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JP7373544B2 - Batteries and battery manufacturing methods - Google Patents

Batteries and battery manufacturing methods Download PDF

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JP7373544B2
JP7373544B2 JP2021201720A JP2021201720A JP7373544B2 JP 7373544 B2 JP7373544 B2 JP 7373544B2 JP 2021201720 A JP2021201720 A JP 2021201720A JP 2021201720 A JP2021201720 A JP 2021201720A JP 7373544 B2 JP7373544 B2 JP 7373544B2
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current collector
laminated
extends
collector terminal
battery case
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JP2023087373A (en
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洋平 進藤
正人 中山
大樹 森下
祐樹 城山
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Prime Planet Energy and Solutions Inc
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Description

本発明は、電池及び電池の製造方法に関する。 The present invention relates to a battery and a method for manufacturing the battery.

特許文献1,2には、集電箔の表面に電極合材層が積層された合材積層部と、前記集電箔のうち前記電極合材層が積層されることなく前記合材積層部から延出する集電タブと、を有する複数枚の電極板を備え、複数の前記合材積層部がセパレータを介して積層方向に積層された電極積層部を有する積層電極体と、金属フィルムの両面が樹脂フィルムで被覆された構造のラミネートフィルムからなり、前記積層電極体を収容する電池ケースと、前記積層電極体のうち複数の前記集電タブに接合して、前記電池ケースの内部から外部に延出する集電端子と、を備える電池が開示されている。 Patent Documents 1 and 2 disclose a composite material laminated portion in which an electrode composite material layer is laminated on the surface of the current collector foil, and a composite material laminated portion in which the electrode composite material layer is not laminated on the surface of the current collector foil. a laminated electrode body including a plurality of electrode plates having a current collecting tab extending from the electrode, and a laminated electrode body having an electrode laminated portion in which a plurality of the composite laminated portions are laminated in the lamination direction with a separator interposed therebetween; It is made of a laminate film having a structure in which both sides are covered with resin films, and is connected to a battery case housing the laminated electrode body and a plurality of current collecting tabs of the laminated electrode body, and is connected to the battery case to connect the battery case from the inside to the outside. A battery is disclosed that includes a current collector terminal that extends into the battery.

特開2012-54029号公報Japanese Patent Application Publication No. 2012-54029 特開2012-164470号公報Japanese Patent Application Publication No. 2012-164470

前記集電端子は、側面視L字形状をなし、前記積層方向に延びる形態をなして前記電池ケース内に収容される第1部位と、前記積層方向に直交する方向に延びる形態をなして前記電池ケースの内部から外部に延出する第2部位と、が連結された形態を有する。複数の前記集電タブは、これらの厚み方向に隙間なく重ね合わされたタブ重なり部であって、その長さ方向について前記電極積層部側から先端側へ延びるタブ重なり部を形成している。前記集電端子の前記第1部位は、当該第1部位が延びる前記積層方向にかかる端部であって前記第2部位から最も離れて位置する第1端部を有する。 The current collector terminal has an L-shape when viewed from the side, and includes a first portion that extends in the stacking direction and is housed in the battery case, and a first portion that extends in the stacking direction and a first portion that extends in the stacking direction. A second portion extending from the inside of the battery case to the outside is connected to the second portion. The plurality of current collecting tabs are overlapped with each other without gaps in their thickness direction, and form a tab overlap that extends in the length direction from the electrode stack side to the tip side. The first portion of the current collector terminal has a first end that extends in the stacking direction and is located farthest from the second portion.

前記タブ重なり部は、前記集電端子の前記第1部位のうち前記電極積層部側を向く第1面に沿って、前記第1端部側から前記第2部位に向かって延びる形態をなしている。そして、前記タブ重なり部のうち前記第1部位の前記第1面に沿って前記第1端部側から前記第2部位に向かって延びる部位が、前記第1部位の前記第1面に溶接されている。なお、前記電極板は、正極板または負極板であり、前記集電タブは、正極集電タブまたは負極集電タブであり、前記集電端子は、正極集電端子または負極集電端子である。 The tab overlapping portion extends from the first end toward the second portion along a first surface of the first portion of the current collector terminal facing the electrode lamination portion. There is. A portion of the tab overlapping portion that extends from the first end side toward the second portion along the first surface of the first portion is welded to the first surface of the first portion. ing. The electrode plate is a positive electrode plate or a negative electrode plate, the current collector tab is a positive electrode current collector tab or a negative electrode current collector tab, and the current collector terminal is a positive electrode current collector terminal or a negative electrode current collector terminal. .

ところで、側面視L字形状をなす集電端子の第1端部の角部が、ラミネートフィルムからなる電池ケースに対して直接に接触すると、電池ケースを構成するラミネートフィルムが損傷する虞がある。さらには、ラミネートフィルムの樹脂フィルムのうち第1端部の角部が接触した部分が破断し、第1部位の第1端部が、ラミネートフィルム内部の金属フィルムに対して直接に接触して、金属フィルムと集電端子とが導通する不具合が生じる虞もある。このような不具合を防止するため、前述の特許文献1,2の電池では、絶縁性の被覆部材(絶縁シートや絶縁テープ)によって、集電端子の第1部位の第1端部を覆うようにしていた。しかしながら、絶縁性の被覆部材を別途用意し、この被覆部材によって集電端子の第1端部を覆う作業を行うことは、製造時間が増加すると共に、製造コストが増加する。 By the way, if the corner of the first end of the current collector terminal, which is L-shaped in side view, comes into direct contact with the battery case made of a laminate film, there is a risk that the laminate film forming the battery case will be damaged. Furthermore, the part of the resin film of the laminate film that the corner of the first end comes into contact with breaks, and the first end of the first part directly contacts the metal film inside the laminate film. There is also a possibility that a problem may occur in which the metal film and the current collector terminal are electrically connected. In order to prevent such problems, in the batteries of Patent Documents 1 and 2 mentioned above, the first end of the first portion of the current collector terminal is covered with an insulating covering member (insulating sheet or insulating tape). was. However, preparing a separate insulating covering member and covering the first end of the current collector terminal with this covering member increases manufacturing time and manufacturing cost.

本発明は、かかる現状に鑑みてなされたものであって、絶縁性の被覆部材を用いることなく、集電端子の第1端部の角部が、ラミネートフィルムからなる電池ケースに対して直接に接触することを防ぐことができる電池、及び、その製造方法を提供することを目的とする。 The present invention has been made in view of the current situation, and the present invention has been made in such a way that the corner of the first end of the current collector terminal is directly connected to the battery case made of a laminate film without using an insulating covering member. An object of the present invention is to provide a battery that can prevent contact, and a method for manufacturing the same.

本発明の一態様は、集電箔の表面に電極合材層が積層された合材積層部と、前記集電箔のうち前記電極合材層が積層されることなく前記合材積層部から延出する集電タブと、を有する複数枚の電極板を備え、複数の前記合材積層部がセパレータを介して積層方向に積層された電極積層部を有する積層電極体と、金属フィルムの両面が樹脂フィルムで被覆された構造のラミネートフィルムからなり、前記積層電極体を収容する電池ケースと、前記積層電極体のうち複数の前記集電タブに接合して、前記電池ケースの内部から外部に延出する集電端子と、を備える電池において、前記集電端子は、側面視L字形状をなし、前記積層方向に延びる形態をなして前記電池ケース内に収容される第1部位と、前記積層方向に直交する方向に延びる形態をなして前記電池ケースの内部から外部に延出する第2部位と、が連結された形態を有し、複数の前記集電タブは、これらの厚み方向に隙間なく重ね合わされたタブ重なり部であって、その長さ方向について前記電極積層部側から先端側へ延びるタブ重なり部を形成しており、前記集電端子の前記第1部位は、当該第1部位が延びる前記積層方向にかかる端部であって前記第2部位から最も離れて位置する第1端部を有し、前記タブ重なり部は、前記第1部位のうち前記電極積層部側を向く第1面に沿って前記第2部位側から前記第1端部に向かって延び、前記第1端部を覆う態様で前記第2部位側へ折り返されて、前記第1部位のうち前記第1面と反対側を向く第2面に沿って前記第2部位に向かって延びる形態をなしており、前記タブ重なり部のうち、前記第1部位の前記第1面に沿って前記第2部位側から前記第1端部に向かって延びる部位に含まれる溶接部が、前記第1部位の前記第1面に溶接されている電池である。 One aspect of the present invention includes a composite material laminated part in which an electrode composite material layer is laminated on the surface of the current collector foil, and a composite material laminated part in which the electrode composite material layer is not laminated on the surface of the current collector foil. a laminated electrode body including a plurality of electrode plates having an extending current collecting tab, and an electrode lamination part in which a plurality of the composite material lamination parts are laminated in the lamination direction with a separator interposed therebetween; and both sides of a metal film. is made of a laminate film having a structure covered with a resin film, and is bonded to a battery case housing the laminated electrode body and a plurality of current collecting tabs of the laminated electrode body, and is connected to the battery case from the inside to the outside of the battery case. a first portion of the current collecting terminal that is L-shaped in side view and extends in the stacking direction and is accommodated in the battery case; and a second portion that extends in a direction perpendicular to the stacking direction and extends from the inside of the battery case to the outside, and the plurality of current collecting tabs have a shape that extends in the thickness direction of the second portion. The tab overlap portion is overlapped without a gap and extends in the length direction from the electrode laminated portion side to the tip end side, and the first portion of the current collector terminal is connected to the first portion. The portion has a first end that extends in the stacking direction and is located farthest from the second portion, and the tab overlapping portion faces toward the electrode stacking portion of the first portion. The first portion of the first portion extends along the first surface from the second portion side toward the first end portion, and is folded back toward the second portion side in a manner that covers the first end portion. The tabs extend toward the second portion along a second surface facing opposite to the second surface, and of the tab overlapping portion, the second portion side extends along the first surface of the first portion. A welded portion included in a portion extending from the battery toward the first end portion is welded to the first surface of the first portion.

上述の電池では、タブ重なり部が、集電端子の第1部位のうち積層電極体の電極積層部側を向く第1面に沿って第2部位側から第1端部に向かって延び、第1端部を覆う態様で第2部位側へ折り返されて、第1部位のうち第1面と反対側を向く第2面に沿って第2部位に向かって延びる形態をなしている。従って、集電端子の第1部位の第1端部は、タブ重なり部によって覆われている。これにより、絶縁性の被覆部材を用いることなく、集電端子の第1端部の角部が、ラミネートフィルムからなる電池ケースに対して直接に接触することを防止できる。これにより、「集電端子の第1端部の角部の接触によって電池ケースを構成するラミネートフィルムが損傷すること」を防止することができる。さらには、「ラミネートフィルムの樹脂フィルムのうち第1端部の角部が接触した部分が破断し、第1部位の第1端部が、ラミネートフィルム内部の金属フィルムに対して直接に接触して、金属フィルムと集電端子とが導通する不具合」が発生することを防止できる。 In the battery described above, the tab overlapping portion extends from the second portion side toward the first end portion along the first surface of the first portion of the current collector terminal facing the electrode lamination portion side of the laminated electrode body, and extends from the second portion side toward the first end portion. It is folded back toward the second portion in such a manner as to cover one end, and extends toward the second portion along a second surface of the first portion that faces opposite to the first surface. Therefore, the first end of the first portion of the current collector terminal is covered by the tab overlapping portion. Thereby, the corner of the first end of the current collector terminal can be prevented from coming into direct contact with the battery case made of the laminate film, without using an insulating covering member. This can prevent damage to the laminate film constituting the battery case due to contact with the corner of the first end of the current collector terminal. Furthermore, ``the part of the resin film of the laminate film that the corner of the first end touched broke, and the first end of the first part directly contacted the metal film inside the laminate film. It is possible to prevent the occurrence of "a problem in which electrical conduction occurs between the metal film and the current collector terminal."

なお、電極板は、正極板または負極板であり、集電タブは、正極集電タブまたは負極集電タブであり、集電端子は、正極集電端子または負極集電端子である。また、タブ重なり部は、複数の集電タブ(正極集電タブまたは負極集電タブ)が厚み方向に隙間なく重ね合わされた部位であり、積層電極体に含まれる同一極(正極または負極)の全ての集電タブ(全ての正極集電タブまたは全ての負極集電タブ)が重なっている部分のみならず、少なくとも2以上の集電タブ(正極集電タブまたは負極集電タブ)が重なっている部分も含む。 Note that the electrode plate is a positive electrode plate or a negative electrode plate, the current collector tab is a positive electrode current collector tab or a negative electrode current collector tab, and the current collector terminal is a positive electrode current collector terminal or a negative electrode current collector terminal. In addition, the tab overlapping portion is a region where multiple current collecting tabs (positive electrode current collecting tabs or negative electrode current collecting tabs) are overlapped without any gaps in the thickness direction, and the same electrode (positive electrode or negative electrode) included in the laminated electrode body. Not only where all current collecting tabs (all positive current collecting tabs or all negative current collecting tabs) overlap, but also where at least two or more current collecting tabs (positive current collecting tabs or negative current collecting tabs) overlap. Including the part where it is.

本発明の他の態様は、前記の電池の製造方法であって、複数枚の前記電極板のうち複数の前記合材積層部を前記セパレータを介して積層して、前記電極積層部を有する前記積層電極体を形成する積層電極体形成工程と、前記積層電極体のうち複数の前記集電タブについて、これらの先端を切り揃えることなく、これらの厚み方向に隙間なく重ね合わせて、前記電極積層部側から前記積層方向に直交する方向に延びる前記タブ重なり部を形成するタブ重なり部形成工程と、前記集電端子の前記第1部位が延びる方向を前記タブ重なり部が延びる方向に一致させると共に、前記タブ重なり部の先端部が前記第1部位の前記第1端部よりも前記第2部位から遠い側に配置されるようにした状態で、前記タブ重なり部のうち前記第1部位の前記第1面に沿って前記第2部位側から前記第1端部に向かって延びる部位に含まれる前記溶接部を、前記第1部位の前記第1面に溶接する溶接工程と、前記タブ重なり部のうち前記第1部位の前記第1端部よりも前記第2部位から遠い側に配置されている部分を、前記第1端部を覆うようにして前記第2部位側へ折り返して、前記第1部位のうち前記第1面と反対側を向く第2面に沿って前記第2部位に向かって延びる部位を形成する折り返し工程と、前記集電端子の前記第1部位が前記電池ケース内に収容されると共に前記第2部位が前記電池ケースの内部から外部に延出する態様で、前記積層電極体を、前記ラミネートフィルムからなる前記電池ケース内に収容する収容工程と、を備える電池の製造方法である。 Another aspect of the present invention is the method for manufacturing the battery, in which a plurality of the composite material laminated parts among the plurality of electrode plates are laminated with the separator interposed therebetween, and the battery having the electrode laminated part is a laminated electrode body forming step of forming a laminated electrode body; and a laminated electrode body forming step in which the plurality of current collecting tabs of the laminated electrode body are stacked without any gaps in the thickness direction without trimming the tips of the plurality of current collecting tabs, and the electrode lamination is performed. a tab overlapping portion forming step of forming the tab overlapping portion extending in a direction perpendicular to the stacking direction from the top side, and aligning the direction in which the first portion of the current collector terminal extends with the direction in which the tab overlapping portion extends; , the tip of the tab overlapping portion is disposed further from the second portion than the first end of the first portion; a welding step of welding the welded portion included in a portion extending from the second portion side toward the first end portion along the first surface to the first surface of the first portion; and the tab overlap portion. A portion of the first portion that is located farther from the second portion than the first end portion is folded back toward the second portion so as to cover the first end portion. a folding step of forming a portion of one portion extending toward the second portion along a second surface facing opposite to the first surface; and a step of folding the first portion of the current collector terminal into the battery case. manufacturing a battery, comprising: housing the laminated electrode body in the battery case made of the laminate film in such a manner that the second portion extends from the inside of the battery case to the outside; It's a method.

上述の製造方法では、折り返し工程において、タブ重なり部のうち集電端子の第1部位の第1端部よりも第2部位から遠い側に配置されている部分を、集電端子の第1部位の第1端部を覆うようにして第2部位側へ折り返す。これにより、集電端子の第1部位の第1端部は、タブ重なり部によって覆われる。従って、上述の製造方法によって製造された電池では、絶縁性の被覆部材を用いることなく、集電端子の第1端部の角部が、ラミネートフィルムからなる電池ケースに対して直接に接触することを防止できる。これにより、「集電端子の第1端部の角部の接触によって電池ケースを構成するラミネートフィルムが損傷すること」を防止することができる。さらには、「ラミネートフィルムの樹脂フィルムのうち第1端部の角部が接触した部分が破断し、第1部位の第1端部が、ラミネートフィルム内部の金属フィルムに対して直接に接触して、金属フィルムと集電端子とが導通する不具合」が発生することを防止できる。 In the above-mentioned manufacturing method, in the folding process, the portion of the tab overlapping portion that is located farther from the second portion than the first end of the first portion of the current collector terminal is replaced with the first portion of the current collector terminal. Fold it back toward the second part so as to cover the first end of the. As a result, the first end of the first portion of the current collector terminal is covered by the tab overlapping portion. Therefore, in the battery manufactured by the above-mentioned manufacturing method, the corner of the first end of the current collector terminal can directly contact the battery case made of the laminate film without using an insulating covering member. can be prevented. This can prevent damage to the laminate film constituting the battery case due to contact with the corner of the first end of the current collector terminal. Furthermore, ``the part of the resin film of the laminate film that the corner of the first end touched broke, and the first end of the first part directly contacted the metal film inside the laminate film. It is possible to prevent the occurrence of "a problem in which electrical conduction occurs between the metal film and the current collector terminal."

さらに、上述の製造方法では、積層電極体のうち複数の集電タブについて、これらの先端を切り揃えることなく、これらの厚み方向に隙間なく重ね合わせてタブ重なり部を形成する。従って、上述の製造方法では、従来の製造方法に比べて、複数の集電タブの先端を切り揃える切断工程を省略することができるので、製造コストを低減することができる。さらには、前記切断工程を省略することによって、前記切断工程によって発生した金属粉等の異物が電池内に混入する虞もなくなる。 Furthermore, in the above-described manufacturing method, the tab overlapping portions are formed by overlapping the plurality of current collecting tabs in the stacked electrode body without cutting the ends thereof in the thickness direction without any gaps. Therefore, in the above-described manufacturing method, the cutting step of trimming the ends of the plurality of current collecting tabs can be omitted compared to the conventional manufacturing method, so that the manufacturing cost can be reduced. Furthermore, by omitting the cutting step, there is no possibility that foreign matter such as metal powder generated in the cutting step will enter the battery.

実施形態にかかる電池の正面図である。FIG. 1 is a front view of a battery according to an embodiment. 図1のF-F断面図である。2 is a sectional view taken along line FF in FIG. 1. FIG. 図1のG-G断面図である。2 is a sectional view taken along line GG in FIG. 1. FIG. 図2のJ部拡大図である。FIG. 3 is an enlarged view of part J in FIG. 2; 実施形態にかかる積層電極体の平面図である。FIG. 2 is a plan view of a laminated electrode body according to an embodiment. 図5のB-B断面図である。6 is a sectional view taken along line BB in FIG. 5. FIG. 実施形態にかかる正極板の平面図である。FIG. 2 is a plan view of a positive electrode plate according to an embodiment. 図7のC-C断面図である。8 is a sectional view taken along the line CC in FIG. 7. FIG. 実施形態にかかる負極板の平面図である。FIG. 2 is a plan view of a negative electrode plate according to an embodiment. 図9のD-D断面図である。9 is a sectional view taken along line DD in FIG. 9. FIG. 図2のE部拡大図である。3 is an enlarged view of section E in FIG. 2. FIG. 図3のH部拡大図である。4 is an enlarged view of part H in FIG. 3. FIG. 集電端子の側面図である。It is a side view of a current collection terminal. 実施形態にかかる電池の製造方法の流れを示すフローチャートである。1 is a flowchart showing the flow of a battery manufacturing method according to an embodiment. 溶接工程を説明する図である。It is a figure explaining a welding process. 折り返し工程を説明する図である。It is a figure explaining a folding process. 収容工程を説明する図である。It is a figure explaining an accommodation process.

次に、本発明の実施形態について説明する。本実施形態の電池1は、リチウムイオン二次電池であり、積層電極体50と、積層電極体50を収容する電池ケース10と、集電端子(正極集電端子20と負極集電端子30)とを備える(図1~図3参照)。このうち、積層電極体50は、複数枚の正極板60(電極板)と、複数枚の負極板70(電極板)と、複数枚のセパレータ80とを備える。 Next, embodiments of the present invention will be described. The battery 1 of this embodiment is a lithium ion secondary battery, and includes a stacked electrode body 50, a battery case 10 that accommodates the stacked electrode body 50, and current collector terminals (a positive current collector terminal 20 and a negative current collector terminal 30). (See Figures 1 to 3). Among these, the laminated electrode body 50 includes a plurality of positive electrode plates 60 (electrode plates), a plurality of negative electrode plates 70 (electrode plates), and a plurality of separators 80.

正極板60は、正極集電箔66の表面(本実施形態では両面)に正極合材層62(電極合材層)が積層された矩形平板状の正極合材積層部61と、正極集電箔66のうち正極合材層62が積層されることなく正極合材積層部61から延出する正極集電タブ65とを有する(図7及び図8参照)。負極板70は、負極集電箔76の表面(本実施形態では両面)に負極合材層72(電極合材層)が積層された矩形平板状の負極合材積層部71と、負極集電箔76のうち負極合材層72が積層されることなく負極合材積層部71から延出する負極集電タブ75とを有する(図9及び図10参照)。 The positive electrode plate 60 includes a rectangular flat positive electrode composite material laminated portion 61 in which a positive electrode composite material layer 62 (electrode composite material layer) is laminated on the surface (in this embodiment, both surfaces) of a positive electrode current collector foil 66, and a positive electrode current collector. The foil 66 includes a positive electrode current collector tab 65 that extends from the positive electrode composite material laminated portion 61 without being laminated with the positive electrode composite material layer 62 (see FIGS. 7 and 8). The negative electrode plate 70 includes a rectangular flat negative electrode composite material laminated portion 71 in which a negative electrode composite material layer 72 (electrode composite material layer) is laminated on the surface (in this embodiment, both surfaces) of a negative electrode current collector foil 76, and a negative electrode current collector. The foil 76 includes a negative electrode current collector tab 75 that extends from the negative electrode composite material laminated portion 71 without being laminated with the negative electrode composite material layer 72 (see FIGS. 9 and 10).

積層電極体50は、複数の正極合材積層部61と複数の負極合材積層部71とが、矩形平板状のセパレータ80を介して積層方向DLに積層された電極積層部51を有する(図2、図3、図5、図6参照)。なお、図5及び図6は、正極集電タブ65及び負極集電タブ75を正極集電端子20及び負極集電端子30に取り付ける前の積層電極体50を示している。 The laminated electrode body 50 has an electrode laminated portion 51 in which a plurality of positive electrode composite material laminated portions 61 and a plurality of negative electrode composite material laminated portions 71 are laminated in the lamination direction DL via a rectangular flat plate-shaped separator 80 (see FIG. 2, see Figures 3, 5, and 6). Note that FIGS. 5 and 6 show the laminated electrode body 50 before the positive electrode current collecting tab 65 and the negative electrode current collecting tab 75 are attached to the positive electrode current collecting terminal 20 and the negative electrode current collecting terminal 30.

電池ケース10は、金属フィルム12の両面が樹脂フィルム(内側樹脂フィルム11と外側樹脂フィルム13)で被覆された構造のラミネートフィルム15からなる。すなわち、電池ケース10は、電池ケース10の最も内側に位置する内側樹脂フィルム11、この内側樹脂フィルム11の外側に隣り合って位置する金属フィルム12、及びこの金属フィルム12の外側に隣り合って位置する外側樹脂フィルム13が積層されたラミネートフィルム15によって形成されている(図4参照)。 The battery case 10 is made of a laminate film 15 having a structure in which both sides of a metal film 12 are covered with resin films (inner resin film 11 and outer resin film 13). That is, the battery case 10 includes an inner resin film 11 located at the innermost side of the battery case 10, a metal film 12 located adjacent to the outside of the inner resin film 11, and a metal film 12 located adjacent to the outside of the metal film 12. It is formed of a laminate film 15 on which an outer resin film 13 is laminated (see FIG. 4).

正極集電端子20は、積層電極体50のうち複数の(全ての)正極集電タブ65に接合して、電池ケース10の内部から外部に延出している(図3参照)。この正極集電端子20は、矩形平板状の金属板を折り曲げることによって形成されており、側面視L字形状をなしている。この正極集電端子20は、積層方向DLに延びる形態をなして電池ケース10内に収容される第1部位21と、積層方向DLに直交する直交方向DCに延びる形態をなして電池ケース10の内部から外部に延出する第2部位22とが連結された形態を有する(図3及び図13参照)。正極集電端子20の第1部位21は、当該第1部位21が延びる積層方向DLにかかる端部であって第2部位22から最も離れて位置する第1端部21bを有する(図3、図12、図13参照)。 The positive electrode current collector terminal 20 is joined to a plurality of (all) positive electrode current collector tabs 65 of the laminated electrode body 50 and extends from the inside of the battery case 10 to the outside (see FIG. 3). This positive electrode current collector terminal 20 is formed by bending a rectangular flat metal plate, and has an L-shape in side view. This positive electrode current collector terminal 20 has a first portion 21 that extends in the stacking direction DL and is housed in the battery case 10, and a first portion 21 that extends in the stacking direction DL and is accommodated in the battery case 10. It has a form in which a second portion 22 extending from the inside to the outside is connected (see FIGS. 3 and 13). The first portion 21 of the positive electrode current collector terminal 20 has a first end portion 21b that is an end in the stacking direction DL in which the first portion 21 extends and is located farthest from the second portion 22 (FIG. 3, (See Figures 12 and 13).

負極集電端子30は、積層電極体50のうち複数の(全ての)負極集電タブ75に接合して、電池ケース10の内部から外部に延出している(図2参照)。この負極集電端子30は、矩形平板状の金属板を折り曲げることによって形成されており、側面視L字形状をなしている。この負極集電端子30は、積層方向DLに延びる形態をなして電池ケース10内に収容される第1部位31と、積層方向DLに直交する直交方向DCに延びる形態をなして電池ケース10の内部から外部に延出する第2部位32とが連結された形態を有する(図2及び図13参照)。負極集電端子30の第1部位31は、当該第1部位31が延びる積層方向DLにかかる端部であって第2部位32から最も離れて位置する第1端部31bを有する(図3、図12、図13参照)。 The negative electrode current collector terminal 30 is joined to a plurality of (all) negative electrode current collector tabs 75 of the laminated electrode body 50 and extends from the inside of the battery case 10 to the outside (see FIG. 2). This negative electrode current collector terminal 30 is formed by bending a rectangular flat metal plate, and has an L-shape in side view. This negative electrode current collector terminal 30 has a first portion 31 that extends in the stacking direction DL and is accommodated in the battery case 10, and a first portion 31 that extends in the orthogonal direction DC perpendicular to the stacking direction DL and is housed in the battery case 10. It has a form in which a second portion 32 extending from the inside to the outside is connected (see FIGS. 2 and 13). The first portion 31 of the negative electrode current collector terminal 30 has a first end portion 31b that is an end in the stacking direction DL in which the first portion 31 extends and is located farthest from the second portion 32 (FIG. 3, (See Figures 12 and 13).

複数の正極集電タブ65は、これらの厚み方向に隙間なく重ね合わされた正極タブ重なり部67を形成している(図3及び図12参照)。この正極タブ重なり部67は、その長さ方向について電極積層部51側から先端側へ延びている。なお、正極タブ重なり部67は、複数の正極集電タブ65が厚み方向に隙間なく重ね合わされた部位であり、積層電極体50に含まれる全ての正極集電タブ65が重なっている部分のみならず、少なくとも2以上の正極集電タブ65が重なっている部分も含む。 The plurality of positive electrode current collecting tabs 65 are overlapped in the thickness direction to form a positive electrode tab overlapping portion 67 (see FIGS. 3 and 12). This positive electrode tab overlapping portion 67 extends in its length direction from the electrode laminated portion 51 side to the tip side. Note that the positive electrode tab overlapping portion 67 is a portion where a plurality of positive electrode current collecting tabs 65 are overlapped without any gaps in the thickness direction, and is a portion where all positive electrode current collecting tabs 65 included in the laminated electrode body 50 overlap. It also includes a portion where at least two or more positive electrode current collecting tabs 65 overlap.

正極タブ重なり部67は、正極集電端子20の第1部位21のうち電極積層部51側を向く第1面21cに沿って第2部位22側(図3及び図12において左側)から第1端部21bに向かって延び、第1端部21bの全体を覆う態様で第2部位22側へ折り返されて、第1部位21のうち第1面21cと反対側を向く第2面21dに沿って第2部位22に向かって延びる形態をなしている。なお、正極タブ重なり部67の幅寸法(図12において紙面に直交する方向の寸法)は、正極集電端子20の第1部位21の幅寸法(図12において紙面に直交する方向の寸法)よりも大きく、正極タブ重なり部67の幅方向中心の位置を第1部位21の幅方向中心の位置に合わせている。 The positive electrode tab overlapping portion 67 extends from the second portion 22 side (the left side in FIGS. 3 and 12) along the first surface 21c of the first portion 21 of the positive electrode current collector terminal 20 facing the electrode laminated portion 51 side. It extends toward the end portion 21b, is folded back toward the second portion 22 side in a manner to cover the entire first end portion 21b, and extends along a second surface 21d of the first portion 21 facing opposite to the first surface 21c. and extends toward the second portion 22. Note that the width dimension of the positive electrode tab overlapping portion 67 (the dimension in the direction perpendicular to the plane of paper in FIG. 12) is smaller than the width dimension of the first portion 21 of the positive electrode current collector terminal 20 (the dimension in the direction perpendicular to the plane of paper in FIG. 12). is also large, and the position of the center in the width direction of the positive electrode tab overlapping portion 67 is aligned with the center position of the first portion 21 in the width direction.

従って、正極集電端子20の第1部位21の第1端部21bは、正極タブ重なり部67によって覆われている。これにより、絶縁性の被覆部材を用いることなく、正極集電端子20の第1端部21bの角部が、ラミネートフィルム15からなる電池ケース10に対して直接に接触することを防止できる。これにより、「正極集電端子20の第1端部21bの角部の接触によって電池ケース10を構成するラミネートフィルム15が損傷すること」を防止することができる。さらには、「ラミネートフィルム15の内側樹脂フィルム11のうち第1端部21bの角部が接触した部分が破断し、第1部位21の第1端部21bがラミネートフィルム15の内部の金属フィルム12に対して直接に接触して、金属フィルム12と正極集電端子20とが導通する不具合」が発生することを防止できる。 Therefore, the first end portion 21b of the first portion 21 of the positive electrode current collector terminal 20 is covered by the positive electrode tab overlapping portion 67. Thereby, the corner of the first end 21b of the positive electrode current collector terminal 20 can be prevented from directly contacting the battery case 10 made of the laminate film 15 without using an insulating covering member. This can prevent "damage to the laminate film 15 constituting the battery case 10 due to contact with the corner of the first end 21b of the positive electrode current collector terminal 20." Furthermore, "the part of the inner resin film 11 of the laminate film 15 that the corner of the first end 21b comes into contact with is broken, and the first end 21b of the first portion 21 is damaged by the metal film 12 inside the laminate film 15. It is possible to prevent the occurrence of a problem in which the metal film 12 and the positive electrode current collector terminal 20 are electrically connected due to direct contact with the metal film 12.

また、複数の負極集電タブ75は、これらの厚み方向に隙間なく重ね合わされた負極タブ重なり部77を形成している(図2及び図11参照)。この負極タブ重なり部77は、その長さ方向について電極積層部51側から先端側へ延びている。なお、負極タブ重なり部77は、複数の負極集電タブ75が厚み方向に隙間なく重ね合わされた部位であり、積層電極体50に含まれる全ての負極集電タブ75が重なっている部分のみならず、少なくとも2以上の負極集電タブ75が重なっている部分も含む。 Further, the plurality of negative electrode current collecting tabs 75 are overlapped in the thickness direction to form a negative electrode tab overlapping portion 77 (see FIGS. 2 and 11). This negative electrode tab overlapping portion 77 extends in its length direction from the electrode laminated portion 51 side to the tip side. Note that the negative electrode tab overlapping portion 77 is a portion where a plurality of negative electrode current collecting tabs 75 are overlapped without any gaps in the thickness direction, and is only a portion where all negative electrode current collecting tabs 75 included in the laminated electrode body 50 overlap. It also includes a portion where at least two or more negative electrode current collecting tabs 75 overlap.

負極タブ重なり部77は、負極集電端子30の第1部位31のうち電極積層部51側を向く第1面31cに沿って第2部位32側(図2及び図11において左側)から第1端部31bに向かって延び、第1端部31bの全体を覆う態様で第2部位32側へ折り返されて、第1部位31のうち第1面31cと反対側を向く第2面31dに沿って第2部位32に向かって延びる形態をなしている。なお、負極タブ重なり部77の幅寸法(図11において紙面に直交する方向の寸法)は、負極集電端子30の第1部位31の幅寸法(図12において紙面に直交する方向の寸法)よりも大きく、負極タブ重なり部77の幅方向中心の位置を第1部位21の幅方向中心の位置に合わせている。 The negative electrode tab overlapping portion 77 extends from the second portion 32 side (left side in FIGS. 2 and 11) to the first surface 31c of the first portion 31 of the negative electrode current collector terminal 30 facing the electrode laminated portion 51 side. It extends toward the end portion 31b, is folded back toward the second portion 32 side in a manner to cover the entire first end portion 31b, and extends along a second surface 31d of the first portion 31 facing the opposite side to the first surface 31c. It has a shape that extends toward the second portion 32. Note that the width dimension of the negative electrode tab overlapping portion 77 (the dimension in the direction perpendicular to the plane of paper in FIG. 11) is smaller than the width dimension of the first portion 31 of the negative electrode current collector terminal 30 (the dimension in the direction perpendicular to the plane of paper in FIG. 12). is also large, and the widthwise center position of the negative electrode tab overlapping portion 77 is aligned with the widthwise center position of the first portion 21 .

従って、負極集電端子30の第1部位31の第1端部31bは、負極タブ重なり部77によって覆われている。これにより、絶縁性の被覆部材を用いることなく、負極集電端子30の第1端部31bの角部が、ラミネートフィルム15からなる電池ケース10に対して直接に接触することを防止できる。これにより、「負極集電端子30の第1端部31bの角部の接触によって電池ケース10を構成するラミネートフィルム15が損傷すること」を防止することができる。さらには、「ラミネートフィルム15の内側樹脂フィルム11のうち第1端部31bの角部が接触した部分が破断し、第1部位31の第1端部31bがラミネートフィルム15の内部の金属フィルム12に対して直接に接触して、金属フィルム12と負極集電端子30とが導通する不具合」が発生することを防止できる。 Therefore, the first end portion 31b of the first portion 31 of the negative electrode current collector terminal 30 is covered by the negative electrode tab overlapping portion 77. Thereby, the corner of the first end 31b of the negative electrode current collector terminal 30 can be prevented from directly contacting the battery case 10 made of the laminate film 15 without using an insulating covering member. This can prevent damage to the laminate film 15 that constitutes the battery case 10 due to contact with the corner of the first end 31b of the negative electrode current collector terminal 30. Furthermore, "the part of the inner resin film 11 of the laminate film 15 that the corner of the first end 31b comes into contact with is broken, and the first end 31b of the first portion 31 touches the metal film 12 inside the laminate film 15. It is possible to prevent the occurrence of "a problem in which the metal film 12 and the negative electrode current collector terminal 30 are electrically connected due to direct contact with the negative electrode current collector terminal 30."

なお、正極タブ重なり部67のうち、正極集電端子20の第1部位21の第1面21cに沿って第2部位22側から第1端部21bに向かって延びる部位67cに含まれる溶接部67bが、第1部位21の第1面21cに溶接されている(図12参照)。また、負極タブ重なり部77のうち、負極集電端子30の第1部位31の第1面31cに沿って第2部位32側から第1端部31bに向かって延びる部位77cに含まれる溶接部77bが、第1部位31の第1面31cに溶接されている(図11参照)。 In addition, in the positive electrode tab overlapping portion 67, a welded portion included in a portion 67c extending from the second portion 22 side toward the first end portion 21b along the first surface 21c of the first portion 21 of the positive electrode current collector terminal 20. 67b is welded to the first surface 21c of the first portion 21 (see FIG. 12). Further, in the negative electrode tab overlapping portion 77, a welded portion included in a portion 77c extending from the second portion 32 side toward the first end portion 31b along the first surface 31c of the first portion 31 of the negative electrode current collector terminal 30. 77b is welded to the first surface 31c of the first portion 31 (see FIG. 11).

ラミネートフィルム15からなる電池ケース10は、正極集電端子20及び負極集電端子30が接合された積層電極体50を内部に収容しつつ、正極集電端子20の第2部位22の一部及び負極集電端子30の第2部位32の一部を電池ケース10の外部に突出させた状態で、略コの字状の溶着封止部15b(電池ケース10の3つの縁)が熱溶着によって封止されることによって形成されている(図1~図3参照)。なお、正極集電端子20の第2部位22の一部は樹脂膜25によって被覆されており、この樹脂膜25と電池ケース10の溶着封止部15bとが熱溶着することで、正極集電端子20が電池ケース10に接合されている。また、負極集電端子30の第2部位32の一部も樹脂膜35によって被覆されており、この樹脂膜35と電池ケース10の溶着封止部15bとが熱溶着することで、負極集電端子30が電池ケース10に接合されている。 A battery case 10 made of a laminate film 15 accommodates therein a laminated electrode body 50 to which a positive current collector terminal 20 and a negative current collector terminal 30 are bonded, and a part of the second portion 22 of the positive current collector terminal 20 and With a part of the second portion 32 of the negative electrode current collector terminal 30 protruding to the outside of the battery case 10, the approximately U-shaped weld sealing portion 15b (three edges of the battery case 10) is thermally welded. It is formed by being sealed (see FIGS. 1 to 3). Note that a part of the second portion 22 of the positive electrode current collector terminal 20 is covered with a resin film 25, and by thermally welding the resin film 25 and the welding sealing portion 15b of the battery case 10, the positive electrode current collector A terminal 20 is joined to the battery case 10. In addition, a part of the second portion 32 of the negative electrode current collector terminal 30 is also covered with a resin film 35, and this resin film 35 and the welding sealing part 15b of the battery case 10 are thermally welded, so that the negative electrode current collector A terminal 30 is joined to the battery case 10.

次に、実施形態にかかる電池1の製造方法について説明する。本実施形態では、電池1として、リチウムイオン二次電池を製造する。図14は、実施形態にかかる電池1の製造方法の流れを示すフローチャートである。まず、ステップS1(積層電極体形成工程)において、積層電極体50(図5及び図6参照)を形成する。具体的には、複数枚の正極板60と複数枚の負極板70と複数枚のセパレータ80とを用意し、正極板60の正極合材積層部61と負極板70の負極合材積層部71との間にセパレータ80が介在するようにして、これらを積層して、電極積層部51を有する積層電極体50を作製する。 Next, a method for manufacturing the battery 1 according to the embodiment will be described. In this embodiment, a lithium ion secondary battery is manufactured as the battery 1. FIG. 14 is a flowchart showing the flow of the method for manufacturing the battery 1 according to the embodiment. First, in step S1 (stacked electrode body forming step), a stacked electrode body 50 (see FIGS. 5 and 6) is formed. Specifically, a plurality of positive electrode plates 60, a plurality of negative electrode plates 70, and a plurality of separators 80 are prepared, and the positive electrode composite material laminated portion 61 of the positive electrode plate 60 and the negative electrode composite material laminated portion 71 of the negative electrode plate 70 are prepared. The laminated electrode body 50 having the electrode laminated portion 51 is produced by laminating these with the separator 80 interposed between them.

次に、ステップS2(タブ重なり部形成工程)において、積層電極体50に含まれる複数の(全ての)負極集電タブ75について、これらの先端を切り揃えることなく、これらの厚み方向に隙間なく重ね合わせて、電極積層部51側(図15において下方)から積層方向DLに直交する直交方向DC(図15において上方)に延びる負極タブ重なり部77を形成する(図15参照)。これと同様に、積層電極体50に含まれる複数の(全ての)正極集電タブ65について、これらの先端を切り揃えることなく、これらの厚み方向に隙間なく重ね合わせて、電極積層部51側から積層方向DLに直交する直交方向DCに延びる正極タブ重なり部67を形成する。 Next, in step S2 (tab overlapping portion forming step), the plurality of (all) negative electrode current collecting tabs 75 included in the laminated electrode body 50 are formed without trimming their ends and without gaps in the thickness direction. By overlapping them, a negative electrode tab overlapping portion 77 is formed that extends from the electrode laminated portion 51 side (lower side in FIG. 15) in the orthogonal direction DC (upper side in FIG. 15) perpendicular to the lamination direction DL (see FIG. 15). Similarly, the plurality of (all) positive electrode current collecting tabs 65 included in the laminated electrode body 50 are stacked on top of each other in the thickness direction without any gaps, without trimming their tips to the electrode laminated portion 51 side. A positive electrode tab overlapping portion 67 extending from the stacking direction DL in a perpendicular direction DC perpendicular to the stacking direction DL is formed.

次に、ステップS3(溶接工程)において、負極タブ重なり部77と負極集電端子30を超音波溶接する。具体的には、図15に示すように、負極集電端子30の第1部位31が延びる方向を負極タブ重なり部77が延びる方向(直交方向DC、図15において上下方向)に一致させると共に、負極タブ重なり部77の先端部77fが第1部位31の第1端部31bよりも第2部位32から遠い側(図15において上側)に配置されるようにして、負極集電端子30の第1部位31の第1面31cに、負極タブ重なり部77を接触させる。 Next, in step S3 (welding step), the negative electrode tab overlapping portion 77 and the negative electrode current collector terminal 30 are ultrasonically welded. Specifically, as shown in FIG. 15, the direction in which the first portion 31 of the negative electrode current collector terminal 30 extends is made to match the direction in which the negative electrode tab overlapping portion 77 extends (orthogonal direction DC, the vertical direction in FIG. 15), The tip portion 77f of the negative electrode tab overlapping portion 77 is disposed on the side farther from the second portion 32 than the first end portion 31b of the first portion 31 (upper side in FIG. 15). The negative electrode tab overlapping portion 77 is brought into contact with the first surface 31c of the first portion 31.

この状態で、超音波ホーン91と超音波アンビル92とにより、負極タブ重なり部77のうち負極集電端子30の第1面31cに沿って第2部位32側から第1端部31bに向かって延びる部位77cに含まれる溶接部77bと負極集電端子30の第1部位31とを挟んで圧接する。この状態で、超音波ホーン91を超音波振動させて、負極タブ重なり部77の溶接部77bを負極集電端子30の第1部位31の第1面31cに溶接する。これと同様にして、正極タブ重なり部67の溶接部67bを、正極集電端子20の第1部位21の第1面21cに超音波溶接する。 In this state, the ultrasonic horn 91 and the ultrasonic anvil 92 move the negative electrode tab overlapping portion 77 along the first surface 31c of the negative electrode current collector terminal 30 from the second portion 32 side toward the first end portion 31b. The welding portion 77b included in the extending portion 77c and the first portion 31 of the negative electrode current collector terminal 30 are sandwiched and pressed together. In this state, the ultrasonic horn 91 is ultrasonically vibrated to weld the welded portion 77b of the negative electrode tab overlapping portion 77 to the first surface 31c of the first portion 31 of the negative electrode current collector terminal 30. In the same manner, the welded portion 67b of the positive electrode tab overlap portion 67 is ultrasonically welded to the first surface 21c of the first portion 21 of the positive electrode current collector terminal 20.

次に、ステップS4(折り返し工程)において、負極タブ重なり部77のうち、負極集電端子30の第1部位31の第1端部31bよりも第2部位32から遠い側(図15において上側)に配置されている部分77dを、第1端部31bを覆うようにして第2部位32側へ折り返して(図15において反時計回りに折り返して)、第1部位31のうち第1面31cと反対側を向く第2面31dに沿って第2部位32に向かって延びる部位77gを形成する(図15及び図16参照)。 Next, in step S4 (folding step), in the negative electrode tab overlapping portion 77, the side farther from the second portion 32 than the first end 31b of the first portion 31 of the negative electrode current collector terminal 30 (the upper side in FIG. 15) The portion 77d located at A portion 77g extending toward the second portion 32 is formed along the second surface 31d facing the opposite side (see FIGS. 15 and 16).

さらに、ステップS4(折り返し工程)では、負極タブ重なり部77と共に負極集電端子30を、図15に示す位置から時計回りに90°回転移動させて、負極タブ重なり部77のうち負極集電端子30の第1面31cに沿って第2部位32側から第1端部31bに向かって延びる部位77cを、第2部位32側で折り曲げると共に、負極集電端子30の第1部位31が延びる方向が積層方向DLに一致して、第1部位31の第1面31cが電極積層部51の端面(図16において上端面)に対向した状態にする。 Furthermore, in step S4 (folding step), the negative electrode current collector terminal 30 is rotated 90 degrees clockwise from the position shown in FIG. A portion 77c extending from the second portion 32 side toward the first end portion 31b along the first surface 31c of the negative electrode current collector terminal 30 is bent on the second portion 32 side, and the direction in which the first portion 31 of the negative electrode current collector terminal 30 extends. corresponds to the stacking direction DL, and the first surface 31c of the first portion 31 is brought into a state opposite to the end surface (the upper end surface in FIG. 16) of the electrode stack 51.

さらに、ステップS4(折り返し工程)では、負極タブ重なり部77と同様に、正極タブ重なり部67のうち、正極集電端子20の第1部位21の第1端部21bよりも第2部位22から遠い側に配置されている部分を、第1端部21bを覆うようにして第2部位22側へ折り返して、第1部位21のうち第1面21cと反対側を向く第2面21dに沿って第2部位22に向かって延びる部位67gを形成する。その後、正極タブ重なり部67と共に正極集電端子20を90°回転移動させて、正極タブ重なり部67のう正極集電端子20の第1面21cに沿って第2部位22側から第1端部21bに向かって延びる部位67cを、第2部位22側で折り曲げると共に、正極集電端子20の第1部位21が延びる方向が積層方向DLに一致した状態にする(図12参照)。 Furthermore, in step S4 (folding step), similarly to the negative electrode tab overlapping portion 77, in the positive electrode tab overlapping portion 67, the second portion 22 of the positive electrode current collecting terminal 20 is further away from the first end portion 21b of the first portion 21 of the positive electrode tab overlapping portion 67. The part disposed on the far side is folded back toward the second part 22 side so as to cover the first end part 21b, and is folded along the second surface 21d of the first part 21 facing opposite to the first surface 21c. A portion 67g extending toward the second portion 22 is formed. Thereafter, the positive electrode current collector terminal 20 is rotated by 90 degrees together with the positive electrode tab overlapping portion 67, and the first end is moved from the second portion 22 side along the first surface 21c of the positive electrode current collector terminal 20 through the positive electrode tab overlapping portion 67. The portion 67c extending toward the portion 21b is bent on the second portion 22 side, and the direction in which the first portion 21 of the positive electrode current collector terminal 20 extends coincides with the stacking direction DL (see FIG. 12).

次に、ステップS5(収容工程)において、積層電極体50を、ラミネートフィルム15からなる電池ケース10内に収容する。具体的には、正極集電端子20の第1部位21と負極集電端子30の第1部位31が電池ケース10内に収容されると共に、正極集電端子20の第2部位22と負極集電端子30の第2部位32が電池ケース10の内部から外部に延出する態様で、積層電極体50を、ラミネートフィルム15からなる電池ケース10内に収容する(図17、図1~図3参照)。 Next, in step S5 (housing step), the laminated electrode body 50 is housed in the battery case 10 made of the laminate film 15. Specifically, the first portion 21 of the positive electrode current collector terminal 20 and the first portion 31 of the negative electrode current collector terminal 30 are housed in the battery case 10, and the second portion 22 of the positive electrode current collector terminal 20 and the negative electrode collector terminal 30 are housed in the battery case 10. The laminated electrode body 50 is housed in the battery case 10 made of the laminate film 15 in such a manner that the second portion 32 of the electrical terminal 30 extends from the inside of the battery case 10 to the outside (FIG. 17, FIGS. 1 to 3 reference).

詳細には、積層電極体50をラミネートフィルム15からなる封止前の電池ケース10の内部に配置して、正極集電端子20の第1部位21と負極集電端子30の第1部位31が封止前の電池ケース10の内部に配置されると共に、正極集電端子20の第2部位22と負極集電端子30の第2部位32が封止前の電池ケース10の内側から外側に延出する状態とする。この状態で、略コの字状の溶着封止部15b(電池ケース10の3つの縁)を、その厚み方向に加圧しつつ加熱して、内側樹脂フィルム11同士を熱溶着させる(図17、図1~図3参照)。 Specifically, the laminated electrode body 50 is placed inside the battery case 10 made of the laminate film 15 before sealing, and the first portion 21 of the positive electrode current collector terminal 20 and the first portion 31 of the negative electrode current collector terminal 30 are connected to each other. The second portion 22 of the positive current collector terminal 20 and the second portion 32 of the negative current collector terminal 30 extend from the inside of the battery case 10 before sealing to the outside. It is in the state where it is released. In this state, the approximately U-shaped welding sealing portions 15b (three edges of the battery case 10) are heated while being pressurized in the thickness direction to thermally weld the inner resin films 11 together (FIG. 17, (See Figures 1 to 3).

但し、このとき、溶着封止部15bの一部を熱溶着(封止)することなく、電解液を注入する注液口(図示省略)とする。また、正極集電端子20の第2部位22の一部は樹脂膜25によって被覆されており、この樹脂膜25と電池ケース10の溶着封止部15b(内側樹脂フィルム11)とが熱溶着されることで、正極集電端子20が電池ケース10に接合される。また、負極集電端子30の第2部位32の一部も樹脂膜35によって被覆されており、この樹脂膜35と電池ケース10の溶着封止部15b(内側樹脂フィルム11)とが熱溶着されることで、負極集電端子30が電池ケース10に接合される。 However, at this time, a part of the welding sealing part 15b is not thermally welded (sealed), but instead is used as a liquid injection port (not shown) for injecting the electrolyte. Further, a part of the second portion 22 of the positive electrode current collector terminal 20 is covered with a resin film 25, and this resin film 25 and the weld sealing portion 15b (inner resin film 11) of the battery case 10 are thermally welded. By doing so, the positive electrode current collector terminal 20 is joined to the battery case 10. Further, a part of the second portion 32 of the negative electrode current collector terminal 30 is also covered with a resin film 35, and this resin film 35 and the welding sealing portion 15b (inner resin film 11) of the battery case 10 are thermally welded. By doing so, the negative electrode current collector terminal 30 is joined to the battery case 10.

次に、ステップS6(注液工程)において、注液口(図示省略)を通じて、非水電解液(図示省略)を電池ケース10内に注入する。その後、熱溶着により注液口を閉塞することで、電池ケース10が封止され、電池1が完成する。 Next, in step S6 (liquid injection step), a non-aqueous electrolyte (not shown) is injected into the battery case 10 through a liquid injection port (not shown). Thereafter, the battery case 10 is sealed by closing the liquid injection port by thermal welding, and the battery 1 is completed.

以上説明したように、本実施形態の製造方法では、折り返し工程(ステップS4)において、負極タブ重なり部77のうち、負極集電端子30の第1部位31の第1端部31bよりも第2部位32から遠い側(図15において上側)に配置されている部分77dを、第1端部31bを覆うようにして第2部位32側へ折り返す(図15及び図16参照)。これにより、負極集電端子30の第1部位31の第1端部31bは、負極タブ重なり部77によって覆われる。さらに、正極タブ重なり部67のうち、正極集電端子20の第1部位21の第1端部21bよりも第2部位22から遠い側に配置されている部分を、第1端部21bを覆うようにして第2部位22側へ折り返す。これにより、正極集電端子20の第1部位21の第1端部21bも、正極タブ重なり部67によって覆われる(図3参照)。 As described above, in the manufacturing method of the present embodiment, in the folding process (step S4), the second end portion 31b of the first portion 31 of the negative electrode current collector terminal 30 is The portion 77d located far from the portion 32 (upper side in FIG. 15) is folded back toward the second portion 32 so as to cover the first end portion 31b (see FIGS. 15 and 16). As a result, the first end portion 31b of the first portion 31 of the negative electrode current collector terminal 30 is covered by the negative electrode tab overlapping portion 77. Further, a portion of the positive electrode tab overlapping portion 67 that is located farther from the second portion 22 than the first end portion 21b of the first portion 21 of the positive electrode current collector terminal 20 covers the first end portion 21b. In this way, fold it back toward the second portion 22 side. As a result, the first end portion 21b of the first portion 21 of the positive electrode current collector terminal 20 is also covered by the positive electrode tab overlapping portion 67 (see FIG. 3).

従って、本実施形態の製造方法によれば、絶縁性の被覆部材を用いることなく、「負極集電端子30の第1端部31bの角部及び正極集電端子20の第1端部21bの角部が、ラミネートフィルム15からなる電池ケース10に対して直接に接触することを防止できる電池1」を製造することができる(図2及び図3参照)。これにより、「正極集電端子20及び負極集電端子30の第1端部21b,31bの角部の接触によって、電池ケース10を構成するラミネートフィルム15が損傷すること」を防止することができる。さらには、「ラミネートフィルム15の樹脂フィルム(内側樹脂フィルム11)のうち第1端部21b,31bの角部が接触した部分が破断し、第1部位21,31の第1端部21b,31bが、ラミネートフィルム15の内部の金属フィルム12に対して直接に接触して、金属フィルム12と集電端子(正極集電端子20及び負極集電端子30)とが導通する不具合」が発生することを防止できる。 Therefore, according to the manufacturing method of the present embodiment, "the corners of the first end 31b of the negative electrode current collector terminal 30 and the first end 21b of the positive electrode current collector terminal 20 are It is possible to manufacture a battery 1 in which the corners can be prevented from coming into direct contact with the battery case 10 made of the laminate film 15 (see FIGS. 2 and 3). This can prevent damage to the laminate film 15 constituting the battery case 10 due to contact between the corners of the first ends 21b and 31b of the positive current collector terminal 20 and the negative current collector terminal 30. . Furthermore, "the part of the resin film (inner resin film 11) of the laminate film 15 that the corners of the first ends 21b, 31b are in contact with breaks, and the first ends 21b, 31b of the first parts 21, 31 may come into direct contact with the metal film 12 inside the laminate film 15, causing a problem in which the metal film 12 and the current collector terminals (the positive electrode current collector terminal 20 and the negative electrode current collector terminal 30) are electrically connected. can be prevented.

さらに、本実施形態の製造方法では、積層電極体50に含まれる複数の(全ての)負極集電タブ75について、これらの先端を切り揃えることなく、これらの厚み方向に隙間なく重ね合わせて、負極タブ重なり部77を形成する(図15参照)。これと同様に、積層電極体50に含まれる複数の(全ての)正極集電タブ65について、これらの先端を切り揃えることなく、これらの厚み方向に隙間なく重ね合わせて、正極タブ重なり部67を形成する。 Furthermore, in the manufacturing method of the present embodiment, the tips of the plurality of (all) negative electrode current collecting tabs 75 included in the laminated electrode body 50 are not trimmed and are stacked without any gaps in the thickness direction, A negative electrode tab overlapping portion 77 is formed (see FIG. 15). Similarly, the plurality of (all) positive electrode current collecting tabs 65 included in the laminated electrode body 50 are overlapped in the thickness direction without any gaps without trimming their ends to form the positive electrode tab overlapping portion 67. form.

従って、本実施形態の製造方法では、従来の製造方法に比べて、複数の集電タブ(正極集電タブ及び負極集電タブ)の先端を切り揃える切断工程を省略することができるので、製造コストを低減することができる。さらには、前記切断工程を省略することによって、前記切断工程によって発生した金属粉等の異物が電池内に混入する不具合も無くなるので好ましい。 Therefore, in the manufacturing method of this embodiment, compared to the conventional manufacturing method, the cutting step of trimming the ends of the plurality of current collecting tabs (positive electrode current collecting tab and negative electrode current collecting tab) can be omitted, so the manufacturing method Cost can be reduced. Furthermore, by omitting the cutting step, there is no problem that foreign matter such as metal powder generated by the cutting step gets mixed into the battery, which is preferable.

以上において、本発明を実施形態に即して説明したが、本発明は前記実施形態に限定されるものではなく、その要旨を逸脱しない範囲で、適宜変更して適用できることはいうまでもない。 Although the present invention has been described above based on the embodiments, it goes without saying that the present invention is not limited to the embodiments, and can be applied with appropriate modifications without departing from the gist thereof.

1 電池
10 電池ケース
11 内側樹脂フィルム
12 金属フィルム
13 外側樹脂フィルム
15 ラミネートフィルム
20 正極集電端子
21,31 第1部位
21b,31b 第1端部
21c,31c 第1面
21d,31d 第2面
22,32 第2部位
30 負極集電端子
50 積層電極体
51 電極積層部
60 正極板(電極板)
61 正極合材積層部
62 正極合材層(電極合材層)
65 正極集電タブ
66 正極集電箔
67 正極タブ重なり部
67b,77b 溶接部
70 負極板(電極板)
71 負極合材積層部
72 負極合材層(電極合材層)
75 負極集電タブ
76 負極集電箔
77 負極タブ重なり部
80 セパレータ
1 Battery 10 Battery case 11 Inner resin film 12 Metal film 13 Outer resin film 15 Laminate film 20 Positive electrode current collector terminal 21, 31 First portion 21b, 31b First end portion 21c, 31c First surface 21d, 31d Second surface 22 , 32 Second portion 30 Negative current collector terminal 50 Laminated electrode body 51 Electrode laminated portion 60 Positive electrode plate (electrode plate)
61 Positive electrode composite material laminated part 62 Positive electrode composite material layer (electrode composite material layer)
65 Positive electrode current collector tab 66 Positive electrode current collector foil 67 Positive electrode tab overlapping part 67b, 77b Welding part 70 Negative electrode plate (electrode plate)
71 Negative electrode composite material laminated part 72 Negative electrode composite material layer (electrode composite material layer)
75 Negative electrode current collector tab 76 Negative electrode current collector foil 77 Negative electrode tab overlapping portion 80 Separator

Claims (2)

集電箔の表面に電極合材層が積層された合材積層部と、前記集電箔のうち前記電極合材層が積層されることなく前記合材積層部から延出する集電タブと、を有する複数枚の電極板を備え、複数の前記合材積層部がセパレータを介して積層方向に積層された電極積層部を有する積層電極体と、
金属フィルムの両面が樹脂フィルムで被覆された構造のラミネートフィルムからなり、前記積層電極体を収容する電池ケースと、
前記積層電極体のうち複数の前記集電タブに接合して、前記電池ケースの内部から外部に延出する集電端子と、を備える
電池において、
前記集電端子は、側面視L字形状をなし、前記積層方向に延びる形態をなして前記電池ケース内に収容される第1部位と、前記積層方向に直交する方向に延びる形態をなして前記電池ケースの内部から外部に延出する第2部位と、が連結された形態を有し、
複数の前記集電タブは、これらの厚み方向に隙間なく重ね合わされたタブ重なり部であって、その長さ方向について前記電極積層部側から先端側へ延びるタブ重なり部を形成しており、
前記集電端子の前記第1部位は、当該第1部位が延びる前記積層方向にかかる端部であって前記第2部位から最も離れて位置する第1端部を有し、
前記タブ重なり部は、前記第1部位のうち前記電極積層部側を向く第1面に沿って前記第2部位側から前記第1端部に向かって延び、前記第1端部を覆う態様で前記第2部位側へ折り返されて、前記第1部位のうち前記第1面と反対側を向く第2面に沿って前記第2部位に向かって延びる形態をなしており、
前記タブ重なり部のうち、前記第1部位の前記第1面に沿って前記第2部位側から前記第1端部に向かって延びる部位に含まれる溶接部が、前記第1部位の前記第1面に溶接されている
電池。
A composite material laminated part in which an electrode composite material layer is laminated on the surface of the current collector foil, and a current collector tab that extends from the composite material laminated part without the electrode composite material layer being laminated on the current collector foil. A laminated electrode body comprising a plurality of electrode plates having a plurality of electrode plates, and having an electrode lamination part in which a plurality of the composite material lamination parts are laminated in the lamination direction with a separator interposed therebetween;
a battery case that is made of a laminate film having a structure in which both sides of a metal film are covered with a resin film, and that houses the laminated electrode body;
A battery comprising: a current collecting terminal connected to a plurality of the current collecting tabs of the laminated electrode body and extending from the inside of the battery case to the outside;
The current collector terminal has an L-shape when viewed from the side, and includes a first portion that extends in the stacking direction and is housed in the battery case, and a first portion that extends in the stacking direction and a first portion that extends in the stacking direction. and a second portion extending from the inside of the battery case to the outside,
The plurality of current collecting tabs are overlapped with each other without gaps in their thickness direction, forming a tab overlapping part extending from the electrode lamination part side to the tip side in the length direction,
The first portion of the current collector terminal has a first end that extends in the stacking direction and is located farthest from the second portion,
The tab overlapping portion extends from the second portion side toward the first end portion along a first surface of the first portion facing the electrode lamination portion side, and covers the first end portion. It is folded back toward the second portion and extends toward the second portion along a second surface of the first portion that faces opposite to the first surface;
A welded portion included in a portion of the tab overlapping portion that extends from the second portion side toward the first end portion along the first surface of the first portion is Batteries welded to the surface.
請求項1に記載の電池の製造方法であって、
複数枚の前記電極板のうち複数の前記合材積層部を前記セパレータを介して積層して、前記電極積層部を有する前記積層電極体を形成する積層電極体形成工程と、
前記積層電極体のうち複数の前記集電タブについて、これらの先端を切り揃えることなく、これらの厚み方向に隙間なく重ね合わせて、前記電極積層部側から前記積層方向に直交する方向に延びる前記タブ重なり部を形成するタブ重なり部形成工程と、
前記集電端子の前記第1部位が延びる方向を前記タブ重なり部が延びる方向に一致させると共に、前記タブ重なり部の先端部が前記第1部位の前記第1端部よりも前記第2部位から遠い側に配置されるようにした状態で、前記タブ重なり部のうち前記第1部位の前記第1面に沿って前記第2部位側から前記第1端部に向かって延びる部位に含まれる前記溶接部を、前記第1部位の前記第1面に溶接する溶接工程と、
前記タブ重なり部のうち前記第1部位の前記第1端部よりも前記第2部位から遠い側に配置されている部分を、前記第1端部を覆うようにして前記第2部位側へ折り返して、前記第1部位のうち前記第1面と反対側を向く第2面に沿って前記第2部位に向かって延びる部位を形成する折り返し工程と、
前記集電端子の前記第1部位が前記電池ケース内に収容されると共に前記第2部位が前記電池ケースの内部から外部に延出する態様で、前記積層電極体を、前記ラミネートフィルムからなる前記電池ケース内に収容する収容工程と、を備える
電池の製造方法。
A method for manufacturing a battery according to claim 1, comprising:
a laminated electrode body forming step of laminating a plurality of the composite material laminated parts of the plurality of electrode plates via the separator to form the laminated electrode body having the electrode laminated parts;
The plurality of current collecting tabs of the laminated electrode body are overlapped without gaps in the thickness direction without trimming the tips thereof, and the plurality of current collecting tabs are arranged so as to extend from the electrode lamination part side in a direction perpendicular to the lamination direction. a tab overlapping portion forming step of forming a tab overlapping portion;
The direction in which the first portion of the current collector terminal extends is made to match the direction in which the tab overlapping portion extends, and the tip of the tab overlapping portion is further away from the second portion than the first end of the first portion. The tab is included in a portion of the tab overlapping portion that extends from the second portion side toward the first end portion along the first surface of the first portion in a state where the tab is disposed on the far side. a welding step of welding a welding portion to the first surface of the first portion;
A portion of the tab overlapping portion that is located farther from the second portion than the first end of the first portion is folded back toward the second portion so as to cover the first end. a folding step of forming a portion of the first portion that extends toward the second portion along a second surface facing opposite to the first surface;
The laminated electrode body is connected to the laminated electrode body made of the laminate film in such a manner that the first portion of the current collector terminal is housed in the battery case and the second portion extends from the inside of the battery case to the outside. A method of manufacturing a battery, comprising: housing the battery in a battery case.
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Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
JP2007234466A (en) 2006-03-02 2007-09-13 Nec Tokin Corp Stacked lithium ion cell and its manufacturing method
JP2012054029A (en) 2010-08-31 2012-03-15 Sanyo Electric Co Ltd Laminate type battery
JP2012164470A (en) 2011-02-04 2012-08-30 Sanyo Electric Co Ltd Laminate type battery and manufacturing method thereof
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