JP7464922B1 - Metal ion generation method - Google Patents
Metal ion generation method Download PDFInfo
- Publication number
- JP7464922B1 JP7464922B1 JP2023018810A JP2023018810A JP7464922B1 JP 7464922 B1 JP7464922 B1 JP 7464922B1 JP 2023018810 A JP2023018810 A JP 2023018810A JP 2023018810 A JP2023018810 A JP 2023018810A JP 7464922 B1 JP7464922 B1 JP 7464922B1
- Authority
- JP
- Japan
- Prior art keywords
- metal
- carbon
- electrons
- adhesive
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910021645 metal ion Inorganic materials 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 60
- 229910052751 metal Inorganic materials 0.000 claims abstract description 60
- 239000000463 material Substances 0.000 claims abstract description 30
- 239000000853 adhesive Substances 0.000 claims abstract description 28
- 230000001070 adhesive effect Effects 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 9
- 238000010000 carbonizing Methods 0.000 claims abstract description 7
- 238000004898 kneading Methods 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 55
- 229910052799 carbon Inorganic materials 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 29
- 229910052742 iron Inorganic materials 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 238000003763 carbonization Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 241000209094 Oryza Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000010903 husk Substances 0.000 description 4
- -1 iron ions Chemical class 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 239000005909 Kieselgur Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002313 adhesive film Substances 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000021321 essential mineral Nutrition 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000206761 Bacillariophyta Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000221535 Pucciniales Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Landscapes
- Carbon And Carbon Compounds (AREA)
Abstract
【課題】従来技術の上記問題点を解消し、金属電子の流れを妨害しないように限りなく密接接着して金属電子の流れ導電性を改善向上し金属イオン生成の効率促進を図ることができる金属イオン生成材の製造方法の提供。【解決手段】電気陰性度が2.4以下でイオン化傾向を持つ金属の多数の粉粒を水分含有の糊状接着剤と混煉する第１工程と、前記混煉済み材を炭化させる第２工程とから成る金属イオン生成材の製造方法。[Problem] To provide a method for manufacturing a metal ion generating material that can solve the above problems of the prior art, improve the conductivity of the metal electron flow by bonding as closely as possible so as not to impede the flow of metal electrons, and promote the efficiency of metal ion generation. [Solution] The method for manufacturing a metal ion generating material comprises a first step of kneading a large number of powder particles of a metal that has an electronegativity of 2.4 or less and a tendency to ionize with a moisture-containing paste-like adhesive, and a second step of carbonizing the kneaded material.
Description
本発明は、金属イオン生成材の製造方法に関する。 The present invention relates to a method for producing a metal ion generating material.
従来の製造方法は、鉄粉を水分含有の糊状接着剤を用いて接合。（特許文献１、２参照。）。 The conventional manufacturing method involves bonding iron powder with a water-containing paste-like adhesive (see Patent Documents 1 and 2).
しかしながら、従来の技術にあっては、特に、水分や吸湿で時間が経てば鉄が酸化し酸化膜を作る/水に溶けるクエン酸粉粒を配合すれば溶けて隙間をつくる。更に、不純物の介在は抵抗物となって鉄電子が流れ難い問題がある。
即ち、従来技術は、鉄粉粒と炭素粉粒の接着接合に糊系接着剤を使った場合の接合接着であって局部電池形成のために接着剤なしで直接密着したり、水分をゼロ無くす工夫の記述も概念も見当たらない。
だから、接合部分が極限まで薄い接着膜で密接.密着した接合とはいえミクロンの間隙が生じ導電性に障害が生まれていた。
しかも接合接着部全てが均一で極限まで薄い接着膜とは限らない。
また、製造に使用する接合接着剤に含まれる水分の介在で酸化反応が起こり発錆し鉄の性状を失い不良導体になる。更に、製造後の保管時に湿気を吸い触れるための酸化で発錆し鉄は性状を少しずつ失うので、２価鉄イオンの生成機能と局部電池形成と生成量は大きく低下する。
However, in the conventional technology, iron oxidizes over time due to moisture or moisture absorption, forming an oxide film, and when water-soluble citric acid powder is added, it dissolves and creates gaps. Furthermore, the presence of impurities creates a resistance that makes it difficult for iron electrons to flow.
In other words, the prior art relates to the use of a paste-based adhesive to bond iron powder particles and carbon powder particles, but there is no description or concept of direct adhesion without adhesive to form a local battery, or of any ingenuity in eliminating moisture to zero.
Therefore, even though the joint was tightly bonded with an extremely thin adhesive film, there were still gaps of microns that caused problems with conductivity.
Moreover, not all of the bonded joints are necessarily made of a uniform and extremely thin adhesive film.
In addition, the presence of moisture in the adhesive used in manufacturing causes an oxidation reaction, which causes rusting and the iron to lose its properties and become a poor conductor.Furthermore, when stored after manufacturing, iron rusts and loses its properties little by little due to oxidation caused by absorbing moisture and coming into contact with it, which significantly reduces the ability to generate divalent iron ions and the formation and amount of local batteries.
本発明の解決しようとする課題は、従来技術の上記問題点を解消し、金属と炭素との間の鉄電子の流れを妨害しないように限りなく密接接着して金属電子の流れ導電性を改善向上し金属イオン生成の効率促進を図ることができる金属イオン生成材の製造方法を提供することにある。 The problem that the present invention aims to solve is to provide a method for producing a metal ion generating material that can eliminate the above-mentioned problems of the conventional technology and can improve the conductivity of the metal electron flow by bonding the metal and carbon as closely as possible so as not to interfere with the flow of iron electrons between them, thereby promoting the efficiency of metal ion generation.
上記課題を解決するため請求項１記載の金属イオン生成方法は、
電気陰性度が２．４以下でイオン化傾向を持つ金属の粉粒を水分含有の糊状接着剤と混練する第１工程と、前記混練済み材を炭化させる第２工程とから成る製造方法で製造した金属イオン生成材を、水液中に没した状態にすることにより、水液を媒体にして金属／炭素（炭化された糊状接着剤）間で電位差が発生し局部電池を形成し、金属の電子が炭素へ継続して不可逆的に流れ、炭素に金属電子が満杯になるまで及び／又は金属が完全に金属電子を失うまで奪取され続け、金属に陽子が残り余って不安定になり、安定化するために金属イオンとなって水液の媒体中に溶出し続けることを特徴とする金属イオン生成方法。 In order to solve the above problems, the method for producing metal ions according to claim 1 comprises the steps of:
A metal ion generating method comprising a first step of kneading powder particles of a metal having an electronegativity of 2.4 or less and a tendency to ionize with a moisture-containing paste-like adhesive, and a second step of carbonizing the kneaded material, and by immersing the metal ion generating material in an aqueous solution, a potential difference is generated between the metal and carbon (carbonized paste-like adhesive) with the aqueous solution as a medium, forming a local battery, and electrons of the metal continue to flow irreversibly to the carbon, continuing to be stolen until the carbon is filled with metal electrons and/or the metal has completely lost its metal electrons, leaving protons in the metal, making it unstable, and turning into metal ions to stabilize and continuing to dissolve into the aqueous solution medium .
また、請求項２記載の金属イオン生成材の生成方法は、
炭素含有率が質量９０％以上の炭素粉を配合した接着剤に電気陰性度が２．４以下でイオン化傾向を持つ金属の粉粒を混練する第１工程と、前記混練済み材を炭化させる第２工程とから成る製造方法で製造した金属イオン生成材を、水液中に没した状態にすることにより、水液を媒体にして金属／炭素（炭化された糊状接着剤）間で電位差が発生し局部電池を形成し、金属の電子が炭素へ継続して不可逆的に流れ、炭素に金属電子が満杯になるまで及び／又は金属が完全に金属電子を失うまで奪取され続け、金属に陽子が残り余って不安定になり、安定化するために金属イオンとなって水液の媒体中に溶出し続けることを特徴とする金属イオン
生成方法。 The method for producing a metal ion generating material according to claim 2 further comprises the steps of:
A metal ion generating method comprising a first step of kneading metal powder particles having an electronegativity of 2.4 or less and a tendency to ionize with an adhesive containing carbon powder with a carbon content of 90% or more by mass, and a second step of carbonizing the kneaded material, and immersing the metal ion generating material in an aqueous solution, whereby a potential difference is generated between the metal/carbon (carbonized paste-like adhesive) with the aqueous solution as a medium to form a local battery, and electrons of the metal continue to flow irreversibly to the carbon, continuing to be taken away until the carbon is filled with metal electrons and/or the metal has completely lost its metal electrons, leaving protons in the metal, making it unstable, and turning into metal ions to stabilize and continuing to dissolve into the aqueous solution as a medium .
請求項１記載の金属イオン生成方法では、上述のように、電気陰性度が２．４以下でイオン化傾向を持つ金属の粉粒を水分含有の糊状接着剤と混練する第１工程と、前記混練済み材を炭化させる第２工程とから成る製造方法で製造した金属イオン生成材を、水液中に没した状態にすることにより、以下の効果が得られる。
即ち、金属と炭素（炭化された糊状接着剤）間は通電導電性を阻害しない密着接合した材だから水液中に没した状態にすると水液を媒体にして金属／炭素（炭化された糊状接着剤）間で電位差が発生し局部電池を形成、金属の電子が炭素へ継続して不可逆的に流れ、炭素に金属電子が満杯になるまで及び／又は金属が完全に金属電子を失うまで奪取され続けるので金属には陽子が残り余って不安定になる。安定化するために金属イオンとなって水液の媒体中に溶出し続ける効果。 In the metal ion generating method described in claim 1, as described above, the metal ion generating material produced by a manufacturing method comprising a first step of kneading metal powder particles having an electronegativity of 2.4 or less and a tendency to ionize with a moisture-containing paste-like adhesive, and a second step of carbonizing the kneaded material , is submerged in an aqueous liquid, thereby obtaining the following effects.
That is, since the metal and carbon (carbonized adhesive) are tightly bonded materials that do not inhibit electrical conductivity, when they are submerged in water, a potential difference occurs between the metal and carbon (carbonized adhesive), with the water as the medium, forming a local battery, and the metal's electrons continue to flow irreversibly to the carbon, continuing to be stolen until the carbon is full of metal electrons and/or the metal loses all metal electrons, leaving the metal with excess protons and making it unstable. This effect is that the metal ions continue to dissolve into the water medium to stabilize it.
請求項２記載の金属イオン生成材の製造方法では、上述のように、炭素含有率が質量９０％以上の炭素粉を配合した接着剤に電気陰性度が２．４以下でイオン化傾向を持つ金属の粉粒を混練する第１工程と、前記混練済み材を炭化させる第２工程とから成る製造方法で製造した金属イオン生成材を、水液中に没した状態に
することにより、以下の効果が得られる。
即ち、接合接着剤に炭素粉を添加し加熱炭化すれば、喩え接合接着剤の加熱炭化が不十分であっても確実に鉄と炭素は接着しているので添加した炭素粉が通電導通性を補完して金属をイオン化することができる。
接着剤や繋ぎ剤が炭化して溶けないので分離せず金属と炭素の密着性が失われない。
練り込み混合状態で加熱し炭化するから金属は接着剤または繋ぎ剤で覆われ、無酸素下での加熱炭化と相似になり還元される。
炭化物が金属の保護膜となって製造後の保管時に湿気との接触が遮断され金属の不導体膜の発生を防ぎ酸化による性状喪失問題は解消する。
加熱炭化処理で確実に水分は無くなり、製品を水に没するまで炭化物が金属を酸化から保護する。
用途としては、・板状に成形して利用・砕いて水液との接触面を増やし水域に散布・水中で研磨研削や砕粒化する材として使える効果。
炭素粉として、黒鉛粉や活性炭粉やコークス粉等があり炭素含有率が高ければ高いほど金属のイオン化に大変大切な役割を果たす。 In the manufacturing method of a metal ion generating material described in claim 2, as described above, the metal ion generating material produced by a manufacturing method comprising a first step of kneading metal powder particles having an electronegativity of 2.4 or less and a tendency to ionize with an adhesive containing carbon powder with a carbon content of 90% by mass or more, and a second step of carbonizing the kneaded material, is submerged in an aqueous liquid , thereby obtaining the following effects.
In other words, if carbon powder is added to a bonding adhesive and then heated and carbonized, even if the bonding adhesive is not sufficiently carbonized by heating, the iron and carbon are still bonded together, and the added carbon powder complements the electrical conductivity and can ionize the metal.
The adhesives and binders do not carbonize or melt, so they do not separate and the adhesion between the metal and carbon is not lost.
The metal is heated and carbonized in a kneaded mixed state, so that the metal is covered with an adhesive or binder and reduced in a manner similar to that of heating and carbonization in the absence of oxygen.
The carbide acts as a protective film for the metal, blocking contact with moisture during storage after manufacture, preventing the formation of a non-conductive film on the metal, and eliminating the problem of loss of properties due to oxidation.
The heating and carbonization process ensures that all moisture is removed, and the carbide protects the metal from oxidation until the product is immersed in water.
It can be used in plates, crushed to increase the contact area with water and spread in bodies of water, and used as a material for polishing, grinding, and granulating underwater.
Carbon powder includes graphite powder, activated carbon powder, coke powder, etc., and the higher the carbon content, the more important the role it plays in the ionization of metals.
なお、金属を鉄とした場合、発生する無垢な２価鉄イオンは多機能特性をもち水や水に溶存する化学物質と反応して水環境賦活に働く他、生き物動植物や微生物に必要不可欠な必須ミネラルとなる。また、炭化した籾殻の成分のケイ素は珪藻プランクトンに必要不可欠なミネラルとなる。また、水中に於いて本材(鉄／炭素)から無垢な２価鉄イオン生成し補給と籾殻炭中のケイ素成分を補給すると食物連鎖や循環や生物多様性や光合成その他に貢献することができる。
また、金属を鉄とし鉄容器内に鉄粉と炭素粉(活性炭やコークスの粉)を混合し接着させたものを詰めて加熱、接合剤部分を炭化する方法とすれば、容器の容量形状を選択でき、鉄イオン生成としても自由な形状と大きさに製造可能。電子と陽子が脱け出した鉄容器は原子.分子レベルのスカスカな固体となり原子.分子レベルの超極微物質を捕集濾過することができる。
Furthermore, when the metal is iron, the pure divalent iron ions that are generated have multifunctional properties and react with water and chemicals dissolved in water to activate the aquatic environment, as well as being an essential mineral for living things, plants, animals, and microorganisms. Silicon, a component of carbonized rice husks, is an essential mineral for diatom plankton. Furthermore, generating and replenishing pure divalent iron ions from this material (iron/carbon) in water, along with replenishing the silicon components in rice husk charcoal, can contribute to the food chain, circulation, biodiversity, photosynthesis, and more.
Also, if the metal is iron and a mixture of iron powder and carbon powder (activated carbon or coke powder) is filled into an iron container and heated to carbonize the adhesive, the volume and shape of the container can be selected, and it can be manufactured into any shape and size for generating iron ions. The iron container from which the electrons and protons have escaped becomes a porous solid at the atomic and molecular level , capable of collecting and filtering ultrafine substances at the atomic and molecular level.
以下にこの発明の実施例を説明する。 An embodiment of the invention is described below.
まず、この実施例１の金属イオン生成材の製造方法は、アトマイズや還元や切削，その他などの製法で造った電気陰性度が2.4以下でイオン化傾向のある金属の箔，粉，粒，片に、炭化が可能な接合.接着剤(デンプン糊や化学糊，接合や繋ぎの効果をもつ剤材)＋炭素含有率が質量98％以上の炭素粉(黒鉛粉，活性炭粉，コークス粉)を調合し加え混練したものを板状に延ばして炭化工程の炭化炉(電磁波加熱式や電熱または火力等で間接または直接的加熱式など)に入れて加熱し接合.接着剤材すべてを芯まで炭化する。と、電気陰性度が2.5の炭素と電気陰性度が2.4以下の２種(金属と炭素(炭化した接着剤))密接密着体ができる。
※加熱炭化には電磁加熱方式,間接加熱方式,遠赤外線加熱方式などがある。
First, the manufacturing method of the metal ion generating material of Example 1 is to mix and knead a carbonizable bonding/adhesive (starch paste, chemical paste, bonding/binding agent) and a carbon powder (graphite powder, activated carbon powder, coke powder) with a carbon content of 98% or more by mass with foil, powder, grain, or piece of metal with an electronegativity of 2.4 or less and a tendency to ionize, which is produced by atomization, reduction, cutting, or other manufacturing methods, and then stretch it into a plate shape and heat it in a carbonization furnace (electromagnetic heating type, electric heating, indirect or direct heating type using fire, etc.) for the carbonization process to carbonize all of the bonding/adhesive material to the core. Then, a body is formed in which carbon with an electronegativity of 2.5 and two types of materials (metal and carbon (carbonized adhesive)) are closely attached to each other.
*There are various heating and carbonization methods, including electromagnetic heating, indirect heating, and far-infrared heating.
次に、この実施例１の作用・効果を説明する。
〔用い方〕
板状の塊にして媒体となる水液中に設置。及び／又は、水中設置資材等に取り付け付帯する。或は、砕いて砕粒化し媒体となる水液中(水域)に散布する。或は、水中研磨粉化装置の収容物として用いる。
Next, the operation and effects of the first embodiment will be described.
[How to use]
It is made into a plate-shaped block and placed in the water medium, and/or attached to underwater installation materials, etc., or crushed into granules and scattered in the water medium (water area), or used as a container for underwater polishing and pulverizing equipment.
〔イオン生成原理〕
金属/媒体/炭素の三位一体密接合境界部分に酸化還元電位や電極電位や電気陰性度などの電位差(局部電池)で通電(導通)が生まれ、金属の電子が炭素側に不可逆的に流れて金属電子は炭素に奪取されると金属には陽子が残り余って不安定になるから安定する為に金属イオンとなって媒体中に溶出する。
※金属と炭素の密接密着が通電導通性を向上する。
※電子と陽子が脱け出した金属は原子.分子レベルでスカスカの固体になる。
※シリカ(ケイ素)成分を多量に含有する籾殻(炭化可能)や珪藻土粉,その他を接合剤(材料)に予め加えておいたものを接合接着剤材として使ってもよい。
※珪藻プランクトンの殻(珪藻土)主成分はシリカ成分
※炭化可能で自然界に優しい剤(材料)なら粘液体でも使用可能。
[Ion generation principle]
Electricity (conduction) is created at the boundary of the metal/medium/carbon trinity close junction due to a potential difference (local battery) such as redox potential, electrode potential, and electronegativity, and when the metal electrons flow irreversibly to the carbon side and are taken by the carbon, the metal is left with an excess of protons, making it unstable, and so to stabilize it, it becomes a metal ion and dissolves into the medium.
*The close adhesion between metal and carbon improves electrical conductivity.
*Metals that have lost electrons and protons become porous solids at the atomic and molecular level.
*Rice husks (which can be carbonized), diatomaceous earth powder, and other materials that contain a large amount of silica (silicon) can be added to the bonding agent (material) in advance and used as a bonding adhesive material.
*The main component of diatomaceous plankton shells (diatomaceous earth) is silica. *It can be used in viscous liquids if the agent (material) is carbonizable and environmentally friendly.
以上本実施例を説明してきたが、本発明は上述の実施例に限られるものではなく、本発明の要旨を逸脱しない範囲の設計変更等があっても、本発明に含まれる。
接着剤または繋ぎ剤の炭化が万が一完全でない場合でも炭素含有率が100％に近い高純度の各種炭素粉(黒鉛,コークス,活性炭,他炭化粉)を接着剤または繋ぎ剤に多量配合しておけば電位差の局部電池形成に全く支障が生じない。
ケイ素成分含有が多くポーラスな珪藻土粉の配合或は加熱すれば炭化できる籾殻を配合しておくことで炭素／金属の密着体を水中に置いた時ポーラス部から水の浸透性を助けると共に＋加熱処理したケイ素成分が溶け出せば植物プランクトン(珪藻類)へ補給となる。
Although the present embodiment has been described above, the present invention is not limited to the above embodiment, and even if there are design changes and the like within the scope of the present invention that do not depart from the gist of the present invention, they are included in the present invention.
Even if the adhesive or binder is not completely carbonized, there will be no hindrance to the formation of a local battery due to the potential difference if a large amount of high-purity carbon powder (graphite, coke, activated carbon, other carbonized powder) with a carbon content close to 100% is mixed into the adhesive or binder.
By mixing in porous diatomaceous earth powder, which has a high silicon content, or rice husks, which can be carbonized by heating, when the carbon/metal bond is placed in water, it helps water permeate through the porous parts, and when the heat-treated silicon components dissolve, they are supplied to the phytoplankton (diatoms).
Claims (2)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022205100 | 2022-12-22 | ||
| JP2022205100 | 2022-12-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP7464922B1 true JP7464922B1 (en) | 2024-04-10 |
| JP2024091202A JP2024091202A (en) | 2024-07-04 |
Family
ID=90606724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023018810A Active JP7464922B1 (en) | 2022-12-22 | 2023-02-10 | Metal ion generation method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP7464922B1 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017201609A (en) | 2016-05-06 | 2017-11-09 | 株式会社Ｐａｒａｍ | Electron gun |
| JP2020536173A (en) | 2017-10-05 | 2020-12-10 | プランゼー エスエー | Additional manufacturing parts and their manufacturing methods |
-
2023
- 2023-02-10 JP JP2023018810A patent/JP7464922B1/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017201609A (en) | 2016-05-06 | 2017-11-09 | 株式会社Ｐａｒａｍ | Electron gun |
| JP2020536173A (en) | 2017-10-05 | 2020-12-10 | プランゼー エスエー | Additional manufacturing parts and their manufacturing methods |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2024091202A (en) | 2024-07-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103764561B (en) | The compound porous plastid of silica-carbon and manufacture method thereof | |
| JP5127179B2 (en) | Method for producing positive electrode active material for lithium secondary battery | |
| CN102130407B (en) | Carbon brush for truck starting motor as well as manufacture method and application thereof | |
| CN106670501A (en) | Preparing method for graphene-metal base composite powder | |
| CN102060561B (en) | Preparation method of porous diatomite-based AgO ceramic material | |
| CN1995438A (en) | Method for preparing elconite | |
| CN110479226B (en) | A clay mineral/agricultural and forestry waste biomass composite sewage treatment agent, its preparation method and application | |
| CN101781757A (en) | Method for chemically plating nano nickel particles on surface of multi-wall carbon nano tube without using palladium | |
| WO2019044042A1 (en) | Battery having electrolytic solution containing alkaline mineral ionized water, electrolyte active material, and method for producing battery electrolytic solution | |
| JP7464922B1 (en) | Metal ion generation method | |
| CN101621121A (en) | Preparation method of high-power lithium iron phosphate composite material | |
| JP5733805B2 (en) | Positive electrode active material for non-aqueous electrolyte secondary battery and method for producing positive electrode active material for non-aqueous electrolyte secondary battery | |
| CN114182124B (en) | High-dispersibility silver tungsten carbide electrical contact material and preparation method thereof | |
| CN104743644B (en) | Water process electrode film and its preparation and application | |
| CN101020960B (en) | A kind of pellet for smelting aluminum-silicon alloy and preparation method thereof | |
| JP2007210878A (en) | Hydrogen generation agent composition | |
| CN104211128A (en) | Preparation method of supercapacitor material NiCo2O4 one-dimensional nanorods | |
| CN115287074B (en) | A high-efficiency nickel-contaminated soil passivator and its preparation method and application | |
| JP2014094336A (en) | Magnetic adsorbent for cesium and its manufacturing method | |
| JP2000164220A (en) | Electrode material for silver oxide battery | |
| JP2016221459A (en) | Metal ion generator and method for producing metal ion generator | |
| JP5404195B2 (en) | Method for producing electrode catalyst for fuel cell | |
| EP3229297B1 (en) | Air battery using a positive electrode, and method of manufacturing the positive electrode | |
| RU2131841C1 (en) | Hydroreacting mixture | |
| JPS62260709A (en) | Formed carbon article and production thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20230210 |
|
| A871 | Explanation of circumstances concerning accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A871 Effective date: 20230210 |
|
| AA64 | Notification of invalidation of claim of internal priority (with term) |
Free format text: JAPANESE INTERMEDIATE CODE: A241764 Effective date: 20230228 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230314 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20230516 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230606 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230704 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20230926 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20231019 Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20231019 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20231204 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20240118 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20240312 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20240314 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7464922 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |