JP6081438B2 - Thermochromic writing instrument - Google Patents

Description

The present invention relates to a thermochromic writing instrument.

In Patent Document 1, a writing body is accommodated in a shaft cylinder so as to be movable in the front-rear direction, an operation portion is provided on an outer surface of the shaft tube, and the pen tip of the writing body is attached to the shaft tube by operating the operation portion. It is configured to be able to appear and retract from a front end hole, accommodates thermochromic ink inside the cursive body, provides a pen tip capable of ejecting the thermochromic ink at the front end of the cursive body, on the outer surface of the shaft cylinder, There has been disclosed a thermochromic writing instrument provided with a friction portion capable of thermally changing the handwriting with frictional heat generated by rubbing the handwriting of the thermochromic ink.

In Patent Document 1, in the type in which the operation portion protrudes rearward from the rear end portion of the shaft tube and the operation portion (corresponding to the knock body of the present application) is pressed forward, when the friction portion is provided in the operation portion, When the friction operation is performed using the friction portion, the operation portion may move forward due to the writing surface, and a stable friction operation may not be performed. In particular, when both a pen tip protruding operation and a pen tip immersing operation employ a retracting mechanism (so-called double knock type) that pushes the operating portion forward and a friction portion is provided in the operating portion, the pen tip protrudes. In this state, the operating body may rattle in the front-rear direction, and a stable friction operation may not be performed.

International Publication No. 2008/105227 Pamphlet

The present invention is intended to solve the above-described conventional problems, and to provide a thermochromic writing instrument that enables stable friction operation using a friction portion of an operation portion. In the present invention, “front” refers to the pen tip side, and “rear” refers to the opposite side. In the present invention, the “pen nib immersive state” refers to a state in which the pen nib is immersed in the shaft cylinder, and the “pen nib protruding state” refers to a state in which the pen nib projects outward from the front end of the shaft cylinder. Say.

[1] In the first invention of the present application, the cursive body 3 containing the thermochromic ink therein and having the nib 31 capable of ejecting the thermochromic ink at one end is urged rearward. A thermochromic writing instrument that is accommodated in the shaft cylinder 2 so as to be movable in the front-rear direction, and that the pen tip 31 of the writing body 3 can be projected and retracted from the front end hole 21 of the shaft cylinder 2. The front end hole 21 is opened along with the forward movement of the pen 3, and the pen tip 31 protrudes from the front end hole 21. On the other hand, the front end hole 21 is closed and submerged with the rearward movement of the writing body 3. The pen tip 31 is provided with a pen tip dry prevention mechanism 8 that is sealed in the shaft tube 2, and the operation unit 7 protrudes rearward from the rear end of the shaft tube 2 to press the operation unit 7 forward. Thus, the pen tip 31 is projected from the front end hole 21 to the outside. A friction mechanism 71 provided on the outer surface of the rear end portion of the operation section 7 for rubbing the handwriting with the thermochromic ink and capable of thermally discoloring the handwriting by frictional heat generated at that time. It is a requirement that a gripping portion 72 that can be gripped when the frictional portion 71 is used for friction is provided on the outer surface.

The thermochromic writing instrument 1 according to the first invention of the present application is a friction that can rub the handwriting by the thermochromic ink on the outer surface of the rear end portion of the operation portion 7 and thermally change the handwriting by frictional heat generated at that time. By providing a grip portion 72 that can be gripped when rubbing using the friction portion 71 on the outer surface of the operation portion 7 at least in the pen tip immersing state, at least in the pen tip immersing state. The gripping portion 72 can be gripped and the friction portion 71 can be used, and a stable friction operation can be performed using the friction portion 71 of the knock body 6.

[2] According to a second invention of the present application, in the thermochromic writing instrument 1 of the first invention, the protruding length L in the axial direction of the operation portion 7 from the rear end of the shaft cylinder 2 in the pen tip immersion state. However, it is a requirement that it is 15-30 mm.

The thermochromic writing instrument 1 according to the second aspect of the present invention is configured such that the protruding length L in the axial direction of the operation unit 7 from the rear end of the shaft tube 2 in the pen tip immersion state is 15 mm to 30 mm. 7 can be stably held, and the operation unit 7 can be easily pushed forward. If the protruding length L in the axial direction of the operation portion 7 from the rear end of the shaft tube 2 is less than 15 mm, the grip portion 72 of the operation portion 7 may not be stably gripped during friction. If the protruding length L in the axial direction of the operation portion 7 from the rear end of the shaft cylinder 2 is larger than 30 mm, it is difficult to push the operation portion 7 forward.

[3] According to a third invention of the present application, in the thermochromic writing instrument 1 of the first or second invention, an anti-slip portion (for example, an elastic material, unevenness) is formed on the grip portion 72 on the outer surface of the operation portion 7. Part)).

The thermochromic writing instrument 1 according to the third aspect of the present invention is provided with a non-slip portion (for example, an elastic material, a concavo-convex portion) on the grip portion 72 on the outer surface of the operation portion 7, so that it can be made more stable. The grip portion 72 can be gripped.

[4] The fourth invention of the present application is that, in the thermochromic writing instrument 1 of any one of the first to third inventions, the entire operation section 7 is made of an elastic material.

In the thermochromic writing instrument 1 according to the fourth aspect of the present invention, the operating body can be composed of one part, the increase in the number of parts can be suppressed, and the gripping part 72 provided with a non-slip part on the outer surface of the operating part 7 is provided. It can be formed easily.

[5] The thermochromic writing instrument 1 of the fifth invention of the present application is the thermochromic writing instrument 1 of any one of the first to fourth inventions, wherein the pen tip 31 of the writing body 3 is a fiber pen, It is required to be selected from a porous pen body, a pen body made of a synthetic resin extrusion-molded body provided with an ink guide path in the axial direction, and a brush pen body.

The thermochromic writing instrument 1 according to the fifth aspect of the present invention is a pen body in which the pen tip 31 of the writing body 3 is a fiber pen body, a porous pen body, and a synthetic resin extruded body provided with an ink guide path in the axial direction. Alternatively, a retractable thermochromic writing instrument 1 having a brush pen body can be easily obtained.

[6] The thermochromic writing instrument 1 of the sixth invention of the present application is the thermochromic writing instrument 1 of the fifth invention, wherein the shaft tube 2 is made of a fiber processed body impregnated with the thermochromic ink. The ink storage body 35 is accommodated, the rear end portion of the pen tip 31 is connected to the ink storage body 35, and the ink is supplied to the front end portion of the pen tip 31.

In the sixth thermochromic writing instrument 1, the nib 31 and the ink occlusion body 35 have a capillary force, and the heat in the ink occlusion body 35 is generated by the capillary force of the nib 31 and the capillary force of the ink occlusion body 35. The discolorable ink can be properly supplied to the tip of the nib 31.

-Friction part It is preferable that the friction part 71 used by this invention is comprised from an elastic material (soft material). The elastic material constituting the friction part 71 is preferably a synthetic resin (rubber or elastomer) having elasticity. For example, silicone resin, SBS resin (styrene-butadiene-styrene copolymer), SEBS resin (styrene-ethylene-butadiene). -Styrene copolymer), fluorine resin, chloroprene resin, nitrile resin, polyester resin, ethylene propylene diene rubber (EPDM) and the like. The synthetic resin having elasticity constituting the friction portion 71 is a low wear elastic material that hardly generates wear debris (rubbing debris) at the time of friction, rather than a high wear elastic material (for example, an eraser). Preferably it consists of.

-Thermochromic ink In the present invention, the thermochromic ink is preferably a reversible thermochromic ink. The reversible thermochromic ink is a heat decoloring type that decolors by heating from a colored state, a color memory retaining type that reversibly stores and retains a colored state or a decolored state in a specific temperature range, or from a decolored state Various types such as a heating coloring type that develops color by heating and returns to a decolored state by cooling from the colored state can be used alone or in combination.

The coloring material contained in the reversible thermochromic ink includes conventionally known (a) electron donating color-forming organic compounds, (b) electron-accepting compounds, and (c) color reactions of both. A reversible thermochromic pigment in which a reversible thermochromic composition containing at least the essential three components of a reaction medium for determining the occurrence temperature of the polymer is encapsulated in a microcapsule is preferably used.

In the present invention, as shown in FIG. 3, the shape of the curve plotting the change in color density due to the temperature change is opposite to the case where the temperature is raised from the lower temperature side than the color change temperature range, and from the higher temperature side than the color change temperature range. The color changes by following a different path depending on the descending state, and the color development state in the low temperature range below the complete color development temperature (t ₁ ) or the color erase state in the high temperature range above the complete color erase temperature (t ₄ ) It is preferable to apply a color memory retention type thermochromic ink that can be stored and retained in a specific temperature range [temperature range between t _{2 and} t ₃ (substantially two-phase retention temperature range)]. In FIG. 3, ΔH indicates a temperature width (ie, hysteresis width) indicating the degree of hysteresis. When the value of ΔH is small, only one of the two states before and after the color change can exist. When the value of ΔH is large, it is easy to maintain each state before and after the color change.

In the present invention, the color change temperature of the thermochromic ink due to the frictional heat of the friction part 71 is set to 25 ° C. to 95 ° C. (preferably 36 ° C. to 95 ° C.). That is, in the present invention, the high temperature side discoloration point [complete decoloring temperature (t ₄ )] is set in a range of 25 ° C. to 95 ° C. (preferably 36 ° C. to 90 ° C.), and the low temperature side discoloration point [ It is effective to set the complete color development temperature (t ₁ )] in the range of −30 ° C. to + 20 ° C. (preferably −30 ° C. to + 10 ° C.). Accordingly, it is possible to effectively maintain the color exhibited in the normal state (daily life temperature range), and it is possible to easily change the handwriting by the reversible thermochromic ink by the frictional heat generated by the friction portion 71.

The thermochromic writing instrument of the present invention enables a stable friction operation using the friction part of the operation part.

It is a longitudinal cross-sectional view which shows the pen tip immersion state of embodiment of this invention. It is a longitudinal cross-sectional view which shows the pen tip protrusion state of FIG. It is explanatory drawing which shows the color change behavior of a thermochromic ink.

An embodiment of the present invention is shown in FIGS.
The thermochromic writing instrument 1 of the present embodiment includes a shaft tube 2, a writing body 3 accommodated in the shaft tube 2, and a pen tip 31 of the writing body 3 that can be projected and retracted from a front end hole 21 of the shaft tube 2. And a haunting mechanism.

Writing body The writing body 3 includes a cylindrical main body 32, a pen tip 31 attached to a front end opening of the main body 32, and an ink occlusion body 35 accommodated in the main body 32. A tail plug 34 is attached to the rear end opening of the main body 32. A pen point is attached to the front end opening of the main body 32 via a holder 33.

Pen Tip The pen tip 31 is made of a fiber pen body, a porous pen body, a pen body made of a synthetic resin extruded body having an axial ink guide path, or a brush pen body. The ink occlusion body 35 is made of a fiber processed body and is impregnated with thermochromic ink. The rear end portion of the pen tip 31 is pierced and connected to the front end portion of the ink storage body 35. Thereby, the thermochromic ink in the ink occlusion body 35 can be supplied to the front end of the nib 31.

-Intrusion mechanism The intrusion mechanism is a knock-type intrusion mechanism using a rotating cam mechanism, and engages with a cam portion 4 formed on the inner surface of the shaft cylinder 2 and contacts the rear end of the writing body 3; , A knock body 6 that engages with the rotating member 5 and protrudes from the rear end of the shaft cylinder 2, an operation section 7 attached to the rear portion of the knock body 6, and is accommodated in the shaft cylinder 2 and the writing body 3 is moved backward. It consists of a projectile 9 (for example, a compression coil spring) that urges it. The retracting mechanism of the present embodiment is a double knock type in which both the pen tip protruding operation and the pen tip retracting operation push the operation unit 7 forward.

-Operation part The said operation part 7 is integrally formed with an elastic material (for example, silicone resin, SBS resin, SEBS resin, etc.). A rear end portion of the operation unit 7 serves as a friction unit 71, and an outer surface of the operation unit 7 serves as a grip unit 72. The grip portion 72 includes an anti-slip portion made of an elastic material or an uneven portion. The protruding length L in the axial direction of the operation unit 7 from the rear end of the shaft cylinder 2 is set to 15 mm to 30 mm when the pen tip is immersed.

Friction part The friction part 71 may be provided at least on the outer surface of the rear end of the operation part 7. For example, the friction part 71 made of an elastic material is press-fitted, engaged, screwed, and the like at the rear end part of the knock body 6. The structure which adheres by fitting, adhesion | attachment, 2 color molding, etc. may be sufficient.

-Nib drying prevention mechanism In the shaft cylinder 2, the front end hole 21 is opened with the forward movement of the writing body 3, and the front end hole 21 is closed with the rearward movement of the writing body 3. A nib drying prevention mechanism 8 for sealing the nib 31 in the nib immersing state in the shaft cylinder 2 is provided. Specifically, the nib drying prevention mechanism 8 includes an accommodating cylinder 81 that accommodates the writing body 3, a lid 82 that is provided at the front end of the accommodating cylinder 81, and that opens and closes in conjunction with the protruding and retracting of the nib 31. An annular seal portion 83 made of an elastic material that slides closely with the outer peripheral surface of the writing body 3 is provided.

The thermochromic writing instrument 1 according to the embodiment of the present application includes a friction portion capable of rubbing the handwriting by the thermochromic ink on the outer surface of the rear end portion of the operation portion 7 and heat-discoloring the handwriting with frictional heat generated at that time. 71 is provided, and at least in the pen tip immersion state, a grip portion 72 that can be gripped when rubbing using the friction portion 71 is provided on the outer surface of the operation unit 7. The friction portion 71 can be used by gripping the portion 72, and a stable friction operation can be performed using the friction portion 71 of the knock body 6.

In the thermochromic writing instrument 1 according to the embodiment of the present application, the protruding length L in the axial direction of the operation unit 7 from the rear end of the shaft tube 2 in the pen tip immersion state is 15 mm to 30 mm. 7 can be stably held, and the operation unit 7 can be easily pushed forward.

The thermochromic writing instrument 1 according to the embodiment of the present application is provided with a non-slip portion (for example, an elastic material, an uneven portion) on the grip portion 72 on the outer side surface of the operation portion 7, so that it is more stable. The grip portion 72 can be gripped.

In the thermochromic writing instrument 1 according to the embodiment of the present application, the operation body can be configured by one component, and an increase in the number of components can be suppressed, and a gripping portion 72 provided with a non-slip portion on the outer surface of the operation portion 7 is provided. It can be formed easily.

A thermochromic writing instrument 1 according to an embodiment of the present application is a pen body in which a pen tip 31 of a writing body 3 is a fiber pen body, a porous pen body, and a synthetic resin extruded body provided with an ink guide path in the axial direction. Alternatively, a retractable thermochromic writing instrument 1 having a brush pen body can be easily obtained.

In the thermochromic writing instrument 1 according to the embodiment of the present application, the nib 31 and the ink occlusion body 35 have a capillary force, and the capillary force of the nib 31 and the capillary force of the ink occlusion body 35 cause the inside of the ink occlusion body 35. Can be properly supplied to the tip of the nib 31.

DESCRIPTION OF SYMBOLS 1 Thermochromic writing instrument 2 Shaft cylinder 21 Front end hole 3 Writing body 31 Pen tip 32 Main body 33 Holder 34 Tail plug 35 Ink occlusion body 4 Cam part 5 Rotating member 6 Knock body 7 Operation part 71 Friction part 72 Grasping part 8 Pen point drying Prevention mechanism 81 Housing cylinder 82 Lid 83 Annular seal 9 Projectile L Projection length in the axial direction of the operating part

Claims (4)

Shaft cylinder that accommodates reversible thermochromic ink inside and has a pen tip that can eject thermochromic ink at one end so that it can move in the front-rear direction while being urged rearward by a projectile A thermochromic writing instrument comprising a pen tip of the cursive body configured to be able to protrude and retract from a front end hole of the shaft cylinder,
The front end hole is opened along with the forward movement of the cursive body and the pen tip protrudes from the front end hole. On the other hand, the front end hole is closed and submerged as the cursive body moves backward. Has a nib drying prevention mechanism that is sealed in the shaft cylinder, and the nib drying prevention mechanism is in close contact with the outer peripheral surface of the writing body, and a lid that opens and closes in conjunction with the pen tip protrusion and depression. An annular seal portion made of an elastic material, and projecting the knock body rearward from the rear end of the shaft cylinder, attaching an operation portion to the rear portion of the knock body, and pressing the operation portion forward, A retracting mechanism for projecting the pen tip from the front end hole to the outside;
The entire operation portion is made of a low-abrasion elastic material,
The rear end outer surface of the operating portion, provided friction portion configured to該筆traces in frictional heat generated when the rubbing handwriting by the thermochromic ink from thermochromic possible the low wear of the elastic material, wherein the outer surface of the operating portion, thermochromic writing instrument, characterized in that a gripping portion comprised of the low wear of the elastic material that can be gripped when the friction with the friction portion. 2. The thermochromic writing instrument according to claim 1, wherein a projection length in the axial direction of the operation portion from the rear end of the shaft cylinder in the pen tip immersion state is 15 mm to 30 mm. 2. The pen point of the writing body is selected from any of a fiber pen body, a porous pen body, a pen body made of a synthetic resin extruded body having an axial ink guide path, or a brush pen body. Or the thermochromic writing instrument according to 2. An ink occlusion body made of a fiber processed body impregnated with the thermochromic ink is accommodated in the shaft cylinder, the rear end portion of the pen tip is connected to the ink occlusion body, and the front end portion of the pen tip is connected. The thermochromic writing instrument according to claim 3, wherein ink is supplied .

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