JP6683440B2 - Oily solid makeup cosmetics - Google Patents
Oily solid makeup cosmetics Download PDFInfo
- Publication number
- JP6683440B2 JP6683440B2 JP2015174587A JP2015174587A JP6683440B2 JP 6683440 B2 JP6683440 B2 JP 6683440B2 JP 2015174587 A JP2015174587 A JP 2015174587A JP 2015174587 A JP2015174587 A JP 2015174587A JP 6683440 B2 JP6683440 B2 JP 6683440B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- oily solid
- secondary adhesion
- less effect
- dimethicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002537 cosmetic Substances 0.000 title claims description 47
- 239000007787 solid Substances 0.000 title claims description 46
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 49
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 49
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 49
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 48
- 239000000843 powder Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 26
- 229920001296 polysiloxane Polymers 0.000 claims description 26
- 239000000377 silicon dioxide Substances 0.000 claims description 22
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- 229940008099 dimethicone Drugs 0.000 description 30
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- 230000014759 maintenance of location Effects 0.000 description 16
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- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- AVYKQOAMZCAHRG-UHFFFAOYSA-N triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F AVYKQOAMZCAHRG-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- RKPOLXDFMLKRHE-UHFFFAOYSA-N tritridecyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCCCCCCC)C(C(=O)OCCCCCCCCCCCCC)=C1 RKPOLXDFMLKRHE-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Description
本発明は油性固形メークアップ化粧料に関し、特に二次付着レス効果とその持続性に優れ、安定性も良好な油性固形メークアップ化粧料に関するものである。 TECHNICAL FIELD The present invention relates to an oily solid make-up cosmetic composition, and more particularly to an oily solid make-up cosmetic composition which is excellent in secondary adhesion-less effect and its durability and has good stability.
近年、口紅等の油性固形メークアップ化粧料においては、経時による色もち及びツヤもちのよさに加え、口唇に塗布した口紅が衣服やカップに色移りしにくい二次付着レス効果も重要な品質として求められている。特に、口紅等の発色の高い油性固形メークアップ化粧料においては、色移りが目立ちやすいことから、優れた二次付着レス効果が求められ、これまでにも、経時による色もちやツヤもちのよさや二次付着レス効果を具現化する様々な検討がなされている。例えば、メチルフェニルシリコーンと特定のイソステアリン酸ポリグリセリル、ワックスを組み合わせて二次付着レス効果、ツヤの持続性を向上させる技術（特許文献１）、フェニル変性シリコーン、多分岐型イソステアリン酸エステル、ワックスを組み合わせ、耐色移り性及び化粧効果の持続性を向上させる技術（特許文献２）等がある。 In recent years, in oily solid make-up cosmetics such as lipsticks, in addition to the goodness of color and luster over time, the secondary adhesion-less effect in which lipstick applied to the lips does not easily transfer color to clothes or cups is also an important quality. It has been demanded. In particular, oily solid make-up cosmetics with high color development such as lipsticks are required to have an excellent secondary adhesion-less effect because the color transfer is easily noticeable. Various studies have been made to realize the secondary adhesionless effect. For example, a technique of combining methylphenylsilicone with a specific polyglyceryl isostearate and a wax to improve the secondary adhesion-less effect and the durability of gloss (Patent Document 1), a phenyl-modified silicone, a hyperbranched isostearate ester, and a wax are combined. , A technique for improving the color transfer resistance and the durability of the cosmetic effect (Patent Document 2).
しかしながら、特許文献１や特許文献２の技術では、塗布後にシリコーン相が分離することにより二次付着レス効果を出しているが、二次付着レス効果や、経時での二次付着レス効果、色持ちの持続が十分とはいえなかった。これらの技術は、フェニル変性シリコーンと、油性化粧料に広く用いられる炭化水素油やエステル油と相溶性が低い組合せの性質を用いたものであるが、二次付着レス効果は得られるものの、不均一になりやすく、みずみずしいつや、美しい均一な仕上がりが得られにくく、安定性を保つのに困難な傾向がある。一方、相溶性が良い組み合わせを用いた場合は、安定性や化粧膜の均一性には優れるが、二次付着レス効果、その持続性、効果発現の速さに満足がいかない傾向が見られる。 However, in the techniques of Patent Document 1 and Patent Document 2, although the secondary adhesion-less effect is obtained by separating the silicone phase after coating, the secondary adhesion-less effect, the secondary adhesion-less effect over time, and the color I couldn't say that I had enough. These techniques use the property of a combination having low compatibility with phenyl-modified silicone and hydrocarbon oils and ester oils widely used in oily cosmetics. It tends to be uniform, it is difficult to obtain a fresh and even finish, and it tends to be difficult to maintain stability. On the other hand, when a combination having good compatibility is used, the stability and the uniformity of the cosmetic film are excellent, but there is a tendency that the secondary adhesion-less effect, its sustainability, and the speed of effect expression are not satisfactory.
このため、均一で美しい仕上がりに加え、更に色持ちが良く、みずみずしいツヤの持続性が高く、特に二次付着レス効果とその発現の速さにも優れる油性固形メークアップ化粧料の開発が望まれている。 Therefore, in addition to a uniform and beautiful finish, it is desired to develop an oily solid make-up cosmetic which has a good color retention and a long-lasting lustrous gloss, and which is particularly excellent in the secondary adhesion-less effect and the speed of its development. ing.
本発明者らは鋭意検討の結果、３０℃で３相に分離するフェニル変性シリコーン、ジメチルポリシロキサン及び炭化水素油やエステル油を組み合わせ、煙霧状粉体とワックスにより安定な油性固型化粧料が得られ、塗布直後から最表層に相分離したジメチルポリシロキサンが直ちに色移りを抑制した二次付着レス効果を発現すると共に、みずみずしいツヤを発揮し、更にフェニル変性シリコーンと、着色剤を抱えた油相が層になることにより優れた二次付着レス効果が持続するため、みずみずしいツヤと均一で美しい仕上がりを有することに加え、特に二次付着レス効果とその持続性に優れ、色持ちがよく、ツヤの持続性が高く、安定性も良好な油性固形メークアップ化粧料を完成させた。 As a result of diligent studies, the present inventors have combined phenyl-modified silicone, dimethylpolysiloxane, and hydrocarbon oil or ester oil that separate into three phases at 30 ° C., and obtained a stable oily solid cosmetic composition by using fumed powder and wax. The dimethylpolysiloxane phase-separated into the outermost layer immediately after coating immediately exhibits a secondary adhesion-less effect that suppresses color transfer, and also exhibits a fresh luster, and an oil containing a phenyl-modified silicone and a colorant. Since the excellent secondary adhesion-less effect lasts because the phase becomes a layer, in addition to having a fresh gloss and a uniform and beautiful finish, it is particularly excellent in the secondary adhesion-less effect and its durability, and has good color retention. We have completed an oily solid make-up cosmetic with high luster and stability.
すなわち、本発明は、以下の成分（Ａ）（Ｂ）（Ｃ）（Ｄ）（Ｅ）及び（Ｆ）；
（Ａ）フェニル変性シリコーン
（Ｂ）ジメチルポリシロキサン
（Ｃ）煙霧状粉体
（Ｄ）炭化水素油およびエステル油から選ばれる１種または２種以上の油剤
（Ｅ）ワックス
（Ｆ）着色剤；
を含有する油性固形メークアップ化粧料であって、成分（Ａ）及び（Ｂ）を化粧料中に合計で３５〜７５質量％含有し、成分（Ａ）、（Ｂ）及び（Ｄ）の混合物が３０℃で３相に分離する油性固形メークアップ化粧料である。
That is, the present invention provides the following components (A) (B) (C) (D) (E) and (F);
(A) Phenyl-modified silicone (B) Dimethylpolysiloxane (C) Fume-like powder (D) One or more oil agents (E) Wax (F) Colorant selected from hydrocarbon oil and ester oil;
A mixture of components (A), (B) and (D), which is an oily solid makeup cosmetic containing the components (A) and (B) in a total amount of 35 to 75% by mass. Is an oily solid makeup cosmetic that separates into three phases at 30 ° C.
本発明は油性メークアップ化粧料に関し、更に詳細には、みずみずしいツヤと均一で美しい仕上がりを有することに加え、特に二次付着レス効果とその持続性に優れ、色持ちがよく、ツヤの持続性が高く、安定性も良好な油性固形メークアップ化粧料に関するものである。 The present invention relates to an oily makeup cosmetic product, and more specifically, in addition to having a fresh luster and a uniform and beautiful finish, it is particularly excellent in the secondary adhesion-less effect and its sustainability, has good color retention, and has long-lasting luster. The present invention relates to an oily solid make-up cosmetic having high stability and good stability.
以下、本発明を詳細に説明する。
本発明の油性固型メークアップ化粧料は、３０℃で３相に分離するフェニル変性シリコーン、ジメチルポリシロキサンや炭化水素油やエステル油を用いることで、塗布直後にみずみずしいツヤの発揮と二次付着レス効果を発現する層が表出し、その後に着色剤を抱えた炭化水素油やエステル油とが層となることで、フェニル変性シリコーン層による二次付着レス効果が持続することができる。
Hereinafter, the present invention will be described in detail.
The oily solid makeup cosmetic of the present invention uses phenyl-modified silicone, dimethylpolysiloxane, hydrocarbon oil or ester oil that separates into three phases at 30 ° C., so that a fresh gloss and secondary adhesion immediately after application are obtained. A layer exhibiting a lacquer effect is exposed, and then a hydrocarbon oil or an ester oil carrying a colorant becomes a layer, whereby the secondary adhesion-less effect by the phenyl-modified silicone layer can be maintained.
尚、本発明において“３相に分離する”とは以下の条件で確認した場合の状態を指す。
〔確認条件〕
成分（Ａ）、（Ｂ）及び（Ｄ）の質量比１：１：１混合物が、それぞれ３０℃の状態で攪拌混合し、この混合物を３０℃で静置した時に２つの境界が見られ、３相に分離しているものを“分離する”とした。
一方、境界が１つも見られない１相、または境界が１つのみ見られる２相である状態を“分離せず”とした。
In the present invention, “separate into three phases” refers to the state when confirmed under the following conditions.
[Confirmation conditions]
A 1: 1: 1 mass ratio mixture of components (A), (B) and (D) was stirred and mixed at 30 ° C., respectively, and when this mixture was allowed to stand at 30 ° C., two boundaries were observed, Those separated into three phases were designated as "separated".
On the other hand, a state in which there is one boundary without any boundary or two phases with only one boundary is defined as “not separated”.
本発明における成分（Ａ）フェニル変性シリコーンは、３０℃で成分（Ｂ）や（Ｄ）と相溶せず、塗布後に肌上で層を作り、二次付着レス効果とその持続性、ツヤの持続性を発揮することができる。成分（Ａ）としては、ジメチルポリシロキサン骨格とフェニル基を有しているものであれば特に限定されないが、具体的にはトリメチルシロキシフェニルジメチコン、トリメチルペンタフェニルトリシロキサン、ジフェニルジメチコン、フェニルトリメチコン、ジフェニルシロキシフェニルトリメチコン等が挙げられ、これらの１種または２種以上を混合して用いることができる。成分（Ａ）は二次付着レス効果の持続性の点から、３０℃で液状であり、粘度が３００〜１０００ｍＰａ・ｓであるものが好ましく、３００〜８００ｍＰａ・ｓのものが更に好ましい。中でも９００ｍＰａ・ｓ以上のものと５００ｍＰａ・ｓ以下のものの混合物が好ましい。 The component (A) phenyl-modified silicone in the present invention is incompatible with the components (B) and (D) at 30 ° C., and forms a layer on the skin after application, and has a secondary adhesion-less effect and its sustainability and gloss. It can exhibit sustainability. The component (A) is not particularly limited as long as it has a dimethylpolysiloxane skeleton and a phenyl group, and specifically, trimethylsiloxyphenyldimethicone, trimethylpentaphenyltrisiloxane, diphenyldimethicone, phenyltrimethicone, Examples thereof include diphenylsiloxyphenyltrimethicone, and these can be used alone or in combination of two or more. The component (A) is preferably liquid at 30 ° C. and has a viscosity of 300 to 1000 mPa · s, more preferably 300 to 800 mPa · s, from the viewpoint of the durability of the secondary adhesion-less effect. Above all, a mixture of 900 mPa · s or more and 500 mPa · s or less is preferable.
成分（Ａ）の市販品としては、例えばＰＤＭ２０、ＰＤＭ３５０ＶＰ、ＰＤＭ１０００（以上、旭化成ワッカー社製）、ＫＦ−５０−１００ｃｓ／１０００ｃｓ、ＫＦ−５３、ＫＦ−５４、ＫＦ−５６Ａ、ＫＦ−５４ＨＶ、（以上、信越化学工業社製）、ＳＨ−５５６ Ｆｌｕｉｄ、ＰＨ−１５５５ ＨＲＩ Ｃｏｓｍｅｔｉｃ Ｆｌｕｉｄ、ＦＺ−３１５６（以上東レ・ダウコ−ニング社製）等が挙げられる。 Examples of commercially available products of component (A) include PDM20, PDM350VP, PDM1000 (all manufactured by Asahi Kasei Wacker Co., Ltd.), KF-50-100cs / 1000cs, KF-53, KF-54, KF-56A, KF-54HV, ( Above, manufactured by Shin-Etsu Chemical Co., Ltd.), SH-556 Fluid, PH-1555 HRI Cosmetic Fluid, FZ-3156 (all manufactured by Toray Dow Corning).
本発明における成分（Ｂ）ジメチルポリシロキサンは、３０℃で成分（Ａ）（Ｄ）と相溶せず、塗布後に直ちに優れた二次付着レス効果を発現すると共に、みずみずしいツヤも発揮することができる。成分（Ｂ）は１種または２種以上を混合して用いることができ、効果の発現の早さと、良好な安定性の点から、３０℃で液状であり、粘度が１０〜１０００ｍＰａ・ｓのものが好ましく、１０〜５００ｍＰａ・ｓのものがより好ましい。 The component (B) dimethylpolysiloxane in the present invention is incompatible with the components (A) and (D) at 30 ° C., exhibits an excellent secondary adhesion-less effect immediately after coating, and exhibits a fresh gloss. it can. The component (B) can be used alone or in combination of two or more, and is liquid at 30 ° C. and has a viscosity of 10 to 1000 mPa · s, from the viewpoint of rapid onset of effect and good stability. Those having 10 to 500 mPa · s are more preferable.
成分（Ｂ）の市販品としては、例えばＫＦ−９６Ａ−５ｃｓ／６ｃｓ／１０ｃｓ／２０ｃｓ／３０ｃｓ／５０ｃｓ／１００ｃｓ／２００ｃｓ／３００ｃ／３５０ｃｓ／５００ｃｓ／１０００ｃｓ／３０００ｃｓ／５０００ｃｓ／６０００ｃｓ、ＫＦ−９６Ｈ−１万ｃｓ／１、２５万ｃｓ／３万ｃｓ／５万ｃｓ／６万ｃｓ／１０万ｃｓ／３０万ｃｓ／５０万ｃｓ／１００万ｃｓ、（以上、信越化学工業社製）、ＳＨ−２００ Ｃ Ｆｌｕｉｄ ５ＣＳ／６ＣＳ／１０ＣＳ／２０ＣＳ／３０ＣＳ／５０ＣＳ／１００ＣＳ／２００ＣＳ／３５０ＣＳ／５００ＣＳ／１０００ＣＳ／３０００ＣＳ／５０００ＣＳ／１００００ＣＳ／１２５００ＣＳ／３００００ＣＳ／６００００ＣＳ／１０００００ＣＳ／１００００００ＣＳ、（以上、東レ・ダウコ−ニング社製）が挙げられる。 Examples of commercially available products of the component (B) include KF-96A-5cs / 6cs / 10cs / 20cs / 30cs / 50cs / 100cs / 200cs / 300c / 350cs / 500cs / 1000cs / 3000cs / 5000cs / 6000cs, KF-96H-1. 10,000 cs / 1, 250,000 cs / 30,000 cs / 50,000 cs / 60,000 cs / 100,000 cs / 300,000 cs / 500,000 cs / 1 million cs (above, manufactured by Shin-Etsu Chemical Co., Ltd.), SH-200 C Fluid 5CS / 6CS / 10CS / 20CS / 30CS / 50CS / 100CS / 200CS / 350CS / 500CS / 1000CS / 3000CS / 5000CS / 10000CS / 12500CS / 30000CS / 60000CS / 100000CS / 1000000CS, (above, Toray Daukoni Made grayed Co., Ltd.) and the like.
本発明における粘度は、測定試料を外径４５ｍｍ、内径３８ｍｍ、高さ８２ｍｍのガラス製ビンにエアスペースが生じないように充填し、ふたをして３０℃恒温槽にて一昼夜放置した後、単一円筒型回転粘度計ビスメトロン（登録商標）（芝浦システム社製）にて、付属の１〜４号ローターを用い、０.３〜３０ｒｐｍで１分後の測定値を読み取り、各々の乗数を乗したものである。 The viscosity in the present invention is measured by filling a measurement sample in a glass bottle having an outer diameter of 45 mm, an inner diameter of 38 mm, and a height of 82 mm so that an air space does not occur, and then allowing the cap to stand overnight in a constant temperature bath at 30 ° C. With a one-cylinder type rotational viscometer Bismetron (registered trademark) (manufactured by Shibaura System Co., Ltd.), using the attached No. 1 to 4 rotors, read the measured value after 1 minute at 0.3 to 30 rpm, and multiply each multiplier. It was done.
本発明の油性固型メークアップ化粧料は、成分（Ａ）と成分（Ｂ）を合計で３５〜７５質量％（以下、単に％とする）含有するものであるが、更に好ましくは４０〜７０％である。この範囲であると、二次付着レス効果とその持続性に優れ、色持ちがよく、みずみずしいツヤとツヤの持続性が高く、安定性も良好な油性固形メークアップ化粧料が得られる。成分（Ａ）及び（Ｂ）の含有量が３５％未満では、二次付着レス効果とその持続性に欠け、みずみずしいツヤとツヤの持続性も満足できるレベルとはならない。また、７５％を超えると安定性が悪くなる。また、成分（Ａ）の含有量は、油性固型メークアップ化粧料中に３０〜７０％であることが好ましく、３５〜６０％であるとより好ましく、成分（Ｂ）の含有量は、３〜２５％であることが好ましく、５〜１５％であるとより好ましい。 The oily solid makeup cosmetic of the present invention contains the component (A) and the component (B) in a total amount of 35 to 75% by mass (hereinafter, simply referred to as%), and more preferably 40 to 70. %. Within this range, an oily solid make-up cosmetic having excellent secondary adhesion-less effect and its durability, having good color retention, high freshness and long-lasting gloss, and good stability can be obtained. When the content of the components (A) and (B) is less than 35%, the secondary adhesion-less effect and its durability are lacking, and the fresh gloss and the durability of the gloss are not satisfactory. Further, if it exceeds 75%, the stability deteriorates. In addition, the content of the component (A) is preferably 30 to 70%, more preferably 35 to 60%, and the content of the component (B) is 3 in the oily solid makeup cosmetic. -25% is preferable, and 5-15% is more preferable.
成分（Ａ）と成分（Ｂ）は油性固型メークアップ化粧料中に質量比（Ａ）/（Ｂ）が１．５〜２０で含有されることが好ましく、１．５〜１４であるとより好ましく、２〜６であると更に好ましい。この範囲であると、二次付着レス効果とその持続性に優れ、みずみずしいツヤとツヤの持続性が高く、安定性も良好な油性固形メークアップ化粧料が得られる。 The mass ratio (A) / (B) of the component (A) and the component (B) in the oily solid makeup cosmetic is preferably 1.5 to 20, and is preferably 1.5 to 14. More preferably, it is more preferably 2 to 6. Within this range, an oily solid make-up cosmetic having excellent secondary adhesion-less effect and its durability, having a fresh gloss and high durability, and good stability can be obtained.
本発明における成分（Ｃ）煙霧状粉体は、通常化粧料に用いられるものであれば特に限定されず、一種または二種以上を用いても良く、フッ素化合物、シリコーン系化合物、金属石ケン、界面活性剤、油剤、炭化水素等を用いた公知の方法により表面処理したものを用いても良い。平均粒子径としては５００ｎｍ以下のものが好ましく、具体的には、シリカ、ジメチルシリル化シリカ、トリメチルシリル化シリカ、オクチルシリル化シリカ等が挙げられ、シリカとしては例えばＡＥＲＯＳＩＬ−５０／ＯＸ５０／９０Ｇ／１３０／１５０／２００／３００／３８０（以上、日本アエロジル社製）が挙げられ、ジメチルシリル化シリカとしては、例えばＡＥＲＯＳＩＬ−Ｒ９７２／Ｒ９７２ＣＦ／Ｒ９７２Ｖ／Ｒ９２００／Ｒ９７４／Ｒ９７６Ｓ（以上、日本アエロジル社製）が挙げられ、トリメチルシリル化シリカとしては、例えばＡＥＲＯＳＩＬ−ＲＸ５０／ＮＡＸ５０／ＮＸ９０Ｇ／ＲＸ２００／Ｒ８２００／ＲＸ３００／Ｒ８１２／Ｒ８１２Ｓ（以上、日本アエロジル社製）が挙げられ、オクチルシリル化シリカとしては、例えばＡＥＲＯＳＩＬ−Ｒ８０５（日本アエロジル社製）が挙げられる。中でも、良好な安定性の点からシリカ、またはジメチルシリル化シリカ、トリメチルシリル化シリカが好ましい。 The component (C) fumed powder in the present invention is not particularly limited as long as it is usually used in cosmetics, and one or more may be used, such as a fluorine compound, a silicone compound, a metal soap, You may use what was surface-treated by the well-known method using surfactant, an oil agent, hydrocarbon, etc. The average particle diameter is preferably 500 nm or less, and specific examples thereof include silica, dimethylsilylated silica, trimethylsilylated silica, and octylsilylated silica. Examples of the silica include AEROSIL-50 / OX50 / 90G / 130. / 150/200/300/380 (above, manufactured by Nippon Aerosil Co., Ltd.), and examples of the dimethylsilylated silica include AEROSIL-R972 / R972CF / R972V / R9200 / R974 / R976S (above manufactured by Nippon Aerosil Co., Ltd.). Examples of the trimethylsilylated silica include AEROSIL-RX50 / NAX50 / NX90G / RX200 / R8200 / RX300 / R812 / R812S (all manufactured by Nippon Aerosil Co., Ltd.), and octylsilylated silica. Te is, for example AEROSIL-R805 (manufactured by Nippon Aerosil Co., Ltd.) and the like. Among them, silica, dimethylsilylated silica, or trimethylsilylated silica is preferable from the viewpoint of good stability.
成分（Ｃ）は、油性固形メークアップ化粧料中での成分（Ａ）（Ｂ）と成分（Ｄ）の分離を抑制し、安定性を向上させる効果がある。本発明における成分（Ｃ）の含有量は０．１〜３％が好ましく、更に好ましくは０．１〜２％の範囲である。この範囲であると、二次付着レス効果とその持続性に優れ、均一な仕上がり、みずみずしいツヤと持続性を損なうことなく、良好な安定性を維持することが可能である。 The component (C) has the effect of suppressing the separation of the components (A) (B) and the component (D) in the oily solid make-up cosmetics and improving the stability. The content of the component (C) in the present invention is preferably 0.1 to 3%, more preferably 0.1 to 2%. Within this range, the secondary adhesion-less effect and its durability are excellent, a uniform finish can be obtained, and good stability can be maintained without impairing fresh gloss and durability.
本発明における成分（Ｄ）は炭化水素油またはエステル油であれば特に限定されず、一種または二種以上を用いても良い。炭化水素油としてはポリブテン、水添ポリイソブテン、α−オレフィンオリゴマー、流動パラフィン、ワセリン等が挙げられ、市販品としては、パールリーム４／ＥＸ／６／１８／２４／４６（以上、日油社製）、精製ポリブテンＨＶ−１００Ｆ（ＳＢ）（日本ナチュラルプロダクツ社製）、日石ポリブテン ＨＶ−３５／ＨＶ−１００／３００Ｆ／１９００Ｆ（以上、ＪＸ日光日石エネルギー社製）、ノムコートＨＰ３０／ＨＰ１００（以上、日清オイリオグループ社製）、ＫＬＥＡＲＯＬ ＷＨＩＴＥ ＭＩＮＥＲＡＬ ＯＩＬ、ＳＮＯＷ ＷＨＩＴＥ ＳＰＥＣＩＡＬ（以上、ＳＯＮＮＥＢＯＲＮ社製）等が挙げられる。エステル油としてはトリイソステアリン酸ポリグリセリル−２、トリ−２エチルヘキサン酸グリセリル、リンゴ酸ジイソステアリル、（ビニルピロリドン／ヘキサデセン）コポリマー、ヒマシ油、酢酸液状ラノリン、ショ糖脂肪酸エステル、パラメトキシケイ皮酸２−エチルヘキシル、トリメリト酸トリトリデシル、ダイマージリノール酸（フィトステリル／イソステアリル／セチル／ステアリル／ベヘニル）、ダイマージリノレイル水添ロジン縮合物、（カプリル／カプリン／ミリスチン／ステアリン酸）トリグリセリル、ヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ペンタエリスリチル等が挙げられ、市販品としては、コスモール４３Ｖ、コスモール２２２、サラコス３３４、コスモール１６８ＡＲＮ（以上、日清オイリオグループ社製）、ＭＹＲＩＴＯＬ ＧＴＥＨ（ＢＡＳＦ社製）、ＡＮＴＡＲＯＮ Ｖ２１６（アイエスピー・ジャパン社製）、ＡＣＥＬＡＮ ＳＰ（クローダジャパン社製）、ＬＩＰＯＮＡＴＥ ＴＤＴＭ（ＬＩＰＯ ＣＨＥＭＩＣＡＬＳ社製）、ＰＬＡＮＤＯＯＬ−Ｓ、ＬＵＳＰＬＡＮ ＤＤ−ＤＨＲ（以上、日本精化社製）等が挙げられる。中でも、ツヤとツヤの持続性及び良好な安定性の点から、トリイソステアリン酸ポリグリセリル−２、トリ−２エチルヘキサン酸グリセリル、リンゴ酸ジイソステアリル、（ビニルピロリドン／ヘキサデセン）コポリマー等のエステル油が特に好ましい。
本発明における成分（Ｄ）の含有量は２０〜６０％が好ましく、更に好ましくは２０〜４０％の範囲である。
The component (D) in the present invention is not particularly limited as long as it is a hydrocarbon oil or an ester oil, and one kind or two or more kinds may be used. Examples of the hydrocarbon oil include polybutene, hydrogenated polyisobutene, α-olefin oligomer, liquid paraffin, petrolatum, and the like, and commercially available products include Pearlream 4 / EX / 6/18/24/46 (above, manufactured by NOF Corporation). ), Purified polybutene HV-100F (SB) (manufactured by Japan Natural Products Co., Ltd.), Nisseki Polybutene HV-35 / HV-100 / 300F / 1900F (above, JX Nikko Nisseki Energy Co., Ltd.), Nomcoat HP30 / HP100 (above). , Manufactured by Nisshin Oillio Group Co., Ltd.), KLEAROL WHITE MINUAL OIL, SNOW WHITE SPECIAL (above, manufactured by SONNEBORN), and the like. Examples of the ester oil include polyglyceryl-2 triisostearate, glyceryl tri-2 ethylhexanoate, diisostearyl malate, (vinylpyrrolidone / hexadecene) copolymer, castor oil, acetic acid liquid lanolin, sucrose fatty acid ester, and paramethoxycinnamic acid. 2-Ethylhexyl, tritridecyl trimellitate, dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleyl hydrogenated rosin condensate, (capryl / caprin / myristin / stearic acid) triglyceryl, hexa (Hydroxystearic acid / stearic acid / rosin acid) pentaerythrityl and the like can be mentioned. Commercially available products include Cosmol 43V, Cosmol 222, Saracos 334, Cosmol 168ARN (above, Nisshin Oy O group company), MYRITO L GTEH (manufactured by BASF company), ANTARON V216 (manufactured by ISPE Japan company), ACELAN SP (manufactured by Croda Japan company), LIPONATE TDTM (manufactured by LIPO CHEMICALS company), PLANDOOL-S, LUSPLAN DD- DHR (above, Nippon Seika Co., Ltd. make) etc. are mentioned. Among them, ester oils such as polyglyceryl-2 triisostearate, glyceryl tri-2 ethylhexanoate, diisostearyl malate, and (vinylpyrrolidone / hexadecene) copolymers are used in terms of gloss and durability and good stability. Particularly preferred.
The content of the component (D) in the present invention is preferably 20 to 60%, more preferably 20 to 40%.
本発明における成分（Ｅ）ワックスは、通常化粧料に配合されるものであれば特に限定されず、一種または二種以上を用いても良い。例えばパラフィンワックス、セレシンワックス、マイクロクリスタリンワックス、エチレンプロピレンコポリマー、ポリエチレン、モンタンワックス、フィッシャートロプシュワックス、モクロウ、ミツロウ、カルナウバワックス、キャンデリラワックス、コメヌカロウ、ゲイロウ等が挙げられる。中でも、良好な安定性の点から、パラフィンワックス、セレシンワックス、マイクロクリスタリンワックス、エチレンプロピレンコポリマー、ポリエチレン、フィッシャートロプシュワックス、カルナウバワックス、キャンデリラワックスが好ましく、融点は７０〜１０５℃であることが好ましい。 The component (E) wax in the present invention is not particularly limited as long as it is usually blended in cosmetics, and one kind or two or more kinds may be used. Examples thereof include paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, polyethylene, montan wax, Fischer-Tropsch wax, wax, beeswax, carnauba wax, candelilla wax, rice bran wax, and gallow wax. Among them, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, polyethylene, Fischer-Tropsch wax, carnauba wax, and candelilla wax are preferable from the viewpoint of good stability, and the melting point is 70 to 105 ° C. preferable.
本発明における成分（Ｅ）の含有量は３〜１０％が好ましく、更に好ましくは４〜８％の範囲である。この範囲であると、二次付着レス効果とその持続性に優れ、均一な仕上がり、みずみずしいツヤとツヤの持続性を損なうことなく、良好な安定性を維持することが可能である。 The content of the component (E) in the present invention is preferably 3 to 10%, more preferably 4 to 8%. Within this range, the secondary adhesion-less effect and its durability are excellent, a uniform finish is achieved, and good stability can be maintained without impairing the fresh gloss and the durability of the gloss.
本発明の油性メークアップ化粧料における成分（Ｆ）の着色剤は、通常化粧料で用いられるものであれば特に制限なく使用することができる。具体的には、酸化チタン、酸化亜鉛、酸化セリウム、硫酸バリウム等の白色無機顔料、酸化鉄、カーボンブラック、チタン・酸化チタン焼結物、酸化クロム、水酸化クロム、紺青、群青、チタン酸リチウムコバルト、マンガンバイオレット等の有色無機顔料、タルク、白雲母、金雲母、紅雲母、黒雲母、合成雲母、絹雲母（セリサイト）、合成セリサイト、二酸化珪素、酸化アルミニウム、酸化マグネシウム、酸化ジルコニウム、酸化アンチモン、ケイ酸アルミニウム、メタケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、硫酸バリウム、ハイドロタルサイト、ヒドロキシアパタイト、窒化ホウ素等の白色体質粉体、、酸化チタン被覆雲母、酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、酸化チタン被覆合成金雲母、酸化チタン被覆ガラス末、酸化チタン・酸化鉄被覆ガラス末、オキシ塩化ビスマス、魚鱗箔、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリオレフィン積層フィルム末、ポリエチレンテレフタレート・ポリメチルメタクリレート積層フィルム末等の光輝性粉体、赤色２０１号、赤色２０２号、赤色２０５号、赤色２２６号、赤色２２８号、橙色２０３号、橙色２０４号、青色４０４号、黄色４０１号等の有機顔料粉体、赤色２２３号、赤色２１８号、橙色２０１号等の染料、赤色３号、赤色１０４号、赤色１０６号、橙色２０５号、黄色４号、黄色５号、緑色３号、青色１号等のジルコニウム、バリウム又はアルミニウムレーキ等の有機顔料粉体、アルミニウム粉、金粉、銀粉等の金属粉体、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有二酸化珪素、酸化亜鉛含有二酸化珪素等の複合粉体等が挙げられ、これらは１種又は２種以上、または複合化して用いることができる。また、フッ素化合物、金属石ケン、界面活性剤、レシチン、アミノ酸、油剤、炭化水素等を用いた公知の方法により表面処理したものを用いても良い。 The colorant as the component (F) in the oily makeup cosmetic of the present invention can be used without particular limitation as long as it is one that is usually used in cosmetics. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered products, chromium oxide, chromium hydroxide, navy blue, ultramarine blue, lithium titanate. Colored inorganic pigments such as cobalt and manganese violet, talc, muscovite, phlogopite, phlogopite, biotite, synthetic mica, sericite, synthetic sericite, silicon dioxide, aluminum oxide, magnesium oxide, zirconium oxide, White powder such as antimony oxide, aluminum silicate, magnesium aluminum metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, barium sulfate, hydrotalcite, hydroxyapatite, and boron nitride, Titanium oxide coated mica, titanium oxide coated Bismuth xylchloride, iron oxide mica titanium, dark blue treated mica titanium, carmine treated mica titanium, titanium oxide coated synthetic phlogopite, titanium oxide coated glass powder, titanium oxide / iron oxide coated glass powder, bismuth oxychloride, fish scale foil, polyethylene terephthalate・ Aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethylmethacrylate laminated film powder, etc., bright powder, red 201, red 202, red 205, red 226, red 228 , Orange 203, orange 204, blue 404, yellow 401, and other organic pigment powders, red 223, red 218, orange 201, and other dyes, red 3, red 104, red 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1 or the like organic pigment powder such as zirconium, barium or aluminum lake, metal powder such as aluminum powder, gold powder, silver powder, fine titanium oxide-coated titanium mica, fine zinc oxide-coated titanium mica, barium sulfate-coated titanium mica, oxidized Examples thereof include composite powders of titanium-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like. These can be used alone or in combination of two or more, or can be used in combination. In addition, those surface-treated by a known method using a fluorine compound, a metal soap, a surfactant, lecithin, an amino acid, an oil agent, a hydrocarbon and the like may be used.
本発明における成分（Ｆ）の含有量は０．００１〜２５％、更には０．００１〜１５％であることが好ましい。この範囲であると、色もちのよさ、二次付着レス効果が十分に発揮される。 The content of the component (F) in the present invention is preferably 0.001 to 25%, more preferably 0.001 to 15%. Within this range, good color retention and secondary adhesion-less effect are sufficiently exhibited.
本発明の油性固形メークアップ化粧料は、更に成分（Ｇ）親油性界面活性剤を含有すると化粧膜の均一性および良好な安定性において好ましい。成分（Ｇ）としては、本発明の油性固形メークアップ化粧料の効果を妨げないものであれば特に限定されず使用することができる。例えばグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ポリオキシエチレン硬化ヒマシ油、ポリオキシアルキレンアルキル共変性オルガノポリシロキサン、ポリエーテル変性オルガノポリシロキサン、レシチン等が挙げられ、これらの中でもセスキイソステアリン酸ソルビタン、セスキオレイン酸ソルビタン、ラウリルポリグリセリル−３ポリジメチルシロキシエチルジメチコン、ＰＥＧ−９ポリジメチルシロキシエチルジメチコン、ラウリルＰＥＧ−９ポリジメチルシロキシエチルジメチコン、セチル／ＰＥＧ／ＰＰＧ−１０／１ジメチコン、ビス−セチルＰＥＧ／ＰＰＧ−１４／１４ジメチコン等が加熱製造時に成分（Ａ）や（Ｂ）の分離を抑制するため、良好な安定性において好ましく、ラウリルポリグリセリル−３ポリジメチルシロキシエチルジメチコン、ＰＥＧ−９ポリジメチルシロキシエチルジメチコン、ラウリルＰＥＧ−９ポリジメチルシロキシエチルジメチコン、セチル／ＰＥＧ／ＰＰＧ−１０／１ジメチコン、ビス−セチルＰＥＧ／ＰＰＧ−１４／１４ジメチコン等のジメチルポリシロキサンを骨格とするシリコーン系の親油性界面活性剤が更に好ましい。これらの市販品として、セスキイソステアリン酸ソルビタンとしてはコスモール１８２Ｖ、セスキオレイン酸ソルビタンとしては、コスモール８２（以上、日清オイリオグループ社製）、ラウリルポリグリセリル−３ポリジメチルシロキシエチルジメチコンとしては、ＫＦ−６１０５、ＰＥＧ−９ポリジメチルシロキシエチルジメチコンとしてはＫＦ−６０２８、ラウリルＰＥＧ−９ポリジメチルシロキシエチルジメチコンとしては、ＫＦ−６０３８（以上、信越化学工業社製）、セチル／ＰＥＧ／ＰＰＧ−１０／１ジメチコンとしては、ＡＢＩＬ ＥＭ９０（Ｄｅｇｕｓｓａ社製）、ビス−セチルＰＥＧ／ＰＰＧ−１４／１４ジメチコンとしては、ＡＢＩＬ ＥＭ９７（Ｄｅｇｕｓｓａ社製）等が挙げられる。 It is preferable that the oily solid makeup cosmetic of the present invention further contains the component (G) lipophilic surfactant in terms of uniformity and good stability of the cosmetic film. The component (G) is not particularly limited as long as it does not impair the effects of the oily solid makeup cosmetic of the present invention and can be used. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, poly Examples thereof include ether-modified organopolysiloxane and lecithin. Among these, sorbitan sesquiisostearate, sorbitan sesquioleate, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, PEG-9 polydimethylsiloxyethyl dimethicone, lauryl PEG-9 polydimethyl. Siloxyethyl dimethicone, cetyl / PEG / PPG-10 / 1 dimethicone, bis-cetyl PEG / PPG-14 / 1 Dimethicone and the like suppress the separation of the components (A) and (B) during the production by heating, and therefore are preferable in terms of good stability. Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, PEG-9 polydimethylsiloxyethyl dimethicone, lauryl PEG A silicone-based lipophilic surfactant having a dimethylpolysiloxane as a skeleton such as 9 polydimethylsiloxyethyl dimethicone, cetyl / PEG / PPG-10 / 1 dimethicone, and bis-cetyl PEG / PPG-14 / 14 dimethicone is more preferable. These commercially available products include Cosmol 182V as sorbitan sesquiisostearate, Cosmol 82 (above, manufactured by Nisshin OilliO Group) as sorbitan sesquioleate, and KF-6105 as lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone. , PEG-9 polydimethylsiloxyethyl dimethicone KF-6028, lauryl PEG-9 polydimethylsiloxyethyl dimethicone KF-6038 (above, Shin-Etsu Chemical Co., Ltd.), cetyl / PEG / PPG-10 / 1 dimethicone. Examples include ABIL EM90 (manufactured by Degussa), and examples of bis-cetyl PEG / PPG-14 / 14 dimethicone include ABIL EM97 (manufactured by Degussa).
本発明における成分（Ｇ）の含有量は、油性固形メークアップ化粧料中の０．０１〜１０％が好ましく、更に好ましくは０．１〜５％の範囲である。この範囲であれば、二次付着レス効果を損なうことなく、均一な仕上がりと良好な安定性を更に向上させることが出来る。 The content of the component (G) in the present invention is preferably 0.01 to 10%, and more preferably 0.1 to 5% in the oily solid makeup cosmetic. Within this range, the uniform finish and good stability can be further improved without impairing the secondary adhesion-less effect.
本発明の油性固形メークアップ化粧料には、上記の成分（Ａ）〜（Ｇ）の他に、通常化粧料に使用される成分、例えば基材やエモリエント成分としての油性成分、粉体、粉体分散や感触調整としての界面活性剤、紫外線吸収剤、保湿剤、褪色防止剤、酸化防止剤、消泡剤、美容成分、防腐剤、香料等を、本発明の効果を損なわない範囲で適宜含有することができる。 In the oily solid makeup cosmetic of the present invention, in addition to the above components (A) to (G), components usually used in cosmetics, for example, oily components as base materials and emollient components, powders, powders Surfactants for body dispersion and texture adjustment, ultraviolet absorbers, humectants, anti-fading agents, antioxidants, defoamers, cosmetic ingredients, preservatives, fragrances, etc. are appropriately added within a range that does not impair the effects of the present invention. Can be included.
油性成分としては、動物油、植物油、合成油等の起源、及び、固形油、半固形油、液体油等の性状を問わず、高級アルコール類、フッ素系油類、油性ゲル化剤類等が挙げられる。具体的には、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、デカメチルシクロペンタシロキサン、フッ素変性オルガノポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、デンプン脂肪酸エステル、１２−ヒドロキシステアリン酸、ステアリン酸カルシウム等の油性ゲル化剤類等が挙げられる。 Examples of the oily component include the origin of animal oil, vegetable oil, synthetic oil, and the like, and regardless of the properties of solid oil, semi-solid oil, liquid oil, higher alcohols, fluorine-based oils, oily gelling agents, etc. To be Specifically, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, and behenyl alcohol, silicones such as decamethylcyclopentasiloxane, fluorine-modified organopolysiloxane, perfluorodecane, perfluoro. Fluorine-based oil agents such as octane and perfluoropolyether, oily gelling agents such as starch fatty acid ester, 12-hydroxystearic acid, and calcium stearate.
成分（Ｃ）、（Ｆ）以外の粉体としては、板状、紡錘状、針状等の形状、微粒子、顔料級などの粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、有機粉体類、複合粉体類、等が挙げられる。具体的にはカオリン等の無機粉体類、ステアリン酸マグネシウム、ステアリン酸亜鉛、Ｎ−アシルリジン、ポリエチレンテレフタレート、ナイロン、ポリメタクリル酸メチル、メチルシロキサン網状重合体等の有機粉体類、微粒子酸化チタン含有二酸化珪素、微粒子酸化亜鉛含有二酸化珪素等の複合粉体、等が挙げられ、これらを１種又は２種以上を用いることができる。また、これら粉体は１種又は２種以上の複合化したものを用いても良く、フッ素化合物、金属石ケン、界面活性剤、油剤、炭化水素等を用いた公知の方法により表面処理したものを用いても良い。 The powder other than the components (C) and (F) is particularly limited depending on the shape such as a plate shape, a spindle shape, a needle shape, a particle size such as fine particles and pigment grade, and a particle structure such as porous and non-porous. However, inorganic powders, organic powders, composite powders, etc. may be mentioned. Specifically, inorganic powders such as kaolin, organic powders such as magnesium stearate, zinc stearate, N-acyl lysine, polyethylene terephthalate, nylon, polymethyl methacrylate, methyl siloxane network polymer, and titanium oxide fine particles are included. Examples thereof include composite powders of silicon dioxide, silicon dioxide containing fine particle zinc oxide, and the like, and these may be used alone or in combination of two or more. In addition, these powders may be used alone or in combination of two or more kinds, and those subjected to surface treatment by a known method using a fluorine compound, a metal soap, a surfactant, an oil agent, a hydrocarbon and the like. May be used.
成分（Ｇ）以外の界面活性剤としては、化粧料一般に用いられている界面活性剤であればいずれのものも使用でき、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等が挙げられる。 As the surfactant other than the component (G), any surfactant that is commonly used in cosmetics can be used, and a nonionic surfactant, an anionic surfactant, a cationic surfactant can be used. , Amphoteric surfactants and the like.
紫外線吸収剤としては、例えばベンゾフェノン系、ＰＡＢＡ系、ケイ皮酸系、サリチル酸系、４−ｔｅｒｔ−ブチル−４’−メトキシジベンゾイルメタン、オキシベンゾン等、保湿剤としては、例えばタンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等、酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等、美容成分としては、例えばビタミン類、消炎剤、生薬等、防腐剤としては、例えばパラオキシ安息香酸エステル、フェノキシエタノール、１，２ペンタンジオール等が挙げられる。 Examples of the ultraviolet absorber include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like, and moisturizers include, for example, protein, mucopolysaccharide, and collagen. , Elastin, keratin and the like, antioxidants such as α-tocopherol, ascorbic acid and the like, cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines and the like, preservatives such as paraoxybenzoate, phenoxyethanol, 1 , 2 pentanediol and the like.
本発明の油性固形メークアップ化粧料は、固形であれば特に限定されず、口紅、リップグロスなどの口唇化粧料、ファンデーション、コンシーラー、アイライナー、アイカラー、ほほ紅等に用いることができる。中でも、本発明の油性固形メークアップ化粧料の色持ちのよさ、みずみずしいツヤとツヤの持続性、二次付着レス効果とその持続性は、カップなどへの接触機会の多い口唇化粧料において好適に使用でき、良好な安定性は、加熱溶融充填により成型するものに好適に使用できる。 The oily solid makeup cosmetic of the present invention is not particularly limited as long as it is solid, and can be used for lip cosmetics such as lipsticks and lip glosses, foundations, concealers, eyeliners, eye colors, and blushers. Among them, the longevity of the oily solid make-up cosmetic composition of the present invention, the freshness of the gloss and the luster, the secondary adhesion-less effect and its persistence are suitable for lip cosmetics that often have a chance of contacting a cup or the like. It can be used and has good stability, so that it can be suitably used for molding by hot melt filling.
以下に実施例をあげて本発明を詳細に説明する。尚、これらは本発明を何ら限定するものではない。
実施例１〜９及び比較例１〜６：スティック状口紅
下記表1及び２に示す処方のスティック状口紅を調製し、イ．３０℃での成分（Ａ）（Ｂ）（Ｄ）混合物３相分離状態、ロ．二次付着レス効果の発現の速さ、ハ．色持ちの持続性、ニ．みずみずしいツヤの持続性、ホ．二次付着レス効果と持続性、ヘ．均一な仕上がり、ト．経時安定性について下記評価方法により評価した。その結果も併せて表１及び２に示す。
The present invention will be described in detail below with reference to examples. These do not limit the present invention in any way.
Examples 1 to 9 and Comparative Examples 1 to 6: Stick Lipsticks Stick lipsticks having the formulations shown in Tables 1 and 2 below were prepared. Component (A) (B) (D) mixture three phase separation state at 30 ° C., b. Speed of development of secondary adhesion-less effect, c. Persistence of color, d. Persistence of fresh luster, e. Secondary adhesion-less effect and durability, f. Uniform finish, The temporal stability was evaluated by the following evaluation method. The results are also shown in Tables 1 and 2.
※２：ＫＦ−５４（信越化学工業社製）
※３：シリコン ＫＦ−５６（信越化学工業社製）
※４：ＡＮＴＡＲＯＮ Ｖ−２１６（アイエスピー・ジャパン社製）
※５：コスモール２２２（日清オイリオグループ社製）
※６：コスモール ４３Ｖ（日清オイリオグループ社製）
※７：ＰＥＲＦＯＲＭＡＬＥＮＥ ６５５
（融点１００℃：ニューフェーズテクノロジー社製）
※８：ＫＦ−６１０５（信越化学工業社製）
※９：ＡＥＲＯＳＩＬ Ｒ９７６Ｓ（日本アエロジル社製）
* 2: KF-54 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 3: Silicon KF-56 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 4: ANTARON V-216 (made by ISPE Japan)
* 5: Cosmall 222 (manufactured by Nisshin Oillio Group)
* 6: Cosmall 43V (manufactured by Nisshin OilliO Group)
* 7: PERFORMALENE 655
(Melting point 100 ° C: manufactured by New Phase Technology)
* 8: KF-6105 (produced by Shin-Etsu Chemical Co., Ltd.)
* 9: AEROSIL R976S (manufactured by Nippon Aerosil Co., Ltd.)
（製造方法）
Ａ．成分（１）〜（１０）を均一に１０５℃にて溶解する。
Ｂ．Ａに成分（１１）〜（１５）を加え、均一に混合する。
Ｃ．Ｂを容器に９０℃にて溶解充填して冷却固化しスティック状口紅を得た。
(Production method)
A. Components (1) to (10) are uniformly dissolved at 105 ° C.
B. Ingredients (11) to (15) are added to A and mixed uniformly.
C. B was melted and filled in a container at 90 ° C., cooled and solidified to obtain a stick lipstick.
（評価方法）
下記評価項目について各々下記方法により評価を行った。
（評価項目）
イ．３０℃での成分（Ａ）（Ｂ）（Ｄ）混合物の３相分離状態
ロ．二次付着レス効果の発現の速さ
ハ．色持ちの持続性
ニ．みずみずしいツヤの持続性
ホ．二次付着レス効果と持続性
ヘ．均一な仕上がり
ト．経時安定性
イの３０℃での３相分離状態は、各試料に用いた成分（Ａ）（Ｂ）（Ｄ）の混合物が３０℃において、３相に分離しているかどうかを目視にて確認した。
ロ〜ヘの項目については、各試料について専門パネル２０名による使用テストを行った。パネル各人が下記評価基準にて７段階に評価し評点をつけ、パネル全員の評点合計からその平均値を算出し、下記判定基準により判定した。なお、ハの色持ちの持続性とニのみずみずしいツヤの持続性については各試料を塗布し、パネルに通常の生活をしてもらった後、６時間後に口唇上に口紅の色及びツヤの状態を評価した。ロの二次付着レス効果の発現の速さとホの二次付着レス効果と持続性については、塗布後すぐと塗布２時間後にコーヒーカップでお茶を飲み、カップに移ったリップマークの濃淡で評価した。ヘの均一な仕上がりについては、塗布直後の色ムラのなさ及び化粧膜のよれのなさを目視にて評価した。トの経時安定性については、各試料を容器に充填した状態で４０℃で１ヶ月保存したものを使用し、塗布膜の均一性や顔料の凝集や分離、発汗が見られないかを評価した。
(Evaluation methods)
Each of the following evaluation items was evaluated by the following methods.
(Evaluation item)
I. Three-phase separated state of component (A) (B) (D) mixture at 30 ° C. b. Speed of development of secondary adhesion-less effect c. Long-lasting d. A long-lasting fresh luster. Secondary adhesion-less effect and persistence f. Uniform finish. Regarding the three-phase separation state of stability over time at 30 ° C, it was visually confirmed whether the mixture of the components (A), (B) and (D) used for each sample was separated into three phases at 30 ° C. did.
With respect to items (b) to (e), a usage test was conducted by 20 specialist panels for each sample. Each panel was rated on a scale of 7 according to the following evaluation criteria, a rating was given, the average value was calculated from the sum of the ratings of all panelists, and the rating was determined according to the following criteria. Regarding the persistence of the color of c and the persistence of the fresh luster, after applying each sample and having the panel have a normal life, the color of lipstick and the condition of gloss on the lip 6 hours later. Was evaluated. Regarding the speed of development of the secondary adhesion-less effect of b and the secondary adhesion-less effect of e and the persistence, it was evaluated by the intensity of the lip mark transferred to the cup after drinking tea immediately after application and 2 hours after the application. did. With regard to the uniform finish of F, the color unevenness immediately after application and the smoothness of the cosmetic film were visually evaluated. Regarding the stability with time, each sample was stored in a container and stored at 40 ° C. for 1 month, and the uniformity of the coating film, the aggregation and separation of the pigment, and the appearance of perspiration were evaluated. .
＜評価基準＞
（評点）：（評価）
６ ：非常に良い
５ ：良い
４ ：やや良い
３ ：普通
２ ：やや悪い
１ ：悪い
０ ：非常に悪い
＜判定基準＞
（判定）：（評点の平均点）
◎ ：非常に良好 ：５．５点を超える
○ ：良好 ：３．５点を超え５．５点以下
△ ：不良 ：１点を超え３．５点以下
× ：非常に不良 ：１点以下
<Evaluation criteria>
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad <Criteria>
(Judgment): (Average score)
◎: Very good: Over 5.5 points ○: Good: Over 3.5 points and under 5.5 points △: Defect: Over 1 point and under 3.5 points ×: Very poor: Under 1 point
表１及び２の結果から明らかなように、本発明の実施例１〜９のスティック状口紅は、比較例１〜６のスティック状口紅に比べ、二次付着レス効果の発現の速さ、色持ちの持続性、みずみずしいツヤの持続性、二次付着レス効果と持続性、均一な仕上がり、経時安定性に優れたものであった。
一方、成分（Ａ）及び（Ｂ）の含有量が少ない比較例１では、成分（Ａ）、（Ｂ）及び（Ｄ）が３０℃において３相に分離するものの、二次付着レス効果の発現の速さ、二次付着レス効果と持続性に欠け、更にそれに伴い成分（Ｆ）の分散した化粧膜も色移りにより剥がれてしまうため、色持ちも満足のいくものが得られなかった。また、成分（Ａ）及び（Ｂ）の含有量が多い比較例２では、成分（Ａ）、（Ｂ）及び（Ｄ）が３０℃において３相に分離するものの、均一な仕上がりと経時安定性において満足のいくものが得られなかった。成分（Ａ）、（Ｂ）及び（Ｄ）が３相に分離しない比較例３では、二次付着レス効果の発現の速さ、二次付着レス効果と持続性に欠けそれに伴い色持ちの持続性、みずみずしいツヤの持続性において満足のいくものが得られなかった。成分（Ａ）を含有しない比較例４では、二次付着レス効果と持続性に欠け、それに伴い色持ちの持続性も不十分であり、均一な仕上がりと経時安定性においても満足のいくものが得られなかった。成分（Ｂ）を含有しない比較例５では、二次付着レス効果の発現の速さ、二次付着レス効果と持続性に欠け、均一な仕上がりと経時安定性においても満足のいくものが得られなかった。成分（Ｃ）を含有しない比較例６では、成分（Ａ）、（Ｂ）及び（Ｄ）が３０℃において３相に分離するものの、分離してしまい固化せず、製剤として成り立たないものであった。
As is clear from the results of Tables 1 and 2, the stick-shaped lipsticks of Examples 1 to 9 of the present invention were faster than the stick-shaped lipsticks of Comparative Examples 1 to 6 in the development of the secondary adhesion-less effect and the color. It had excellent long-lasting durability, fresh and long-lasting luster, secondary adhesion-less effect and durability, uniform finish, and stability over time.
On the other hand, in Comparative Example 1 in which the content of the components (A) and (B) is small, although the components (A), (B) and (D) are separated into three phases at 30 ° C, the secondary adhesion-less effect is exhibited. However, the effect of the secondary adhesion-less effect and the durability are not sufficient, and the makeup film in which the component (F) is dispersed is also peeled off due to the color transfer, so that the color retention is not satisfactory. Further, in Comparative Example 2 containing a large amount of the components (A) and (B), the components (A), (B) and (D) were separated into three phases at 30 ° C, but a uniform finish and stability with time were obtained. I didn't get what I was happy with. In Comparative Example 3 in which the components (A), (B) and (D) were not separated into three phases, the speed of the secondary adhesion-less effect was exhibited, the secondary adhesion-less effect and the persistence were lacking, and the coloring was maintained. Satisfaction with freshness and fresh luster was not obtained. In Comparative Example 4 which does not contain the component (A), the secondary adhesion-less effect and the durability are lacking, and accordingly, the persistence of the color retention is insufficient, and the uniform finish and the stability with time are satisfactory. I couldn't get it. In Comparative Example 5 which does not contain the component (B), the speed of development of the secondary adhesion-less effect, the secondary adhesion-less effect and the lack of durability are obtained, and a satisfactory finish and stability over time are obtained. There wasn't. In Comparative Example 6 which does not contain the component (C), the components (A), (B) and (D) separate into three phases at 30 ° C., but they do not solidify because they separate and do not hold as a formulation. It was
実施例１０：金皿充填口紅
（成分） （％）
（１）（エチレン／プロピレン）コポリマー※１０ ２
（２）キャンデリラワックス※１１ ８
（３）トリメチルシロキシフェニルジメチコン※１ ３０
（４）ジメチルポリシロキサン ２０
（５）ラウリルＰＥＧ−９ポリジメチル
シロキシエチルジメチコン※１２ ５
（６）ポリブテン※１３ １０
（７）トリ（カプリル／カプリン酸）グリセリル ５
（８）ジリノール酸ジ（フィトステリル／イソステアリル／
セチル／ステアリル／ベヘニル） １
（９）ジ２−エチルヘキサン酸ネオペンチルグリコール 残量
（１０）酢酸トコフェロール ０．５
（１１）赤色２０１号 ０．５
（１２）シリカ※１４ ０．５
（１３）ベンガラ被覆ガラス末 １
（１４）シリコーン２％処理黄酸化鉄被覆雲母チタン ２
組成物中のフェニル変性シリコーン粘度（３０℃）：１０００ｍＰａ・ｓ
組成物中のジメチルポリシロキサン粘度（３０℃）：１０００ｍＰａ・ｓ
※１０：ペトロライトＥＰ−７００（融点９６℃：Baker Petrolite社製）
※１１：融点：７０℃
※１２：ＫＦ−６０３８（信越化学工業社製）
※１３：日石ポリブテンＨＶ−１００（ＪＸ日鉱日石エネルギー社製）
※１４：ＡＥＲＯＳＩＬ３００（日本アエロジル社製）
（製造方法）
Ａ．成分（１）〜（１０）を均一に１００℃にて溶解する。
Ｂ．Ａに成分（１１）〜（１４）を加え、均一に混合する。
Ｃ．Ｂを９０℃にて金皿に溶解充填して冷却固化し金皿充填口紅を得た。
以上のようにして得られた金皿充填口紅は、色持ち、ツヤ持ち、二次付着レス効果、均一な仕上がり、経時安定性に優れたものであった。
Example 10: Gold plate filled lipstick (ingredient) (%)
(1) (Ethylene / Propylene) Copolymer * 10 2
(2) Candelilla wax * 11 8
(3) Trimethylsiloxyphenyl dimethicone * 1 30
(4) Dimethyl polysiloxane 20
(5) Lauryl PEG-9 polydimethyl
Siloxyethyl dimethicone * 125
(6) Polybutene * 13 10
(7) Glyceryl 5 tri (capryl / capric acid)
(8) Dilinoleic acid di (phytosteryl / isostearyl /
Cetyl / stearyl / behenyl) 1
(9) Neopentyl glycol di2-ethylhexanoate Remaining amount (10) Tocopherol acetate 0.5
(11) Red No. 201 0.5
(12) Silica * 14 0.5
(13) Red iron oxide coated glass powder 1
(14) Silicone 2% treated yellow iron oxide coated mica titanium 2
Phenyl-modified silicone viscosity in composition (30 ° C.): 1000 mPa · s
Dimethylpolysiloxane viscosity in the composition (30 ° C.): 1000 mPa · s
* 10: Petrolite EP-700 (melting point 96 ° C: manufactured by Baker Petrolite)
* 11: Melting point: 70 ° C
* 12: KF-6038 (produced by Shin-Etsu Chemical Co., Ltd.)
* 13: Nisseki Polybutene HV-100 (made by JX Nikko Nisseki Energy Co., Ltd.)
* 14: Aerosil 300 (manufactured by Nippon Aerosil Co., Ltd.)
(Production method)
A. Components (1) to (10) are uniformly dissolved at 100 ° C.
B. Components (11) to (14) are added to A and mixed uniformly.
C. B was melt-filled at 90 ° C. in a gold plate and cooled and solidified to obtain a gold plate-filled lipstick.
The gold plate-filled lipstick obtained as described above was excellent in color retention, gloss retention, secondary adhesion-less effect, uniform finish, and stability over time.
実施例１１：固形状リップグロス
（成分） （％）
（１）フィッシャートロプシュワックス※１５ ５
（２）イヌリンステアレート ３
（３）トリメチルシロキシフェニルジメチコン※１ ３５
（４）トリメチルペンタフェニルトリシロキサン※１６ ２０
（５）ジメチルポリシロキサン ３
（６）ＰＥＧ−９ポリジメチルシロキシエチルジメチコン※１７ ２
（７）水添ポリイソブテン※１８ ３
（８）炭酸ジアルキル（１４，１５） ５
（９）トリ２−エチルヘキサン酸グリセリル 残量
（１０）ヘキサ（ヒドロキシステアリン酸/ステアリン酸/ロジン酸）
ジペンタエリスリチル ５
（１１）フェノキシエタノール ０．２
（１２）ハイドロゲンジメチコン５％処理赤色２０２号 ０．５
（１３）トリエトキシカプリリルシラン３％処理酸化チタン ０．１
（１４）ジメチルシリル化シリカ※９ ３
（１５）パーフルオロオクチルトリエトキシシラン３％処理
酸化チタン被覆ガラス末 １
（１６）球状ポリメチルシルセスキオキサン末 １
組成物中のフェニル変性シリコーン粘度（３０℃）：４００ｍＰａ・ｓ
組成物中のジメチルポリシロキサン粘度（３０℃）：５０ｍＰａ・ｓ
※１５：ＣＩＲＥＢＥＬＬＥ１０８（融点８０〜８５℃：ＤＫＳＨジャパン社製）
※１６：ＰＨ１５５５ ＨＲＩ Ｃ．Ｆ．（東レ・ダウコーニング社製）
※１７：ＫＦ−６０２８（信越化学工業社製）
※１８：パールリーム２４（日油社製）
（製造方法）
Ａ．成分（１）〜（１１）を均一に１００℃にて溶解する。
Ｂ．Ａに成分（１２）〜（１６）を加え、均一に混合する。
Ｃ．Ｂを容器に９０℃にて溶解充填して冷却固化し固形状リップグロスを得た。
以上のようにして得られた固形状リップグロスは、色持ち、ツヤ持ち、二次付着レス効果、均一な仕上がり、経時安定性に優れたものであった。
Example 11: Solid lip gloss (component) (%)
(1) Fischer-Tropsch wax * 15 5
(2) Inulin stearate 3
(3) Trimethylsiloxyphenyl dimethicone * 1 35
(4) Trimethylpentaphenyltrisiloxane * 16 20
(5) Dimethyl polysiloxane 3
(6) PEG-9 polydimethylsiloxyethyl dimethicone * 17 2
(7) Hydrogenated polyisobutene * 18 3
(8) Dialkyl carbonate (14,15) 5
(9) Glyceryl tri-2-ethylhexanoate Residual amount (10) Hexa (hydroxystearic acid / stearic acid / rosin acid)
Dipentaerythrityl 5
(11) Phenoxyethanol 0.2
(12) Hydrogen dimethicone 5% treated red No. 202 0.5
(13) Titanium oxide treated with triethoxycaprylylsilane 3% 0.1
(14) Dimethylsilylated silica * 9 3
(15) Perfluorooctyltriethoxysilane 3% treatment
Titanium oxide coated glass powder 1
(16) Spherical polymethylsilsesquioxane powder 1
Phenyl-modified silicone viscosity in composition (30 ° C.): 400 mPa · s
Dimethylpolysiloxane viscosity in the composition (30 ° C.): 50 mPa · s
* 15: CIREBELLE 108 (melting point 80 to 85 ° C .: manufactured by DKSH Japan)
* 16: PH1555 HRI C. F. (Made by Toray Dow Corning)
* 17: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 18: Pearl Ream 24 (made by NOF Corporation)
(Production method)
A. Components (1) to (11) are uniformly dissolved at 100 ° C.
B. Ingredients (12) to (16) are added to A and mixed uniformly.
C. B was melted and filled in a container at 90 ° C. and solidified by cooling to obtain a solid lip gloss.
The solid lip gloss thus obtained was excellent in color retention, gloss retention, secondary adhesion-less effect, uniform finish, and stability over time.
実施例１２：固形状ファンデーション
（成分） （％）
（１）カルナウバワックス※１９ １
（２）フィッシャートロプシュワックス※１５ ４
（３）ワセリン ２
（４）リンゴ酸ジイソステアリル 残量
（５）ラウリルポリグリセリル−３ポリジメチル
シロキシエチルジメチコン※８ ３
（６）ジメチルポリシロキサン １０
（７）ジフェニルジメチコン※２ ２０
（８）フェニルトリメチコン※２０ ５
（９）スクワラン １
（１０）（ビニルジメチコン／ラウリルジメチコン）
クロスポリマー※２１ １
（１１）ラウリルＰＥＧ−９ポリジメチル
シロキシエチルジメチコン※１２ １
（１２）パラメトキシケイ皮酸２−エチルヘキシル ５
（１３）トリメチルシロキシケイ酸 ２
（１４）デカメチルシクロペンタシロキサン １０
（１５）マカデミアナッツ油脂肪酸フィトステリル ０．５
（１６）球状シリコーン末※２２ １０
（１７）メタクリル酸メチルクロスポリマー ５
（１８）ジメチルシリル化シリカ※９ １
（１９）フェノキシエタノール ０．２
（２０）トリイソステアリン酸イソプロピルチタン
２％処理酸化チタン ９
（２１）メチルハイドロゲンジメチコン２％処理ベンガラ ０．５
（２２）ジメチコン３％処理黒酸化鉄 ０．１
（２３）黄酸化鉄 ２
（２４）香料 ０．１
組成物中のフェニル変性シリコーン粘度（３０℃）：３００ｍＰａ・ｓ
組成物中のジメチルポリシロキサン粘度（３０℃）：１００ｍＰａ・ｓ
※１９：融点８０〜８６℃
※２０：ＳＨ５５６（東レ・ダウコーニング社製）
※２１：ＫＳＧ−４３（トリオクタノイン混合物：信越化学工業社製）
※２２：ＫＳＰ−３００（信越化学工業社製）
（製造方法）
Ａ．成分（１）〜（１５）を均一にて溶解する。
Ｂ．Ａに成分（１６）〜（２４）を加え、均一に混合する。
Ｃ．Ｂを容器に９０℃にて溶解して充填し、固形状ファンデーションを得た。
以上のようにして得られた固形状ファンデーションは、色持ち、二次付着レス効果、均一な仕上がり、経時安定性に優れたものであった。
Example 12: Solid foundation (component) (%)
(1) Carnauba wax * 19 1
(2) Fischer-Tropsch wax * 15 4
(3) Vaseline 2
(4) Diisostearyl malate Residual amount (5) Lauryl polyglyceryl-3 polydimethyl
Siloxyethyl dimethicone * 8 3
(6) Dimethyl polysiloxane 10
(7) Diphenyldimethicone * 2 20
(8) Phenyltrimethicone * 20 5
(9) Squalane 1
(10) (Vinyl dimethicone / lauryl dimethicone)
Cross polymer * 21 1
(11) Lauryl PEG-9 polydimethyl
Siloxyethyl dimethicone * 12 1
(12) 2-Ethylhexyl paramethoxycinnamate 5
(13) Trimethylsiloxysilicic acid 2
(14) Decamethylcyclopentasiloxane 10
(15) Macadamia nut oil fatty acid phytosteryl 0.5
(16) Spherical silicone powder * 2 2 10
(17) Methyl methacrylate crosspolymer 5
(18) Dimethylsilylated silica * 91
(19) Phenoxyethanol 0.2
(20) Isopropyl titanium triisostearate
2% treated titanium oxide 9
(21) Methyl hydrogen dimethicone 2% treated red iron oxide 0.5
(22) Dimethicone 3% treated black iron oxide 0.1
(23) Yellow iron oxide 2
(24) Perfume 0.1
Phenyl-modified silicone viscosity in composition (30 ° C.): 300 mPa · s
Dimethylpolysiloxane viscosity in the composition (30 ° C.): 100 mPa · s
* 19: Melting point 80-86 ℃
* 20: SH556 (manufactured by Toray Dow Corning)
* 21: KSG-43 (trioctanoin mixture: manufactured by Shin-Etsu Chemical Co., Ltd.)
* 22: KSP-300 (Shin-Etsu Chemical Co., Ltd.)
(Production method)
A. Components (1) to (15) are uniformly dissolved.
B. Ingredients (16) to (24) are added to A and mixed uniformly.
C. B was melted and filled in a container at 90 ° C. to obtain a solid foundation.
The solid foundation thus obtained was excellent in color retention, secondary adhesion-less effect, uniform finish, and stability over time.
実施例１３：固形状ほほ紅
（成分） （％）
（１）ポリエチレンワックス※７ ３
（２）コメヌカロウ※２３ ７
（３）トリ２−エチルヘキサン酸グリセリル 残量
（４）ラウリルポリグリセリル−３ポリジメチル
シロキシエチルジメチコン※８ １
（５）ジメチルポリシロキサン ２０
（６）ジフェニルシロキシフェニルトリメチコン※３ １０
（７）トリメチルシロキシフェニルジメチコン※１ ３０
（８）（ＰＥＧ−１５／ラウリルジメチコン）クロスポリマー※２４ ２
（９）セチル／ＰＥＧ／ＰＰＧ−１０／１ジメチコン※２５ ０．５
（１０）イソステアリン酸デキストリン※２６ ０．５
（１１）（ビニルピロリドン／ヘキサデセン）コポリマー※４ ５
（１２）ホホバ油 ０．１
（１３）赤色２２６号 ０．４
（１４）メチコン・ジメチコン３％処理黄色４号 ０．１
（１５）ジメチコン２％処理合成金雲母 ３
（１６）酸化亜鉛 ２
（１７）硫酸バリウム １
（１８）ポリアクリル酸アルキル １０
（１９）フェノキシエタノール ０．１
（２０）シリカ※１３ ０．１
組成物中のフェニル変性シリコーン粘度（３０℃）：４００ｍＰａ・ｓ
組成物中のジメチルポリシロキサン粘度（３０℃）：１０ｍＰａ・ｓ
※２３：融点７０〜８３℃
※２４：ＫＳＧ−３１０（信越化学工業社製）
※２５：ＡＢＩＬ ＥＭ９０（Ｄｅｇｕｓｓａ社製）
※２６：ユニフィルマＨＶＹ（千葉製粉社製）
（製造方法）
Ａ．成分（１）〜（１２）を均一に１００℃にて溶解する。
Ｂ．Ａに成分（１３）〜（２０）を加え、均一に混合する。
Ｃ．Ｂを樹脂皿に９０℃にて溶解充填して冷却固化し固形状ほほ紅を得た。
以上のようにして得られた固形状ほほ紅は、色持ち、ツヤ持ち、二次付着レス効果、均一な仕上がり、経時安定性に優れたものであった。
Example 13: Solid blusher (ingredient) (%)
(1) Polyethylene wax * 7 3
(2) Komenukarou * 2 3 7
(3) Glyceryl tri-2-ethylhexanoate Remaining amount (4) Lauryl polyglyceryl-3 polydimethyl
Siloxyethyl dimethicone * 81
(5) Dimethyl polysiloxane 20
(6) Diphenylsiloxyphenyltrimethicone * 3 10
(7) Trimethylsiloxyphenyl dimethicone * 1 30
(8) (PEG-15 / lauryl dimethicone) crosspolymer * 24 2
(9) Cetyl / PEG / PPG-10 / 1 Dimethicone * 25 0.5
(10) Dextrin isostearate * 26 0.5
(11) (Vinylpyrrolidone / hexadecene) Copolymer * 45
(12) Jojoba oil 0.1
(13) Red No. 226 0.4
(14) Methicone / Dimethicone 3% treated Yellow No. 4 0.1
(15) Dimethicone 2% treated synthetic phlogopite 3
(16) Zinc oxide 2
(17) Barium sulfate 1
(18) Polyalkyl acrylate 10
(19) Phenoxyethanol 0.1
(20) Silica * 13 0.1
Phenyl-modified silicone viscosity in composition (30 ° C.): 400 mPa · s
Dimethylpolysiloxane viscosity in the composition (30 ° C.): 10 mPa · s
* 23: Melting point 70-83 ° C
* 24: KSG-310 (produced by Shin-Etsu Chemical Co., Ltd.)
* 25: ABIL EM90 (manufactured by Degussa)
* 26: Unifilma HVY (Chiba Flour Milling Co.)
(Production method)
A. Components (1) to (12) are uniformly dissolved at 100 ° C.
B. Ingredients (13) to (20) are added to A and mixed uniformly.
C. B was melted and filled in a resin dish at 90 ° C., cooled and solidified to obtain a solid blusher.
The solid blusher thus obtained was excellent in color retention, gloss retention, secondary adhesion-less effect, uniform finish, and stability over time.
実施例１４：固形状アイカラー
（成分） （％）
（１）キャンデリラワックス※１１ ５
（２）カルナウバワックス※１９ ５
（３）トリイソステアリン酸ポリグリセリル−２ ３
（４）スクワラン 残量
（５）ラウリルポリグリセリル−３ポリジメチル
シロキシエチルジメチコン※８ １
（６）セスキイソステアリン酸ソルビタン １
（７）ジメチルポリシロキサン １０
（８）フェニルトリメチコン※２０ １５
（９）トリメチルシロキシフェニルジメチコン※１ １０
（１０）（ジメチコン／（ＰＥＧ−１０／１５））クロスポリマー※２７
３
（１１）ビス−セチルＰＥＧ／ＰＰＧ−１４／１４ジメチコン※２８ ０．１
（１２）ジ水添ロジンダイマージリノレイル※２９ ４
（１３）トリメチルシロキシケイ酸 ２
（１４）ジブチルヒドロキシトルエン ０．０１
（１５）パラオキシ安息香酸メチル ０．１
（１６）天然ビタミンＥ ０．１
（１７）青色１号 ０．５
（１８）赤色２０２号 ０．１
（１９）ジメチコン処理３％ベンガラ ０．５
（２０）架橋型シリコーン・網状型シリコーンブロック共重合体 ３
（２１）ポリエチレンテレフタレート・アルミニウム・エポキシ積層末 ５
（２２）雲母チタン ５
（２３）パーフルオロオクチルトリエトキシシラン５％処理
酸化チタン被覆ガラス末 ５
（２４）酸化チタン被覆合成マイカ １０
（２５）ジステアルジモニウムヘクトライト ２
（２６）シリカ※１４ １
組成物中のフェニル変性シリコーン粘度（３０℃）：３００ｍＰａ・ｓ
組成物中のジメチルポリシロキサン粘度（３０℃）：１０ｍＰａ・ｓ
※２７：ＫＳＧ−２１０（信越化学工業社製）
※２８：ＡＢＩＬ ＥＭ９７（Ｄｅｇｕｓｓａ社製）
※２９：ＬＵＳＰＬＡＮ ＤＤ−ＤＨＲ（日本精化社製）
（製造方法）
Ａ．成分（１）〜（１４）を均一に９０℃にて溶解する。
Ｂ．Ａに成分（１５）〜（２６）を加え、均一に混合、分散する。
Ｃ．Ｂを容器に８５℃にて充填して冷却し固形状アイカラーを得た。
以上のようにして得られた固形状アイカラーは、色持ち、ツヤ持ち、二次付着レス効果、均一な仕上がり、経時安定性に優れたものであった。
Example 14: Solid eye color (component) (%)
(1) Candelilla wax * 115
(2) Carnauba wax * 195
(3) Polyglyceryl-2 3 triisostearate
(4) Squalane remaining amount (5) Lauryl polyglyceryl-3 polydimethyl
Siloxyethyl dimethicone * 81
(6) Sorbitan sesquiisostearate 1
(7) Dimethyl polysiloxane 10
(8) Phenyltrimethicone * 20 15
(9) Trimethylsiloxyphenyl dimethicone * 1 10
(10) (Dimethicone / (PEG-10 / 15)) Crosspolymer * 27
Three
(11) Bis-cetyl PEG / PPG-14 / 14 dimethicone * 28 0.1
(12) Di-hydrogenated rosin dimer ginolinole * 29 4
(13) Trimethylsiloxysilicic acid 2
(14) Dibutylhydroxytoluene 0.01
(15) Methyl paraoxybenzoate 0.1
(16) Natural Vitamin E 0.1
(17) Blue No. 1 0.5
(18) Red No. 202 0.1
(19) Dimethicone treatment 3% red iron oxide 0.5
(20) Crosslinked silicone / reticular silicone block copolymer 3
(21) Polyethylene terephthalate / aluminum / epoxy laminated powder 5
(22) Mica titanium 5
(23) 5% treatment with perfluorooctyltriethoxysilane
Titanium oxide coated glass powder 5
(24) Titanium oxide coated synthetic mica 10
(25) Disteardimonium hectorite 2
(26) Silica * 14 1
Phenyl-modified silicone viscosity in composition (30 ° C.): 300 mPa · s
Dimethylpolysiloxane viscosity in the composition (30 ° C.): 10 mPa · s
* 27: KSG-210 (produced by Shin-Etsu Chemical Co., Ltd.)
* 28: ABIL EM97 (manufactured by Degussa)
* 29: LUSPLAN DD-DHR (Nippon Seika Co., Ltd.)
(Production method)
A. Components (1) to (14) are uniformly dissolved at 90 ° C.
B. Ingredients (15) to (26) are added to A and mixed and dispersed uniformly.
C. B was filled in a container at 85 ° C. and cooled to obtain a solid eye color.
The solid eye color obtained as described above was excellent in color retention, gloss retention, secondary adhesion-less effect, uniform finish, and stability over time.
Claims (6)
（Ａ）フェニル変性シリコーン
（Ｂ）ジメチルポリシロキサン
（Ｃ）煙霧状粉体
（Ｄ）炭化水素油およびエステル油から選ばれる１種または２種以上の油剤
（Ｅ）ワックス
（Ｆ）着色剤
を含有する油性固形メークアップ化粧料であって、成分（Ａ）及び（Ｂ）を化粧料中に合計で３５〜７５質量％含有し、成分（Ａ）、（Ｂ）及び（Ｄ）の混合物が３０℃で３相に分離し、前記成分（Ａ）のフェニル変性シリコーンの粘度が３０℃において３００ｍＰａ・ｓ〜１０００ｍＰａ・ｓである油性固形メークアップ化粧料。 The following components (A) (B) (C) (D) (E) and (F)
(A) Phenyl-modified silicone (B) Dimethylpolysiloxane (C) Fume-like powder (D) One or more oil agents (E) Wax (F) Colorant selected from hydrocarbon oil and ester oil An oily solid make-up cosmetic which comprises 35 to 75% by mass of the components (A) and (B) in total, and the mixture of the components (A), (B) and (D) is 30%. An oily solid make-up cosmetic composition which is separated into three phases at 0 ° C. and has a viscosity of 300 mPa · s to 1000 mPa · s at 30 ° C. of the phenyl-modified silicone as the component (A) .
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