JP6164911B2 - Method for applying decoration or makeup with high brightness or high concealment to nails and skin, and decoration set or makeup set for applying the decoration or makeup - Google Patents

Description

  The present invention relates to a method for applying high-luminance or high-concealment decoration or makeup to a nail or skin with an arbitrary stroke, and a decoration set or makeup set for applying the decoration or makeup.

Conventionally, in order to decorate or make up nails or skin with arbitrary drawing lines, a liquid in which a coloring material consisting of a dye and a pigment and a fixing resin is mixed and dispersed in a solvent is applied to the nails and skin with a brush or a brush tip. A method of fixing a drawn line by volatilizing is generally known. At that time, in order to obtain a bright and brightly drawn line, scaly pearl pigments, aluminum flakes, lame particles, and the like are blended as color materials.
However, since these scale-like color materials are oriented non-uniformly on the drawn line, the grainy feeling remains and cannot give a continuous glossy feeling. Further, since the particles are large, they are easily clogged with a brush or a brush tip, and it is difficult to blend them at a high concentration.

  Also, in order to apply scaly high-luminance color materials at a high concentration, a method is known in which a press powder obtained by mixing a small amount of wax or oil with these color materials and compression-molding is applied with a brush. (For example, commercially available for eye shadow). However, this method has a drawback in that the coloring material after application can be easily removed because a large amount of fixing resin cannot be blended.

On the other hand, in order to express a high-intensity drawn line, for example, a method of transferring a drawn line by applying an adhesive to a nail or skin application surface and then pressing and contacting a transfer foil on which aluminum vapor deposition has been applied is past. (See, for example, Patent Documents 1 and 2).
The present inventors performed a reproduction test based on each method described in Patent Documents 1 and 2 above, but although a drawn line having a continuous metallic luster was obtained under certain conditions, the outside temperature Further, the transferability varies depending on the drying time of the adhesive, and it is difficult to easily obtain a good drawn line.
In addition, it was found that there are problems such as the inability to obtain stable transfer performance due to the difference in adhesion performance at the application site such as the nail, the back of the hand, and the inner side of the upper arm. For this reason, the type and physical properties of the adhesive and the configuration of each layer of the transfer foil were variously tested. However, sufficient transfer performance could not be obtained.

JP-A-62-284605 (Claims, Examples, etc.) JP-A-2-169290 (Claims, Examples, etc.)

  The present invention has been made in view of the above-mentioned problems of the prior art, and is intended to solve this problem, and a method for simply applying a high-luminance or high-concealment decoration or makeup to a nail and skin with an arbitrary stroke, and its An object is to provide a decoration set or a makeup set for applying decoration or makeup.

  As a result of intensive studies in view of the above-described conventional problems, the present inventors applied a coating liquid composed of a specific composition filled in a known coating container, and applied a specific transfer foil or coloring material. It has been found that, by combining, high-luminance or high-concealment decoration or makeup can be applied to the target nails and skin with an arbitrary drawn line, and the present invention has been completed.

That is, the present invention resides in the following (1) to (9).
(1) Using an applicator filled with a coating solution that remains at least tacky after drying, which contains at least water and an O / W emulsion resin, the coating solution can be applied to nails and skin as an arbitrary shape / character. It is dried after being applied, and the transfer foil is pressed and contacted on the applied drawn line where tackiness is expressed, and the high-brightness or high-hiding property line is transferred by peeling off the foil. A method of applying highly concealing decoration or makeup.
(2) Using an applicator filled with a coating solution that remains tacky even after drying, which contains at least water and an O / W type emulsion resin, the coating solution can be applied to nails and skin as an arbitrary shape / character. It is characterized by obtaining a high-brightness or high concealment drawing line by applying and drying after applying, pressing the colorant powder onto the application drawing line that expresses tackiness, and removing the powder outside the application drawing line with a cleaning tool. A method of applying high-luminance or high-concealment decoration or makeup to nails and skin.
(3) An inclined ball tack test (inclination angle of 30 °, after forming a coating with a coating thickness of 50 μm using the coating solution and drying for 30 minutes in an environment of 25 ° C. and 65% humidity) The method for applying decoration or makeup with high brightness or high concealment to the nails and skin according to the above (1) or (2), wherein the nail and the skin according to the above (1) or (2) have adhesiveness with a ball number at 25 ° C. of 1 or more.
(4) The O / W type emulsion resin of the coating solution is one or more selected from an (acrylates / ethyl hexyl acrylate) copolymer and an [acrylates / alkyl methacrylate (C12-22)] copolymer, A method for applying decoration or makeup with high luminance or high concealment to the nails and skin according to any one of (1) to (3) above.
(5) The drawn line at the time of application is transparent to translucent milky white, and it is possible to confirm the drawn line by becoming white at the time of drying, and the standard of the drawn line is determined by a change in color tone (whiteness). A method of applying decoration or makeup with high luminance or high concealment to the nails and skin according to any one of (1) to (4) above.
(6) Any one of the above (1) to (4), characterized in that an emulsion resin composed of a (styrene / alkyl acrylate) copolymer is blended in order to inform the guideline of drawing strokes by a change in color tone (whiteness). A method of applying decoration or makeup with high brightness or high concealment to the nails and skin described in 1.
(7) The transfer foil is a cold foil that does not have a hot-melt melt layer due to heat sensitivity. The decoration or makeup with high brightness or high concealment on the nails and skin according to (1) above How to apply.
(8) A ball number of 1 or more in an inclined ball tack test (inclination angle 30 °, 25 ° C.) after forming a coating with a coating thickness of 50 μm and drying for 30 minutes in an environment of 25 ° C. and 65% humidity. In order to give a decoration or makeup with high brightness or high concealment to nails and skin, which includes a coating liquid containing at least water and an O / W emulsion resin having a certain adhesive property , and transfer foil or coloring material powder Decorative set or makeup set.
(9) The coating solution contains one or more O / W type emulsion resins selected from (acrylates / ethyl hexyl acrylate) copolymers and [acrylates / alkyl methacrylate (C12-22)] copolymers, A decoration set or makeup set for applying decoration or makeup with high brightness or high concealment to the nails and skin according to (8) above.

  ADVANTAGE OF THE INVENTION According to this invention, the method which can apply a high-intensity or high concealment decoration or makeup to a nail | claw or skin easily by arbitrary drawing lines, and the decoration set or makeup set for applying the decoration or makeup are provided. Is done.

It is a longitudinal cross-sectional view which shows an example of embodiment of the applicator used for the method of giving a high-luminance or high concealment decoration or makeup to the nail | claw and skin of this invention.

Hereinafter, embodiments of the present invention will be described in detail.
The method for applying decoration or makeup with high brightness or high concealment to the nails and skin of the present invention, as a first embodiment, remains tacky even after drying containing at least water and an O / W emulsion resin. Using an applicator filled with the coating solution, the coating solution is applied to the nail and the skin as an arbitrary shape and character, dried, and the transfer foil is pressed and contacted on the coated line where tackiness is expressed, and the foil is peeled off. In the second embodiment, an application tool filled with the same application liquid as that of the first embodiment is used as the second embodiment, and the application liquid is transferred. Apply to the nail and skin as an arbitrary shape and character, then dry, press the colorant powder onto the painted line with tackiness, and remove the powder outside the painted line with a cleaning tool to increase the brightness or Characterized by obtaining highly concealed drawn lines It is intended.
Hereinafter, the term “present invention” includes the first and second embodiments.

The coating solution used in the present invention contains at least an O / W type emulsion resin and water (purified water, ion-exchanged water, pure water, etc.) and remains tacky (adhesive) after drying. It is characterized by being.
In the present invention, in order to express tackiness after drying, it is necessary to blend a specific O / W type emulsion resin. Examples of the O / W type emulsion resin that can be used include at least one selected from an (acrylates / ethyl hexyl acrylate) copolymer and an [acrylates / alkyl methacrylate (C12-22)] copolymer.
Commercially available products include (Acrylates / ethylhexyl acrylate) copolymers Nicazole MH-6010, TS-620 (Nippon Carbide Corp., emulsion resin), [Acrylates / alkyl methacrylate (C12-22)] copolymer, SOLTX OPT ( Dow Chemical Co., Ltd. emulsion resin) can be used.

The coating liquid of the present invention comprises the above O / W type emulsion resin and water as main components. These O / W type emulsion resins are 10 to 70 (in terms of solid content) with respect to the total amount of the coating liquid. It is preferable to mix in the range of mass%.
When the blending amount of the O / W type emulsion resin is less than 10% by mass, the tackiness after drying is insufficient, and the transfer foil as the next work process is insufficiently peeled, or the brightness is high. Alternatively, there is a problem that the fixing of the high hiding colorant is weak and easy to remove, and on the other hand, when the blending amount of the O / W type emulsion resin is more than 70% by mass, the tip of the coated body is used. Neither is preferable because it is easy to dry and solidify and it is difficult to produce a stable drawn line.

As the coating solution in the present invention, in addition to the O / W type emulsion resin, a known water-soluble resin for enhancing the adhesive strength may be added as an optional component, and the dryness of the drawn line may be increased. Ethanol may be added to. However, if a large amount of ethanol is added, the above-mentioned O / W type emulsion resin becomes unstable, and sufficient tackiness cannot be obtained after drying. preferable.
In addition, this coating solution may be combined with known preservatives and thickeners for viscosity adjustment, but ultimately it is necessary to retain tackiness after drying, so selection of materials Adjust to a suitable combination. In addition, a known water-soluble resin may be used in combination for adjusting the adhesiveness. The known water-soluble resin here gradually increases in viscosity due to drying and loses tackiness after drying, so the function of the present invention is not fulfilled when used alone, but the initial tackiness improvement and transfer of foil, etc. It is possible to supplementarily add for the purpose of improving the adhesiveness later.
For example, Tori Gosei Co., Ltd., Jurimer AT-210 (alkyl acrylate copolymer ammonium), Nippon Shokubai Co., Ltd., PVP-K90 (polyvinylpyrrolidone), etc. can be used.

The coating liquid used in the present invention contains at least water and an O / W type emulsion resin, and, if necessary, each of the above-mentioned blending components and the balance as water, but more preferably, the drawn line is dried. In order to be able to discriminate the standard based on a change in color tone (whiteness), it is desirable to blend an emulsion resin composed of a (styrene / alkyl acrylate) copolymer.
In the coating liquid of the present invention, the O / W type emulsion resin as a main component is generally milky white, but the colorability is slightly weak and the coating line is slightly indistinguishable. Here, a method of blending a coloring material such as a dye or a pigment is conceivable. In this case, however, the quality of drawn lines such as transfer in a subsequent process may be adversely affected. In addition, since it is difficult to determine whether the drawn lines are dry or not, it is desirable to blend an emulsion resin made of a copolymer (styrene / alkyl acrylate) that is an acrylic emulsion resin.

As the (styrene / alkyl acrylate) copolymer that can be used, commercially available products such as ROMSPHERE PGL, OPULYN 305 (above, manufactured by Dow Chemical Co., Ltd., emulsion resin) can be used.
The blending amount of the (styrene / alkyl acrylate) copolymer is preferably blended in the range of 2.5 to 10% by mass (in terms of solid content) with respect to the total amount of the coating solution with respect to the total amount of the coating solution.
When the blending amount of this (styrene / alkyl acrylate) copolymer is less than 2.5% by mass, the coloring power is weak and the effect is insufficient. On the other hand, when it exceeds 10% by mass, the coating after drying is applied. Since it becomes a factor which inhibits surface tack property, it is not preferable again.

By blending the above (styrene / alkyl acrylate) copolymer, it is a thin white line at the time of application, but the whiteness clearly increases as 2 minutes pass at room temperature, and becomes a constant white after drying. For this reason, since the application location can be understood and the dry state of the drawn line can be grasped, the quality of the foil transfer in the subsequent process can be stabilized.
By blending this (styrene / alkyl acrylate) copolymer into the coating solution containing water and an O / W type emulsion resin, it is possible to discriminate an indication of drawn line drying by color tone (whiteness) change. . Specifically, it changes from transparent to translucent milky white (thin white line) at the time of application, but the whiteness clearly increases as several minutes (2 minutes) elapses at room temperature, and the whiteness is constant after drying. (White). For this reason, the application location and the dry state of the drawn line can be grasped, so the standard for drawn line drying can be easily determined by changing the color tone (whiteness), and quality such as foil transfer in the subsequent process and pressing contact of the coloring material Can be stabilized.

In the present invention, the coating liquid that remains tacky after drying is specifically a film having a coating thickness of 50 μm formed using the coating liquid and dried for 30 minutes in an environment of 25 ° C. and 65% humidity. After that, a coating solution having a ball number of 1 or more in an inclined ball tack test (inclination angle of 30 °, 25 ° C.).
The tilt type ball tack test in the present invention (including examples described later) is a measurement method employed in JIS Z 0237: 2009. This measurement method uses two types of high-carbon chromium bearing steel specified in JIS G 4805 at the top of a triangular device having an inclination angle of 20 degrees, 30 degrees or 40 degrees. JIS B 1501 “Ball A total of 31 types of balls excluding 5/64, 7/64, 9/64, 15/64 and 17/64 of steel balls with a size of 1/16 to 1 The rolling ball (100mm) rolls over the runway (100mm), and the value that is 32 times the “ball nominal” stopped on the adhesive surface (100mm) of the test piece following the runway is called the “ball number”. It is expressed with a number. This method is described in J. Org. Also called Dow method.
In the present invention, a coating film having a coating thickness of 50 μm is formed using the coating solution having the above composition, and dried for 30 minutes in an environment of 25 ° C. and a humidity of 65%. It is desirable that the coating solution has a tackiness so that the ball number at 30 ° C. and 25 ° C. is 1 or more. Since the stronger the tackiness, the better. The upper limit of the ball number is preferably as large as possible.
Adjustment of the adhesive coating liquid having the ball number can be prepared by suitably combining the type and amount of the O / W type emulsion resin to be blended in the coating liquid and other blending components. .

The coating liquid used for this invention can be prepared by a conventional method, for example, it fills an applicator and is apply | coated to a nail | claw or skin.
The applicator that can be used is not particularly limited as long as it can apply an appropriate amount of the application liquid to the nail and / or the skin as an arbitrary shape and character, for example, the application liquid is applied to a bottle container with a brush. Examples thereof include a filled applicator, and an applicator filled in an applicator container provided with application means (application destination) such as a brush tip or a pen core.

Specifically, in order to apply arbitrary characters and designs, it is an application that fills a container with a brush or pen type application destination via a valve mechanism at the end of a bottle with a brush or the container body. Tools are preferred.
For example, the applicator A shown in FIG. 1 can be mentioned. The applicator A stores the coating liquid by combining the front shaft 3 and the rear shaft 4, and also includes a valve stem 5, a pen-shaped application portion 6 serving as a coating destination, a base 7, a core 8, an agitating ball 9, and the like. It is a configuration of a very general pen type applicator to be held. By pressing the pen-shaped application part 6 against the skin or the like, the valve stem 5 is opened, and the application liquid is supplied to the application part 6 and applied. Needless to say, the present embodiment may be applied not only to this applicator but also to other forms of applicators. The cap body 2 and the cap accessory 1 are fitted to form an integral cap. By fitting the cap with the front shaft 3, it is possible to surround the application part 6 and block the air flow from the external space, and thus it is possible to prevent the application part 6 from drying.

  In the present invention, the user draws an arbitrary shape (design, etc.) and characters on the nails and / or skin from the application destination of each of the above applicators at room temperature (25 ° C.). dry. Preferably, it is desirable to dry for at least 1 minute, usually 1 to 10 minutes, more preferably 1 to 5 minutes. In the prior art, the tackiness of the adhesive changes every moment with the drying time, and if it is too early, the tackiness is weak and the transfer foil cannot be transferred. On the contrary, if the drying time is long, it becomes hard to transfer, and it is difficult to attach lame particles. Conventionally, in order to transfer well, it is necessary to work within a certain drying time range, and these times are not easy because they depend on the outside air temperature and humidity. In the present invention, although there is a difference in the initial drying time depending on the outside temperature and humidity, since the tackiness is maintained after drying, it is possible to transfer with stable quality without worrying about delicate drying time. Is.

In the present invention, after the coated surface is dried, in the first embodiment, the transfer foil is pressed and contacted with the coated drawing line exhibiting tackiness, and the drawn line with high luminance or high concealment is transferred by peeling the foil. Therefore, decoration or makeup with high luminance or high concealment can be applied to the target nail or skin with an arbitrary drawing line. In the second embodiment, the coloring material powder is pressed onto the coating drawing line that exhibits tackiness. Apply high brightness or high concealment decoration or makeup on the desired nails or skin by touching and removing the powder outside of the painted line with a cleaning tool to obtain a high brightness or high concealment drawing line Will be able to.
In the first embodiment of the present invention, the transfer foil to be used is not particularly limited as long as it can transfer a high brightness or high concealment property. For example, 1) To a resin film such as PET as a base material, A thin film coated in the order of 2) a colored layer (peeling layer), 3) an aluminum vapor deposition layer, and 4) an adhesive layer, or a so-called pigment foil without an aluminum vapor deposition layer can be exemplified. In general, 1) heat is applied from the surface of PET or the like, 2) the colored layer (peeling layer) and 4) the adhesive layer resin is heated and melted, and the design is transferred to the non-transferred material. In the present invention, the 2) colored layer (peeling layer) and 4) the adhesive layer is preferably a cold foil that does not have a heat-sensitive hot-melt melt layer so that the resin layer can be easily peeled off without heat. . Specifically, the resin layer can be made easier to peel off by making the resin layer thin or blending silica so that it is easy to cause cohesive failure. The coloring material of the colored layer may be a so-called dye / pigment that can be used for industrial applications. More preferable coloring materials include titanium oxide, iron oxide, kangzhou, gunjo, D & C Black No. 2, and FD & C Blue No. 1 and lake pigments, FD & C Yellow No. 5 and lake pigments, FD & C Yellow No. 6 and lake pigments, D & C Red No. 6, D & C Red No. 7, D & C Red No. Color materials that can be used in cosmetics such as 34 and D & C Red No. 30 are preferred.
In the first embodiment, a transfer foil deposited with aluminum is used in order to obtain a drawn line with high luminance or high concealment. However, the above-described pigment foil composed only of a colored layer and an adhesive layer without providing a vapor deposition layer is used. There is no problem to use. Since a continuous colored layer is transferred to the surface of the drawn line having tackiness, a glossy drawn line can be obtained.

  In the second embodiment of the present invention, the surface of the drawn line with tackiness is lightly pressed with a color material such as scaly pearl pigment, aluminum flakes, glitter particles, or high hiding pigment, and then applied to a brush or tissue. When the excess color material is removed with a cleaning tool such as a brush, the color material remains in high density on the drawn line. For this reason, compared with the drawn line applied in the state dispersed in the liquid, a drawn line having high luminance or high concealing property (high concentration) can be obtained. Further, since the above-described tackiness remains strongly on the surface on which the coating liquid has been dried, the coloring material is fixed, and it is possible to obtain a drawn line that is difficult to remove from the skin or the like as compared with the aforementioned press powder.

In the method of the present invention configured as described above, decoration or makeup with high luminance or high concealment can be easily applied to the nail or the skin with an arbitrary drawn line.
The decorative set or makeup set of the present invention is for simply applying a high-luminance or high-concealment decoration or makeup to the nails or skin with an arbitrary stroke, and is a container filled with the above-described coating liquid or Applicator, inkjet cartridge and inkjet printer, and aluminum-deposited transfer foil, pigment foil, scaly pearl pigment, aluminum flake, lame particles, highly concealing pigment, etc. to obtain a high-brightness or highly concealed drawn line The method of the present invention can be easily carried out by using a set in which the colorant powder is combined.

  Next, the present invention will be described in more detail by way of examples.

[Example 1]
O / W emulsion resin 30.0% by mass
[SOLTEX OPT, manufactured by Dow Chemical Co., Ltd., acrylates / alkyl methacrylate (C12-22) copolymer, solid content 48%]
Ethanol 10.0% by mass
(Styrene / alkyl acrylate) copolymer 20.0% by mass
[ROMSPHERE PGL, manufactured by Dow Chemical Co., Ltd., solid content 25%]
Water (purified water) 24.0% by mass
Tackiness adjusting resin (Julimar AT-210, manufactured by Toagosei Co., Ltd.) 15.0% by mass
Hydroxyethyl cellulose (thickener) 0.1% by mass
Phenoxyethanol (preservative) 0.9% by mass
The raw material components were mixed and stirred to obtain a coating solution.
When the tack property was measured by the above-described tilted ball tack measurement method, the ball number was 1.
This coating solution was filled into a container shown in FIG. 1 provided with a pen-type coating destination made of polyacetal resin at the tip via a valve mechanism to produce an applicator.
Next, an arbitrary pattern was drawn on the arm while the coating solution was taken out from the pen-shaped coating destination.
After drying for 2 minutes at room temperature, a golden transfer foil (Murata Gold Leaf Co., Ltd., Cold Foil NSA-6) was pressed and peeled off slowly, and a high-brightness and high-hiding gold stroke was transferred onto the arm. It was. Similarly, when the transfer foil was pressed and slowly peeled off after drying for 10 minutes and after drying for 20 minutes, a high-brightness and high hiding gold line was transferred onto the arm regardless of the time.
At the time of application on the arm, the coating solution was transparent to translucent milky white (thin white line), but the whiteness increased clearly as the above 2 minutes passed at room temperature, and after drying it was constant It was white (white), and it was found that the application location could be easily understood and the dry state of the drawn line could be grasped, and the standard of drawn line drying could be easily determined by changing the color tone (whiteness). The discrimination based on the change in color tone (whiteness) could be easily made in the same manner in Examples 2 to 5 below.

[Example 2]
Using the coating solution and applicator obtained in Example 1 above, an arbitrary pattern was drawn on the arm while the coating solution was taken out from the coating destination.
After drying for 2 minutes at room temperature, a silver-colored lame powder (Diamond Kogyo Co., Ltd., Diamond Piece H-55UC, average particle size 150 μm) is sprinkled, pressed with tissue paper, and then the excess lame powder is removed with a brush. The silver lines with high brightness and high concealment remained on the arms.

Example 3
A coating solution was obtained by mixing and stirring the same composition as in Example 1 except that 30% of the O / W emulsion resin in Example 1 was replaced with 30% of the following emulsion resin.
O / W emulsion resin 30.0% by mass
[Nicazole MH-6010, manufactured by Nippon Carbide Corporation, (Acrylates / Ethylhexyl acrylate) copolymer, solid content 58%]
When the tackiness of this coating solution was measured by the above-described tilted ball tack measurement method, the ball number was 2.
In the same manner as in Example 1, this coating solution was filled into a container shown in FIG. 1 provided with a pen-type coating destination made of polyacetal resin at the tip through a valve mechanism to prepare an applicator.
Next, an arbitrary pattern was drawn on the arm while the coating solution was taken out from the pen-shaped coating destination.
After drying for 2 minutes at room temperature, a golden transfer foil (Murata Gold Leaf Co., Ltd., Cold Foil NSA-6) was pressed and peeled off slowly. It was.

Example 4
A coating solution was obtained by mixing and stirring the same composition as in Example 1 except that 30% of the O / W emulsion resin in Example 1 was replaced with 30% of the following emulsion resin.
O / W emulsion resin 30.0% by mass
[Nicazole TS-620, manufactured by Nippon Carbide Corporation, (Acrylates / ethylhexyl acrylate) copolymer, solid content 58%]
When the tackiness of this coating solution was measured by the above-described tilted ball tack measurement method, the ball number was 2.
In the same manner as in Example 1, this coating solution was filled into a container shown in FIG. 1 provided with a pen-type coating destination made of polyacetal resin at the tip through a valve mechanism to prepare an applicator.
Next, an arbitrary pattern was drawn on the arm while removing the coating liquid from the pen tip.
After drying for 2 minutes at room temperature, a golden transfer foil (Murata Gold Leaf Co., Ltd., Cold Foil NSA-6) was pressed and peeled off slowly, and a high-brightness and high-hiding gold stroke was transferred onto the arm. It was.

Example 5
In Example 1, 15% of the tackiness adjusting resin (Jurimer AT-210, manufactured by Toagosei Co., Ltd.) was changed to 2% of PVP-K90 (manufactured by Nippon Shokubai Co., Ltd.), and the difference of 13% was replaced with water (purified water). (Total moisture 37%) and others were mixed and stirred in the same composition as in Example 1 to obtain a coating solution.
When the tackiness of this coating solution was measured by the above-described tilted ball tack measurement method, the ball number was 2.
In the same manner as in Example 1, this coating solution was filled into a container shown in FIG. 1 provided with a pen-type coating destination made of polyacetal resin at the tip through a valve mechanism to prepare an applicator.
Next, an arbitrary pattern was drawn on the arm while removing the coating liquid from the pen tip.
After drying for 2 minutes at room temperature, a golden transfer foil (Murata Gold Leaf Co., Ltd., Cold Foil NSA-6) was pressed and peeled off slowly, and a high-brightness and high-hiding gold stroke was transferred onto the arm. It was.

Example 6
An arbitrary design was drawn on the arm using the same coating solution and applicator as in Example 1 above.
After drying for 2 minutes at room temperature, a green pigment foil (manufactured by Murata Gold Leaf Co., Ltd., GF-177 green) was pressed and peeled off slowly. As a result, a highly concealed green line was transferred onto the arm.

Example 7
The same coating liquid as in Example 5 was filled into an ink cartridge ICBK57 (manufactured by EPSON) that was carefully washed, and this was set in a partially modified PX-W8000 printer (manufactured by EPSON). With this printer, an arbitrary pattern is drawn on the back of the hand, and after drying for 2 minutes at room temperature, the golden transfer foil (Murata Metal Co., cold foil NSA-6) is pressed and peeled off slowly. A highly concealed golden drawing was transferred.

[Comparative Example 1]
A coating solution was obtained by mixing and stirring in the same composition as in Example 1 except that 30% of the O / W emulsion resin having tackiness after drying in Example 1 was replaced with 30% of the following general emulsion resin. .
O / W emulsion resin 30.0% by mass
[Yodosol GH800F, manufactured by Akzo Nobel, ammonium acrylate copolymer, solid content 45%]
When the tackiness of this coating solution was measured by the above-described tilted ball tack measurement method, the ball number was smaller than 1 and could not be measured. That is, the tackiness after drying was not expressed.
In the same manner as in Example 1, this coating solution was filled into a container shown in FIG. 1 provided with a pen-type coating destination made of polyacetal resin at the tip through a valve mechanism to prepare an applicator.
Next, an arbitrary pattern was drawn on the arm while the coating solution was taken out from the pen-shaped coating destination.
After drying for 2 minutes at room temperature, a golden transfer foil (Murata Gold Leaf Co., Ltd., cold foil NSA-6) was pressed and peeled off slowly, but the foil was not transferred. Further, after drying for 10 minutes and 20 minutes, the foil was pressed and peeled off slowly, but the foil was not transferred. After 2 minutes, drying is insufficient, the viscosity of the liquid is low, and sufficient tackiness is not exhibited. After 10 to 20 minutes, the liquid is dried, and the resin film is in a surface state without tackiness. Therefore, the foil cannot be transferred. There seems to be a point where the stickiness is just right during this period, but since this time varies depending on the coating thickness, temperature and humidity, it was very difficult to transfer with stable quality.

[Comparative Example 2]
Using the coating solution and applicator obtained in Example 1 above, an arbitrary pattern was drawn on the arm while the coating solution was taken out from the pen-shaped coating destination.
After drying for 2 minutes at room temperature, a commonly used golden thermal transferable transfer foil (FINE FOIL ST-4-H manufactured by Katani Sangyo Co., Ltd.) was pressed and slowly peeled off, but the foil was not transferred. . Generally used thermal transferable transfer foils can be transferred by the strength of the PET film as the base material and the release layer being melted by heating, but only by the tackiness of the coating solution of the present invention. It is thought that it was not possible to make it.

  High brightness or high concealment decoration or makeup can be applied to the nail or the skin with any drawn line in any color.

A Applicator 1 Cap ornament 2 Cap body 3 Lead shaft 4 Rear shaft 5 Valve stem 6 Coating core 7 Base 8 Center core 9 Stirring ball

Claims (9)

  After applying the application liquid to the nail and skin as an arbitrary shape / character using an applicator filled with an application liquid that remains at least tacky after drying, which contains at least water and an O / W emulsion resin. High brightness or high concealment to nails and skin, characterized by transferring the high intensity or high concealment line by pressing the transfer foil onto the applied drawn line that has been dried and exhibiting tackiness, and peeling off the foil How to apply decoration or makeup.   After applying the application liquid to the nail and skin as an arbitrary shape / character using an applicator filled with an application liquid that remains at least tacky after drying, which contains at least water and an O / W emulsion resin. A nail characterized by obtaining a high-brightness or high-concealed drawing line by drying, pressing and contacting the colorant powder on the coated drawing line expressing tackiness, and removing the powder outside the coated drawing line with a cleaning tool; A method of applying decoration or makeup with high brightness or high concealment to the skin.   Inclined ball tack test (inclination angle 30 °, 25 ° C.) after forming a coating with a coating thickness of 50 μm using the coating solution and drying for 30 minutes in an environment of 25 ° C. and 65% humidity 3. A method for applying decoration or makeup with high brightness or high concealment to nails and skin according to claim 1 or 2, characterized in that the ball number in said film is sticky.   The O / W type emulsion resin of the coating solution is at least one selected from an (acrylates / ethyl hexyl acrylate) copolymer and an [acrylates / alkyl methacrylate (C12-22)] copolymer. A method of applying decoration or makeup with high brightness or high concealment to the nail and skin according to any one of.   The drawn line at the time of application is transparent to translucent milky white, and the drawn line can be confirmed by becoming white at the time of drying, and the standard of the drawn line is determined by color tone (whiteness) change. A method of applying decoration or makeup with high brightness or high concealment to the nail and the skin according to any one of 1 to 4.   The nail according to any one of claims 1 to 4, wherein an emulsion resin composed of a (styrene / alkyl acrylate) copolymer is blended in order to inform the guideline of drawn strokes by a change in color tone (whiteness). And a method of applying decoration or makeup with high luminance or high concealment to the skin.   2. The method for applying decoration or makeup with high brightness or high concealment to nails and skin according to claim 1, wherein the transfer foil is a cold foil having no hot-melt melt layer due to heat. Adhesiveness having a ball number of 1 or more in an inclined ball tack test (inclination angle 30 °, 25 ° C.) after forming a coating with a coating thickness of 50 μm and drying for 30 minutes in an environment of 25 ° C. and 65% humidity A decorative set for applying high brightness or high concealment decoration or makeup to nails and skin, comprising: a coating liquid containing at least water and an O / W emulsion resin, and a transfer foil or coloring material powder Or makeup set.   The O / W type emulsion resin contains at least one selected from (acrylates / ethyl hexyl acrylate) copolymer and [acrylates / alkyl methacrylate (C12-22)] copolymer in the coating solution. A decorative set or a cosmetic set for applying decoration or makeup with high brightness or high concealment to the nails and skin described in 1.

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