JP6246667B2 - Improved process for bonding a reactive adhesive to a substrate - Google Patents

Description

  The present invention relates to a method for improving the adhesion and coupling speed of a reactive adhesive to a substrate.

Reactive adhesives such as isocyanate functional (polyurethane or urea forming), epoxy-based and silanol condensation based adhesives are used to bond a wide range of substrates together. The adhesive is used in construction, vehicle manufacturing, electronic subassemblies and device assembly, toys and the like. The adhesive has found a wide range of uses because it allows processing conditions that are less expensive and exhibits good adhesion to a large number of substrates. For many substrates, the process used to assemble the parts with reactive adhesives requires cleaning the substrate surface to remove contaminants and used to clean the surface The system that is done is sometimes called a wipe. In many processes, a primer or activator is utilized to facilitate adhesion of the adhesive to the substrate. The primer or activator system typically contains a film-forming resin, a solvent and one or more adhesion promoters, catalysts, curing agents or crosslinkers. See, for example, German Patent No. 19924139. The primer requires the formation of a film that binds to the substrate surface and the adhesive surface on the substrate surface. For most commercial applications, the primer requires a minimum amount of time between primer application and adhesive application to allow proper film construction. If the adhesive is applied before such a minimum time, the primer has no opportunity to form an adherent film, creating a great risk that it will not bond to either the substrate surface or the adhesive surface. Many primers are moisture curable primers and require the presence of moisture to form a proper film.
Examples of said primers are US Pat. No. 5,115,086; US Pat. No. 5,238,993.
U.S. Pat. No. 5,466,727; U.S. Pat. No. 5,468,317; U.S. Pat.
792,811, which is hereby incorporated by reference in its entirety. Non-film-forming solutions of adhesion promoters, often referred to as activators, are used, which can contain groups intended to react with the substrate and the adhesive. Examples of wipe systems are included in US Pat. No. 6,053,971, which is incorporated herein by reference. Examples of such adhesion promoters useful in the system include, for example, US Patent Application Publication No. 2005/0126683 and US Patent Application Publication No. 2006/012, both of which are incorporated herein by reference.
Silanes, isocyanate-containing compounds, titanates and zirconates disclosed in No. 4225.

One-part isocyanate functional adhesives contain one or more isocyanate functional materials, typically in the form of polyisocyanates or isocyanate functional prepolymers, and a catalyst for curing the adhesive. Typically, these adhesives cure as a result of exposure to moisture and are protected from moisture until applied to the substrate. When a one-part polyurethane adhesive is used with a primer, the cure rate of the primer and adhesive must be matched so that the adhesive can be connected to the primer. For primers that cure or form a film upon exposure to moisture, the adhesive and primer compete for moisture. When an adhesive is applied to one side of a primer, it is often difficult for moisture to diffuse into the primer, and the primer cannot form a film properly. If the primer does not cure properly, the bond of the adhesive system to the substrate may be insufficient for its use.

The two-part polyisocyanate adhesive is a catalyst for reacting a polyisocyanate or an isocyanate functional prepolymer in the first liquid, and a curing agent, the curing agent and the isocyanate group in the second liquid. Including. Furthermore, in order to connect the adhesive to the surface of the substrate or primer, they need to be adapted. If the cure rate of the adhesive is significantly faster than the bonding of the adhesive to the substrate surface or primer surface, poor adhesion to the substrate will occur and the bonding of the adhesive system to the substrate will be due to its use. May be insufficient. Typically, the curing agent is a compound having on average more than one active hydrogen atom, such as an amine or hydroxyl component. Examples of such systems include COMPOSTION U by the same owner as this application.
SEFUL AS AN ADHESIVE FOR INSTALLING VEHICLE
US patent application 11 / 824,984 filed June 3, 2007 in the United States entitled WINDOWS® and PCT / US0 filed PCT on June 5, 2007
7/013; U.S. Patent No. 6,965,008; European Patent No. 1433802 and European Patent No. 1578834, all incorporated herein by reference, are included. These adhesives begin to cure when the two liquids come into contact. Two-part adhesives have the advantage that they cure much faster than one-part adhesives. A problem with utilizing a two-part adhesive with a primer is that the adhesive cures faster than the primer and cannot be connected to the primer. Furthermore, adhesives containing isocyanate groups can interfere with the moisture required to cure the primer. Thus, the time between primer application and adhesive application to the substrate must allow for proper film construction, otherwise the system will be fully connected and along all layers of the adhesive system. A good bond cannot be formed. Furthermore, the connection speed must be adapted to the cure speed of the adhesive. If either is too fast compared to the other, poor adhesion to the substrate occurs and the bonding of the adhesive system to the substrate may be insufficient for its use.

One-part epoxy adhesive systems average 1 which reacts with compounds having an average of more than one epoxy (glycidyl ether group), epoxy components such as hydroxyl or amine components
A curing agent containing more than one component, and a compound having a latent curing catalyst. Latent cure catalysts typically become active when exposed to a set high temperature. One-part epoxy adhesives require heat to cure and can suffer from stability problems if not properly prepared, i.e., cure before being applied. If the catalyst causes the reaction to proceed too fast, the adhesive may not be connected to the substrate surface of the primer applied to the surface of the substrate when used.

A two-part epoxy system is a compound having an average of one or more epoxy groups in one liquid and a curing agent for the epoxy in another liquid and a catalyst (curing for curing the epoxy compound). Often called an accelerator). Typically, the catalyst is active at ambient temperature and promotes the reaction when the two liquids are contacted. The cure rate can be adjusted to suit the application by the choice of curing agent and / or catalyst. Nevertheless, in primer-coated systems, the adhesive cure rate, connection speed and open time must be carefully controlled, otherwise the connection of the adhesive to the primer system may be compromised. The activator system cannot solve the need to balance the linking reaction and the curing reaction.

Another common adhesive system includes an organic polymer having a siloxy group with a hydrolyzable group attached thereto, ie, a group capable of silanol condensation. These adhesives are used to bond a variety of substrates including glasses, painted substrates, metals and plastics with a fairly high degree of polar surface. The adhesive can be prepared as a one-component or two-component adhesive. The one-component adhesive is moisture curable. The two-component adhesive contains a curing agent in the second liquid. Examples of such adhesive systems are described in Mahdi et al., US Pat. No. 6,828,403; Wu et al., US Pat. No. 6,649,016 and Zhu, US Pat. Appl. Publ. No. 2008, which are incorporated herein by reference. No./0017296.

German Patent No. 199224139 US Pat. No. 5,115,086 US Pat. No. 5,238,993 US Pat. No. 5,466,727 US Pat. No. 5,468,317 US Pat. No. 5,792,811 US Pat. No. 6,053,971 US Patent Application Publication No. 2005/0126683 US Patent Application Publication No. 2006/0124225 US patent application 11 / 824,984 PCT / US07 / 013 US Pat. No. 6,965,008 European Patent No. 1433802 European Patent No. 1578834 US Pat. No. 6,828,403 US Pat. No. 6,649,016 US Patent Application Publication No. 2008/0017296

The use of a primer in an adhesive system requires a process step to apply the primer and 2
Because it provides two additional surfaces, the adhesive system can break along with it, further requiring open time and increasing processing time in the manufacturing process. Modern industrial processes require moving parts and loading on the adhesive system as quickly as possible. Moving parts or products that are bonded together with adhesive, or imposing a load on the adhesive bond before the system builds the proper strength, will result in failure of the adhesive system and thus defective parts Or may result in a product. What is needed is a system for bonding parts with reactive adhesives that avoids these problems and adapts the cure rate of the reactive adhesive to the rate of connection to the substrate or primer system. is there.

The present invention is a system or kit comprising i) a stable solution or dispersion of a catalyst for curing a reactive adhesive; and ii) an uncured reactive adhesive system in a separate liquid, The catalyst of the liquid i) is a system or kit that accelerates the curing of the reactive adhesive system. This reactive adhesive system is
One-part or two-part systems may be used.

In another embodiment, the present invention is a method of bonding a reactive adhesive to a substrate comprising:
a) contacting the surface of the substrate to which the adhesive is bonded with a catalyst for curing the reactive adhesive in a volatile solvent or dispersant;
b) volatilizing and removing the volatile solvent or dispersant;
c) contacting a reactive adhesive with the surface treated in step a); and d) curing the adhesive. This process is carried out in the absence of a primer and a film former-containing primer.

In another embodiment, the present invention is a method of bonding two or more substrates together, comprising:
a) contacting a catalyst for curing a reactive adhesive in a volatile solvent or dispersant with the surface of the two or more substrates to which the adhesive is bonded;
b) volatilizing and removing the volatile solvent or dispersant;
c) contacting the reactive adhesive with the surface treated in step a);
d) contacting the substrate together with the adhesive disposed between the substrates; and e) curing the adhesive.

The adhesive bonds directly to the substrate surface, but not directly to a separate primer layer. Preferably, when the solvent is volatilized off, the substrate has a catalyst on the surface to be bonded. In one embodiment, the catalyst is the only significant species disposed on the surface of the substrate.
In addition to retaining the catalyst, the solvent or dispersant can further function to clean the surface of the substrate. In another embodiment, the catalyst solution or dispersion contains markers that are used to confirm application of the catalyst to the substrate surface.

This process provides faster bonding of the adhesive to the substrate, enhances the stability of the one-part adhesive, and allows for the preparation of one-part adhesives with lower catalyst concentrations, This allows for the joining of parts or products that can be processed in even shorter time periods. The surface quality of the new generation of automotive paints has been changing. Although scratch and aging properties have been improved, the improvement, on the other hand, makes it difficult to bond to these paints without a primer when using prior art systems. When glass is used, dripping / sliding of the adhesive can be observed very frequently using the prior art system. The pretreatment according to the invention can avoid this problem and avoid the need for paint primers.

DETAILED DESCRIPTION OF THE INVENTION The adhesive system used in the present invention may be any reactive adhesive system that can utilize a catalyst to promote curing of the system. "Reactive" means herein that the adhesive contains components that react to form a polymer matrix that solidifies irreversibly once cured. Among the preferred reactive adhesive systems, thermosetting polyurethanes based on epoxies, polyisocyanates (forming polyurethanes, polyureas and / or polyisocyanurates), moisture curable silanes, blocked or deactivated isocyanate groups There are adhesives. More preferred systems are epoxy and polyisocyanate adhesive systems. Even more preferred adhesive systems are polyisocyanate systems. The adhesive system may be a one-part or two-part adhesive system. More preferred is a two-part adhesive system.

The catalyst solution or dispersion applied to the substrate may contain any catalyst for the particular adhesive system utilized. The choice of catalyst is determined by the adhesive system. In the following, preferred adhesive systems and catalysts for said systems are described. Preferred catalysts are polyurethane catalysts, silanol condensation catalysts and epoxy catalysts. The solvent or dispersant may be any solvent or dispersant that forms a stable solution or dispersion of the catalyst. “Stability” means that the catalyst remains in the dispersion or solution until applied to the substrate surface. Preferably, the solvent or dispersant is volatile under conditions where the solution or dispersion is applied to a substrate. It is desirable that the solvent or dispersant is evaporated away as soon as possible after application to the substrate or disappears immediately. Preferably, the catalyst solution or dispersion leaves only the catalyst on the surface of the substrate after the solvent or dispersion immediately disappears. In another embodiment, the solution or dispersion may contain a marker that allows a process operator to confirm that the solution or dispersion has been applied. The markers include fluorescent components that are readily available from a number of sources, such as Aldrich Chemical Co. (Milwaukee, Wis.). As a specific example, the fluorescent component is Ciba
It may be a Uvitex OB brand fluorescent agent available from Ciba Specialty Chemicals (Taritown, NY). The amount of fluorescent agent added to the catalyst solution or dispersion must be sufficient so that the area of the window treated with the catalyst solution or dispersion is evident when the window is illuminated with ultraviolet light. In this embodiment, the marker can be left along the catalyst and substrate surface. Among preferred solvents or dispersants, there are alicyclic hydrocarbons, aliphatic hydrocarbons, aromatic hydrocarbons, ketones, esters, ethers or alcohols, and alicyclic hydrocarbons, aliphatic hydrocarbons, aromatic hydrocarbons. More preferred. A more preferred solvent or dispersant is an aliphatic hydrocarbon. Among the preferred aliphatic hydrocarbons are hexane, heptane and octane.
Among the preferred alicyclic hydrocarbons is cyclohexane. Among the preferred aromatic hydrocarbons are toluene and xylene.

The catalyst concentration in the solution or dispersion may be varied to accommodate the adhesive system, the desired curing and linking rate. The amount of catalyst is sufficient to provide the desired coupling rate. "
“Link-up” means a bond to a surface adjacent to a particular material. Preferably, the catalyst is about 0.01 wt% or more, more preferably about 0.0% by weight based on the weight of the solution or dispersion.
It is present in an amount of 5% by weight or more, and most preferably 0.1% by weight or more. Preferably, the catalyst is present in an amount of about 20 wt% or less, more preferably about 5 wt% or less, and most preferably about 2 wt% or less, based on the weight of the solution.

For polyisocyanate adhesive systems, the catalyst may be any catalyst known to those skilled in the art for reacting an isocyanate component with water or an active hydrogen-containing compound. Preferably, the catalyst is not volatile at ambient conditions. Such compounds are well known in the art. Preferred catalysts include strong gelling or trimerization catalysts. A preferred catalyst is a metal salt, an amine catalyst, an aziridine catalyst or a quaternary ammonium catalyst. Among the preferred catalysts are metal alkanoates, metal acetates, metal acetylacetonates, diazabicyclo compounds and tertiary amines. Preferred metals used in the metal salt include tin, bismuth, iron, potassium, sodium, zinc, and titanium, with tin, bismuth, and titanium being more preferred. Preferred metal alkanoate catalysts include bismuth, zinc,
Examples include potassium and sodium alkanoates, including bismuth octoate, bismuth neodecanoate, zinc octoate, potassium octoate, and sodium octoate. Preferred metal acetates include potassium acetate. Preferred metal acetylacetylacetonates include iron acetylacetonate, dibutyltin diacetylacetonate and titanium acetylacetonate. Amine catalysts useful in the present invention include dimorpholino dialkyl ether, di ((dialkylmorpholino) alkyl) ether, bis- (2-dimethylamino-ethyl) ether, triethylenediamine, pentamethyldiethylenetriamine, N, N-dimethylcyclohexane. -Hexylamine, N, N-dimethylpiperazine-4-methoxyethylmorpholine, N-methylmorpholine, N-ethylmorpholine, and mixtures thereof. More preferred catalysts are
Ammonium salts, such as DABCO ™ TMR, TMR-3, TMR-4 catalyst (2 in ethylene glycol available from Air Products)
N-hydroxy-alkyl tertiary ammonium carboxylates blocked with ethylhexanoic acid), DABCO ™ TMR-2 and TMR-5 catalysts available from Air Products (blocked with formic acid in ethylene glycol) N-hydroxy-alkyl tertiary ammonium carboxylate). Preferred amine catalysts include tertiary amines such as POLYCAT ™ 41 catalyst (1,3.5-tris (3 (dimethylamino-propyl) hexahydro-s-triazine); DABCO ™ TMR-30 catalyst (
Tris (dimethylaminomethyl) phenol and ANCAMINE ™ K-542
4,6-tris (dimethylaminomethyl) phenol. Further useful catalysts include CURITHANE ™ 52 catalyst (2-methyl (n-methylamino b-sodium acetate nonylphenol)). The diazabicyclo compound is a compound having a diazobicyclo structure. Among the preferred diazabicyclo hydrocarbons are diazabicycloalkanes and diazabicycloalkene salts. Preferred diazabicycloalkanes include
And diazabicyclooctane available from Air Products under the trademark and trade name DABCO and DABCO WT. Preferred diazabicycloalkane salts include diazabicycloundecene and its salts. Preferred salts are the phenolate, ethyl hexoate, oleate and formate salt forms. The catalyst is a trademark and trade name of POLYCAT SA1, POLYCAT SA1 / 10, POLYCT from Air Products.
Available in SA102 and POLYCAT SA610. Preferred diazabicyclo compounds include POLYCAT DBU catalyst (1,8-diazabicyclo-5,4,0-undecene-7); POLYCAT SA-102 catalyst (1,8 diazabicyclo-5,4 blocked with 2-ethylhexanoic acid) , 0-Undecene-7); POLYCAT ™ S
AI catalyst (62% 1,8-diazabicyclo-5,4,0-undecene-7 blocked with phenolic acid (38%)) is included. Organometallic compounds such as organotin compounds are less preferred for industrial hygiene and technical reasons. When used in the process, the bond formed breaks with exposure to heat and moisture.

For epoxy adhesives, useful catalysts (curing accelerators) known in the art are used to increase the cure rate of the epoxy adhesive. The catalyst contains a compound that can act as a curing agent when used alone, but when combined with a different class of curing agent, will promote curing of the epoxy adhesive composition. Examples of useful catalysts include phenolic compounds such as 2,4,6-tris (dimethylaminomethyl) phenol, tertiary amines such as benzyldimethylamine and piperidine, substituted imidazoles such as n-arylimidazoles and n-alkyls. Examples include imidazole, substituted ureas such as monuron, diuron, phenuron, and chlorotolulone, and calcium trifluoromethyl sulfonate. These curing accelerators can be used alone or in combination together to accelerate the curing of the epoxy adhesive composition. These catalysts are used to promote the adhesion of one-part or two-part adhesive systems prepared by conventional means.

In embodiments where the reactive adhesive system includes an organic polymer having hydrolyzable siloxane (silane) groups, the catalyst utilized includes any catalyst known to those skilled in the art for silanol condensation. Preferred catalysts for catalyzing the silanol condensation reaction include tin catalysts, titanates and titanium chelators, organometallic compounds, aminoalkyl substituted alkoxysilanes, amine compounds and salts thereof, alkali metal salts of lower fatty acids, dialkylhydroxyamines and silanol condensation reactions. Guanidyl-containing silanes or siloxanes well known in the art to be useful. One class of preferred organometallic compounds includes tin compounds such as dialkyltin carboxylates (dialkyltin (IV) salts of organic carboxylates), tin ester compounds such as tin dioctoate; and dialkyltin alcoholates such as dialkyl Contains tin dialkenedione (including dialkyltin bisacetylacetonate). A preferred organometallic catalyst is a dialkyltin alcoholate, with dialkyltin diacetylacetonate being most preferred. Among the preferred dialkyltin carboxylates are dibutyltin diacetate, dimethyltin dilaurate, dibutyltin dilaurate, dibutyltin maleate, dibutyltin dioctoate or dioctyltin diacetate, and the reaction products of dialkyltin oxides and phthalates. Dialkyltin alcoholates include reaction products of dialkyltin oxides and alkanediones, such as dialkyltin diacetylacetonates, such as dibutyltin diacetylacetonate (more commonly referred to as dibutyltin acetylacetonate). Among the particularly preferred dialkyltin carboxylates, the trade name FOMREZ ™ SUL from Witco Corporation.
Dibutyltin oxide and phthalate ester adducts available from -11A, dimethyltin dicarboxylate available from Witco Corporation under the trade name FOMREZ ™ UL-28, trade name T-12 from Air Products, and Dibutyltin dilaurate available under the trade name FOMREZ ™ SUL-4 from Witco Corporation and trade name DABCO ™ T-1 from Air Products and trade name FOMREZ ™ UL-1 from Witco Corporation Dibutyltin diacetate available. Preferred organometallic compounds include zinc naphthenate, zinc stearate, zinc 2-ethyl octoate, iron 2-ethyl hexoate, cobalt 2-ethyl hexoate, manganese 2-ethyl hexoate and cobalt naphthenate. It is. A catalyst that undergoes hydrolytic dissociation at a higher rate is preferred. Preferred titanate and titanium chelators include tetraisopropoxytitanium, tetra-n-butoxytitanium, tetrakis (2-ethylhexoxy) titanium, dipropoxybis (acetylacetonato) titanium, and titanium isopropoxyoctylene glycol. Preferred aminoalkyl substituted alkoxy silanes include 3-aminopropyltriethoxysilane and N- (β-aminoethyl) -γ-aminopropyl-trimethoxysilane. Preferred amine compounds and salts thereof include hexylamine, dodecylamine phosphate, tetramethylguanidine and diazabicyclononane. Preferred quaternary ammonium salts include benzyltriethylammonium acetate. Preferred alkali metal salts of lower fatty acids include potassium acetate, sodium acetate and lithium oxalate, and preferred dialkylhydroxyamines include dimethylhydroxylamine and diethylhydroxyamine. Preferred guanidyl-containing silanes or siloxanes include tetramethylguanidylpropyltrimethoxysilane, tetramethylguanidylpropylmethyl-dimethoxysilane, and tetramethylguanidyl-propyltris (trimethylsiloxy) silane. Of these, preferred are amine compounds such as tetramethylguanidine and diazabicyclononane, and guanidyl-containing silanes or siloxanes such as tetramethylguanidylpropyltrimethoxysilane, tetramethylguanidyl-propylmethyl-dimethoxysilane and Tetramethylguanidylpropyl-tris (trimethylsiloxy) silane. Tin and titanate compounds are more preferred. The most preferred catalyst is dibutyltin bisacetylacetonate (dibutyltin dipentenedione) available from Nitto Kasei Co. under the trade name NEOSTANN ™ U-220. These catalysts may be used alone or in a mixed state of two or more.

The curable epoxy adhesive composition generally comprises: (a) an epoxy resin; (b) a curing agent for the epoxy resin; and (c) a catalyst (curing accelerator) for curing the epoxy resin. It is out. The epoxy adhesive is prepared as a one-part thermosetting adhesive with a curing agent contained in latent form, or as a two-part adhesive with an epoxy resin component and a curing agent component containing a curing agent. Also good. The systems and processes of the present invention for adhesion promotion use a solution or stable dispersion of a curing accelerator or catalyst for epoxy curing, whether or not the epoxy adhesive contains a catalyst. Epoxy resins useful in the adhesive composition of the present invention may be any organic compound having at least one epoxy ring that is polymerizable by ring opening. Preference is given to organic compounds having an average epoxy functionality of more than one and preferably at least two. Epoxides can be monomeric or polymeric and aliphatic, cycloaliphatic, heterocyclic, aromatic, or mixtures thereof. More preferred epoxides are aromatic, more than 1.5 epoxy groups per molecule and most preferably 1
Contains more than 2 epoxy groups per molecule. Preferred epoxy resins are about 150-10.
Having a molecular weight of about 300 to 1,000. Preferred epoxy resins include linear polymer epoxides having terminal epoxy groups (eg, diglycidyl ether of polyoxyalkylene glycol), polymer epoxides having backbone epoxy groups (eg,
Polybutadiene polyepoxy), and polymer epoxides having pendant epoxy groups (eg, glycidyl methacrylate polymers or copolymers), or mixtures thereof. Preference is given to aromatic glycidyl ethers, for example aromatic glycidyl ethers prepared by reacting polyhydric phenols with excess epichlorohydrin. Examples of useful phenols include resorcinol, catechol, hydroquinone, and polynuclear phenols such as p, p'-dihydroxydibenzyl, p, p'-dihydroxydiphenyl, p
, P′-dihydroxydiphenylsulfone, p, p′-dihydroxybenzophenone, 2
, 2'-dihydroxy-1,1-dinaphthylmethane and dihydroxydiphenylmethane, dihydroxydiphenyldimethylmethane, dihydroxydiphenylethylmethylmethane, dihydroxydiphenylmethylpropylmethane, dihydroxydiphenylethylphenylmethane, dihydroxydiphenylpropylphenylmethane, dihydroxydiphenylbutylphenyl 2,2 ′, 2,3 ′, 2,4 ′, 3,3 ′, 3,4 ′ and 4 of methane, dihydroxydiphenyltolylmethane, dihydroxydiphenyltolylmethylmethane, dihydroxydiphenyldicyclohexylmethane, and dihydroxydiphenylcyclohexane
, 4 'isomer. More preferred are polyglycidyl ethers containing only polyhydric phenol formaldehyde condensation products as well as epoxy or hydroxy groups as reactive groups. Useful materials include diglycidyl ethers of bisphenol A and novolac resins, such as “Handbook of Epoxy Resins” by Lee a, incorporated herein by reference.
nd Neville, McGraw-Hill Book Co., New York (1967). Epoxides with a flexibilized backbone are also useful. Preferred materials include diglycidyl ethers of bisphenol A and diglycidyl ethers of bisphenol F, most preferred are diglycidyl ethers of bisphenol A, which are desirable structural adhesive properties to be achieved when these materials are cured. For. Examples of commercially available epoxides useful in the present invention include diglycidyl ethers of bisphenol A (eg, Shell Chemical (Shell Chemical
From the company EPON 828, EPON 1001, and EPONEX 1510, and DER-331, DE from The Dow Chemical.
R-332, and those available at DER-334); diglycidyl ether of bisphenol F (eg, Dai Nippon Ink and Chemicals)
n EPICLON ™ 8 available from n Ink and Chemicals
30); silicone resin containing diglycidyl epoxy functional group; flame retardant epoxy resin (
For example, D, a brominated bisphenol type epoxy resin available from Dow Chemical Company
ER ™ 580); and 1,4-butanediol diglycidyl ether.

The epoxy adhesive composition may include reinforcing agents that are well known in the art. In some cases, a reactive diluent can be added to control the flow characteristics of the adhesive composition. Suitable diluents have at least one reactive terminal moiety and preferably a saturated or unsaturated cyclic skeleton and are well known in the art. Various other adjuvants can be added to the epoxy adhesive composition to enhance the properties of the composition before and after curing. Among the particularly useful adjuvants, non-reactive diluents; plasticizers such as conventional phosphates and phthalates; flame retardants such as borate, metaborate, aluminum hydroxide, magnesium hydroxide, and bromine compounds; thixotropic agents such as flow control Fumed silica to provide color; pigments to enhance color tone such as iron oxide, brick dust, carbon black, and titanium dioxide; fillers such as talc, silica, magnesium,
Calcium sulfate, beryllium aluminum silicate; clays such as bentonite; glass and ceramic beads and bubbles; compounds imparting radiopacity such as barium metaborate; and reinforcing materials such as organic and inorganic fibers such as polyester,
Includes woven and non-woven webs of polyimide, glass fiber and ceramic fiber. Dispersants and wetting agents, such as silanes, can also be added as long as they do not interfere with the curing reaction of the epoxy adhesive composition. An adjuvant may be added in an amount effective for a given purpose.

Epoxy adhesive compositions may be prepared in a variety of ways, including one-part and two-part adhesive systems. By providing a two-part composition, combining the two parts before use of the composition provides the desired shelf life or pot life of the composition. For two-part adhesive compositions, curing can be performed at room temperature for about 24 hours. In order to cure at a higher speed, a process of heating to 120 ° C. can be used. In some applications, it is desirable to select the amount and distribution of components in each liquid in order to provide viscosity control and better mixing of the two liquids. For example, the filler can be divided so that each liquid contains a portion of the filler used.

The one-part epoxy composition can be cured by any means that allows sufficient heat to initiate the curing reaction. The means for curing can include a conventional oven, induction heating, infrared radiation, microwave radiation, immersion in a fluid bath, or any combination thereof. Curing is in several stages, for example induction curing for 30 seconds, as well as about 120 ° C.
Above and preferably can be achieved by oven curing at about 180 ° C. Curing time will depend on the specific process for curing. Induction heating times typically range from about 1 to 60 seconds. The oven cure time can range from about 0.1 to about 2 hours.

Epoxy adhesive compositions are particularly useful for bonding metals to metals and plastics to metals, but epoxy adhesive compositions bond plastic molding surfaces such as polyester-based sheet molding compounds. May be used to Examples of metal surfaces include steel, titanium, oily steel, aluminum, and magnesium.
Plastic surfaces include sheet molding compounds, glass fiber reinforced epoxy resins, polycarbonates, polyesters, polyurethanes, acrylonitrile butadiene styrene, and urea formaldehyde. Epoxy adhesives can be used in assembling assembly parts such as automobiles, aircraft, cooling units and the like.

Isocyanate-based (polyurethane or polyurea forming) adhesive systems contain isocyanate-functional components. The isocyanate functional component contains, on average, one or more compounds having more than one isocyanate functional group per molecule. The isocyanate-functional compound can be any compound that on average contains more than one isocyanate component. The isocyanate functional compound may be in the form of an isocyanate functional prepolymer or in the form of a monomer or oligomer having on average more than one isocyanate group and preferably two or more isocyanate groups. Isocyanate prepolymers average on average are the prepolymers prepared with one or more compounds having on average more than one isocyanate-reactive functional group, such as hydroxyl, amine, thiol, carboxyl, etc., with an isocyanate functional compound. It can be any prepolymer prepared by reaction under conditions that have more than one isocyanate component (group) per molecule. The polyisocyanate-based adhesive system may be a one-part type or a two-part type system. In a one-part system, the isocyanate functional component further includes a catalyst and other components described below. One component systems are typically cured by moisture curing. Once prepared,
The one-part adhesive is packaged in an airtight and waterproof container to prevent curing before application.

In another embodiment, the adhesive system used in the present invention is a two-part polyisocyanate-containing adhesive system. The two liquids are reactive with each other and, when brought into contact, have adhesive properties and undergo a curing reaction, at which time the composition can bond the substrates together. One liquid of the composition is
Contains or contains an isocyanate functional product. This is typically referred to as the resin side, or A side. The other component of the composition comprises or contains one or more compounds, oligomers or prepolymers having on average more than one group that are reactive with the isocyanate component described herein. It is a reactive component. The second liquid is generally known as a curing agent or B side. The compound having on average one or more isocyanate-reactive groups may be a prepolymer, or may be a short chain compound, such as a bifunctional chain extender or multifunctional crosslinker known in the art. Typically, chain extenders and crosslinkers have a molecular weight of about 250 daltons or less. The catalyst described above can be used on the curing agent side. The reaction product is a cured product that can bond a given substrate together.

Preferred polyisocyanates for use in the present invention include aliphatic, cycloaliphatic, araliphatic, heterocyclic or aromatic polyisocyanates, or mixtures thereof. Preferably, the polyisocyanate used has an average isocyanate functionality of at least about 2.0 and an equivalent weight of at least about 80. Preferably, the number of isocyanate functional groups of the polyisocyanate is at least about 2.0, more preferably at least about 2.2, most preferably at least about 2.4; and preferably no more than about 4.0, more preferably Is about 3.5 or less, most preferably about 3.0 or less. A higher number of functional groups can also be used, but it induces excessive cross-linking, resulting in a composition that is too viscous to be easily handled and applied, making the cured composition too brittle. May trigger. Preferably, the equivalent weight of the polyisocyanate is at least about 100, more preferably at least about 110, most preferably at least about 120; and preferably about 300 or less, more preferably about 250 or less, most preferably About 20
0 or less. Examples of preferred polyisocyanates include those disclosed in Wu, US Pat. No. 6,512,033, column 3, lines 3 to 49, incorporated herein by reference. More preferred isocyanates are aromatic isocyanates, alicyclic isocyanates and derivatives thereof. Even more preferred polyisocyanates include diphenylmethane diisocyanate and its polymer derivatives, isophorone diisocyanate, tetramethylxylene diisocyanate, 1,6-hexamethylene diisocyanate and its polymer derivatives, bis (4-isocyanatocyclohexyl) methane, and trimethyl. Hexamethylene diisocyanate is mentioned. The most preferred isocyanate is diphenylmethane diisocyanate.

As used herein, the term “isocyanate-reactive compound” includes any organic compound having at least two isocyanate-reactive components, such as a compound containing an active hydrogen component, or an imino functional compound. For the purposes of the present invention, an active hydrogen-containing component is because of its position in the molecule, Journal of the American Chemical Society, Vol. 49, p. 3181 (
1927) means a component containing a hydrogen atom that exhibits significant activity according to the Zerewininoff test described by Wohler. Examples of the active hydrogen component are -COO
_{H, -OH, -NH 2, -NH} -, - CONH 2, -SH, and is -CONH-. Preferred active hydrogen-containing compounds include polyols, polyamines, polymercaptans and polyacids. Suitable imino functional compounds are compounds having at least one terminal imino group per molecule, such as US Pat. No. 4,497, which is incorporated herein by reference in its entirety.
910,279. Preferably, the isocyanate-reactive compound is a polyol or a polyamine, more preferably a polyether polyol.

Preferred polyols useful in the preparation of the prepolymer include the polyols disclosed in US Pat. No. 6,512,033, column 4, lines 10 to 64 of Wu, incorporated herein by reference, for example , Polyether polyols, polyester polyols, poly (alkylene carbonate) polyols, hydroxyl-containing polythioethers, polymer polyols (dispersions of vinyl polymers in the polyols, commonly referred to as copolymer polyols) and mixtures thereof. Preferably, the isocyanate-reactive compound is at least about 1.5, more preferably at least about 1.8, most preferably at least about 2.0; and preferably no more than about 4.0, more preferably about 3.
The number of functional groups is 5 or less, most preferably about 3.0 or less. Preferably, the equivalent weight of the isocyanate-reactive compound is at least about 200, more preferably at least about 5
00, and more preferably at least about 1,000; and preferably about 5
3,000 or less, more preferably about 3,000 or less, and most preferably about 2,500.
0 or less.

Isocyanate functional prepolymers for use in isocyanate functional adhesive systems preferably have an average number of isocyanate functional groups of at least about 2.0 and at least about 5
It exhibits a molecular weight of 00 and more preferably about 1,000. Preferably, the prepolymer has an average isocyanate functionality of at least about 2.0, more preferably at least about 2.
2. Preferably, the number of isocyanate functional groups is about 4.0 or less, more preferably about 3.
5 or less, and most preferably about 3.0 or less. Preferably, the prepolymer has a weight average molecular weight of at least about 2,500, more preferably at least about 3,000; and preferably no more than about 40,000, even more preferably no more than about 20,000, And most preferably no more than about 10,000. The prepolymer can be synthesized by any suitable method, for example, a compound having two or more groups reactive with an isocyanate group, such as a polyol or polyamine, under the reaction conditions sufficient to form the corresponding prepolymer. It can be prepared by reacting with excess polyisocyanate beyond theory. The prepolymer can be prepared by any suitable method, such as bulk polymerization and solution polymerization. The reaction for preparing the prepolymer is carried out under anhydrous conditions to prevent crosslinking of isocyanate groups by atmospheric moisture, preferably under an inert atmosphere, for example under a nitrogen blanket. This reaction is catalyzed by a catalyst for reacting isocyanate groups with isocyanate reactive groups. Examples of the above include tin salts of carboxylic acids such as tin octoate, tin oleate, tin acetate, and tin laurate; dialkyltin dialboxylates such as dibutyltin dilaurate and dibutyltin diacetate,
Secondary amines and tin mercaptides are mentioned. Preferably, the reaction for preparing the prepolymer is catalyzed by tin octoate. The amount of catalyst used is generally from about 0.005 to about 5% by weight of the mixture being catalyzed, depending on the nature of the isocyanate.
The reaction is preferably at a temperature of about 0 to about 150 ° C, more preferably about 25 to about 80 ° C,
This is done until the residual isocyanate content determined by titration of the sample is very close to the desired theoretical value. For a two-part isocyanate adhesive system, the isocyanate content in the prepolymer is preferably in the range of about 6 to about 35 weight percent, more preferably about 8 to about 3
It is in the range of 0% by weight and most preferably in the range of about 10 to about 25% by weight. For one-part moisture curable systems, the isocyanate content in the prepolymer is preferably in the range of about 0.1 to about 10% by weight, more preferably in the range of about 1.5 to about 5.0% by weight, And most preferably in the range of about 1.8 to about 3.0 weight percent.

The isocyanate functional component is present in the adhesive system in an amount sufficient to form a cured component when exposed to curing conditions. In the two-part composition, the isocyanate functional component is
When combined with an isocyanate-reactive compound, the substrate is about −
They can be bonded together in such a way that they remain bonded together when exposed to temperatures of 30 ° C. to about 100 ° C .; and for short periods of up to 30 minutes to temperatures of about 180 ° C.

The isocyanate functional adhesive compositions useful in the present invention can further comprise a polyfunctional isocyanate to improve elasticity in the cured form. “Polyfunctional” as used in the context of isocyanate means an isocyanate having a functional group number of 2.2 or greater.
The polyisocyanate can be any monomeric, oligomeric or polymeric isocyanate having a nominal functional group number of about 2.2 or greater. More preferably, the polyfunctional isocyanate has a nominal functional group number of about 2.7 or greater. Preferably, the polyfunctional isocyanate has a nominal functionality of about 4 or less and most preferably about 3.2 or less. The polyfunctional isocyanate can be any isocyanate that is reactive with the isocyanate functional prepolymer and / or the oligomer or prepolymer used in the composition and that improves the elasticity of the cured composition. The polyfunctional isocyanate may be a reaction product of several units of monomer; monomeric trimer, isocyanurate or biuret; oligomer or polymer, one or more monomeric isocyanates. Examples of preferred polyfunctional isocyanates include the trademark and trade name DESMOD from Bayer.
Trimers of hexamethylene diisocyanate available in UR N3300 and N-100, and polymeric isocyanates such as polymeric MDI (methylenediphenyl diisocyanate), such as PAPI 2 marketed under the trademark PAPI by Dow Chemical Company
Polymer isocyanates including zero polymer isocyanates. The polyfunctional isocyanate is present in an amount sufficient to significantly affect the elasticity of the cured composition of the present invention. When used in excess, the cure rate of the composition is slowed unacceptably. If used too little, the desired level of elasticity cannot be achieved. The polyfunctional isocyanate is preferably present in an amount of about 0.5 wt% or more, more preferably about 1.0 wt% or more, and most preferably about 1.4 wt% or more, based on the weight of the composition. To do. The polyfunctional isocyanate is preferably present in an amount of no more than about 8 wt%, more preferably no more than about 5 wt%, and most preferably no more than about 2.5 wt%, based on the weight of the composition. The polyfunctional isocyanate may be used in one-part and two-part adhesive compositions. In a two-part composition, the polyfunctional isocyanate is placed in a liquid containing an isocyanate functional component, preferably in the form of an isocyanate functional prepolymer.

The isocyanate functional adhesive system further includes one or more catalysts for the reaction of isocyanate functional groups with isocyanate reactive groups, said catalyst being included in the isocyanate functional group-containing component or isocyanate reactive component. You may arrange. Preferably, for a two-part adhesive system, a catalyst may be placed in the isocyanate-reactive component to improve the stability of the two-component system. The catalyst may be any catalyst known to those skilled in the art for reacting isocyanate groups with active hydrogen-containing compounds. Among preferred catalysts, organotin compounds,
There are metal alkanoates, tertiary amines and diazabicyclo compounds. The catalyst is utilized in an amount sufficient to induce the isocyanate groups to react with the isocyanate reactive groups at a reasonable rate. The amount of catalyst utilized will depend on the choice of catalyst and the desired reaction rate.
Preferably, the catalyst is utilized in an amount of about 0.006 wt% or more, more preferably about 0.01 wt% or more, and most preferably 0.02 wt% or more, based on the weight of the adhesive system. Will. Preferably, the catalyst is utilized in an amount of no more than about 5.0 wt%, more preferably no more than about 2.0 wt%, and most preferably no more than about 1.0 wt%, based on the weight of the adhesive system. It will be. Useful organotin catalysts include compounds such as alkyl tin oxides,
Tin alkanoates, dialkyltin carboxylates and tin mercaptides. Tin alkanoate includes tin octoate. Alkyl tin oxides include dialkyl tin oxides such as dibutyl tin oxide and its derivatives. The organotin catalyst is preferably a dialkyltin dicarboxylate or a dialkyltin dimercaptide. The dialkyltin dicarboxylate is preferably of the formula (R ¹ OC (O))
_2- Sn- (R ¹ ) ₂ , where R ¹ is independently C _1-10 alkyl, preferably C _1-3 alkyl and most preferably methyl at each occurrence. Dialkyltin dicarboxylates with lower total carbon atoms are preferred because they are more active catalysts in the compositions used in the present invention. Preferred dialkyl dicarboxylates include
Examples include 1,1-dimethyltin dilaurate, 1,1-dibutyltin diacetate, and 1,1-dimethyldimaleate. Preferred metal alkanoates include bismuth octoate or bismuth neodecanoate. The organotin or metal alkanoate catalyst is preferably present in an amount of about 0.006 wt% or more and more preferably about 0.012 wt% or more based on the weight of the composition. The organotin or metal alkanoate catalyst is preferably in an amount of no greater than about 1.0 parts by weight, more preferably no greater than about 0.5% by weight, and most preferably no greater than about 0.1% by weight, based on the weight of the composition. Exists. Among preferred tertiary amines, dimorpholino dialkyl ether, di ((dialkylmorpholino) alkyl) ether, bis- (2-dimethylaminoethyl) ether, triethylenediamine, pentamethyldiethylenetriamine, N, N-dimethylcyclohexylamine, N , N-dimethylpiperazine, 4-methoxyethylmorpholine, N-methylmorpholine, N-ethylmorpholine, and mixtures thereof. More preferred tertiary amines include dimorpholinodiethyl ether or (di- (2- (3,5-dimethyl-morpholino) ethyl) ether). The tertiary amine is preferably about 0.01 wt% based on the weight of the composition, more preferably about 0.05 wt% or more, and even more preferably about 0.00 wt%, based on the adhesive system. 1
% By weight, and most preferably about 0.2% by weight or more, and preferably about 2.0% by weight.
Or less, more preferably about 1.75 wt% or less, even more preferably about 1.0 wt% or less,
And most preferably in an amount up to about 0.4% by weight.

Diazabicyclo compounds useful in the present isocyanate functional adhesive system are compounds having a diazobicyclo structure. It is preferred to use a diazabicyclo compound in a two-part system. Particularly preferred diazabicyclohydrocarbons include diazabicycloalkanes and diazabicycloalkene salts. In some embodiments, the catalyst preferably comprises one or more diazabicycloalkanes and one or more diazabicycloalkene salts.
When both classes of compounds are present, the molar ratio of one or more diazabicycloalkanes to one or more diazabicycloalkene salts is preferably about 1: 9 or more; more preferably Is about 2: 8 or more; and most preferably about 4: 6 or more. When both classes of compounds are present, the molar ratio of one or more diazabicycloalkanes to one or more diazabicycloalkene salts is preferably about 9: 1.
Or less; more preferably about 8: 2 or less; and most preferably about 6: 4 or less. Preferred diazabicycloalkanes include diazabicyclooctane available from Air Products under the trademark and trade names DABCO, DABCO WT, DABCO DC1, DABCO DC2, and DABCO DC21. Preferred diazabicycloalkene salts include trade names and trade names POLYCAT SA1, P from Air Products in the form of phenolate, ethylhexoate, oleate and formiate salts.
OLYCAT SA1 / 10, POLYCAT SA102 and POLYCAT SA6
And diazabicycloundecene available at 10. In preferred embodiments, one or more diazabicyclo compounds and one or more organometallic and / or tertiary amine catalysts are present in the adhesive system. The diazabicyclo compound is present in an amount sufficient so that the composition exhibits an acceptable cure rate as defined herein. The diazabicyclo compound is preferably at least about 0.01% by weight, more preferably about 0.0% by weight in the composition of the present invention.
Present in an amount of 2% by weight or more. Preferably, the diazabicyclo compound is not more than about 5% by weight, more preferably not more than about 1% by weight, and most preferably about 0.
Present in an amount of 5% by weight or less.

The isocyanate functional adhesive composition can further comprise one or more low molecular weight compounds having two or more isocyanate reactive groups and a hydrocarbon backbone, wherein the backbone is one or more. The hetero atom may further be included. It is beneficial to use the low molecular weight compound in a two-part composition. The low molecular weight compound may be a compound known in the art as a chain extender, and the compound is bifunctional. The low molecular weight compound may be a compound also known as a cross-linking agent in the art,
On average, it has more than two active hydrogen groups per compound. The heteroatom in the skeleton may be oxygen, sulfur, nitrogen or a mixture thereof, but oxygen, nitrogen or a mixture thereof is more preferable at this time, and oxygen is most preferable. Preferably, the molecular weight of the low molecular weight compound is about 120 or less and more preferably about 100 or less. Preferably, the low molecular weight compound is 1
One or more polyfunctional alcohols, polyfunctional alkanolamines, one or more addition compounds of polyfunctional alcohols and alkylene oxides, one or more addition compounds of polyfunctional alkanolamines and alkylene oxides and mixtures thereof Is included.
Among preferred polyfunctional alcohols and polyfunctional alkanolamines, ethanediol, propanediol, butanediol, hexanediol, heptanediol, octanediol, glycerin, trimethylolpropane, pentaerythritol, neopentylglycol, ethanolamine (diethanolamine, triethanol) Lamin) and propanolamine (di-isopropanolamine, tri-isopropanolamine).
Mixtures of various low molecular weight compounds may be used. The low molecular weight compound has the desired G-modulus (
E-modulus) is used in an amount sufficient to obtain. In the two-component adhesive composition, the low molecular weight compound can be disposed on the resin side, the curing agent side, or both. Preferably, the low molecular weight compound is arranged on the curing agent side. Preferably, the low molecular weight compound is present in the adhesive composition in an amount of about 2 wt% or more, more preferably about 2.5 wt% or more, and most preferably about 3.0 wt% or more. Preferably, the low molecular weight compound is present in the adhesive composition.
It is present in an amount of about 10 wt% or less, more preferably about 8 wt% or less, and most preferably about 6 wt% or less.

In a two-part isocyanate functional adhesive system, the curing agent portion may further comprise a polyoxyalkylene polyamine having two or more amines per polyamine. Preferably, the polyoxyalkylene polyamine has 2 to 4 amines per polyamine and most preferably 2 to 3 amines per polyamine. Preferably, the polyoxyalkylene polyamine has a weight average molecular weight of about 200 or greater and most preferably about 400 or greater. Preferably, the polyoxyalkylene polyamine has a weight average molecular weight of about 5,000 or less and most preferably about 3,000 or less. A particularly preferred polyoxyalkylene polyamine is JEFFAMINE ™ DT having a molecular weight of about 400.
-403 polypropylene oxide triamine and JEFFAM having a molecular weight of about 400
INE ™ D-400 polypropylene oxide diamine. The polyoxyalkylene polyamine is present in an amount sufficient to prevent the composition from dripping once mixed and applied. Preferably, the polyoxyalkylene polyamine is in the adhesive system
About 0.2% by weight or more, more preferably about 0.3% by weight or more, and most preferably about 0.5% by weight.
Present in an amount greater than or equal to weight percent. Preferably, the polyoxyalkylene polyamine is present in the adhesive system in an amount of about 6 wt% or less, more preferably about 4 wt% or less, and most preferably about 2 wt% or less.

The two liquids of this adhesive system are preferably bonded so that the equivalent of isocyanate groups is greater than the equivalent of isocyanate-reactive groups. More preferably, the equivalent ratio of isocyanate groups to isocyanate reactive groups is greater than about 1.0: 1.0, even more preferably about 1.05: 1.0 or greater, and most preferably about 1.10: 1.0 or more. More preferably, the equivalent ratio of isocyanate groups to isocyanate reactive groups is about 2.0: 1.0.
And most preferably about 1.40: 1.0 or less.

One-part polyisocyanate functional adhesive system and one or both of resin part and hardener part for resin part and two-part isocyanate functional system form plasticizer, filler, pigment, stabilizer and generally curable polyurethane Other additives present in the adhesive may be included. By adding the material, physical properties such as rheology, flow rate, etc. can be altered.
However, to prevent premature hydrolysis of the moisture sensitive groups of the present isocyanate functional component, the filler must be completely dried before mixing with them. The composition of the present invention may contain an ultraviolet stabilizer and an antioxidant.

Among useful fillers include clay, alumina, limestone, talc, calcium carbonate and expanded perlite. Preferred clays useful in the present invention include kaolin, surface treated kaolin, calcined kaolin, aluminum silicate and surface treated anhydrous aluminum silicate. The clay may be used in any form that facilitates the preparation of a pumpable adhesive. Preferably, the clay is mixed in the form of crushed powder, spray dried beads or finely drawn particles. The clay is about 0% by weight or more, more preferably about 5% by weight
And even more preferably, it may be used in an amount of about 10% by weight or more. Preferably, the clay is used in an amount of no more than about 70% and more preferably no more than about 60% by weight of the adhesive system.

The plasticizer is included so that the rheological properties can be modified to the desired consistency. The material is
It must not contain water, must be inert with respect to isocyanate groups, and must be compatible with the polymer present. Suitable plasticizers are well known in the art, and preferred plasticizers include alkyl phthalates such as diisononyl phthalate or diisodecyl phthalate, partially hydrogenated terpenes, trioctyl phosphate, toluene-sulfamide, esters of alkyl sulfonic acids, adipic acid Examples include esters, castor oil, toluene and alkylnaphthalene. The amount of plasticizer in each liquid of the curable composition is an amount that provides the desired rheological properties. The amounts disclosed herein include those added during the preparation of the isocyanate-containing prepolymer and during compounding of the curable composition. Preferably, the plasticizer is used in the adhesive system in an amount of about 0 wt% or more, more preferably about 5 wt% or more, and most preferably about 10 wt% or more, based on the weight of the adhesive system. Is done. The plasticizer is preferably used in an amount of about 45 wt% or less, and more preferably about 40 wt% or less, based on the weight of the adhesive system.

The adhesive used in the present invention further comprises a stabilizer having the function of protecting the adhesive composition from moisture, thereby inhibiting and preventing the advancement of premature crosslinking of isocyanates in the curable preparation. May be included. Stabilizers known to those skilled in the art for isocyanate functional adhesive systems may be used herein. Among the stabilizers, diethyl malonate, alkylphenol alkylate, p-toluenesulfonic acid isocyanate, benzoyl chloride and orthoalkylformate can be mentioned. The plasticizer is preferably in an amount of about 0.1 wt% or more, preferably about 0.5 wt% or more, and more preferably about 0.8 wt% or more, based on the total weight of the adhesive system. used. The stabilizer is about 5.0 wt% or less, more preferably about 2.0 wt% or less, and most preferably about 1.4 wt%, based on the total weight of the adhesive system.
Used in amounts up to weight percent.

Adhesives useful in the present invention include adhesion promoters, such as Mahdi, US Patent Application No. 2002/0100550, 0055-0065, incorporated herein by reference.
Paragraph and Hsieh, US Pat. No. 6,015,475, column 5, line 27 to column 6, 41.
It may further comprise an adhesion promoter disclosed in the row. Useful amounts of such adhesion promoters are also disclosed in these references and are incorporated herein by reference. In another embodiment, the adhesive system may include both isocyanate functional groups and hydrolyzable siloxane groups. The adhesive system is a blend of a prepolymer having an isocyanate functional group and a prepolymer containing a hydrolyzable siloxane functional group, for example, Zhu incorporated herein by reference.
, By the process disclosed in US Pat. No. 7,345,130 or by forming a prepolymer having both isocyanate and hydrolyzable siloxane functionalities, eg Hsieh, US Pat. , 015,475.

One-part isocyanate functional and hydrolyzable siloxane functional adhesives useful in the present invention can further comprise a hydrophilic material that functions to draw atmospheric moisture into the composition. This material can enhance the cure rate of the preparation by drawing atmospheric moisture into the composition. Preferably, the hydrophilic material is a liquid. Among the preferred hydrophilic materials are pyrrolidones, such as 1 methyl-2-pyrrolidone (or N-methylpyrrolidone). Another class of hydrophilic materials are high ethylene oxide-containing polyether polyols or catalytically active polyols containing amine groups, which may be present independently or have the isocyanate functionality and / or hydrolyzate. It may be incorporated into a degradable siloxane functional prepolymer. The hydrophilic material is preferably about 0.1 wt% or more, more preferably about 0.3 wt% or more, and preferably about 1.0 wt% or less, and more preferably about 0.1 wt%, based on the weight of the adhesive system. Present in an amount of 0.6% by weight or less. Optionally, the curable composition may further comprise a thixotrope (rheological additive). The thixotropic agent is well known to those skilled in the art, and examples thereof include fumed silica, calcium carbonate, and carbon black. A thixotropic agent can be added to the composition in an amount sufficient to provide the desired rheological properties. Preferably, the thixotropic agent is present in an amount of about 0% by weight or more, preferably about 1 part by weight or more, based on the weight of the adhesive system. Preferably, the optional thixotropic agent is present in an amount of no more than about 10 wt%, and more preferably no more than about 2 wt%, based on the weight of the adhesive system. The preparation may further comprise known additives, such as heat stabilizers and antioxidants known to those skilled in the art.

Adhesives useful in the present invention can be prepared by blending these components together using means well known in the art. In general, these ingredients are mixed in a suitable mixer. The blending is preferably carried out in the absence of oxygen and atmospheric moisture in an inert atmosphere to prevent premature reaction. To prepare the isocyanate-containing component, it may be beneficial to add a plasticizer to the reaction mixture so that the mixture can be easily mixed and handled. Alternatively, the plasticizer may be added during the mixing of all components. Preferably, these ingredients are blended at a temperature of about 20 ° C to about 100 ° C, more preferably about 25 ° C to about 70 ° C. Preferably, these materials are mixed under vacuum or under an inert gas such as nitrogen or argon. These ingredients are mixed for a time sufficient to prepare a well-mixed mixture, preferably about 10 to about 60 minutes. Once the adhesive composition liquids are prepared, they are packaged in a suitable container so that they are protected from atmospheric moisture and oxygen. Contact with atmospheric moisture and oxygen can result in premature crosslinking of the isocyanate-containing component.

In one embodiment, the adhesive composition used in the present invention is a hydrolyzable siloxane functional group (as described in Mahdi, US Pat. No. 6,828,403, incorporated herein by reference). An organic polymer having a silane component capable of silanol condensation). Preferably, the composition contains a polymer having a plastic skeleton and a hydrolyzable siloxane functional group (a silane component capable of silanol condensation). The polymer with a plastic skeleton may be any polymer with a plastic skeleton that can be functionalized using a hydrolyzable siloxane functional group (a silane component capable of silanol condensation). Among the particularly preferred polymer skeletons are polyethers, polyurethanes, polyolefins and the like. Of the particularly preferred polymer backbones, there are polyethers and polyurethanes, most preferred are polyethers. Even more preferably, the polymer is a polyether having a silane component capable of silanol condensation. In one embodiment, the polymers useful in the present invention are Yukim
Oto et al., US Pat. No. 4,906,707; Iwakiri et al., US Pat. No. 5,342.
Yukimoto, U.S. Pat. No. 5,063,270; Yukimoto et al., U.S. Pat. No. 5,011,900; Suzuki et al., U.S. Pat. No. 5,650,467; All patents are incorporated herein by reference. More preferably, the polymer is an oxyalkylene polymer containing at least one reactive silicon group per molecule. The term “hydrolyzable siloxane functional group”, “reactive silicon group” or “reactive silane capable of silanol condensation” means that the hydrolyzable group or hydroxyl group is bonded to a silicon atom and is crosslinked through the silanol condensation reaction. It means a silicon-containing group that can be bonded. The hydrolyzable group is not particularly limited and is selected from conventional hydrolyzable groups. Specific examples are hydrogen atom, halogen atom, alkoxy group, acyloxy group, ketoximate group, amino group, amide group, acidic amide group, aminooxy group, mercapto group, and alkenyloxy group. Preferred examples include a hydrogen atom, an alkoxy group, an acyloxy group, a ketoximate group, an amino group, an amide group, an aminooxy group, a mercapto group, and an alkenyloxy group. Alkoxy groups are more preferred, and methoxy or ethoxy groups are
It is most preferable because it is easy to handle due to light moisture instability. In one embodiment, the plastic polymer used in the adhesive composition comprises a polyol described herein with an isocyanatosilane having at least one silane component to which a hydrolyzable component is bound. A silyl-terminated prepolymer prepared by contacting the hydroxyl component of the polyol with the isocyanate component of the isocyanatosilane so that the terminal silane component can be disposed on the polyol; Performed without addition. In another embodiment, the polymer may be a polyurethane-based backbone having hydrolyzable silane groups. Such materials are disclosed in Chang, US Pat. No. 4,622,369 and Pohl, US Pat. No. 4,645,816, the important portions of which are incorporated herein by reference. In another embodiment, the backbone can be a plastic polymer, such as a polyether or polyolefin having a silicon component attached thereto. The unsaturated plastic polymer can be reacted with a compound having a hydrogen or hydroxyl component bonded to silicon, wherein the silicon component also has one or more unsaturated carbon chains. A silicon compound may be added to the polymer at a point of unsaturation by a hydrosilylation reaction. For this reaction, Ka, which is incorporated herein by reference.
Wakubo, U.S. Pat. No. 4,788,254, column 12, lines 38-61; U.S. Pat. Nos. 3,971,751; 5,223,597; 4,923,927; 40
9,995 and 5,567,833. The prepared polymer was prepared in the presence of a hydrosilylation crosslinker and hydrosilylation catalyst in US Pat. No. 5,567,833, column 17, lines 31-57, and US Pat. 5, 4
It can be crosslinked as described in 09,995.

The prepolymer having hydrolyzable siloxane functional groups is present in the adhesive composition in an amount sufficient to allow the adhesive to adhere to a substrate, such as glass, metal, plastic, composite or fiberglass. Preferably, the prepolymer having hydrolyzable siloxane functional groups is about 30% or more, more preferably about 40% by weight, based on the weight of the adhesive.
Thus, even more preferably it is present in an amount of about 45% by weight or more, and most preferably about 50% by weight or more. More preferably, the prepolymer is about 99 based on the weight of the adhesive.
It is present in an amount of no more than wt%, and most preferably no more than about 85 wt%. The adhesive compositions containing siloxy functional groups are known to those skilled in the art and are described in US Patent Application Publication No. 2002/0100550 [004] as described above and incorporated herein by reference.
2] It further comprises one or more catalysts that catalyze the silanol condensation reaction as described in the paragraph. The amount of catalyst in the adhesive preparation is preferably about 0.01 wt% or more, more preferably about 0.1 wt% or more, and most preferably about 0.2 wt% or more, and preferably about 5% or less, even more preferably about 1.0% or less, and most preferably about 0.4% or less. The adhesive composition is disclosed in US Patent Application Publication No. 2002/01005.
A hydrolyzable silicon compound may further be included as described in paragraph [43-47] of No. 50. The hydrolyzable silicon compound is about 0.01 to about 20 parts by weight per 100 parts by weight of a plastic polymer having reactive silicon groups and crosslinkable on siloxane bond formation, and preferably about 0.1 to about Used in an amount of 10 parts by weight. Another example of such a hydrolyzable silicon compound capable of crosslinking a silicon reactive polymer is disclosed in US Pat. No. 5,541,266, incorporated herein by reference. Examples of other such latent additives include U.S. Pat. No. 4,837,274, column 7, column 1, incorporated herein by reference.
The organosilicon compound B as disclosed in the 2nd line to the 9th column, the 15th line is mentioned. In a two-part composition, the hydrolyzable silicon compound and typically the catalyst is found in a second part separate from the silane functional prepolymer. Other adjuvants described for isocyanate functional adhesive compositions can be added to the prepolymer having hydrolyzable siloxane functional groups.

In use, the components of the two-part adhesive composition are mixed as is normally done when working with the materials. For the two-part adhesives that are most easily used in commercial and industrial environments, the capacity ratio for joining the two parts must be a convenient integer. This facilitates application of the curable composition using conventional commercially available static and dynamic mixing dispensers. Such dispensers for static mixing are shown in U.S. Pat. Nos. 4,538,920 and 5,082,147 (incorporated herein by reference), and are manufactured by Conprotec (New Jersey). Trade name MIX from State Salem)
Available under PAC or under SULZER ™ QUADRO manufactured by Sulzer Ltd., Switzerland. Typically, these dispensers use a pair of tubular containers arranged side by side with each tube intended to receive one of the two liquids of the polymerizable composition. Two plungers, one for each tube, to drain the contents of the tube into a common hollow elongated mixing chamber that may also contain a static mixer to facilitate the mixing of the two liquids. Simultaneously advanced (e.g., manually or by hand-operated ratchet mechanism). The blended polymerizable composition is extruded from the mixing chamber onto the substrate. Dynamic mixing may be used when using an electric drive. When the tubes are emptied, they can be replaced with new tubes and the application process can continue. The volume ratio at which the two liquids of the polymerizable composition are combined is controlled by the diameter of the tubes (each plunger is sized to be received in a fixed tube, and these plungers are tube You can move forward at the same speed). A single dispenser is often scheduled for use with a variety of different two-part polymerizable compositions, and the plunger is sized to deliver two parts of the polymerizable composition at a convenient mixing ratio Is done. Some common mixing ratios are 1: 1, 2: 1, 4: 1 and 10: 1. Preferably, the two liquids are mixed at a mixing ratio of about 1: 1.

Preferably, the mixed two-part composition of the present invention has an appropriate viscosity to allow dripping-free application. Preferably, the viscosities of the two separate components should be on the same order. Preferably, for compositions that are mixed using static mixing, the components before curing are about 10 Pa.s. S (10,000 centipoise) or more, more preferably about 20 Pa. S (2
Centipoise) or more, and most preferably about 40 Pa.s. It has a viscosity of S (40,000 centipoise) or more. Preferably, the two parts of the composition are about 15 prior to contact.
0 Pa. S (150,000 centipoise) or less, more preferably about 120 Pa.s. S (1
20,000 centipoise) or less, and most preferably about 100 Pa.s. S (100,00
0 centipoise) or less. The "viscosity" used in this section is determined by a shear rate of 20 round-trip seconds measured using a 20 mm diameter and 4 degree angle cone plate rheometer. Dynamic mixing requires higher viscosities. For lower viscosities, these components may require gelling agents known in the art to prevent sagging of the uncured adhesive system.

The catalysts used in the systems and processes of the present invention are dissolved or dispersed in a solvent or dispersant using standard miscibility techniques known to those skilled in the art. It is preferred to produce the catalyst solution or dispersion under a controlled atmosphere, for example in an inert gas environment.

The process of the present invention is used to bond various substrates together as described above. This process may be used to bond porous and non-porous substrates together. The catalyst solution or dispersion is contacted with the substrate surface that is bonded by the adhesive. This contact can be accomplished manually or using a robot applicator. The catalyst solution or dispersion may be applied by means of a spray applicator, brush, roller, or by wiping on the surface. Robotic and manual devices for such application are well known to those skilled in the art. The solvent can be volatilized. Preferably, the time from application of the catalyst solution or dispersion to application of the adhesive to the substrate is about 0.5 minutes or more, more preferably about 2.0 minutes or more and most preferably about 5.0 minutes or more. It is. Preferably, the time from application of the catalyst solution or dispersion to application of the adhesive to the substrate is about 300 minutes or less, more preferably about 60 minutes or less and most preferably about 30 minutes or less. After the solvent is volatilized, it preferably remains on the surface of the substrate to which only the catalyst is bound. In one embodiment, the treated surface of the substrate can have a catalyst and a marker used to indicate that the treatment has occurred. Alternatively, process steps using a vision system may be used to ensure that the catalyst solution or dispersion has been applied. This may involve exposing the substrate to a light source that triggers the marker to be visible, or it may be a thermal imaging system that confirms temperature changes due to solvent evaporation. Thereafter, the adhesive is brought into contact with the substrate.

The adhesive composition is applied to the location where the catalyst solution or dispersion of the first substrate was previously applied, and the adhesive composition on the first substrate is then contacted with the second substrate. . The catalyst solution or dispersion may be applied to one or more substrates prior to the point at which the adhesive is applied to each substrate. Generally, the adhesive is applied at a temperature at which the adhesive can be pumped. Preferably,
The adhesive is applied at a temperature of about 10 ° C. or higher, more preferably about 18 ° C. or higher for application. Preferably, the polymerizable adhesive system is applied at a temperature of about 40 ° C. or less, and more preferably at a temperature of about 35 ° C. or less. The two-part adhesive composition begins to cure as soon as the two parts are mixed. One-part moisture curable compositions begin to cure as soon as they are exposed to ambient moisture. One-part latent curable adhesives begin to cure as soon as they are exposed to the activation temperature of the catalyst. Curing can be accelerated by applying heat to the curable adhesive by induction heat, radiant heat, microwave heating, or the like. The process of the present invention is particularly useful when thermal acceleration is utilized. For moisture curable adhesives, the cure rate can be enhanced by adding moisture to the atmosphere or by performing curing in a humidified chamber. Preferably, the curable adhesive system is prepared to provide an open time of at least about 3 minutes or more and more preferably about 5 minutes or more. “Open time” is defined as after the contact of two liquids, after application of a one-part moisture curable adhesive, or after activation of a latent catalyst in a one-part adhesive containing a latent catalyst. It means the time until the adhesive begins to become a highly viscous paste and no longer shows a tendency to deform during assembly to adhere to the shape of the second substrate.

The process of the invention is preferably metal, (using an e-coat or paint system)
Used to bond coated metal, plastic, fiber reinforced plastic, wood and / or glass together. In another embodiment, the composition of the present invention may be used to bond modular components to the body of an automobile or to each other. Examples of modular components include vehicle modules such as doors, windows, roof modules or bodies. The process of the present invention can also be used to join an exterior or interior to an automobile body.

The process of the present invention involves bonding an adhesive composition to a given substrate in the absence of a primer or in the absence of any other treatment on the substrate surface other than the application of a catalyst solution or dispersion. Make it possible. Examples of substrates to which the adhesive composition binds without the need for a primer or surface treatment include sheet molding compounds (SMC), fiber reinforced plastics such as polyester, and coated metals such as e-coated metals. And steel and painted metal sheets.

The adhesive system used in the present invention is preferably applied to one of the substrates after about 60 minutes, more preferably after about 40 minutes and most preferably after about 20 minutes without moving the substrates relative to each other. Shows the proper green strength to hold together without applying force. The adhesive system applied using the process of the present invention preferably exhibits full cure after about 7 days, more preferably after about 16 hours and most preferably after about 12 hours. The present polymerizable adhesive system preferably exhibits a tensile strength of about 5 MPa or more, more preferably about 10 MPa or more and most preferably about 15 MPa or more after complete curing. The polymerizable adhesive system preferably exhibits a lap shear strength of about 5 MPa or more, more preferably about 10 MPa or more and most preferably about 15 MPa or more after full cure, wherein the lap shear rate is DIN (German Industry). Standard) 53
Determined in accordance with H.283.

The molecular weights described herein are number average molecular weights that can be determined by gel permeation chromatography (also called SEC). For polyurethane prepolymers, it is also possible to calculate the approximate number average molecular weight from the equivalents of isocyanate compounds and the equivalents of polyol compounds with which they are reacted, as is known to those skilled in the art. Unless otherwise stated, all parts and percentages are by weight based on the weight of the adhesive system.

Exemplary Embodiments of the Invention The following examples are provided to illustrate the present invention and are not intended to limit the scope thereof.

Examples 1-7
Lap shear type samples of e-coated steel (100 × 45 × 1 mm) as one substrate and e-coated aluminum (100 × 45 × 1 mm) as another substrate are used. Prior to applying the adhesive, the contact surface of the substrate is treated with n-heptane or the catalyst solution of the present invention as described in Table 1. The lap shear sample is prepared by applying an adhesive on the substrate so that the overlap is 10 mm, and then the substrate is placed in a jig so that the height of the adhesive is 2 mm. . Wipe off any excess adhesive. The jig on which the lap shear sample is placed is moved to the guidance device (IFF EW2 or IFF EW
5) Place within. This sample is 80% of the desired temperature at 10 kHz on the aluminum side only
Heat by induction until. This takes about 30 seconds. The frequency is then changed to 20 kHz and the desired temperature is maintained for an additional 30 seconds. The lap shear sample is then immediately
Place in nstron test machine and record lap shear strength as strength at break. Failure modes also include adhesion failure (breakage of adhesive bond to the substrate), cohesive failure (CF, adhesive breaks inside) and boundary failure (BF, adhesive removes residue on substrate surface) Record as crush at the interface. This adhesive is a polyisocyanate prepolymer type in one liquid and a polyether polyol type in the other liquid from Dow Chemical Co., Ltd.
A two-part adhesive containing a curing agent available at 850 s. The results are shown in Table 1.

Examples 15-23
The plastic substrate is tested as described below. The tested plastic substrate is
Sheet molding compound (SMC) (polyester), polycarbonate-polybutylene terephthalate blend (PCPBT), and ethylene / propylene / diene / monomer rubber (
EPDM). These substrates are treated with n-heptane or 0.9% tris- (dimethylaminomethyl) phenol in n-heptane as described above. An adhesion test sample is prepared by applying approximately 8 mm beads on a substrate. The adhesive is flattened to a height of 5 mm. The test samples were cured at room temperature for 7 days and Examples 18 and 2
2 further Cataplasma conditions (7 days at 23 ° C. and 50% relative humidity, then 7 days at 70 ° C. and 100% relative humidity, and -20 ° C. for 16 and 2 hours to ambient temperature) Aging under. Remove the adhesive and determine the failure mode. The results are shown in Table 2.

Examples 24-33
Lap shear samples are treated with n-heptane or 2,4,6-tris (dimethylaminomethyl) phenol (0.9% in n-heptane) prior to application of the adhesive. The lap shear samples used are e-coated steel (100 × 25 × 1.5 mm) as well as e-
Coat and paint (1K Monohydrocoat 9147 from PPG)
Artic white steel (100 × 100 × 1.5 mm) and a substrate is prepared. The overlap is 9 mm and the adhesive height is 5 mm. The adhesive used is BETASEAL (TM) 1841, and Die Europe (Dow E
urope) A one-part moisture curable isocyanate functional adhesive available from GmbH is applied on a surface coated with a commercially available base coat at a temperature of 60 ° C. The width of the adhesive is limited by the adhesive tape. This test is conducted according to the following time series.
Time Operation 0 Adhesive application, 40 seconds after starting cooling 20 seconds after finishing cooler 30 seconds after removing adhesive tape 50 seconds after fixing test piece in vertical position Weight load 134 g (including substrate) 10 minutes after applying Measure the sag / slip The test plaques are oriented in a vertical manner after application of the adhesive and the distance of the adhesive sliding is measured in mm. The results are shown in Table 3.

Claims (10)

A method of adhering a reactive polyisocyanate-based adhesive to at least one substrate,
a) a catalyst for curing a reactive polyisocyanate-based adhesive comprising titanium acetylacetonate; and volatile comprising at least one of an aliphatic hydrocarbon, an alicyclic hydrocarbon, and an aromatic hydrocarbon Contacting a solution or dispersant comprising a solvent or a dispersant with the surface of the base to which the reactive polyisocyanate-based adhesive will bind;
b) volatilizing and removing the volatile solvent or dispersant;
c) contacting the reactive polyisocyanate adhesive with the surface treated in step a); and d) curing the reactive polyisocyanate adhesive. Wherein the at least one substrate comprises a first substrate and the second substrate, the first substrate, the second substrate before the reactive polyisocyanate based adhesive is cured, the first The method of claim 1, wherein the reactive polyisocyanate-based adhesive is disposed between the first and second substrates. It said second substrate, a surface portion in contact with the reactive polyisocyanate based adhesive, the step a) and is treated in step b), The method of claim 2.   The method according to any one of claims 1 to 3, wherein the reactive polyisocyanate-based adhesive is a one-component adhesive system or a two-component adhesive system.   The method according to any one of claims 1 to 4, wherein the one or more substrates are coated metals.   The process according to any one of claims 1 to 5, wherein the concentration of the catalyst in the volatile solvent or dispersant is 0.01 to 2% by weight.   The catalyst solution in a volatile solvent is applied to one or more surfaces of the one or more substrates by spraying, rolling, brushing or wiping. The method as described in any one of.   8. A method according to any one of claims 1 to 7, wherein after step b) only the catalyst is placed on the surface of the substrate which is bonded to the reactive polyisocyanate adhesive.   8. The method according to any one of claims 1 to 7, wherein after step b), only the catalyst and the marker are placed on the surface of the substrate that binds to the reactive polyisocyanate adhesive.   The method according to claim 1, wherein the solution or the dispersant does not contain a film-forming resin.