部品、さらには住宅用パネル、ハウジ
ング類、工業部品、レジャー用品、電子−電気機器部品
等多岐に亘って使用することができる。
"Effects of the Invention" The sandwich F and RP molded products of the present invention have significantly improved the usability and mechanical properties of conventional methods, and have superior specific rigidity and moldability than aluminum.
It can be used in a wide variety of applications, including interior and exterior parts of automobiles, housing panels, housings, industrial parts, leisure goods, electronic and electrical equipment parts, etc.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の成形品の一態様を示す断面図、第2図
は自動車のサンルーフハウジングの概略平面図である。 1・・・・・・高強度SMC,2・・・・・・低比重S
MC0出願人  大日本インキ化学工業株式会社出願人
  アイシン精機味式会社 第1凶 第2図 ロサ〉アリング舒分
FIG. 1 is a sectional view showing one embodiment of the molded product of the present invention, and FIG. 2 is a schematic plan view of a sunroof housing for an automobile. 1...High strength SMC, 2...Low specific gravity S
MC0 Applicant: Dainippon Ink & Chemicals Co., Ltd. Applicant: Aisin Seikimeki Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] (1)表面材がガラス繊維強化材を30体積%以上含有
するシートモールディングコンパウンドで構成されると
ともに、芯材が中空状の軽量充填剤を15体積%以上含
有するシートモールディングコンパウンドで構成されて
いることを特徴とするサンドイッチ繊維強化プラスチッ
クス成形品。
(1) The surface material is composed of a sheet molding compound containing 30% by volume or more of glass fiber reinforcement, and the core material is composed of a sheet molding compound containing 15% by volume or more of a hollow lightweight filler. A sandwich fiber-reinforced plastic molded product characterized by:
(2)表面材がガラス繊維強化材を30体積%以上含有
するシートモールディングコンパウンドで構成されると
ともに、芯材が中空状の軽量充填剤を15体積%以上含
有するシートモールディングコンパウンドで構成されて
いることを特徴とするサンドイッチ繊維強化プラスチッ
クス製の自動車部品。
(2) The surface material is composed of a sheet molding compound containing 30% by volume or more of glass fiber reinforcement, and the core material is composed of a sheet molding compound containing 15% by volume or more of a hollow lightweight filler. An automobile part made of sandwich fiber-reinforced plastics characterized by:
JP63050784A 1988-03-04 1988-03-04 Sandwich fiber-reinforced plastic molded products and automobile parts made of sandwich fiber-reinforced plastics Pending JPH01225533A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63050784A JPH01225533A (en) 1988-03-04 1988-03-04 Sandwich fiber-reinforced plastic molded products and automobile parts made of sandwich fiber-reinforced plastics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63050784A JPH01225533A (en) 1988-03-04 1988-03-04 Sandwich fiber-reinforced plastic molded products and automobile parts made of sandwich fiber-reinforced plastics

Publications (1)

Publication Number Publication Date
JPH01225533A true JPH01225533A (en) 1989-09-08

Family

ID=12868447

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63050784A Pending JPH01225533A (en) 1988-03-04 1988-03-04 Sandwich fiber-reinforced plastic molded products and automobile parts made of sandwich fiber-reinforced plastics

Country Status (1)

Country Link
JP (1) JPH01225533A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009007464A (en) * 2007-06-27 2009-01-15 Japan Composite Co Ltd Manufacturing method of molding material, molding material and molded product
WO2009110389A1 (en) 2008-03-07 2009-09-11 旭有機材工業株式会社 Heat-curable resin composition, fiber-reinforced molding material and molded article

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009007464A (en) * 2007-06-27 2009-01-15 Japan Composite Co Ltd Manufacturing method of molding material, molding material and molded product
WO2009110389A1 (en) 2008-03-07 2009-09-11 旭有機材工業株式会社 Heat-curable resin composition, fiber-reinforced molding material and molded article

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