JP7584906B2 - 粘着シート - Google Patents
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- Publication number
- JP7584906B2 JP7584906B2 JP2020081452A JP2020081452A JP7584906B2 JP 7584906 B2 JP7584906 B2 JP 7584906B2 JP 2020081452 A JP2020081452 A JP 2020081452A JP 2020081452 A JP2020081452 A JP 2020081452A JP 7584906 B2 JP7584906 B2 JP 7584906B2
- Authority
- JP
- Japan
- Prior art keywords
- meth
- acrylate
- adhesive sheet
- manufactured
- ultraviolet absorber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000853 adhesive Substances 0.000 title claims description 134
- 230000001070 adhesive effect Effects 0.000 title claims description 134
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 74
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 68
- 239000012790 adhesive layer Substances 0.000 claims description 47
- 239000010410 layer Substances 0.000 claims description 26
- 238000005011 time of flight secondary ion mass spectroscopy Methods 0.000 claims description 21
- 238000002042 time-of-flight secondary ion mass spectrometry Methods 0.000 claims description 21
- 239000006096 absorbing agent Substances 0.000 claims description 18
- 238000001514 detection method Methods 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 98
- -1 2-ethylhexyl Chemical group 0.000 description 79
- 239000000178 monomer Substances 0.000 description 57
- 239000000047 product Substances 0.000 description 47
- 239000003431 cross linking reagent Substances 0.000 description 41
- 229920000058 polyacrylate Polymers 0.000 description 24
- 229920005601 base polymer Polymers 0.000 description 23
- 229920001971 elastomer Polymers 0.000 description 19
- 239000003999 initiator Substances 0.000 description 19
- 239000005060 rubber Substances 0.000 description 19
- 150000001875 compounds Chemical class 0.000 description 18
- 239000000758 substrate Substances 0.000 description 18
- 125000000524 functional group Chemical group 0.000 description 17
- 239000012948 isocyanate Substances 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 13
- 238000002834 transmittance Methods 0.000 description 13
- 239000011521 glass Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 150000002513 isocyanates Chemical class 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 9
- 230000001678 irradiating effect Effects 0.000 description 9
- 239000004814 polyurethane Substances 0.000 description 9
- 229920002635 polyurethane Polymers 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 8
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 229940059574 pentaerithrityl Drugs 0.000 description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 8
- 239000003504 photosensitizing agent Substances 0.000 description 8
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 7
- 239000004593 Epoxy Substances 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 6
- UZUNCLSDTUBVCN-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-(2-phenylpropan-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound C=1C(C(C)(C)CC(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C(O)C=1C(C)(C)C1=CC=CC=C1 UZUNCLSDTUBVCN-UHFFFAOYSA-N 0.000 description 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 125000000623 heterocyclic group Chemical group 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 239000012964 benzotriazole Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 125000003700 epoxy group Chemical group 0.000 description 4
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920013730 reactive polymer Polymers 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 4
- 229960002317 succinimide Drugs 0.000 description 4
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical class C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 239000013638 trimer Substances 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 3
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 3
- SITYOOWCYAYOKL-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(3-dodecoxy-2-hydroxypropoxy)phenol Chemical compound OC1=CC(OCC(O)COCCCCCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 SITYOOWCYAYOKL-UHFFFAOYSA-N 0.000 description 3
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229920002367 Polyisobutene Polymers 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 239000003522 acrylic cement Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 3
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- RBQRWNWVPQDTJJ-UHFFFAOYSA-N methacryloyloxyethyl isocyanate Chemical compound CC(=C)C(=O)OCCN=C=O RBQRWNWVPQDTJJ-UHFFFAOYSA-N 0.000 description 3
- UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 125000000542 sulfonic acid group Chemical group 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 2
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 2
- ZVEMLYIXBCTVOF-UHFFFAOYSA-N 1-(2-isocyanatopropan-2-yl)-3-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC(C(C)(C)N=C=O)=C1 ZVEMLYIXBCTVOF-UHFFFAOYSA-N 0.000 description 2
- IAUGBVWVWDTCJV-UHFFFAOYSA-N 1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound CCC(S(O)(=O)=O)NC(=O)C=C IAUGBVWVWDTCJV-UHFFFAOYSA-N 0.000 description 2
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 2
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- LEVFXWNQQSSNAC-UHFFFAOYSA-N 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexoxyphenol Chemical compound OC1=CC(OCCCCCC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 LEVFXWNQQSSNAC-UHFFFAOYSA-N 0.000 description 2
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 2
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 2
- UZOYICMDDCNJJG-UHFFFAOYSA-N 2-[[3-(benzotriazol-2-yl)-2-hydroxy-5-methylphenyl]methyl]-4,5,6,7-tetrahydroisoindole-1,3-dione Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C)=CC(CN2C(C3=C(CCCC3)C2=O)=O)=C1O UZOYICMDDCNJJG-UHFFFAOYSA-N 0.000 description 2
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 2
- KANZWHBYRHQMKZ-UHFFFAOYSA-N 2-ethenylpyrazine Chemical compound C=CC1=CN=CC=N1 KANZWHBYRHQMKZ-UHFFFAOYSA-N 0.000 description 2
- QENRKQYUEGJNNZ-UHFFFAOYSA-N 2-methyl-1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(C)C(S(O)(=O)=O)NC(=O)C=C QENRKQYUEGJNNZ-UHFFFAOYSA-N 0.000 description 2
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 2
- JEHFRMABGJJCPF-UHFFFAOYSA-N 2-methylprop-2-enoyl isocyanate Chemical compound CC(=C)C(=O)N=C=O JEHFRMABGJJCPF-UHFFFAOYSA-N 0.000 description 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- XMIIGOLPHOKFCH-UHFFFAOYSA-N 3-phenylpropionic acid Chemical compound OC(=O)CCC1=CC=CC=C1 XMIIGOLPHOKFCH-UHFFFAOYSA-N 0.000 description 2
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- FROCQMFXPIROOK-UHFFFAOYSA-N 4-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]benzene-1,3-diol Chemical compound CC1=CC(C)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(O)=CC=2)O)=N1 FROCQMFXPIROOK-UHFFFAOYSA-N 0.000 description 2
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- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
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- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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Description
1つの実施形態においては、上記第2表面から厚み方向における深さ1μmまでの範囲でのTOF-SIMSによる紫外線吸収剤の検出強度の最大値S2と、上記粘着剤層の厚み方向中心点におけるTOF-SIMSによる紫外線吸収剤の検出強度Cとが、S2/C≧1.1の関係を満足する。
図1(a)は、本発明の1つの実施形態による粘着シートの概略断面図である。この実施形態による粘着シート100は、粘着剤層10を備える。粘着剤層10は、紫外線吸収剤を含む。図1(b)は、本発明の1つの実施形態による粘着シートの概略断面図である。この実施形態による粘着シート200は、基材20をさらに備え、基材20の少なくとも片側に粘着剤層10が配置される。図示していないが、本発明の粘着シートは、使用に供するまでの間、粘着面を保護する目的で、粘着剤層の外側に剥離ライナーが設けられていてもよい。また、粘着シートは、本発明の効果が得られる限り、任意の適切なその他の層をさらに含んでいてもよい。1つの実施形態において、本発明の粘着シートは、図1(a)に示すように、粘着剤層1層のみから構成される。別の実施形態においては、本発明の粘着シートは、図1(b)に示すように、基材および粘着剤層を含み、粘着剤層は基材に直接(すなわち、その他の層を介することなく)配置される。本発明においては、後述のように、粘着剤層の粘着力低下および高弾性率化に伴うひずみの発生により被着体を良好に剥離することが可能であるため、粘着シートから被着体を分離するための粘着剤層以外の層(いわゆる分離層)を設けることなく粘着シートを構成することが可能である。
上記粘着剤層の厚みは、好ましくは20μm以下である。このような範囲であれば、剥離の際のレーザー出力をより低くすることを可能とし、剥離発現性に優れる粘着シートを得ることができる。粘着剤層の厚みは、10μm以下であることがより好ましく、8μm以下であることがさらに好ましく、1μm~8μmであることより好ましい。このような範囲であれば、上記効果が顕著となる。
感圧粘着剤としては、例えば、アクリル系粘着剤、ゴム系粘着剤、ビニルアルキルエーテル系粘着剤、シリコーン系粘着剤、ポリエステル系粘着剤、ポリアミド系粘着剤、ウレタン系粘着剤、スチレン-ジエンブロック共重合体系粘着剤、等が挙げられる。なかでも好ましくは、アクリル系粘着剤またはゴム系粘着剤であり、より好ましくはアクリル系粘着剤である。なお、上記粘着剤は、単独で、または2種以上組み合わせて用いてもよい。
1つの実施形態においては、活性エネルギー線硬化型粘着剤として、母剤となるベースポリマーと、該ベースポリマーと結合可能な活性エネルギー線反応性化合物(モノマーまたはオリゴマー)とを含む活性エネルギー線硬化型粘着剤(A1)が用いられる。別の実施形態においては、ベースポリマーとして活性エネルギー線反応性ポリマーを含む活性エネルギー線硬化型粘着剤(A2)が用いられる。好ましくは、上記ベースポリマーは、光重合開始剤と反応し得る官能基を有する。該官能基としては、例えば、ヒドロキシル基、カルボキシル基等が挙げられる。
紫外線吸収剤としては、紫外線(例えば、波長355nm)を吸収する化合物であれば、任意の適切な紫外線吸収剤が用いられ得る。紫外線吸収剤としては、例えば、ベンゾトリアゾール系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤、トリアジン系紫外線吸収剤、サリチレート系紫外線吸収剤、シアノアクリレート系紫外線吸収剤等が挙げられる。なかでも好ましくは、トリアジン系紫外線吸収剤またはベンゾトリアゾール系紫外線吸収剤であり、特に好ましくはトリアジン系紫外線吸収剤である。特に、粘着剤Aとしてアクリル系粘着剤を用いる場合に、当該アクリル系粘着剤のベースポリマーとの相溶性が高いことから、トリアジン系紫外線吸収剤は好ましく用いられ得る。トリアジン系紫外線吸収剤は、水酸基を有する化合物から構成されていることがより好ましく、ヒドロキシフェニルトリアジン系化合物から構成された紫外線吸収剤(ヒドロキシフェニルトリアジン系紫外線吸収剤)であることが特に好ましい。
上記基材は、任意の適切な樹脂から構成され得る。該樹脂としては、例えば、ポリエチレン系樹脂、ポリプロピレン系樹脂、ポリブテン系樹脂、ポリメチルペンテン系樹脂等のポリオレフィン系樹脂、ポリウレタン系樹脂、ポリエステル系樹脂、ポリイミド系樹脂、ポリエーテルケトン系樹脂、ポリスチレン系樹脂、ポリ塩化ビニル系樹脂、ポリ塩化ビニリデン系樹脂、フッ素系樹脂、シリコン系樹脂、セルロース系樹脂、アイオノマー樹脂等が挙げられる。なかでも好ましくはポリオレフィン系樹脂である。
上記粘着シートは、任意の適切な方法により製造され得る。粘着シートは、例えば、基材または剥離ライナー上に、上記粘着剤を塗工して得られ得る。塗工方法としては、バーコーター塗工、エアナイフ塗工、グラビア塗工、グラビアリバース塗工、リバースロール塗工、リップ塗工、ダイ塗工、ディップ塗工、オフセット印刷、フレキソ印刷、スクリーン印刷など種々の方法を採用することができる。また、別途、剥離ライナーに粘着剤層を形成した後、それを基材に貼り合せる方法等を採用してもよい。粘着剤を空気中で乾燥する場合、空気側の表面に紫外線吸収剤が偏在する傾向がある。また、基材や剥離ライナーの表面特性によって、偏在の程度が変化する場合がある。いずれかの表面近傍でのみ紫外線吸収剤が偏在する場合、紫外線吸収剤が偏在した方の面を第1表面とし、当該面が被着体載置面となり得る。
本発明の粘着シートは、任意の適切な被加工部材(例えば、電子部品)を加工する際に、当該被加工部材を仮固定する際に用いられ得る。本発明の粘着シートの使用方法としては、例えば、(i)被着シートに被加工部材を貼着して固定し、(ii)該被加工部材を加工し、(iii)粘着シートの粘着剤層全体に活性エネルギー線(例えば、紫外線)を照射して、粘着シートの粘着力を低下させ、(iv)剥離性発現を所望する箇所にレーザー光を照射して、被加工部材を剥離させるようにして使用する方法が挙げられる。当該方法によれば、被加工部材を自然落下により剥離させることが可能となる。また、複数の被加工部材を仮固定した場合には、その一部のみを剥離させることも可能となる。本発明の粘着シートを用いれば、自然落下するほどまでに粘着力を低下させることができるため、非常に小さい(例えば、50μm角)被加工部材であっても、個々別々に剥離させることが可能である。
粘着剤層の断面について、Arガスクラスターイオンエッチング法によるを行い、粘着剤層の厚み方向における紫外線吸収剤の分布を確認した。紫外線吸収剤の構造に基づき、TOF-SIMSで紫外線吸収剤起因の成分を検出した。得られた紫外線吸収剤の存在分布に基づき、粘着剤層の一方の面(第1表面)から厚み方向における深さ1μmまでの範囲での紫外線吸収剤の検出強度の最大値S1と、他方の面(第2表面)から厚み方向における深さ1μmまでの範囲での紫外線吸収剤の検出強度の最大値S2と、粘着剤層の厚み方向中心点における紫外線吸収剤の検出強度Cとから、S1/CおよびS2/Cを求めた。
なお、TOF-SIMS分析の測定条件は、以下のとおりとした。
装置名:アルバック・ファイ製TRIFT V
エッチングイオン:Arガスクラスターイオン(Arn+)
エッチングイオン加速電圧:17kV
エッチング面積:400μm角
照射した一次イオン:Bi3 2+
一次イオン加速電圧:30kV
測定面積:100μm角
測定極性:負イオン
※測定には帯電補正用中和銃を使用。
ヘイズメーター(商品名「HAZE METER HM-150」,村上色彩技術研究所製)を使用し、入射光がスライドグラスの面に対して垂直に入射するように大型スライドグラス(松浪硝子製、商品名「S9111」)をセットし、ヘイズ値を測定した。その後、粘着シートのPETセパレーターを剥離し、ヘイズ値測定後の大型スライドグラスにハンドローラーを用い貼り合わせ、もう一方の面のPETセパレーターを剥離した状態で、再度ヘイズ値を測定した。得られたヘイズ値から、スライドグラスのみのヘイズ値を減算し、粘着シートのヘイズ値とした。
粘着シートのPETセパレーターを剥離し、大型スライドグラス(松浪硝子製、商品名「S9111」)にハンドローラーを用い貼り合わせ、もう一方の面のPETセパレーターを剥離した状態で、測定を行った。具体的には、分光光度計(商品名「分光光度計 U-4100」,日立ハイテクサイエンス製)を使用して、大型スライドグラス上の粘着シートについて、粘着シート自体における波長355nmの透過率を測定した。
粘着シートの粘着剤層の一方の面(第1表面)をSUS403に貼着して、当該粘着シートの対する粘着力を、JIS Z 0237:2000に準じた方法(貼り合わせ条件:2kgローラー1往復、引張速度:300mm/min、剥離角度180°、測定温度:23℃)により、測定した。
・第1表面の剥離性
粘着シートの第2表面側のPETセパレーターを剥離し、大型スライドグラス(松浪硝子製、商品名「S9111」)にハンドローラーを用い貼り合わせた。その後、もう一方の面(第1表面)のPETセパレーターを剥離し、粘着面に対し100μm角のシリコンチップを貼り合わせた。
実施例7の粘着シートについては、スライドグラス面側から紫外線照射装置(日東精機製、商品名「UM-810」)を用い、高圧水銀灯の紫外線(特定波長:365nm、積算光量:300mJ/cm2)を全面に照射した。
波長355nmのレーザー光を、照射面積:80μmφ、出力0.1Wで、大型スライドグラスト側から狙いの部材位置にのみ照射し(1plus per chip)、自然落下した場合を合格(〇)、自然落下しなかった場合を不合格(×)とした。
・第2表面の剥離性
また、粘着剤層の表裏を入れ替えたこと以外は、「第1表面の剥離性」と同様にして、評価を行った。すなわち、粘着シートの第1表面側のPETセパレーターを剥離し、大型スライドグラス(松浪硝子製、商品名「S9111」)にハンドローラーを用い貼り合わせた。その後、もう一方の面(第2表面)のPETセパレーターを剥離し、粘着面に対し100μm角のシリコンチップを貼り合わせた。
実施例7の粘着シートについては、スライドグラス面側から紫外線照射装置(日東精機製、商品名「UM-810」)を用い、高圧水銀灯の紫外線(特定波長:365nm、積算光量:300mJ/cm2)を全面に照射した。
波長355nmのレーザー光を、照射面積:80μmφ、出力0.1Wで、大型スライドグラスト側から狙いの部材位置にのみ照射し(1plus per chip)、自然落下した場合を合格(〇)、自然落下しなかった場合を不合格(×)とした。
2-メトキシエチルアクリレート100重量部、アクリロイルモルホリン27重量部、アクリル酸2-ヒドロキシエチル22重量部を混合して、モノマー組成物を調製した。
次いで、窒素導入管、温度計、攪拌機を備えた反応容器に窒素を導入し、窒素雰囲気下で、トルエン500重量部、上記モノマー組成物149量部、および、ベンゾイルパーオキサイド(BPO)0.3重量部を仕込み、60℃で5時間攪拌した。その後、室温まで冷却し、2-メタクリロイルオキシエチルイソシアネート24重量部を添加し反応させて、共重合体中のアクリル酸2-ヒドロキシエチルの側鎖末端OH基にNCO基を付加し、末端に炭素-炭素二重結合を有する重量平均分子量100万のアクリル系ポリマーIを含有するアクリル系ポリマー溶液Iを得た。
アクリル酸2-エチルヘキシルエステル89重量部、ヒドロキシエチルアクリレート11重量部を混合して、モノマー組成物を調製した。
次いで、窒素導入管、温度計、攪拌機を備えた反応容器に窒素を導入し、窒素雰囲気下で、トルエン43重量部、上記モノマー組成物100重量部、および、アゾイソブチルニトリル(AIBN)0.2重量部を仕込み、60℃で4時間攪拌した。その後、室温まで冷却し、2-メタクリロイルオキシエチルイソシアネート12重量部を添加し反応させて、共重合体中のアクリル酸2-ヒドロキシエチルの側鎖末端OH基にNCO基を付加し、末端に炭素-炭素二重結合を有する重量平均分子量100万のアクリル系ポリマーIIを含有するアクリル系ポリマー溶液IIを得た。
(粘着剤の調製)
アクリルポリマーIを100重量部含むアクリル系ポリマー溶液Iに、架橋剤(日本ポリウレタン工業株式会社、商品名「コロネートL」)3重量部、紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)20重量部を加え粘着剤(1)を得た。
(粘着シート)
PETセパレーター(厚さ:38μm)のシリコーン処理面に、上記粘着剤(1)を塗布し、その後、130℃で2分間加熱して、第1表面が露出した厚さ5μmの粘着剤層を形成した。
ハンドローラーを用いて、粘着剤層の第1表面上にPETセパレーターを貼り合わせ、セパレーター付粘着シートを得た。
得られた粘着シートを上記評価に供した。結果を表1に示す。また、「紫外線吸収剤の偏在」評価において測定したTOF-SIMS分析チャートを図2に示す。
紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)の配合量を5重量部としたこと以外は、実施例1と同様にして、セパレーター付粘着シートを得た。得られた粘着シートを上記評価に供した。結果を表1に示す。
紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)20重量部に代えて、紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 405」)10重量部を用いたこと以外は、実施例1と同様にして、セパレーター付粘着シートを得た。得られた粘着シートを上記評価に供した。結果を表1に示す。
紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)20重量部に代えて、紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 928」)10重量部を用いたこと以外は、実施例1と同様にして、セパレーター付粘着シートを得た。得られた粘着シートを上記評価に供した。結果を表1に示す。
紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)20重量部に代えて、紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 928」)5重量部を用いたこと以外は、実施例1と同様にして、セパレーター付粘着シートを得た。得られた粘着シートを上記評価に供した。結果を表1に示す。
紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)20重量部に代えて、紫外線吸収剤(ケミプロ化成製、商品名「KEMISORB102L」)5重量部を用いたこと以外は、実施例1と同様にして、セパレーター付粘着シートを得た。得られた粘着シートを上記評価に供した。結果を表1に示す。
(粘着剤の調製)
アクリルポリマーIを100重量部含むアクリル系ポリマー溶液Iに、架橋剤(日本ポリウレタン工業製、商品名「コロネートL」)3重量部、光重合開始剤(BASF社製、商品名「イルガキュア369」)3重量部)3重量部、紫外線吸収剤(ケミプロ化成製、商品名「KEMISORB102L」)5重量部加え粘着剤(7)を得た。
(粘着シートの作製)
PETセパレーター(厚さ:38μm)のシリコーン処理面に、上記粘着剤(7)を塗布し、その後、130℃で2分間加熱して、第1表面が露出した厚さ5μmの粘着剤層を形成した。
ハンドローラーを用いて、粘着剤層の第1表面上にPETセパレーターを貼り合わせ、セパレーター付粘着シートを得た。
得られた粘着シートを上記評価に供した。結果を表1に示す。
紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)20重量部に代えて、紫外線吸収剤(ケミプロ化成製、商品名「KEMISORB111」)20重量部を用いたこと以外は、実施例1と同様にして、セパレーター付粘着シートを得た。得られた粘着シートを上記評価に供した。結果を表1に示す。
紫外線吸収剤を配合しなかったこと以外は、実施例1と同様にして、セパレーター付粘着シートを得た。得られた粘着シートを上記評価に供した。結果を表1に示す。
紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)20重量部に代えて、紫外線吸収剤(ケミプロ化成製、商品名「KEMISORB111」)5重量部を用いたこと以外は、実施例1と同様にして、セパレーター付粘着シートを得た。得られた粘着シートを上記評価に供した。結果を表1に示す。
(粘着剤の調製)
アクリルポリマーIIを100重量部含むアクリル系ポリマー溶液IIに、架橋剤(日本ポリウレタン工業株式会社、商品名「コロネートL」)3重量部、紫外線吸収剤(BASFジャパン製、商品名「Tinuvin 477」)5重量部を加え粘着剤(C3)を得た。
(粘着シート)
PETセパレーター(厚さ:38μm)のシリコーン処理面に、上記粘着剤(C3)を塗布し、その後、130℃で2分間加熱して、第1表面が露出した厚さ5μmの粘着剤層を形成した。
ハンドローラーを用いて、粘着剤層の第1表面上にPETセパレーターを貼り合わせ、セパレーター付粘着シートを得た。
得られた粘着シートを上記評価に供した。結果を表1に示す。
20 基材
100、200 粘着シート
Claims (2)
- 紫外線吸収剤を含む活性エネルギー線硬化型粘着剤から構成された粘着剤層を備え、
該粘着剤層が、第1表面と、該第1表面に対向する第2表面とを有し、
該第1表面から厚み方向における深さ1μmまでの範囲での飛行時間型二次イオン質量分析(TOF-SIMS)による紫外線吸収剤の検出強度の最大値S1と、該粘着剤層の厚み方向中心点におけるTOF-SIMSによる紫外線吸収剤の検出強度Cとが、S1/C≧1.1の関係を満足する、
粘着シート。 - 前記第2表面から厚み方向における深さ1μmまでの範囲でのTOF-SIMSによる紫外線吸収剤の検出強度の最大値S2と、前記粘着剤層の厚み方向中心点におけるTOF-SIMSによる紫外線吸収剤の検出強度Cとが、S2/C≧1.1の関係を満足する、請求項1に記載の粘着シート。
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