JP6972617B2 - Underwater oil type emulsified oil / fat composition for kneading bread dough - Google Patents
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Description
本発明は、パン生地練り込み用水中油型乳化油脂組成物に関する。 The present invention relates to an oil-in-water emulsified oil / fat composition for kneading bread dough.
パンは、元来穀物の加工形態として創出され、通常原料として小麦粉、イースト、食塩、水に、砂糖、乳製品、油脂、その他の副原料を配合し、または食品添加物を加え混合し
た生地を発酵・膨化させ焼成して作られる。
ところで、最近の消費者のパンの嗜好傾向の一つとして、ソフトな食感に加えて、もっちりとした食感のパンを嗜好する傾向にある。パンにもっちりとした食感を付与する方法として、特許文献1には高度分岐環状デキストリンをパン生地に添加する方法が提供されている。
また、特許文献2には、油脂、糖アルコール、澱粉、蛋白質および増粘剤を含む水中油型乳化油脂組成物を、パン生地に添加する方法が提供されている。
また、特許文献3には、湯種製法において、有機酸を水中油型に乳化した、酸性水中油型乳化油脂組成物を湯種生地に添加する方法が提供されている。
Bread was originally created as a processed form of cereals, and is usually made by mixing flour, yeast, salt, water with sugar, dairy products, fats and oils, and other auxiliary ingredients, or by adding food additives. It is made by fermenting, swelling and baking.
By the way, as one of the recent consumer tastes for bread, there is a tendency to prefer bread with a chewy texture in addition to a soft texture. As a method for imparting a firm texture to bread, Patent Document 1 provides a method for adding highly branched cyclic dextrin to bread dough.
Further, Patent Document 2 provides a method for adding an oil-in-water emulsified oil / fat composition containing an oil / fat, a sugar alcohol, starch, a protein and a thickener to a bread dough.
Further, Patent Document 3 provides a method of adding an acidic oil-in-water-type emulsified oil / fat composition in which an organic acid is emulsified into an oil-in-water type to a water roux dough in a water roux production method.
本発明が解決しようとする課題は、もっちりとした食感を有しつつ、かつ、歯切れの良い食感を有するパンを製造することができる、パン生地に練り込んで使用する新素材を提供することである。 The problem to be solved by the present invention is to provide a new material used by kneading into a bread dough, which can produce bread having a chewy texture and a crisp texture. That is.
本発明は、以下の構成を包含する。
(1)油脂、澱粉、蛋白質、水分を含み、かつ下記A)〜C)の特徴を有するパン生地練り込み用水中油型乳化油脂組成物。 A)蛋白質含有素材として、全脂大豆からの水抽出物であって、炭水化物に対する蛋白質の重量比が100〜200質量%である大豆抽出物を含むこと、 B)酸を含むこと、 C)性状が可塑性を有すること、
(2)油脂を5〜40質量%含む、前記(1)記載のパン生地練り込み用水中油型乳化油脂組成物、
(3)澱粉を2〜15質量%含む、前記(1)又は(2)記載のパン生地練り込み用水中油型乳化油脂組成物、
(4)蛋白質を1〜10質量%含む、前記(1)〜(3)の何れか1項記載のパン生地練り込み用水中油型乳化油脂組成物、
(5)蛋白質含有素材として、該大豆抽出物と、さらに他の大豆蛋白素材を含む、前記(1)〜(4)の何れか1項記載のパン生地練り込み用水中油型乳化油脂組成物、
(6)該大豆蛋白素材が、分離大豆蛋白である、前記(5)記載のパン生地練り込み用水中油型乳化油脂組成物。
The present invention includes the following configurations.
(1) An oil-in-water emulsified oil / fat composition for kneading bread dough, which contains oil / fat, starch, protein, and water and has the following characteristics A) to C). A) As a protein-containing material, a water extract from full-fat soybean, which contains a soybean extract having a weight ratio of protein to carbohydrate of 100 to 200% by mass, B) contains acid, C) properties. Has plasticity,
(2) The oil-in-water emulsified oil / fat composition for kneading bread dough according to (1) above, which contains 5 to 40% by mass of oil / fat.
(3) The oil-in-water emulsified oil / fat composition for kneading bread dough according to (1) or (2) above, which contains 2 to 15% by mass of starch.
(4) The oil-in-water emulsified oil / fat composition for kneading bread dough according to any one of (1) to (3) above, which contains 1 to 10% by mass of protein.
(5) The oil-in-water emulsified oil / fat composition for kneading bread dough according to any one of (1) to (4) above, which comprises the soybean extract and another soybean protein material as a protein-containing material.
(6) The oil-in-water emulsified oil / fat composition for kneading bread dough according to (5) above, wherein the soybean protein material is separated soybean protein.
本発明によって提供される水中油型乳化油脂組成物をパン生地に練り込んでパンを製造することにより、もっちりとした食感を有しつつ、かつ、歯切れの良い食感を有するパンを製造することができるを提供することができる。 By kneading the oil-in-water emulsified oil / fat composition provided by the present invention into bread dough to produce bread, bread having a chewy texture and a crisp texture can be produced. Can be provided.
本発明のパン生地練り込み用水中油型乳化油脂組成物(以下、単に「水中油型乳化油脂組成物」と称する場合がある。)は、油脂、澱粉、蛋白質、水分を含み、かつ、A)蛋白質含有素材として、全脂大豆からの水抽出物であって、炭水化物に対する蛋白質の重量比が100〜200質量%である大豆抽出物を含むこと、B)少なくとも蛋白質を含む原料の一部又は全部が乳酸発酵されていること、および、C)性状が可塑性 あることを特徴とする。以下、本発明の実施形態について具体的に説明する。 The oil-in-water emulsified oil / fat composition for kneading bread dough of the present invention (hereinafter, may be simply referred to as “oil-in-water emulsified oil / fat composition”) contains oil / fat, starch, protein, and water, and A) protein. As the contained material, a water extract from full-fat soybean, which contains a soybean extract having a weight ratio of protein to carbohydrate of 100 to 200% by mass, B) at least a part or all of the raw material containing protein. It is characterized by being fermented with lactic acid and C) having plastic properties. Hereinafter, embodiments of the present invention will be specifically described.
(油脂)
本発明の水中油型乳化油脂組成物に用いられる油脂としては、食用として用いられているものであれば植物性油脂、動物性油脂の何れを用いてもよく、例えば、ナタネ油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、胡麻油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油等の植物性油脂、乳脂、牛脂、豚脂、魚油、鯨油等の動物性油脂、又はこれらに水素添加、分別及びエステル交換から選択される一又は二以上の処理を施した加工油脂が挙げられる。本発明においては、これらの油脂を単独で用いることもでき、又は2種以上を組合せて用いることもできる。
(Fat and oil)
As the oil and fat used in the oil-in-water emulsified oil and fat composition of the present invention, either vegetable oil or animal oil or fat may be used as long as it is used for food, and for example, rapeseed oil, soybean oil, etc. Plants such as sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, capoc oil, sesame oil, evening primrose oil, palm oil, shea butter, monkey fat, cocoa butter, palm oil, palm kernel oil, etc. Examples thereof include animal fats and oils such as sex fats and oils, milk fats, beef fats, pork fats, fish oils and whale oils, or processed fats and oils which have been subjected to one or more treatments selected from hydrogenation, fractionation and ester exchange. In the present invention, these fats and oils can be used alone or in combination of two or more.
本発明の水中油型乳化油脂組成物中の油脂の含量は、上記油脂以外の原料中に含まれる脂質も含めた脂質含量として、5質量%以上、7質量%以上、8質量%以上、9質量%以上又は10質量%以上などとすることができる。また、さらに40質量%以下、35質量%以下、30質量%以下又は26質量%以下などとすることができる。 The content of fats and oils in the oil-in-water emulsified fat and oil composition of the present invention is 5% by mass or more, 7% by mass or more, 8% by mass or more, and 9 as the lipid content including lipids contained in raw materials other than the above fats and oils. It can be mass% or more, 10 mass% or more, and the like. Further, it can be further set to 40% by mass or less, 35% by mass or less, 30% by mass or less, 26% by mass or less, and the like.
(澱粉)
本発明の水中油型乳化油脂組成物に用いられる澱粉としては、食用として用いられているものであれば何れを用いてもよく、例えば、小麦澱粉、米澱粉、モチ米澱粉、サゴ澱粉、タピオカ澱粉、甘藷澱粉、コーンスターチ、ワキシーコーンスターチ等の生澱粉や、これらに架橋処理、α化処理、エーテル化処理、エステル化処理、分解処理等の処理が施された化工澱粉等が挙げられる。
(starch)
As the starch used in the oil-in-water emulsified oil / fat composition of the present invention, any starch used for food may be used, for example, wheat starch, rice starch, glutinous rice starch, sago starch, tapioca. Examples thereof include raw starch such as starch, sweet potato starch, corn starch and waxy corn starch, and chemical starch which has been subjected to treatments such as cross-linking treatment, pregelatinization treatment, etherification treatment, esterification treatment and decomposition treatment.
本発明の水中油型乳化油脂組成物中の澱粉の含量は、2質量%以上、3質量%以上、3.5質量%以上、4質量%以上又は4.5質量%以上などとすることができる。また、さらに15質量%以下、12質量%以下、10質量%以下、9質量%以下、8質量%以下又は7.5質量%以下などとすることができる。 The content of starch in the oil-in-water emulsified oil / fat composition of the present invention may be 2% by mass or more, 3% by mass or more, 3.5% by mass or more, 4% by mass or more, 4.5% by mass or more, and the like. can. Further, it can be further set to 15% by mass or less, 12% by mass or less, 10% by mass or less, 9% by mass or less, 8% by mass or less, 7.5% by mass or less, and the like.
(蛋白質)
本発明の水中油型乳化油脂組成物に用いられる蛋白質としては、主に蛋白質含有素材の配合に由来する。
蛋白質含有素材として、少なくとも上記A)の特定の大豆抽出物(以下、「本抽出物」と称する場合がある。)を用いることを特徴とする。本発明の水中油型乳化油脂組成物中の総蛋白質における本抽出物由来の蛋白質の割合は、30質量%以上、40質量%以上、50質量%以上、60質量%以上、70質量%以上、80質量%以上、90質量%以上又は100質量%とすることができる。
(protein)
The protein used in the oil-in-water emulsified oil / fat composition of the present invention is mainly derived from the formulation of a protein-containing material.
As the protein-containing material, at least the specific soybean extract of A) above (hereinafter, may be referred to as “the present extract”) is used. The proportion of the protein derived from this extract in the total protein in the oil-in-water emulsified oil / fat composition of the present invention is 30% by mass or more, 40% by mass or more, 50% by mass or more, 60% by mass or more, 70% by mass or more. It can be 80% by mass or more, 90% by mass or more, or 100% by mass.
(大豆抽出物)
以下、本抽出物の態様について説明する。
本抽出物の原料となる大豆は、全脂大豆である。全脂大豆は、圧搾やロールによる物理的処理や有機溶剤処理などにより大豆油の抽出処理がされていないものをいう。脂質含量は特に限定されないが、抽出処理がされていない全脂大豆では固形分中15質量%を超えるのが通常であり、多くは18質量%以上である。分離大豆蛋白や醤油の製造などに使用されているような脱脂大豆を原料とした場合は、本発明の効果を奏しにくい。
(Soybean extract)
Hereinafter, aspects of the present extract will be described.
The soybean that is the raw material of this extract is full-fat soybean. Full-fat soybeans are soybean oil that has not been extracted by squeezing, physical treatment with rolls, or organic solvent treatment. The lipid content is not particularly limited, but the total fat soybean that has not been extracted usually exceeds 15% by mass in the solid content, and most of them are 18% by mass or more. When defatted soybeans such as those used in the production of isolated soybean protein and soy sauce are used as raw materials, the effects of the present invention are difficult to achieve.
本抽出物の原料となる全脂大豆は未粉砕のままでも良いし、水性溶媒により抽出する前に予め砕かれていても良い。全脂大豆を予め砕く場合の粒子径は任意であり、粗砕でも粉砕でも良い。 The full-fat soybean which is the raw material of the present extract may be left unground or may be crushed in advance before extraction with an aqueous solvent. When the whole fat soybean is crushed in advance, the particle size is arbitrary and may be coarsely crushed or crushed.
また全脂大豆は生のままでも良いが、水性溶媒により抽出される前に、予め加熱処理されていることがより好ましい。特に全脂大豆を砕く場合においては、砕く前に予め加熱処理を行っておくのがより好ましい。全脂大豆の加熱処理の方法は特に限定されず、例えば乾熱処理、水蒸気処理、過熱水蒸気処理、マイクロ波処理等を用いることができる。また水に浸漬した後、抽出前に加熱処理することもできる。 The full-fat soybean may be raw, but it is more preferable that the soybean is heat-treated in advance before being extracted with an aqueous solvent. In particular, when crushing full-fat soybeans, it is more preferable to perform heat treatment in advance before crushing. The method of heat treatment of full-fat soybean is not particularly limited, and for example, dry heat treatment, steam treatment, superheated steam treatment, microwave treatment and the like can be used. It can also be heat-treated after being immersed in water and before extraction.
加熱処理の程度は抽出物に焦げ臭が付与されない程度が好ましい。加熱の程度は蛋白質
の変性度合を表すNSI(水溶性窒素指数)により表すことができ、NSIは15〜77が好ましく、40〜70がより好ましい。かかる範囲に加熱することにより、より低脂質の大豆抽出物を得ることができる。加熱処理の条件は加熱処理装置により異なるため特に限定されず、NSIが上記範囲となるように適宜設定すれば良い。例えば乾熱加熱処理を行う場合、その処理条件は製造環境にも影響されるため一概に言えないが、例えば120〜250℃の過熱水蒸気を用いて1秒〜10分の間で加熱処理後の大豆のNSIが上記範囲となるように処理条件を適宜選択すれば良く、処理条件の決定に特段の困難は要しない。
The degree of heat treatment is preferably such that the extract is not given a burning odor. The degree of heating can be expressed by NSI (water-soluble nitrogen index) indicating the degree of protein denaturation, and the NSI is preferably 15 to 77, more preferably 40 to 70. By heating to such a range, a lower lipid soybean extract can be obtained. The conditions of the heat treatment are not particularly limited because they differ depending on the heat treatment device, and the NSI may be appropriately set so as to be within the above range. For example, in the case of dry heat heat treatment, the treatment conditions are affected by the manufacturing environment, so it cannot be said unconditionally. For example, after heat treatment using superheated steam at 120 to 250 ° C. for 1 second to 10 minutes. The treatment conditions may be appropriately selected so that the NSI of soybeans falls within the above range, and no particular difficulty is required in determining the treatment conditions.
なお、NSIは所定の方法に基づき、全窒素量に占める水溶性窒素(粗蛋白)の比率(質量%)で表すことができ、本発明においては以下の方法に基づいて測定された値とする。
すなわち、試料2.0gに100mlの水を加え、40℃にて60分攪拌抽出し、1400×gにて10分間遠心分離し、上清1を得る。残った沈殿に再度100mlの水を加え、40℃にて60分攪拌抽出し、1400×gにて10分遠心分離し、上清2を得る。上清1および上清2を合わせ、さらに水を加えて250mlとする。No.5Aろ紙にてろ過したのち、ろ液の窒素含量をケルダール法にて測定する。同時に試料中の窒素含量をケルダール法にて測定し、ろ液として回収された窒素(水溶性窒素)の試料中の全窒素に対する割合を質量%として表したものをNSIとする。
In addition, NSI can be expressed by the ratio (mass%) of water-soluble nitrogen (crude protein) to the total amount of nitrogen based on a predetermined method, and in the present invention, it is a value measured based on the following method. ..
That is, 100 ml of water is added to 2.0 g of a sample, the mixture is stirred and extracted at 40 ° C. for 60 minutes, and centrifuged at 1400 × g for 10 minutes to obtain supernatant 1. Add 100 ml of water to the remaining precipitate again, stir and extract at 40 ° C. for 60 minutes, and centrifuge at 1400 × g for 10 minutes to obtain supernatant 2. Combine supernatant 1 and supernatant 2, and add water to make 250 ml. After filtering with No. 5A filter paper, the nitrogen content of the filtrate is measured by the Kjeldahl method. At the same time, the nitrogen content in the sample is measured by the Kjeldahl method, and the ratio of nitrogen (water-soluble nitrogen) recovered as a filtrate to the total nitrogen in the sample is expressed as mass%, which is defined as NSI.
本発明の有効成分を抽出するための水性溶媒は、水や含水アルコール等を用いることができ、水や含水エタノールが食品製造上好ましい。 Water, hydrous alcohol, or the like can be used as the aqueous solvent for extracting the active ingredient of the present invention, and water or hydrous ethanol is preferable in food production.
本抽出物は、一つの好ましい態様として、固形分中の脂質含量が15質量%以下であることができ、さらに12質量%以下、10質量%以下がより好ましい。なお、本発明において、脂質含量は酸分解法により測定される。
かかる態様の場合、例えば全脂大豆から抽出した通常の脂質含量の高い全脂豆乳や、脱脂大豆から抽出した脱脂豆乳とは明確に区別されるものである。本抽出物は、いわゆる「低脂肪豆乳」が典型的には包含されるが、全脂大豆からの水性溶媒抽出物であって脂質含量が上記範囲である限り、これらの呼称に限定されるものではない。
大豆を水性溶媒で抽出する際の加水量、抽出温度、抽出時間等の抽出条件は特に限定されず、例えば加水量は大豆に対して2〜15重量倍、抽出温度は20〜99℃、抽出時間は20分〜14時間などで設定すればよい。本抽出物は液状、固形状、粉末状の何れの形態もとり得る。
As one preferred embodiment, the present extract can have a lipid content of 15% by mass or less in the solid content, and more preferably 12% by mass or less and 10% by mass or less. In the present invention, the lipid content is measured by the acid decomposition method.
In such an embodiment, it is clearly distinguished from, for example, normal full-fat soymilk extracted from full-fat soybean and high-fat soymilk extracted from defatted soybean. The present extract typically includes so-called "low-fat soymilk", but is an aqueous solvent extract from full-fat soybean and is limited to these names as long as the lipid content is within the above range. is not it.
Extraction conditions such as the amount of water added, the extraction temperature, and the extraction time when extracting soybeans with an aqueous solvent are not particularly limited. The time may be set from 20 minutes to 14 hours. The extract may be in the form of liquid, solid or powder.
本抽出物に含まれる脂質以外の成分は、水可溶性の成分が主体であり、炭水化物と蛋白質を主体としてその他のミネラル、イソフラボン、サポニン等の微量成分が含まれる。
ここで、本抽出物中の炭水化物に対する蛋白質含量(以下、「P/C含量」と称する場合がある。)は、100〜200質量%であることが重要である。さらに120質量%以上、130質量%以上や140質量%以上の範囲、またさらに190質量%以下、180質量%以下や170質量%以下の範囲を選択することができる。ちなみに全脂豆乳や脱脂豆乳粉末は、P/C含量が200質量%を大きく超え、相対的に高蛋白質含量であり、本抽出物とは異なる。
The components other than lipids contained in this extract are mainly water-soluble components, mainly carbohydrates and proteins, and include trace components such as other minerals, isoflavones, and saponins.
Here, it is important that the protein content (hereinafter, may be referred to as “P / C content”) with respect to the carbohydrate in the present extract is 100 to 200% by mass. Further, a range of 120% by mass or more, 130% by mass or more, 140% by mass or more, and further 190% by mass or less, 180% by mass or less, or 170% by mass or less can be selected. By the way, the total fat soymilk and the skim milk powder have a P / C content of more than 200% by mass and a relatively high protein content, which is different from this extract.
また上述した分離大豆蛋白などのような、蛋白質が固形分中90質量%程度も含まれるような大豆蛋白質素材は、貯蔵蛋白質が主成分であり炭水化物が微量しか含まれないため、P/C含量が過剰であり、これも本抽出物とは異なるものである。全脂豆乳、脱脂豆乳粉末、分離大豆蛋白のように、P/C含量が比較的高い範囲の蛋白質含有素材を多く使用しすぎると、もっちりとした食感と歯切れの良い食感が両立したパンを得ることが困難となる。また大豆蛋白に由来する特有の青臭みや渋みにより、好ましくない風味となってしまう。
なお、本発明において、蛋白質含量はケルダール法により測定される。また炭水化物含
量は、固形分から脂質、蛋白質及び灰分の含量の和を引いた計算値とする。
Further, soybean protein materials such as the above-mentioned isolated soybean protein containing about 90% by mass of protein in the solid content contain P / C content because the main component is stored protein and only a trace amount of carbohydrate is contained. Is excessive, which is also different from this extract. If too much protein-containing material with a relatively high P / C content, such as full-fat soymilk, skim soymilk powder, and isolated soy protein, is used, both a chewy texture and a crisp texture are achieved. It becomes difficult to get bread. In addition, the peculiar green odor and astringency derived from soy protein result in an unfavorable flavor.
In the present invention, the protein content is measured by the Kjeldahl method. The carbohydrate content is a calculated value obtained by subtracting the sum of the contents of lipid, protein and ash from the solid content.
○低脂肪豆乳
本抽出物の一形態である低脂肪豆乳は、固形分中の脂質含量とP/C含量が上記範囲にあるものである。ちなみに全脂大豆から公知の方法で抽出して得たスラリー(大豆粉砕液)から不溶性画分であるオカラを除去して得られる一般の豆乳(全脂豆乳)では、固形分中の脂質含量が上記範囲よりも高くなり、20質量%以上となる。またP/C含量も250を超える。低脂肪豆乳を得るには、スラリーや全脂豆乳から高速遠心分離等により脂質を分離する方法や、該スラリーからオカラを分離する際に脂質をオカラ側に移行させる方法を用いることができる。より好ましい態様として、上記の通り予め加熱処理された全脂大豆、好ましくはNSI15〜77、より好ましくはNSI40〜70の全脂大豆を原料とすることによって、より本発明の効果を向上させることができる。この方法は例えば特開2012-16348号公報に記載の方法を参照することができる。
○ Low-fat soymilk Low-fat soymilk, which is a form of this extract, has a lipid content and a P / C content in the solid content within the above range. By the way, in general soymilk (full-fat soymilk) obtained by removing okara, which is an insoluble fraction, from a slurry (ground soybean liquid) obtained by extracting from full-fat soybean by a known method, the lipid content in the solid content is high. It is higher than the above range and is 20% by mass or more. The P / C content also exceeds 250. In order to obtain low-fat soymilk, a method of separating lipids from a slurry or full-fat soymilk by high-speed centrifugation or the like, or a method of transferring lipids to the okara side when separating okara from the slurry can be used. As a more preferable embodiment, the effect of the present invention can be further improved by using the pre-heat-treated full-fat soybean as described above, preferably the full-fat soybean of NSI15 to 77, more preferably NSI40 to 70 as a raw material. can. For this method, for example, the method described in JP-A-2012-16348 can be referred to.
本発明の水中油型乳化油脂組成物に用いられる蛋白質には、本抽出物と共にその他の蛋白質含有素材を用いることができる。例えば大豆,エンドウ,緑豆等の豆類や、小麦,米等の穀類由来の植物性蛋白素材、乳蛋白やゼラチン等の動物性蛋白素材等を用いることができる。例えば大豆蛋白素材としては、分離大豆蛋白又はその加水分解物、濃縮大豆蛋白、全脂豆乳や脱脂豆乳(本抽出物に含まれないもの)、大豆粉等を用いることができる。乳蛋白素材としては、ホエー蛋白、カゼイン又はその塩、全脂粉乳、脱脂粉乳、TMP、MPC等を用いることができる。一つの態様として、植物性であり、本抽出物と併用してもパン生地への練り込み性等の物性を阻害しにくい点で、大豆蛋白素材を用いることが好ましい。特に大豆蛋白素材のうち、分離大豆蛋白がより好ましい。 As the protein used in the oil-in-water emulsified oil / fat composition of the present invention, other protein-containing materials can be used together with the present extract. For example, beans such as soybeans, pea and mung beans, vegetable protein materials derived from grains such as wheat and rice, animal protein materials such as milk protein and gelatin can be used. For example, as the soybean protein material, isolated soybean protein or its hydrolyzate, concentrated soybean protein, full-fat soymilk, defatted soymilk (not included in this extract), soybean flour and the like can be used. As the milk protein material, whey protein, casein or a salt thereof, full-fat milk powder, skim milk powder, TMP, MPC and the like can be used. As one embodiment, it is preferable to use a soybean protein material because it is plant-based and does not easily impair physical properties such as kneading property into bread dough even when used in combination with the present extract. In particular, among the soybean protein materials, isolated soybean protein is more preferable.
本発明の水中油型乳化油脂組成物中の蛋白質の含量は、上記蛋白質含有素材以外の原料中に含まれる蛋白質も含めた蛋白質含量として、1質量%以上、1.5質量%以上又は2質量%以上などとすることができる。またさらに10質量%以下、8質量%以下、7質量%以下、6質量%以下、5質量%以下又は4.5質量%以下などとすることができる。 The protein content in the oil-in-water emulsified oil / fat composition of the present invention is 1% by mass or more, 1.5% by mass or more, or 2% by mass as the protein content including proteins contained in raw materials other than the above protein-containing materials. It can be% or more. Further, it can be further 10% by mass or less, 8% by mass or less, 7% by mass or less, 6% by mass or less, 5% by mass or less, 4.5% by mass or less, and the like.
(水分)
本発明の水中油型乳化油脂組成物で用いることができる水分としては、飲用に適する限り特に限定されず、水道水、蒸留水、ミネラルウォーター等を用いることができる。本発明の水中油型乳化油脂組成物の水分含量は、上記水以外の原料中に含まれる水分も含めた水分含量として、40〜80質量%が好ましく、50〜70質量%がより好ましく、55〜65質量%がさらに好ましい。
(moisture)
The water content that can be used in the oil-in-water emulsified oil / fat composition of the present invention is not particularly limited as long as it is suitable for drinking, and tap water, distilled water, mineral water and the like can be used. The water content of the oil-in-water emulsified oil / fat composition of the present invention is preferably 40 to 80% by mass, more preferably 50 to 70% by mass, and more preferably 55, as the water content including the water contained in the raw materials other than the above water. ~ 65% by mass is more preferable.
(他の原料)
本発明の水中油型乳化油脂組成物で用いることができる、その他の原料としては、ゲル化剤、安定剤、乳化剤、食物繊維、糖類、甘味料、塩類等が挙げられる。
(Other raw materials)
Other raw materials that can be used in the oil-in-water emulsified oil / fat composition of the present invention include gelling agents, stabilizers, emulsifiers, dietary fibers, sugars, sweeteners, salts and the like.
ゲル化剤や安定剤としては、カラギーナン、キサンタンガム、ローカストビーンガム、ジェランガム、カラヤガム、グアーガム、タマリンドシードガム、カシアガム、トラガントガム、タラガム、HMペクチン、LMペクチン、ファーセルラン、アラビアガム、グルコマンナン、寒天、メチルセルロース、カルボキシメチルセルロース、水溶性大豆多糖類、難消化性デキストリン、アルギン酸、アルギン酸塩等が挙げられる。 Gelling agents and stabilizers include carrageenan, xanthan gum, locust bean gum, gellan gum, karaya gum, guar gum, tamarind seed gum, cassia gum, polysaccharide gum, tara gum, HM pectin, LM pectin, farcellan, arabic gum, glucomannan, agar. , Methyl cellulose, carboxymethyl cellulose, water-soluble soybean polysaccharide, refractory dextrin, alginic acid, alginate and the like.
乳化剤としては、レシチン、酵素処理レシチン等の天然乳化剤、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル等の合成乳化剤が挙げられる。 Examples of the emulsifier include natural emulsifiers such as lecithin and enzyme-treated lecithin, and synthetic emulsifiers such as sucrose fatty acid ester, propylene glycol fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, and polyoxyethylene sorbitan fatty acid ester. Can be mentioned.
糖類としては、ブドウ糖、果糖、乳糖、キシロース等の単糖、ショ糖、麦芽糖、トレハロース、異性化液糖、フラクトオリゴ糖、大豆オリゴ糖、ガラクトオリゴ糖、乳果オリゴ糖、ラフィノース、ラクチュロース、パラチノース等のオリゴ糖、キシリトール、マルチトール、エリスリトール、ソルビトール、ラクチトール、マンニトール、還元水飴等の糖アルコールが挙げられる。 Examples of sugars include monosaccharides such as glucose, fructose, lactose, and xylitol, sucrose, maltose, trehalose, isomerized liquid sugar, fructoligosaccharide, soybean oligosaccharide, galactooligosaccharide, milk fruit oligosaccharide, raffinose, lactulose, and palatinose. Examples thereof include sugar alcohols such as oligosaccharides, xylitol, maltose, erythritol, sorbitol, lactitol, mannitol, and reduced water candy.
甘味料としては、アスパルテーム、スクラロース、ステビア、アセスルファムカリウム、等が挙げられる。 Examples of the sweetener include aspartame, sucralose, stevia, acesulfame potassium, and the like.
(酸)
本発明の水中油型乳化油脂組成物に用いられる酸としては、食用として用いられているものであれば無機酸、有機酸の何れを用いてもよく、例えば、リン酸等の無機酸や、乳酸、クエン酸、リンゴ酸、コハク酸、酢酸、グルコン酸等の有機酸が挙げられる。本発明においては、これらの酸を単独で用いることもでき、又は2種以上を組合せて用いることもできる。また乳酸を用いる場合、乳酸を添加する代わりに、以下のように乳酸菌を原料に添加して乳酸発酵させて乳酸を生成させても良い。また該乳酸発酵と酸の添加を併用することもできる。
(acid)
As the acid used in the oil-in-water emulsified oil / fat composition of the present invention, either an inorganic acid or an organic acid may be used as long as it is used for food, and for example, an inorganic acid such as phosphoric acid or an inorganic acid such as phosphoric acid may be used. Examples thereof include organic acids such as lactic acid, citric acid, malic acid, succinic acid, acetic acid and gluconic acid. In the present invention, these acids can be used alone or in combination of two or more. When lactic acid is used, instead of adding lactic acid, lactic acid bacteria may be added to the raw material and lactic acid fermentation may be carried out to produce lactic acid as described below. Further, the lactic acid fermentation and the addition of acid can be used in combination.
(乳酸発酵)
本発明の水中油型乳化油脂組成物では、酸を含有させる好ましい態様として、上記の通り、少なくとも蛋白質を含む原料の一部又は全部を乳酸発酵させることができる。特に蛋白質を含む原料として本抽出物が乳酸発酵されていることが好ましく、他の蛋白質を含む原料が用いられる場合には、全ての蛋白質を含む原料が乳酸発酵されていることが好ましい。
蛋白質以外の油脂、澱粉や他の原料は、蛋白質を含む原料と共に乳酸発酵されていてもよい。例えば蛋白質と油脂を共に乳酸発酵する場合には、蛋白質と油脂との乳化物を乳酸発酵することができる。
乳酸発酵に使用される乳酸菌は特に限定はされず、通常の発酵乳に使用する一般的な乳酸菌、例えば、ラクトバチルス・ブルガリクス、ストレプコッカス・サーモフィルス、ラクトバチルス・アシドフィルス、ラクトバチルス・ヘルベチカス、ラクトバチルス・ラクチス、ラクトバチルス・プランタラム、ラクトバチルス・サンフランシスコ、ラクトバチルス・パネックス、ラクトバチルス・コモエンシス、ラクトバチルス・カルバタス、ラクトバチルス・ブレビス、ラクトバチルス・ヒルガルディ、ラクトバチルス・カゼイ、ラクトバチルス・ルテリ、ストレプトコッカス・サーモフィルス、ストレプトコッカス・ラクチス、ストレプトコッカス・クレモリス、ストレプトコッカス・ジアセチルラクチス、ロイコノストック・メセンテロイデス、ロイコノストック・クレモリス、ビフィドバクテリム属等の単独または混合物を使用することができる。
(Lactic acid fermentation)
In the oil-in-water emulsified oil / fat composition of the present invention, as described above, at least a part or all of the raw material containing protein can be lactic acid fermented as a preferable embodiment containing an acid. In particular, it is preferable that the present extract is lactic acid fermented as a raw material containing protein, and when a raw material containing other proteins is used, it is preferable that the raw material containing all proteins is lactic acid fermented.
Fats and oils other than protein, starch and other raw materials may be lactic acid fermented together with raw materials containing protein. For example, when both protein and fat are lactic acid fermented, the emulsion of protein and fat can be lactic acid fermented.
The lactic acid bacteria used for lactic acid fermentation are not particularly limited, and general lactic acid bacteria used for ordinary fermented milk, such as Lactobacillus bulgarix, Strepcoccus thermophilus, Lactobacillus acidophilus, and Lactobacillus herveticas. , Lactobacillus lactis, Lactobacillus plantarum, Lactobacillus San Francisco, Lactobacillus Panex, Lactobacillus comoensis, Lactobacillus carbatas, Lactobacillus brevis, Lactobacillus hirugardi, Lactobacillus casei, Lactobacillus Lactobacillus, Streptococcus thermophilus, Streptococcus lactis, Streptococcus cremoris, Streptococcus diacetyllactis, Leuconostock Mecenteroides, Leuconostock Cremoris, Bifidobacterium genus and the like can be used alone or in combination.
酸の添加や乳酸発酵を経ることにより、本発明の酸を含む水中油型乳化油脂組成物のpHは、3.5以上7未満の所望のpHにすることができる。より好ましくは、pH4〜6.5、pH4.5〜6.5又はpH5〜6.5にすることができる。その際、該水中油型乳化油脂組成物には、乳酸発酵物の発酵停止時のpHに寄っては、必要により乳酸やクエン酸等の有機酸、あるいは逆にアルカリ剤を添加し、適宜目的とするpHに調整することができる。 By adding an acid or undergoing lactic acid fermentation, the pH of the oil-in-water emulsified oil / fat composition containing the acid of the present invention can be a desired pH of 3.5 or more and less than 7. More preferably, it can be pH 4 to 6.5, pH 4.5 to 6.5 or pH 5 to 6.5. At that time, depending on the pH of the lactic acid fermented product at the time of stopping fermentation, an organic acid such as lactic acid or citric acid, or conversely an alkaline agent, may be added to the oil-in-water emulsified oil / fat composition as appropriate. The pH can be adjusted to.
(性状)
本発明の水中油型乳化油脂組成物は、その性状が可塑性を有することを特徴とする。
本発明の水中油型乳化油脂組成物は、可塑性を有し、かつ5℃におけるレオメーター測定値による硬さが200〜400g/19.6mm2(直径30mm円形プランジャー、テーブルスピード50mm/分)であるのが好ましい。
かかる硬さを有する可塑性の水中油型乳化油脂組成物は、パン生地へ練り込む際、特に穀粉を水で一定時間混練し、ある程度グルテンが形成された後のタイミングで加える場合に、均一に生地に練り込みやすい物性を有する。
(Characteristics)
The oil-in-water emulsified oil / fat composition of the present invention is characterized in that its properties are plastic.
The oil-in-water emulsified oil / fat composition of the present invention has plasticity and has a hardness of 200 to 400 g / 19.6 mm 2 (diameter 30 mm circular plunger, table speed 50 mm / min) as measured by a rheometer at 5 ° C. Is preferable.
The plastic oil-in-water emulsified oil / fat composition having such hardness is uniformly applied to the dough when kneaded into the bread dough, especially when the flour is kneaded with water for a certain period of time and added at a timing after gluten is formed to some extent. Has physical properties that are easy to knead.
(水中油型乳化油脂組成物の製造)
本発明の水中油型乳化油脂組成物は、例えば全原料を混合、乳化して得た原料液に、酸を添加するか乳酸発酵することにより製造できる。また、例えば蛋白質を含む原料の一部又は全部を混合し、必要により油脂と乳化して得た原料液に酸を添加するか乳酸発酵した後、残りの原料を混合し、必要により油脂と乳化することにより製造できる。酸の添加又は乳酸発酵の前後には、必要により加熱殺菌を行うこともできる。また乳化はホモゲナイザー等により行うことができ、必要により乳化の前に予め撹拌機等により水相と油相を予備乳化させておいてもよい。
(Manufacturing of oil-in-water emulsified oil / fat composition)
The oil-in-water emulsified oil / fat composition of the present invention can be produced, for example, by adding an acid or lactic acid fermentation to a raw material liquid obtained by mixing and emulsifying all raw materials. In addition, for example, a part or all of the raw materials containing protein are mixed, and if necessary, acid is added to the raw material liquid obtained by emulsifying with fats and oils or lactic acid fermentation is performed, and then the remaining raw materials are mixed and emulsified with fats and oils as necessary. Can be manufactured by Before and after the addition of acid or lactic acid fermentation, heat sterilization can be performed if necessary. Further, emulsification can be performed by a homogenizer or the like, and if necessary, the aqueous phase and the oil phase may be pre-emulsified by a stirrer or the like before emulsification.
(パン)
本発明の水中油型乳化油脂組成物をパン生地に均一に練り込むことにより、もっちりとした食感と、歯切れのある食感が両立したパンを得ることができる。
本発明において、パンとは、食パン,クロワッサン,デニッシュペーストリー,フランスパン,チャバタ,フォカッチャ,ナン,ピザ,ベーグル,イングリッシュマフィン,パイ,菓子パン、イーストドーナツ等をいう。
パンの製造法は常法に則ればよく、一般的には、小麦粉、全粒粉、米粉等の穀粉、水、イースト、糖類、食塩、油脂等を主成分とする原料を混練して生地を調製し、所望の形状に成形した後に、オーブン等により焼成したり、フライ等することにより製造される。
パン生地を調製する際に上記原料を加える順番としては、全原料を一緒に配合する直捏法(ストレート法)により生地を調製する方法でも良いし、中種法や湯種法のように、一部の原料から先に種生地を調製後、残りの原料を加えて本生地を調製する方法でも良い。
ここで、本発明の水中油型乳化油脂組成物を配合するタイミングは特に限定されず、他の原料と一緒に配合することができる。特に好ましい態様として、穀粉、水、イースト、糖類、食塩等の油脂以外の原料を先に混練してグルテンを形成させた後、マーガリン等の油脂を加える製法が知られており、その油脂を加えるタイミングで本発明の水中油型乳化油脂組成物を加えることが好ましい。これにより、本発明の食感発現の効果をより強く発揮させることができる。
(Bread)
By uniformly kneading the oil-in-water emulsified oil / fat composition of the present invention into a bread dough, it is possible to obtain a bread having both a chewy texture and a crispy texture.
In the present invention, bread refers to bread, croissants, Danish pastries, French bread, chabata, focaccia, nan, pizza, bagels, English muffins, pies, sweet buns, yeast donuts and the like.
The method for producing bread may be according to a conventional method. Generally, dough is prepared by kneading raw materials mainly composed of flour such as wheat flour, whole grain flour and rice flour, water, yeast, sugars, salt and fats and oils. Then, after forming into a desired shape, it is manufactured by baking in an oven or the like or frying.
The order in which the above ingredients are added when preparing the bread dough may be a method of preparing the dough by a direct kneading method (straight method) in which all the ingredients are mixed together, or a method such as the medium seed method or the hot water roux method. It is also possible to prepare the seed dough first from the raw materials of the portion and then add the remaining raw materials to prepare the main dough.
Here, the timing of blending the oil-in-water emulsified oil / fat composition of the present invention is not particularly limited, and it can be blended together with other raw materials. As a particularly preferable embodiment, a manufacturing method is known in which raw materials other than fats and oils such as flour, water, yeast, sugar and salt are first kneaded to form gluten, and then fats and oils such as margarine are added. It is preferable to add the oil-in-water emulsified oil / fat composition of the present invention at the timing. As a result, the effect of expressing the texture of the present invention can be more strongly exerted.
本発明の水中油型乳化油脂組成物のパン生地への添加量は、特に限定されないが、穀粉に対して蛋白質量として0.05〜3質量%又は0.1〜2質量%が好ましい。 The amount of the oil-in-water emulsified oil / fat composition of the present invention added to the bread dough is not particularly limited, but the protein mass is preferably 0.05 to 3% by mass or 0.1 to 2% by mass with respect to the flour.
以下、実施例等により本発明の実施形態についてさらに具体的に記載する。なお、以下「%」及び「部」は特に断りのない限り「質量%」及び「質量部」を意味するものとする。 Hereinafter, embodiments of the present invention will be described in more detail with reference to Examples and the like. In the following, "%" and "parts" shall mean "mass%" and "parts by mass" unless otherwise specified.
○水中油型乳化油脂組成物の製造
(実施例1)
菜種硬化油20部を60℃に加温し、水20部と低脂肪豆乳「美味投入(R)」(不二製油(株)製)50部を混合して50℃に加温した。そこに糖類5部、デキストリン5部を混合し、50℃で加熱撹拌して予備乳化した後、該予備乳化液を2MPaの圧力にてホモゲナイザーで均質化し、70〜80℃で殺菌後24℃まで冷却した。
次に、該乳化液に対してラクトバチルス・ブルガリカス及びストレプトコッカス・サーモフィラスを混合した乳酸菌スターターを0.01%添加して37〜40℃で約5時間発酵させた。発酵液のpHは4.5であった。
得られた発酵液80部に対して、菜種硬化油10部、加工澱粉5部、増粘安定剤1部、さらに水を加えて100部とし、50℃で撹拌しながらアルカリでpHを5.5に調整後、80〜90℃で加熱撹拌して殺菌し、次いで2MPaの圧力にてホモゲナイザーで均質化し、冷却して本発明の「水中油型乳化油脂組成物P」を得た。該組成物Pは、脂質含量が8%、澱粉含量が5%、蛋白質含量が2%、水分含量が57%であり、性状は可塑性であり、5℃におけるレオメーター測定値による硬さが280g/19.6mm2(直径30mm円形プランジャー、テーブルスピード50mm/分)である、
なお、本実施例で用いた低脂肪豆乳は、NSIが20〜77の範囲となるように加熱処理された全脂大豆からの抽出物であり、特開2012-16348号公報に記載される方法で製造されている。本製品の固形分9.7%、脂質含量(固形分中)5.0%、蛋白質含量54.6%(固形分中)、炭水化物含量34.1%(固形分中)であり、P/C含量が160%である。
○ Production of oil-in-water emulsified oil / fat composition (Example 1)
20 parts of hydrogenated rapeseed oil was heated to 60 ° C., 20 parts of water and 50 parts of low-fat soymilk "Delicious Input (R) " (manufactured by Fuji Oil Co., Ltd.) were mixed and heated to 50 ° C. After mixing 5 parts of sugar and 5 parts of dextrin and heating and stirring at 50 ° C to pre-emulsify, the pre-emulsified solution is homogenized with a homogenizer at a pressure of 2 MPa, sterilized at 70 to 80 ° C, and then up to 24 ° C. Cooled.
Next, 0.01% of a lactic acid bacterium starter, which was a mixture of Lactobacillus bulgaricus and Streptococcus thermophilus, was added to the emulsion and fermented at 37-40 ° C. for about 5 hours. The pH of the fermented liquor was 4.5.
To 80 parts of the obtained fermented liquid, add 10 parts of hydrogenated rapeseed oil, 5 parts of modified starch, 1 part of thickening stabilizer, and water to make 100 parts, and adjust the pH with alkali while stirring at 50 ° C. After adjusting to 5, the mixture was sterilized by heating and stirring at 80 to 90 ° C., homogenized with a homogenizer at a pressure of 2 MPa, and cooled to obtain the "oil-in-water emulsified oil / fat composition P" of the present invention. The composition P has a lipid content of 8%, a starch content of 5%, a protein content of 2%, a water content of 57%, a plastic property, and a hardness as measured by a rheometer at 5 ° C. of 280 g. / 19.6 mm 2 (30 mm diameter circular plunger, table speed 50 mm / min),
The low-fat soymilk used in this example is an extract from full-fat soybean that has been heat-treated so that the NSI is in the range of 20 to 77, and is a method described in JP-A-2012-16348. Manufactured in. The solid content of this product is 9.7%, lipid content (in solid content) 5.0%, protein content 54.6% (in solid content), carbohydrate content 34.1% (in solid content), and P / The C content is 160%.
(比較例1)
実施例1で使用した低脂肪豆乳に代えて、市販の低脂肪牛乳を使用した以外は、実施例1の配合及び製法と同様にして、比較例の「水中油型乳化油脂組成物C1」を得た。
なお、本比較例で用いた低脂肪牛乳は、固形分11.2%、脂質含量8.9%(固形分中)、蛋白質含量33.9%(固形分中)、炭水化物含量49.1%(固形分中)であり、P/C含量が69.1%である。
(Comparative Example 1)
The "oil-in-water emulsified oil / fat composition C1" of Comparative Example was used in the same manner as in the formulation and manufacturing method of Example 1 except that commercially available low-fat milk was used instead of the low-fat soymilk used in Example 1. Obtained.
The low-fat milk used in this comparative example has a solid content of 11.2%, a lipid content of 8.9% (in the solid content), a protein content of 33.9% (in the solid content), and a carbohydrate content of 49.1%. (In solid content) and has a P / C content of 69.1%.
(比較例2)
実施例1で使用した低脂肪豆乳に代えて、全脂豆乳「無調整豆乳」(不二製油(株)製)を使用した以外は、実施例1の配合及び製法と同様にして、比較例の「水中油型乳化油脂組成物C2」を得た。
なお、本比較例で用いた全脂豆乳は、全脂大豆からの抽出物であり、固形分9.7%、脂質含量38.0%(固形分中)、蛋白質含量48.5%(固形分中)、炭水化物含量17.2%(固形分中)であり、P/C含量が281%である。
(Comparative Example 2)
Comparative Example in the same manner as in the formulation and manufacturing method of Example 1 except that the full-fat soymilk "unadjusted soymilk" (manufactured by Fuji Oil Co., Ltd.) was used instead of the low-fat soymilk used in Example 1. "Oil-in-water emulsified oil / fat composition C2" was obtained.
The full-fat soymilk used in this comparative example is an extract from full-fat soybean, and has a solid content of 9.7%, a lipid content of 38.0% (in the solid content), and a protein content of 48.5% (solid). It has a carbohydrate content of 17.2% (in solids) and a P / C content of 281%.
(比較例3)
実施例1で使用した低脂肪豆乳に代えて、脱脂豆乳粉末「ソヤフィット2000」(不二製油(株)製)を使用した以外は、実施例1の配合及び製法と同様にして、比較例の「水中油型乳化油脂組成物C3」を得た。
なお、本比較例で用いた脱脂豆乳粉末は、脱脂大豆からの抽出物であり、固形分94.9%、脂質含量0.1%(固形分中)、蛋白質含量66.2%(固形分中)、炭水化物含量29.3%(固形分中)であり、P/C含量が226%である。
(Comparative Example 3)
In the same manner as in the formulation and manufacturing method of Example 1, a comparative example was used except that the defatted soymilk powder "Soyafit 2000" (manufactured by Fuji Oil Co., Ltd.) was used instead of the low-fat soymilk used in Example 1. "Oil-in-water emulsified oil / fat composition C3" was obtained.
The defatted soymilk powder used in this comparative example is an extract from defatted soybean, and has a solid content of 94.9%, a lipid content of 0.1% (in the solid content), and a protein content of 66.2% (solid content). Medium), the carbohydrate content is 29.3% (in the solid content), and the P / C content is 226%.
(比較例4)
実施例1で使用した澱粉を無添加とし、その減量分だけ油脂を増量した以外は、実施例1の配合及び製法と同様にして、比較例の「水中油型乳化油脂組成物C4」を得た。
(Comparative Example 4)
The "oil-in-water emulsified oil / fat composition C4" of Comparative Example was obtained in the same manner as in the formulation and manufacturing method of Example 1 except that the starch used in Example 1 was not added and the amount of oil / fat was increased by the amount of the decrease. rice field.
(比較例5)
実施例1で行っている乳酸発酵の工程を省略し、pH調整も行わない以外は、実施例1の配合及び製法と同様にして、比較例の「水中油型乳化油脂組成物C5」を得た。
(Comparative Example 5)
The "oil-in-water emulsified oil / fat composition C5" of Comparative Example was obtained in the same manner as in the formulation and manufacturing method of Example 1 except that the step of lactic acid fermentation performed in Example 1 was omitted and the pH was not adjusted. rice field.
(実施例2)
実施例1で使用したデキストリンに代えて、分離大豆蛋白「フジプロCL」(不二製油(株)製)を使用した以外は、実施例1の配合及び製法と同様にして、本発明の「水中油型乳化油脂組成物Q」を得た。該組成物Qの蛋白質含量は組成物Pの約2倍となった。
(Example 2)
In the same manner as in the formulation and manufacturing method of Example 1, the "water" of the present invention was used except that the isolated soybean protein "Fujipro CL" (manufactured by Fuji Oil Co., Ltd.) was used instead of the dextrin used in Example 1. An oil-type emulsified oil / fat composition Q ”was obtained. The protein content of the composition Q was about twice that of the composition P.
実施例1,2および比較例1〜4で得られた水中油型乳化油脂組成物P,Q,C1〜C5の組成及び物性を表1にまとめた。 Table 1 summarizes the compositions and physical properties of the oil-in-water emulsified oil / fat compositions P, Q, C1 to C5 obtained in Examples 1 and 2 and Comparative Examples 1 to 4.
(表1)
(Table 1)
以上の通り、澱粉を配合していない組成物C4の性状が、離水が多く硬さもやわらかく、パン生地に練り込みにくい物性であり、好ましくなかった。組成物C4以外の組成物はいずれも性状は可塑性を有する適度な硬さを有しており、良好であった。 As described above, the properties of the composition C4 containing no starch are not preferable because they have a large amount of water separation, are soft in hardness, and are difficult to knead into bread dough. All the compositions other than the composition C4 had an appropriate hardness having plasticity in properties and were good.
(試験例1)パンへの添加試験(各種水中油型乳化油脂組成物の品質評価)
実施例1,2及び比較例1〜5により得られた各水中油型乳化油脂組成物P,Q,C1〜C5を食パン生地に練り込み、パンを製造し、これらの品質評価を行った。
(Test Example 1) Addition test to bread (quality evaluation of various oil-in-water emulsified oil and fat compositions)
The oil-in-water emulsified oil and fat compositions P, Q, C1 to C5 obtained in Examples 1 and 2 and Comparative Examples 1 to 5 were kneaded into bread dough to produce bread, and the quality of these was evaluated.
○対照区
強力粉100部、上白糖6部、食塩2部、脱脂粉乳2部、イースト3部、イーストフード0.1部及び水68部をミキサーボウルに投入し、フックを使用し、低速で4分、中速で3分ミキシングした。ここで、練り込み油脂(水分含量15%、油分含量82%のマーガリン)5部を投入し、フックを使用し、低速で3分、中速で3分、高速で2分ミキシングを行ない、食パン生地を得た。得られた食パン生地の捏ね上げ温度は26℃であった。
ここで、発酵室(温度29℃、湿度70%)でフロアタイムを60分とった後、220gに分割し丸めを行った。
次いで、ベンチタイムを20分とった後、モルダー成形し、U字型に入れ、38℃、相対湿度80%で50分ホイロをとった後、焼成温度を上火230℃/下火200℃に設定した固定窯に入れ、40分焼成して食パンを得た。
○ Control group Put 100 parts of strong flour, 6 parts of white sugar, 2 parts of salt, 2 parts of skim milk powder, 3 parts of yeast, 0.1 part of yeast food and 68 parts of water into a mixer bowl, and use a hook to slow down 4 parts. Mixing for 3 minutes at medium speed. Here, add 5 parts of kneaded fat (margarine with a water content of 15% and an oil content of 82%), mix at low speed for 3 minutes, medium speed for 3 minutes, and high speed for 2 minutes using a hook, and eat. I got the bread dough. The kneading temperature of the obtained bread dough was 26 ° C.
Here, after setting the floor time to 60 minutes in the fermentation chamber (temperature 29 ° C., humidity 70%), the mixture was divided into 220 g and rounded.
Next, after setting the bench time to 20 minutes, moulder molding is performed, the mixture is placed in a U shape, and the proof is taken at 38 ° C. and a relative humidity of 80% for 50 minutes. It was placed in a fixed kiln and baked for 40 minutes to obtain bread.
○試験区P,Q,C1〜C5
対照区にて配合している練り込み油脂5部の代わりに、水中油型乳化油脂組成物P,Q,C1〜C5のうち1つを30部配合する以外は、対照区の配合及び製法と同様にして、食パンを得た。各試験区をそれぞれ試験区P,Q,C1〜C5とした。なお、生地作製の際、ミキシング時の各水中油型乳化油脂組成物の練り込み易さを確認した。
○ Test plots P, Q, C1 to C5
With the exception of 30 parts of one of the oil-in-water emulsified oil and fat compositions P, Q, C1 to C5, instead of 5 parts of the kneaded oil and fat blended in the control group, the formulation and manufacturing method of the control group Similarly, bread was obtained. Each test group was designated as test group P, Q, C1 to C5, respectively. When preparing the dough, it was confirmed that each oil-in-water emulsified oil / fat composition was easily kneaded during mixing.
得られた食パンを20℃で保管し、保管開始から2日後の食感(もっちり感及び歯切れ)について、下記評価基準に従って5段階で評価を行った。 The obtained bread was stored at 20 ° C., and the texture (tightness and crispness) 2 days after the start of storage was evaluated on a 5-point scale according to the following evaluation criteria.
○官能評価(n=20)
対照区及び各試験区で調製した食パンを20名のパネラーに試食してもらい、食感(もっちり感と歯切れ)について、下記評価基準により官能評価を実施し、採点をしてもらった。
○ Sensory evaluation (n = 20)
Twenty panelists tasted the bread prepared in the control group and each test group, and the texture (tightness and crispness) was sensory evaluated according to the following evaluation criteria and scored.
(評価基準)
・食感(もっちり感)
5点:非常に良好(もっちり感が強く感じられる)
4点:良好
3点:許容できる
2点:やや不良(もっちり感が弱い)
1点:不良(もっちり感がない、又はもっちり感とは異なる)
・食感(歯切れ)
5点:非常に良好
4点:良好
3点:許容できる
2点:やや不良(ややねちゃつく)
1点:不良(ねちゃつきが多い)
(Evaluation criteria)
・ Texture (chewy)
5 points: Very good (feels strong)
4 points: Good 3 points: Acceptable 2 points: Slightly poor (weak feeling of stickiness)
1 point: Defective (not chewy or different from chewy)
・ Texture (crisp)
5 points: Very good 4 points: Good 3 points: Acceptable 2 points: Slightly defective (slightly messy)
1 point: Defective (many sticky)
各パネラーの評点の平均値を求めた。そして平均値より、
A:4.5点以上
B:3.5点以上4.5点未満
C:2.5点以上3.5点未満
D:1.5点以上2.5点未満
E:1.5点未満
の5段階で評価付けを行い、もっちり感と歯切れがどちらもC評価以上のものを合格品質とした。結果を表2に示した。
The average score of each panelist was calculated. And from the average value
A: 4.5 points or more B: 3.5 points or more and less than 4.5 points C: 2.5 points or more and less than 3.5 points D: 1.5 points or more and less than 2.5 points E: less than 1.5 points The quality was evaluated on a scale of 5 and the quality was judged to be C rating or higher for both firmness and crispness. The results are shown in Table 2.
(表2)官能評価結果
(Table 2) Sensory evaluation results
以上の通り、低脂肪豆乳を用いた組成物P,Qをパン生地に練り込むことにより、いずれももっちり感と歯切れの両立したパンが得られた。試験区C1〜C3のように水中油型乳化油脂組成物に低脂肪豆乳を用いない場合、試験区C4のように水中油型乳化油脂組成物に澱粉を配合しない場合、試験区C5のように水中油型乳化油脂組成物が乳酸発酵を経ていない場合、いずれも目的とする品質のパンが得られなかった。また、試験区C4では組成物C4を生地に練り込む際、離水が多かったため、均一に練り込むのに時間を要し、練り込み性が非常に悪かった。 As described above, by kneading the compositions P and Q using low-fat soymilk into the bread dough, bread having both a firm feeling and crispness was obtained. When low-fat soymilk is not used in the oil-in-water emulsified oil / fat composition as in test groups C1 to C3, when starch is not mixed in the oil-in-water emulsified oil / fat composition as in test group C4, as in test group C5. When the oil-in-water emulsified fat composition had not undergone lactic acid fermentation, bread of the desired quality could not be obtained. Further, in the test group C4, when the composition C4 was kneaded into the dough, a large amount of water was separated, so that it took time to knead the composition uniformly, and the kneading property was very poor.
(試験例2)パンへの添加試験2(本発明の水中油型乳化油脂組成物の配合量の変更)
○試験区P2〜P5
試験区Pにて配合している本発明の水中油型乳化油脂組成物Pの配合量を30部から5部(試験区P2)、10部(試験区P3)、20部(試験区P4)、50部(試験区P5)に変更し、それ以外は試験区Pの配合及び製法と同様にして、食パンを得た。
(Test Example 2) Addition test to bread 2 (Change in blending amount of oil-in-water emulsified oil / fat composition of the present invention)
○ Test plots P2 to P5
The amount of the oil-in-water emulsified oil / fat composition P of the present invention compounded in the test group P is 30 to 5 parts (test group P2), 10 parts (test group P3), 20 parts (test group P4). , 50 parts (test group P5), and other than that, bread was obtained in the same manner as the formulation and manufacturing method of test group P.
得られた各食パンを20℃で保管し、保管開始から2日後の食感(もっちり感及び歯切れ)について、試験例1と同じ評価基準に従って官能評価を行い、A〜Eの5段階で評価付けを行った。結果を対照区、試験区Pと比較して表3に示した。 Each of the obtained breads is stored at 20 ° C., and the texture (tightness and crispness) 2 days after the start of storage is sensory evaluated according to the same evaluation criteria as in Test Example 1, and evaluated on a scale of 5 from A to E. I attached it. The results are shown in Table 3 in comparison with the control group and the test group P.
(表3)
(Table 3)
(実施例3)
実施例1において、発酵液に油脂等を混合した後のpH調整を行わず、発酵液のpHを4.5のままとする以外は、実施例1の配合及び製法と同様にして、本発明の水中油型乳化油脂組成物Rを得た。該組成物Rの性状は可塑性であり、硬さが220g/19.6mm2であった。
(Example 3)
In Example 1, the present invention is the same as the formulation and manufacturing method of Example 1 except that the pH of the fermented liquid is not adjusted after mixing the fermented liquid with oil and fat and the pH of the fermented liquid is kept at 4.5. The oil-in-water emulsified oil / fat composition R of the above was obtained. The composition R had a plastic property and a hardness of 220 g / 19.6 mm 2 .
(実施例4)
実施例1において、発酵液に油脂等を混合した後に調整するpHを5.5から6.5に変更する以外は、実施例1の配合及び製法と同様にして、本発明の水中油型乳化油脂組成物Sを得た。該組成物Sの性状は可塑性であり、硬さが300g/19.6mm2であった。
(Example 4)
In Example 1, the oil-in-water emulsification of the present invention is carried out in the same manner as in the formulation and manufacturing method of Example 1 except that the pH adjusted after mixing the fermented liquid with oil and fat is changed from 5.5 to 6.5. An oil / fat composition S was obtained. The composition S had a plastic property and a hardness of 300 g / 19.6 mm 2 .
(試験例3)パンへの添加試験3(本発明の水中油型乳化油脂組成物のpHの変更)
○試験区R,S
試験区Pにて配合している水中油型乳化油脂組成物Pの代わりに、実施例3,4で得られた水中油型乳化油脂組成物R,Sのうち1つを配合する以外は、試験区Pの配合及び製法と同様にして、食パンを得た。
(Test Example 3) Addition test to bread 3 (Change in pH of oil-in-water emulsified oil / fat composition of the present invention)
○ Test plots R, S
Except for blending one of the oil-in-water emulsified fat compositions R and S obtained in Examples 3 and 4 in place of the oil-in-water emulsified fat composition P blended in the test group P. Bread was obtained in the same manner as in the formulation and manufacturing method of Test Group P.
得られた各食パンを20℃で保管し、保管開始から2日後の食感(もっちり感及び歯切れ)について、試験例1と同じ評価基準に従って官能評価を行い、A〜Eの5段階で評価付けを行った。結果を対照区、試験区Pと比較して表4に示した。 Each of the obtained breads is stored at 20 ° C., and the texture (tightness and crispness) 2 days after the start of storage is sensory evaluated according to the same evaluation criteria as in Test Example 1, and evaluated on a scale of 5 from A to E. I attached it. The results are shown in Table 4 in comparison with the control group and the test group P.
(表4)
(Table 4)
以上の通り、本発明の練り込み用水中油型乳化油脂組成物は、乳酸発酵工程を必須とするが、そのpHは4.5よりも高いことが望ましいことが示された。 As described above, it was shown that the oil-in-water emulsified oil / fat composition for kneading of the present invention requires a lactic acid fermentation step, but its pH is preferably higher than 4.5.
(試験例4)パンへの添加試験4(本発明の水中油型乳化油脂組成物のパン生地への添加タイミングの変更)
○試験区P6
試験区Pで使用する原材料(本発明の水中油型乳化油脂組成物Pを含む)を全てミキサーボウルに投入し、フックを使用し、低速で3分、中速で3分、高速で2分ミキシングを行ない、食パン生地を得た。得られた食パン生地の捏ね上げ温度は26℃であった。これ以降は試験区Pと同様にして、オールイン配合による食パンを得た。
(Test Example 4) Addition test to bread 4 (Change in timing of addition of the oil-in-water emulsified oil / fat composition of the present invention to bread dough)
○ Test area P6
All the raw materials used in the test group P (including the oil-in-water emulsified oil / fat composition P of the present invention) are put into a mixer bowl, and a hook is used for 3 minutes at low speed, 3 minutes at medium speed, and 2 minutes at high speed. Mixing was performed to obtain bread dough. The kneading temperature of the obtained bread dough was 26 ° C. From this point onward, bread with an all-in formulation was obtained in the same manner as in Test Group P.
得られた各食パンを20℃で保管し、保管開始から2日後の食感(もっちり感及び歯切れ)について、試験例1と同じ評価基準に従って官能評価を行い、A〜Eの5段階で評価付けを行った。結果を対照区、試験区Pと比較して表5に示した。 Each of the obtained breads is stored at 20 ° C., and the texture (tightness and crispness) 2 days after the start of storage is sensory evaluated according to the same evaluation criteria as in Test Example 1, and evaluated on a scale of 5 from A to E. I attached it. The results are shown in Table 5 in comparison with the control group and the test group P.
(表5)
(Table 5)
以上の通り、本発明の練り込み用水中油型乳化油脂組成物は、小麦粉等の他の原料と同時期に配合するオールイン配合でパン生地を調製するよりも、小麦粉生地を作成した後、マーガリンを配合するのと同じ後添加による方が望ましいことが示された。 As described above, the oil-in-water emulsified oil / fat composition for kneading of the present invention is used to prepare a flour dough and then margarine, rather than preparing a bread dough with an all-in formulation that is blended at the same time as other raw materials such as wheat flour. It was shown that it is preferable to use the same post-addition as the compounding.
(実施例6) −乳酸発酵から乳酸添加への変更−
実施例1において、調製した予備乳化液を乳酸発酵する代わりに、乳酸を添加して該予備乳化液のpHを5.5に調整する以外は、実施例1と同様にして、本発明の「水中油型乳化油脂組成物T」を得た。該組成物Tの性状は可塑性であり、硬さが320g/19.6mm2であった。
また、該組成物Tを試験例1と同様にして食パン生地に練り込み、パンを製造した。得られた食パンを20℃で保管し、保管開始から2日後の食感(もっちり感及び歯切れ)について、試験例1と同じ評価基準に従って官能評価を行い、これらの品質評価を行った。
その結果、もっちり感の評価はB、歯切れの評価はBであった。
なお、乳酸の代わりにクエン酸を添加して同様に得た水中油型乳化油脂組成物Uを得た場合も、もっちり感と歯切れの評価は同様であった。
(Example 6) -Change from lactic acid fermentation to lactic acid addition-
In Example 1, instead of lactic acid fermentation of the prepared preliminary emulsion, lactic acid is added to adjust the pH of the preliminary emulsion to 5.5, but in the same manner as in Example 1, the present invention ". An oil-in-water emulsified oil / fat composition T ”was obtained. The composition T had a plastic property and a hardness of 320 g / 19.6 mm 2 .
Further, the composition T was kneaded into the bread dough in the same manner as in Test Example 1 to produce bread. The obtained bread was stored at 20 ° C., and the texture (tightness and crispness) 2 days after the start of storage was subjected to sensory evaluation according to the same evaluation criteria as in Test Example 1, and these quality evaluations were performed.
As a result, the evaluation of the firmness was B, and the evaluation of the crispness was B.
In addition, when citric acid was added instead of lactic acid to obtain the oil-in-water emulsified oil / fat composition U obtained in the same manner, the evaluation of firmness and crispness was the same.
Claims (6)
A)蛋白質含有素材として、全脂大豆からの水抽出物であって、炭水化物に対する蛋白質の重量比が100〜200質量%である大豆抽出物を含むこと、
B)酸を含むこと、
C)性状が可塑性を有すること An oil-in-water emulsified oil / fat composition for kneading bread dough, which contains 7 to 40% by mass of fat and oil, 2 to 15% by mass of starch, 2 to 10% by mass of protein, and has the characteristics of A) to C) below.
A) The protein-containing material contains a soybean extract which is a water extract from full-fat soybean and has a weight ratio of protein to carbohydrate of 100 to 200% by mass.
B) Contains acid,
C) The properties are plastic
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