JPH01201343A - Luminescent synthetic resin product - Google Patents
Luminescent synthetic resin productInfo
- Publication number
- JPH01201343A JPH01201343A JP2619188A JP2619188A JPH01201343A JP H01201343 A JPH01201343 A JP H01201343A JP 2619188 A JP2619188 A JP 2619188A JP 2619188 A JP2619188 A JP 2619188A JP H01201343 A JPH01201343 A JP H01201343A
- Authority
- JP
- Japan
- Prior art keywords
- product
- raw material
- synthetic resin
- powder
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 20
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 38
- 239000002994 raw material Substances 0.000 claims abstract description 31
- 239000000049 pigment Substances 0.000 claims abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 238000007796 conventional method Methods 0.000 claims description 8
- 238000004020 luminiscence type Methods 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract description 5
- 239000000835 fiber Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- -1 ropes Substances 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 210000001170 unmyelinated nerve fiber Anatomy 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Illuminated Signs And Luminous Advertising (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は成形品に発光性を付与させた合成樹脂製品、さ
らに詳しくは、繊維、ロープ、織布、シート、板体その
他の合成樹脂製品を成形するに際し、樹脂粉末原料に蓄
光顔料粉末を混入し′″Ｃ製品原料とし、これを成形し
て、製造された製品に発光性を付与させた発光合成樹脂
製品に関するものである。[Detailed Description of the Invention] <Industrial Application Field> The present invention relates to synthetic resin products in which luminescent properties are imparted to molded products, and more specifically, to fibers, ropes, woven fabrics, sheets, plates, and other synthetic resin products. This invention relates to a luminescent synthetic resin product in which a phosphorescent pigment powder is mixed into a resin powder raw material to form a product raw material, which is then molded to impart luminescence to the manufactured product.
〈従来の技術〉
従来、合成樹脂粉末原料に蓄光顔料粉末を混入して製品
原料とし、これを常法で成形して発光合成樹脂製品とす
る技術は一般に知られている。<Prior Art> Conventionally, a technique is generally known in which a luminescent pigment powder is mixed into a synthetic resin powder raw material to form a product raw material, and this is molded by a conventional method to produce a luminescent synthetic resin product.
〈発明が解決しようとする課題〉
従来の技術は、樹脂粉末原料に蓄光顔料粉末を適量混入
（この除、所望に応じて過量の酸化防止剤も合わせて混
入する）し、この餓料混入の原料で常法により成形し、
製品としている。この製品は発光性を有しているが、次
のような点において改良し得る点を有している。<Problems to be Solved by the Invention> The conventional technology involves mixing an appropriate amount of phosphorescent pigment powder into the resin powder raw material (adding an excessive amount of antioxidant if desired), and eliminating the starvation mixture. Molded using raw materials using conventional methods,
It is a product. Although this product has luminescent properties, it has the following points that could be improved.
即ち、上記従来品は、外部から光を照射すると、この光
を蓄えて発光するが、これは、専ら製品〒の蓄光顔料の
作用だけで光るものである。したがって、従来技術のも
のは発光度が比較的小となる問題点を有している。That is, when the above-mentioned conventional product is irradiated with light from the outside, it stores this light and emits light, but this is caused solely by the action of the phosphorescent pigment in the product. Therefore, the prior art has a problem in that the luminous intensity is relatively low.
ところで、発光度の大小は製品原料中における蓄光顔料
の含有率により変えられるようにも思える。しかし、蓄
光顔料の混入料を多くしても、これにより高め得る発光
度には限度があり、また、原料中の顔料の比率が多すぎ
ると、樹脂製品の品質を低下させる問題点が生じる。By the way, it seems that the magnitude of luminescence can be changed depending on the content of luminous pigment in the product raw material. However, even if the amount of phosphorescent pigment added is increased, there is a limit to the amount of luminescence that can be increased, and if the ratio of pigment in the raw material is too high, the quality of the resin product will be degraded.
本発明は上記のような点に鑑みてなされたものであり、
その目的とするところは、樹脂原料に対する蓄光顔料の
比率を変えることなく、発光度を大巾に高めることがで
きる発光合成樹脂製品を提供しようとするものである。The present invention has been made in view of the above points,
The objective is to provide a light-emitting synthetic resin product that can greatly increase luminescence intensity without changing the ratio of luminescent pigment to resin raw material.
く課題を解決するための手段〉
上記目的を達成するために、本発明は、アルミ系金属粉
末を発光増進剤として混入したものである。即ち、本発
明は、合成樹脂粉末原料に適量の蓄光顔料粉末とアルミ
系金属粉末を混入して製品原料とし、この製品原料な常
法により成形したことを特徴とするものである。Means for Solving the Problems> In order to achieve the above object, the present invention mixes aluminum-based metal powder as a luminescence enhancer. That is, the present invention is characterized in that a suitable amount of phosphorescent pigment powder and aluminum metal powder are mixed into a synthetic resin powder raw material to obtain a product raw material, and this product raw material is molded by a conventional method.
く作 用〉
本発明の製品に外部から光を照射すると、この光は製品
に含有されている蓄光顔料に蓄えられて発光するが、こ
の光は製品に含有されているアルミ系金属粉末により増
進されるので、発光度は大巾に大になる。このことは実
験により発見したものであるが、アルミ系金属粉末を含
有させることにより発光度が増進するのは次のような理
由によるものと考えられろ。即ち、蓄光顔料が発光する
と、この光はアルミ系金属粉末によって乱反射され、こ
れが発光度の増進の原因になるものと思慮する。Function> When the product of the present invention is irradiated with light from the outside, this light is stored in the phosphorescent pigment contained in the product and emits light, but this light is enhanced by the aluminum metal powder contained in the product. As a result, the luminous intensity will be greatly increased. This was discovered through experiments, and it is believed that the reason why luminescence is increased by including aluminum-based metal powder is as follows. That is, when the phosphorescent pigment emits light, this light is diffusely reflected by the aluminum-based metal powder, which is considered to be the cause of the increase in luminescence intensity.
〈実施例〉
以下、図面を参照して本発明の実施例につい℃説明ｊ心
。、１−／図は本発明の１夷Ａｔ例を示す発光合成樹脂
製品である。本実力ガは製品とし℃、繊維を成形【、た
ものである。本実施例では、所望の合成樹脂繊維の粉末
原料に蓄光顔料とアルミ系金属粉末を混入して製品原料
とし、これを常法により成形し℃所望の径の蓄光原料含
有の繊維１としたもので、この繊維１にはアルミ系金属
の粉末２が全体的に散在し℃いる。<Examples> Hereinafter, examples of the present invention will be explained with reference to the drawings. , 1-/ are luminescent synthetic resin products showing one example of the present invention. This product is manufactured by molding fibers. In this example, a product raw material is obtained by mixing a luminescent pigment and an aluminum metal powder into a powder raw material of a desired synthetic resin fiber, and this is molded by a conventional method to obtain a fiber 1 containing a luminescent raw material having a desired diameter at °C. In this fiber 1, aluminum-based metal powder 2 is scattered throughout.
上記蓄光顔料は市販の過当のものを選択して採用でき、
また、アルミ系金属粉末としては、アルミ箔を適当な手
段で粉砕し曵粉末化したものやアルミ金属を同様にして
粉砕したものなどが採用できる。The above phosphorescent pigments can be selected from commercially available ones.
Further, as the aluminum-based metal powder, it is possible to use aluminum foil that has been crushed and ground into powder by an appropriate means, or aluminum metal that has been crushed in the same way.
そし℃、その具体的製造は、たとえば次のように行なえ
ば良いものである。即ち、矛３図に示すように、所望の
合成樹脂粉末原料Ａに適量の蓄光顔料粉末Ｂとアルミ系
金属粉末Ｃを同図に）のように混入（この際、所望に応
じて適量の酸化防止剤も合わせ℃混入する）し、これを
同図（ホ）のように攪拌混合して製品原料りとする。こ
の製品原料りを公知の成呈機で常法により成形し″Ｃ繊
維製品とすり。The specific production thereof can be carried out, for example, as follows. That is, as shown in Figure 3, an appropriate amount of phosphorescent pigment powder B and aluminum metal powder C are mixed into a desired synthetic resin powder raw material A (as shown in the same figure) (at this time, an appropriate amount of oxidation is added as desired). The inhibitor is also mixed in (°C), and the mixture is stirred and mixed as shown in the same figure (e) to form the raw material for the product. This product raw material is formed into a "C fiber product" using a known forming machine using a conventional method.
上記製品原料り中の原料Ａに対する粉末Ｂ、Ｃり配合比
率は任意に選定できるもので、たとえば、その１例とし
て、上記各粉末Ａ、Ｂ、Ｃの割合を重量比で１００ ：
５０ ： １０とした例を挙げることができる。但し
、この比率は装造する製品の種類や用途等に応じ℃自由
に変更でさるものである。The blending ratio of powder B and C to raw material A in the product raw material can be arbitrarily selected. For example, as an example, the ratio of each of the powders A, B, and C is 100:
An example of a ratio of 50:10 can be given. However, this ratio can be freely changed according to the type of product to be assembled and its intended use.
７２図は本発明の別実施例を示すもので、本実施例では
、１７図の実施例のように成形した繊維１を用い、これ
を捩り合わせてロープ３を製造したものである。この実
施列のロープは、たとえば、定を網や生は賃なとの漁網
のロープや、境界や橋の標識ロープ等に適している。FIG. 72 shows another embodiment of the present invention. In this embodiment, fibers 1 formed as in the embodiment of FIG. 17 are used and twisted together to produce a rope 3. The ropes of this series are suitable, for example, as ropes for fishing nets and fishing nets, as well as marking ropes for boundaries and bridges.
矛３図は、上記と同様にして製造した繊維１を織成して
織布４（生地）を製造したものである。Figure 3 shows a fabric 4 (fabric) produced by weaving the fibers 1 produced in the same manner as above.
この実施例の織布４は各種の標識用のシートとし℃使用
するのに適し℃いる。The woven fabric 4 of this embodiment is suitable for use as a sheet for various signs.
オグ図は、上記製品原料りを公知の成屋戦で常法により
成形し、柔軟なシート材又は硬質の板状体５を製造した
ものである。この実施クリの製品は第３図と同様に各種
の標識用板材として使用するの＆Ｃａしていり。The figure shows a flexible sheet material or a hard plate-shaped body 5 produced by molding the above-mentioned product raw material using a conventional method using a well-known method. The products of this implementation will be used as board materials for various signs as shown in Fig. 3.
なお、本発明は、実施例の他の合成樹脂製品に広（適応
し得るものである。It should be noted that the present invention can be broadly applied to other synthetic resin products of the Examples.
〈発明の効果〉
本発明は以上説明したとおり、合成樹脂粉末原料に適量
の蓄光顔料とアルミ系金属粉末を混入して製品原料とし
、これを常法により成形して合成樹脂製品としたもので
あるから、製造が簡単であると共に樹脂粉末原料に対す
る蓄光顔料の混合比率を変えることなく、成形した製品
の発光度を大巾に増大させることができる。<Effects of the Invention> As explained above, the present invention is a product raw material by mixing an appropriate amount of phosphorescent pigment and aluminum metal powder into a synthetic resin powder raw material, which is then molded by a conventional method to produce a synthetic resin product. Because of this, manufacturing is simple and the luminescence intensity of the molded product can be greatly increased without changing the mixing ratio of the phosphorescent pigment to the resin powder raw material.
１７図ないしオグ図は本発明に係る発光合成樹脂製品の
夫々側実施例を示す図、矛！図Ｈ）ないしくホ）は製品
原料の製造工程を示す図である。
Ａ・・・・・・合成樹脂粉末原料
Ｂ・・・・・・蓄光顔料粉末
Ｃ・・・・・・アルミ系金属粉末
Ｄ・・・・・・夷品原料
特許出願人 武 井 正 義Figures 17 and 17 are diagrams showing respective embodiments of the light-emitting synthetic resin product according to the present invention. Figures H) to E) are diagrams showing the manufacturing process of product raw materials. A... Synthetic resin powder raw material B... Luminous pigment powder C... Aluminum metal powder D... Material raw material patent applicant Masayoshi Takei
Claims (1)
系金属粉末を混入して製品原料とし、この製品原料を常
法により成形した発光合成樹脂製品。(1) A light-emitting synthetic resin product made by mixing an appropriate amount of phosphorescent pigment powder and aluminum metal powder into a synthetic resin powder raw material to form a product raw material, and molding this product raw material by a conventional method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2619188A JPH01201343A (en) | 1988-02-05 | 1988-02-05 | Luminescent synthetic resin product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2619188A JPH01201343A (en) | 1988-02-05 | 1988-02-05 | Luminescent synthetic resin product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01201343A true JPH01201343A (en) | 1989-08-14 |
Family
ID=12186602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2619188A Pending JPH01201343A (en) | 1988-02-05 | 1988-02-05 | Luminescent synthetic resin product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01201343A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999025230A1 (en) * | 1997-11-13 | 1999-05-27 | Creative Labs, Inc. | Pillow with ventilation and microbicide |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5545753A (en) * | 1978-09-28 | 1980-03-31 | Mitsubishi Rayon Co Ltd | Resin composition with metallic luster |
| JPS6055051A (en) * | 1983-09-06 | 1985-03-29 | Kyowa Gas Chem Ind Co Ltd | Resin composition having light storing property |
-
1988
- 1988-02-05 JP JP2619188A patent/JPH01201343A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5545753A (en) * | 1978-09-28 | 1980-03-31 | Mitsubishi Rayon Co Ltd | Resin composition with metallic luster |
| JPS6055051A (en) * | 1983-09-06 | 1985-03-29 | Kyowa Gas Chem Ind Co Ltd | Resin composition having light storing property |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999025230A1 (en) * | 1997-11-13 | 1999-05-27 | Creative Labs, Inc. | Pillow with ventilation and microbicide |
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