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JP7615591B2 - Membrane separation device, its operation method, and biological treatment device - Google Patents

Membrane separation device, its operation method, and biological treatment device Download PDF

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JP7615591B2
JP7615591B2 JP2020163640A JP2020163640A JP7615591B2 JP 7615591 B2 JP7615591 B2 JP 7615591B2 JP 2020163640 A JP2020163640 A JP 2020163640A JP 2020163640 A JP2020163640 A JP 2020163640A JP 7615591 B2 JP7615591 B2 JP 7615591B2
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membrane separation
water
membrane
separation device
backwash pump
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JP2022055924A (en
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和也 小松
拓哉 菅原
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Kurita Water Industries Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02W10/10Biological treatment of water, waste water, or sewage

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Description

本発明は、有機物含有排水を生物処理し、膜分離により処理水を得る膜分離式生物処理装置に関する。また、本発明は、この生物処理装置に好適な膜分離装置と、その運転方法に関する。 The present invention relates to a membrane separation type biological treatment device that biologically treats wastewater containing organic matter and obtains treated water by membrane separation. The present invention also relates to a membrane separation device suitable for this biological treatment device and its operating method.

生物反応槽から槽外膜に汚泥を循環させながら、膜の一次側から二次側に向けて濾過することにより処理水を得る生物処理装置が特許文献1に記載されている。この生物処理装置の運転を行っていると、膜の一次側に次第に固形物が付着してくるので、二次側から一次側に向けて処理水を通過させて、膜の一次側面に付着している固形物を剥離除去する逆洗操作を所定時間毎に実行する。これにより、一次側の膜面への汚泥付着による濾過能力の低下を防ぎ、安定して処理水を得ることができるようになる。なお、逆洗排水は生物処理槽に返送される。 Patent Document 1 describes a biological treatment device that obtains treated water by filtering from the primary side of the membrane to the secondary side while circulating sludge from a biological reaction tank to an outer membrane of the tank. When this biological treatment device is in operation, solids gradually adhere to the primary side of the membrane, so a backwash operation is performed at regular intervals by passing treated water from the secondary side to the primary side to peel off and remove the solids adhering to the primary side of the membrane. This prevents a decrease in filtering ability due to sludge adhering to the membrane surface on the primary side, and makes it possible to obtain treated water stably. The backwash wastewater is returned to the biological treatment tank.

特開2004-249235号公報JP 2004-249235 A

膜の逆洗は、濾過時より高いフラックス(透過流束)で短時間行うのが、膜面の洗浄効果、処理水の回収率の点でよい。しかし、所定時間毎に逆洗ポンプが起動する際、逆洗ポンプが始動してからその吐出流量が所定の値に達するまでには若干の時間(以下、これをタイムラグという。)がかかる。このタイムラグの間は逆洗水(処理水を使用)は流量が小さいため充分な洗浄効果がないまま逆洗排水として生物反応槽に返送されることとなってしまう。このように逆洗に寄与しない処理水の返送を行う分だけ、膜濾過効率(処理水の回収率)が低下してしまうという問題があった。 Backwashing of the membrane is best done for a short time with a higher flux (permeation flux) than during filtration, in terms of the cleaning effect on the membrane surface and the recovery rate of treated water. However, when the backwash pump is started at a specified time, it takes some time (hereinafter referred to as the time lag) from when the backwash pump starts until its discharge flow rate reaches a specified value. During this time lag, the backwash water (treated water is used) has a small flow rate and is returned to the biological reactor as backwash wastewater without having a sufficient cleaning effect. This creates a problem in that the membrane filtration efficiency (recovery rate of treated water) decreases to the extent that treated water that does not contribute to backwashing is returned.

また、濾過サイクル中に膜の一次側面に付着する汚泥量が増加したり、付着汚泥が難透水性のものであったりすることにより、膜の透過差圧が大きく上昇する。そのため、逆洗ポンプの出力を一定値に固定設定していた場合、逆洗に必要な吐出圧が逆洗ポンプの実際の吐出圧よりも高くなり、所定の逆洗流束を得ることができなくなってしまうおそれもあった。 In addition, if the amount of sludge adhering to the primary side of the membrane increases during the filtration cycle, or if the adhering sludge is poorly permeable, the membrane permeation differential pressure increases significantly. Therefore, if the backwash pump output is set to a fixed value, the discharge pressure required for backwashing will be higher than the actual discharge pressure of the backwash pump, and it may not be possible to obtain the desired backwash flux.

本発明は、膜分離装置の逆洗を効果的に行うことができ、また、逆洗水の使用量も少なくなり、膜濾過性能を長期間、安定に維持することができる膜分離装置、その運転方法及び生物処理装置を提供することを課題とする。 The objective of the present invention is to provide a membrane separation device, an operating method thereof, and a biological treatment device that can effectively backwash the membrane separation device, reduce the amount of backwash water used, and stably maintain membrane filtration performance for a long period of time.

本発明の膜分離装置は、被処理水が一次側に通水され、膜を透過した処理水が二次側から処理水槽に取り出される膜分離装置であって、処理水槽内の処理水を該二次側に供給するための逆洗ポンプを備えた膜分離装置において、該逆洗ポンプの吐出水の供給先を該二次側と該処理水槽とで切り替える切替手段を備えたことを特徴とする。 The membrane separation device of the present invention is a membrane separation device in which the water to be treated is passed through the primary side, and the treated water that has permeated the membrane is taken out from the secondary side to a treated water tank. The membrane separation device is equipped with a backwash pump for supplying the treated water in the treated water tank to the secondary side, and is characterized by having a switching means for switching the supply destination of the backwash pump's discharge water between the secondary side and the treated water tank.

本発明の一態様では、前記切替手段は、前記逆洗ポンプの始動後、逆洗ポンプの出力が基準値に達するまで、又は所定時間が経過するまでは吐出水を前記処理水槽に返送し、その後は吐出水を前記二次側に導入するように作動する。 In one aspect of the present invention, the switching means operates to return discharged water to the treatment tank after the backwash pump starts until the output of the backwash pump reaches a reference value or until a predetermined time has elapsed, and thereafter to introduce the discharged water into the secondary side.

本発明の膜分離装置の運転方法は、かかる本発明の膜分離装置の運転方法であって、前記逆洗ポンプによって前記処理水槽内の処理水を前記二次側に供給して膜を逆洗する工程を有する膜分離装置の運転方法において、該逆洗ポンプの始動後、該逆洗ポンプの出力が基準値に達するまで又は所定時間が経過するまでは逆洗ポンプの吐出水を前記処理水槽に返送し、その後、逆洗ポンプの吐出水を前記二次側に供給して逆洗を行うことを特徴とする。 The method of operating the membrane separation apparatus of the present invention is a method of operating the membrane separation apparatus of the present invention, which includes a step of backwashing the membrane by supplying treated water in the treatment water tank to the secondary side by the backwash pump, and is characterized in that after the backwash pump is started, the discharge water of the backwash pump is returned to the treatment water tank until the output of the backwash pump reaches a reference value or a predetermined time has elapsed, and then the discharge water of the backwash pump is supplied to the secondary side to perform backwashing.

本発明の生物処理装置は、有機物含有排水を生物処理する反応槽と、反応槽外に設置され膜濾過により処理水を得る膜分離装置と、処理水を貯留する処理水槽と、該膜分離装置を間欠的に処理水で逆洗する逆洗ポンプとを有する生物処理装置において、該逆洗ポンプの吐出水の供給先を、前記膜分離装置の二次側と該処理水槽とで切り替える切替手段を備えたことを特徴とする。 The biological treatment device of the present invention has a reaction tank for biologically treating wastewater containing organic matter, a membrane separation device installed outside the reaction tank for obtaining treated water by membrane filtration, a treated water tank for storing the treated water, and a backwash pump for intermittently backwashing the membrane separation device with the treated water, and is characterized by having a switching means for switching the supply destination of the backwash pump's discharge water between the secondary side of the membrane separation device and the treated water tank.

本発明では、逆洗ポンプを濾過サイクル中に処理水を処理水槽に循環する形で起動させ、逆洗ポンプの出力が十分に高くなった後、バルブ切替えにより膜逆洗を行う。これにより、膜の逆洗を十分に効率的に行うことができる。また、逆洗水の使用量も少なくなり、処理水の回収率が向上する。 In the present invention, the backwash pump is started during the filtration cycle to circulate the treated water to the treatment tank, and after the output of the backwash pump becomes sufficiently high, the valve is switched to perform membrane backwash. This allows the membrane to be backwashed sufficiently efficiently. In addition, the amount of backwash water used is reduced, improving the recovery rate of treated water.

さらに、逆洗ポンプの該所定の出力を、ポンプの性能曲線から求めた濾過サイクル中の管状膜内の圧力に対して所定の逆洗フラックスとなる値とすることにより、かかる効果がさらに向上する。 Furthermore, this effect can be further improved by setting the specified output of the backwash pump to a value that results in a specified backwash flux relative to the pressure inside the tubular membrane during the filtration cycle, as determined from the pump performance curve.

実施の形態に係る生物処理装置の構成図である。FIG. 1 is a configuration diagram of a biological treatment device according to an embodiment. 実施の形態に係る生物処理装置の構成図である。FIG. 1 is a configuration diagram of a biological treatment device according to an embodiment. 実施の形態に係る生物処理装置の構成図である。FIG. 1 is a configuration diagram of a biological treatment device according to an embodiment. 実施の形態に係る生物処理装置の構成図である。FIG. 1 is a configuration diagram of a biological treatment device according to an embodiment. 実施の形態に係る生物処理装置の構成図である。FIG. 1 is a configuration diagram of a biological treatment device according to an embodiment. 実施の形態に係る生物処理装置の構成図である。FIG. 1 is a configuration diagram of a biological treatment device according to an embodiment. 実施の形態に係る生物処理装置の構成図である。FIG. 1 is a configuration diagram of a biological treatment device according to an embodiment.

以下、図面を参照して実施の形態について説明する。 The following describes the embodiment with reference to the drawings.

図1は、実施の形態に係る膜分離装置を示すものであり、(a)は濾過工程を示し、(b)は逆洗ポンプの始動直後を示し、(c)は逆洗工程を示している。 Figure 1 shows a membrane separation device according to an embodiment, where (a) shows the filtration process, (b) shows the state immediately after starting the backwash pump, and (c) shows the backwash process.

原水は、生物処理反応槽1に導入され、生物処理される。反応槽1には撹拌機1aが設けられている。 The raw water is introduced into the biological treatment reactor 1 and undergoes biological treatment. The reactor 1 is equipped with an agitator 1a.

図1(a)に示す通り、濾過工程では、弁8を開とし、給水ポンプ3を作動させる。反応槽1内の生物処理液は、配管2、給水ポンプ3、配管4を通って膜分離装置5の一次側に供給され、膜5aによって膜分離処理される。膜5aを透過しなかった濃縮水は、膜分離装置5の一次側から流出し、配管6を通って反応槽1に返送される。膜5aを透過した処理水は、膜分離装置5の二次側から、配管7、弁8及び配管9を通って処理水槽10に流入し、配管11を通って取り出される。この濾過工程では、後述の逆洗ポンプ13は停止している。 As shown in FIG. 1(a), in the filtration process, valve 8 is opened and water supply pump 3 is operated. The biological treatment liquid in reaction tank 1 is supplied to the primary side of membrane separation device 5 through pipe 2, water supply pump 3, and pipe 4, and is subjected to membrane separation treatment by membrane 5a. Concentrated water that has not permeated membrane 5a flows out from the primary side of membrane separation device 5 and is returned to reaction tank 1 through pipe 6. Treated water that has permeated membrane 5a flows from the secondary side of membrane separation device 5 through pipe 7, valve 8, and pipe 9 into treated water tank 10, and is taken out through pipe 11. In this filtration process, backwash pump 13, which will be described later, is stopped.

この実施の形態では、処理水槽10内の処理水によって膜分離装置5の膜5aを逆洗するように、処理水槽10と配管7とが配管12、逆洗ポンプ13、配管14,18、弁19、配管20によって接続されている。また、逆洗ポンプ13の始動時に配管14からの水を処理水槽10に戻すように、配管15、弁16及び配管17が設けられている。濾過工程では、弁16,19はいずれも閉としている。 In this embodiment, the treated water tank 10 and piping 7 are connected by piping 12, backwash pump 13, piping 14, 18, valve 19, and piping 20 so that the treated water in the treated water tank 10 backwashes the membrane 5a of the membrane separation device 5. In addition, piping 15, valve 16, and piping 17 are provided so that water from piping 14 is returned to the treated water tank 10 when the backwash pump 13 starts. During the filtration process, both valves 16 and 19 are closed.

膜分離装置5の逆洗を開始するには、図1(b)のように、弁8が開、給水ポンプ3が作動している状態で弁19を閉、弁16を開とし、逆洗ポンプ13を始動する。逆洗ポンプ13の吐出水は、配管14,15、弁16、配管17を通って処理水槽10に返送される。 To start backwashing the membrane separation device 5, as shown in FIG. 1(b), valve 8 is open, the water supply pump 3 is operating, valve 19 is closed, valve 16 is opened, and the backwash pump 13 is started. The discharge water from the backwash pump 13 is returned to the treatment water tank 10 through pipes 14 and 15, valve 16, and pipe 17.

所定時間が経過し、逆洗ポンプ13の出力が十分に大きくなった後、図1(c)の通り、給水ポンプ3を作動させた状態で、弁8を閉、弁16を閉、弁19を開とする。これにより、処理水槽10内の処理水が、配管12,14,18、弁19、配管20,7を通って、膜分離装置5の二次側に供給され、膜5aを二次側から一次側に透過することにより、膜5aの一次側に付着した付着物を剥離させる。 After a predetermined time has passed and the output of the backwash pump 13 has become sufficiently large, as shown in FIG. 1(c), valve 8 is closed, valve 16 is closed, and valve 19 is opened while the water supply pump 3 is operating. This causes the treated water in the treated water tank 10 to pass through pipes 12, 14, 18, valve 19, and pipes 20 and 7 and be supplied to the secondary side of the membrane separation device 5, where it permeates the membrane 5a from the secondary side to the primary side, peeling off any deposits that have adhered to the primary side of the membrane 5a.

なお、この逆洗工程においても、給水ポンプ3は作動しており、膜分離装置5の一次側には反応槽1からの生物処理液が通水されている。そのため、膜5aの一次側から剥離した剥離物は、生物処理液と共に配管6を通って反応槽1に流入する。 Even during this backwash process, the water supply pump 3 is operating, and the biological treatment liquid from the reaction tank 1 is passed through the primary side of the membrane separation device 5. Therefore, the material that has peeled off from the primary side of the membrane 5a flows into the reaction tank 1 through the pipe 6 together with the biological treatment liquid.

所定時間、かかる逆洗を行った後、図1(a)のように、逆洗ポンプ13を停止し、弁8を開、弁19を閉とし、濾過工程に復帰する。 After performing this backwash for a predetermined period of time, as shown in Figure 1(a), the backwash pump 13 is stopped, valve 8 is opened, and valve 19 is closed, and the filtration process is resumed.

この実施の形態では、図1(b)のように、逆洗ポンプ13の始動時に弁19を閉、弁16を開とし、ポンプ13の出力が十分に高くなるまでの立上げ期間ではポンプ13の吐出水を処理水槽10に返送し、膜分離装置5には逆洗水を供給しない。そのため、逆洗ポンプ13の立上げ期間に低流量の逆洗水が膜分離装置5に供給されることがなく、逆洗効果の乏しい処理水返送が行われない。この結果、処理水が無駄に逆洗に使用されることが回避され、処理効率(膜濾過効率)が向上する。 In this embodiment, as shown in FIG. 1(b), when the backwash pump 13 is started, valve 19 is closed and valve 16 is opened, and during the start-up period until the output of the pump 13 becomes sufficiently high, the discharge water of the pump 13 is returned to the treated water tank 10, and backwash water is not supplied to the membrane separation device 5. Therefore, during the start-up period of the backwash pump 13, low flow rate backwash water is not supplied to the membrane separation device 5, and treated water with poor backwash effect is not returned. As a result, the wasteful use of treated water for backwashing is avoided, and the treatment efficiency (membrane filtration efficiency) is improved.

図2~7を参照して別の実施の形態について説明する。この実施の形態は、2基の膜分離装置38,44を配置した生物処理装置に関するものである。 Another embodiment will be described with reference to Figures 2 to 7. This embodiment relates to a biological treatment device in which two membrane separation devices 38, 44 are arranged.

図2は、生物処理液を第1の膜分離装置38に通水し、その濃縮水を第2の膜分離装置44に通水して濾過処理している状態を示している。なお、図2では、膜分離装置38,44に対し被処理液が順方向に通水されている。 Figure 2 shows the state in which the biological treatment liquid is passed through the first membrane separation device 38, and the concentrated water is passed through the second membrane separation device 44 for filtration. In Figure 2, the liquid to be treated is passed through the membrane separation devices 38 and 44 in the forward direction.

図2では、逆洗ポンプ62は停止しており、給水ポンプ33のみが作動している。また、弁35,41,47,53,58が開となっており、その他の弁は閉となっている。 In FIG. 2, the backwash pump 62 is stopped, and only the water supply pump 33 is operating. Valves 35, 41, 47, 53, and 58 are open, and the other valves are closed.

撹拌機31aを有した反応槽31内の生物処理液は、配管32、給水ポンプ33、配管34、弁35、配管36,37を通って膜分離装置38の一次側に供給される。膜38aを透過しなかった濃縮水は、膜分離装置38の一次側から、配管39,40、弁41、配管42,43を通って膜分離装置44の一次側に供給される。膜44aを透過しなかった濃縮水は、膜分離装置44の一次側から、配管45,46、弁47、配管48,49を通って反応槽31に返送される。 The biological treatment liquid in the reaction tank 31 having the agitator 31a is supplied to the primary side of the membrane separation device 38 through the pipe 32, the water supply pump 33, the pipe 34, the valve 35, and the pipes 36 and 37. The concentrated water that did not permeate the membrane 38a is supplied from the primary side of the membrane separation device 38 through the pipes 39 and 40, the valve 41, and the pipes 42 and 43 to the primary side of the membrane separation device 44. The concentrated water that did not permeate the membrane 44a is returned from the primary side of the membrane separation device 44 to the reaction tank 31 through the pipes 45 and 46, the valve 47, and the pipes 48 and 49.

膜分離装置38の膜38aを透過した処理水は、膜分離装置38の二次側から、配管51,52、弁53、配管54を通って処理水槽55に導入される。膜分離装置44の膜44aを透過した処理水は、膜分離装置44の二次側から、配管56,57、弁58、配管59を通って処理水槽55に導入される。 The treated water that has permeated the membrane 38a of the membrane separation device 38 is introduced from the secondary side of the membrane separation device 38 through pipes 51 and 52, valve 53, and pipe 54 into the treated water tank 55. The treated water that has permeated the membrane 44a of the membrane separation device 44 is introduced from the secondary side of the membrane separation device 44 through pipes 56 and 57, valve 58, and pipe 59 into the treated water tank 55.

この実施の形態では、処理水槽55内の処理水によって膜分離装置38を逆洗するために、配管61、逆洗ポンプ62、弁90、配管63,64、弁65、配管66が設けられており、該配管66が配管51,52の接続点に接続されている。 In this embodiment, in order to backwash the membrane separation device 38 with the treated water in the treated water tank 55, a pipe 61, a backwash pump 62, a valve 90, pipes 63 and 64, a valve 65, and a pipe 66 are provided, and the pipe 66 is connected to the connection point of the pipes 51 and 52.

また、膜分離装置44を逆洗するために、配管63,64の接続点から分岐した配管67が、弁68、配管69によって、配管56,57の接続点に接続されている。 In addition, in order to backwash the membrane separation device 44, a pipe 67 branched off from the connection point of pipes 63 and 64 is connected to the connection point of pipes 56 and 57 via a valve 68 and a pipe 69.

この実施の形態においても、逆洗ポンプ62の始動時にポンプ62の吐出水を処理水槽55に返送するための弁90,91、配管92が設けられている。 In this embodiment, valves 90 and 91 and piping 92 are also provided to return the discharge water from the backwash pump 62 to the treatment water tank 55 when the backwash pump 62 is started.

図3は、膜分離装置38を逆洗し、膜分離装置44で濾過を行っている状態を示している。この状態ではポンプ33,62が作動し、弁35,41,47,58,65,90が開とされ、その他の弁は閉とされている。 Figure 3 shows the state in which membrane separation device 38 is backwashed and filtration is performed by membrane separation device 44. In this state, pumps 33 and 62 are operating, valves 35, 41, 47, 58, 65, and 90 are open, and the other valves are closed.

反応槽31内の生物処理液は、配管32、給水ポンプ33、配管34、弁35、配管36,37を通って膜分離装置38の一次側に供給される。膜分離装置38の二次側には、後述の通り逆洗水が供給されている。一次側に供給された生物処理液と膜38aを二次側から一次側に透過してきた逆洗排水とが混ざり合って膜分離装置38の一次側から、配管39,40、弁41、配管42,43を通って膜分離装置44の一次側に供給される。膜44aを透過しなかった濃縮水は、膜分離装置44の一次側から、配管45,46、弁47、配管48,49を通って反応槽31に返送される。 The biological treatment liquid in the reaction tank 31 is supplied to the primary side of the membrane separation device 38 through pipe 32, water supply pump 33, pipe 34, valve 35, and pipes 36 and 37. Backwash water is supplied to the secondary side of the membrane separation device 38 as described below. The biological treatment liquid supplied to the primary side and the backwash wastewater that has permeated the membrane 38a from the secondary side to the primary side are mixed and supplied from the primary side of the membrane separation device 38 to the primary side of the membrane separation device 44 through pipes 39 and 40, valve 41, and pipes 42 and 43. The concentrated water that has not permeated the membrane 44a is returned from the primary side of the membrane separation device 44 to the reaction tank 31 through pipes 45 and 46, valve 47, and pipes 48 and 49.

膜分離装置44の膜44aを透過した処理水は、膜分離装置44の二次側から、配管56,57、弁58、配管59を通って処理水槽55に導入される。 The treated water that has permeated the membrane 44a of the membrane separation device 44 is introduced into the treated water tank 55 from the secondary side of the membrane separation device 44 through pipes 56 and 57, valve 58, and pipe 59.

処理水槽55内の処理水の一部は、配管61、逆洗ポンプ62、配管63,64,66,51及び弁90,65を通って膜分離装置38の二次側に供給され、膜38aが逆洗される。 A portion of the treated water in the treated water tank 55 is supplied to the secondary side of the membrane separation device 38 through pipe 61, backwash pump 62, pipes 63, 64, 66, 51, and valves 90 and 65, and the membrane 38a is backwashed.

図4は、膜分離装置38で濾過を行い、膜分離装置44を逆洗している状態を示している。この状態ではポンプ33,62が作動し、弁35,41,47,53,68,90が開とされ、その他の弁は閉とされている。 Figure 4 shows the state in which filtration is performed in membrane separation device 38 and membrane separation device 44 is backwashed. In this state, pumps 33 and 62 are operating, valves 35, 41, 47, 53, 68, and 90 are open, and the other valves are closed.

反応槽31内の生物処理液は、配管32、給水ポンプ33、配管34、弁35、配管36,37を通って膜分離装置38の一次側に供給される。膜38aを透過しなかった濃縮水は、膜分離装置38の一次側から、配管39,40、弁41、配管42,43を通って膜分離装置44の一次側に供給される。膜分離装置44の二次側には、配管61、逆洗ポンプ62、配管63,67,69,56及び弁90,68を通り、逆洗水が供給されている。一次側に供給された膜分離装置38からの液と膜44aを二次側から一次側に透過してきた逆洗排水とが混ざり合って、膜分離装置44の一次側から、配管45,46、弁47、配管48,49を通って反応槽31に返送される。 The biological treatment liquid in the reaction tank 31 is supplied to the primary side of the membrane separation device 38 through pipe 32, water supply pump 33, pipe 34, valve 35, pipes 36 and 37. The concentrated water that has not permeated the membrane 38a is supplied from the primary side of the membrane separation device 38 through pipes 39 and 40, valve 41, pipes 42 and 43 to the primary side of the membrane separation device 44. Backwash water is supplied to the secondary side of the membrane separation device 44 through pipe 61, backwash pump 62, pipes 63, 67, 69, 56, and valves 90 and 68. The liquid from the membrane separation device 38 supplied to the primary side and the backwash wastewater that has permeated the membrane 44a from the secondary side to the primary side are mixed together and returned from the primary side of the membrane separation device 44 to the reaction tank 31 through pipes 45 and 46, valve 47, pipes 48 and 49.

膜分離装置38の膜38aを透過した処理水は、膜分離装置38の二次側から、配管51,52、弁53、配管54を通って処理水槽55に導入される。 The treated water that has permeated the membrane 38a of the membrane separation device 38 is introduced into the treated water tank 55 from the secondary side of the membrane separation device 38 through pipes 51 and 52, valve 53, and pipe 54.

なお、図3,4の逆洗を行うに際して逆洗ポンプ62を始動させる場合は、図1(a)の場合と同様の立上げ操作を行う。即ち、逆洗ポンプ62を始動させるときには、弁90を閉、弁91を開として逆洗ポンプ62を始動させ、ポンプ吐出水を処理水槽55に返送する。そして、ポンプ62の出力が十分に大きくなってから図3,4のように弁90を開、弁91を閉とし、逆洗を行う。後述の図6,7の場合も同様である。 When starting the backwash pump 62 to perform the backwash in Figures 3 and 4, the same start-up operation is performed as in Figure 1(a). That is, when starting the backwash pump 62, valve 90 is closed, valve 91 is opened, the backwash pump 62 is started, and the pump discharge water is returned to the treatment water tank 55. Then, once the output of the pump 62 has become sufficiently large, valve 90 is opened and valve 91 is closed as shown in Figures 3 and 4, and backwash is performed. The same applies to the cases of Figures 6 and 7 described below.

図2~4では、膜分離装置38,44の一次側に生物処理液を上記の方向(以下、順方向ということがある。)に通水しているが、次に説明する図5~7では膜分離装置38,44の一次側に該順方向とは反対方向(以下、逆方向ということがある。)に生物処理液を通水している。 In Figures 2 to 4, the biological treatment liquid is passed through the primary side of the membrane separation devices 38, 44 in the above-mentioned direction (hereinafter sometimes referred to as the forward direction), but in Figures 5 to 7, which will be explained next, the biological treatment liquid is passed through the primary side of the membrane separation devices 38, 44 in the opposite direction to the forward direction (hereinafter sometimes referred to as the reverse direction).

図5は、膜分離装置38,44を逆方向通水による濾過運転を行っている状態を示している。この状態では給水ポンプ33が作動し、逆洗ポンプ62が停止している。また、弁53,58,72,76,82が開とされ、その他の弁は閉とされている。 Figure 5 shows the membrane separation devices 38 and 44 in a state where they are performing filtration operation with reverse water flow. In this state, the water supply pump 33 is operating and the backwash pump 62 is stopped. In addition, valves 53, 58, 72, 76, and 82 are open, and the other valves are closed.

反応槽31内の生物処理液は、配管32、給水ポンプ33、配管34,71、弁72、配管73,39を通って膜分離装置38の一次側に供給される。膜38aを透過しなかった濃縮水は、膜分離装置38の一次側から、配管37,75、弁76、配管77,45を通って膜分離装置44の一次側に供給される。膜44aを透過しなかった濃縮水は、膜分離装置44の一次側から、配管43,81、弁82、配管83,49を通って反応槽31に返送される。 The biological treatment liquid in the reaction tank 31 is supplied to the primary side of the membrane separation device 38 through pipe 32, water supply pump 33, pipes 34 and 71, valve 72, and pipes 73 and 39. The concentrated water that did not permeate the membrane 38a is supplied from the primary side of the membrane separation device 38 through pipes 37 and 75, valve 76, and pipes 77 and 45 to the primary side of the membrane separation device 44. The concentrated water that did not permeate the membrane 44a is returned from the primary side of the membrane separation device 44 to the reaction tank 31 through pipes 43 and 81, valve 82, and pipes 83 and 49.

膜分離装置38の膜38aを透過した処理水は、膜分離装置38の二次側から、配管51,52、弁53、配管54を通って処理水槽55に導入される。膜分離装置44の膜44aを透過した処理水は、膜分離装置44の二次側から、配管56,57、弁58、配管59を通って処理水槽55に導入される。 The treated water that has permeated the membrane 38a of the membrane separation device 38 is introduced from the secondary side of the membrane separation device 38 through pipes 51 and 52, valve 53, and pipe 54 into the treated water tank 55. The treated water that has permeated the membrane 44a of the membrane separation device 44 is introduced from the secondary side of the membrane separation device 44 through pipes 56 and 57, valve 58, and pipe 59 into the treated water tank 55.

図6は、膜分離装置38を逆洗し、膜分離装置44で逆方向通水による濾過を行っている状態を示している。この状態ではポンプ33,62が作動し、弁58,65,72,76,82,90が開とされ、その他の弁は閉とされている。 Figure 6 shows the state in which the membrane separation device 38 is backwashed and filtration is performed by reverse water flow in the membrane separation device 44. In this state, the pumps 33 and 62 are operating, the valves 58, 65, 72, 76, 82, and 90 are open, and the other valves are closed.

反応槽31内の生物処理液は、配管32、給水ポンプ33、配管34,71、弁72、配管73,39を通って膜分離装置38の一次側に供給される。膜分離装置38の二次側には、配管61、逆洗ポンプ62、配管63,64,66,51及び弁90,65を通り逆洗水が供給されている。一次側に供給された生物処理液と膜38aを二次側から一次側に透過してきた逆洗排水とが混ざり合って膜分離装置38の一次側から、配管37,75、弁76、配管77,45を通って膜分離装置44の一次側に供給される。膜44aを透過しなかった濃縮水は、膜分離装置44の一次側から、配管43,81、弁82、配管83,49を通って反応槽31に返送される。 The biological treatment liquid in the reaction tank 31 is supplied to the primary side of the membrane separation device 38 through the pipe 32, the water supply pump 33, the pipes 34 and 71, the valve 72, and the pipes 73 and 39. Backwash water is supplied to the secondary side of the membrane separation device 38 through the pipe 61, the backwash pump 62, the pipes 63, 64, 66 and 51, and the valves 90 and 65. The biological treatment liquid supplied to the primary side and the backwash wastewater that has permeated the membrane 38a from the secondary side to the primary side are mixed and supplied from the primary side of the membrane separation device 38 to the primary side of the membrane separation device 44 through the pipes 37 and 75, the valve 76, and the pipes 77 and 45. The concentrated water that has not permeated the membrane 44a is returned from the primary side of the membrane separation device 44 to the reaction tank 31 through the pipes 43 and 81, the valve 82, and the pipes 83 and 49.

膜分離装置44の膜44aを透過した処理水は、膜分離装置44の二次側から、配管56,57、弁58、配管59を通って処理水槽55に導入される。 The treated water that has permeated the membrane 44a of the membrane separation device 44 is introduced into the treated water tank 55 from the secondary side of the membrane separation device 44 through pipes 56 and 57, valve 58, and pipe 59.

図7は、膜分離装置38で濾過を行い、膜分離装置44を逆洗している状態を示している。この状態ではポンプ33,62が作動し、弁53,68,72,76,82,90が開とされ、その他の弁は閉とされている。 Figure 7 shows the state in which filtration is performed in the membrane separation device 38 and the membrane separation device 44 is backwashed. In this state, the pumps 33 and 62 are operating, the valves 53, 68, 72, 76, 82, and 90 are open, and the other valves are closed.

反応槽31内の生物処理液は、配管32、給水ポンプ33、配管34,71、弁72、配管73,39を通って膜分離装置38の一次側に供給される。膜38aを透過しなかった濃縮水は、膜分離装置38の一次側から、配管37,75、弁76、配管77,45を通って膜分離装置44の一次側に供給される。膜分離装置44の二次側には、配管61、逆洗ポンプ62、配管63,67,69,56及び弁90,68を通り、逆洗水が供給されている。一次側に供給された膜分離装置38からの液と膜44aを二次側から一次側に透過してきた逆洗排水とが混ざり合って、膜分離装置44の一次側から、配管43,81、弁82、配管83,49を通って反応槽31に返送される。 The biological treatment liquid in the reaction tank 31 is supplied to the primary side of the membrane separation device 38 through the pipe 32, the water supply pump 33, the pipes 34, 71, the valve 72, and the pipes 73, 39. The concentrated water that has not permeated the membrane 38a is supplied from the primary side of the membrane separation device 38 through the pipes 37, 75, the valve 76, and the pipes 77, 45 to the primary side of the membrane separation device 44. Backwash water is supplied to the secondary side of the membrane separation device 44 through the pipe 61, the backwash pump 62, the pipes 63, 67, 69, 56, and the valves 90, 68. The liquid from the membrane separation device 38 supplied to the primary side and the backwash wastewater that has permeated the membrane 44a from the secondary side to the primary side are mixed together and returned from the primary side of the membrane separation device 44 to the reaction tank 31 through the pipes 43, 81, the valve 82, and the pipes 83, 49.

膜分離装置38の膜38aを透過した処理水は、膜分離装置38の二次側から、配管51,52、弁53、配管54を通って処理水槽55に導入される。 The treated water that has permeated the membrane 38a of the membrane separation device 38 is introduced into the treated water tank 55 from the secondary side of the membrane separation device 38 through pipes 51 and 52, valve 53, and pipe 54.

図2~4に示す順方向通水と、図5~7に示す逆方向通水とを交互に行うことにより、膜分離装置38,44の入口付近に付着した付着物を、通水方向切替によって除去することができる。 By alternately passing water in the forward direction as shown in Figures 2 to 4 and passing water in the reverse direction as shown in Figures 5 to 7, deposits that have adhered near the inlets of the membrane separation devices 38 and 44 can be removed by switching the water flow direction.

すなわち、順方向通水を行うと、膜分離装置38の配管37側の入口付近及び膜分離装置44の配管43側の入口付近にそれぞれ汚泥、析出無機物、膜剥離物等が付着してくる。順方向通水を逆方向通水に切り替えると、順方向通水時に膜分離装置38の配管37側の入口付近に付着した付着物は、配管37から配管75側に流出し、膜分離装置44の配管43側の入口付近に付着した付着物は配管43から配管81側に流出する。 That is, when water is passed in the forward direction, sludge, precipitated inorganic matter, membrane peelings, etc. adhere to the vicinity of the inlet on the pipe 37 side of the membrane separation device 38 and the vicinity of the inlet on the pipe 43 side of the membrane separation device 44. When the forward water flow is switched to the reverse water flow, the deposits that adhered to the vicinity of the inlet on the pipe 37 side of the membrane separation device 38 during the forward water flow flow out from the pipe 37 to the pipe 75 side, and the deposits that adhered to the vicinity of the inlet on the pipe 43 side of the membrane separation device 44 flow out from the pipe 43 to the pipe 81 side.

逆方向通水時に膜分離装置38の配管39側の入口付近及び膜分離装置44の配管45側の入口付近に付着した付着物も、同様に順方向通水に切り替えたときにそれぞれ配管40側、配管46側にそれぞれ流出する。 When water is flowing in the reverse direction, deposits that have adhered near the inlet of membrane separation device 38 on the pipe 39 side and near the inlet of membrane separation device 44 on the pipe 45 side also flow out to pipe 40 and pipe 46, respectively, when water is switched to flowing in the forward direction.

1~8時間毎に膜モジュールの通泥方向を反転することで、付着物による流路閉塞を防止し、安定した濾過性能を保つことができる。 By reversing the direction of sludge flow through the membrane module every 1 to 8 hours, it is possible to prevent blockage of the flow path due to deposits and maintain stable filtration performance.

以下本発明で用いるのに好適な生物処理槽、膜分離装置及び好適な運転条件等について説明する。 The following describes the biological treatment tank, membrane separation device, and suitable operating conditions for use in the present invention.

<生物処理槽>
生物処理槽としては、好気、嫌気いずれのものでもよいが、槽外管状膜を用いた場合には、嫌気処理が好適である。この場合、槽内汚泥濃度は3,000~50,000mg/L、好ましくは8,000~40,000mg/Lで、特に20,000~30,000mg/Lが高負荷処理が可能、かつ、膜濾過性能が悪化しない点で好ましい。温度は25~40℃または45~60℃、好ましくは30~38℃、または50~58℃。槽内pHは6.5~8.0、好ましくは6.8~7.4で、必要に応じて槽外膜への汚泥循環ライン(膜から嫌気反応槽への戻りの配管49)にNaOH、NaHCOなどのアルカリ剤やHClなどの酸剤を添加してpH調整を行う。
<Biological treatment tank>
The biological treatment tank may be either aerobic or anaerobic, but when an external tubular membrane is used, anaerobic treatment is preferred. In this case, the sludge concentration in the tank is 3,000 to 50,000 mg/L, preferably 8,000 to 40,000 mg/L, and particularly 20,000 to 30,000 mg/L, which is preferred in terms of enabling high-load treatment and preventing deterioration of membrane filtration performance. The temperature is 25 to 40°C or 45 to 60°C, preferably 30 to 38°C, or 50 to 58°C. The pH in the tank is 6.5 to 8.0, preferably 6.8 to 7.4, and pH adjustment is performed by adding an alkaline agent such as NaOH or NaHCO3 or an acid agent such as HCl to the sludge circulation line to the external membrane (return pipe 49 from the membrane to the anaerobic reaction tank) as necessary.

<膜分離装置>
膜分離装置としては内圧式管状膜が好適である。
<Membrane separation device>
As the membrane separation device, an internal pressure type tubular membrane is preferred.

内圧式管状膜としては、内径(直径)3mm~10mmのチューブラが内部に複数本(例えば100~1000本)充填された膜モジュールで、汚泥は各チューブラの内部を流れるものが好適である。透過水がチューブラ外に浸み出し、各チューブラから浸み出した透過水が集められ、膜モジュールから処理水として排出される。膜の細孔径は0.01~1μm特に0.03~0.1μmが好ましい。 The internal pressure tubular membrane is preferably a membrane module with multiple tubulars (e.g. 100 to 1000 tubulars) with an inner diameter of 3 mm to 10 mm packed inside, with sludge flowing inside each tubular. The permeate seeps out of the tubulars, and the permeate that seeps out of each tubular is collected and discharged from the membrane module as treated water. The pore size of the membrane is preferably 0.01 to 1 μm, and more preferably 0.03 to 0.1 μm.

管状膜の汚泥入口と汚泥出口の配管に圧力センサーを取り付け、その中間の値を管状膜の一次側圧力とするなどして膜内の圧力を測定し、透過水側の配管に取り付けた圧力センサーで二次側圧力を測定する。 Pressure sensors are attached to the sludge inlet and outlet pipes of the tubular membrane, and the intermediate value is set as the primary pressure of the tubular membrane to measure the pressure inside the membrane, while a pressure sensor attached to the permeate side pipe measures the secondary pressure.

<膜濾過と逆洗の通水形態>
膜濾過工程においては、生物処理槽から汚泥を、チューブラ内の流速が好ましくは0.5~2m/sec、特に好ましくは0.8~1.5m/secとなるように流すのが好適である。濾過時のフラックスは0.1~0.8m/d、特に0.2~0.5m/dが好ましい。
<Water flow patterns of membrane filtration and backwash>
In the membrane filtration step, it is preferable to allow the sludge from the biological treatment tank to flow through the tubular filter at a flow rate of preferably 0.5 to 2 m/sec, and more preferably 0.8 to 1.5 m/sec. The flux during filtration is preferably 0.1 to 0.8 m/d, and more preferably 0.2 to 0.5 m/d.

逆洗工程においては、10~60分の濾過に対し、5~30秒間、フラックス4~10m/dで処理水による逆洗を行うのが好ましい。かかる膜濾過工程と逆洗工程とを交互に繰り返す形態で運転するのが好ましい。 In the backwashing process, it is preferable to perform backwashing with treated water for 5 to 30 seconds at a flux of 4 to 10 m/d for 10 to 60 minutes of filtration. It is preferable to operate in a form in which such membrane filtration process and backwashing process are repeated alternately.

<逆洗ポンプの立上げ運転>
逆洗ポンプを始動させるに際しては、濾過工程中において、逆洗工程に移行する10秒~5分前、好ましくは1~5分前に、処理水を処理水槽に循環させる形態で逆洗ポンプを起動し、逆洗ポンプの出力が規定の値にまで上昇後、バルブ切替えにより逆洗を開始するのが好ましい。
<Backwash pump startup operation>
When starting the backwash pump, it is preferable to start the backwash pump in a form that circulates the treated water in the treated water tank during the filtration process 10 seconds to 5 minutes, preferably 1 to 5 minutes, before moving to the backwash process, and after the output of the backwash pump has increased to a specified value, to start backwashing by switching the valve.

逆洗ポンプの該規定の出力は、生物処理装置の試運転時に、膜濾過時の管状膜内の圧力を測定し、これに膜の通水圧力を考慮したうえで、所定の逆洗フラックスとなる出力をポンプの性能曲線(各ポンプ出力における吐出圧と吐出流量の検量関係)から決定するようにするのが好ましい。例えば、膜濾過時の管状膜内の圧力をP1とし、膜の通水圧力をP2とした場合、吐出圧P1+P2で所定の逆洗フラックスに相当する吐出流量となる出力をポンプの性能曲線から求めることにより、該規定の出力を設定する。なお、該規定の出力は、試運転時や実際の逆洗時の吐出量から設定することもできる。 The specified output of the backwash pump is preferably determined by measuring the pressure inside the tubular membrane during membrane filtration during trial operation of the biological treatment device, taking into account the membrane's water flow pressure, and then determining the output that results in a specified backwash flux from the pump's performance curve (the calibration relationship between the discharge pressure and discharge flow rate at each pump output). For example, if the pressure inside the tubular membrane during membrane filtration is P1 and the membrane's water flow pressure is P2, the specified output is set by finding from the pump's performance curve the output that results in a discharge flow rate equivalent to the specified backwash flux at discharge pressure P1 + P2. The specified output can also be set from the discharge volume during trial operation or actual backwashing.

上記実施の形態では、逆洗ポンプ13,62はON/OFF制御するが、給水ポンプ3,33は常にONであるから、膜が1段で膜濾過工程から逆洗工程に移行したときも循環通泥は継続しており、膜濾過時と同様に膜の一次側に内圧がかかっている。 In the above embodiment, the backwash pumps 13, 62 are controlled to be ON/OFF, but the water supply pumps 3, 33 are always ON, so even when the membrane is in one stage and the process transitions from the membrane filtration process to the backwash process, the circulating sludge continues, and internal pressure is applied to the primary side of the membrane, just as during membrane filtration.

膜モジュールを複数用いる際は、モジュールを直列、並列のいずれ、または両方の配置で用いてよいが、直列に配置する際はモジュール間に粗大な固形粒子が蓄積しないように、前述の図2~7の実施の形態のように、通泥方向を反転する際に、モジュール間の接続配管中の汚泥がモジュールを介さずに嫌気反応槽に返送されるような構成とするのが好ましい。 When multiple membrane modules are used, the modules may be arranged in series, parallel, or both. However, when arranged in series, it is preferable to configure the modules so that when the sludge flow direction is reversed, the sludge in the connecting piping between the modules is returned to the anaerobic reaction tank without passing through the modules, as in the embodiment of Figures 2 to 7 described above, in order to prevent the accumulation of coarse solid particles between the modules.

処理水槽の滞留時間は、処理水槽での微生物の増殖による逆洗水の汚濁を防止するため、0.5~8時間、特に1~4時間とするのが好ましい。 The retention time in the treatment tank is preferably 0.5 to 8 hours, and more preferably 1 to 4 hours, to prevent contamination of the backwash water due to the proliferation of microorganisms in the treatment tank.

このような条件で逆洗を行うことにより、槽外に設置された内圧式管状膜を用いた膜分離式生物処理装置において、逆洗をより効果的に行うことができ、膜濾過性能を長期間安定に維持できるようになる。 By performing backwashing under these conditions, backwashing can be performed more effectively in a membrane separation type biological treatment device that uses an internal pressure type tubular membrane installed outside the tank, and the membrane filtration performance can be maintained stably for a long period of time.

1,31 生物処理槽
3,33 給水ポンプ
5,38,44 膜分離装置
13,62 逆洗ポンプ
1, 31 Biological treatment tank 3, 33 Feed pump 5, 38, 44 Membrane separation device 13, 62 Backwash pump

Claims (3)

被処理水が一次側に通水され、膜を透過した処理水が二次側から処理水槽に取り出される膜分離装置であって、
処理水槽内の処理水を該二次側に供給するための逆洗ポンプを備えた膜分離装置において、
該逆洗ポンプの吐出水の供給先を、該二次側に供給することなく該処理水槽に供給する供給態様から、該二次側に供給する供給態様へ切り替える切替手段を備え
前記切替手段は、前記逆洗ポンプの始動後、逆洗ポンプの出力が基準値に達するまでの期間は吐出水を前記処理水槽に返送し、その後は吐出水を前記二次側に導入するように作動するものであることを特徴とする膜分離装置。
A membrane separation device in which water to be treated is passed through a primary side, and treated water that has permeated the membrane is taken out to a treated water tank from a secondary side,
A membrane separation apparatus equipped with a backwash pump for supplying treated water in a treatment tank to the secondary side,
A switching means is provided for switching the supply destination of the discharge water of the backwash pump from a supply mode in which the discharge water is supplied to the treatment water tank without being supplied to the secondary side to a supply mode in which the discharge water is supplied to the secondary side ,
A membrane separation apparatus characterized in that the switching means operates to return discharged water to the treatment water tank after the backwash pump is started until the output of the backwash pump reaches a reference value, and thereafter to introduce the discharged water into the secondary side .
請求項1の膜分離装置の運転方法であって、前記逆洗ポンプによって前記処理水槽内の処理水を前記二次側に供給して膜を逆洗する工程を有する膜分離装置の運転方法において、
該逆洗ポンプの始動後、該逆洗ポンプの出力が基準値に達するまでは逆洗ポンプの吐出水を前記処理水槽に返送し、その後、逆洗ポンプの吐出水を前記二次側に供給して逆洗を行うことを特徴とする膜分離装置の運転方法。
2. The method for operating a membrane separation apparatus according to claim 1, further comprising the step of supplying treated water in the treated water tank to the secondary side by the backwash pump to backwash the membrane,
A method for operating a membrane separation apparatus, characterized in that after starting the backwash pump, the discharge water of the backwash pump is returned to the treatment water tank until the output of the backwash pump reaches a reference value, and then the discharge water of the backwash pump is supplied to the secondary side to perform backwashing.
有機物含有排水を生物処理する反応槽と、反応槽外に設置され膜濾過により処理水を得る膜分離装置と、処理水を貯留する処理水槽と、該膜分離装置を間欠的に処理水で逆洗する逆洗ポンプとを有する生物処理装置において、
該逆洗ポンプの吐出水の供給先を、前記膜分離装置の二次側に供給することなく該処理水槽に供給する供給態様から、該二次側に供給する供給態様へ切り替える切替手段を備え
前記切替手段は、前記逆洗ポンプの始動後、該逆洗ポンプの出力が基準値に達するまでの期間は吐出水を前記処理水槽に返送し、その後は吐出水を前記二次側に導入するように作動するものであることを特徴とする生物処理装置。
A biological treatment device having a reaction tank for biologically treating wastewater containing organic matter, a membrane separation device installed outside the reaction tank for obtaining treated water by membrane filtration, a treated water tank for storing the treated water, and a backwash pump for intermittently backwashing the membrane separation device with the treated water,
A switching means is provided for switching the supply destination of the discharge water of the backwash pump from a supply mode in which the discharge water is supplied to the treated water tank without being supplied to the secondary side of the membrane separation device to a supply mode in which the discharge water is supplied to the secondary side ,
This biological treatment device is characterized in that the switching means operates to return the discharged water to the treatment tank after the backwash pump is started until the output of the backwash pump reaches a standard value, and thereafter to introduce the discharged water into the secondary side .
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