JP6080287B2 - Shochu, food processing method, processed food manufacturing method, and fermented seasoning - Google Patents
Shochu, food processing method, processed food manufacturing method, and fermented seasoning Download PDFInfo
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- Alcoholic Beverages (AREA)
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Description
本発明は、焼酎、食材の処理方法、加工食品の製造方法、並びに、発酵調味料に関する。さらに詳細には、本発明は、所定濃度以上の2−フルアルデヒド、5−メチル−2−フルアルデヒド、及び5−ヒドロキシメチル−2−フルアルデヒドを含有する焼酎、該焼酎を食材に接触させる食材の処理方法、該焼酎で食材を処理する加工食品の製造方法、並びに、発酵調味料に関する。本発明の焼酎は、食材を加熱調理した際に発生する不快臭の消臭と食感改善に有用なものである。 The present invention, shochu, food processing methods, the method of manufacturing processed foods, as well as, on the fermented seasoning. More specifically, the present invention relates to a shochu containing 2-furaldehyde, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde at a predetermined concentration or more, and a food material for contacting the shochu with the food material. The processing method of this , the manufacturing method of the processed food which processes a foodstuff with this shochu , and a fermented seasoning. The shochu of the present invention is useful for deodorizing unpleasant odors generated when cooking foods and improving the texture.
畜肉や魚介類を加熱調理した際に不快臭が発生する場合がある。不快臭の原因は硫黄を含む物質、すなわち含硫化合物であると言われているが、不快臭の消臭は非常に困難であり、加工食品分野において不快臭を消臭する技術開発が求められている。野菜や玉子なども同様に加熱調理した際に不快臭が発生することがある。 An unpleasant odor may be generated when cooking meat and seafood. The cause of unpleasant odors is said to be sulfur-containing substances, that is, sulfur-containing compounds, but it is very difficult to deodorize unpleasant odors, and there is a need for technological development to eliminate unpleasant odors in the processed food field. ing. An unpleasant odor may be generated when cooking vegetables and eggs in the same manner.
またレトルト食品においても、いわゆるレトルト臭という不快臭の発生が起こる場合がある。レトルト食品とは、レトルト(高圧釜)により、100℃以上の湿熱加熱を受けて、商業的無菌性を付与された密封容器詰食品のうちで、プラスチックフィルム及びアルミ箔を積層したフィルムを、熱シールによって密封した容器を用いて製造したものと定義されている(非特許文献1)。また、缶詰や瓶詰も同様に、高温殺菌時に不快臭を発生する場合がある。 In addition, unpleasant odors called so-called retort odors may occur in retort foods. A retort food is a sealed container-packaged food that has been subjected to heat and humidity at 100 ° C. or higher by a retort (high-pressure kettle), and is a film in which plastic film and aluminum foil are laminated. It is defined as a product manufactured using a container sealed with a seal (Non-Patent Document 1). Similarly, canned foods and bottles may generate unpleasant odors during high temperature sterilization.
一方、飲用の酒類においては、原料の一部に生姜などを用いる機能性酒が開発されており(特許文献1)、また、生姜などの薬味料を用いる料理用酒類も開発されている(特許文献2)。特許文献2に開示されている料理用酒類は、生姜等の薬味料に対して特定の処理を施すことにより得られるものであり、特定の揮発性香気成分を多く含有し香味が豊富であるとともに、畜肉や魚介類の不快臭のマスキング、食感改善、焦げつき防止といった効果を有する優れたものである。 On the other hand, in drinking alcoholic beverages, functional liquors using ginger and the like as part of the raw materials have been developed (Patent Document 1), and cooking liquors using condiments such as ginger have also been developed (patents) Reference 2). The liquor for cooking disclosed in Patent Document 2 is obtained by subjecting a condiment such as ginger to a specific treatment, and contains a lot of specific volatile aroma components and is rich in flavor. It has excellent effects such as masking of unpleasant odors of livestock meat and seafood, improving texture, and preventing burning.
しかしながら、前述したように、食材を加熱調理した際に発生する不快臭、特に含硫化合物に起因する不快臭やレトルト臭をさらに効果的に消臭する技術が求められている。そして、不快臭の高い消臭効果を有するとともに、調理効果等にも優れた料理用酒類が求められている。そこで本発明は、前記した従来技術が抱える問題点を踏まえ、食材を加熱調理した際に発生する不快臭の消臭効果が高い焼酎を提供するとともに、当該焼酎の用途、並びに、当該焼酎を利用した加工食品の製造方法を提供することを目的とする。 However, as described above, there is a need for a technique for more effectively deodorizing unpleasant odors generated when cooking foods, particularly unpleasant odors caused by sulfur-containing compounds and retort odors. Further, there is a demand for cooking liquors that have a deodorizing effect with a high unpleasant odor and are excellent in cooking effect and the like. Accordingly, the present invention provides a shochu that has a high deodorizing effect for unpleasant odors generated when cooking foods, taking into account the problems of the above-described conventional technology, and uses the shochu and the shochu It aims at providing the manufacturing method of processed food.
本発明者らは、上記した課題を解決するために検討を重ねた結果、タマネギを原料の一部として使用することで、不快臭の高い消臭効果を有する焼酎を製造できることを見出した。さらに、当該焼酎の有効成分について詳細に検討し、3種の有効成分を特定することに成功した。さらに、当該焼酎を用いることで、不快臭の消臭とともに食材の食感を改善できることを見出し、本発明を完成した。すなわち、上記した課題を解決するために提供される本発明は、以下のとおりである。 As a result of repeated studies to solve the above-mentioned problems, the present inventors have found that by using onion as a part of the raw material, a shochu liquor having a high deodorizing effect with an unpleasant odor can be produced. Furthermore, the active ingredients of the shochu were examined in detail, and three kinds of active ingredients were successfully identified. Furthermore, the present inventors have found that by using the shochu, the texture of the food can be improved together with the deodorization of unpleasant odor, and the present invention has been completed. That is, the present invention provided to solve the above-described problems is as follows.
請求項1に記載の発明は、アルコール濃度25v/v%換算で、1.0mg/L以上の2−フルアルデヒド、0.3mg/L以上の5−メチル−2−フルアルデヒド、及び0.1mg/L以上の5−ヒドロキシメチル−2−フルアルデヒドを含有し、原料の少なくとも一部にタマネギを用いたものであることを特徴とする焼酎である。 The invention according to claim 1 is 1.0 mg / L or more of 2-furaldehyde, 0.3 mg / L or more of 5-methyl-2-furaldehyde, and 0.1 mg in terms of alcohol concentration of 25 v / v%. / L or more of 5-hydroxymethyl-2-furaldehyde, and is a shochu characterized by using onion as at least a part of the raw material.
本発明の焼酎は、3種のフルアルデヒド類、すなわち、2−フルアルデヒド、5−メチル−2−フルアルデヒド、及び5−ヒドロキシメチル−2−フルアルデヒドを所定濃度以上含むものである。本発明の焼酎は、食材を加熱調理した際に発生する不快臭の消臭効果が高い。さらに、本発明の焼酎で食材を処理することにより、食材の食感を改善することができる。本発明の焼酎は、例えば、調理前における畜肉、魚介類、野菜又は玉子類の処理に有用である。すなわち、畜肉や魚介類、野菜又は玉子類に対して本発明の焼酎に接触させる処理を予め行うことにより、加熱した際に不快臭の消臭、食感改善といった効果が得られる。 The shochu of the present invention contains at least a predetermined concentration of three types of furaldehydes, namely, 2-furaldehyde, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde. The shochu of the present invention has a high deodorizing effect for unpleasant odors generated when cooking foods. Furthermore, the food texture of a foodstuff can be improved by processing a foodstuff with the shochu of this invention. The shochu of the present invention is useful, for example, for the treatment of livestock meat, seafood, vegetables or eggs before cooking. That is, effects of deodorizing unpleasant odors and improving the texture when heated are obtained by preliminarily performing the treatment of bringing the meat, seafood, vegetables or eggs into contact with the shochu of the present invention.
また本発明の焼酎においては、原料の少なくとも一部にタマネギを用いている。かかる構成により、上記3種のフルアルデヒド類をタマネギから得ることができる。さらに、タマネギに由来する調味にふさわしい香味が付与され、不快臭の消臭効果と食感の改善効果に加えて、香味が豊富な焼酎が提供される。 In the shochu of the present invention, onion is used as at least a part of the raw material. With this configuration, the above three types of furaldehydes can be obtained from onions. Furthermore, the flavor suitable for the seasoning derived from an onion is provided, and the shochu rich in flavor is provided in addition to the deodorizing effect of an unpleasant odor, and the improvement effect of food texture.
また焼酎であるので、調味にふさわしい香味が特に豊富となる。 Moreover, since it is shochu, the flavor suitable for seasoning is particularly abundant.
ここで、「アルコール濃度」とは、エチルアルコール(エタノール)の濃度をいう。すなわち、本明細書において「アルコール」と記載した場合は、特に断らない限りエチルアルコール(エタノール)を指す。 Here, “alcohol concentration” refers to the concentration of ethyl alcohol (ethanol). That is, in the present specification, the term “alcohol” refers to ethyl alcohol (ethanol) unless otherwise specified.
焼酎(粕取焼酎を含む)の原料に特に限定はなく、また、発酵方法、蒸留方法にも特に限定は無い。焼酎には、連続式蒸留焼酎と単式蒸留焼酎の両方が含まれる。 There is no particular limitation on the raw material of the shochu (including the shochu shochu), and there is no particular limitation on the fermentation method and the distillation method. Shochu includes both continuous and single distillation shochu.
請求項2に記載の発明は、アルコール濃度25v/v%換算で、28mg/L以上の2−フルアルデヒド、0.3mg/L以上の5−メチル−2−フルアルデヒド、及び0.1mg/L以上の5−ヒドロキシメチル−2−フルアルデヒドを含有し、原料の少なくとも一部にタマネギを用いたものであることを特徴とする焼酎である。 Invention of Claim 2 is 28 mg / L or more of 2-furaldehyde, 0.3 mg / L or more of 5-methyl-2-furaldehyde, and 0.1 mg / L in terms of alcohol concentration of 25 v / v%. A shochu characterized by containing the above 5-hydroxymethyl-2-furaldehyde and using onion as at least a part of the raw material.
請求項3に記載の発明は、アルコール濃度25v/v%換算で、38mg/L以上の2−フルアルデヒド、0.5mg/L以上の5−メチル−2−フルアルデヒド、及び0.1mg/L以上の5−ヒドロキシメチル−2−フルアルデヒドを含有し、原料の少なくとも一部にタマネギを用いたものであることを特徴とする焼酎である。 Invention of Claim 3 is 38 mg / L or more of 2-furaldehyde, 0.5 mg / L or more of 5-methyl-2-furaldehyde, and 0.1 mg / L in terms of alcohol concentration of 25 v / v%. A shochu characterized by containing the above 5-hydroxymethyl-2-furaldehyde and using onion as at least a part of the raw material.
請求項4に記載の発明は、請求項1〜3のいずれかに記載の焼酎を食材に接触させ、加熱する工程を含むことを特徴とする食材の処理方法である。 Invention of Claim 4 is the processing method of the foodstuff characterized by including the process of making the shochu in any one of Claims 1-3 contact a foodstuff, and heating.
本発明は食材の処理方法に係るものであり、上記した本発明の焼酎を食材に接触させ、加熱する工程を含む。本発明では、上記した3種のフルアルデヒド類を多く含有する焼酎を用いるので、少量の使用で食材の不快臭を消臭することができる。特に、含硫アミノ酸高含有の調味料である場合には、加熱時に発生する硫黄臭(硫化水素臭)を消臭することができる。例えば、畜肉、魚介類、野菜又は玉子類である場合には、畜肉、魚介類、野菜又は玉子類に対する不快臭の消臭といった効果を得ることができる。さらに、畜肉、魚介類に対して、食感の改善効果を得ることができる。 The present invention relates to a food processing method, and includes a step of bringing the above-described shochu of the present invention into contact with the food and heating. In the present invention, since the shochu containing a large amount of the above-mentioned three kinds of furaldehydes is used, the unpleasant odor of the food can be eliminated with a small amount of use. In particular, in the case of a seasoning containing a high content of sulfur-containing amino acids, the sulfur odor (hydrogen sulfide odor) generated during heating can be deodorized. For example, in the case of livestock meat, seafood, vegetables or eggs, effects such as deodorization of unpleasant odors with respect to livestock meat, seafood, vegetables or eggs can be obtained. Furthermore, the texture improvement effect can be obtained for livestock meat and seafood.
関連の発明は、請求項1〜3のいずれかに記載の焼酎を、含硫アミノ酸を含有する調味料に添加し、前記調味料の加熱時に発生する不快臭を消臭することを特徴とする不快臭の消臭方法である。 A related invention is characterized in that the shochu according to any one of claims 1 to 3 is added to a seasoning containing a sulfur-containing amino acid to deodorize an unpleasant odor generated when the seasoning is heated. It is a deodorizing method for unpleasant odors.
本発明は不快臭の消臭方法に係るものであり、上記した本発明の焼酎を「含硫アミノ酸を含有する調味料」に添加し、当該調味料の加熱時に発生する不快臭を消臭する。本発明の不快臭の消臭方法によれば、含硫アミノ酸を多く含有する調味料(含硫アミノ酸高含有の調味料)を用いた際に発生する硫黄臭を含む不快臭を、効率的かつ簡単に消臭することができる。
含硫アミノ酸の例としては、メチオニン、システイン、シスチン、シスタチオニン、タウリン、などが挙げられる。
The present invention relates to a method for deodorizing an unpleasant odor, and the above-described shochu of the present invention is added to a “seasoning containing a sulfur-containing amino acid” to deodorize the unpleasant odor generated when the seasoning is heated. . According to the method for deodorizing an unpleasant odor of the present invention, an unpleasant odor including a sulfur odor that is generated when a seasoning containing a large amount of sulfur-containing amino acids (a seasoning containing a high content of sulfur-containing amino acids) is used efficiently and It can be easily deodorized.
Examples of sulfur-containing amino acids include methionine, cysteine, cystine, cystathionine, taurine, and the like.
関連の発明は、請求項4に記載の食材の処理方法によって食材を処理し、前記食材の不快臭を消臭することを特徴とする不快臭の消臭方法である。 A related invention is a method for deodorizing an unpleasant odor characterized in that the food is treated by the method for treating a food according to claim 4 to deodorize the unpleasant odor of the food.
関連の発明は、前記食材が、畜肉、魚介類、野菜又は玉子類であることを特徴とする上記の不快臭の消臭方法である。 A related invention is the above- described method for deodorizing an unpleasant odor, wherein the food material is livestock meat, seafood, vegetables or eggs.
本発明の不快臭の消臭方法は、上記した本発明の焼酎によって畜肉、魚介類、野菜、玉子類等の食材を処理し、これらの食材から発生する不快臭を消臭するものである。本発明の不快臭の消臭方法によっても、硫黄臭等を含む不快臭を効率的かつ簡単に消臭することができる。 The method for deodorizing an unpleasant odor according to the present invention treats food materials such as livestock meat, seafood, vegetables and eggs with the shochu according to the present invention, and deodorizes the unpleasant odor generated from these food materials. The unpleasant odor deodorizing method of the present invention can also efficiently and easily deodorize unpleasant odors including sulfur odors.
関連の発明は、請求項4に記載の食材の処理方法によって畜肉又は魚介類を処理し、畜肉又は魚介類の食感を改善することを特徴とする食感の改善方法である。 A related invention is a texture improving method characterized in that livestock meat or fishery products is processed by the food processing method according to claim 4 to improve the texture of livestock meat or fishery products.
本発明は食感の改善方法に係るものであり、上記した本発明の食材の処理方法によって畜肉又は魚介類を処理し、これらの食感を改善するものである。本発明の食感の改善方法によれば、調理後における畜肉又は魚介類の食感を簡単に改善することができる。 The present invention relates to a method for improving texture, and by treating the meat or seafood with the above-described method for treating food, the texture is improved. According to the texture improving method of the present invention, the texture of livestock meat or seafood after cooking can be easily improved.
請求項5に記載の発明は、請求項1〜3のいずれかに記載の焼酎を食材に接触させることによって加工食品を得ることを特徴とする加工食品の製造方法である。 Invention of Claim 5 is a manufacturing method of processed food characterized by obtaining processed food by making the shochu according to any one of Claims 1-3 contact foodstuff.
本発明は加工食品の製造方法に係るものであり、上記した本発明の焼酎を食材に接触させ、加熱することによって加工食品を得るものである。本発明によれば、不快臭が極めて少なく、かつ食感のよい高品質の加工食品が提供される。 The present invention relates to a method for producing a processed food, and the processed food is obtained by bringing the shochu of the present invention into contact with a food material and heating it. According to the present invention, a high-quality processed food with very little unpleasant odor and good texture is provided.
前記食材が、畜肉、魚介類、野菜又は玉子類である構成が推奨される(請求項6)。 The food is meat, seafood, constituting a vegetable or egg compound is recommended (claim 6).
請求項7に記載の発明は、請求項1〜3のいずれかに記載の焼酎を含有する発酵調味料である。 The invention according to claim 7 is a fermented seasoning containing the shochu according to any one of claims 1 to 3.
本発明の焼酎によれば、食材を加熱調理した際に発生する不快臭を効率的に消臭することができる。さらに、本発明の焼酎で食材を処理することにより、畜肉等の食材の食感を改善することができる。さらに、原材料の少なくとも一部にタマネギを用いるので、不快臭の消臭効果と食感の改善効果に加えて、調味にふさわしい香味が豊富な焼酎が提供される。 According to the shochu of the present invention, it is possible to efficiently deodorize the unpleasant odor generated when the food is cooked. Furthermore, the texture of foodstuffs, such as livestock meat, can be improved by processing a foodstuff with the shochu of this invention. Further, since the onion is used as at least a part of the raw material, a shochu rich in flavor suitable for seasoning is provided in addition to the deodorizing effect of unpleasant odor and the texture improving effect.
本発明の食材の処理方法によれば、食材を加熱調理した際に発生する不快臭を消臭することができ、さらに食材の食感を改善することができる。 According to the processing method of the foodstuff of this invention, the unpleasant odor which generate | occur | produces when heat-cooking a foodstuff can be deodorized, and also the food texture of a foodstuff can be improved.
本発明の不快臭の消臭方法によれば、含硫アミノ酸高含有の調味料や、畜肉、魚介類、野菜、玉子類といった食材を加熱した際に発生する不快臭を効率的に消臭することができる。 According to the method for deodorizing an unpleasant odor of the present invention, an unpleasant odor that is generated when a seasoning containing a high content of sulfur-containing amino acids or foods such as meat, seafood, vegetables, and eggs is heated is efficiently deodorized. be able to.
本発明の食感の改善方法によれば、調理後における畜肉又は魚介類の食感を簡単に改善することができる。 According to the texture improving method of the present invention, the texture of livestock meat or seafood after cooking can be easily improved.
本発明の加工食品の製造方法によれば、不快臭が極めて少なく、かつ食感のよい高品質の加工食品が提供される。 According to the method for producing a processed food of the present invention, a high-quality processed food with very little unpleasant odor and good texture is provided.
以下、本発明を実施するための形態について具体的に説明する。
本発明の焼酎は、所定濃度以上の2−フルアルデヒド、5−メチル−2−フルアルデヒド、及び5−ヒドロキシメチル−2−フルアルデヒドを含有するものである。蒸留することにより、前記した3種のフルアルデヒド類が効率的に得られるとともに調理に好適な揮発性成分が濃縮される。その結果、少量の添加で不快臭の消臭効果が得られるとともに、加工食品に前記揮発性成分を付与できる。さらに、品質劣化を惹起する成分は蒸留残渣、末垂れ区分や後留区分に残存することになるため、蒸留して得られた蒸留液の品質安定性は極めて高いものとなる。
Hereinafter, the form for implementing this invention is demonstrated concretely.
The shochu of the present invention contains 2-furaldehyde, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde at a predetermined concentration or higher. By distillation, the above-mentioned three kinds of furaldehydes can be obtained efficiently and volatile components suitable for cooking are concentrated. As a result, an unpleasant odor eliminating effect can be obtained with a small amount of addition, and the volatile component can be imparted to the processed food. Furthermore, since components that cause quality degradation remain in the distillation residue, the tail-end section or the post-end section, the quality stability of the distilled liquid obtained by distillation is extremely high.
蒸留方法について特に限定はなく、例えば、甲類焼酎(連続式蒸留焼酎)を得るための連続蒸留法、乙類焼酎を得るための単式蒸留法のいずれもが採用可能である。また、醪を通常の大気圧下で蒸留する常圧蒸留法、真空ポンプで醪を大気圧より低くして蒸留する減圧蒸留法のいずれもが採用可能である。 There is no particular limitation on the distillation method, and for example, any of a continuous distillation method for obtaining a shell shochu (continuous distillation shochu) and a single distillation method for obtaining an oyster shochu can be employed. In addition, any of an atmospheric distillation method in which the soot is distilled at a normal atmospheric pressure and a vacuum distillation method in which the soot is distilled at a pressure lower than the atmospheric pressure using a vacuum pump can be employed.
本発明の焼酎では、原料の少なくとも一部にタマネギを用いる。タマネギは、食品の調味のために用いる芳香性と刺激性を持った植物であり、生食ではサラダや和え物などに用いられているほか、肉類を中心とした煮物や炒め物、焼き物の材料など多くの調理に用いられている。タマネギは、ユリ科ネギ属の1〜2年性草本で、球を形成する球茎作物として代表的なものである。 In the shochu of the present invention, an onion is used as at least a part of the raw material. Onions are aromatic and irritating plants used for seasoning foods. In addition to being used for salads and salads in raw foods, there are many ingredients such as boiled foods, stir-fried foods, and grilled foods. It is used for cooking. Onion is a 1-2 year herb belonging to the genus Liliaceae, and is a typical corm crop that forms a sphere.
原料として用いるタマネギの形態としては、生鮮品、冷蔵品、冷凍品又は乾燥品があるが、いずれでもよい。またタマネギは加熱処理したものが好ましく、刺激臭や辛みが消失し、特有の甘いフレーバーである2−フルアルデヒドや5−メチル−2−フルアルデヒドなどの2−フルアルデヒド誘導体を含有するタマネギを用いるのがよい。タマネギを加熱処理することによりにより、2−フルアルデヒドや5−メチル−2−フルアルデヒドなどが多く生成するので、これらの物質による不快臭の消臭効果は高いものとなる。また、加熱に先立って細断、粉砕、磨砕などの処理を必要に応じて行えばよい。 The form of onion used as a raw material includes a fresh product, a refrigerated product, a frozen product, or a dried product, and any may be used. The onion is preferably heat-treated, and the onion containing 2-furaldehyde derivatives such as 2-furaldehyde and 5-methyl-2-furaldehyde, which are characteristic sweet flavors, disappears. It is good. By heating the onion, a large amount of 2-furaldehyde, 5-methyl-2-furaldehyde and the like are produced, so that the deodorizing effect of the unpleasant odor due to these substances becomes high. Moreover, what is necessary is just to perform processes, such as shredding, grinding | pulverization, and grinding, before heating.
タマネギの加熱方法に制限はないが、焦げ臭が生成しないように、弱火でゆっくりロースト及び/又はソテーしたタマネギが好適である。ロースト及び/又はソテー後のタマネギの重量は、生の3分の1程度となる。さらに、消臭効果を上げるために、アルコールや水などで抽出したエキスを用いるか、あるいはそのエキスを必要に応じて濃縮して用いてもよい。 Although there is no restriction | limiting in the heating method of an onion, The onion slowly roasted and / or sauteed on low heat is suitable so that a burning smell may not be produced | generated. The weight of the onion after roasting and / or sauteing is about one third of the raw weight. Furthermore, in order to increase the deodorizing effect, an extract extracted with alcohol or water may be used, or the extract may be concentrated as necessary.
2−フルアルデヒドとは、別名フルフラール、2−フランカルボキシアルデヒド、2−フランカルボアルデヒドなどと呼ばれる物質である。また、5−メチル−2−フルアルデヒドとは、別名5−メチルフラン−2−カルボアルデヒド、5−メチル−2−フランカルボアルデヒド、5−メチルフルフラール、5−メチルフルフルアルデヒドなどと呼ばれる物質である。さらに、5−ヒドロキシメチル−2−フルアルデヒドとは、別名5−ヒドロキシメチル−2−フランカルボキシアルデヒド、5−ヒドロキシメチル−2−フランカルボナール、5−ヒドロキシメチル−2−フルフラールなどと呼ばれる物質である。 2-Furaldehyde is a substance called alias furfural, 2-furancarboxaldehyde, 2-furancarbaldehyde and the like. Further, 5-methyl-2-furaldehyde is a substance called alias 5-methylfuran-2-carbaldehyde, 5-methyl-2-furancarbaldehyde, 5-methylfurfural, 5-methylfurfuraldehyde and the like. . Furthermore, 5-hydroxymethyl-2-furaldehyde is a substance called alias 5-hydroxymethyl-2-furancarboxaldehyde, 5-hydroxymethyl-2-furancarbonal, 5-hydroxymethyl-2-furfural. is there.
原料の一部にタマネギを用いて蒸留することを経て最終的に焼酎が得られる。その焼酎を用いて、酒税法でいう混成酒類のうち、みりんとしてもよい。その製造方法は、酒税法に則ったみりんの製造方法であれば特に限定はない。一般的なみりんの製造方法は、まず、搗精、洗米等の原料処理を行い、麹などを添加して仕込醪となし、糖化・熟成する。次に、糖化・熟成を終えた醪を圧搾機で上槽して搾汁液と粕に分離する。最後に、得られた搾汁液に対して精製工程で火入れし、滓下げして清澄な製品みりんとなる。ここでいう原料処理には、精白、洗米、浸漬、水切り、蒸煮、放冷の各工程があるが、更に掛原料の液化及び/又は糖化工程も含んでいる。原料として、米、米麹、醸造用アルコール又は焼酎以外に、デンプン部分加水分解物を使用してもよい。また、必要に応じて酵素製剤を掛原料の処理の液化及び/又は糖化工程並びに醪へ添加してもよい。 Shochu is finally obtained through distillation using onion as part of the raw material. Using the shochu, it can be mirin among the mixed liquors referred to in the Liquor Tax Law. The production method is not particularly limited as long as it is a production method of mirin in accordance with the liquor tax law. A general method for producing mirin is to first treat raw materials such as milled rice, washed rice, etc., add koji, etc. to make a koji, and saccharify and ripen. Next, after finishing the saccharification and ripening, the koji is separated into a squeezed liquid and koji by using a press machine. Finally, the resulting juice is fired in a purification process and lowered into a clear product mirin. The raw material treatment mentioned here includes the steps of whitening, rice washing, dipping, draining, steaming, and allowing to cool, but further includes a liquefaction and / or saccharification step of the hanging raw material. As a raw material, a starch partial hydrolyzate may be used in addition to rice, rice bran, alcohol for brewing or shochu. Moreover, you may add an enzyme formulation to the liquefaction and / or saccharification process of a processing of a hanging raw material, and a koji as needed.
本発明の食材の処理方法は、本発明の焼酎を食材に接触させ、加熱する工程を含むことを特徴とする。
また本発明の不快臭の消臭方法は、本発明の焼酎を、含硫アミノ酸を含有する調味料に添加、あるいは、本発明の焼酎によって畜肉、魚介類、野菜、玉子類等の食材を処理し、これらの調味料や食材から発生する不快臭を消臭するものである。
さらに、本発明の食感の改善方法は、本発明の食材の処理方法によって畜肉又は魚介類を処理し、畜肉又は魚介類の食感を改善するものである。
The processing method of the foodstuff of this invention includes the process of making the shochu of this invention contact a foodstuff, and heating.
Further, the method for deodorizing an unpleasant odor of the present invention includes adding the shochu of the present invention to a seasoning containing a sulfur-containing amino acid, or treating foods such as livestock meat, seafood, vegetables and eggs with the shochu of the present invention. The unpleasant odor generated from these seasonings and foods is eliminated.
Furthermore, the texture improving method of the present invention is to improve the texture of livestock meat or seafood by treating livestock meat or seafood with the food processing method of the present invention.
すなわち、本発明の食材の処理方法を実施することにより、処理対象が含硫アミノ酸高含有の調味料である場合には、加熱時に発生する硫黄臭の消臭を達成することができる。食材が畜肉、魚介類、野菜又は玉子類である場合には、畜肉、魚介類、野菜又は玉子類の不快臭の消臭を達成することができる。さらに、食材が畜肉、魚介類である場合には、畜肉、魚介類に対する食感改善も達成することができる。 That is, by implementing the food processing method of the present invention, when the treatment target is a seasoning containing a high content of sulfur-containing amino acids, it is possible to achieve deodorization of sulfur odor generated during heating. When the food material is livestock meat, seafood, vegetables or eggs, it is possible to achieve elimination of unpleasant odors of livestock meat, seafood, vegetables or eggs. Furthermore, when foodstuffs are livestock meat and fishery products, the texture improvement with respect to livestock meat and fishery products can also be achieved.
焼酎を接触させる方法としては浸漬が代表的であるが、塗布あるいは噴霧によって接触させてもよい。本発明の食材の処理方法を含硫アミノ酸高含有の調味料や畜肉、魚介類、野菜又は玉子類に適用する場合の、本発明の焼酎の使用量は、2−フルアルデヒド、5−メチル−2−フルアルデヒド、及び5−ヒドロキシメチル−2−フルアルデヒドの組成や含有量に応じて適宜設定すればよく、特に限定はない。溶解度や調理効果が異なるため一概には決められないが、含硫アミノ酸高含有の調味料や畜肉、魚介類、野菜又は玉子類100部に対して0.1〜2000部の焼酎の使用が好ましい。なお、焼酎の使用量が高いほど不快臭の消臭等の顕著な調理効果を示す。 As a method for bringing the shochu into contact, immersion is typical, but contact may be made by coating or spraying. The amount of shochu used in the present invention when applying the food processing method of the present invention to seasonings containing high sulfur-containing amino acids, livestock meat, seafood, vegetables or eggs is 2-furaldehyde, 5-methyl- What is necessary is just to set suitably according to a composition and content of 2-furaldehyde and 5-hydroxymethyl-2-furaldehyde, and there is no limitation in particular. Although the solubility and cooking effect are different, it cannot be determined unconditionally, but it is preferable to use 0.1 to 2000 parts of shochu per 100 parts of the seasoning and meat, seafood, vegetables or eggs containing high sulfur-containing amino acids. . In addition, the higher the amount of shochu used, the more remarkable cooking effects such as deodorization of unpleasant odors.
前述のように、本発明の食材の処理方法の対象となる好適な食材は、例えば加熱する際に硫黄臭がするものであり、畜肉、魚介類、野菜又は玉子類が代表的である。畜肉は、食用できる肉であれば特に限定なく、例えば獣肉類では、牛、豚、馬、羊、山羊、鹿、猪、熊などが挙げられ、鳥肉類では、鶏、アヒル、七面鳥、雉、鴨、鶉などが挙げられる。同様に、魚介類は、食用できる魚介類であれば特に限定はなく、魚類及び貝類などの水中にすむ水産動物が例として挙げられる。さらに、エビ、カニなどの節足動物、イカ、タコなどの軟体動物、クラゲなどの腔腸動物、ウニ、ナマコなどの棘皮動物、ホヤなどの原索動物なども対象となる。 As described above, suitable foods that are subject to the food processing method of the present invention have a sulfur odor when heated, for example, livestock meat, seafood, vegetables, or eggs. Livestock meat is not particularly limited as long as it is edible meat, for example, for beef, beef, pig, horse, sheep, goat, deer, shark, bear, etc., for poultry, chicken, duck, turkey, salmon, Examples include duck and salmon. Similarly, the seafood is not particularly limited as long as it is an edible seafood, and examples thereof include marine animals that live in water such as fish and shellfish. Furthermore, arthropods such as shrimps and crabs, molluscs such as squid and octopus, coelenterates such as jellyfish, echinoderms such as sea urchins and sea cucumbers, and protozoa such as sea squirts are also targeted.
野菜では、キャベツ、ブロッコリー、ダイコンなどが代表的である。玉子類は、食用できる玉子であれば特に限定なく、例えば、鶏、アヒル、七面鳥、雉、鴨、鶉などの玉子が挙げられる。その他タラコやカラスミなどの魚類の卵も本発明の玉子類に含まれる。 Typical vegetables are cabbage, broccoli and radish. The eggs are not particularly limited as long as they are edible eggs, and examples thereof include eggs such as chickens, ducks, turkeys, salmon, duck, and salmon. In addition, eggs of fish such as tarako and crow are also included in the eggs of the present invention.
上記食材の他、本発明の焼酎は、ソーセージや蒲鉾等の加工食品、漬物等の発酵食品、などに由来する不快臭の消臭にも有用である。さらに、本発明の焼酎は、植物性タンパク質である大豆タンパク等の加熱時に発生する不快臭の消臭にも有用である。 In addition to the above ingredients, the shochu of the present invention is also useful for deodorizing unpleasant odors derived from processed foods such as sausages and strawberries, fermented foods such as pickles. Furthermore, the shochu of the present invention is also useful for deodorizing unpleasant odors generated during heating of soybean protein, which is a vegetable protein.
本発明の加工食品の製造方法は、本発明の焼酎を食材に接触させることによって加工食品を得ることを特徴とする。この場合の焼酎の使用量も、2−フルアルデヒド、5−メチル−2−フルアルデヒド、及び5−ヒドロキシメチル−2−フルアルデヒドの組成や含有量に応じて適宜設定すればよく、特に限定はない。特に、加熱時に発生する硫黄臭の発生抑制に効果があり、高温加熱処理時に発生するレトルト臭の発生抑制に顕著な効果を奏する。好ましい実施形態では、当該食材が畜肉、魚介類、野菜又は玉子類である。畜肉、魚介類、野菜又は玉子類の例は上記で挙げたものと同じである。玉子類から得られる加工食品としては、出し巻き玉子、茶碗蒸しなどが挙げられ、中華料理のピータンの硫黄臭を除去することもできる。 The method for producing a processed food of the present invention is characterized in that a processed food is obtained by bringing the shochu of the present invention into contact with a food material. The amount of shochu used in this case may be set as appropriate according to the composition and content of 2-furaldehyde, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde, and is not particularly limited. Absent. In particular, it is effective in suppressing the generation of sulfur odor generated during heating, and has a remarkable effect in suppressing the generation of retort odor generated during high-temperature heat treatment. In a preferred embodiment, the food material is livestock meat, seafood, vegetables or eggs. Examples of livestock meat, seafood, vegetables or eggs are the same as those given above. Processed foods obtained from eggs include egg rolls, steamed rice bowls and the like, and the sulfur odor of Chinese food Pean can also be removed.
前記したように、本発明の焼酎はレトルト臭の発生抑制に顕著な効果を奏するので、本発明の焼酎を食材に接触させてレトルト食品とすると、不快臭の発生が抑制されたレトルト食品を得ることができる。レトルト食品には、包装形態から、レトルトパウチ食品、レトルト容器食品、レトルトパック食品が挙げられる。また、缶詰や瓶詰の加工食品にも有効である。 As described above, the shochu of the present invention has a remarkable effect in suppressing the generation of retort odor. Therefore, when the shochu of the present invention is brought into contact with a food material to obtain a retort food, a retort food in which the generation of unpleasant odor is suppressed is obtained. be able to. Examples of the retort food include a retort pouch food, a retort container food, and a retort pack food from a packaging form. It is also effective for canned and bottled processed foods.
本発明の焼酎は、2−フルアルデヒド、5−メチル−2−フルアルデヒド、及び5−ヒドロキシメチル−2−フルアルデヒドを含む。ここで、本発明の焼酎の実施形態について、さらに詳細に説明する。本実施形態の焼酎を製造するには、焼酎醪を使用する。より具体的には、まず、原料の米又は大麦を蒸きょう後、麹菌(白又は黒麹菌)の胞子を散布し、33〜40℃で約40時間かけて製麹し、一次醪として麹に水と焼酎酵母を加えて混合し、25〜30℃で7日間かけて酵母の増殖を図り、この一次醪に主原料の穀類、水を加えて混合し二次醪とし、25〜30℃で8〜20日間(主原料の種類によって日数が異なる)かけて発酵させる。また、アミラーゼ、セルラーゼ、プロテアーゼ、リパーゼ、ヘミセルラーゼ、エステラーゼ、ペクチナーゼの群から選択される1つ以上の酵素剤が共存していてもよい。 The shochu of the present invention contains 2-furaldehyde, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde. Here, the embodiment of the shochu of the present invention will be described in more detail. To produce the shochu of this embodiment, shochu is used. More specifically, after steaming the raw rice or barley, the spores of koji molds (white or black koji molds) are sprayed and kneaded at 33 to 40 ° C. for about 40 hours to be used as primary koji. Add water and shochu yeast and mix for 7 days at 25-30 ° C. Add primary cereal and water to the primary koji and mix to make secondary koji at 25-30 ° C. It is fermented over 8 to 20 days (the number of days varies depending on the type of main raw material). One or more enzyme agents selected from the group of amylase, cellulase, protease, lipase, hemicellulase, esterase and pectinase may coexist.
二次醪の段階でタマネギを添加する。ここで添加するタマネギは、加熱処理したものであることが好ましい。タマネギの添加時期は、二次醪の段階であれば特に限定はない。タマネギの醪中での浸漬期間としては、1〜5日間が特に好適である。これにより、前記した3種のフルアルデヒド類とともにタマネギから抽出された香味成分が作用して、複雑な香味成分が増強され、種々の成分が合わさってさらなる香味の多様化、製品の熟成効果などが生み出される。 Add the onion at the second stage. The onion added here is preferably heat-treated. The onion addition time is not particularly limited as long as it is in the secondary koji stage. As the soaking period of the onion in the cage, 1 to 5 days is particularly suitable. As a result, the flavor components extracted from the onion together with the above-mentioned three types of furaldehydes act to enhance the complex flavor components, and various components combine to further diversify the flavor, ripen the product, etc. Produced.
タマネギ由来の有効成分を含有する二次醪を、仕込み(発酵)終了後、単式蒸留器に入れ、減圧又は常圧で蒸留する。ここで、蒸留直後の原酒には油性成分があるので、過剰の不溶物をろ過して取り除く。こうして得られた焼酎は、2−フルアルデヒド、5−メチル−2−フルアルデヒド、及び5−ヒドロキシメチル−2−フルアルデヒドの香気が引き立った優れた酒質のものになる。 A secondary koji containing an onion-derived active ingredient is placed in a single-type distiller after completion of the preparation (fermentation) and distilled at reduced pressure or normal pressure. Here, since the raw sake immediately after distillation has an oily component, excess insoluble matter is removed by filtration. The shochu obtained in this way has an excellent liquor quality with an aroma of 2-furaldehyde, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde.
このようにして得られる焼酎は、アルコール濃度25v/v%換算で、1.0mg/L以上の2−フルアルデヒド、0.3mg/L以上の5−メチル−2−フルアルデヒド、及び0.1mg/L以上の5−ヒドロキシメチル−2−フルアルデヒドを含有する、きわめて優れた不快臭の消臭効果と食感の改善効果を有するものとなる。なお、市販されている料理用焼酎、飲用焼酎には、アルコール濃度25v/v%換算で、1.0mg/L以上の2−フルアルデヒド、0.3mg/L以上の5−メチル−2−フルアルデヒド、及び0.1mg/L以上の5−メチル−2−フルアルデヒドを含有するものはない。 The shochu obtained in this way is 1.0 mg / L or more of 2-furaldehyde, 0.3 mg / L or more of 5-methyl-2-furaldehyde, and 0.1 mg in terms of an alcohol concentration of 25 v / v%. / L or more of 5-hydroxymethyl-2-furaldehyde, which has a very excellent unpleasant odor eliminating effect and texture improving effect. In addition, commercially available shochu for cooking and drinking shochu include 1.0 mg / L or more of 2-furaldehyde and 0.3 mg / L or more of 5-methyl-2-fur in terms of an alcohol concentration of 25 v / v%. None contains aldehydes and more than 0.1 mg / L of 5-methyl-2-furaldehyde.
さらに、タマネギ又はタマネギの加工処理物の添加量を上げると、2−フルアルデヒド等の含有量をさらに高めることができる。タマネギ又はタマネギの加工処理物の醪に対する添加量は特に限定はなく、流動性があって蒸留できればよく、例えば醪に対して75w/v%程度まで添加することが可能である。本実施形態におけるこれら3成分の上限値としては特に限定はないが、例えば、2−フルアルデヒド含有量を3000mg/L以下とすることができる。すなわち、本実施形態では、2−フルアルデヒド含有量を1〜3000mg/Lとすることが可能である。 Furthermore, content of 2-furaldehyde etc. can further be raised when the addition amount of the onion or the processed product of onion is increased. There is no particular limitation on the amount of onion or onion processed product added to the straw. The amount of the onion or onion processed can be distilled as long as it has fluidity. For example, it can be added up to about 75 w / v% with respect to the straw. Although there is no limitation in particular as an upper limit of these three components in this embodiment, For example, 2-furaldehyde content can be 3000 mg / L or less. That is, in the present embodiment, the 2-furaldehyde content can be 1 to 3000 mg / L.
本発明の焼酎は、そのまま食材の処理剤、畜肉、魚介類、野菜又は玉子類の不快臭の消臭剤、畜肉や魚介類の食感改善剤として使用することができる。 The shochu of the present invention can be used as it is as a food processing agent, livestock meat, seafood, deodorant for vegetables or eggs, and food texture improver for livestock meat and seafood.
以下、実施例をもって本発明を更に具体的に説明するが、本発明はこれらの実施例に限定されるものではない。 EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples.
含硫アミノ酸高含有の調味料に対する不快臭の消臭について検討を行った。
2−フルアルデヒドが181mg/L、5−メチル−2−フルアルデヒドが0.3mg/L、及び5−ヒドロキシメチル−2−フルアルデヒドが0.1mg/L(すべてアルコール濃度25v/v%換算)含まれているアルコール濃度40v/v%の酒精含有溶液を調製した。アミノ酸液精製R〔播州調味料(株)製〕30mLに、前記したアルコール濃度40v/v%の酒精含有溶液0.3mLを加え、真空密封後、120℃、60分間のレトルト加熱殺菌を行い、15分間冷却し、アミノ酸液のレトルト加熱殺菌処理物を得た(実施例1)。氷冷下、20mL容ヘッドスペースガス測定用バイアルに5mLをはかりとり、ヘッドスペースガスをGC/MSにより分析を行った。分析は、キャピラリーカラムDB−WAX(J&W社製)を接続したガスクロマトグラフG1530A(アジレント社製)に質量検出器5973(HEWLETT PACKARD社製)を連結したもので、常法通り行った。対照は、アルコール濃度40.0v/v%のアルコール水溶液を用いて、同様にレトルト加熱殺菌したものとした(比較例1)。
The deodorization of the unpleasant odor to the seasoning containing high sulfur-containing amino acid was examined.
2-Furaldehyde is 181 mg / L, 5-Methyl-2-furaldehyde is 0.3 mg / L, and 5-Hydroxymethyl-2-furaldehyde is 0.1 mg / L (all in terms of alcohol concentration 25 v / v%) An alcohol-containing solution having an alcohol concentration of 40 v / v% was prepared. Amino acid solution refined R [manufactured by Banshu Seasoning Co., Ltd.] is added to 0.3 mL of a spirit-containing solution having an alcohol concentration of 40 v / v% described above, and after vacuum sealing, sterilized by heating at 120 ° C. for 60 minutes, It cooled for 15 minutes and obtained the retort heat sterilization processed material of the amino acid liquid (Example 1). Under ice cooling, 5 mL was weighed into a 20 mL headspace gas measurement vial, and the headspace gas was analyzed by GC / MS. The analysis was carried out as usual by connecting a mass detector 5973 (manufactured by HEWLETT PACKARD) to a gas chromatograph G1530A (manufactured by Agilent) connected to a capillary column DB-WAX (manufactured by J & W). As a control, an aqueous alcohol solution having an alcohol concentration of 40.0 v / v% was used, and the mixture was sterilized by retort heating (Comparative Example 1).
実施例1と比較例1のアミノ酸液のレトルト加熱殺菌処理物について比較した結果、比較例1では硫化水素、ジメチルスルフィド、ジメチルトリスルフィド、メチオナールなどの含硫化合物(硫黄臭の成分)が検出されたのに対し、実施例1では含硫化合物が検出されなかった。以上より、実施例1の酒精含有溶液によって、含硫アミノ酸高含有のアミノ酸液の加熱時に発生する硫黄臭(不快臭)を消臭できることが示された。 As a result of comparing the retort heat-treated products of the amino acid solutions of Example 1 and Comparative Example 1, in Comparative Example 1, sulfur-containing compounds (sulfur odor components) such as hydrogen sulfide, dimethyl sulfide, dimethyl trisulfide, and methional were detected. In contrast, in Example 1, no sulfur-containing compound was detected. From the above, it was shown that the sulfur odor (unpleasant odor) generated during heating of the amino acid solution containing a high amount of sulfur-containing amino acid can be removed by the alcohol-containing solution of Example 1.
細断した生タマネギ740gを、弱火で焦げないようにローストし、ローストタマネギ206gを得た。ローストタマネギ40gに95v/v%発酵アルコール42mL、水158mLを加え、常温で1時間攪拌抽出後、40℃の条件下、エバポレーターで減圧濃縮し、アルコール濃度29.9v/v%の留液120mLを得た(実施例2)。なお、エバポレーターでの減圧濃縮は、減圧蒸留と同等の効果を有するものである。
一方、細断した生タマネギ144gに、95v/v%発酵アルコール42mL、水158mLを加え、同様の条件下、エバポレーターで減圧濃縮し、アルコール濃度24.2v/v%の留液150mLを得た(比較例2−1)。
740 g of the chopped raw onion was roasted so as not to burn on low heat, to obtain 206 g of roasted onion. Add 40mL of 95v / v% fermented alcohol and 158mL of water to 40g of roasted onion, stir and extract at room temperature for 1 hour, concentrate under reduced pressure with an evaporator at 40 ° C, and add 120mL of distillate with an alcohol concentration of 29.9v / v%. Obtained (Example 2). In addition, the vacuum concentration by an evaporator has an effect equivalent to vacuum distillation.
On the other hand, to 144 g of chopped raw onion, 42 mL of 95 v / v% fermented alcohol and 158 mL of water were added and concentrated under reduced pressure using an evaporator under the same conditions to obtain 150 mL of a distillate having an alcohol concentration of 24.2 v / v% ( Comparative Example 2-1).
得られた各留液について、GC/MSにより香気成分解析を行った。分析は、キャピラリーカラムDB−WAX(J&W社製)を接続したガスクロマトグラフG1530A(アジレント社製)に質量検出器5973(HEWLETT PACKARD社製)を連結したもので、常法通り行った。その結果、実施例2の留液には、2−フルアルデヒドが1.0mg/L、5−メチル−2−フルアルデヒドが0.3mg/L、及び5−ヒドロキシメチル−2−フルアルデヒドが0.1mg/L(すべてアルコール濃度25v/v%換算)含まれていた。一方、比較例2−1の留液には、2−フルアルデヒド、5−メチル−2−フルアルデヒド、及び5−ヒドロキシメチル−2−フルアルデヒドは、すべて痕跡程度しか検出されなかった。 About each obtained distillate, the aromatic component analysis was performed by GC / MS. The analysis was carried out as usual by connecting a mass detector 5973 (manufactured by HEWLETT PACKARD) to a gas chromatograph G1530A (manufactured by Agilent) connected to a capillary column DB-WAX (manufactured by J & W). As a result, in the distillate of Example 2, 2-furaldehyde was 1.0 mg / L, 5-methyl-2-furaldehyde was 0.3 mg / L, and 5-hydroxymethyl-2-furaldehyde was 0. .1 mg / L (all in terms of alcohol concentration of 25 v / v%) was included. On the other hand, in the distillate of Comparative Example 2-1, all traces of 2-furaldehyde, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde were detected.
アルミ積層のレトルトパウチに、牛肉17g、水20mL、実施例2の留液0.2mLを加え、自動真空包装機で真空密封後、120℃、60分、0.185MPaで加熱殺菌した。対照として、比較例2−1の留液又は水(比較例2−2)各々0.2mLを加え、同様に加熱したものについて評価した。その結果、比較例2−1、比較例2−2ではレトルト加熱殺菌に由来する不快臭は消臭されていなかったが、実施例2ではレトルト加熱殺菌に由来する不快臭がよく消臭されていた。 17 g of beef, 20 mL of water, and 0.2 mL of the distillate of Example 2 were added to the aluminum-laminated retort pouch, vacuum-sealed with an automatic vacuum packaging machine, and then heat sterilized at 120 ° C. for 60 minutes at 0.185 MPa. As a control, 0.2 mL each of the distillate or water of Comparative Example 2-1 (Comparative Example 2-2) was added, and the same heating was evaluated. As a result, in Comparative Example 2-1 and Comparative Example 2-2, the unpleasant odor derived from retort heat sterilization was not deodorized, but in Example 2, the unpleasant odor derived from retort heat sterilization was well deodorized. It was.
畜肉の不快臭の消臭について検討を行った。
原料の一部にタマネギを用いて、2−フルアルデヒドが38mg/L、5−メチル−2−フルアルデヒドが0.5mg/L、及び5−ヒドロキシメチル−2−フルアルデヒドが0.1mg/L(すべてアルコール濃度25v/v%換算)含まれているアルコール濃度25.0v/v%のタマネギ焼酎を製造した。このタマネギ焼酎を、割水してアルコール濃度が13.0v/v%となるようにした。この割水したタマネギ焼酎を用い、表1に示す配合の調味液(実施例3と比較例3の計2種)を調製した。表1中の「タマネギ焼酎」は割水したタマネギ焼酎(アルコール濃度13.0v/v%)である。
We examined the deodorization of the unpleasant odor of livestock meat.
Using onion as a part of the raw material, 2-furaldehyde is 38 mg / L, 5-methyl-2-furaldehyde is 0.5 mg / L, and 5-hydroxymethyl-2-furaldehyde is 0.1 mg / L. (All in terms of alcohol concentration 25 v / v%) Onion shochu having an alcohol concentration of 25.0 v / v% was produced. This onion shochu was split to adjust the alcohol concentration to 13.0 v / v%. Using this watered onion shochu, seasoning liquids having the composition shown in Table 1 (a total of two types, Example 3 and Comparative Example 3) were prepared. “Onion shochu” in Table 1 is onion shochu (alcohol concentration: 13.0 v / v%).
鍋にオーストラリア産牛肉60gを入れ、表1の実施例3の調味料120mLを注ぎ入れ、加熱した。沸騰後さらに弱火で10分間加熱し、120℃、20分間のレトルト加熱殺菌を行い、牛丼の具を得た(実施例3)。対照は、タマネギ焼酎の代わりにアルコール濃度13.0v/v%のアルコール水溶液を含む調味液(比較例3の調味料)を用いて、同様に調理したものとした(比較例3)。実施例3と比較例3の牛丼の具について、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例3より実施例3の方が、不快臭が消臭されており、また食感もよいと回答した。 60 g of Australian beef was put into a pan, and 120 mL of the seasoning of Example 3 in Table 1 was poured and heated. After boiling, the mixture was further heated for 10 minutes with low heat and sterilized by retort heating at 120 ° C. for 20 minutes to obtain beef bowl (Example 3). The control was prepared in the same manner using a seasoning liquid (condiment of Comparative Example 3) containing an alcohol aqueous solution having an alcohol concentration of 13.0 v / v% instead of onion shochu (Comparative Example 3). About the beef bowl of Example 3 and Comparative Example 3, an unpleasant odor and the like were subjected to a sensory evaluation test by 11 skilled panelists. As a result, 11 out of 11 responded that Example 3 had better unpleasant odor and better texture than Comparative Example 3.
野菜の不快臭の消臭について検討を行った。
原料の一部にタマネギを用いて、2−フルアルデヒドが28mg/L、5−メチル−2−フルアルデヒドが0.3mg/L、及び5−ヒドロキシメチル−2−フルアルデヒドが0.1mg/L(すべてアルコール濃度25v/v%換算)含まれているアルコール濃度12.9v/v%のタマネギ焼酎を製造した。このタマネギ焼酎を、割水してアルコール濃度が3.0v/v%となるようにした。
The deodorization of the unpleasant odor of vegetables was examined.
Using onion as part of the raw material, 28 mg / L of 2-furaldehyde, 0.3 mg / L of 5-methyl-2-furaldehyde, and 0.1 mg / L of 5-hydroxymethyl-2-furaldehyde (All in terms of alcohol concentration of 25 v / v%) Onion shochu having an alcohol concentration of 12.9 v / v% was produced. This onion shochu was split to adjust the alcohol concentration to 3.0 v / v%.
ブロッコリーに、割水したタマネギ焼酎40mLを加え、真空密封後、沸騰水中で5分間煮沸し、水冷して、ブロッコリーの加工食品を得た(実施例4)。対照は、タマネギ焼酎の代わりにアルコール濃度3.0v/v%のアルコール水溶液を用いて、同様に調理したものとした(比較例4)。実施例4と比較例4のブロッコリーの加工食品について、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例4より実施例4の方が、不快臭が消臭されていると回答した。 To the broccoli was added 40 mL of split onion shochu, vacuum sealed, boiled in boiling water for 5 minutes, and water-cooled to obtain a broccoli processed food (Example 4). As a control, an alcohol aqueous solution having an alcohol concentration of 3.0 v / v% was used instead of the onion shochu, and the same cooking was performed (Comparative Example 4). About the processed food of the broccoli of Example 4 and the comparative example 4, an unpleasant odor etc. were subjected to the sensory evaluation test by 11 skilled panelists. As a result, 11 out of 11 responded that the unpleasant odor was eliminated in Example 4 than in Comparative Example 4.
ソーセージの不快臭の消臭について検討を行った。
実施例3と同様のタマネギ焼酎(アルコール濃度13.0v/v%)を用い、表2に示す配合で各材料を混合し、ケーシングに注入した後、80℃で30分間ボイルし、氷水で急冷してソーセージ(実施例5と比較例5の計2種)を調製した。表2中の「タマネギ焼酎」は割水したタマネギ焼酎(アルコール濃度13.0v/v%)である。
We investigated the deodorization of sausage.
Using the same onion shochu (alcohol concentration: 13.0 v / v%) as in Example 3, each material was mixed in the formulation shown in Table 2, poured into the casing, boiled at 80 ° C. for 30 minutes, and rapidly cooled with ice water. Then, sausages (a total of two types of Example 5 and Comparative Example 5) were prepared. “Onion shochu” in Table 2 is onion shochu (alcohol concentration: 13.0 v / v%).
実施例5と比較例5のソーセージについて、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例5より実施例5の方が、不快臭が消臭されており、また食感もよいと回答した。 About the sausage of Example 5 and Comparative Example 5, an unpleasant odor and the like were subjected to a sensory evaluation test by 11 skilled panelists. As a result, 11 persons out of 11 answered that Example 5 had better unpleasant odors and better texture than Comparative Example 5.
蒲鉾の不快臭の消臭について検討を行った。
実施例3と同様のタマネギ焼酎(アルコール濃度13.0v/v%)を用い、表3に示す配合で各材料を混合し、ケーシングに注入した後、5℃で一晩静置した。その後、96℃で1時間ボイルし、氷水で急冷して蒲鉾を調製した。表3中の「タマネギ焼酎」は割水したタマネギ焼酎(アルコール濃度13.0v/v%)である。
We examined the deodorization of unpleasant odors.
Using the same onion shochu (alcohol concentration: 13.0 v / v%) as in Example 3, each material was mixed in the formulation shown in Table 3, poured into the casing, and allowed to stand overnight at 5 ° C. Thereafter, it was boiled at 96 ° C. for 1 hour, and quenched with ice water to prepare a koji. “Onion shochu” in Table 3 is onion shochu (alcohol concentration: 13.0 v / v%).
実施例6と比較例6の蒲鉾について、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例6より実施例6の方が、不快臭が消臭されており、また食感もよいと回答した。 For the soot of Example 6 and Comparative Example 6, an unpleasant odor was subjected to a sensory evaluation test by 11 skilled panelists. As a result, 11 out of 11 responded that the unpleasant odor was eliminated and the texture was better in Example 6 than in Comparative Example 6.
沢庵漬けの不快臭の消臭について検討を行った。
食塩濃度15w/w%の塩蔵大根を1w/w%になるまで流水脱塩して、5mm厚に輪切りした。実施例3と同様のタマネギ焼酎(アルコール濃度13.0v/v%)を用い、表4に示す配合の調味液で調味漬けを行った後、70℃の湯浴中で10分間殺菌して大根の沢庵漬けを調製した。かつお節調味液として「だししるべKP−1」(宝酒造株式会社製)、昆布調味液として「だししるべL−利尻」(宝酒造株式会社製)を、それぞれ使用した。表4中の「タマネギ焼酎」は割水したタマネギ焼酎(アルコール濃度13.0v/v%)である。
We examined the deodorization of the unpleasant odor of the pickled rice cake.
The salted radish with a salt concentration of 15 w / w% was desalted with running water until it reached 1 w / w%, and cut into 5 mm thicknesses. Using onion shochu (alcohol concentration: 13.0 v / v%) similar to that in Example 3, seasoned with a seasoning liquid having the composition shown in Table 4, and then sterilized in a 70 ° C. hot water bath for 10 minutes Nozawazuke pickles were prepared. “Dashi Shirube KP-1” (Takara Shuzo Co., Ltd.) was used as the bonito seasoning liquid, and “Dashi Shirube L-Rishiri” (Takara Shuzo Co., Ltd.) was used as the kelp seasoning liquid. The “onion shochu” in Table 4 is the onion shochu (alcohol concentration 13.0 v / v%) that has been split.
実施例7で得られた大根の沢庵漬けについて、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例7より実施例7の方が、塩蔵臭、沢庵臭と呼ばれる不快臭が消臭されており、また食感もよいと回答した。 For the radish pickled in radish obtained in Example 7, an unpleasant odor and the like were subjected to a sensory evaluation test by 11 skilled panelists. As a result, 11 out of 11 responded that in Example 7, the unpleasant odor called salted odor and saw odor was eliminated and the texture was better than Comparative Example 7.
玉子類の不快臭の消臭について検討を行った。
実施例3と同様のタマネギ焼酎(アルコール濃度13.0v/v%)を用い、表5に示す配合の茶碗蒸し調味液(実施例8と比較例8の計2種)を調製した。表5中の「タマネギ焼酎」は割水したタマネギ焼酎(アルコール濃度13.0v/v%)である。
We examined the deodorization of unpleasant odors in eggs.
Using the same onion shochu (alcohol concentration: 13.0 v / v%) as in Example 3, a tea-boiled seasoning liquid having a formulation shown in Table 5 (two types in total, Example 8 and Comparative Example 8) was prepared. “Onion shochu” in Table 5 is water onion shochu (alcohol concentration: 13.0 v / v%).
容器に実施例8の茶碗蒸し調味液を入れ、95℃の蒸気で14分間加熱し、茶碗蒸しを得た(実施例8)。対照は、タマネギ焼酎の代わりにアルコール濃度13.0v/v%のアルコール水溶液を用いて、同様に加熱したものとした(比較例8)。実施例8と比較例8の茶碗蒸しについて、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例8より実施例8の方が、玉子類の加熱により発生する硫黄臭である不快臭が消臭されており、また食感もよいと回答した。 The steamed steamed seasoning liquid of Example 8 was placed in a container and heated with steam at 95 ° C. for 14 minutes to obtain steamed steamed tea (Example 8). As a control, an alcohol aqueous solution having an alcohol concentration of 13.0 v / v% was used in place of onion shochu and heated in the same manner (Comparative Example 8). About the tea fumigation of Example 8 and Comparative Example 8, the sensory evaluation test was done by 11 skilled panelists about the unpleasant odor etc. As a result, 11 out of 11 responded that in Example 8, the unpleasant odor, which is a sulfur odor generated by heating the eggs, was eliminated and the texture was good in Comparative Example 8.
魚介類の不快臭の消臭について検討を行った。
アルミ積層のレトルトパウチに紅ズワイガニ5g、実施例3と同様のタマネギ焼酎(アルコール濃度13.0v/v%)5mLを入れ、自動真空包装機で真空密封後、120℃、60分、0.185MPaで加熱殺菌を行った(実施例9)。対照は、紅ズワイガニ5gとタマネギ焼酎の代わりにアルコール濃度13.0v/v%のアルコール水溶液5mLを入れ、同様に加熱したものとした(比較例9)。実施例9と比較例9について、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例9より実施例9の方が、カニ加熱時に発生する不快臭が消臭されていると回答した。
We investigated the deodorization of unpleasant odors in seafood.
Place 5 g of red snow crab and 5 mL of onion shochu (alcohol concentration: 13.0 v / v%) as in Example 3 in an aluminum laminated retort pouch, vacuum seal with an automatic vacuum packaging machine, 120 ° C., 60 minutes, 0.185 MPa (Example 9). As a control, 5 g of an alcohol aqueous solution having an alcohol concentration of 13.0 v / v% was placed in place of 5 g of red snow crab and onion shochu, and heated in the same manner (Comparative Example 9). For Example 9 and Comparative Example 9, unpleasant odors were subjected to a sensory evaluation test by 11 skilled panelists. As a result, 11 persons out of 11 answered that the unpleasant odor generated during the crab heating in Example 9 was eliminated from Comparative Example 9.
野菜類の不快臭の消臭について検討を行った。
アルミ積層のレトルトパウチにキャベツ30g、水28.5mL、実施例3と同様のタマネギ焼酎(アルコール濃度13.0v/v%)1.5mLを入れ、自動真空包装機で真空密封後、120℃、60分、0.185MPaで加熱殺菌を行った(実施例10)。対照は、キャベツ30gとタマネギ焼酎の代わりにアルコール濃度13.0v/v%のアルコール水溶液1.5mLを入れ、同様に加熱したものとした(比較例10)。実施例10と比較例10について、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例10より実施例10の方が、キャベツ加熱時に発生する不快臭が消臭されていると回答した。
We examined the deodorization of unpleasant odors in vegetables.
30g cabbage, 28.5mL water, 1.5mL onion shochu (alcohol concentration 13.0v / v%) similar to Example 3 were put into an aluminum laminated retort pouch. After vacuum-sealing with an automatic vacuum packaging machine, 120 ° C, Heat sterilization was performed at 0.185 MPa for 60 minutes (Example 10). As a control, 30 g of cabbage and 1.5 mL of an alcohol aqueous solution having an alcohol concentration of 13.0 v / v% were placed in place of cabbage and onion shochu, and heated in the same manner (Comparative Example 10). About Example 10 and Comparative Example 10, an unpleasant odor and the like were subjected to a sensory evaluation test by 11 skilled panelists. As a result, 11 out of 11 responded that the unpleasant odor generated during the cabbage heating was eliminated in Example 10 than in Comparative Example 10.
卵白の不快臭の消臭について検討を行った。
実施例3と同様にして、アルコール濃度25.0v/v%のタマネギ焼酎を製造した。このタマネギ焼酎に加塩清酒と食塩を添加し、割水してアルコール濃度が13.0v/v%となるようにした。この割水したタマネギ焼酎を含有する発酵調味料を用い、表6に示す配合で混合し、ケーシングに入れソーセージ状の形状に成型し、80℃で40分間処理を行い、成型卵白を調製した(実施例11)。対照は、タマネギ焼酎を含有する発酵調味料の代わりにアルコール濃度13.0v/v%のアルコール水溶液10gを入れ、同様に加熱・成型したものとした(比較例11)。
We examined the deodorization of the unpleasant odor of egg white.
In the same manner as in Example 3, an onion shochu liquor having an alcohol concentration of 25.0 v / v% was produced. Salted sake and salt were added to this onion shochu, and water was added to adjust the alcohol concentration to 13.0 v / v%. Using the fermented seasoning containing this watered onion shochu, mixed in the formulation shown in Table 6, put into a casing, molded into a sausage shape, processed at 80 ° C. for 40 minutes to prepare a molded egg white ( Example 11). As a control, 10 g of an alcohol aqueous solution having an alcohol concentration of 13.0 v / v% was added instead of the fermented seasoning containing onion shochu, and the mixture was heated and molded in the same manner (Comparative Example 11).
実施例11の成型卵白に等量の水を加えホモジナイズ(10,000rpm、3分間)した。その後、20mL容ヘッドスペースガス測定用バイアルに、ホモジナイズ後の溶液5mLを入れ密栓後、バイアル中のヘッドスペースガスをGC/MSにより分析を行った。対照は、比較例11の成型卵白を、同様にホモジナイズしたものとした。 An equal amount of water was added to the molded egg white of Example 11 and homogenized (10,000 rpm, 3 minutes). Thereafter, 5 mL of the homogenized solution was placed in a 20 mL headspace gas measurement vial and sealed, and the headspace gas in the vial was analyzed by GC / MS. As a control, the molded egg white of Comparative Example 11 was similarly homogenized.
実施例11と比較例11の硫化水素量を測定した結果を図1に示す。すなわち、比較例11に比べて、実施例11では検出された硫化水素量は少なかった。 The results of measuring the amount of hydrogen sulfide in Example 11 and Comparative Example 11 are shown in FIG. That is, the amount of hydrogen sulfide detected in Example 11 was smaller than that in Comparative Example 11.
実施例11と比較例11の成型卵白について、不快臭等を、熟練したパネラー11名により官能評価試験を行った。その結果、11名中11名が、比較例11より実施例11の方が、卵白加熱時に発生する不快臭が消臭されていると回答した。 For the molded egg whites of Example 11 and Comparative Example 11, an unpleasant odor was subjected to a sensory evaluation test by 11 skilled panelists. As a result, 11 out of 11 responded that the unpleasant odor generated during the heating of egg white in Example 11 was eliminated from Comparative Example 11.
以上のことから、タマネギ焼酎を含有する発酵調味料によって、卵白加熱時に発生する硫化水素臭と呼ばれる不快臭を消臭することができることがわかった。 From the above, it was found that an unpleasant odor called hydrogen sulfide odor generated during egg white heating can be deodorized with a fermented seasoning containing onion shochu.
Claims (7)
原料の少なくとも一部にタマネギを用いたものであることを特徴とする焼酎。 In terms of an alcohol concentration of 25 v / v%, 1.0 mg / L or more of 2-furaldehyde, 0.3 mg / L or more of 5-methyl-2-furaldehyde, and 0.1 mg / L or more of 5-hydroxymethyl- Contains 2-furaldehyde,
Shochu characterized by using onion as at least a part of the raw material.
原料の少なくとも一部にタマネギを用いたものであることを特徴とする焼酎。 In terms of an alcohol concentration of 25 v / v%, 28 mg / L or more of 2-furaldehyde, 0.3 mg / L or more of 5-methyl-2-furaldehyde, and 0.1 mg / L or more of 5-hydroxymethyl-2- Contains furaldehyde,
Shochu characterized by using onion as at least a part of the raw material.
原料の少なくとも一部にタマネギを用いたものであることを特徴とする焼酎。 In terms of an alcohol concentration of 25 v / v%, 38 mg / L or more of 2-furaldehyde, 0.5 mg / L or more of 5-methyl-2-furaldehyde, and 0.1 mg / L or more of 5-hydroxymethyl-2- Contains furaldehyde,
Shochu characterized by using onion as at least a part of the raw material.
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