JP5088459B2 - Skin cleanser composition - Google Patents

Description

  The present invention relates to a skin cleansing composition that has good foaming even in hard water, is smooth without squeaky feeling during rinsing, has little feeling of tension after washing, and is mild to the skin.

  Hitherto, higher fatty acid salts have been widely used as detergents for washing skin with good foaming and a refreshing finish. However, long-chain fatty acid salts having 14 or more carbon atoms have the property of combining with divalent metal ions such as calcium ions in tap water during washing to form metal salts (scum), which adhere to the skin. For this reason, particularly when a long-chain fatty acid salt is used, there is a drawback that a squeaky feeling at the time of rinsing and a feeling of squeezing after washing, and when used in hard water, foaming power is reduced.

  In order to solve these problems, a detergent that combines an amide ether derivative and a metal sequestering agent with a fatty acid salt has been proposed as a detergent excellent in foaming properties and skin feel even in hard water (Patent Document 1). : JP-A-10-218758). However, the amount of the conventional sequestering agent is limited depending on the type, and even if the upper limit of blending is not determined, the blending amount is limited from the viewpoint of the stability of the preparation and skin irritation, so it is sufficient. The effect was not able to be demonstrated.

  In addition, there has been proposed a cleaning composition that suppresses irritation to the skin by adding a specific polyhydric alcohol and charcoal to a higher fatty acid salt (Patent Document 2: JP-A-2002-167325). However, this technique has a problem that the squeakiness at the time of rinsing is not sufficient, and when a higher fatty acid salt having 12 or less carbon atoms is blended, the mildness to the skin during and after washing is not sufficient.

Furthermore, a creamy detergent composition that does not contain lauric acid and is mild to the skin by using at least one of an anionic surfactant and an amphoteric surfactant other than the higher fatty acid salt has been proposed. (Patent Document 3: JP-A-7-309742). However, this technique has a problem that the squeak is not sufficient at the time of rinsing. In addition, a method of blending an oil or a polymer is generally used as a means for alleviating the feeling of being washed up. However, when a large amount of these is blended in order to obtain a sufficient effect, there is a drawback that the ease of rinsing and the refreshing feeling are impaired. In view of the above, there has been a demand for a skin cleansing composition that has good foaming even in hard water, has no squeaky feeling during rinsing, has a low feeling of tension after washing, and is mild to the skin.
In addition, the following is mentioned as a prior art document relevant to this invention.

Japanese Patent Laid-Open No. 10-218758 JP 2002-167325 A Japanese Patent Laid-Open No. 7-309742 JP-A-6-212198 Publication No. 7-501785 JP-A-8-269485 JP-A-10-273429 JP-A-11-180855 JP 2001-31561 A JP 2004-155716 A Japanese National Patent Publication No. 7-501785 JP-A-10-273429

  The present invention has been made in view of the above circumstances, and provides a skin cleansing composition that has good foaming even in hard water, has no squeaky feeling during rinsing, and has a smooth feeling after washing, and is mild to the skin. The purpose is to do.

  As a result of intensive studies to achieve the above object, the present inventor has found that (B) a fatty acid salt having 14 or more carbon atoms and / or a salt thereof of 1% by mass or more and (C) 12 carbon atoms in the skin cleanser composition. By making the following fatty acids and / or salts thereof less than 1% by mass, the skin becomes milder, and (D) edetic acid, edetate, hydroxyethanediphosphonic acid and hydroxyethanediphosphonate In combination with 0.01 to 2% by mass of one or more compounds selected from 1 and 25% by mass or more of (A) a tetrahydric or higher sugar alcohol, foaming is good even in hard water and is rinsed. The present inventors have found that the scum is sometimes smooth and free of squeakiness due to adsorption of the scum to the skin, and that the feeling of tension after washing is reduced.

Accordingly, the present invention provides the following skin cleanser composition.
[1]. (A) 35 to 45 % by mass of a tetrahydric or higher sugar alcohol selected from sorbitol, xylitol, mannitol, erythritol, lactitol, and maltitol
(B) C14 or more fatty acid and / or its salt 3-35 mass%
(C) C12 or less fatty acid and / or salt thereof less than 1% by mass,
(D) One or more compounds selected from edetic acid, edetate, hydroxyethane diphosphonic acid and hydroxyethane diphosphonate 0.01-2% by mass
A skin cleanser composition comprising:
[2]. The skin cleanser composition according to [1], further comprising polyoxyethylene coconut oil fatty acid monoethanolamide.
[3]. The skin cleanser composition according to [1] or [2], which is a liquid skin cleanser composition or a cream facial cleanser.

  According to the skin cleanser composition of the present invention, foaming is good even in hard water, and there is no squeaky feeling at the time of rinsing.

  The component (A) is a tetrahydric or higher sugar alcohol. A tetrahydric or higher sugar alcohol is one having four or more alcoholic hydroxyl groups present in the sugar alcohol structure. Specific examples include sorbitol, xylitol, mannitol, erythritol, lactitol, and maltitol. With sugar alcohols having a valence of 3 or less, the effect of suppressing the squeaky feeling during rinsing and the feeling of tension after washing cannot be obtained. The sugar alcohols can be used singly or in appropriate combination of two or more, and any of D-form, L-form and mixtures thereof can be used.

  (A) The compounding quantity of a component is 25 mass% or more with respect to skin cleansing composition whole quantity, 25-45 mass% is preferable, More preferably, it is 30-45 mass%. By blending 25% by mass or more of the component (A), a synergistic effect with the component (D) is smooth without any squeaky feeling at the time of rinsing, and a good feeling of use is obtained with less stickiness after washing. In addition, although the upper limit of content of (A) component is not specifically limited, it is 50 mass%, and when it exceeds 50 mass%, a luster may arise at the time of a rinse. In addition, a compounding quantity is the total amount, when there are two or more types of (A) component.

  The component (B) is a fatty acid having 14 or more carbon atoms and / or a salt thereof, and examples thereof include myristic acid, palmitic acid, stearic acid, oleic acid, and salts thereof, and the salt in the fatty acid is not particularly limited. Alkali metal salts (for example, sodium salts and potassium salts), amine salts, ammonium salts and the like can be mentioned. The said C14 or more fatty acid and / or its salt can be used individually by 1 type or in combination of 2 or more types.

  (B) The compounding quantity of a component is 1 mass% or more with respect to skin cleanser composition whole quantity, and 1-30 mass% is preferable in a liquid formulation, More preferably, it is 3-25 mass%. In the case of a creamy preparation, 5 to 40% by mass is preferable, and more preferably 10 to 35% by mass. In the case of a solid preparation, 20 to 70% by mass is preferable, and more preferably 30 to 60% by mass. When the blending amount is less than 1% by mass, foaming is insufficient, and the upper limit of the blending amount is not particularly limited. However, when it is 70% by mass or more, foaming is excellent, but a squeaky feeling or a tight feeling may occur.

  The component (C) is a fatty acid having 12 or less carbon atoms and / or a salt thereof, and examples thereof include lauric acid and laurate, and these can be used alone or in combination of two or more. There is no restriction | limiting in particular in the salt in a fatty acid, For example, an alkali metal salt (for example, sodium salt, potassium salt etc.), an amine salt, ammonium salt etc. are mentioned. The fatty acid salts of (B) and (C) may be combined with a fatty acid and a base at the time of blending to form a fatty acid salt in the prescription system.

  (C) The compounding quantity of a component is less than 1 mass% with respect to the skin cleansing composition whole quantity, and less than 0.2 mass% is preferable. Component (C) may not be contained in the composition, and the smaller the blending amount, the better from the viewpoint of mildness to the skin. By setting the fatty acid salts of (B) and (C) within the above ranges, it becomes a skin cleanser having good foaming, refreshing feeling and mildness to the skin.

  Component (D) is one or more compounds selected from edetic acid, edetate, hydroxyethane diphosphonic acid and hydroxyethane diphosphonate. These compounds include edetate, edetates such as edetate, disodium edetate, trisodium edetate, tetrasodium edetate, and hydroxyethanediphosphonic acid, trisodium hydroxyethanediphosphonate, hydroxyethanediphosphonic acid And hydroxyethane diphosphonates such as tetrasodium. These compounds may be combined with an acid and a base at the time of compounding to form a salt in the formulation system.

  (D) The compounding quantity of a component is 0.01-2 mass% with respect to the skin cleaning composition whole quantity. When the blending amount is less than 0.01% by mass, the effect of suppressing the squeaky feeling and the feeling of tension is not sufficient. Moreover, when it exceeds 2 mass%, it may be inferior to the mildness with respect to skin.

  In the skin cleansing composition of the present invention, in addition to the above essential components, other optional components that are usually used in skin cleansing compositions, such as other surfactants (anionic surfactants, nonionic surfactants, cations) Surfactants, amphoteric surfactants), oils, silicones, celluloses, alcohols, polyhydric alcohols, moisturizers, thickeners, preservatives, antioxidants, pH adjusters, fragrances, dyes, lubricants In addition, pigments, inorganic powders, vitamins, amino acids, water, ethanol and the like can be blended within a range that does not impair the effects of the present invention. Moreover, the range of pH used for these components is not particularly limited.

  Examples of amphoteric surfactants include imidazoline type, amide amino acid salt, alkylbetaine type, alkylamide betaine type such as amide propylbetaine laurate, sulfobetaine type, phosphobetaine type, and the like. Nonionic surfactants include polyoxyethylene fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene alkyl ether, coconut oil fatty acid alkanolamide, fatty acid monoethanolamide, polyoxyethylene Examples thereof include oxyethylene coconut oil fatty acid monoethanolamide, sucrose fatty acid ester, and alkyl glycoside. Examples of the polyhydric alcohol include propylene glycol and 1,3 butylene glycol.

  The properties of the skin cleansing composition of the present invention are not particularly limited, and for example, it can be a cream, paste, gel, liquid, solid or the like. Further, the solubilization system, the emulsification system, the powder dispersion system and the like are not particularly limited. The method for using the skin cleansing composition is not particularly limited, and can be used for the whole body, face and hands in a normal manner.

  Moreover, the skin cleansing composition of the present invention can be prepared according to a conventional method of skin cleansing composition by appropriately blending the above essential components and optional components.

  EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not restrict | limited to the following Example. In the following examples, unless otherwise specified, “%” in the composition represents mass%, and the amount of each component in the table is an amount converted into a pure component.

[Examples 1 and 2, Reference Examples 1 to 14 and Comparative Examples 1 to 8]
Skin cleansing compositions having the compositions shown in Tables 1 to 3 were prepared according to a conventional method, and skin cleansing compositions of Examples 1 and 2, Reference Examples 1 to 14 and Comparative Examples 1 to 8 were obtained. For each of the cleaning compositions, the “foaming in hard water”, “no squeaky feeling when rinsing”, “no slickness when rinsing”, “no feeling of tension after washing” and “mildness to the skin” Evaluation was performed by the following method. The results are shown in Tables 1 to 3 below.

(1) Method for evaluating foaming in hard water After 20 panelists diluted the skin cleanser compositions of Examples and Comparative Examples 20 times with hard water at 10 degrees, the whole body was washed with this, based on the following evaluation criteria The amount of foam was sensory evaluated. In the table, the average values of the panelists are shown. If the average value is 3 or more, foaming is good.
<Evaluation criteria>
4 points: good 3 points: slightly good 2 points: bad 1 point: very bad

(2) Evaluation method for lack of squeakiness at the time of rinsing, lack of sliminess at the time of rinsing and feeling of squeezing after washing An expert evaluator (n = 10) evaluated the skin cleansing compositions of Examples and Comparative Examples as 1 It was used once a day for a month, and sensory evaluation was performed on each of the above items based on the following evaluation criteria. The average value of expert evaluators is shown in the table. If the average value is 3 points or more, the composition is excellent in “no squeaky feeling during rinsing”, “no slickness in rinsing”, and “no feeling of squeezing after washing”.
<Evaluation criteria for lack of squeaking during rinsing>
4 points: No squeaky feeling and smoothness 3 points: No squeaky feeling 2 points: Slightly squeezed feeling 1 point: Strong squeaky feeling <Evaluation criteria for non-smoothness during rinsing>
4 points: There is no sliminess at all, and there is a refreshing feeling. 3 points: There is no sliminess. 2 points: There is a little sliminess. 1 point: There is a strong feeling of slipping, and there is no feeling of rinsing. Evaluation criteria>
4 points: No sense of tension 3 points: No sense of tension 2 points: Some sense of tension 1 point: Strong sense of tension

(3) Mildness evaluation method for skin An expert evaluator (n = 10) used the skin cleanser compositions of Examples and Comparative Examples once a day for one month, and the feeling of irritation during and after cleaning ( Sensory evaluation of skin tingling sensation, irritation, etc. The average value of expert evaluators is shown in the table. If the average value is 3 points or more, it is a mild detergent composition for the skin.
<Evaluation criteria for mildness to skin>
3 points: No irritation during and after washing 2 points: Slight irritation during and after washing 1 point: Clear irritation during and after washing

As is clear from the results in the above table, the skin cleanser compositions of Examples 1 and 2 were foamed in hard water, squeaky and non-smooth when rinsed, lack of feeling of tension after washing, and mild to the skin. It was found to be excellent. On the other hand, Comparative Examples 1 to 4 are excellent in no slickness at the time of rinsing and mildness to the skin, but are not good in foaming in hard water, no squeaky feeling in rinsing, and a feeling of tension after washing. Absent. Comparative Examples 5 and 6 are excellent in non-stickiness at the time of rinsing, but are not good in foaming in hard water, no squeak in rinsing, a feeling of squeezing after washing, and mildness on the skin. Comparative Example 7 is excellent in bubbling in hard water, no squeaky feeling during rinsing, and no stickiness during rinsing, but is not good in the feeling of squeezing after washing and mild to the skin. Comparative Example 8 is excellent in the non-stickiness at the time of rinsing and mildness to the skin, but is not good in foaming in hard water, no squeaky feeling in the rinsing, and a feeling of tension after washing.

[ Reference Example 15 ]
Pump type foam discharge container filling Liquid cleansing composition (%)
Potassium myristate 2.5
Amidopropyl betaine laurate 2.0
(Enagicol L-30B, manufactured by Lion Chemical Co., Ltd.)
Mannitol 10.0
Sorbitol 15.0
Propylene glycol 15.0
POE (2) Palm oil fatty acid monoethanolamide 3.0
(Amidette 2CY Kawaken Fine Chemical Co., Ltd.)
Hydroxyethanediphosphonic acid 0.2
Fragrance A 1.0
Purified water balance <br/> Total 100.0
The composition was adjusted to pH 10.0 with potassium hydroxide and filled into a pump-type foam discharge container to obtain a product.

[ Reference Example 16 ]
Liquid facial cleanser composition (%)
Myristic acid triethanolamine 10.0
Triethanolamine palmitate 2.0
Lauroylmethyl-β-alanine triethanolamine 3.0
Cationized cellulose 0.2
(Leogard GPS manufactured by Lion Chemical Co., Ltd.)
Propylene glycol 5.0
Xylitol 25.0
Alkyl acrylate copolymer 1.2
(Leoir MS-200, manufactured by Lion Chemical Co., Ltd.)
Ethylene glycol distearate 2.0
Fragrance B 1.0
Edetic acid 0.1
Hydroxyethane diphosphonic acid 0.1
Purified water balance <br/> Total 100.0
The above composition was adjusted to pH 7.5 with triethanolamine and filled into an arbitrary container (bottle, pump bottle, bag-like container, etc.) to obtain a product.

[ Reference Example 17 ]
Facial cleansing foam composition (%)
Myristic acid 15.0
Palmitic acid 10.0
Stearic acid 3.0
Potassium hydroxide 5.5
Dimethyldiallylammonium chloride / acrylamide copolymer solution 0.3
(Kayakrill Resin M-50, manufactured by Nippon Kayaku Co., Ltd.)
Palm oil fatty acid amidopropyl betaine 3.0
(Obazoline CAB-30, manufactured by Toho Chemical Co., Ltd.)
POE (3) polyoxyethylene glyceryl isostearate 2.0
(EMALEX GWIS-103, manufactured by Nippon Emulsion Co., Ltd.)
POE (5) monostearate polyoxyethylene glycerin 2.0
(EMALEX GM-5, manufactured by Nippon Emulsion Co., Ltd.)
1,3-butylene glycol 5.0
Sorbitol 30.0
Edetic acid 0.4
Fragrance C 0.5
Purified water balance <br/> Total 100.0
The above composition was adjusted to pH 8.5 to 9.0 and filled into an arbitrary container (tube, jar container, etc.) to obtain a product.

[Example 3 ]
Cleansing gel composition Composition (%)
Triethanolamine myristic acid 6.0
N-lauroyl-N-methyl-β-alanine triethanolamine 2.0
Dimethyldiallylammonium chloride / acrylamide copolymer solution 0.3
(Kayakrill Resin M-50, manufactured by Nippon Kayaku Co., Ltd.)
Palm oil fatty acid diethanolamide 3.0
(Home Lead CD, manufactured by Lion Chemical Co., Ltd.)
POE (3) lauryl ether sulfate 4.0
POE (10) behenyl ether 3.0
(Emalex BHA-10, manufactured by Nippon Emulsion Co., Ltd.)
Isononyl isononanoate 2.0
Alkyl acrylate copolymer emulsion 1.5
(Leoir MS-200, manufactured by Lion Chemical Co., Ltd.)
Xylitol 35.0
Isopropylmethylphenol 0.1
LAPONITE XLG (manufactured by Nippon Silica Co., Ltd.) 0.3
Polyethylene powder (average particle size 100 μm) 0.3
Edetic acid 0.1
Hydroxyethane diphosphonic acid 0.1
Fragrance D 1.0
Purified water balance <br/> Total 100.0
The composition was adjusted to pH 8.0 with triethanolamine and filled into an arbitrary container (tube, jar container, bottle, etc.) to obtain a product.

[ Reference Example 18 ]
Body soap composition (%)
Potassium myristate 12.0
Potassium palmitate 3.0
Lauroylmethyl-β-alanine potassium 4.5
Mannitol 30.0
Propylene glycol 7.0
Acrylic acid / alkyl copolymer emulsion 1.0
(Leoir MS-200, manufactured by Lion Chemical Co., Ltd.)
Dimethyldiallylammonium chloride / acrylamide copolymer 0.2
(Kayakrill Resin M-50, manufactured by Nippon Kayaku Co., Ltd.)
Edetate tetrasodium tetrahydrate 0.2
Fragrance A 0.7
Purified water balance <br/> Total 100.0
The above composition was adjusted to pH 10.0 with potassium hydroxide and filled into an arbitrary container (bottle, pump bottle, bag-like container, etc.) to obtain a product.

[Example 4 ]
Cream facial cleanser composition (%)
Myristic acid 5.0
N-myristoyl-sodium L-glutamate 18.0
Sodium lauryl sulfosuccinate 3.0
Lauroylmethyl-β-alanine sodium 2.0
Monostearate polyoxyethylene glycerol (6E.O) 1.0
(EMALEX GM-1000, manufactured by Nippon Emulsion Co., Ltd.)
Pyroglutamate polyoxyethylene glyceryl (25E.O.) 3.0
(EMALEX GPI-25, manufactured by Nippon Emulsion Co., Ltd.)
Polyethylene glycol 300000 0.5
Sorbitol 35.0
Propylene glycol 5.0
Hydroxyethanediphosphonic acid tetrasodium 0.2
Fragrance B 0.1
Purified water balance <br/> Total 100.0
The above composition was adjusted to pH 5.5 to 6.0 and filled into an arbitrary container (tube, jar container, etc.) to obtain a product.

[ Reference Example 19 ]
Liquid face wash composition (%)
Potassium myristate 5.0
Lauroylmethyl-β-alanine potassium 3.0
Amidopropyl betaine laurate 2.0
Sorbitol 30.0
Hydroxypropyl methylcellulose 0.3
(HPMC60SH-4000 manufactured by Shin-Etsu Chemical Co., Ltd.)
Ethylene glycol distearate 0.5
Hydroxyethanediphosphonic acid 0.05
Edetate trisodium 0.05
Fragrance C 0.2
Purified water balance <br/> Total 100.0
The above composition was adjusted to pH 10.0 with potassium hydroxide and filled into an arbitrary container (bottle, pump bottle, bag-like container, etc.) to obtain a product.

[ Reference Example 20 ]
Solid detergent composition (%)
Sodium myristate 20.0
Sodium palmitate 25.0
Sodium stearate 20.0
Sodium oleate 2.0
Sorbitol 32.0
Edetic acid 0.2
Fragrance B 1.0
Purified water balance <br/> Total 100.0
The above composition was packaged in an arbitrary container (paper, bag-like container, etc.) to obtain a product.

[ Reference Example 21 ]
Cream facial cleanser composition (%)
Myristic acid 5.0
N-myristoyl-sodium L-glutamate 18.0
Sodium lauryl sulfosuccinate 3.0
Lauroylmethyl-β-alanine sodium 2.0
Monostearate polyoxyethylene glycerol (6E.O) 1.0
(EMALEX GM-1000, manufactured by Nippon Emulsion Co., Ltd.)
Pyroglutamate polyoxyethylene glyceryl (25E.O.) 3.0
(EMALEX GPI-25, manufactured by Nippon Emulsion Co., Ltd.)
Polyethylene glycol 300000 0.5
Erythritol 30.0
Propylene glycol 5.0
Hydroxyethanediphosphonic acid 0.2
Fragrance D 0.1
Purified water balance <br/> Total 100.0
The above composition was adjusted to pH 5.5 to 6.0 and filled into an arbitrary container (tube, jar container, etc.) to obtain a product.

[Example 5 ]
Body soap composition (%)
Potassium myristate 12.0
Potassium palmitate 3.0
Lauryldimethylaminoacetic acid betaine 4.5
(Amogen SH, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.)
Maltitol 35.0
Propylene glycol 7.0
Acrylic acid / alkyl copolymer emulsion 1.0
(Leoir MS-200, manufactured by Lion Chemical Co., Ltd.)
Dimethyldiallylammonium chloride / acrylamide copolymer 0.2
(Kayakrill Resin M-50, manufactured by Nippon Kayaku)
Edetate tetrasodium 0.1
Hydroxyethane diphosphonic acid 0.1
Fragrance A 0.7
Purified water balance <br/> Total 100.0
The above composition was adjusted to pH 10.0 with potassium hydroxide and filled into an arbitrary container (bottle, pump bottle, bag-like container, etc.) to obtain a product.

[ Reference Example 22 ]
Pump type foam discharge container filling Liquid cleansing composition (%)
Potassium myristate 3.5
Amidopropyl betaine laurate 2.0
(Softazolin LPB-R, manufactured by Kawaken Fine Chemicals Co., Ltd.)
Lactitol 10.0
Sorbitol 15.0
Propylene glycol 15.0
POE (2) Palm oil fatty acid monoethanolamide 3.0
(Amidette 2CY Kawaken Fine Chemical Co., Ltd.)
Edetic acid 0.1
Hydroxyethane diphosphonic acid 0.1
Fragrance A 1.0
Purified water balance <br/> Total 100.0
The composition was adjusted to pH 10.0 with potassium hydroxide and filled into a pump-type foam discharge container to obtain a product.

[ Reference Example 23 ]
Liquid face wash composition (%)
Potassium laurate 0.8
Potassium myristate 6.0
Potassium palmitate 1.0
Lauric acid amidopropyl betaine 3.0
(Softazolin LPB-R, manufactured by Kawaken Fine Chemicals Co., Ltd.)
Maltitol 10.0
Sorbitol 15.0
Propylene glycol 10.0
Hydroxypropyl methylcellulose 0.2
(HPMC60SH-4000 manufactured by Shin-Etsu Chemical Co., Ltd.)
POE (2) Palm oil fatty acid monoethanolamide 2.0
(Amidette 2CY made by Kawaken Fine Chemical)
Hydroxyethanediphosphonic acid 0.2
Fragrance A 1.0
Purified water balance <br/> Total 100.0
The above composition was adjusted to pH 10.0 with potassium hydroxide and filled into an arbitrary container (bottle, pump bottle, bag-like container, etc.) to obtain a product.

[ Reference Example 24 ]
Facial cleansing foam composition (%)
Lauric acid 0.5
Myristic acid 14.0
Palmitic acid 11.0
Stearic acid 3.0
Potassium hydroxide 5.5
Dimethyldiallylammonium chloride / acrylamide copolymer solution 0.2
(Kayakrill Resin M-50, manufactured by Nippon Kayaku Co., Ltd.)
Lauryldimethylaminoacetic acid betaine 3.0
(Amogen SH, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.)
POE (3) polyoxyethylene glyceryl isostearate 2.0
(EMALEX GWIS-103, manufactured by Nippon Emulsion Co., Ltd.)
POE (5) monostearate polyoxyethylene glycerin 2.0
(EMALEX GM-5, manufactured by Nippon Emulsion Co., Ltd.)
1,3-butylene glycol 8.0
Sorbitol 30.0
Hydroxyethanediphosphonic acid 0.15
Fragrance B 0.2
Purified water balance <br/> Total 100.0
The composition was adjusted to pH 8.5 to 9.0 and filled into an arbitrary container (tube, jar container, etc.) to obtain a product.

According to the said composition, the cleaning composition of Examples 3-5 and Reference Examples 15-24 was prepared according to the conventional method of each formulation. For these, as in Examples 1 and 2 and Reference Examples 1 to 14 , when foaming in hard water, squeaky feeling at the time of rinsing, lack of stickiness, and lack of feeling of squeezing after washing were evaluated, both were effective. It was excellent. Incidentally, perfumes used above clean is a part of the disclosure of this specification by reference a list of [0027] to [0045], wherein the JP 2002-128658.

Claims (3)

(A) A tetrahydric or higher sugar alcohol selected from sorbitol, xylitol, mannitol, erythritol, lactitol, and maltitol 35 to 45% by mass
(B) C14 or more fatty acid and / or its salt 3-35 mass%
(C) C12 or less fatty acid and / or salt thereof less than 1% by mass,
(D) One or more compounds selected from edetic acid, edetate, hydroxyethane diphosphonic acid and hydroxyethane diphosphonate 0.01-2% by mass
A skin cleanser composition comprising:   The skin cleanser composition according to claim 1, further comprising polyoxyethylene coconut oil fatty acid monoethanolamide. 3. A skin cleanser composition according to claim 1 or 2, which is a liquid skin cleanser composition or a cream facial cleanser.