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JPH01130785A - Ozone water sterilizer - Google Patents

Ozone water sterilizer

Info

Publication number
JPH01130785A
JPH01130785A JP28954087A JP28954087A JPH01130785A JP H01130785 A JPH01130785 A JP H01130785A JP 28954087 A JP28954087 A JP 28954087A JP 28954087 A JP28954087 A JP 28954087A JP H01130785 A JPH01130785 A JP H01130785A
Authority
JP
Japan
Prior art keywords
water tank
ozone
water
cooling
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP28954087A
Other languages
Japanese (ja)
Inventor
Tadao Yamada
山田 唯雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IHI Corp
Original Assignee
Ishikawajima Harima Heavy Industries Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ishikawajima Harima Heavy Industries Co Ltd filed Critical Ishikawajima Harima Heavy Industries Co Ltd
Priority to JP28954087A priority Critical patent/JPH01130785A/en
Publication of JPH01130785A publication Critical patent/JPH01130785A/en
Pending legal-status Critical Current

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  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、オゾン水殺菌装置に関する もので、詳しくは、バイオ、食品工業、医療分野等にお
いて、研究よまたは衛生上必要となる細菌類の殺菌を行
なうためのオゾン水殺菌装置に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to an ozone water sterilizer. Specifically, it is used in the biotechnology, food industry, medical fields, etc. to sterilize bacteria required for research or hygiene. The present invention relates to an ozone water sterilization device for sterilizing ozone water.

従来の技術 従来は、高濃度のオゾン水を作る場合 には、オゾン発生器からの高濃度のオゾンガスを水槽の
水中に吹込んでいた。
2. Description of the Related Art Conventionally, when producing highly concentrated ozone water, highly concentrated ozone gas from an ozone generator was blown into the water of an aquarium.

発明が解決しようとする問題点 水は低温度程、オゾンを多量に溶解す る性質を有するが、前述のように、従来は、高濃度のオ
ゾン水を作る場合には、高濃度のオゾンガスを水中に吹
込んでいたので、高濃度のオゾンガスを発生させるため
のオゾン発生器の製作費用および運転費用等が増加する
という問題点があった。また殺菌効果は、水中のオゾン
が酸素に分解し、活性化された酸素原子を作ることでな
されるが、この酸素への分解は高温になる程、多くなる
。しかし、従来は、温度調整をしないので、排水中のオ
ゾン濃度が高く、その分解処理費用が多くなるという問
題点があった。
Problems to be Solved by the Invention Water has the property of dissolving a large amount of ozone at lower temperatures. Therefore, there was a problem in that the manufacturing cost and operating cost of an ozone generator for generating highly concentrated ozone gas increased. The bactericidal effect is achieved by decomposing ozone in water into oxygen and creating activated oxygen atoms, and the higher the temperature, the more this decomposition into oxygen occurs. However, in the past, there was a problem that the ozone concentration in the wastewater was high and the decomposition treatment cost was high because the temperature was not adjusted.

本発明は、このような問題点を解決し ようとするものである。The present invention solves these problems. This is what we are trying to do.

問題点を解決するだめの手段 内部に冷却器を有してオゾン発生器か らのオゾンガスを溶解してオゾン水とする冷却水槽と、
内部に加熱器を有して前記冷却水槽からのオゾン水を加
温して殺菌水とする加熱水槽と、冷却側で前記冷却水槽
の冷却器を冷却するとともに放熱側で前記加熱水槽の加
熱器を加熱するヒートポンプ式の冷凍機とを備えたもの
とした。
A cooling water tank having a cooler inside and dissolving ozone gas from an ozone generator to form ozone water;
a heating water tank that has a heater inside and heats ozonated water from the cooling water tank to make sterilized water; a heating water tank that cools the cooler of the cooling water tank on the cooling side and a heater of the heating water tank on the heat radiation side; It is equipped with a heat pump type refrigerator that heats the air.

作用 本発明によれば、オゾン水を作る冷却 水槽には冷却器が設けられており、また殺菌用水を作る
加熱水槽には加熱器が設けられているので、まず、冷却
水槽でオゾンガスを溶解させる水の温度を下げて溶解度
を上げることができ、つぎに、加熱水槽でこのオゾン水
の温度を上げて殺菌効果を高めることができる。また前
記冷却水槽の冷却器の冷却および前記加熱水槽の加熱器
の加熱を、それぞれヒートポンプ式の冷凍機の冷却側と
放熱側で行なうので、冷熱源および加熱源を一つの冷凍
機で行なうことができる。
According to the present invention, the cooling water tank for producing ozone water is equipped with a cooler, and the heating water tank for producing sterilizing water is equipped with a heater, so first, ozone gas is dissolved in the cooling water tank. The solubility can be increased by lowering the temperature of the water, and then the temperature of this ozonated water can be raised in a heated water bath to enhance the bactericidal effect. Furthermore, since the cooling of the cooler of the cooling water tank and the heating of the heater of the heating water tank are performed on the cooling side and the heat radiation side of the heat pump type refrigerator, respectively, the cold source and the heating source can be performed by one refrigerator. can.

実施例 図面は本発明の一実施例を示している。Example The drawing shows an embodiment of the invention.

図において、1は冷却水槽、2は該冷却水槽1の内部に
設けられた冷却器、3は該冷却水槽1の水を循環させる
循環ポンプ、4 はエジェクタ、5は加熱水槽、6は該
加熱水槽5の内部に設けられた加熱器、7と8はオゾン
分解器、9は冷却側で前記冷却器2′f:冷却するとと
もに放熱側で前記加熱器6を加熱するヒートポンプ式の
冷凍機、10はオゾン発生器、 11は給水管、12は排水管、13は排気管である。
In the figure, 1 is a cooling water tank, 2 is a cooler installed inside the cooling water tank 1, 3 is a circulation pump that circulates water in the cooling water tank 1, 4 is an ejector, 5 is a heating water tank, and 6 is the heating water tank. A heater provided inside the water tank 5, 7 and 8 are ozone decomposers, 9 is a cooling side and the cooler 2'f: a heat pump type refrigerator that cools and also heats the heater 6 on the heat radiation side; 10 is an ozone generator, 11 is a water supply pipe, 12 is a drain pipe, and 13 is an exhaust pipe.

図に示すように構成されたオゾン水殺 菌装置においては、冷却水槽lへ供給された水は冷却器
2で所定の温度まで冷却される。循環ポンプ3は冷却水
槽lの水を吸入して循環させるが、この循環ポンプ3の
吐出側には2つのエジェクタ4が設けられており、まず
、冷却水槽lの未溶解オゾン混合気を吸入し、さらに、
オゾン発生器10からのオゾン混合気を吸入して溶解さ
せる。
In the ozone water sterilizer configured as shown in the figure, water supplied to a cooling water tank 1 is cooled to a predetermined temperature by a cooler 2. The circulation pump 3 sucks in and circulates the water in the cooling water tank L. Two ejectors 4 are provided on the discharge side of the circulation pump 3, and first, the undissolved ozone mixture in the cooling water tank L is sucked in. ,moreover,
The ozone mixture from the ozone generator 10 is inhaled and dissolved.

そして、冷却水槽lで冷却されてオシ /ガスを溶解したオゾン水は加熱水槽5に送られ、ここ
で、所定の温度まで加熱されて殺菌用水となり、殺菌に
用いられる。
Then, the ozonated water that has been cooled in the cooling water tank 1 and dissolved therein is sent to the heating water tank 5, where it is heated to a predetermined temperature to become sterilizing water and used for sterilization.

前記冷却水槽1および加熱水槽5の気 □相部のオゾン
混合気はオゾン分解器7でオゾンを分解処理して排気管
13から排気される。また加熱水槽5の排水も同様にオ
ゾン分解器8で処理されたのちに排水管12から排水さ
れる。
The ozone mixture in the gas phase in the cooling water tank 1 and the heating water tank 5 undergoes ozone decomposition treatment in the ozone decomposer 7, and is exhausted from the exhaust pipe 13. Further, the waste water from the heating water tank 5 is similarly treated by the ozone decomposer 8 and then drained from the drain pipe 12.

前記冷凍機9はヒートポンプとして作 用をする。すなわち、冷却側で冷却器2を冷却し、放熱
側で加熱器6を加熱する。
The refrigerator 9 functions as a heat pump. That is, the cooler 2 is cooled on the cooling side, and the heater 6 is heated on the heat radiation side.

さらに説明すると、オゾン発生器10 はそのエネルギー効率が低く、現状では10%程度とい
われている。また高濃度オゾンの発生も、技術的に困難
で、最高1重量%程度のものが多い。またオゾンが水に
溶解する量は、圧力、温度、オゾン濃度により影響を受
ける。圧力を一定とすると、ヘンリーの法則により、水
への溶解量は、気体中のオゾン濃度に比例するとともに
、水温を低くすると増加する。
To explain further, the ozone generator 10 has a low energy efficiency, which is currently said to be about 10%. Furthermore, it is technically difficult to generate high-concentration ozone, which is often around 1% by weight at most. The amount of ozone dissolved in water is also affected by pressure, temperature, and ozone concentration. Assuming that the pressure is constant, the amount of ozone dissolved in water is proportional to the ozone concentration in the gas, and increases as the water temperature is lowered, according to Henry's law.

たとえば、気体体積1リットル当り空 気中1ミリグラムのオゾン濃度では、水中平衡濃度は第
1表のとおりである。
For example, at an ozone concentration of 1 milligram in air per liter of gas volume, the equilibrium concentration in water is as shown in Table 1.

第  1  表 第1表にみられるように、水温が5°Cでは、30°C
の2倍のオゾンを溶解できることになる。
Table 1 As shown in Table 1, when the water temperature is 5°C, the water temperature is 30°C.
This means that twice as much ozone can be dissolved.

一方、水温を高くすると、オゾンは自 己分解速度が増大して、 03→o2+。On the other hand, when the water temperature is raised, ozone is released automatically. The rate of self-decomposition increases, 03→o2+.

の反応が促進されるが、この過程で発生するO(酸素原
子)が強力な酸化・殺菌作用を示す。
This reaction is promoted, but the O (oxygen atoms) generated during this process has a strong oxidizing and bactericidal effect.

すなわち、低濃度のオゾン発生器10 でも、冷却水槽lの水を冷却することによって、高温度
のオゾン水が作られ、また加熱水槽5でオゾン水を加熱
して温度を上げることにより、殺菌用水の酸化・殺菌力
を高めることが可能である。
That is, even in the low concentration ozone generator 10, high temperature ozonated water is produced by cooling the water in the cooling water tank 1, and by heating the ozonated water in the heating water tank 5 to raise the temperature, sterilizing water is produced. It is possible to increase the oxidizing and sterilizing power of

発明の詳細 な説明したように、本発明によれば、 冷却水槽の水を最適な温度に下げることができてオゾン
ガスの溶解度を上げることができ、かつ、加熱水槽のオ
ゾン水を最適な温度に上げて殺菌効果を高めることがで
きるので、オゾン発生器を性能のよい高価なものとしな
くてもよく、また通常の運転でもよいため、経済的にき
わめて有利である。また前記冷却水槽の冷却と加熱水槽
の加熱を、それぞれヒートポンプ式の冷凍機の冷却側と
放熱側で行なうので、冷熱源と加熱源を一つの冷凍機で
行なうことができて経済的である。
As described in detail, according to the present invention, the water in the cooling water tank can be lowered to the optimal temperature to increase the solubility of ozone gas, and the ozone water in the heating water tank can be brought to the optimal temperature. Since the sterilization effect can be enhanced by increasing the sterilization effect, the ozone generator does not need to be a high-performance, expensive one, and can be operated normally, which is extremely advantageous economically. Furthermore, since the cooling water tank and the heating water tank are respectively cooled and heated on the cooling side and the heat radiation side of the heat pump type refrigerator, it is possible to use a single refrigerator as a cold source and a heating source, which is economical.

なお使用目的に応じて、冷却のみでの高濃度オゾン水の
製造または加熱のみで殺菌効果を高めることも、温度制
御により、゛容易に実現することが可能である。
Depending on the purpose of use, it is also possible to easily produce high-concentration ozonated water by cooling only, or to increase the sterilizing effect by heating only, by controlling the temperature.

【図面の簡単な説明】[Brief explanation of the drawing]

図は本発明の一実施例を示した説明図 である。 1・・・冷却水槽、2・・・冷却器、 5・・・加熱水槽、6・・・加熱器、9・・・冷凍機、
10・・・オゾン発生器。
The figure is an explanatory diagram showing one embodiment of the present invention. 1... Cooling water tank, 2... Cooler, 5... Heating water tank, 6... Heater, 9... Freezer,
10...Ozone generator.

Claims (1)

【特許請求の範囲】 1、内部に冷却器を有してオゾン発生器 からのオゾンガスを溶解してオゾン水と する冷却水槽と、内部に加熱器を有して 前記冷却水槽からのオゾン水を加温して 殺菌用水とする加熱水槽と、冷却側で前 記冷却水槽の冷却器を冷却するとともに 放熱側で前記加熱水槽の加熱器を加熱す るヒートポンプ式の冷凍機とを備えてい ることを特徴とする、オゾン水殺菌装置。[Claims] 1. Ozone generator with internal cooler Dissolve ozone gas from It has a cooling water tank and a heater inside. By heating the ozonated water from the cooling water tank, A heated water tank is used for sterilization water, and a In addition to cooling the cooler of the cooling water tank. Heat the heater of the heating water tank on the heat radiation side. It is equipped with a heat pump type refrigerator. An ozone water sterilization device characterized by:
JP28954087A 1987-11-18 1987-11-18 Ozone water sterilizer Pending JPH01130785A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28954087A JPH01130785A (en) 1987-11-18 1987-11-18 Ozone water sterilizer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28954087A JPH01130785A (en) 1987-11-18 1987-11-18 Ozone water sterilizer

Publications (1)

Publication Number Publication Date
JPH01130785A true JPH01130785A (en) 1989-05-23

Family

ID=17744565

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28954087A Pending JPH01130785A (en) 1987-11-18 1987-11-18 Ozone water sterilizer

Country Status (1)

Country Link
JP (1) JPH01130785A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0372993A (en) * 1989-08-10 1991-03-28 Ishikawajima Harima Heavy Ind Co Ltd Ozone manufacturing device
JPH0338198U (en) * 1989-08-24 1991-04-12
US5971368A (en) * 1997-10-29 1999-10-26 Fsi International, Inc. System to increase the quantity of dissolved gas in a liquid and to maintain the increased quantity of dissolved gas in the liquid until utilized
JP2001079376A (en) * 1999-09-10 2001-03-27 Kurita Water Ind Ltd Preparation method of gas dissolved water
US6235641B1 (en) 1998-10-30 2001-05-22 Fsi International Inc. Method and system to control the concentration of dissolved gas in a liquid
US6274506B1 (en) 1999-05-14 2001-08-14 Fsi International, Inc. Apparatus and method for dispensing processing fluid toward a substrate surface
US6406551B1 (en) 1999-05-14 2002-06-18 Fsi International, Inc. Method for treating a substrate with heat sensitive agents
JP2003512736A (en) * 1999-10-19 2003-04-02 フィファー・スミス・コーポレーション Method and apparatus for treating substrate using ozone-solvent solution
WO2020008884A1 (en) * 2018-07-06 2020-01-09 栗田工業株式会社 Reverse osmosis treatment method and system
KR102235746B1 (en) * 2020-09-14 2021-04-02 주식회사 목간 Air purification device

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0372993A (en) * 1989-08-10 1991-03-28 Ishikawajima Harima Heavy Ind Co Ltd Ozone manufacturing device
JPH0338198U (en) * 1989-08-24 1991-04-12
US5971368A (en) * 1997-10-29 1999-10-26 Fsi International, Inc. System to increase the quantity of dissolved gas in a liquid and to maintain the increased quantity of dissolved gas in the liquid until utilized
US6648307B2 (en) 1997-10-29 2003-11-18 Fsi International, Inc. Method to increase the quantity of dissolved gas in a liquid and to maintain the increased quantity of dissolved gas in the liquid until utilized
US6488271B1 (en) * 1997-10-29 2002-12-03 Fsi International, Inc. Method to increase the quantity of dissolved gas in a liquid and to maintain the increased quantity of dissolved gas in the liquid until utilized
US6235641B1 (en) 1998-10-30 2001-05-22 Fsi International Inc. Method and system to control the concentration of dissolved gas in a liquid
US6406551B1 (en) 1999-05-14 2002-06-18 Fsi International, Inc. Method for treating a substrate with heat sensitive agents
US6274506B1 (en) 1999-05-14 2001-08-14 Fsi International, Inc. Apparatus and method for dispensing processing fluid toward a substrate surface
JP2001079376A (en) * 1999-09-10 2001-03-27 Kurita Water Ind Ltd Preparation method of gas dissolved water
JP2003512736A (en) * 1999-10-19 2003-04-02 フィファー・スミス・コーポレーション Method and apparatus for treating substrate using ozone-solvent solution
WO2020008884A1 (en) * 2018-07-06 2020-01-09 栗田工業株式会社 Reverse osmosis treatment method and system
JPWO2020008884A1 (en) * 2018-07-06 2020-07-09 栗田工業株式会社 Reverse osmosis treatment method and system
KR102235746B1 (en) * 2020-09-14 2021-04-02 주식회사 목간 Air purification device

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