JP6675275B2 - Liquid detergent composition for textile products - Google Patents

Description

  The present invention relates to a liquid detergent composition.

Conventionally, as a method of drying the items to be washed after washing, `` outdoor drying '' of drying the items to dry outside has been performed, but in recent years, due to concerns about air pollution and changes in lifestyle, indoors "Room drying", in which clothes are dried and dried, has been performed.
However, there is a problem that, when the object to be washed is dried in a room, a soft and voluminous tactile sensation which can be obtained by drying outside and a dry tactile sensation cannot be obtained at the same time.
Conventionally, detergents containing softeners have been used to impart a soft touch to the items to be washed. For example, detergent products containing a cationic surfactant such as amidoamine or a quaternary ammonium salt have been put on the market. Have been. However, they are insufficient in providing a soft and voluminous feel.
Patent Literature 1 discloses a detergent containing water-insoluble silicone and cationic cellulose and having improved flexibility. However, the detergent disclosed in Patent Literature 1 can enhance a soft and voluminous feel, but at the same time imparts a moist feel, and thus has a problem that it is difficult to recall a dry feel.
In addition, detergents are required to have good defoaming properties (defoaming property), moderate viscosity (usability) that is easy to use, and an effect of suppressing malodor (deodorizing property). Not.

JP-T-2005-537408

  The present invention has been made in view of the above circumstances, and can simultaneously impart a soft and voluminous tactile sensation and a dry touch, and is excellent in usability, defoaming properties, and deodorant liquid detergent. For the composition.

［式中、Ｒ^１、Ｒ^２は、それぞれ独立して炭素数１〜３のアルキル基または炭素数１〜３のヒドロキシアルキル基であり、Ｘ⁻は対イオンである。］

［式中、Ｒ^３、Ｒ^４は、それぞれ独立して炭素数１〜３のアルキル基または炭素数１〜３のヒドロキシアルキル基であり、Ｘ⁻は対イオンである。］

［式中、Ｒ^５は、水素原子または炭素数１〜３のアルキル基であり、Ｒ^６、Ｒ^７は、それぞれ独立して、水素原子または炭素数１〜３のアルキル基もしくは炭素数１〜３のヒドロキシアルキル基である。］

［式中、Ｒ^１１〜Ｒ^１３は、それぞれ独立に水素原子又は炭素数１〜３のアルキル基であり、Ｒ^１４は、水素原子又はアセチル基である。］

［式中、Ｒ^１５は、炭素数１〜６のアルキル基、又はフェニル基であり、ｎは０〜１０であり、ｍは０〜１０であり、ｎ＋ｍ＞０である。］
［２］さらに、（Ｄ）成分：炭素数８〜２２の脂肪酸、及びその塩からなる群から選択される少なくとも１種を含む、［１］に記載の液体洗浄剤組成物。
［３］さらに（Ｅ）成分：下記一般式（ｅ−１）で表されるモノマーから誘導された繰り返し単位、及び下記一般式（ｅ−２）で表されるモノマーから誘導された繰り返し単位からなる群から選択される少なくとも１種の繰り返し単位を有するポリマーを含む、［１］又は［２］に記載の液体洗浄剤組成物。

［式（ｅ−１）中、Ｒ^５１は水素原子又はメチル基であり、Ｒ^５２は水素原子である。
式（ｅ−２）中、Ｒ^５３は水素原子又はメチル基であり、Ｒ^５４は炭素数１〜４０のアルキル基である。］
［４］さらにカプセル香料を含む、［１］〜［３］のいずれか一項に記載の液体洗浄剤組成物。
［５］さらにノニオン界面活性剤を含む、［１］〜［４］のいずれか一項に記載の液体洗浄剤組成物。 Means for Solving the Problems As a result of intensive studies, the present inventors have found that the following liquid detergent composition can solve the above-mentioned problems.
That is, the present invention has the following aspects.
[1] Component (A): an anionic surfactant excluding a fatty acid salt having 8 to 22 carbon atoms;
(B) component: at least one type of repeating unit selected from the group consisting of a repeating unit represented by the following general formula (b-1) and a repeating unit represented by the following general formula (b-2); A polymer having a repeating unit represented by the following general formula (b-3);
Component (C): a liquid containing a compound represented by the following general formula (c-1) and at least one compound selected from the group consisting of compounds represented by the following general formula (c-2) Detergent composition.

[Wherein, R ¹ and R ² are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁻ is a counter ion. ]

[Wherein, R ³ and R ⁴ are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁻ is a counter ion. ]

[Wherein, R ⁵ is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R ⁶ and R ⁷ are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms or 1 to 3 carbon atoms. 3 is a hydroxyalkyl group. ]

[Wherein, R ^{11 to} R ¹³ are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R ¹⁴ is a hydrogen atom or an acetyl group. ]

[Wherein, R ¹⁵ is an alkyl group having 1 to 6 carbon atoms or a phenyl group, n is 0 to 10, m is 0 to 10, and n + m> 0. ]
[2] The liquid detergent composition according to [1], further comprising (D) component: at least one selected from the group consisting of fatty acids having 8 to 22 carbon atoms and salts thereof.
[3] Component (E): From a repeating unit derived from a monomer represented by the following general formula (e-1) and a repeating unit derived from a monomer represented by the following general formula (e-2) The liquid detergent composition according to [1] or [2], comprising a polymer having at least one type of repeating unit selected from the group consisting of:

[In the formula (e-1), R ⁵¹ is a hydrogen atom or a methyl group, and R ⁵² is a hydrogen atom.
In the formula (e-2), R ⁵³ is a hydrogen atom or a methyl group, and R ⁵⁴ is an alkyl group having 1 to 40 carbon atoms. ]
[4] The liquid detergent composition according to any one of [1] to [3], further comprising a capsule flavor.
[5] The liquid detergent composition according to any one of [1] to [4], further comprising a nonionic surfactant.

  ADVANTAGE OF THE INVENTION According to this invention, while being able to provide the soft tactile sensation which is fluffy at the same time, and the tactile sensation which was very dry, the usability, defoaming property, and the liquid detergent composition excellent in the deodorant property can be provided. .

The liquid detergent composition of the present invention contains the following components (A) to (C).
<(A) component: anionic surfactant except fatty acid salt having 8 to 22 carbon atoms>
The component (A) is an anionic surfactant excluding a fatty acid salt having 8 to 22 carbon atoms. The component (A) is used for imparting detergency to the liquid detergent composition. Here, the fatty acid salt having 8 to 22 carbon atoms means a salt of a fatty acid having 8 to 22 carbon atoms.

As the component (A), an anionic surfactant commonly used in detergents for clothing and the like can be used.
As the component (A), for example, linear alkylbenzene sulfonic acid or a salt thereof; α-olefin sulfonate; linear or branched alkyl sulfate, alkyl ether sulfate or alkenyl ether sulfate, alkyl group Α-sulfofatty acid ester salts; carboxylic acid types such as alkyl ether carboxylate, polyoxyalkylene ether carboxylate, alkyl (or alkenyl) amide ether carboxylate, acylamino carboxylate, etc. Anionic surfactants; phosphate ester-type anion fields such as alkyl phosphate ester salts, polyoxyalkylene alkyl phosphate ester salts, polyoxyalkylene alkyl phenyl phosphate ester salts, and glycerin fatty acid ester monophosphate ester salts; Surfactants and the like.
Examples of these salts include alkali metal salts such as sodium and potassium, alkaline earth metal salts such as magnesium, and alkanolamine salts such as monoethanolamine salt and diethanolamine salt.

Among the above, as the linear alkylbenzene sulfonic acid or a salt thereof, a linear alkyl group having 8 to 16 carbon atoms is preferable, and one having 10 to 14 carbon atoms is particularly preferable.
As the α-olefin sulfonate, those having 10 to 20 carbon atoms are preferable.
The alkyl sulfate salt preferably has 10 to 20 carbon atoms.
The alkyl ether sulfate or alkenyl ether sulfate has a linear or branched alkyl or alkenyl group having 10 to 20 carbon atoms, and has an average of 1 to 10 moles of ethylene oxide and an average of 0 to 6 moles. A polyoxyalkylene alkyl ether sulfate or a polyoxyalkylene alkenyl ether sulfate to which propylene oxide is added is preferred. When the polyoxyalkylene alkyl ether sulfate or the polyoxyalkylene alkenyl ether sulfate is an adduct to which both ethylene oxide and propylene oxide are added, the method of adding ethylene oxide and propylene oxide is not particularly limited. For example, random addition or block addition may be used. As a block addition method, for example, a method of adding propylene oxide after adding ethylene oxide, a method of adding ethylene oxide after adding propylene oxide, a method of adding propylene oxide after adding ethylene oxide, and further adding ethylene oxide And the like.
As the alkane sulfonate, those having 10 to 20 carbon atoms are preferable, and those having 14 to 17 carbon atoms are more preferable. Further, a secondary alkanesulfonic acid salt in which the alkyl group is a secondary alkyl group is preferable.
As the α-sulfofatty acid ester salt, a compound represented by the following formula (a-1) is preferable.
_{^{R 23 CH (SO 3 M)}} COOR 24 ··· (a-1)
(In the formula (a-1), R ²³ is a hydrocarbon group having 8 to 18 carbon atoms, R ²⁴ is a hydrocarbon group having 1 to 6 carbon atoms, and M is a counter ion.)
In the above formula ^(a-1), the carbon number of the hydrocarbon group ^{R 23} is 8-18. That is, the carbon number of the fatty acid residue of the α-sulfofatty acid ester salt is 10 to 20.

The hydrocarbon group for R ²³ may be linear, branched, or include a cyclic structure. The hydrocarbon group for R ²³ is preferably an aliphatic hydrocarbon group, more preferably a linear or branched alkyl group, or a linear or branched alkenyl group, and more preferably a linear alkyl group. Groups or linear alkenyl groups are more preferred.

In the formula (a-1), R ²⁴ has 1 to 6 carbon atoms, and preferably 1 to 3 carbon atoms.
The hydrocarbon group for R ²⁴ may be linear, branched, or may have a cyclic structure. The hydrocarbon group for R ²⁴ is preferably an aliphatic hydrocarbon group, more preferably a linear or branched alkyl group, or a linear or branched alkenyl group, and more preferably a linear alkyl group. Groups or branched alkyl groups are more preferred.
As R ²⁴ , a methyl group, an ethyl group, an n-propyl group, an isopropyl group and the like are preferable, a methyl group, an ethyl group and an n-propyl group are preferable, and a methyl group is particularly preferable.

In the formula (a-1), as the counter ion of M, those capable of forming a water-soluble salt with R ²³ CH (COOR ²⁴ ) SO ₃ ^— are preferable, for example, an alkali metal ion, a protonated amine, and an ammonium ion And the like. Examples of the alkali metal that can be the counter ion include sodium and the like. Examples of the amine that can be the counter ion include primary to tertiary amines. The amine preferably has 1 to 6 carbon atoms in total. Further, the amine may have a hydroxy group. The amine preferably has a hydroxy group, since the solubility of the α-sulfofatty acid ester salt in water increases. Examples of the amine having a hydroxy group include alkanolamines, and the alkanol group preferably has 1 to 3 carbon atoms. Examples of the alkanolamine include monoethanolamine, diethanolamine, and triethanolamine.
M is preferably an alkali metal ion, and particularly preferably a sodium ion, from the viewpoint that it is easily available and that the low-temperature stability of the liquid detergent is more easily increased.
As the α-sulfofatty acid ester salt, R ²³ in the above formula (a-1) is a linear or branched alkyl group having 14 to 16 carbon atoms, or a linear or branched alkenyl group. And a compound wherein R ²⁴ is a methyl group is particularly preferred.

  Among these, straight-chain alkylbenzene sulfonic acid or a salt thereof, α-olefin sulfonate, polyoxyethylene alkyl ether sulfate, alkane sulfonate are preferable because of excellent handling properties and anti-redeposition property. Alkylbenzene sulfonic acid or a salt thereof is particularly preferred.

As the component (A), one type may be used alone, or two or more types may be used in combination.
The content of the component (A) is preferably from 2 to 20% by mass, more preferably from 5 to 15% by mass, and still more preferably from 10 to 12% by mass, based on the total mass of the liquid detergent composition. When the content of the component (A) is at most the above upper limit, defoaming properties and usability (at low temperatures in winter) are good, and when it is at least at the above lower limit, it is dry and creepy. The fibers can have a soft and voluminous feel while maintaining the tactile sensation, and have good deodorant properties.

<Component (B): at least one type of repeating unit selected from the group consisting of a repeating unit represented by general formula (b-1) and a repeating unit represented by general formula (b-2); Polymer having a repeating unit represented by the formula (b-3)>
The component (B) includes at least one repeating unit selected from the group consisting of a repeating unit represented by the following general formula (b-1) and a repeating unit represented by the following general formula (b-2). And a repeating unit represented by the following general formula (b-3). By containing the component (B), the liquid detergent composition of the present invention can impart a soft, voluminous touch and a dry touch to an object to be washed after washing.

[Wherein, R ¹ and R ² are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁻ is a counter ion. ]

[Wherein, R ³ and R ⁴ are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁻ is a counter ion. ]

[Wherein, R ⁵ is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R ⁶ and R ⁷ are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms or 1 to 3 carbon atoms. 3 is a hydroxyalkyl group. ]

  The repeating unit represented by the general formula (b-1) and the repeating unit represented by the general formula (b-2) are each a dialkyldiallylammonium salt represented by the following general formula (b-4) It is a repeating unit derived from a monomer.

[Wherein, R ⁸ and R ⁹ are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁻ is a counter ion. ]

In the above general formulas (b-1), (b-2) and (b-4), X ⁻ represents a halogen ion such as a chloride ion or a bromine ion, an inorganic acid ion such as a sulfate ion, a nitrate ion or a sulfite ion; Organic acid ions such as methylsulfate ion, acetate ion and lactate ion are exemplified.

  The component (B) generally has a weight average molecular weight of 1,000 to 5,000,000, preferably 3,000 to 2,000,000, and more preferably 10,000 to 2,000,000. The weight average molecular weight in the present specification means a value determined by gel permeation chromatography (GPC) using polyethylene glycol as a standard substance.

The form of polymerization of the component (B) is not particularly limited, and may be any of block polymerization, random polymerization, and graft polymerization.
In the component (B), the content ratio of the repeating unit represented by (b-1) and the repeating unit represented by (b-2) to the repeating unit represented by (b-3) is particularly limited. However, the molar ratio of the repeating unit represented by (b-1) and the repeating unit represented by (b-2) to the repeating unit represented by (b-3) is [(b- Repeating unit represented by 1) and repeating unit represented by (b-2)]: repeating unit represented by (b-3) = 1: 9-7: 3, preferably 2: 8-6 : 4 is more preferable.

At least one repeating unit selected from the group consisting of a repeating unit represented by the general formula (b-1) and a repeating unit represented by the general formula (b-2); Examples of the polymer having the repeating unit represented by -3) include diallyldimethylammonium chloride / acrylamide copolymer, diallyldimethylammonium chloride / acrylamide / acrylic acid terpolymer, and the like.
As these polymers, synthetic products or commercially available products may be used.

  The polymer is not particularly limited, but can be produced by ordinary radical polymerization. For example, it can be produced by polymerizing monomers constituting the component (B) such as diallyldimethylammonium chloride and acrylamide by a polymerization method such as bulk polymerization, solution polymerization, emulsion polymerization and suspension polymerization. In the case of polymerization, it is preferable to use a polymerization initiator used for ordinary radical polymerization, for example, benzoyl peroxide, peroxides such as potassium persulfate, azobisisobutyronitrile, azobiscyanovaleric acid And the like.

Commercially available products of the copolymer include, for example, brand names “Mercoat 550”, “Mercoat 740”, “Mercoat 2200”, and “Noverite 300”, “Noverite 302”, etc., manufactured by Lubrizol.
Examples of commercially available terpolymers include “Mercoat 3330” and “Mercoat 3940” (trade names, manufactured by Lubrizol).
These components (B) may be used alone or in combination of two or more.

  The content of the component (B) is preferably from 0.05 to 1% by mass, more preferably from 0.1 to 0.4% by mass, and preferably from 0.2 to 0.4% by mass, based on the total mass of the liquid detergent composition. 3% by mass is more preferred. When the content of the component (B) is equal to or less than the above upper limit, the defoaming property and usability (at low temperature in winter) are good, and when the content is equal to or more than the above lower limit, it is dry and creepy. A soft and voluminous texture can be imparted to the fiber while maintaining the texture.

<Component (C): at least one compound selected from the group consisting of compounds represented by general formula (c-1) and compounds represented by general formula (c-2)>
The component (C) includes a compound represented by the following general formula (c-1) (hereinafter, also referred to as “component (c-1)”) and a compound represented by the following general formula (c-2) (hereinafter, referred to as “component (c-1)”). , "(C-2) component"). The liquid detergent composition of the present invention can improve the defoaming property and the usability by containing the component (C).

[Wherein, R ^{11 to} R ¹³ are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R ¹⁴ is a hydrogen atom or an acetyl group. ]

[Wherein, R ¹⁵ is an alkyl group having 1 to 6 carbon atoms or a phenyl group, n is 0 to 10, m is 0 to 10, and n + m> 0. ]

In the formula (c-1), all of R ^{11 to} R ¹³ are hydrogen atoms, or one is an alkyl group and the other two are hydrogen atoms, that is, among R ^{11 to} R ¹³ , Preferably, two or more are hydrogen atoms. When two or more of R ^{11 to} R ¹³ are hydrogen atoms, film formation and gelation can be prevented more favorably even if the film is left in an open system.
When any one of R ^{11 to} R ¹³ is an alkyl group, the alkyl group preferably has 1 to 2 carbon atoms, and more preferably 1 carbon atom. When the number of carbon atoms of R ^{11 to} R ¹³ is within the above range, even if the carbon is left in an open system, the formation of a film and the formation of a gel can be prevented more favorably.
R ¹⁴ is preferably a hydrogen atom from the viewpoint of better preventing film formation and gelling even when left in an open system.

As the component (c-1), 3-methoxybutanol, 3-methoxy-3-methylbutanol, 3-methoxy-3-ethylbutanol, 3-methoxy-3-propylbutanol, 3-methoxy-2-methylbutanol, 3-methoxy-2-ethylbutanol, 3-methoxy-2-propylbutanol, 3-methoxy-1-methylbutanol, 3-methoxy-1-ethylbutanol, 3-methoxy-1-propylbutanol and the like, the formula (c- 1) those ^{wherein R 14} is a hydrogen atom in; 3-methoxybutyl acetate, 3-methoxy-3-methylbutyl acetate, 3-methoxy-3-ethyl butyl acetate, 3-methoxy-3-propyl-butyl acetate, 3 -Methoxy-2-methylbutyl acetate, 3-methoxy-2-ethylbutyl acetate, R in the formula (c-1) such as 3-methoxy-2-propylbutyl acetate, 3-methoxy-1-methylbutyl acetate, 3-methoxy-1-ethylbutyl acetate, 3-methoxy-1-propylbutyl acetate, etc. Those in which ¹⁴ is an acetyl group are fisted. Above all, as the component (c-1), 3-methoxybutanol, 3-methoxy-3-methylbutanol, 3-methoxy-2-methylbutanol, 3-methoxy-1-methylbutanol, 3-methoxy-3-methyl Butyl acetate is preferred, and 3-methoxy-3-methylbutanol is more preferred.
These components (c-1) may be used alone or in combination of two or more.

In the formula (c-2), m is 0 to 10, and preferably 1 to 5. n is 0-10, preferably 0-5. m + n is more than 0, 1 to 20, preferably 2 to 5, and more preferably 2.
The component (c-2) includes diethylene glycol monopropyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monobutyl ether (butyl carbitol), propylene glycol diethylene glycol monobutyl ether, and dipropylene glycol ethylene glycol monobutyl ether. Ter, diethylene glycol monoisobutyl ether, propylene glycol diethylene glycol monoisobutyl ether, dipropylene glycol ethylene glycol monoisobutyl ether, diethylene glycol mono-s-butyl ether, propylene glycol diethylene glycol mono -S-butyl ether, dipropylene glycol ethylene glycol mono-s-butyl ether, diethylene glycol -T-butyl ether, propylene glycol diethylene glycol mono-t-butyl ether, dipropylene glycol ethylene glycol mono-t-butyl ether, triethylene glycol monopentyl ether, tetraethylene glycol monopentyl ether , Pentaethylene glycol monopentyl ether, pentaethylene glycol propylene glycol monopentyl ether, triethylene glycol mono isopentyl ether, tetraethylene glycol mono isopentyl ether, pentaethylene glycol mono isopentyl ether, pentaethylene glycol propylene glycol mono isopentyl ether , Triethylene glycol monocyclopentyl ether, tetraethylene glycol monocyclopentyl Ether, pentaethylene glycol propylene glycol monocyclopentyl ether, triethylene glycol monohexyl ether, tetraethylene glycol monohexyl ether, pentaethylene glycol monohexyl ether, hexaethylene glycol propylene glycol monohexyl ether, triethylene glycol mono (1,3- Dimethyl butyl) ether, tetraethylene glycol mono (1,3-dimethylbutyl) ether, pentaethylene glycol mono (1,3-dimethylbutyl) ether, hexaethylene glycol propylene glycol mono (1,3-dimethylbutyl) ether, Ethylene glycol monocyclohexyl ether, tetraethylene glycol monocyclohexyl ether, penta Examples thereof include ethylene glycol monocyclohexyl ether, hexaethylene glycol propylene glycol monocyclohexyl ether, diethylene glycol monophenyl ether, and triethylene glycol monophenyl ether.
These components (c-2) may be used alone or in combination of two or more.

  The content of the component (C) is preferably 0.1 to 15% by mass, more preferably 4 to 10% by mass, and still more preferably 6 to 8% by mass, based on the total mass of the liquid detergent composition. When the content of the component (C) is equal to or less than the upper limit, the defoaming property is easily improved. When the content of the component (C) is equal to or more than the above lower limit, usability (at low temperature in winter) is easily improved.

<Optional components>
If necessary, the liquid detergent composition of the present invention can contain components other than the above-mentioned components (A) to (C) as long as the effects of the present invention are not impaired. At least one selected from the group consisting of 8 to 22 fatty acids and salts thereof, polymers other than the component (B), microcapsules, water-miscible organic solvents, solvents, nonionic surfactants, amphoteric surfactants, metal ions Capture agents (chelating agents), inorganic salts, antioxidants, enzymes such as proteases, lipases, cellulases, texture improvers other than component (B), alkali builders such as alkanolamines, hydrotropes, silicone compounds, storage stability Includes enhancers, preservatives, fluorescent agents, dye transfer inhibitors, anti-staining agents, pearlescent agents, soil release agents, flavoring agents, coloring agents, emulsions, extracts of natural products, pH adjusters, etc. It is.

The liquid detergent composition of the present invention may contain at least one selected from the group consisting of fatty acids having 8 to 22 carbon atoms and salts thereof (hereinafter, also referred to as component (D)).
The liquid detergent composition of the present invention can improve the defoaming property and the usability by containing the component (D).
As the component (D), a fatty acid having 10 to 20 carbon atoms or a salt thereof is preferable. For example, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, hydroxystearic acid, oleic acid, Single fatty acids such as behenic acid or salts thereof, coconut oil fatty acids, mixed fatty acids such as tallow fatty acids and salts thereof, and the like. Among them, coconut fatty acids containing lauric acid, myristic acid, and palmitic acid or salts thereof are preferable.
Examples of the salt of a fatty acid include salts of the above fatty acids with alkali metals such as sodium and potassium; ammonium salts, monoethanolamine salts, diethanolamine salts, triethanolamine salts, 2-amino-2-methylpropanol salts, 2-amino- Salts with alkanolamines such as 2-methylpropanediol; salts with basic amino acids such as lysine and arginine.

As the component (D), one type may be used alone, or two or more types may be used in combination.
The content of the component (D) is preferably 1 to 8% by mass, more preferably 3 to 6% by mass, and still more preferably 4 to 5% by mass, based on the total mass of the liquid detergent composition. When the content of the component (D) is equal to or more than the lower limit, the defoaming property is easily improved.

  As the polymer other than the component (B), a repeating unit derived from a monomer represented by the following general formula (e-1) (hereinafter, also referred to as “monomer (e1)”), and a polymer represented by the following general formula (e- Polymer having one or more kinds of repeating units selected from repeating units derived from the monomer represented by 2) (hereinafter also referred to as “monomer (e2)”) (hereinafter also referred to as “component (E)”) Is mentioned. The liquid detergent composition of the present invention easily improves usability by containing the component (E).

式（ｅ−１）中、Ｒ^５１は水素原子又はメチル基であり、Ｒ^５２は水素原子である。
式（ｅ−２）中、Ｒ^５３は水素原子又はメチル基であり、Ｒ^５４は炭素数１〜４０のアルキル基である。

In the formula (e-1), R ⁵¹ is a hydrogen atom or a methyl group, and R ⁵² is a hydrogen atom.
In the formula (e-2), R ⁵³ is a hydrogen atom or a methyl group, and R ⁵⁴ is an alkyl group having 1 to 40 carbon atoms.

(Monomer (e1))
Examples of the monomer (e1) include acrylic acid and methacrylic acid.
In the component (E), as the monomer (e1), one type may be used alone, or two types may be used in combination.

(Monomer (e2))
The alkyl group for R ⁵⁴ may be linear or branched, and may have a cyclic structure.
The carbon number of the alkyl group of R ⁵⁴ is 1 to 40, preferably from 1 to 20, 1 to 10 is more preferable.

Examples of the monomer (e2) include acrylic esters such as methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, octyl acrylate, decyl acrylate, dodecyl acrylate, and icosyl acrylate; Examples include methacrylates such as methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, n-butyl methacrylate, decyl methacrylate, dodecyl methacrylate, and icosyl methacrylate.
As the monomer (e2), an acrylate ester is preferable.
In the component (E), as the monomer (e2), one type may be used alone, or two or more types may be used in combination.

The component (E) is preferably crosslinked. The component (E) may not be crosslinked.
Examples of the cross-linked copolymer as the component (E) include those cross-linked by a cross-linking agent (polymer cross-linked product).
Examples of the crosslinking agent include an allyl ether compound.

Examples of the allyl ether compound include allyl ether, allyl ether of sugar, allyl ether of sugar alcohol, and the like.
Examples of the sugar in the sugar allyl ether include sucrose and the like.
Examples of the sugar alcohol in the allyl ether of the sugar alcohol include pentaerythritol and the like.

Examples of commercially available products of the component (E) include the following.
Commercial products of the crosslinked type (E) component include, for example, a product name of a crosslinked copolymer composed of two or more monomers selected from alkyl acrylate, alkyl methacrylate, acrylic acid and methacrylic acid manufactured by Lubrizol. "Carbopol Aqua30", a crosslinked copolymer comprising two or more monomers selected from the group consisting of alkyl acrylates (C1 to C4 and C8), alkyl methacrylates (C1 to C4 and C8), acrylic acid and methacrylic acid manufactured by Lubrizol. “Carbopol Aqua SF-1”, a crosslinked copolymer composed of two or more monomers selected from the group consisting of alkyl acrylates (C10 to 30), alkyl methacrylates (C10 to 30) and acrylic acid manufactured by Lubrizol Is the product name "Carbopol EZ -4 ", a product name of" ACUSOL "which is a cross-linked copolymer composed of monomers of alkyl acrylate and acrylic acid or methacrylic acid manufactured by DOW.
830 "and the like.
As the non-crosslinked type (E) component, for example, a product name “Novethix HC200” which is a copolymer made of two or more kinds of monomers selected from alkyl acrylate, alkyl methacrylate, acrylic acid and methacrylic acid manufactured by Lubrizol. And the like.

  As the component (E), one type may be used alone, or two or more types may be used in combination.

The microcapsules are composed of a core material and a wall material covering the core material. Microcapsules are used for the purpose of imparting various functions, and as core substances, flavors, essential oils, whitening agents, insect repellents, silicones, waxes, flavors, vitamins, skin care agents, enzymes, probiotics, dyes, It may contain a pigment, a perfume precursor, a cooling agent, a warming agent, an attractant such as a pheromone, an antibacterial agent, a bleaching agent and the like. As the components of such a core substance, components well known in the technical field of the present invention can be used.
The microcapsules may be used alone or in a combination of two or more. The microcapsules can be appropriately selected from commercially available products according to the purpose, and specific examples include the following.
Specific examples of the microcapsules containing a fragrance as a core substance, that is, Popscent BLUEFLOWERPOP “MHN2814” manufactured by Filmenich, MechaCaps Cosmic1, AURORACAPPS manufactured by Givaudan, UNICAP 101 manufactured by IFFF, and UNICAP503, etc. .
When the microcapsule is a capsule flavor, the flavor used as the core substance in the capsule flavor may be any one used in the field of liquid detergent without any particular limitation, and may be appropriately selected according to the purpose. Examples of the components of the included perfume include the perfume compositions shown in Table 1 below.

The wall material of the microcapsule is composed of a polymer material, and a material generally used for a capsule contained in a liquid detergent for fabric, a softener, or the like can be used. Examples of the wall material include natural polymers such as gelatin and agar, oily film-forming materials such as oils and fats, and synthetic polymer materials such as polyacrylic acid, polyvinyl, polymethacrylic acid, melamine, and urethane. These can be used alone or in combination of two or more. The wall material is preferably an aminoplast polymer made of a melamine-formaldehyde resin or a urea-formaldehyde resin, a polyacrylic acid-based or polymethacrylic acid-based polymer, from the viewpoint of fragrance when the capsule is broken.
The liquid detergent composition of the present invention can easily improve deodorant properties by containing a capsule flavor. These may be used alone or in combination of two or more.

The average particle size of the capsule flavor is preferably 1 to 50 μm, more preferably 5 to 40 μm, and still more preferably 10 to 25 μm.
The average particle size of the capsule flavor is a value measured by a laser diffraction / scattering method.
The content of the capsule flavor is preferably from 0.01 to 0.4% by mass, more preferably from 0.05 to 0.4% by mass, and more preferably from 0.1 to 0.4% by mass, based on the total mass of the liquid detergent composition. 2% by mass is more preferred. When the capsule flavor is not less than the lower limit, the deodorizing performance is good.

  As the nonionic surfactant (hereinafter, also referred to as the component (F)), any nonionic surfactant may be used as long as it is conventionally used in liquid detergents. For example, polyoxyalkylene nonionic surfactants, alkylphenols, higher amines and the like can be used. Alkylene oxide adduct, polyoxyethylene polyoxypropylene block copolymer, fatty acid alkanolamine, fatty acid alkanolamide, polyhydric alcohol fatty acid ester or alkylene oxide adduct thereof, polyhydric alcohol fatty acid ether, alkyl (or alkenyl) amine oxide, cured castor Examples include oil alkylene oxide adducts, sugar fatty acid esters, N-alkyl polyhydroxy fatty acid amides, and alkyl glycosides. These nonionic surfactants may be used alone or in a combination of two or more.

As the nonionic surfactant, among the above, a polyoxyalkylene-type nonionic surfactant is preferable in terms of viscosity and liquid stability.
Examples of the polyoxyalkylene-type nonionic surfactant include a compound represented by the following general formula (f-1) (hereinafter, sometimes referred to as compound (f1)).

_{^{R 21 -X- (EO) s (}} PO) t -R 22 ··· (f-1)

[In the formula (f-1), R ²¹ is a hydrocarbon group having 8 to 22 carbon atoms, -X- is a divalent linking group, and R ²² is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. Or an alkenyl group having 2 to 6 carbon atoms. EO is an oxyethylene group, and s is a number from 3 to 20 representing the average number of repetitions of EO. PO is an oxypropylene group, and t is a number from 0 to 6 representing the average number of repetitions of PO. ]

(F-1) In the formula, the carbon number of the hydrocarbon group of R ²¹ is preferably from 10 to 18. The hydrocarbon group for R ²¹ may be linear or branched, and may or may not have an unsaturated bond.
Examples of -X- include -O-, -COO-, -CONH- and the like.
The number of carbon atoms in the alkyl group in R ²² is 1 to 6, 1 to 3 are preferred.
The number of carbon atoms of the alkenyl group for R ²² is 2-6, preferably 2-3.

Compound (f1) in which —X— is —O—, —COO— or —CONH— is a primary or secondary higher alcohol (R ¹ —OH), higher fatty acid (R ²¹ —COOH) or higher fatty acid amide. (R ²¹ -CONH) is obtained as a raw material.

s is a number of 3 to 20 representing the average number of repetitions of EO (that is, the average number of moles of ethylene oxide added), preferably 5 to 18. If the value exceeds the upper limit, the HLB value may be too high, and the detergency for sebum may decrease. If the value is less than the above lower limit, the odor may deteriorate.
t is a number of 0 to 6 representing the average number of repetitions of PO (that is, the average number of moles of propylene oxide added), preferably 0 to 3. If it exceeds the above upper limit, the liquid stability of the liquid detergent composition at high temperatures tends to decrease.
When t is 1 or more, that is, when compound (f1) has EO and PO, the method of adding ethylene oxide and propylene oxide is not particularly limited, and may be, for example, a random addition method or a block addition method. As a block addition method, for example, a method of adding propylene oxide after adding ethylene oxide, a method of adding ethylene oxide after adding propylene oxide, a method of adding propylene oxide after adding ethylene oxide, and further adding ethylene oxide A method of adding the information is included.

The addition mole number distribution of ethylene oxide or propylene oxide is not particularly limited.
The addition mole number distribution is likely to vary depending on the reaction method used to produce the nonionic surfactant. For example, when ethylene oxide or propylene oxide is added to a hydrophobic raw material using a common alkali catalyst such as sodium hydroxide or potassium hydroxide, the addition mole number distribution of ethylene oxide or propylene oxide is relatively wide. It tends to be. Also, specific alkoxylation of magnesium oxide or the like to which metal ions such as Al ³⁺ , Ga ³⁺ , In ³⁺ , Tl ³⁺ , Co ³⁺ , Sc ³⁺ , La ³⁺ , and Mn ²⁺ described in Japanese Patent Publication No. 6-15038 are added. When ethylene oxide or propylene oxide is added to a raw material of a hydrophobic group using a catalyst, the distribution of the number of moles of ethylene oxide or propylene oxide added tends to be relatively narrow.

The compound (f1), in particular, compounds -X- is -O- (alcohol type nonionic surface active agents), or a -X- is ^-COO-, alkyl ^{R 22} is 1 to 6 carbon atoms A compound which is a group or an alkenyl group having 2 to 6 carbon atoms (fatty acid alkyl (alkenyl) ester) is preferred.

When —X— is —O—, the carbon number of R ²¹ is preferably 10 to 22, more preferably 10 to 20, and even more preferably 10 to 18.
If -X- is ^{-O-, R 22} is preferably a hydrogen atom.

When —X— is —COO—, the carbon number of R ²¹ is preferably 9 to 21, and more preferably 11 to 21.
When -X- is -COO-, R ²² is preferably an alkyl group having 1 to 6 carbon atoms or an alkenyl group having 2 to 6 carbon atoms, and more preferably an alkyl group having 1 to 3 carbon atoms.

  As the compound (f1) in which -X- is -O- or -COO-, for example, Diadol (trade name, C13 (C represents the number of carbon atoms; the same applies hereinafter)) manufactured by Mitsubishi Chemical Corporation, Shell Addition of 12 moles or 15 moles of ethylene oxide to alcohols such as Neodol (trade name, mixture of C12 and C13) and Sasol 23 (trade name, mixture of C12 and C13) manufactured by Sasol Co. What is obtained by adding 12 mol equivalent or 15 mol equivalent of ethylene oxide to a natural alcohol such as CO-1214 or CO-1270 (trade name) manufactured by Procter &Gamble; The obtained C12 alkene is subjected to the oxo method, and 7 moles of ethylene oxide is added to the C13 alcohol obtained. (Trade name: Lutensol TO7, manufactured by BASF); a product obtained by adding 9 moles of ethylene oxide to C10 alcohol obtained by subjecting pentanol to a Garbet reaction (trade name: Lutensol XP90, manufactured by BASF); C10 alcohol obtained by subjecting pentanol to a garbet reaction to which 7 moles of ethylene oxide is added (trade name: Lutensol XL70, manufactured by BASF); C10 alcohol obtained by subjecting pentanol to a garbet reaction 6 moles of ethylene oxide (trade name: Lutensol XA60, manufactured by BASF); 9 moles or 15 moles of ethylene oxide were added to a secondary alcohol having 12 to 14 carbon atoms. Things (Product Name: S Phthanol 90, Sophthalanol 150, manufactured by Nippon Shokubai Co., Ltd .; methyl coconut fatty acid (lauric acid / myristic acid = 8/2) to which 15 moles of ethylene oxide has been added using an alkoxylation catalyst (polyoxygen) Ethylene coconut fatty acid methyl ester (EO 15 mol)).

As the compound (f1), among the above compounds, -X- is -COO-, R ²² is an alkyl group having 1 to 6 carbon atoms, and t is 0, that is, polyoxyethylene fatty acid alkyl ester. More preferably, polyoxyethylene fatty acid methyl ester in which R ²² is a methyl group (hereinafter sometimes referred to as MEE) is more preferable.
By using a polyoxyethylene fatty acid alkyl ester as the nonionic surfactant, the solubility of the liquid detergent composition in water can be increased, and the detergency can be increased. In addition, even if the content of the component (B) in the liquid detergent composition is increased, a remarkable increase in viscosity (gelation) hardly occurs, and a concentrated liquid detergent composition having good fluidity is obtained. Can be
Polyoxyethylene fatty acid alkyl esters, particularly MEE, are nonionic surfactants in which the orientation of molecules in an aqueous solution system is weak and micelles are unstable. For this reason, it is presumed that polyoxyethylene fatty acid alkyl ester does not cause gelation or the like at a high concentration and that the solubility in water can be increased even when one kind is used alone in a large amount in the liquid detergent composition. You. Therefore, when the liquid detergent composition containing the polyoxyethylene fatty acid alkyl ester is dispersed in water, the concentration of the polyoxyethylene fatty acid alkyl ester in the cleaning liquid quickly becomes uniform, and the concentration of the object to be washed at an arbitrary concentration from the initial stage of cleaning. It is thought that it exerts a high detergency on contact.

  In the polyoxyethylene fatty acid alkyl ester, the narrow ratio indicating the distribution ratio of the compound having a different addition mole number of ethylene oxide is preferably 20% by mass or more. The upper limit of the narrow ratio is preferably substantially 80% by mass or less. The narrow ratio is more preferably from 20 to 60% by mass. The higher the narrow ratio, the better the detergency is obtained, but if it is too high, the liquid stability at low temperatures may be reduced.

  The narrow ratio of a polyoxyalkylene-type nonionic surfactant such as a polyoxyethylene fatty acid alkyl ester is a value determined by the following equation (S).

In the formula (S), S _max represents the number of moles of addition of alkylene oxide (value of s + t) in the alkylene oxide adduct that is most frequently present in the polyoxyalkylene-type nonionic surfactant.
i represents the number of moles of alkylene oxide added.
Yi represents the ratio (mass%) of the alkylene oxide adduct having the addition mole number of the alkylene oxide present in the entire component represented by the formula (S) of i.

The narrow ratio can be controlled by, for example, a method for producing a polyoxyethylene fatty acid alkyl ester.
The method for producing the polyoxyethylene fatty acid alkyl ester is not particularly limited. For example, a method in which ethylene oxide is addition-polymerized to the fatty acid alkyl ester using a surface-modified composite metal oxide catalyst (particularly, JP-A-2000-144179).
Suitable examples of the surface-modified composite metal oxide catalyst include, for example, metal ions (Al ³⁺ , Ga ³⁺ , In ³⁺ , Tl ³⁺ , Co ³⁺⁾ surface-modified with a metal hydroxide or the like. , Sc ³⁺ , La ³⁺ , Mn ²⁺ ), a composite metal oxide catalyst such as magnesium oxide, a hydrotalcite calcined product surface-modified with a metal hydroxide and / or a metal alkoxide, etc. Is mentioned.
In the surface modification of the composite metal oxide catalyst, the ratio of the metal hydroxide and / or metal alkoxide is preferably 0.5 to 10 parts by mass with respect to 100 parts by mass of the composite metal oxide. More preferably, it is set to 5 parts by mass.

  As another method for producing the component (F), there is a method in which an alkylene oxide is added to a fatty acid alkyl ester using an alkoxylation catalyst prepared from a mixture of an alkaline earth metal compound and an oxyacid. The above-mentioned alkoxylation catalysts are disclosed in Japanese Patent No. 049767709, WO1993004030, WO2002038269, WO20122043535 and the like. Examples include an alkoxylation catalyst prepared from the mixture.

  By increasing the content of the component (F) in the liquid detergent composition, it is possible to obtain an advantage that an object to be washed can be washed with a small amount of the liquid detergent composition and a container of the liquid detergent composition can be made compact. Can be When increasing the content of the component (F) in the liquid detergent composition, ethylene oxide was added to the secondary alcohol as the component (F) because the gelling region was small even at a high concentration and the compound was easy to mix. Secondary alcohol ethoxylate (for example, Sophtanol series manufactured by Nippon Shokubai Co., Ltd.) and MEE are preferred. These have a small gelling region even at a high concentration, so that gelation hardly occurs even when the content in the liquid detergent composition is increased.

As the component (F), one type may be used alone, or two or more types may be used in combination.
For example, as the component (F), a secondary alcohol ethoxylate or MEE and a primary alcohol ethoxylate obtained by adding ethylene oxide to a primary alcohol may be used in combination.
When the secondary alcohol ethoxylate or MEE is used in combination with the primary alcohol ethoxylate, the component (F) is represented by (secondary alcohol ethoxylate or MEE) / (primary alcohol ethoxylate). The mass ratio is preferably 3/7 to 10/0, more preferably 5/5 to 10/0, and still more preferably 9/1 to 10/0.

  The content of the component (F) in the liquid detergent composition is preferably 0.1% by mass or more, more preferably 0.1 to 70% by mass, still more preferably 5 to 50% by mass, and preferably 10 to 30% by mass. Particularly preferred. When the amount is equal to or more than the lower limit, the effect of blending the nonionic surfactant is easily obtained, and when the amount is equal to or less than the upper limit, an increase in viscosity of the liquid detergent composition at low temperatures can be further suppressed.

  The mass ratio represented by the component (F) / the component (A) (hereinafter, also referred to as F / A ratio) is preferably from 0.2 to 50, and more preferably from 0.5 to 25. When the F / A ratio is equal to or less than the lower limit, the defoaming property becomes good. When the F / A ratio is equal to or more than the above lower limit, the detergency becomes good.

[Thickener and solubilizer]
Examples of the viscosity reducing agent and the solubilizer include triethylene glycol, tetraethylene glycol, polyethylene glycol having an average molecular weight of about 200, polyethylene glycol having an average molecular weight of about 400, polyethylene glycol having an average molecular weight of about 1,000, and glycols such as dipropylene glycol; Examples include p-toluenesulfonic acid, benzoate, and urea.
When the liquid detergent composition of the present invention contains a thickener and a solubilizer, the content of the thickener and the solubilizer is 0.01 to 15% by mass based on the total mass of the liquid detergent composition. Is preferred.

[Metal ion scavenger (chelating agent)]
Examples of the metal ion scavenger (chelating agent) include malonic acid, succinic acid, malic acid, diglycolic acid, tartaric acid, citric acid and the like.
When the liquid detergent composition of the present invention contains a metal ion scavenger, the content of the metal ion scavenger is preferably from 0.1 to 20% by mass based on the total mass of the liquid detergent composition.

[Antioxidant]
Examples of the antioxidant include butylhydroxytoluene, distyrenated cresol, sodium sulfite, sodium hydrogen sulfite, and the like.
When the liquid detergent composition of the present invention contains an antioxidant, the content of the antioxidant is preferably 0.01 to 2% by mass based on the total mass of the liquid detergent composition.

[Preservative]
Examples of the preservative include “Caisson CG” (trade name) manufactured by Dow Chemical Company, “Activis MBS” (trade name) manufactured by So Japan, and “NIPACIDE BIT 20” (trade name) manufactured by Clariant. .

[Colorant]
Examples of the colorant include Acid Red 138, Polar Red RLS, Acid Yellow 203, Acid Blue 9, Blue No. 1, Blue 205, Green No. 3, Red No. 106, Yellow No. 203, Turquoise P-GR (all are commercial products). General-purpose dyes and pigments such as
When the liquid detergent composition of the present invention contains a colorant, the content of the colorant is preferably 0.00005 to 0.005% by mass based on the total mass of the liquid detergent composition.

[Emulsifier]
Examples of the emulsifier include a polystyrene emulsion and a polyvinyl acetate emulsion, and usually include an emulsion having a solid content of 30 to 50% by mass. Specifically, a polystyrene emulsion (trade name, manufactured by Seiden Chemical Co., Ltd. (trade name) ) Cybinol RPX-196 PE-3, solid content 40% by mass).
When the liquid detergent composition of the present invention contains an emulsifier, the content of the emulsifier is preferably from 0.01 to 0.5% by mass based on the total mass of the liquid detergent composition.
[Fragrances other than capsule flavors]
Examples of the fragrance include a fragrance component described in JP-A-2002-146399.
When the liquid detergent composition of the present invention contains a fragrance, the content of the fragrance is preferably 0.01 to 2% by mass based on the total mass of the liquid detergent composition.

The liquid detergent composition of the present invention preferably has a pH at 25 ° C of 4 to 10, more preferably 5 to 9, and even more preferably 6 to 8. When the pH is in such a range, the storage stability of the liquid detergent composition can be favorably maintained.
The pH of the detergent for clothing can be adjusted by adding a pH adjuster, if necessary. The pH adjuster is optional as long as the effects of the present invention are not impaired, but sulfuric acid, sodium hydroxide, potassium hydroxide, alkanolamine and the like are preferable.
In the present specification, the pH means a value measured with a pH meter (product name: HM-30G, manufactured by Toa DKK Ltd.) at 25 ° C.
The sum of the contents of the components of the liquid cleaning composition of the present invention does not exceed 100% by mass.

The liquid detergent composition of the present invention is produced by a conventionally known liquid detergent production method.
As a method for producing a liquid detergent, for example, a method in which components (A) to (C) and optional components are added to water as a solvent, and if necessary, are mixed.

As a method of using the liquid detergent composition of the present invention, for example, when used for cleaning textile products, the liquid detergent composition alone or together with a known bleaching agent and softener in water to form a washing liquid. A method in which an object to be washed is placed in the washing liquid and washed with a washing machine, a method in which the object to be washed is immersed in the washing liquid for a certain period of time, and then washed in a washing machine, and the like. Further, when used for washing dishes and the like, a method of washing dishes and the like by including a liquid detergent composition in an undiluted solution in a sponge, preparing a dilute washing solution by dissolving the liquid detergent composition in water. And a method of immersing tableware and the like in the washing liquid and rubbing with a sponge.
Examples of items to be washed include kitchen utensils such as tableware and textile products such as clothing, fabric, sheets, curtains, and carpets.

The number represented by the content of the linear alkylbenzene sulfonate x the content of the component (B) (hereinafter, also referred to as "LAS salt x B value") is preferably from 0.15 to 200, and more preferably from 1.2 to 50. Is more preferable, and 3 to 10 is further preferable.
When the LAS salt × B value is within the above range, it becomes easy to achieve both a soft and voluminous tactile sensation and a dry and crisp tactile sensation.

  Number represented by (C) component content × (E) component content / {((A) component content + (D) component content) × (B) component content} , “CE / {(A + D) B} value”) is preferably 0 to 50, more preferably 0.6 to 15, and still more preferably 1.6 to 8. By setting the CE / {(A + D) B} value within the above range, usability (at a low temperature in winter) can be easily improved.

The number represented by the content of the component (D) / (the content of the component (A) × the content of the component (B)) (hereinafter, also referred to as “D / AB value”) is preferably from 0 to 100, 0.6-5 is more preferable.
By setting the D / AB value within the above range, the defoaming property is easily improved.

The number represented by the content of the component (A) × the content of the component (B) × the content of the microcapsules (hereinafter, also referred to as “ABM value”) is preferably 0 to 100, and 0.1 to 10 is preferable. More preferably, 0.3 to 5 is even more preferred.
When the ABM value is within the above range, the deodorizing property is easily improved.
The above contents all mean the value of the mass% of each component with respect to the total mass of the liquid detergent composition.

  The liquid detergent composition of the present invention comprises a component (A), a component (B), and a component (C), wherein the component (A) is a linear alkylbenzene sulfonate, and the component (B) is a compound represented by the general formula (b) -1) and at least one type of repeating unit selected from the group consisting of a repeating unit represented by the general formula (b-2) and a repeating unit represented by the general formula (b-3) A polymer having a repeating unit, wherein the component (C) is at least one selected from the group consisting of a compound represented by the general formula (c-1) and a compound represented by the general formula (c-2) Preferably, it is a compound of the species.

  The liquid detergent composition of the present invention comprises a component (A), a component (B), a component (C), and a component (D), wherein the component (A) is a linear alkylbenzene sulfonate, and the component (B) Is at least one repeating unit selected from the group consisting of a repeating unit represented by the general formula (b-1) and a repeating unit represented by the general formula (b-2); And a repeating unit represented by formula (c-1), wherein the component (C) is a compound represented by formula (c-1) or a compound represented by formula (c-2): It is at least one compound selected and the component (D) is preferably a coconut fatty acid.

  The liquid detergent composition of the present invention comprises a component (A), a component (B), a component (C), a component (D), and a component (E), wherein the component (A) is a linear alkylbenzene sulfonate. And (B) at least one repeating unit selected from the group consisting of a repeating unit represented by the general formula (b-1) and a repeating unit represented by the general formula (b-2); And a repeating unit represented by the formula (b-3), wherein the component (C) is a compound represented by the general formula (c-1) and a compound represented by the general formula (c-2) At least one compound selected from the group consisting of compounds, wherein the component (D) is coconut fatty acid, and the component (E) is selected from the group consisting of alkyl acrylate, alkyl methacrylate, acrylic acid and methacrylic acid. Frame obtained by polymerizing two or more types of monomers It is preferably a type copolymer.

  The liquid detergent composition of the present invention comprises (A) component, (B) component, (C) component, (D) component, (E) component, and a nonionic surfactant, wherein (A) component is linear alkylbenzene. A sulfonic acid salt, wherein the component (B) is at least one member selected from the group consisting of a repeating unit represented by the general formula (b-1) and a repeating unit represented by the general formula (b-2) A polymer having a repeating unit and a repeating unit represented by the general formula (b-3), wherein the component (C) is a compound represented by the general formula (c-1), and a compound represented by the general formula (c-2) ) Is at least one compound selected from the group consisting of compounds represented by formula (I), wherein the component (D) is a coconut fatty acid and the component (E) is an alkyl acrylate, an alkyl methacrylate, an acrylic acid and a methacrylic acid. Two or more types selected from the group It is preferably a crosslinked copolymer obtained by polymerizing mer.

  The liquid detergent composition of the present invention contains (A) component, (B) component, (C) component, (D) component, (E) component, nonionic surfactant, and capsule flavor. A linear alkylbenzene sulfonate, wherein the component (B) is at least one selected from the group consisting of a repeating unit represented by the general formula (b-1) and a repeating unit represented by the general formula (b-2) A polymer having one type of repeating unit and a repeating unit represented by the general formula (b-3), wherein the component (C) is a compound represented by the general formula (c-1), at least one compound selected from the group consisting of compounds represented by c-2), wherein the component (D) is a coconut fatty acid, the component (E) is an alkyl acrylate, an alkyl methacrylate, an acrylic acid, Selected from the group consisting of methacrylic acid It is preferably obtained by polymerizing a monomer or monomers cross-linked copolymer.

  Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.

(Raw materials used)
<(A) component>
A-1: linear alkyl (C10-C13) potassium benzenesulfonate, product name "LAS-K", manufactured by Lion Corporation)
A-2: sodium salt of polyoxyethylene dodecyl ether sulfate, average number of added moles of oxyethylene group 3, product name "AES", manufactured by Lion Corporation.

<(B) component>
B-1: Copolymer of dimethyldiallylammonium and acrylamide, trade name "Noverite 300", manufactured by Lubrizol.
B-2: a copolymer of dimethyldiallylammonium and acrylamide, trade name “Noverite 302”, manufactured by Lubrizol.

<(C) component>
C-1: 3-methoxy-3-methyl-1-butanol, trade name "SOLFIT", manufactured by Kuraray Co., Ltd.
C-2: butyl carbitol, trade name "butyl diglycol", manufactured by Nippon Emulsifier.
-C'-1: ethanol, trade name "fermented alcohol 95 degree 1st grade", manufactured by Godo Shuseisha.

<Others>
-Coconut fatty acid, trade name "coconut fatty acid (PKO) TC", manufactured by NOF Corporation.
-Capsule perfume C: trade name "Mecapcaps Cosmic 1", manufactured by Givaudan.
-Capsule perfume D: trade name "Popscent BLUEFLOWERPOP MHN2814", manufactured by Filmenich.
-Carbopol Aqua 30: a crosslinked copolymer obtained by polymerizing two or more monomers selected from the group consisting of alkyl acrylate, alkyl methacrylate, acrylic acid and methacrylic acid, trade name "Carbopol Aqua 30", manufactured by Lubrizol.

[Common component A]
The numerical value described at the end of each component is the content in the liquid detergent composition.
F-1: MEE: methyl coconut fatty acid (a mixture of methyl laurate / methyl myristate = 8/2 by mass ratio) to which 15 mol of ethylene oxide is added using an alkoxylation catalyst (MEE) ). In the general formula (f-1), R ²¹ = alkyl group having 11 carbon atoms and alkyl group having 13 carbon atoms, R ²² = methyl group, s = 15, and t = 0. Narrow rate 33%. Synthesized by the following synthesis method: 19% by mass.
[Synthesis method of A-1]
It synthesized according to the synthesis method of Unexamined-Japanese-Patent No. 2000-144179.
Alumina / magnesium hydroxide having a composition of 2.5 MgO.Al ₂ O ₃ .wH ₂ O (Kyoward 300 (trade name), manufactured by Kyowa Chemical Industry Co., Ltd.) is fired at 600 ° C. for 1 hour in a nitrogen atmosphere. Thus, a calcined alumina hydroxide / magnesium (unmodified) catalyst was obtained. 2.2 g of calcined alumina / magnesium hydroxide (unmodified) catalyst, 2.9 mL of 0.5N potassium hydroxide in ethanol solution, 280 g of lauric acid methyl ester, and 70 g of myristic acid methyl ester were charged into a 4 L autoclave, and autoclaved. The catalyst was reformed inside. Next, after the inside of the autoclave was replaced with nitrogen, 1052 g of ethylene oxide was introduced while maintaining the temperature at 180 ° C. and the pressure at 0.3 MPa, and reacted while stirring.
The obtained reaction solution was cooled to 80 ° C., and 159 g of water and 5 g each of activated clay and diatomaceous earth as filter aids were added and mixed, and the catalyst was separated by filtration to obtain F-1.
[Narrow analysis method]
The narrow ratio of the component (F) was measured according to the following procedure.
The distribution of ethylene oxide adducts having different addition mole numbers of ethylene oxide was measured under the following measurement conditions, and the narrow ratio (% by mass) was calculated by the above equation (S).
[Conditions for measuring distribution of ethylene oxide adduct by HPLC]
Apparatus: LC-6A (manufactured by Shimadzu Corporation)
Detector: SPD-10A
Measurement wavelength: 220 nm
Column: Zorbax C8 (manufactured by Du Pont)
Mobile phase: acetonitrile / water = 60/40 (volume ratio)
Flow rate: 1 mL / min Temperature: 20 ° C
· AE (EO15): polyoxyethylene alkyl ether, trade name "LMAO-90", manufactured by Lion Corporation; formula (f-1) ^{in, R 21} = a straight-chain alkyl group having 12 to 14 carbon atoms, X = —O—, R ²² = hydrogen atom, s = 15, t = 0... 2% by mass.
-SR agent: trade name "TexCare SRN-170C", manufactured by Clariant Japan Ltd. ... 0.5% by mass.
PEG: polyethylene glycol, trade name "PEG # 1000-L60", manufactured by Lion Chemical Co., Ltd .: 2% by mass
-Na benzoate: trade name "sodium benzoate", manufactured by Toagosei Co., Ltd. ... 0.5% by mass.
-Isothiazolone liquid: 5-chloro-2-methyl-4-isothiazolin-3-one / 2-methyl-4-isothiazolin-3-one / magnesium salt / water mixture, trade name "Caisson CG", ROHM &・ Haas Co., Ltd .: 0.01% by mass.
MEA: monoethanolamine, manufactured by Nippon Shokubai Co., Ltd .... 3.6% by mass.
-Citric acid: On the other hand, manufactured by Yushi Yushi Kogyo Co., Ltd. ... 0.1% by mass.
-BHT: dibutylhydroxytoluene, trade name "SUMILZER BHT-R", manufactured by Sumitomo Chemical Co., Ltd .: 0.05% by mass.
-Dye: trade name "Red No. 106", manufactured by Kishi Kasei Co., Ltd. ... 0.0001% by mass.
Perfume (other than capsule perfume): Perfume (perfume composition A described in JP-A-2002-146399): 0.85% by mass.

[Common component B]
The numerical value described at the end of each component is the content in the liquid detergent composition.
F-2: MEE: Methyl coconut fatty acid (a mixture of methyl laurate / methyl myristate = 8/2 by mass ratio) to which 15 moles of ethylene oxide has been added using an alkoxylation catalyst. In the above general formula (f-1), R ²¹ = alkyl group having 11 carbon atoms and alkyl group having 13 carbon atoms, R ²² = methyl group, s = 15, t = 0, and narrow ratio 33%. Synthesized by the following synthesis method: 14% by mass.
[Method of synthesizing F-2]
F-2 was synthesized according to the following synthesis method.
In a 1 L separable flask, 525 g of isopropyl alcohol (IPA) (first grade reagent, manufactured by Kanto Chemical Co., Ltd.) and 150 g of calcium acetate monohydrate (special grade reagent, manufactured by Kanto Chemical Co., Ltd.) are put, and the dispersion is stirred at 20 ° C. To obtain a dispersion (dispersion step). While the dispersion was stirred at 3000 rpm, 75 g of sulfuric acid (special grade reagent, manufactured by Kanto Chemical Co., Ltd.) was added and mixed by a dropping funnel over 60 minutes (mixing step). In the mixing step, since heat is generated by the addition of sulfuric acid, the reaction temperature was controlled at 15 to 25 ° C. with a separable flask in a warm bath. After the addition of sulfuric acid, the mixture was further stirred for 2 hours while maintaining the temperature at 20 ° C. (catalyst aging step) to obtain an alkoxylation catalyst.
In an autoclave, 2.1 g of the above alkoxylation catalyst, 462 g of methyl laurate (Pastel M12, manufactured by Lion Chemical Co., Ltd.) and 166 g of methyl myristate (Pastel M14, manufactured by Lion Chemical Co., Ltd.) were stirred. While stirring, the inside of the autoclave was replaced with nitrogen, the temperature was raised to 160 ° C., and under a condition of 0.1 to 0.5 MPa, 1876 g of ethylene oxide (EO) (15 times mol of the total of methyl laurate and methyl myristate) And the mixture was stirred (addition reaction step). The mixture was further stirred at an addition reaction temperature for 0.5 hour (aging step), and then cooled to 80 ° C. to obtain 2516 g of a reaction crude product (fatty acid methyl ester ethoxylate (MEE), average number of moles of added EO = 15). The reaction crude product was filtered to remove the catalyst and was designated F-2.
· AE (EO15): polyoxyethylene alkyl ether, trade name "LMAO-90", manufactured by Lion Corporation; formula (f-1) ^{in, R 21} = a straight-chain alkyl group having 12 to 14 carbon atoms, X = ^{-O-, R 22} = hydrogen atom, s = 15, t = 0 ··· 7 wt%.
-SR agent: trade name "TexCare SRN-170C", manufactured by Clariant Japan Ltd. ... 0.5% by mass.
PEG: polyethylene glycol, trade name "PEG # 1000-L60", manufactured by Lion Chemical Co., Ltd .: 2% by mass
-Na benzoate: trade name "sodium benzoate", manufactured by Toagosei Co., Ltd. ... 0.5% by mass.
-Isothiazolone liquid: 5-chloro-2-methyl-4-isothiazolin-3-one / 2-methyl-4-isothiazolin-3-one / magnesium salt / water mixture, trade name "Caisson CG", ROHM &・ Haas Co., Ltd .: 0.01% by mass.
MEA: monoethanolamine, manufactured by Nippon Shokubai Co., Ltd .... 3.6% by mass.
-Citric acid: On the other hand, manufactured by Yushi Yushi Kogyo Co., Ltd. ... 0.1% by mass.
-BHT: dibutylhydroxytoluene, trade name "SUMILZER BHT-R", manufactured by Sumitomo Chemical Co., Ltd .: 0.05% by mass.
-Dye: trade name "Red No. 106", manufactured by Kishi Kasei Co., Ltd. ... 0.0001% by mass.
Perfume (other than capsule perfume): Perfume (perfume composition A described in JP-A-2002-146399): 0.85% by mass.

[Common component C]
・ F-2: 19% by mass
· AE (EO15): polyoxyethylene alkyl ether, trade name "LMAO-90", manufactured by Lion Corporation; formula (f-1) ^{in, R 21} = a straight-chain alkyl group having 12 to 14 carbon atoms, X = —O—, R ²² = hydrogen atom, s = 15, t = 0... 2% by mass.
-SR agent: trade name "TexCare SRN-170C", manufactured by Clariant Japan Ltd. ... 0.5% by mass.
PEG: polyethylene glycol, trade name "PEG # 1000-L60", manufactured by Lion Chemical Co., Ltd .: 2% by mass
-Na benzoate: trade name "sodium benzoate", manufactured by Toagosei Co., Ltd. ... 0.5% by mass.
-Isothiazolone liquid: 5-chloro-2-methyl-4-isothiazolin-3-one / 2-methyl-4-isothiazolin-3-one / magnesium salt / water mixture, trade name "Caisson CG", ROHM &・ Haas Co., Ltd .: 0.01% by mass.
MEA: monoethanolamine, manufactured by Nippon Shokubai Co., Ltd .... 3.6% by mass.
-Citric acid: On the other hand, manufactured by Yushi Yushi Kogyo Co., Ltd. ... 0.1% by mass.
-BHT: dibutylhydroxytoluene, trade name "SUMILZER BHT-R", manufactured by Sumitomo Chemical Co., Ltd .: 0.05% by mass.
-Dye: trade name "Red No. 106", manufactured by Kishi Kasei Co., Ltd. ... 0.0001% by mass.
Perfume (other than capsule perfume): Perfume (perfume composition A described in JP-A-2002-146399): 0.85% by mass.

<Examples 1 to 32, Comparative Examples 1 to 3>
According to the compositions shown in Tables 2 to 5, the components (A) to (C) and other components were added to water and mixed to obtain liquid cleaning compositions of Examples 1 to 32 and Comparative Examples 1 to 3. . Example 11 is a reference example.
Tables 2 to 5 show the compositions (mixing components, content (% by mass)) of the obtained liquid detergent compositions of the respective examples.
In the table, when there is a blank component, the compound component is not blended.
The water content "balance" is an amount necessary to make 100% by mass in the entire liquid detergent composition.

With respect to the liquid detergent compositions of each example, the soft and voluminous tactile sensation, the dry tactile sensation, the defoaming property, the usability, and the deodorizing property were evaluated as follows. The evaluation results are shown in Tables 2 to 5.
[Evaluation of the soft and voluminous feel and the dry feel]
Into a fully automatic electric washing machine (JW-Z23A manufactured by Haier), two commercially available T-shirts (manufactured by BVD, product number G013TSLL, 100% cotton) and a bath ratio (washing water / total cloth to be washed) were used. In order to adjust the mass by 20 times, two cotton T-shirts (manufactured by BVD Co., total weight of all cloths to be washed: about 600 g) were added, and the detergent for clothing of each example was added ( A washing operation was performed in which washing, rinsing, and dehydration were sequentially performed in the standard course (4 mL of clothing detergent). Using tap water at 15 ° C., the washing time, rinsing, dehydration, and water volume (set at a low water level, water volume of about 12 L) were not adjusted at all, and the standard course settings of the washing machine were used. After washing, the removed T-shirt was left in a constant temperature and humidity room at 25 ° C. and a humidity of 65% RH for 1 day to obtain a test cloth. Ten “special panelists” performed a paired comparison with the control cloth according to the following criteria and scored the “soft and voluminous touch” of the test cloth. The average value of the scores of the ten specialized panelists was classified into the following evaluation criteria, and the respective tactile sensations were evaluated. In each evaluation, △, 、, and ◎ were judged to be acceptable.
The evaluation of the tactile sensation was performed in the constant temperature and humidity chamber (closed space of 20 m ³ ). As a control cloth, a standard detergent (an average of 15 mol of ethylene oxide per mol of lauryl alcohol) was used instead of the laundry detergent of each example. (A 20% by mass aqueous solution of alcohol ethoxylate to which acetic acid was added), and a towel treated in the same washing operation as above was used.
The evaluation results of the soft and voluminous feel and the dry feel (two days after drying) are shown in the table.

判断 Soft and voluminous tactile criterion≫
1 point: equal to or less than control cloth.
2 points: Slightly voluminous and softer than the control cloth.
3 points: considerably voluminous and softer than the control cloth.
4 points: Very voluminous and softer than the control cloth.
評 価 Evaluation criteria for soft and voluminous touch 感
◎: 3.5 or more.
：: 2.5 or more and less than 3.5 points.
Δ: 1.5 or more and less than 2.5 points.
X: Less than 1.5 points.

判断 Criteria for judging a dry touch 感
1 point: Feel wetter than control cloth.
2 points: Feel slightly wet than control cloth.
3 points: equivalent to control cloth.
4 points: Feel slightly dry than the control cloth.
5 points: Feel dry than the control cloth.
評 価 Evaluation criteria for a completely dry touch 感
：: 3 or more.
：: 2 or more and less than 3 points.
X: Less than 2 points.

[Usability (easiness of putting detergent into the inlet at low temperature in winter)]
The clothing detergent of each example was put in a PS11 bottle and stored in a constant temperature room (5 ° C.) for one day. Thereafter, 10 ml was put into a measuring cap of a top NANOX (lot. 160121C8X), and the whole amount was put into a fully automatic electric washing machine (BD-V7300 manufactured by Hitachi, Ltd.). At that time, 10 expert panelists gave a paired comparison with a control detergent according to the following criteria, and scored "easiness of putting detergent into the inlet". The average value of the scores of the ten expert panelists was classified into the following evaluation criteria, and each "easiness of putting the detergent into the inlet" was evaluated. In each evaluation, △, 、, and ◎ were judged to be acceptable. The detergent of Comparative Example 3 was used as the target detergent.
判断 Judgment criteria for ease of putting detergent into the inlet 口
1 point: equal to or less than control detergent.
2 points: slightly easier to put than control cloth.
3 points: considerably easier to put than control cloth.
4 points: It is much easier to put in than the control cloth.
評 価 Evaluation criteria for ease of putting detergent into the inlet 口
A: Greater than 2 points.
：: More than 1.5 points and 2 points or less.
Δ: Greater than 1 point, 1.5 points or less.
X: 1 point.

[Defoaming property]
0.3 g of the liquid detergent composition of each example was dissolved in 900 mL of 3 ° hard water at 25 ° C. to prepare a washing solution. 20 mL of this washing solution was put into a 100 mL Epton tube, shaken 30 times in 30 seconds, foamed, and allowed to stand for 1 minute. The height of the subsequent foam (the length from the boundary between the foam and the washing liquid to the top surface of the foam) was measured and compared with the control detergent. ◎ and △ were accepted. The detergent of Example 24 was used as the target detergent.
評 価 Evaluation criteria for ease of putting detergent into the inlet 口
X: Foam is higher than control detergent.
Δ: Equal to or slightly lower than the control detergent.
A: Foam is lower than control detergent.

[Deodorant]
A towel (100% cotton) for wiping hands and face was used eight times in total every 60 minutes, and 10 pieces were divided into eight equal parts to obtain test cloths.
In a drum type fully automatic electric washing machine (BD-V7300 manufactured by Hitachi, Ltd.), 10 test cloths described above, wet-type artificially stained cloth (manufactured by Washing Science Association, 28.3% by mass of oleic acid, 15.6% by mass of triolein) Cholesterol oleate 12.2% by mass, liquid paraffin 2.5% by mass, squalene 2.5% by mass, cholesterol 1.6% by mass, gelatin 7.0% by mass, mud 29.8% by mass, carbon black 0.5 5% by mass, 10 cm × 10 cm / 1 sheet), and a cotton T-shirt (100% cotton, manufactured by BVD) to adjust the weight of the clothes to 1 kg. Detergent was added to the inlet (the amount of clothing detergent used was adjusted to be 5 ml / kg of cloth). Using tap water at 15 ° C., a washing operation in which washing, rinsing, and dehydration were sequentially performed in a standard course was performed. The washing time, rinsing, dehydration and water volume were not adjusted at all and the standard course settings of the washing machine were used. After washing, the plate was left in a constant temperature and humidity room at 25 ° C. and a humidity of 85% RH for one day.
The odor intensity of the test cloth was scored according to the criteria. In the evaluation, ten panelists conducted a sensory test on the strength of the odor remaining on the cloth according to the following criteria, and scored them based on a six-step odor intensity display method shown in the following criteria. The deodorizing property was evaluated from the average value according to the evaluation criteria. 、, 、, ◎ were accepted.
判断 Criteria for determining deodorant properties 性 の
5 points: Strong smell.
4 points: Strong odor.
3 points: Smell intensity enough to be easily perceived.
2 points: Smell intensity enough to tell what smell it is.
1 point: Smell intensity that can be detected at last.
0 point: odorless.
≪Evaluation criteria B≫
◎: Less than one point.
○: 1 point or more and less than 2 points.
Δ: 2 or more and less than 3 points.
X: 4 or more points.

From the results shown in Tables 2 to 5, the liquid detergent compositions of Examples 1 to 32 to which the present invention has been applied can provide a soft and voluminous tactile sensation, and can provide a dry tactile sensation. Excellent defoaming and deodorizing properties.
On the other hand, in Comparative Example 1 containing no component (A), a soft and voluminous tactile sensation could not be provided, and the deodorizing property was poor.
In Comparative Example 2 containing no (B) component, a soft and voluminous tactile sensation could not be provided.
Comparative Example 3 in which the component (C) was replaced with ethanol was inferior in usability.
From the above results, the liquid detergent composition to which the present invention has been applied can impart both a soft and voluminous feel and a dry feel, and is easy to use, defoaming, and deodorant. It was confirmed that it was excellent.

Claims (6)

(A) component: 5 to 20% by mass of an anionic surfactant excluding fatty acid salts having 8 to 22 carbon atoms (however, excluding potassium N-coconut fatty acid acylglycine);
(B) component: at least one type of repeating unit selected from the group consisting of a repeating unit represented by the following general formula (b-1) and a repeating unit represented by the following general formula (b-2); A polymer having a repeating unit represented by the following general formula (b-3);
Component (C): 4 to 10 mass of at least one compound selected from the group consisting of a compound represented by the following general formula (c-1) and a compound represented by the following general formula (c-2) % Liquid detergent composition for textiles.

[Wherein, R ¹ and R ² are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁻ is a counter ion. ]

[Wherein, R ³ and R ⁴ are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁻ is a counter ion. ]

[Wherein, R ⁵ is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R ⁶ and R ⁷ are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms or 1 to 3 carbon atoms. 3 is a hydroxyalkyl group. ]

[Wherein, R ^{11 to} R ¹³ are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R ¹⁴ is a hydrogen atom or an acetyl group. ]

[Wherein, R ¹⁵ is an alkyl group having 1 to 6 carbon atoms or a phenyl group, n is 0 to 10, m is 0 to 10, and n + m> 0. ]   The liquid detergent composition for textile products according to claim 1, further comprising (D) component: at least one selected from the group consisting of fatty acids having 8 to 22 carbon atoms and salts thereof. Component (E): a group consisting of a repeating unit derived from a monomer represented by the following general formula (e-1) and a repeating unit derived from a monomer represented by the following general formula (e-2) The liquid detergent composition for textiles according to claim 1 or 2, comprising a polymer having at least one selected repeating unit.

[In the formula (e-1), R ⁵¹ is a hydrogen atom or a methyl group, and R ⁵² is a hydrogen atom.
In the formula (e-2), R ⁵³ is a hydrogen atom or a methyl group, and R ⁵⁴ is an alkyl group having 1 to 40 carbon atoms. ]   The liquid detergent composition for textiles according to any one of claims 1 to 3, further comprising a nonionic surfactant. (B) the content of the component, Ru 0.05% by mass, textiles liquid detergent composition according to any one of claims 1-4.   The liquid detergent composition for textile products according to any one of claims 1 to 5, wherein the component (C) is a compound represented by the general formula (c-1).