JP5097330B2 - Elastic sealant composition for building - Google Patents

Description

The present invention relates to an elastic sealant composition for building , and more particularly to an elastic sealant composition for building which is excellent in resilience , durability, weather resistance and paint non-staining properties.

  Conventionally, an oxypropylene polymer having a crosslinkable silyl group that can be cured into a rubber-like substance by moisture or the like has been used for an elastic sealant of a building or the like. In this case, a composition in which a plasticizer, a filler and the like are blended with a polymer is used from the viewpoint of physical properties and cost. In order to follow fluctuations in the joints of buildings due to humidity differences, the resilience of the sealant filling the joints is important.

Various studies have been made on the curable composition having excellent resilience (see, for example, Patent Documents 1 and 2), but there have been problems in physical properties such as weather resistance and paint non-contamination.
JP 55-9669 A Japanese Patent Publication No. 1-29821 Japanese Patent No. 3062626 Japanese Patent Publication No. 1-58219 Japanese Patent No. 3062625 JP-A-8-337713 JP 2003-138151 A Japanese Patent Laid-Open No. 11-12480 JP-A-52-73998 JP 59-122541 A Japanese Unexamined Patent Publication No. 60-6747 JP-A-61-233043 Japanese Unexamined Patent Publication No. Sho 63-112642 JP-A-3-79627 JP-A-4-283259 JP-A-5-70531 JP-A-5-287186 Japanese Patent Laid-Open No. 11-80571 Japanese Patent Laid-Open No. 11-116763 JP-A-11-130931 Japanese Patent No. 3313360 JP 2003-155469 A Japanese Examined Patent Publication No. 3-14068 Japanese Patent Publication No. 5-72427 Japanese Patent Publication No. 4-55444 JP-A-6-221922 JP 2000-345136 A Japanese Patent Laid-Open No. 2003-48721 Japanese Patent Laid-Open No. 2001-40037 Japanese Patent Laid-Open No. 11-80250 JP 60-31556 A JP 59-78223 A JP 59-168014 A JP-A-60-228516 Japanese Patent Publication No. 7-42376 Japanese Patent Publication No. 10-195151 Japanese Patent Publication No. 2-44845 Japanese Patent Publication No. 7-238143 JP 2000-17249 A JP 2004-51830 A JP 2004-59782 A JP 2001-329065 A JP 2001-271055 A WO96 / 30421 publication WO97 / 18247 WO98 / 01480 publication WO98 / 40415 publication JP-A-9-208616 Japanese Patent Laid-Open No. 8-41117 JP-A-4-132706 JP-A 61-271306 Japanese Patent No. 2594402 JP 54-47782 A J. Am. Chem. Soc., 1994, 116, 7943 Macromolecules, 1994, 27, 7228 J. Am. Chem. Soc., 1995, 117, 5614 Macromolecules, 1995, 28, 7901 Science, 1996, 272, 866 Macromolecules, 1995, 28, 1721 Macromolecules, 1999, 32, 2872

An object of this invention is to provide the elastic sealing material composition for buildings excellent in a weather resistance, paint nonfouling property, a resilience, and durability.

In order to solve the above-mentioned problems, the elastic sealant composition for building of the present invention comprises (A) 100 parts by weight of a (meth) acrylic polymer having a crosslinkable silyl group at the molecular chain end, and (B) containing an epoxy group. 5 to 150 parts by weight of (meth) acrylic polymer, (C) 0.001 to 10 parts by weight of divalent tin organic carboxylate, and (D) 0.001 to 10 parts by weight of organic amine compound. It is characterized by. In the present invention, acryl and methacryl are collectively referred to as (meth) acryl.

  The polymer (A) is preferably a crosslinkable silyl group-containing (meth) acrylic polymer. The crosslinkable silyl group-containing (meth) acrylic polymer includes a (meth) acrylic organic polymer having a crosslinkable silyl group at the molecular chain end, and a (meth) having the crosslinkable silyl group at the molecular chain end. A mixture of an acrylic polymer and a crosslinkable silyl group-containing organic polymer is preferred. The method for producing the (meth) acrylic polymer having a crosslinkable silyl group at the terminal is not particularly limited, but a controlled radical polymerization method is preferable, a living radical polymerization method is more preferable, and an atom transfer radical polymerization method is further preferable.

  The epoxy group-containing (meth) acrylic polymer (B) preferably has a weight average molecular weight of 1,000 or more and 7,500 or less.

The building elastic sealant composition of the present invention has excellent weather resistance and paint non-staining properties, as well as excellent resilience and durability, and can be suitably used particularly for building sealants and the like. .

  Embodiments of the present invention will be described below, but these embodiments are exemplarily shown, and it goes without saying that various modifications can be made without departing from the technical idea of the present invention.

The building elastic sealant composition of the present invention contains the following components (A), (B), (C) and (D) as essential components.
(A) Crosslinkable silyl group-containing organic polymer (B) Epoxy group-containing (meth) acrylic polymer (C) Divalent tin organic carboxylate (D) Organic amine compound

  The crosslinkable silyl group-containing organic polymer (A) includes a silicon-containing group having a hydroxyl group or hydrolyzable group bonded to a silicon atom and capable of crosslinking by forming a siloxane bond, that is, a crosslinkable silyl group. The containing organic polymer is used. Examples of the crosslinkable silyl group-containing organic polymer (A) include those disclosed in Patent Documents 1 and 4 to 43, for example. Specifically, the crosslinkable silyl group-containing organic polymer (A) specifically includes a crosslinkable silyl group, the main chain may each contain an organosiloxane, a polyoxyalkylene polymer, a vinyl-modified polymer. Examples thereof include polyoxyalkylene polymers, vinyl polymers, polyester polymers, (meth) acrylic acid ester polymers, copolymers and mixtures thereof.

  The crosslinkable silyl group is not particularly limited, but generally 1 to 6 crosslinkable silyl groups are contained in the molecule from the viewpoint of the curability of the composition and the physical properties after curing. Further, the crosslinkable silyl group is preferably one represented by the following general formula (1) which is easy to crosslink and easy to produce.

Wherein (1), R ¹ is a monovalent organic group having a substituted or unsubstituted 1 to 20 carbon atoms, an alkyl group, the number aryl group or C 6 to 20 carbon atoms having 1 to 20 carbon atoms 7 An aralkyl group of ˜20 is preferred, and a methyl group is most preferred. When a plurality of R ¹ are present, they may be the same or different. X is a hydroxyl group or a hydrolyzable group, and is a group selected from a halogen atom, hydrogen atom, hydroxyl group, alkoxy group, acyloxy group, ketoximate group, amide group, acid amide group, mercapto group, alkenyloxy group and aminooxy group Are preferred, alkoxy groups are more preferred, and methoxy groups are most preferred. When a plurality of X are present, they may be the same or different. a is 1, 2 or 3, and 2 is most preferable. ]

  In the crosslinkable silyl group-containing organic polymer (A), when a plurality of crosslinkable silyl groups are present, these may be the same or different, and the number of a in the formula (1) is also They can be the same or different. Two or more organic polymers having different crosslinkable silyl groups may be used.

  The main chain of the crosslinkable silyl group-containing organic polymer (A) is a polyoxyalkylene polymer which may contain an organosiloxane from the viewpoint of physical properties such as tensile adhesiveness after curing and modulus. A (meth) acryl-modified polyoxyalkylene polymer, a (meth) acrylic polymer, a polyisobutylene polymer, a copolymer or a mixture thereof is preferable, and a (meth) acrylic polymer is particularly preferable. Specifically, a polyoxyalkylene polymer containing a crosslinkable silyl group as disclosed in Patent Documents 1 and 4 to 22, and a crosslinkable silyl group as disclosed in Patent Documents 18 to 43 are used. Preferable examples include the acrylic polymer contained, the acrylic-modified polyoxyalkylene polymer containing a crosslinkable silyl group as disclosed in Patent Documents 10 and 31 to 36, and a mixture thereof.

  The crosslinkable silyl group-containing organic polymer (A) is particularly preferably a vinyl polymer having a crosslinkable silyl group at the end, a (meth) acrylic polymer having a crosslinkable silyl group at the end, and the A mixture of a (meth) acrylic polymer having a crosslinkable silyl group at the terminal and a polyoxyalkylene polymer having a crosslinkable silyl group is more preferred.

  The manufacturing method of the said crosslinkable silyl group containing organic polymer (A) is not specifically limited, A well-known synthesis method can be utilized. When the crosslinkable silyl group-containing organic polymer contains a crosslinkable silyl group and the main chain is a vinyl polymer such as an acrylic polymer, a vinyl polymer synthesized by a radical polymerization method is used. Is preferably used.

  The radical polymerization method uses a general radical polymerization method in which a monomer having a specific functional group and a vinyl monomer are simply copolymerized using an azo compound, a peroxide, or the like as a polymerization initiator. The control radical polymerization method can introduce a specific functional group at a controlled position. In the present invention, a vinyl polymer synthesized by a controlled radical polymerization method is more effective.

  The controlled radical polymerization method further includes a chain transfer agent method in which a vinyl polymer having a functional group at the terminal is obtained by polymerization using a chain transfer agent having a specific functional group, and a polymerization growth terminal is terminated. It can be divided into the living radical polymerization method that grows without causing etc.

  The living radical polymerization method has an arbitrary molecular weight, a molecular weight distribution is narrow, a polymer having a low viscosity can be obtained, and a monomer having a specific functional group can be introduced at an arbitrary position. Is particularly preferred. In the present invention, in addition to the polymerization in which the terminal always has activity and the molecular chain grows, the terminal inactivated and the activated one are grown while in equilibrium. Living polymerization is also included in living polymerization.

  Examples of the living radical polymerization method include a method using a cobalt porphyrin complex as disclosed in Non-Patent Document 1, a method using a radical scavenger such as a nitroxide compound as disclosed in Non-Patent Document 2, and the like. Atom transfer radical polymerization (Atom Transfer) in which vinyl monomers are polymerized using an organic halogen compound or a sulfonyl halide compound as disclosed in Patent Documents 3-6 and 44-49 as an initiator and a transition metal complex as a catalyst. Radical Polymerization (ATRP) method and the like. The living radical polymerization method is not particularly limited, but the atom transfer radical polymerization method is preferable. In the present invention, a reverse atom transfer radical polymerization method, that is, a high oxidation state when a normal atom transfer radical polymerization catalyst generates radicals, for example, Cu (II) when Cu (I) is used as a catalyst, is used. In addition, a method in which a general radical initiator such as a peroxide is allowed to act on, and as a result an equilibrium similar to that of atom transfer radical polymerization (see, for example, Non-Patent Document 7) is also used. Is included.

  Examples of the chain transfer agent method include a method of obtaining a halogen-terminated polymer using a halogenated hydrocarbon as disclosed in Patent Document 50 as a chain transfer agent, and Patent Documents 51 to 53. Examples thereof include a method for obtaining a hydroxyl-terminated polymer using such a hydroxyl group-containing mercaptan or a hydroxyl group-containing polysulfide as a chain transfer agent.

  Hereinafter, the atom transfer radical polymerization method will be described. As an initiator of the atom transfer radical polymerization method, an organic halide, particularly an organic halide having a highly reactive carbon-halogen bond (for example, a carbonyl compound having a halogen at the α-position or a compound having a halogen at the benzyl-position). Or, a halogenated sulfonyl compound or the like is used, and specific examples include compounds represented by the following formulas (2) to (5).

_{^{C 6 H 5 -CR 2 R 3}} Y ··· (2)
R ⁴ CR ² YCOOR ⁵ (3)
R ⁴ CR ² YCOR ⁵ (4)
R ⁴ —C ₆ H ₅ —SO ₂ Y (5)
[In the formulas (2) to (5), R ² and R ³ are hydrogen atoms or methyl groups, R ⁴ and R ⁵ are hydrogen atoms or alkyl groups having 1 to 20 carbon atoms, aryl groups or aralkyl groups, Y is chlorine Bromine or iodine. )

  Further, as an initiator of atom transfer radical polymerization, an organic halide having a functional group other than a functional group for initiating polymerization, such as an alkenyl group, a crosslinkable silyl group, a hydroxyl group, an epoxy group, an amino group, an amide group, or the like Halogenated sulfonyl compounds can also be used. In this case, a vinyl polymer having a functional group at one end of the main chain and a growth terminal structure of atom transfer radical polymerization at the other main chain end is synthesized. In the present invention, it is preferable to use an organic halide or sulfonyl halide compound having a crosslinkable silyl group. In this case, a polymer having a crosslinkable silyl group at one end and a halogen end at the other end is obtained, and a polymer having a crosslinkable silyl group at both ends is obtained by substituting the halogen end. be able to.

  Although it does not specifically limit as a vinyl-type monomer used in superposition | polymerization, In this invention, acrylic-type single quantities, such as (meth) acrylic acid, (meth) acrylic acid ester, (meth) acrylonitrile, (meth) acrylamide, etc. The main component is preferably one or more of the body, and more preferably a main component is a (meth) acrylic acid ester such as alkyl (meth) acrylate and alkoxyalkyl (meth) acrylate. Specific examples of the (meth) acrylic acid ester include (meth) acrylic acid esters exemplified in the following polymer (B).

  Although there is no limitation in particular as a transition metal complex used as a polymerization catalyst, the metal complex complex which uses a 7th, 8th, 9th, 10th, or 11th group element of a periodic table as a central metal is preferable, and a zerovalent A complex of copper, monovalent copper, divalent ruthenium, divalent iron or divalent nickel is more preferred, and a copper complex is particularly preferred.

  Examples of the monovalent copper compound include cuprous chloride, cuprous bromide, cuprous iodide, cuprous cyanide, cuprous oxide, cuprous perchlorate, and the like. When a copper compound is used, 2,2′-bipyridyl and its derivatives, 1,10-phenanthroline and its derivatives, tetramethylethylenediamine, pentamethyldiethylenetriamine, hexamethyltris (2-aminoethyl) amine, etc. in order to increase the catalytic activity A ligand such as a polyamine is added.

In addition, tristriphenylphosphine complex of divalent ruthenium chloride [RuCl ₂ (PP
h ₃ ) ₃ ] divalent iron bistriphenylphosphine complex [FeCl ₂ (PPh ₃ ) ₂ ], 2
Bivalent nickel bistriphenylphosphine complex [NiCl ₂ (PPh ₃ ) ₂ ] and 2
A bivalent bistributylphosphine complex of nickel [NiBr ₂ (PBu ₃ ) ₂ ] is also suitable as a catalyst. When a ruthenium compound is used as a catalyst, an aluminum alkoxide is added as an activator.

  The polymerization can be carried out without solvent or in various solvents. The polymerization temperature is preferably in the range of 0 to 200 ° C, more preferably in the range of room temperature to 150 ° C.

  Acrylics having a halogen at the end by radical polymerization of vinyl monomers containing acrylic monomers as the main component, using organic halides or sulfonyl halides as initiators and transition metal complexes as catalysts. A polymer is produced. The (meth) acrylic polymer having a crosslinkable silyl group at the molecular chain end used in the present invention can be obtained by converting the halogen of the acrylic polymer having the halogen at the end to a crosslinkable silyl group. . The conversion method is not particularly limited, and a known method (for example, see Patent Documents 18 to 20, 40 to 43, etc.) can be used.

  In the present invention, the crosslinkable silyl group-containing organic polymer (A) has a number average molecular weight of 1000 or more and 100,000 or less, particularly 3000 to 50000, which has a narrow molecular weight distribution, and is easy to handle because of its low viscosity before curing. Physical properties such as later strength, elongation, modulus, etc. are preferred. The crosslinkable silyl group-containing organic polymer (A) may be used alone or in combination of two or more.

  The epoxy group-containing (meth) acrylic polymer (B) preferably has a weight average molecular weight of 1000 to 7500, more preferably 1500 to 6000, and still more preferably 2000 to 5500. When the weight average molecular weight exceeds 7500, a sufficient plasticizing effect is not exhibited and workability is deteriorated, and when it is less than 1000, a low molecular weight polymer is bleed and contamination is reduced. . The number of epoxy groups in the polymer (B) is not particularly limited, but is preferably 0.05 or more and more preferably 0.1 or more on average per molecule. The epoxy group-containing (meth) acrylic polymer functions as a plasticizer and an amine catcher. The epoxy group has a polarity. By increasing the polarity of the polymer, the affinity with the top coat is increased, so that the adhesion is considered to be improved.

  The method for producing the epoxy group-containing (meth) acrylic polymer is not particularly limited, and specifically, an epoxy group-containing (meth) acrylic monomer (for example, glycidyl (meth) acrylate) is copolymerized. Or it can be obtained by reacting an epoxy group-containing compound with a functional group-containing (meth) acrylic polymer. Examples of the method of reacting the latter functional group-containing (meth) acrylic polymer with an epoxy group-containing compound include a method of reacting a polymer having an isocyanate group with glycidol.

  Although the manufacturing method of a (meth) acrylic-type polymer is not specifically limited, (meth) acrylic-type monomers, such as (meth) acrylic acid, (meth) acrylic acid ester, (meth) acrylonitrile, and (meth) acrylamide, It can be obtained by (co) polymerizing one or more (co) by a known method. As the (meth) acrylic monomer, a (meth) acrylic ester is particularly preferable.

  Examples of the (meth) acrylic acid ester include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, isopropyl (meth) acrylate, butyl (meth) acrylate, (meth) Isobutyl acrylate, s-butyl (meth) acrylate, t-butyl (meth) acrylate, neopentyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, isodecyl (meth) acrylate, (meth) acrylic acid Lauryl, alkyl (meth) acrylates such as tridecyl (meth) acrylate and stearyl (meth) acrylate, cyclohexyl (meth) acrylate, isobornyl (meth) acrylate and tricyclodecynyl (meth) acrylate ( (Meth) acrylic acid alicyclic alkyl, (meth) acrylic acid 2-methyl Examples include heteroatom-containing (meth) acrylic acid esters such as xylethyl, dimethylaminoethyl (meth) acrylate, chloroethyl (meth) acrylate, trifluoroethyl (meth) acrylate, and tetrahydrofurfuryl (meth) acrylate. . Among these, methyl methacrylate, ethyl acrylate, butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, methoxyethyl acrylate, and cyclohexyl acrylate are particularly preferable in terms of balancing plasticity. Other than these (meth) acrylic acid esters, other copolymerizable monomers may be used as long as the physical properties are not impaired. Examples of such monomers include α-olefins such as ethylene, propylene and isobutylene; chloroethylenes such as vinyl chloride and vinylidene chloride; and alkyl vinyl ethers such as ethyl vinyl ether and butyl vinyl ether.

  Although the compounding ratio of a component (B) is not specifically limited, It is preferable to use 5-150 weight part with respect to 100 weight part of component (A), 10-120 weight part is more preferable, 15-100 weight part is Further preferred. If the amount is less than 5 parts by weight, a sufficient plasticizing effect and restoring property cannot be obtained. If the amount is more than 150 parts by weight, bleeding may occur on the surface and contamination may be deteriorated. The said epoxy group containing (meth) acrylic-type polymer may be used by 1 type, and may be used together 2 or more types.

  Examples of the divalent tin organic carboxylate (C) include tin (II) octylate, tin (II) naphthenate, and tin (II) stearate. The blending ratio of the component (C) is not particularly limited, but is preferably about 0.001 to 10 parts by weight with respect to 100 parts by weight of the component (A). These divalent tin organic carboxylates may be used alone or in combination of two or more.

  Examples of the organic amine compound (D) include diethylenetriamine, triethylenetetramine, tetraethylenepentamine, butylamine, hexylamine, octylamine, decylamine, laurylamine, hexamethylenediamine, triethanolamine, dibutylamine, diethanolamine, N , N, N ′, N′-tetramethyl-1,3-butanediamine, benzylamine, cyclohexylamine, dodecamethylenediamine, dimethylethylenediamine, dimethylaminoethanol, N, N, N ′, N′-tetramethylethylenediamine, Examples include triethylamine, N, N-dimethylaniline, dimethylbenzylaniline and the like. Moreover, the compound which reacts with water, such as ketimine, and produces | generates an organic amine can also be used as an organic amine.

  The blending ratio of the component (D) is not particularly limited, but is preferably about 0.001 to 10 parts by weight with respect to 100 parts by weight of the component (A). These organic amine compounds may be used alone or in combination of two or more.

In addition to the above-described components, the elastic sealing material composition for building of the present invention includes other curing catalyst, adhesion-imparting agent, physical property modifier, filler, plasticizer, thixotropic agent, and dehydrating agent as necessary. (Storage stability improver), tackifiers, sag-preventing agents, UV absorbers, antioxidants, flame retardants, colorants, radical polymerization initiators, and various solvents such as toluene and alcohol May be.

  The present invention will be described more specifically with reference to the following examples. However, it is needless to say that these examples are shown by way of illustration and should not be construed in a limited manner.

Example 1
As shown in Table 1, the modified silicone polymer SA100S (manufactured by Kaneka Chemical Co., Ltd .: trade name SA100S) as the component (A) crosslinkable silyl group-containing organic polymer, and XG-4010 (Toagosei Co., Ltd.) as the component (B) ), Heavy calcium carbonate, surface-treated calcium carbonate, anti-aging agent, Neostan U-28 (manufactured by Nitto Kasei Co., Ltd.) as component (C), and Farmin 20D (Kao Corporation) as component (D) )) Were prepared in predetermined amounts, respectively, to prepare curable compositions.

The compounding amounts of the compounding substances in Table 1 are shown in parts by weight, and * 1 , * 3, * 5 to * 14 are as follows.
* 1: Acrylic polymer having a crosslinkable silyl group at the molecular end produced by living radical polymerization (manufactured by Kaneka Chemical Co., Ltd .: trade name SA100S)
* 3: Crosslinkable silyl group-containing polyoxyalkylene polymer (manufactured by Kaneka Chemical Co., Ltd .: trade name S-810)
* 5: Epoxy group-containing acrylic polymer (manufactured by Toagosei Co., Ltd .: trade name XG-4010, 1.4 number of average epoxy groups per molecule)
* 6: Epoxy plasticizer (Shin Nihon Rika Co., Ltd .: trade name Sansosizer E-145, EPS, molecular weight 410)
* 7: Phthalic acid plasticizer (DINP)
* 8: Acrylic polymer (no functional group, manufactured by Toagosei Co., Ltd .: trade name UP-1000)
* 9: Stanas octoate divalent tin compound (manufactured by Nitto Kasei Co., Ltd .: trade name Neostan U-28)
* 10: Dibutyltin laurate, tetravalent tin compound (manufactured by Nitto Kasei Co., Ltd .: trade name Neostan U-100)
* 11: Laurylamine (manufactured by Kao Corporation: trade name Farmin 20D)
* 12: Heavy calcium carbonate (manufactured by Bihoku Flourishing Co., Ltd .: trade name Whiten SB)
* 13: Surface-treated calcium carbonate (manufactured by Maruo Calcium Co., Ltd .: trade name Calfine 200)
* 14: Anti-aging agent (manufactured by Ciba Specialty Chemicals, Inc., trade name: Tinuvin B-75)

(Example 2 and Comparative Examples 1 to 4)
As shown in Table 1, a curable composition was prepared in the same procedure as in Example 1 except that the compounding material and the compounding ratio were changed.

  The following measurement was performed with respect to the obtained curable composition. The results are shown in Table 2.

1. Restorability An H-shaped test body according to JIS A 1439 was prepared and cured for 7 days in a 23 ° C. and 50% RH environment, for 7 days in a 50 ° C. environment, and for 14 days in a 90 ° C. environment. Thereafter, it was allowed to stand for 24 hours in an environment of 23 ° C. and 50% RH. The thickness at that time (about 12.00 mm) was set as the initial value. Next, a predetermined jig was used in an environment of 23 ° C. and 50% RH, and left for 24 hours in a state of 200% elongation (about 24.00 mm). After 24 hours, the jig was removed and allowed to stand for 1 hour, after which the thickness was measured and restoration was obtained using the following formula.
Restorability (%) = (thickness after stretching−thickness after release) / initial thickness × 100

2. Durability Test JIS A 1439 (1997) 4.17 Durability Test (Durability Category 9030) was performed. As for the durability test results, ○ was acceptable and × was unacceptable.

3. Paint non-contamination sealant curing conditions: 7 days under 23 ° C and 50% RH conditions Paint curing conditions: 7 days under 23 ° C and 50% RH conditions Evaluation method: After accelerating heating for 7 days in a 50 ° C dryer, Sprinkling on the paint, the presence or absence of contamination was visually confirmed by the degree of sand adhesion. When no contamination was observed for all the paints, the evaluation was evaluated as ○.

Various paints used in the paint non-staining test are as follows.
Paints: Bildec: Solvent acrylic, Dainippon Paint Co., Ltd. Vinylose: Solvent vinyl chloride, Dainippon Paint Co., Ltd. Buron: Water acrylic, Dainippon Paint Co., Ltd. Odecoat G: Water acrylic, Nihon Paint DAN UNI Co., Ltd .: Water-based acrylic, Nippon Paint Co., Ltd. New Topless screen: Water-based acrylic silicone, SK Kaken Co., Ltd. Please coat: Water-based acrylic, SK Kaken Co., Ltd. Tile rack U: Urethane system , Nippon Paint Co., Ltd. New Soft Lysine: Water-based acrylic, SK Kaken Co., Ltd.

4). Weather resistance A weather resistance test was conducted in a sunshine weatherometer, and the appearance after 1000 hours and 2000 hours was examined. In the weather resistance test results, ◯ indicates that there are no cracks, Δ indicates that there are slight cracks, and × indicates that there are many cracks.

As shown in Table 2, the curable compositions of Examples 1 and 2 were excellent in weather resistance, paint non-fouling property and durability, and the restorability was very good at 95% or more, whereas the comparative example The curable compositions of 1 and 2 were poor in paint non-staining and weather resistance. In addition, Comparative Examples 2 to 4 had poor recoverability, and the durability test also failed.

The building elastic sealant composition of the present invention is excellent in resilience, weather resistance, and paint non-contamination, and can be suitably used particularly as a building sealant.

Claims (5)

(A) 100 parts by weight of a (meth) acrylic polymer having a crosslinkable silyl group at the molecular chain end,
(B) 5 to 150 parts by weight of an epoxy group-containing (meth) acrylic polymer,
(C) 0.001-10 weight part of bivalent tin organic carboxylate, and (D) 0.001-10 weight part of organic amine compounds, The elastic sealing material composition for buildings characterized by the above-mentioned. 2. The building elastic sealant composition according to claim 1, wherein the polymer (A) is a (meth) acrylic polymer produced by a living radical polymerization method. 3. The architectural elastic sealant composition according to claim 1, wherein the polymer (A) is a (meth) acrylic polymer produced by an atom transfer radical polymerization method. 2. The polymer (A) is a mixture of a (meth) acrylic polymer having a crosslinkable silyl group at a molecular chain terminal and a crosslinkable silyl group-containing polyoxyalkylene polymer. The architectural elastic sealant composition according to any one of -3. The weight-average molecular weight of the epoxy group-containing (meth) acrylic polymer (B) is 1,000 or more and 7,500 or less, and the elastic sealing for building according to any one of claims 1 to 4. Material composition.