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JP6326953B2 - Coke oven coal charging method - Google Patents

Coke oven coal charging method Download PDF

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JP6326953B2
JP6326953B2 JP2014100453A JP2014100453A JP6326953B2 JP 6326953 B2 JP6326953 B2 JP 6326953B2 JP 2014100453 A JP2014100453 A JP 2014100453A JP 2014100453 A JP2014100453 A JP 2014100453A JP 6326953 B2 JP6326953 B2 JP 6326953B2
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coke oven
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bulk density
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JP2015218189A (en
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裕樹 藤田
裕樹 藤田
鈴木 博
博 鈴木
深澤 康裕
康裕 深澤
正 梅津
正 梅津
健介 正木
健介 正木
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Nippon Steel Corp
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Description

本発明は、高炉向けコークスを製造するコークス炉に装入する石炭の装入方法に関し、殊に、石炭の装入嵩密度を制御可能なコークス炉の石炭装入方法に関するものである。   The present invention relates to a method for charging coal charged in a coke oven for producing coke for a blast furnace, and more particularly to a method for charging coal in a coke oven capable of controlling the bulk density of coal charged.

高炉向けコークスは、石炭をコークス炉に装入し、乾留して、石炭中の揮発分を除去することによって製造される。従来、石炭の嵩密度向上によるコークス強度の向上や、乾留時間の短縮による生産性の向上等の観点から、原料石炭を事前に乾燥、加熱する事前処理を行った後に、コークス炉に装入することが行われている。   Coke for blast furnaces is produced by charging coal into a coke oven and dry distillation to remove volatiles in the coal. Conventionally, from the viewpoint of improving the coke strength by improving the bulk density of coal and improving productivity by shortening the carbonization time, the raw coal is preliminarily dried and heated before being charged into the coke oven. Things have been done.

また、原料石炭には、粒径の比較的大きな(例えば0.5mm超)粗粒炭と、粒径の比較的小さな(例えば0.5mm以下)細粒炭とが含まれている。このうち、細粒炭は、乾燥、加熱の際に発塵したり、コークス炉での乾留によって発生するコークス炉ガス等に乗って、炉頂空間や上昇管等に付着し通気性を阻害する、キャリーオーバー現象と呼ばれる現象が起こることがある。そのため、従来、原料石炭を乾燥、加熱するとともに、分級して粗粒炭と細粒炭とに分離し、分離した細粒炭を塊成化した後に、粗粒炭と混合してコークス炉に装入することが行われている。   The raw coal includes coarse coal having a relatively large particle size (for example, more than 0.5 mm) and fine coal having a relatively small particle size (for example, 0.5 mm or less). Among these, fine-grained coal generates dust during drying and heating, rides on coke oven gas generated by dry distillation in a coke oven, etc., adheres to the furnace top space, riser pipe, etc. and impairs air permeability. A phenomenon called carry-over phenomenon may occur. Therefore, conventionally, the raw coal is dried and heated, classified and separated into coarse coal and fine coal, and the separated fine coal is agglomerated and then mixed with the coarse coal into a coke oven. Charging is done.

コークス炉に装入する石炭は、嵩密度を上昇させることにより、コークスの品質が向上するというメリットはあるが、押出負荷が増大するため、炉況や窯のコンディションに合わせて嵩密度を制御することが望ましい。   Coal charged in the coke oven has the merit of improving the coke quality by increasing the bulk density, but the extrusion load increases, so the bulk density should be controlled according to the furnace conditions and kiln conditions. Is desirable.

例えば特許文献1には、装入炭の水分や成型炭の配合率等を変化させて、装入炭の嵩密度を制御する技術が開示されている。また、特許文献2には、処理炭の粒度分布を調整することで、装入炭の嵩密度分布のバラツキを低減させることが開示されている。   For example, Patent Literature 1 discloses a technique for controlling the bulk density of the charged coal by changing the moisture content of the charged coal, the blending ratio of the cast coal, and the like. Patent Document 2 discloses that the variation in the bulk density distribution of the charged coal is reduced by adjusting the particle size distribution of the treated coal.

特開昭63−202691号公報JP 63-202691 A 特開昭59−36188号公報JP 59-36188

しかしながら、嵩密度を制御する手段として水分を調整する場合、水分を下げすぎると過熱する場合があり、上げすぎると送炭過程でベルトコンベアなどに付着してトラブルを生じる場合がある。また、成型炭配合率による制御の場合は、成型炭配合率が高すぎると偏析が起こりやすくなる等の問題がある。したがって、これらの手段では、嵩密度の制御範囲に制限が生じる。   However, when adjusting the moisture as a means for controlling the bulk density, if the moisture is lowered too much, it may overheat, and if it is raised too much, it may adhere to the belt conveyor or the like during the coal feeding process and cause trouble. In addition, in the case of the control by the coal blending ratio, there is a problem that segregation is likely to occur if the coal blending ratio is too high. Therefore, these means limit the control range of the bulk density.

本発明の目的は、コークス炉に装入する石炭において、水分や成型炭配合率を変化させることなく、装入炭の嵩密度を制御することを目的とする。   The object of the present invention is to control the bulk density of the charged coal in the coal charged into the coke oven without changing the water content or the ratio of coal blending.

上記問題を解決するため、本発明は、原料石炭を流動層乾燥機に装入し、前記流動層乾燥機で前記原料石炭を乾燥させるとともに粗粒炭と細粒炭とに分級し、前記細粒炭のみを混練機でバインダと混練し、その混練物を塊成機の成型ロールで加圧して成型炭を形成し、前記成型炭と前記粗粒炭とを混合した装入炭をコークス炉に装入するコークス炉の石炭装入方法において、前記混練機は横型混練機であり、パドル周速を2.4〜4.9m/secに制御し、且つ、前記成型ロールの周速を0.25〜0.31m/secに制御することで、前記成型炭の成型率を変化させ、前記装入炭の嵩密度を0.75〜0.83t/mに制御することを特徴とする、コークス炉の石炭装入方法を提供する。
In order to solve the above problems, the present invention introduces raw coal into a fluidized bed dryer, dries the raw coal with the fluidized bed dryer, classifies it into coarse coal and fine coal, Only granulated coal is kneaded with a binder in a kneader, the kneaded product is pressed with a molding roll of an agglomerator to form molded coal, and the charged coal obtained by mixing the molded coal and the coarse coal is coke oven In the method of charging coal in a coke oven, the kneader is a horizontal kneader, the paddle peripheral speed is controlled to 2.4 to 4.9 m / sec , and the peripheral speed of the molding roll is 0. By controlling to .25 to 0.31 m / sec, the molding rate of the coal is changed, and the bulk density of the charging coal is controlled to 0.75 to 0.83 t / m 3. To provide a method for charging coal in a coke oven.

本発明によれば、装入炭の水分や成型炭配合率を変化させることなく、コークス炉装入炭の嵩密度を制御することができる。   According to the present invention, the bulk density of the coke oven charging coal can be controlled without changing the moisture of the charging coal or the blending ratio of the formed coal.

本発明の一実施形態に係るコークス炉装入炭の製造設備の全体構成の概略を示す説明図である。It is explanatory drawing which shows the outline of the whole structure of the manufacturing equipment of the coke oven charging coal which concerns on one Embodiment of this invention. パドル周速および成型ロールの周速毎の成型炭の成型率を示すグラフである。It is a graph which shows the molding rate of the charcoal for every paddle peripheral speed and peripheral speed of a forming roll. パドル周速および成型ロールの周速毎の成型炭の嵩密度を示すグラフである。It is a graph which shows the bulk density of the charcoal for every paddle peripheral speed and peripheral speed of a forming roll.

以下、本発明の実施の形態を、図を参照して説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

本発明にかかるコークス炉装入炭の製造方法の概要は、先ず、コークス炉に装入する原料石炭を流動層乾燥機に装入し、原料石炭を乾燥、加熱するとともに、原料石炭を粗粒炭と細粒炭とに分級する。そして、細粒炭をバインダとともに混練機で撹拌して混練物とし、この混練物を、一対の加圧成型ロールを備えた塊成機へ送り、塊成機で成型炭を形成する。この成型炭と粗粒炭とを混合したものが、装入炭となる。   The outline of the method for producing the coke oven charging coal according to the present invention is as follows. First, the raw material coal charged into the coke oven is charged into a fluidized bed dryer, the raw material coal is dried and heated, and the raw material coal is coarse-grained. Classification into charcoal and fine coal. Then, the fine-grained charcoal is stirred together with a binder in a kneader to obtain a kneaded product, and the kneaded product is sent to an agglomerator equipped with a pair of pressure forming rolls, and the agglomerator forms the coal. A mixture of this coal and coarse coal becomes the charging coal.

図1は、上記の装入炭の製造を行う製造設備の全体構成の概要を示す。本実施形態に係るコークス炉装入炭の製造設備1は、コークス炉7に装入する石炭の事前処理を行う設備であり、原料石炭を乾燥及び加熱することで、コークス炉7における乾留時間を短縮し、かつ、原料石炭中の細粒炭を分級して塊成化することで、細粒炭の発塵やキャリーオーバー現象を抑制するものである。   FIG. 1 shows an overview of the overall configuration of a production facility for producing the above-mentioned charging coal. The coke oven charging coal manufacturing facility 1 according to the present embodiment is a facility for pre-treating coal to be charged into the coke oven 7, and drying and heating the raw coal allows the carbonization time in the coke oven 7 to be increased. By shortening and classifying and agglomerating fine coal in the raw coal, dust generation and carry-over phenomenon of fine coal are suppressed.

図1に示すように、コークス炉装入炭の製造設備1は、湿炭槽2、流動層乾燥機3、混練機4、塊成機5、石炭槽6を有している。   As shown in FIG. 1, a coke oven charging coal production facility 1 includes a wet coal tank 2, a fluidized bed dryer 3, a kneader 4, an agglomerator 5, and a coal tank 6.

湿炭槽2には、コークス炉7に装入するために事前処理を行う対象となる原料石炭が貯蓄されている。原料石炭は、通常、8〜12質量%程度の水分を含んでおり、これを乾燥して2〜5質量%程度の水分量まで低減させた後、コークス炉7に装入する。また、原料石炭は、広範な粒度を有する(0.1mm〜10mm程度)ため、粒径に応じて、細粒炭と粗粒炭とに分級する。細粒炭と粗粒炭それぞれの粒径範囲は、コークス炉7の設備構成や塊成機5による塊成条件等によって適宜設定すればよいが、例えば、概ね、粒径が0.5mm(又は0.3mm)以下のものを細粒炭、粒径が0.5mm(又は0.3mm)超のものを粗粒炭とする。   In the wet coal tank 2, raw material coal to be pretreated for charging into the coke oven 7 is stored. The raw material coal usually contains about 8 to 12% by mass of moisture, which is dried and reduced to a moisture content of about 2 to 5% by mass, and then charged into the coke oven 7. Moreover, since raw material coal has a wide particle size (about 0.1 mm-10 mm), it classifies into fine coal and coarse coal according to a particle size. The particle size ranges of the fine coal and the coarse coal may be appropriately set depending on the equipment configuration of the coke oven 7, the agglomeration conditions by the agglomerator 5 and the like. 0.3 mm) or less is defined as fine-grained coal, and those having a particle size exceeding 0.5 mm (or 0.3 mm) are defined as coarse-grained coal.

流動層乾燥機3は、湿炭槽2から供給された原料石炭を、熱風により乾燥及び加熱するとともに、加熱した原料石炭中の粗粒炭と細粒炭とを分級する装置であり、従来公知の流動層乾燥装置を用いることができる。   The fluidized bed dryer 3 is an apparatus for drying and heating the raw coal supplied from the wet coal tank 2 with hot air and classifying the coarse coal and fine coal in the heated raw coal. The fluidized bed drying apparatus can be used.

流動層乾燥機3で加熱分級された粗粒炭は、流動層乾燥機3から排出されて、石炭槽6へ向けて搬送される。一方、流動層乾燥機3で加熱分級された細粒炭は、流動層乾燥機3から排出された後、混練機4へ搬送される。   The coarse coal that has been heated and classified by the fluidized bed dryer 3 is discharged from the fluidized bed dryer 3 and conveyed toward the coal tank 6. On the other hand, the fine coals classified by heating in the fluidized bed dryer 3 are discharged from the fluidized bed dryer 3 and then conveyed to the kneader 4.

混練機4は横型混練機が用いられ、流動層乾燥機3から搬送された細粒炭と、塊成用のバインダとが供給され、パドル11によってこれらを混練する。そして、細粒炭とバインダとの混練物が、塊成機5に供給される。混練物にされる細粒炭は、例えば粒径が0.5mm以下、水分が10質量%以下の粉状石炭である。バインダには、コークスから副生されるタール系のものが用いられ、例えば、コークス炉に装入した石炭を乾留することにより副生するコ−ルタールを蒸留し、タール軽油、カルボル油、ナフタリン油、洗浄油等の低沸点油が10質量%以下、クレオソート油、ピレン等の軽質油と低沸点油との合計が15〜20質量%を含有するバインダが望ましい。なお、このバインダは、特開2004−149647号公報に開示されているものである。このような細粒炭とバインダを混練機4へ供給して撹拌し、混練物を製造する。この混練機4は、例えば、従来公知のネスコニーダ、パドルミキサー、ピンミキサー、または、筒状の搬送路内に1本または2本のスクリュー(回転軸の周囲に螺旋状に羽根が設けられたもの)が回転可能に設けられたもの等を使用できる。   As the kneader 4, a horizontal kneader is used. Fine coal conveyed from the fluidized bed dryer 3 and a binder for agglomeration are supplied, and these are kneaded by the paddle 11. Then, a kneaded product of fine-grained coal and binder is supplied to the agglomerator 5. The fine coal used in the kneaded material is, for example, pulverized coal having a particle size of 0.5 mm or less and a water content of 10 mass% or less. As the binder, tar-based ones that are by-produced from coke are used. For example, coal tar produced as a by-product by distillation of coal charged in a coke oven is distilled to produce tar light oil, carbol oil, naphthalene oil. A binder containing 10% by mass or less of low boiling point oil such as cleaning oil and 15 to 20% by mass of the total of light oils such as creosote oil and pyrene and low boiling point oil is desirable. This binder is disclosed in Japanese Patent Application Laid-Open No. 2004-149647. Such fine coal and binder are supplied to the kneader 4 and stirred to produce a kneaded product. This kneading machine 4 is, for example, a conventionally known Nesconida, paddle mixer, pin mixer, or one or two screws in a cylindrical conveying path (having spiral blades around the rotating shaft) ) Can be used.

製造された混練物は、多数の細粒炭がバインダによって結合された擬似造粒物の形態となっている。この混練物を製造する際、パドル11の周速を下げることで、細粒炭の滞留時間を確保でき、細粒炭とバインダとの混練が均一化される。それにより、装入炭の嵩密度を増加させることができる。ただし、パドル11の周速を下げすぎると、十分な混練が行えなくなる。パドル周速を2.4〜4.9m/secに制御することにより、水分が2〜5質量%の装入炭の嵩密度を適切に制御することができる。   The manufactured kneaded material is in the form of a pseudo-granulated product in which a large number of fine coals are combined by a binder. When manufacturing this kneaded material, the residence time of the fine coal can be ensured by lowering the peripheral speed of the paddle 11, and the fine coal and the binder are uniformly kneaded. Thereby, the bulk density of charging coal can be increased. However, if the peripheral speed of the paddle 11 is too low, sufficient kneading cannot be performed. By controlling the paddle circumferential speed to 2.4 to 4.9 m / sec, the bulk density of the charged coal having a moisture content of 2 to 5 mass% can be appropriately controlled.

塊成機5は、一対の成型ロール21、22を有している。混練機4から供給された細粒炭とバインダとの混練物は、塊成機5の上部に設けられた調整板23で成型ロール21、22への噛み込み量を調整され、押し込みスクリュー24によって一対の成型ロール21、22の間に押し込まれる。成型ロール21、22は、所定のロールギャップを有して配置されており、一方の成型ロール21が固定され、他方の成型ロール22が油圧により一定圧力で押されて回転し、これにより、塊成された成型炭が得られる。   The agglomerator 5 has a pair of molding rolls 21 and 22. The kneaded product of fine coal and binder supplied from the kneading machine 4 is adjusted in the amount of biting into the molding rolls 21 and 22 by the adjusting plate 23 provided at the upper part of the agglomerating machine 5. It is pushed between the pair of molding rolls 21 and 22. The molding rolls 21 and 22 are arranged with a predetermined roll gap, and one molding roll 21 is fixed, and the other molding roll 22 is pressed and rotated by hydraulic pressure at a constant pressure. The formed coal is obtained.

このように、混練物が一対の成型ロール21、22により加圧成形されて成型炭が製造される際、成型ロール22の周速を下げることによって、混練物にかかる仕事量が増し、嵩密度を増加させるとともに、成型炭の歩留を向上させることができる。ただし、成型ロールの周速を下げすぎると、生産性が低下する。成型ロールの周速を0.25〜0.31m/secに制御することにより、水分が2〜5質量%の装入炭の嵩密度および成型炭の成型率を適切に制御することができる。この水分の条件において、装入炭の嵩密度の下限は、成型率0%に相当する0.75t/m程度である。嵩密度の上限は、成型率の上限90%程度に相当する0.83t/m程度である。 In this way, when the kneaded product is pressure-molded by the pair of molding rolls 21 and 22 to produce molded charcoal, the work speed applied to the kneaded product is increased by reducing the peripheral speed of the molding roll 22, and the bulk density is increased. And the yield of coal char can be improved. However, if the peripheral speed of the forming roll is lowered too much, the productivity is lowered. By controlling the peripheral speed of the forming roll to 0.25 to 0.31 m / sec, the bulk density of the charged coal having a moisture content of 2 to 5% by mass and the molding rate of the formed coal can be appropriately controlled. Under this moisture condition, the lower limit of the bulk density of the charged coal is about 0.75 t / m 3 corresponding to a molding rate of 0%. The upper limit of the bulk density is about 0.83 t / m 3 corresponding to the upper limit of about 90% of the molding rate.

塊成機5で製造された成型炭は、粗粒炭と合流して混合されたのち、石炭槽6まで搬送されて石炭槽6で貯留され、粗粒炭及び成型炭は、装入コンベア等によってコークス炉7に装入される。   The coal coal produced by the agglomerator 5 is mixed with coarse coal and mixed, and then transported to the coal tank 6 and stored in the coal tank 6. Coarse coal and coal coal are charged conveyors, etc. Is charged into the coke oven 7.

以上、本発明の好適な実施形態について説明したが、本発明はかかる例に限定されない。当業者であれば、特許請求の範囲に記載された技術的思想の範疇内において、各種の変更例または修正例に想到しうることは明らかであり、それらについても当然に本発明の技術的範囲に属するものと了解される。   As mentioned above, although preferred embodiment of this invention was described, this invention is not limited to this example. It is obvious for those skilled in the art that various changes or modifications can be conceived within the scope of the technical idea described in the claims. It is understood that it belongs to.

図1に示すコークス炉装入炭の製造設備1により、装入炭の製造を行った。原料石炭は、流動層乾燥機で2〜5質量%の水分量とし、混練機4のパドル周速を、2.4m/sec、3.7m/sec、4.9m/secの3種類とし、それぞれのパドル周速に対して、塊成機5の成型ロールの周速を、0.25m/sec、0.28m/sec、0.31m/secの3種類とした。   The charging coal was manufactured by the coke oven charging coal manufacturing equipment 1 shown in FIG. The raw material coal has a moisture content of 2 to 5% by mass in a fluidized bed dryer, and the paddle peripheral speed of the kneader 4 is 2.4 m / sec, 3.7 m / sec, and 4.9 m / sec. For each paddle circumferential speed, the circumferential speed of the forming roll of the agglomerator 5 was set to three types of 0.25 m / sec, 0.28 m / sec, and 0.31 m / sec.

図2は、パドルの周速および成型ロールの周速毎の成型炭の成型率を示し、図3は、パドルの周速および成型ロールの周速毎の装入炭の嵩密度を示す。図2、図3に示すように、パドル周速、ロール周速のいずれについても、低くするにつれて、成型炭の成型率および装入炭の嵩密度が高くなった。例えばパドル周速を2.4m/secとした場合には、成型ロールの周速が図2に示す本実施例の範囲において、成型率を30%〜86%とすることができた。ここでいう成型率とは、10mm篩上の割合を意味する。そして、例えばパドル周速が4.9m/secで、成型ロールの周速が図3に示す本実施例の範囲では、装入炭の嵩密度が0.76〜0.79t/mとなり、パドル周速が2.4〜4.9m/secで、成型ロールの周速が図3に示す本実施例の範囲において、装入炭の嵩密度を0.76〜0.83t/mとすることができた。また、パドル周速が2.4〜4.9m/secの範囲において、さらに成型ロールの周速を0.25〜0.28m/secに制御することで、装入炭の嵩密度を0.77〜0.83t/mに制御することができた。 FIG. 2 shows the molding rate of the charcoal for each peripheral speed of the paddle and the peripheral speed of the molding roll, and FIG. 3 shows the bulk density of the charged coal for each peripheral speed of the paddle and the peripheral speed of the molding roll. As shown in FIGS. 2 and 3, as the paddle circumferential speed and the roll circumferential speed were both lowered, the molding rate of the coal and the bulk density of the charging coal were increased. For example, when the paddle circumferential speed was 2.4 m / sec, the molding rate could be 30% to 86% within the range of the present embodiment shown in FIG. The molding rate here means the ratio on a 10 mm sieve. And, for example, the paddle peripheral speed is 4.9 m / sec, and the peripheral speed of the molding roll is within the range of the present embodiment shown in FIG. 3, the bulk density of the charged coal becomes 0.76 to 0.79 t / m 3 , The paddle circumferential speed is 2.4 to 4.9 m / sec, and the circumferential speed of the molding roll is within the range of the present embodiment shown in FIG. 3, and the bulk density of the charged coal is 0.76 to 0.83 t / m 3 . We were able to. Further, when the paddle circumferential speed is in the range of 2.4 to 4.9 m / sec, the bulk density of the charging coal is set to 0.00 by further controlling the circumferential speed of the molding roll to 0.25 to 0.28 m / sec. It was possible to control to 77 to 0.83 t / m 3 .

本発明は、高炉向けコークスを製造するコークス炉に装入する原料石炭の事前処理に適用できる。   INDUSTRIAL APPLICABILITY The present invention can be applied to pretreatment of raw material coal charged in a coke oven that produces coke for a blast furnace.

1 コークス炉装入炭の製造設備
2 湿炭槽
3 流動層乾燥機
4 混練機
5 塊成機
6 石炭槽
7 コークス炉
11 パドル
21、22 成型ロール
DESCRIPTION OF SYMBOLS 1 Coke oven charging coal manufacturing equipment 2 Wet coal tank 3 Fluidized bed dryer 4 Kneading machine 5 Agglomeration machine 6 Coal tank 7 Coke oven 11 Paddles 21 and 22 Forming rolls

Claims (1)

原料石炭を流動層乾燥機に装入し、前記流動層乾燥機で前記原料石炭を乾燥させるとともに粗粒炭と細粒炭とに分級し、前記細粒炭のみを混練機でバインダと混練し、その混練物を塊成機の成型ロールで加圧して成型炭を形成し、前記成型炭と前記粗粒炭とを混合した装入炭をコークス炉に装入するコークス炉の石炭装入方法において、
前記混練機は横型混練機であり、パドル周速を2.4〜4.9m/secに制御し、且つ、前記成型ロールの周速を0.25〜0.31m/secに制御することで、前記成型炭の成型率を変化させ、前記装入炭の嵩密度を0.75〜0.83t/mに制御することを特徴とする、コークス炉の石炭装入方法。
Raw coal is charged into a fluidized bed dryer, the raw coal is dried with the fluidized bed dryer and classified into coarse coal and fine coal, and only the fine coal is kneaded with a binder with a kneader. The coke oven is charged with a molding roll of an agglomerator to form a coal, and a coal charging method for a coke oven is performed by charging the coal obtained by mixing the coal and the coarse coal into the coke oven. In
The kneader is a horizontal kneader, and the paddle peripheral speed is controlled to 2.4 to 4.9 m / sec, and the peripheral speed of the molding roll is controlled to 0.25 to 0.31 m / sec. A method for charging coal in a coke oven, wherein the molding rate of the coal is changed and the bulk density of the coal is controlled to 0.75 to 0.83 t / m 3 .
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