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JP6410163B1 - Electric wire with terminal - Google Patents

Electric wire with terminal Download PDF

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Publication number
JP6410163B1
JP6410163B1 JP2018016150A JP2018016150A JP6410163B1 JP 6410163 B1 JP6410163 B1 JP 6410163B1 JP 2018016150 A JP2018016150 A JP 2018016150A JP 2018016150 A JP2018016150 A JP 2018016150A JP 6410163 B1 JP6410163 B1 JP 6410163B1
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conductor
electric wire
terminal
compression
conductive particles
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JP2019009101A (en
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佐藤　哲朗
哲朗 佐藤
正嗣 小島
正嗣 小島
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Proterial Ltd
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Hitachi Metals Ltd
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Priority to CN201810541366.8A priority Critical patent/CN109119777B/en
Priority to EP18175004.3A priority patent/EP3419118B1/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R11/00—Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts
    • H01R11/11—End pieces or tapping pieces for wires, supported by the wire and for facilitating electrical connection to some other wire, terminal or conductive member
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R4/00—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
    • H01R4/04—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation using electrically conductive adhesives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R4/00—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
    • H01R4/10—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation effected solely by twisting, wrapping, bending, crimping, or other permanent deformation
    • H01R4/18—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation effected solely by twisting, wrapping, bending, crimping, or other permanent deformation by crimping
    • H01R4/20—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation effected solely by twisting, wrapping, bending, crimping, or other permanent deformation by crimping using a crimping sleeve
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R4/00—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
    • H01R4/58—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation characterised by the form or material of the contacting members
    • H01R4/62—Connections between conductors of different materials; Connections between or with aluminium or steel-core aluminium conductors

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  • Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)
  • Insulated Conductors (AREA)

Abstract

【課題】圧縮接続された端子と電線の導体との間の電気抵抗が、高温環境下に曝されても増加し難い端子付き電線を提供する。
【解決手段】アルミニウム又はアルミニウム合金からなる導体４を絶縁被覆５で被覆してなる電線２と、電線２の端部において、導体が絶縁被覆５で被覆されずに露出してなる導体露出部４ａに圧縮接続される圧縮部８を有する圧縮端子３と、を備える端子付き電線であって、導体露出部４ａには、Ｎｉ−ＰまたはＮｉ−Ｂからなる導電粒子７を含む導電粒子入りコンパウンドが付着しており、前記導電粒子入りコンパウンド中の前記導電粒子の含有量が２０ｗｔ％以下である。
【選択図】図１Provided is a terminal-attached electric wire in which the electrical resistance between a compression-connected terminal and a conductor of the electric wire does not easily increase even when exposed to a high temperature environment.
An electric wire 2 in which a conductor 4 made of aluminum or an aluminum alloy is coated with an insulating coating 5, and a conductor exposed portion 4a in which the conductor is exposed without being covered with the insulating coating 5 at the end of the electric wire 2. And a compression terminal 3 having a compression portion 8 that is compressed and connected to the conductive exposed portion 4a. The conductor exposed portion 4a includes a compound containing conductive particles including the conductive particles 7 made of Ni-P or Ni-B. It adheres and the content of the conductive particles in the compound containing the conductive particles is 20 wt% or less.
[Selection] Figure 1

Description

本発明は、端子付き電線に関する。   The present invention relates to an electric wire with a terminal.

従来、車両などに使用される電線の導体を、軽量化等を目的に、アルミニウムまたはアルミニウム合金で構成し、この導体に圧縮端子を圧縮した構成の端子付き電線が知られている（たとえば、特許文献１を参照）。   2. Description of the Related Art Conventionally, an electric wire with a terminal having a configuration in which a conductor of an electric wire used in a vehicle or the like is made of aluminum or an aluminum alloy for the purpose of weight reduction and the like and a compression terminal is compressed to the conductor is known (for example, a patent Reference 1).

この種の端子付き電線では、図３（Ａ）に示すように、アルミニウムまたはアルミニウム合金からなる導体１００が空気中などの酸素１０１に触れると、同図（Ｂ）に示すように、導体１００の表面に酸化膜１０２が形成される。このため、同図（Ｃ）に示すように、電線の導体１００に圧縮端子１０３を圧縮する際に、酸化膜１０２の介在によって導体１００と圧縮端子１０３間の電気抵抗が大きくなってしまう。なお、図３（Ｃ）は圧縮端子１０３を圧縮する前の状態を示している。   In this type of electric wire with terminal, as shown in FIG. 3 (A), when the conductor 100 made of aluminum or an aluminum alloy comes into contact with oxygen 101 such as in the air, as shown in FIG. An oxide film 102 is formed on the surface. For this reason, as shown in FIG. 3C, when the compression terminal 103 is compressed to the conductor 100 of the electric wire, the electrical resistance between the conductor 100 and the compression terminal 103 is increased due to the interposition of the oxide film 102. FIG. 3C shows a state before the compression terminal 103 is compressed.

特許文献１には、電線の導体に圧縮端子を圧縮するのに先立って、電線の導体に導電粒子（金属粒子）を塗布しておき、圧縮端子を圧縮したときに、圧縮時の加圧力を利用して導体表面の酸化膜を導電粒子で突き破る技術が記載されている。この技術によれば、アルミニウムからなる金属素線を撚り合わせて導体を構成した場合に、金属素線の表面を覆う酸化膜を導電粒子で破壊することができる。   In Patent Document 1, prior to compressing the compression terminal on the conductor of the electric wire, conductive particles (metal particles) are applied to the conductor of the electric wire, and when the compression terminal is compressed, the applied pressure at the time of compression is applied. A technique is described in which an oxide film on a conductor surface is broken through with conductive particles. According to this technique, when a conductor is formed by twisting metal strands made of aluminum, the oxide film covering the surface of the metal strands can be broken with the conductive particles.

特開平８−３２１３３１号公報JP-A-8-321331

導電粒子として、Ｚｎ粒子を用いた場合、金属素線の表面の酸化膜を破壊して、圧縮端子と電線との間の初期電気抵抗（以下、初期抵抗ともいう）を低減させることができる。しかし、圧縮端子と導体とがアルミニウムまたはアルミニウム合金からなる場合において、大電流の通電による温度上昇などにより圧縮端子と導体との接続部分が高温環境下に長時間曝されると、応力緩和によって金属素線間に作用する圧縮応力、及び金属素線と圧縮端子との間に作用する圧縮応力が弱まる。そうすると、圧縮端子と導体との接続部分では、金属素線の表面に酸化膜が再形成されてしまうか、又は金属素線間に隙間が生じてしまう。その結果、圧縮端子と電線との間の電気抵抗が初期抵抗と比べて増加する虞があった。   When Zn particles are used as the conductive particles, the oxide film on the surface of the metal strand can be destroyed, and the initial electrical resistance (hereinafter also referred to as initial resistance) between the compression terminal and the electric wire can be reduced. However, when the compression terminal and the conductor are made of aluminum or an aluminum alloy, if the connecting portion between the compression terminal and the conductor is exposed to a high temperature environment for a long time due to a temperature rise caused by energization of a large current, The compressive stress acting between the strands and the compressive stress acting between the metal strand and the compression terminal are weakened. If it does so, in the connection part of a compression terminal and a conductor, an oxide film will be re-formed on the surface of a metal strand, or a crevice will arise between metal strands. As a result, there is a possibility that the electrical resistance between the compression terminal and the electric wire is increased as compared with the initial resistance.

本発明の主な目的は、圧縮接続された端子と電線の導体との間の電気抵抗が、高温環境下に曝されても増加し難い端子付き電線を提供することにある。   A main object of the present invention is to provide a terminal-attached electric wire in which the electrical resistance between the terminal connected by compression and the conductor of the electric wire does not easily increase even when exposed to a high temperature environment.

本発明は、アルミニウム又はアルミニウム合金からなる導体を絶縁被覆で被覆してなる電線と、前記電線の端部において、前記導体が前記絶縁被覆で被覆されずに露出してなる導体露出部に圧縮接続される圧縮部を有する圧縮端子と、を備える端子付き電線であって、前記導体露出部には、Ｎｉ−ＰまたはＮｉ−Ｂからなる導電粒子を含む導電粒子入りコンパウンドが付着しており、前記導電粒子入りコンパウンド中の前記導電粒子の含有量が２０ｗｔ％以下である端子付き電線を提供する。   The present invention compresses and connects an electric wire formed by coating a conductor made of aluminum or an aluminum alloy with an insulating coating, and an exposed portion of the electric wire at which the conductor is exposed without being covered with the insulating coating. A compressed terminal having a compressed portion, wherein the conductor exposed portion is attached with a compound containing conductive particles including conductive particles made of Ni-P or Ni-B, Provided is a terminal-attached electric wire in which the content of the conductive particles in the compound containing conductive particles is 20 wt% or less.

本発明によれば、圧縮接続された端子と電線の端子との間の電気抵抗が、高温環境下に曝されても増加し難い端子付き電線を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the electrical resistance between the terminal connected by compression and the terminal of an electric wire can provide the electric wire with a terminal which is hard to increase even if exposed to a high temperature environment.

本発明の実施形態に係る端子付き電線の構成を説明するための模式図である。It is a schematic diagram for demonstrating the structure of the electric wire with a terminal which concerns on embodiment of this invention. 本発明の実施形態に係る電線の構成を示す断面図である。It is sectional drawing which shows the structure of the electric wire which concerns on embodiment of this invention. 端子付き電線で生じる問題を説明する図である。It is a figure explaining the problem which arises with an electric wire with a terminal.

以下、本発明の実施の形態について図面を参照しつつ詳細に説明する。   Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

＜端子付き電線の構成＞
図１は本発明の実施形態に係る端子付き電線の構成を説明するための模式図である。
本発明の実施形態に係る端子付き電線１は、電線２と、圧縮端子３と、を備えた構成となっている。端子付き電線１は、たとえば、鉄道車両や自動車などの車両の内部に配線される配線材に用いることができる。もちろん、端子付き電線１は電気・電子機器等の車両以外の用途で用いることもできる。 <Configuration of electric wire with terminal>
Drawing 1 is a mimetic diagram for explaining the composition of the electric wire with a terminal concerning the embodiment of the present invention.
The electric wire with terminal 1 according to the embodiment of the present invention includes an electric wire 2 and a compression terminal 3. The electric wire 1 with a terminal can be used for the wiring material wired inside vehicles, such as a rail vehicle and a motor vehicle, for example. Of course, the electric wire 1 with a terminal can also be used for uses other than vehicles, such as an electrical / electronic device.

（電線）
電線２は、導体４と、この導体４を被覆する絶縁被覆５と、を備えた構成となっている。また、電線２は、当該電線２の端部に、導体４が絶縁被覆５で被覆されずに露出してなる導体露出部４ａを有する。この導体露出部４ａは、圧縮端子３と圧縮接続される部分となる。 (Electrical wire)
The electric wire 2 includes a conductor 4 and an insulating coating 5 that covers the conductor 4. Moreover, the electric wire 2 has a conductor exposed portion 4 a formed by exposing the conductor 4 without being covered with the insulating coating 5 at the end of the electric wire 2. The conductor exposed portion 4 a is a portion that is compression-connected to the compression terminal 3.

（導体）
導体４は、電線２の芯線を構成している。導体４は、たとえば、複数の金属素線１１を撚り合わせてなる同心撚り線、集合撚り線、又は複合撚り線によって構成されている。複合撚り線とは、図２に示すように、複数の金属素線１１を撚り合わせて集合撚り線１２とし、この集合撚り線１２を複数撚り合わせて構成されるものである。この場合、１本の集合撚り線１２を構成する金属素線１１の本数を「ｍ」とし、１本の複合撚り線を構成する集合撚り線１２の本数を「ｎ」とすると、１本の導体（複合撚り線）４を構成する金属素線１１の総本数は「ｍ×ｎ」となる。金属素線１１は、たとえば、アルミニウムまたはアルミニウム合金によって構成されている。導体４の断面形状は、全体的に円形になっている。 (conductor)
The conductor 4 constitutes the core wire of the electric wire 2. The conductor 4 is configured by, for example, a concentric stranded wire, a collective stranded wire, or a composite stranded wire formed by twisting a plurality of metal strands 11. As shown in FIG. 2, the composite stranded wire is formed by twisting a plurality of metal strands 11 to form a collective stranded wire 12 and twisting the collective stranded wire 12 together. In this case, if the number of the metal strands 11 constituting one aggregate strand 12 is “m” and the number of the aggregate strands 12 constituting one composite strand is “n”, one wire The total number of the metal strands 11 constituting the conductor (composite stranded wire) 4 is “m × n”. The metal strand 11 is made of, for example, aluminum or an aluminum alloy. The cross-sectional shape of the conductor 4 is generally circular.

電線２の導体４を複合撚り線によって構成する主な理由は、電線２の大電流化と高屈曲性を両立させることにある。すなわち、電線２により多くの電流を流せるようにするためには導体４の実効断面積（ｓｑ値；ｓｑは平方ミリメートルの略）を大きくすることが有効であるが、そのために太い金属素線１１を用いると屈曲性が低下する。また、屈曲性を高めるには細い（例えば、直径が１ｍｍ以下である）金属素線１１を用いることが有効であるが、細い金属素線１１を集合撚りによって太くするにも限界がある。これに対して、本実施形態のように、複数の金属素線１１を撚り合わせて集合撚り線１２とし、この集合撚り線１２を複数撚り合わせた複合撚り線によって導体４を構成すれば、細い金属素線１１を使用した場合でも導体４の実効断面積を大きく確保することができる。このため、電線２の大電流化と高屈曲性を両立させることが可能となる。   The main reason for configuring the conductor 4 of the electric wire 2 with a composite stranded wire is to make the electric wire 2 have both high current and high flexibility. That is, in order to allow a larger amount of current to flow through the electric wire 2, it is effective to increase the effective cross-sectional area (sq value; sq is an abbreviation of square millimeter) of the conductor 4. If is used, the flexibility is lowered. In order to improve the flexibility, it is effective to use a thin metal wire 11 (for example, a diameter of 1 mm or less), but there is a limit to making the thin metal wire 11 thick by collective twisting. On the other hand, if the conductor 4 is constituted by a composite stranded wire obtained by twisting a plurality of the metal strands 11 to form a collective stranded wire 12 as in this embodiment, and a plurality of the collective stranded wires 12 are twisted together, it is thin. Even when the metal strand 11 is used, a large effective cross-sectional area of the conductor 4 can be secured. For this reason, it becomes possible to make high electric current and high flexibility of the electric wire 2 compatible.

圧縮端子３と圧縮接続される導体露出部４ａを構成する複数の金属素線１１には、それぞれ導電性の粒子（導電粒子）７を含む導電粒子入りコンパウンドが付着している。導電粒子入りコンパウンドとしては、例えば、潤滑油や増ちょう剤などからなるグリースに導電性の粒子が含まれているものからなる。導電粒子入りコンパウンドを構成する潤滑油としては、例えば、フッ素系油、シリコーン系油、エステル系油、合成炭化水素系油等がある。これらの潤滑油のうち、高温環境下に曝されても圧縮端子３と電線２の導体４との間の電気抵抗を増加しにくくする観点からすれば、フッ素系油、又はシリコーン系油を適用することが好ましい。導電粒子７は、導体４の導体露出部４ａと圧縮端子３の圧縮部８とを圧縮接続する際に、導体露出部４ａを構成する金属素線１１の表面を覆う酸化膜を破壊するように作用するものである。そのため、導電粒子７は、導体露出部４ａを構成する複数の金属素線１１の表面に付着していることが好ましい。導電粒子７は、導体露出部４ａを構成する複数の金属素線１１の表面に導電粒子入りコンパウンドを塗布すること、又は導電粒子入りコンパウンドがあらかじめ付着している圧縮部８の内部に導体露出部４ａを挿入して導電粒子入りコンパウンドが金属素線１１の表面に付着することにより、複数の金属素線１１の表面に導体露出部４ａの長手方向に沿って付着させることができる。導電粒子７は、導体４の内部と外周部を含めて、導体４の断面領域全体に設けられていることが好ましい。導体４の内部とは、導体４の外周部よりも内周側（導体４の径方向の中心側）の部分をいい、導体４の外周部とは、導体４を裸線状態（剥き出しの状態）で見たときに外部から視認できる導体４の外周まわりの部分をいう。また、導体４の断面領域とは、電線２の長さ方向と直交する方向に導体４を断面したときに、導体４を構成している複数の集合撚り線１２の断面の集合によって形成される略円形の領域をいう。図２においては、押さえテープ６の巻き位置よりも内側の領域が、導体４の断面領域となる。   A compound containing conductive particles including conductive particles (conductive particles) 7 is attached to the plurality of metal wires 11 constituting the conductor exposed portions 4a to be compressed and connected to the compression terminals 3. As the compound containing conductive particles, for example, grease containing lubricating oil, a thickener, etc. contains conductive particles. Examples of the lubricating oil constituting the compound containing conductive particles include fluorine oil, silicone oil, ester oil, and synthetic hydrocarbon oil. Of these lubricating oils, fluorine oil or silicone oil is applied from the viewpoint of making it difficult to increase the electrical resistance between the compression terminal 3 and the conductor 4 of the electric wire 2 even when exposed to a high temperature environment. It is preferable to do. When the conductive particles 7 compressively connect the conductor exposed portion 4a of the conductor 4 and the compressed portion 8 of the compression terminal 3, the conductive particles 7 destroy the oxide film covering the surface of the metal wire 11 constituting the conductor exposed portion 4a. It works. For this reason, the conductive particles 7 are preferably attached to the surfaces of the plurality of metal strands 11 constituting the conductor exposed portion 4a. The conductive particles 7 are formed by applying a compound containing conductive particles to the surfaces of the plurality of metal wires 11 constituting the conductor exposed portion 4a, or by exposing the conductor exposed portion inside the compression unit 8 to which the compound containing conductive particles is attached in advance. By inserting 4a and attaching the compound containing conductive particles to the surface of the metal strand 11, it can be attached to the surface of the plurality of metal strands 11 along the longitudinal direction of the conductor exposed portion 4a. The conductive particles 7 are preferably provided in the entire cross-sectional area of the conductor 4 including the inside and the outer periphery of the conductor 4. The inside of the conductor 4 refers to a portion on the inner peripheral side (center side in the radial direction of the conductor 4) from the outer peripheral portion of the conductor 4, and the outer peripheral portion of the conductor 4 refers to the conductor 4 in a bare wire state (a bare state). ) Means a portion around the outer periphery of the conductor 4 that can be visually recognized from the outside. The cross-sectional area of the conductor 4 is formed by a set of cross-sections of the plurality of aggregate strands 12 constituting the conductor 4 when the conductor 4 is cross-sectioned in a direction orthogonal to the length direction of the electric wire 2. A substantially circular region. In FIG. 2, a region inside the winding position of the pressing tape 6 is a cross-sectional region of the conductor 4.

導電粒子７は、導体４の断面領域全体に均等に分散していることが望ましい。本実施形態では、導体露出部４ａにおいて、導電粒子７が集合撚り線１２を構成する各々の金属素線１１の表面に付着している。そのため、導電粒子７は、集合撚り線１２の内部と外周部を含めて、集合撚り線１２の断面領域全体に多数分散している。また、このような集合撚り線１２を複数撚り合わせて、複合撚り線からなる１本の導体４を構成している。これにより、本実施形態では、導体４の導体露出部４ａの断面領域全体に導電粒子７を均等に分散させることができる。なお、集合撚り線１２の内部、外周部および断面領域の意味するところは、それぞれ導体４の場合と同様である。   It is desirable that the conductive particles 7 are evenly distributed throughout the cross-sectional area of the conductor 4. In the present embodiment, the conductive particles 7 adhere to the surface of each metal strand 11 constituting the aggregate strand 12 in the conductor exposed portion 4a. Therefore, a large number of conductive particles 7 are dispersed in the entire cross-sectional area of the collective stranded wire 12 including the inside and the outer peripheral portion of the collective stranded wire 12. A plurality of such stranded wires 12 are twisted together to form one conductor 4 made of a composite stranded wire. Thereby, in this embodiment, the electroconductive particle 7 can be disperse | distributed uniformly to the whole cross-sectional area | region of the conductor exposed part 4a of the conductor 4. FIG. In addition, the meaning of the inside, the outer peripheral portion, and the cross-sectional area of the assembly strand 12 is the same as that of the conductor 4.

導電粒子７のサイズに関しては、たとえば、金属素線１１の外径（直径）が０．４５ｍｍ（１ｍｍ以下）であるとすると、平均粒子径が１．０μｍ以上１０．０μｍ以下の微粒子を、導電粒子７として用いることができる。導電粒子７は、このような範囲の平均粒子径からなることにより、複数の金属素線１１を撚り合わせた撚り線からなる導体露出部４ａの内部に導電粒子入りコンパウンドが入り込みやすくなるため、導体露出部４ａを構成する金属素線１１の表面に導電粒子７が均一に付着しやすい。導電粒子７の平均粒子径は、金属素線１１の外径に応じて適宜変更可能である。なお、導電粒子７の平均粒子径は、レーザー回折散乱法によって求められる累積粒子径分布において、Ｄ５０（メジアン径）となる粒子径で表されるものである。   Regarding the size of the conductive particles 7, for example, if the outer diameter (diameter) of the metal strand 11 is 0.45 mm (1 mm or less), fine particles having an average particle diameter of 1.0 μm or more and 10.0 μm or less are electrically conductive. It can be used as particles 7. Since the conductive particles 7 have an average particle diameter in such a range, the compound containing the conductive particles can easily enter the conductor exposed portion 4a formed of a stranded wire obtained by twisting a plurality of metal strands 11. The conductive particles 7 tend to adhere uniformly to the surface of the metal wire 11 constituting the exposed portion 4a. The average particle diameter of the conductive particles 7 can be appropriately changed according to the outer diameter of the metal strand 11. The average particle diameter of the conductive particles 7 is represented by a particle diameter that becomes D50 (median diameter) in the cumulative particle diameter distribution obtained by the laser diffraction scattering method.

導電粒子７は、圧縮端子３を導体４の導体露出部４ａに圧縮接続するときに、金属素線１１の表面の酸化膜を突き破って金属素線１１の表面に食い込むことができる程度の硬さ（例えば、ビッカース硬さＨｖ４００以上）を有するものであればよい。また、導電粒子７は、金属素線１１の材料（すなわち、アルミニウム又はアルミニウム合金）との標準酸化還元電位差が小さい材料で構成されていることが望ましい。本実施形態では、高温環境下における端子付き電線１の電気抵抗（端子−電線間の電気抵抗）の変化を抑制するために、酸化しにくい材料、たとえば、Ｎｉ−ＰまたはＮｉ−Ｂからなる粒子によって導電粒子７を構成することが望ましい。このような材料で導電粒子７を構成することにより、長期にわたって高温環境下で使用される端子付き電線１の電気抵抗の変化を抑制することができる。   The conductive particles 7 are hard enough to penetrate the surface of the metal strand 11 by breaking through the oxide film on the surface of the metal strand 11 when the compression terminal 3 is compression-connected to the conductor exposed portion 4 a of the conductor 4. What is necessary is just to have (for example, Vickers hardness Hv400 or more). The conductive particles 7 are preferably made of a material having a small standard oxidation-reduction potential difference from the material of the metal wire 11 (that is, aluminum or aluminum alloy). In this embodiment, in order to suppress the change of the electrical resistance (electrical resistance between the terminal and the electric wire) of the electric wire with terminal 1 in a high temperature environment, particles made of a material that is not easily oxidized, for example, Ni-P or Ni-B. It is desirable to form the conductive particles 7 by the above. By constituting the conductive particles 7 with such a material, it is possible to suppress a change in electric resistance of the terminal-attached electric wire 1 used in a high temperature environment for a long period of time.

すなわち、端子付き電線１では、圧縮端子３と導体４とがアルミニウムまたはアルミニウム合金からなる場合において、大電流の通電による温度上昇などにより圧縮端子３と導体４の導体露出部４ａとの接続部分が高温環境下に長時間曝されたときに、応力緩和によって金属素線１１間に作用する圧縮応力、及び金属素線１１と圧縮端子３との間に作用する圧縮応力が弱まる。これに対して、本実施形態の端子付き電線１では、導体露出部４ａにＮｉ−ＰまたはＮｉ−Ｂからなる導電粒子７を含む導電粒子入りコンパウンドが付着していることにより、金属素線１１の表面に酸化膜が再形成されてしまうこと、及び金属素線１１間に隙間が生じてしまうことを防止することができる。その結果、本実施形態の端子付き電線１では、高温環境下に曝されても圧縮端子３と電線２との間の電気抵抗（すなわち、圧縮部８と導体露出部４ａとの間の電気抵抗）を初期抵抗と比べて増加しにくくすることができる。なお、本実施形態の端子付き電線１では、上述した作用効果を得られやすくするために、Ｎｉ−ＰまたはＮｉ−Ｂからなる導電粒子７を含む導電粒子入りコンパウンド中の導電粒子７の含有量が２０ｗｔ％以下であることが好ましく、２ｗｔ％以上２０ｗｔ％以下がより好ましい。   That is, in the electric wire with terminal 1, when the compression terminal 3 and the conductor 4 are made of aluminum or an aluminum alloy, a connection portion between the compression terminal 3 and the conductor exposed portion 4 a of the conductor 4 is caused by a temperature rise due to energization of a large current. When exposed to a high temperature environment for a long time, the compressive stress acting between the metal strands 11 and the compressive stress acting between the metal strand 11 and the compression terminal 3 are weakened by stress relaxation. On the other hand, in the electric wire 1 with a terminal according to the present embodiment, the conductive wire 4 containing the conductive particles 7 including the conductive particles 7 made of Ni-P or Ni-B is attached to the conductor exposed portion 4a. It is possible to prevent the oxide film from being re-formed on the surface and the formation of a gap between the metal strands 11. As a result, in the electric wire with terminal 1 of the present embodiment, even when exposed to a high temperature environment, the electric resistance between the compression terminal 3 and the electric wire 2 (that is, the electric resistance between the compression portion 8 and the conductor exposed portion 4a). ) Can be made difficult to increase compared to the initial resistance. In addition, in the electric wire 1 with a terminal of this embodiment, in order to make it easy to obtain the above-described effects, the content of the conductive particles 7 in the compound containing the conductive particles including the conductive particles 7 made of Ni-P or Ni-B. Is preferably 20 wt% or less, more preferably 2 wt% or more and 20 wt% or less.

（絶縁被覆）
絶縁被覆５は、絶縁材料によって構成されている。絶縁被覆５の材料としては、たとえば、フッ素系樹脂、オレフィン系樹脂、又はシリコーン系樹脂などを用いることができる。絶縁被覆５は、導体４の外周部を囲むように断面円形に形成されている。絶縁被覆５は、電線２の長手方向にわたって導体４を被覆している。ただし、図１に示すように、電線２の長手方向の端部では絶縁被覆５が被覆されていない部分を備えており、この部分によって導体４の一部（以下、「導体露出部」という。）４ａが露出している。導体露出部４ａは、導体４の全長にわたって絶縁被覆５が被覆された電線２の端部のみを剥ぐことによって得ることができる。また、導体露出部４ａは、電線２の端部のみをあらかじめ露出させた状態で導体４の周囲に絶縁被覆５を被覆させることなどによっても得ることができる。 (Insulation coating)
The insulating coating 5 is made of an insulating material. As a material of the insulating coating 5, for example, a fluorine resin, an olefin resin, or a silicone resin can be used. The insulating coating 5 is formed in a circular cross section so as to surround the outer periphery of the conductor 4. The insulating coating 5 covers the conductor 4 over the longitudinal direction of the electric wire 2. However, as shown in FIG. 1, the end portion of the electric wire 2 in the longitudinal direction is provided with a portion that is not covered with the insulating coating 5, and this portion is referred to as a part of the conductor 4 (hereinafter referred to as “conductor exposed portion”). 4a is exposed. The conductor exposed portion 4 a can be obtained by peeling only the end portion of the electric wire 2 covered with the insulating coating 5 over the entire length of the conductor 4. The conductor exposed portion 4a can also be obtained by covering the conductor 4 with the insulating coating 5 in a state where only the end of the electric wire 2 is exposed in advance.

電線２の径方向において、導体４と絶縁被覆５との間には押さえテープ６が介在している。押さえテープ６は、導体４と絶縁被覆５とを物理的に分離するように、導体４の外周部に巻かれている。導体４の外周部に押さえテープ６を巻く理由は、導体４の周囲に押し出し成形によって絶縁被覆５を形成する場合に、絶縁被覆５を構成する材料が金属素線１１に悪影響を及ぼさないようにするためである。ただし、導体４の露出部４ａでは、絶縁被覆５と一緒に押さえテープ６が剥がされている。   A pressing tape 6 is interposed between the conductor 4 and the insulating coating 5 in the radial direction of the electric wire 2. The holding tape 6 is wound around the outer periphery of the conductor 4 so as to physically separate the conductor 4 and the insulating coating 5. The reason why the holding tape 6 is wound around the outer periphery of the conductor 4 is that when the insulating coating 5 is formed around the conductor 4 by extrusion, the material constituting the insulating coating 5 does not adversely affect the metal strand 11. It is to do. However, the pressing tape 6 is peeled off together with the insulating coating 5 at the exposed portion 4 a of the conductor 4.

（圧縮端子）
圧縮端子３は、圧縮部８と、接続部９と、を一体に有している。圧縮端子３は、たとえば、アルミニウム又はアルミニウム合金からなる端子素材の表面に錫メッキなどからなるメッキを施したものである。なお、錫メッキ以外のメッキ（例えば、銀メッキなど）で構成してもよい。 (Compression terminal)
The compression terminal 3 integrally includes a compression portion 8 and a connection portion 9. The compression terminal 3 is obtained by plating a surface of a terminal material made of aluminum or an aluminum alloy, for example, with tin plating. In addition, you may comprise by plating (for example, silver plating etc.) other than tin plating.

圧縮部８は、電線２の導体４（導体露出部４ａ）に接続される部分となる。圧縮部８は、断面円形の筒状（円筒状）に形成されている。圧縮部８の内部は、電線２の導体４の露出部４ａを挿入可能な中空部１４になっている。中空部１４の一端（入口部分）は、電線２の導体４の外径よりも大きく開口している。圧縮部８は、図１に示すように、中空部１４の一端から電線２の導体４（導体露出部４ａ）が挿入された状態で所定の部分が圧縮される。これにより、圧縮部８は、導体４（導体露出部４ａ）の表面に接触した状態で圧縮接続されることになる。なお、圧縮部８は、導体４（導体露出部４ａ）の長手方向に対して複数の圧縮箇所（図１では、Ｐ１、Ｐ２、Ｐ３、Ｐ４）を有して、導体４（導体露出部４ａ）に圧縮接続されていることが好ましい。複数の圧縮箇所は、当該圧縮箇所の各々が所定の間隔で離間している。また、複数の圧縮箇所は、当該圧縮箇所の各々が圧縮部８の周方向の全周にわたって圧縮されている。圧縮部８は、導体４（導体露出部４ａ）の長手方向に対して上述したような複数の圧縮箇所を有することにより、特に圧縮端子３と導体４とがアルミニウム又はアルミニウム合金からなる場合において、圧縮端子３と導体４との間の電気抵抗を増加しにくくすることに有効である。   The compression part 8 becomes a part connected to the conductor 4 (conductor exposed part 4a) of the electric wire 2. The compression part 8 is formed in a cylindrical shape (cylindrical shape) having a circular cross section. The inside of the compression part 8 is a hollow part 14 into which the exposed part 4a of the conductor 4 of the electric wire 2 can be inserted. One end (entrance portion) of the hollow portion 14 opens larger than the outer diameter of the conductor 4 of the electric wire 2. As shown in FIG. 1, the compression portion 8 is compressed at a predetermined portion with the conductor 4 (conductor exposed portion 4 a) of the electric wire 2 inserted from one end of the hollow portion 14. Thereby, the compression part 8 is compression-connected in the state which contacted the surface of the conductor 4 (conductor exposed part 4a). In addition, the compression part 8 has a some compression location (in FIG. 1, P1, P2, P3, P4) with respect to the longitudinal direction of the conductor 4 (conductor exposed part 4a), and the conductor 4 (conductor exposed part 4a). ) Is preferably compression-connected. In the plurality of compressed locations, each of the compressed locations is separated by a predetermined interval. In addition, each of the plurality of compression points is compressed over the entire circumference in the circumferential direction of the compression unit 8. The compression portion 8 has a plurality of compression portions as described above with respect to the longitudinal direction of the conductor 4 (conductor exposed portion 4a), and particularly when the compression terminal 3 and the conductor 4 are made of aluminum or an aluminum alloy. This is effective for making it difficult to increase the electrical resistance between the compression terminal 3 and the conductor 4.

接続部９は、板状に形成されている。接続部９には、図示しない相手側端子との接続用孔１５が設けられている。接続用孔１５は、接続部９を厚み方向に貫通する状態で平面視円形に形成されている。接続部９の形状等は、相手側端子の形態に応じて任意に変更可能である。   The connection part 9 is formed in a plate shape. The connection portion 9 is provided with a connection hole 15 for connection with a counterpart terminal (not shown). The connection hole 15 is formed in a circular shape in plan view so as to penetrate the connection portion 9 in the thickness direction. The shape or the like of the connection portion 9 can be arbitrarily changed according to the form of the counterpart terminal.

以下、本発明を実施例によってさらに具体的に説明するが、本発明はこれらの実施例にのみ制限されるものではない。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited only to these examples.

（実施例）
実施例１〜４及び比較例１〜３の試料の構成を表１、２に示す。また、後述する評価項目についての評価結果も表１に示す。 (Example)
Tables 1 and 2 show the configurations of the samples of Examples 1 to 4 and Comparative Examples 1 to 3. Table 1 also shows evaluation results for evaluation items described later.

Figure 0006410163
Figure 0006410163

Figure 0006410163
Figure 0006410163

（実施例１）
実施例１では、以下の手順で端子付き電線の試料を製造した。具体的には、アルミニウムからなる複数本の金属素線を用いて製造した２００ＳＱ（平方ミリメートル）の断面積を有する複合撚り線の導体（金属素線の外径：φ０．４５ｍｍ、金属素線の総本数：３７×３４本）を準備し、当該導体の周囲に絶縁被覆を被覆して電線を製造した。この電線の一端において絶縁被覆を剥がして、導体の一端に導体露出部を形成した。この導体露出部に、平均粒子径が３μｍのＮｉ−Ｐからなる導電粒子を含有するフッ素系油で構成される導電粒子入りコンパウンドを塗布した。次に、アルミニウムからなる圧縮端子の圧縮部に、導電粒子入りコンパウンドが塗布された導体露出部を挿入し、挿入部を加締める（圧縮する）ことにより、アルミニウムからなる導体露出部とアルミニウムからなる圧縮端子の圧縮部とを電気的に接続し、端子付き電線の試料を製造した。ここで、Ｎｉ−Ｐからなる導電粒子の含有量は２ｗｔ％であった。 Example 1
In Example 1, the sample of the electric wire with a terminal was manufactured in the following procedures. Specifically, a conductor of a composite stranded wire having a cross-sectional area of 200 SQ (square millimeter) manufactured using a plurality of metal strands made of aluminum (the outer diameter of the metal strand: φ0.45 mm, The total number of wires: 37 × 34) was prepared, and an electric wire was manufactured by covering the conductor with an insulating coating. The insulation coating was peeled off at one end of the electric wire to form a conductor exposed portion at one end of the conductor. A conductive particle-containing compound composed of fluorine-based oil containing conductive particles made of Ni—P having an average particle diameter of 3 μm was applied to the exposed conductor portion. Next, the conductor exposed portion coated with the compound containing the conductive particles is inserted into the compressed portion of the compression terminal made of aluminum, and the inserted portion is crimped (compressed), whereby the conductor exposed portion made of aluminum and the aluminum are made. The compression part of the compression terminal was electrically connected to produce a sample of a terminal-attached electric wire. Here, the content of the conductive particles made of Ni—P was 2 wt%.

（実施例２）
実施例２では、Ｎｉ−Ｐからなる導電粒子の含有量が５ｗｔ％であるフッ素系油で構成される導電粒子入りコンパウンドを用い、それ以外は実施例１と同様に、端子付き電線の試料を製造した。 (Example 2)
In Example 2, using a compound containing conductive particles composed of fluorine-based oil having a content of conductive particles made of Ni-P of 5 wt%, a sample of a terminal-attached electric wire is obtained in the same manner as in Example 1 except that. Manufactured.

（実施例３）
実施例３では、Ｎｉ−Ｐからなる導電粒子の含有量が１０ｗｔ％であるフッ素系油で構成される導電粒子入りコンパウンドを用い、それ以外は実施例１と同様に、端子付き電線の試料を製造した。 (Example 3)
In Example 3, a compound containing conductive particles composed of fluorine-based oil having a content of conductive particles made of Ni-P of 10 wt% was used. Manufactured.

（実施例４）
実施例４では、Ｎｉ−Ｐからなる導電粒子の含有量が２０ｗｔ％であるフッ素系油で構成される導電粒子入りコンパウンドを用い、それ以外は実施例１と同様に、端子付き電線の試料を製造した。 Example 4
In Example 4, a compound containing conductive particles composed of fluorine-based oil having a conductive particle content of Ni-P of 20 wt% was used, and other than that, a sample of a terminal-attached electric wire was obtained in the same manner as in Example 1. Manufactured.

（比較例１）
比較例１では、導電粒子を含有するフッ素系油で構成される導電粒子入りコンパウンドを導体露出部に塗布せずに、アルミニウムからなる圧縮端子の圧縮部へ導体露出部を挿入し、挿入部を加締める（圧縮する）ことにより、アルミニウムからなる導体露出部とアルミニウムからなる圧縮端子の圧縮部とを電気的に接続を行い、端子付き電線の試料を製造した。 (Comparative Example 1)
In Comparative Example 1, the conductor exposed portion was inserted into the compressed portion of the compression terminal made of aluminum without applying the compound containing conductive particles composed of fluorine-based oil containing conductive particles to the conductor exposed portion, and the insertion portion was By crimping (compressing), the conductor exposed portion made of aluminum and the compressed portion of the compressed terminal made of aluminum were electrically connected to produce a sample of a terminal-attached electric wire.

（比較例２）
比較例２では、Ｎｉ−Ｐからなる導電粒子の代わりに、Ｚｎからなる導電粒子（含有量５ｗｔ％）を含有する導電粒子入りコンパウンドを用い、それ以外は実施例１と同様に、端子付き電線の試料を製造した。 (Comparative Example 2)
In Comparative Example 2, a compound containing conductive particles containing conductive particles (content 5 wt%) made of Zn was used instead of the conductive particles made of Ni-P, and the other was the same as in Example 1, except that the electric wire with terminal was used. Samples of

（比較例３）
比較例３では、Ｎｉ−Ｐからなる導電粒子の含有量が４０ｗｔ％であるフッ素系油で構成される導電粒子入りコンパウンドを用い、それ以外は実施例１と同様に、端子付き電線の試料を製造した。 (Comparative Example 3)
In Comparative Example 3, using a compound containing conductive particles composed of fluorine-based oil having a conductive particle content of Ni-P of 40 wt%, a sample of a terminal-attached electric wire was obtained in the same manner as in Example 1 except that. Manufactured.

（抵抗増加率）
抵抗増加率は、初期抵抗に対する高温環境暴露試験後の抵抗の値の変化率（（高温環境暴露試験後の抵抗の値／初期抵抗の値）×１００）である。
ここで初期抵抗の値は、製造した端子付き電線において、アルミニウムからなる圧縮端子と、アルミニウムからなる導体の他端との間で抵抗の測定を行った。
また、高温環境暴露試験は、初期抵抗の値を測定した後の端子付き電線を２００℃に設定した恒温槽に配置し、大気中で２００時間まで保持することによって行った。なお、高温環境暴露試験後の抵抗の値の測定は、試料を室温まで冷却した後に、初期抵抗の値を測定するときと同様の方法で行った。
抵抗増加率が、１５％以下であるものを合格とした。
以上の結果から、Ｎｉ−Ｐからなる導電粒子を含む導電粒子入りコンパウンドを用いたものは、Ｚｎからなる導電粒子を含む導電粒子入りコンパウンドを用いたものよりも抵抗増加率の増加を抑制できていることが確認された。特に、これらの粒子の含有量を２ｗｔ％以上２０ｗｔ％以下にすることにより、抵抗増加率を１５％以下に抑制できることが確認された。 (Resistance increase rate)
The resistance increase rate is the rate of change of the resistance value after the high-temperature environment exposure test with respect to the initial resistance ((resistance value after high-temperature environment exposure test / initial resistance value) × 100).
Here, the value of the initial resistance was measured for resistance between the compressed terminal made of aluminum and the other end of the conductor made of aluminum in the manufactured electric wire with terminal.
Moreover, the high temperature environment exposure test was performed by arrange | positioning the electric wire with a terminal after measuring the value of initial resistance to the thermostat set to 200 degreeC, and hold | maintaining in the atmosphere for 200 hours. The resistance value after the high-temperature environment exposure test was measured by the same method as that for measuring the initial resistance value after cooling the sample to room temperature.
A resistance increase rate of 15% or less was accepted.
From the above results, those using a compound containing conductive particles containing conductive particles made of Ni-P can suppress the increase in resistance increase rate more than those using a compound containing conductive particles containing conductive particles made of Zn. It was confirmed that In particular, it was confirmed that the resistance increase rate can be suppressed to 15% or less by setting the content of these particles to 2 wt% or more and 20 wt% or less.

（本発明の他の実施形態）
以上、本発明の一実施形態を具体的に説明したが、本発明は上述の実施形態に限定されるものではなく、その要旨を逸脱しない範囲で適宜変更可能である。
例えば、実施形態を具体的に示す実施例では、Ｎｉ−Ｐからなる導電粒子を含有するフッ素系油で構成される導電粒子入りコンパウンドを用いたが、シリコーン系油で構成される導電粒子入りコンパウンドも使用することができる。また、実施形態を具体的に示す実施例で用いた導電粒子入りコンパウンドでは、Ｎｉ−Ｐからなる導電粒子の代わりに、Ｎｉ−Ｂからなる導電粒子（含有量２ｗｔ％以上２０ｗｔ％以下）を用いることもできる。 (Other embodiments of the present invention)
As mentioned above, although one Embodiment of this invention was described concretely, this invention is not limited to the above-mentioned embodiment, In the range which does not deviate from the summary, it can change suitably.
For example, in the example specifically showing the embodiment, a compound containing conductive particles composed of fluorine-based oil containing conductive particles made of Ni-P was used, but a compound containing conductive particles composed of silicone-based oil was used. Can also be used. In addition, in the compound containing conductive particles used in Examples specifically showing the embodiment, conductive particles made of Ni-B (content of 2 wt% or more and 20 wt% or less) are used instead of the conductive particles made of Ni-P. You can also.

１…端子付き電線
２…電線
３…圧縮端子
４…導体
４ａ…導体露出部
５…絶縁被覆
７…導電粒子
８…圧縮部
１１…金属素線
１２…集合撚り線 DESCRIPTION OF SYMBOLS 1 ... Electric wire with a terminal 2 ... Electric wire 3 ... Compression terminal 4 ... Conductor 4a ... Conductor exposure part 5 ... Insulation coating 7 ... Conductive particle 8 ... Compression part 11 ... Metal strand 12 ... Collected strand wire

Claims (5)

アルミニウム又はアルミニウム合金からなる金属素線を複数本撚り合わせて構成された導体を絶縁被覆で被覆してなる電線と、
前記電線の端部において、前記導体が前記絶縁被覆で被覆されずに露出してなる導体露出部に圧縮接続される圧縮部を有する圧縮端子と、を備える端子付き電線であって、
前記導体露出部の前記金属素線のそれぞれの表面には、Ｎｉ−Ｐからなる導電粒子を含む導電粒子入りコンパウンドが付着しており、前記導電粒子入りコンパウンド中の前記導電粒子の含有量が２ｗｔ％以上２０ｗｔ％以下である
端子付き電線。 An electric wire formed by coating a conductor formed by twisting a plurality of metal wires made of aluminum or an aluminum alloy with an insulating coating;
At the end of the electric wire, the electric wire with a terminal comprising: a compression terminal having a compression portion that is compressed and connected to a conductor exposed portion formed by exposing the conductor without being covered with the insulating coating,
A compound containing conductive particles including conductive particles made of Ni-P is attached to each surface of the metal strand of the conductor exposed portion , and the content of the conductive particles in the compound containing conductive particles is 2 wt %. % To 20 wt%. 前記圧縮端子は、アルミニウム又はアルミニウム合金からなる請求項１に記載の端子付き電線。   The electric wire with a terminal according to claim 1, wherein the compression terminal is made of aluminum or an aluminum alloy. 前記圧縮部は、前記導体露出部の長手方向に対して複数の圧縮箇所を有する請求項１又は２に記載の端子付き電線。   The electric wire with a terminal according to claim 1 or 2 in which said compression part has a plurality of compression parts to the longitudinal direction of said conductor exposure part. 前記圧縮部は、前記複数の圧縮箇所の各々が離間している請求項３に記載の端子付き電線。 The electric wire with a terminal according to claim 3 , wherein each of the plurality of compression portions is separated from the compression portion. 前記複数の圧縮箇所は、前記圧縮部の周方向の全周にわたって圧縮されている請求項３又は４に記載の端子付き電線。   The terminal-attached electric wire according to claim 3 or 4, wherein the plurality of compression locations are compressed over the entire circumference in the circumferential direction of the compression section.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6923570B2 (en) 2019-01-23 2021-08-18 株式会社アマダ Laser machining equipment and laser machining head
JP2020119865A (en) * 2019-01-28 2020-08-06 日立金属株式会社 Electric wire with terminal, manufacturing method of the same, and terminal included in the same
JP7345978B2 (en) * 2019-09-24 2023-09-19 矢崎総業株式会社 Electric wire with terminal, manufacturing method of electric wire with terminal
JP6872088B1 (en) * 2020-03-27 2021-05-19 日本航空電子工業株式会社 Manufacturing method of contact members, connectors, compositions, contact members
JP7380459B2 (en) * 2020-07-13 2023-11-15 株式会社プロテリアル Electric wire with terminal

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003243057A (en) * 2002-02-18 2003-08-29 Auto Network Gijutsu Kenkyusho:Kk Wire connection terminal
JP2006149102A (en) * 2004-11-19 2006-06-08 Chugoku Electric Power Co Inc:The Compression sleeve for wire splicing
JP2009176729A (en) * 2007-12-25 2009-08-06 Oita Univ Sleeve with insulation coating for electric wire
JP2009193939A (en) * 2008-02-18 2009-08-27 Asahi Electric Works Ltd Compound coating method of sleeve, compound coating device, and compression connecting method of sleeve
JP2014127467A (en) * 2012-12-26 2014-07-07 Dokusan High Metal Co Ltd Conductive particle and conductive material containing conductive particle
JP2014164934A (en) * 2013-02-23 2014-09-08 Furukawa Electric Co Ltd:The Crimp terminal and method for manufacturing crimp terminal
WO2016076228A1 (en) * 2014-11-10 2016-05-19 古河電気工業株式会社 Covered electric wire, terminal-equipped covered electric wire, wire harness and covered electric wire production method
JP2017111883A (en) * 2015-12-14 2017-06-22 日立金属株式会社 Crimp terminal and wire with terminal

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08321331A (en) 1995-05-26 1996-12-03 Sumitomo Wiring Syst Ltd Method of joining electric wires
JP3847043B2 (en) * 1999-02-24 2006-11-15 ニチアス株式会社 Oil applicator
JP2010244895A (en) * 2009-04-07 2010-10-28 Hitachi Cable Ltd Compression connection terminal for aluminum conductors, and connection method thereof
JP2011040194A (en) * 2009-08-07 2011-02-24 Autonetworks Technologies Ltd Crimped electric wire with terminal and method for producing the same
CN202034505U (en) * 2011-04-28 2011-11-09 佟元江 Railway signal connecting wire
JP5687955B2 (en) * 2011-05-20 2015-03-25 矢崎総業株式会社 Structure and manufacturing method of crimp connection part of aluminum wire and metal terminal
JP5650611B2 (en) * 2011-08-23 2015-01-07 デクセリアルズ株式会社 Anisotropic conductive film, method for manufacturing anisotropic conductive film, connection method, and joined body
DE102011084174A1 (en) * 2011-10-07 2013-04-11 Tyco Electronics Amp Gmbh crimp
CN104380543B (en) * 2012-06-04 2016-03-02 松下知识产权经营株式会社 The manufacture method of the aluminium electric wire of the formation method in electric connection structure portion, band terminal, electric connection structure portion and possess its motor and possess the electric equipment of this motor, the aluminium electric wire of band terminal and possess its motor and possess the electric equipment of this motor

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003243057A (en) * 2002-02-18 2003-08-29 Auto Network Gijutsu Kenkyusho:Kk Wire connection terminal
JP2006149102A (en) * 2004-11-19 2006-06-08 Chugoku Electric Power Co Inc:The Compression sleeve for wire splicing
JP2009176729A (en) * 2007-12-25 2009-08-06 Oita Univ Sleeve with insulation coating for electric wire
JP2009193939A (en) * 2008-02-18 2009-08-27 Asahi Electric Works Ltd Compound coating method of sleeve, compound coating device, and compression connecting method of sleeve
JP2014127467A (en) * 2012-12-26 2014-07-07 Dokusan High Metal Co Ltd Conductive particle and conductive material containing conductive particle
JP2014164934A (en) * 2013-02-23 2014-09-08 Furukawa Electric Co Ltd:The Crimp terminal and method for manufacturing crimp terminal
WO2016076228A1 (en) * 2014-11-10 2016-05-19 古河電気工業株式会社 Covered electric wire, terminal-equipped covered electric wire, wire harness and covered electric wire production method
JP2017111883A (en) * 2015-12-14 2017-06-22 日立金属株式会社 Crimp terminal and wire with terminal

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