JP5071351B2 - Method for manufacturing resin liner and method for manufacturing fluid storage container - Google Patents
Method for manufacturing resin liner and method for manufacturing fluid storage container Download PDFInfo
- Publication number
- JP5071351B2 JP5071351B2 JP2008286057A JP2008286057A JP5071351B2 JP 5071351 B2 JP5071351 B2 JP 5071351B2 JP 2008286057 A JP2008286057 A JP 2008286057A JP 2008286057 A JP2008286057 A JP 2008286057A JP 5071351 B2 JP5071351 B2 JP 5071351B2
- Authority
- JP
- Japan
- Prior art keywords
- liner
- liner assembly
- pressure
- laser
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 69
- 239000011347 resin Substances 0.000 title claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000012530 fluid Substances 0.000 title claims description 10
- 238000003860 storage Methods 0.000 title claims description 10
- 238000003466 welding Methods 0.000 claims abstract description 55
- 238000005304 joining Methods 0.000 claims abstract description 13
- 238000002834 transmittance Methods 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 abstract description 9
- 239000000853 adhesive Substances 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 27
- 239000001257 hydrogen Substances 0.000 description 27
- 229910052739 hydrogen Inorganic materials 0.000 description 27
- 239000003822 epoxy resin Substances 0.000 description 6
- 229920000647 polyepoxide Polymers 0.000 description 6
- 229920002292 Nylon 6 Polymers 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 239000004918 carbon fiber reinforced polymer Substances 0.000 description 3
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- 238000003825 pressing Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- -1 aluminum Chemical class 0.000 description 2
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- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
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- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
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Images
Classifications
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- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/54—Joining several hollow-preforms, e.g. half-shells, to form hollow articles, e.g. for making balls, containers; Joining several hollow-preforms, e.g. half-cylinders, to form tubular articles
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1629—Laser beams characterised by the way of heating the interface
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C66/01—General aspects dealing with the joint area or with the area to be joined
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C66/80—General aspects of machine operations or constructions and parts thereof
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- B29C66/8126—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the composition, by the structure, by the intensive physical properties or by the optical properties of the material constituting the pressing elements, e.g. constituting the welding jaws or clamps characterised by the intensive physical properties or by the optical properties of the material constituting the pressing elements, e.g. constituting the welding jaws or clamps
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- B29L2031/7154—Barrels, drums, tuns, vats
- B29L2031/7156—Pressure vessels
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
Description
この発明は、流体貯留容器に関する。 The present invention relates to a fluid storage container.
ガスタンクの中には、樹脂製の内殻(以下、「樹脂ライナ」という。)を備えるものがある。樹脂ライナは、成型の都合上、複数のライナ部品を、レーザ溶着により接合して完成される構造になっているものが多い。以下、各ライナ部品において、レーザ溶着により接合される箇所を、「接合部」ともいう。 Some gas tanks have a resin inner shell (hereinafter referred to as “resin liner”). Many resin liners have a structure in which a plurality of liner parts are joined by laser welding for the convenience of molding. Hereinafter, in each liner component, a portion to be joined by laser welding is also referred to as a “joint portion”.
レーザ溶着により樹脂部品を接合する場合には、各樹脂部品の接合部を、適度な圧力で押し付ける必要がある。そこで、従来は、ライナ部品の接合部が接触するように組み合わせた状態で、その内部と外部の圧力差を設けることによって、接合部を適度な圧力で押し付けた状態にして、レーザ溶着を行う技術が提案されている(例えば、特許文献1参照)。 When joining resin parts by laser welding, it is necessary to press the joining part of each resin part with an appropriate pressure. Therefore, conventionally, a technique for performing laser welding in a state where the joint part of the liner part is in contact with each other and a pressure difference between the inside and the outside is provided to press the joint part with an appropriate pressure. Has been proposed (see, for example, Patent Document 1).
しかしながら、上記した特許文献1に記載された方法では、レーザ溶着により接合された接合部に、充分な接着強度が得られないという問題があった。なお、このような問題は、内部に液体を貯留するタンクを含め、種々の流体貯留容器に用いられる樹脂ライナに共通する問題であった。
However, the above-described method described in
そこで、本発明は、このような課題に鑑みてなされたものであり、複数のライナ部品の互いの接合部が接合されて成る樹脂ライナにおいて、接合部の接着強度を向上させる技術を提供することを目的とする。 Therefore, the present invention has been made in view of such a problem, and provides a technique for improving the adhesive strength of a joint portion in a resin liner in which joint portions of a plurality of liner parts are joined to each other. With the goal.
本発明は、上述の課題の少なくとも一部を解決するためになされたものであり、以下の形態又は適用例として実現することが可能である。 SUMMARY An advantage of some aspects of the invention is to solve at least a part of the problems described above, and the invention can be implemented as the following forms or application examples.
[適用例1] 流体貯留容器に用いられる樹脂ライナであって、複数のライナ部品の互いの接合部が接合されて成る前記樹脂ライナの製造方法であって、
(a)少なくとも2つの前記ライナ部品の互いの前記接合部を接触させた状態に組み合わせたライナ組立体を生成する工程と、
(b)前記ライナ組立体において、接触された前記接合部の少なくとも一部を、保持具によって、保持する工程と、
(c)密閉された前記ライナ組立体の内部の圧力を制御しつつ、レーザ溶着により、接触された前記接合部を接合する工程と、
を備え、
前記工程(c)は、前記圧力の制御において、
(c1)密閉された前記ライナ組立体の内部の圧力を前記ライナ組立体の外部の圧力よりも高い、第1の値に制御する工程と、
(c2)前記工程(c1)の後に、密閉された前記ライナ組立体の内部の圧力を前記第1の値よりも低く、前記ライナ組立体の外部の圧力よりも高い第2の値に制御する工程と、
を備える、樹脂ライナの製造方法。
[Application Example 1] A resin liner used for a fluid storage container, wherein the joint parts of a plurality of liner parts are joined to each other.
(A) generating a liner assembly that combines at least two of the liner parts in contact with each other;
(B) in the liner assembly, a step of holding at least a part of the contacted contact portion by a holder;
(C) joining the contacted joints by laser welding while controlling the pressure inside the sealed liner assembly;
With
In the step (c), in the control of the pressure,
(C1) controlling the pressure inside the sealed liner assembly to a first value higher than the pressure outside the liner assembly;
(C2) After the step (c1), the pressure inside the sealed liner assembly is controlled to a second value lower than the first value and higher than the pressure outside the liner assembly. Process,
A method for producing a resin liner.
この樹脂ライナの製造方法によれば、ライナ組立体の外圧よりも内圧が高くなるように制御すると共に、接合部を外部から保持具によって保持しているため、ライナ部品の互いの接合部の密着性が向上される。ライナ部品の互いの接合部が密着された状態で、レーザ溶着により接合部を接合(接着)することによって、接合部の接着強度が向上される。 According to this resin liner manufacturing method, the inner pressure is controlled to be higher than the outer pressure of the liner assembly, and the joint is held by the holder from the outside. Is improved. By bonding (bonding) the bonding parts by laser welding in a state where the bonding parts of the liner parts are in close contact with each other, the bonding strength of the bonding parts is improved.
また、工程(c)において、ライナの内圧を、第1の内圧から第2の内圧に下げることによって、接合部に過剰に圧力がかかることによるバリの生成を抑制することができる。 Further, in the step (c), by reducing the internal pressure of the liner from the first internal pressure to the second internal pressure, it is possible to suppress the generation of burrs due to excessive pressure applied to the joint portion.
[適用例2] 適用例1に記載の樹脂ライナの製造方法において、
前記工程(b)において、前記保持具は、互いの前記接合部が接触される接触面であって、前記ライナ組立体の内側から外側に向かう向きと交わる向きの接触面の全体を加圧するように配置され、
前記保持具は、レーザ透過性の材料より成る、樹脂ライナの製造方法。
[Application Example 2] In the method for producing a resin liner according to Application Example 1,
In the step (b), the holding tool pressurizes the entire contact surface, which is a contact surface with which the joints are brought into contact with each other, and intersects the direction from the inner side to the outer side of the liner assembly. Placed in
The method of manufacturing a resin liner, wherein the holder is made of a laser transmissive material.
このように、保持具を配置すると、レーザ光の照射経路の途中に保持具が入る場合が多い。このとき、レーザ透過性の保持具を用いると、レーザ光が保持具を透過するため、互いの接合部が接触される接触面にレーザ光を照射することが可能となる。互いの接合部が接触される接触面の全体を充分に加圧しつつレーザ光を照射することにより、接合部同士の接着強度をさらに向上させることができる。 As described above, when the holder is arranged, the holder often enters the middle of the laser light irradiation path. At this time, when a laser transmissive holder is used, the laser light is transmitted through the holder, so that it is possible to irradiate the laser beam onto the contact surface where the joint portions are in contact with each other. By irradiating the laser beam while sufficiently pressurizing the entire contact surface with which the joint portions are brought into contact with each other, the adhesive strength between the joint portions can be further improved.
[適用例3] 適用例1または2に記載の樹脂ライナの製造方法において、
前記工程(c)において、前記ライナ組立体が回転されることによって、全周にわたる前記接合部がレーザ溶着により接合される場合に、前記ライナ組立体の回転と関連付けて、前記ライナ組立体の内部の圧力を、前記第1の値から前記第2の値へと減圧するように制御する、樹脂ライナの製造方法。
[Application Example 3] In the method for producing a resin liner according to Application Example 1 or 2,
In the step (c), when the liner assembly is rotated so that the joint portion over the entire circumference is joined by laser welding, the inside of the liner assembly is associated with the rotation of the liner assembly. A method for manufacturing a resin liner, wherein the pressure is controlled so as to reduce the pressure from the first value to the second value.
このようにすると、ライナ組立体が回転されるため、例えば、レーザ光を発振するレーザ発振機を固定して、一定の方向にレーザを発振させれば、樹脂ライナの全周に亘る接合部を、容易にレーザ溶着することができる。例えば、ライナ組立体を3回転させることによって、接合部同士が完全に接合される場合に、ライナ組立体の内部の圧力を、1回転目は第1の値に制御して、2回転目と3回点目は第2の値に制御するというように、ライナ組立体の回転と関連付けてライナ組立体の内部の圧力を制御すると、ライナ組立体の内部の圧力を容易に制御することができる。 In this way, since the liner assembly is rotated, for example, if a laser oscillator that oscillates laser light is fixed and the laser is oscillated in a certain direction, the joint portion over the entire circumference of the resin liner is formed. Can be easily laser-welded. For example, when the joints are completely joined by rotating the liner assembly three times, the pressure inside the liner assembly is controlled to the first value for the first rotation, When the pressure inside the liner assembly is controlled in association with the rotation of the liner assembly, such as controlling the second time to the second value, the pressure inside the liner assembly can be easily controlled. .
[適用例4] 適用例2または3に記載の樹脂ライナの製造方法において、
接合される2つの前記ライナ部品は、レーザ透過率の高い第1のライナ部品と、レーザ透過率の低い第2のライナ部品とを含み、
前記レーザ溶着を行う際に、レーザ光は、前記保持具と、前記第1のライナ部品とを透過して、前記第2のライナ部品に到達するように照射される、樹脂ライナの製造方法。
[Application Example 4] In the method for producing a resin liner according to Application Example 2 or 3,
The two liner parts to be joined include a first liner part having a high laser transmittance and a second liner part having a low laser transmittance,
When performing the laser welding, the laser beam is irradiated so as to pass through the holder and the first liner part and reach the second liner part.
なお、本発明は、種々の形態で実現することが可能であり、例えば、流体貯留容器の製造方法等の形態で実現することができる。 In addition, this invention can be implement | achieved with various forms, for example, can be implement | achieved with forms, such as a manufacturing method of a fluid storage container.
A.実施例:
図1は、本発明の一実施例としての樹脂ライナの製造方法によって製造される樹脂ライナを有する流体貯留容器の一実施例としての高圧水素タンク100の概略構成を示す断面図である。図1では、高圧水素タンク100の中心軸に平行で中心軸を通る切断面で切断された断面図を示している。高圧水素タンク100の中心軸は、略円筒状を成す高圧水素タンク本体の円の中心を通る軸と一致する。本実施例において、高圧水素タンク100は、圧縮水素が充填されるためのものである。例えば、高圧水素タンク100は、圧縮水素が充填された状態で、燃料電池に水素を供給するために、燃料電池車に搭載される。
A. Example:
FIG. 1 is a cross-sectional view showing a schematic configuration of a high-
高圧水素タンク100は、樹脂ライナ10と、外殻20と、バルブ側口金30と、エンド側口金40と、バルブ50と、を備える。樹脂ライナ10は、ナイロン樹脂から成り、内部に水素が充填される空間を備える中空状に形成される。樹脂ライナ10は、水素が外部に漏れないように内部空間を密閉する性質(以下、「ガスバリア性」ともいう。)を有する。樹脂ライナ10は、バルブ側ライナ部品10vと、エンド側ライナ部品10eとを備え、後に詳述するように、バルブ側ライナ部品10vと、エンド側ライナ部品10eとを、レーザ溶着により接合して生成される。
The high-
外殻20は、樹脂ライナ10の外周を覆うように形成される。外殻20は、繊維強化プラスチックとしてのCFRP(Carbon Fiber Reinforced Plastics)から成り、フィラメントワインディング法(以下、「FW法」ともいう。)により形成される。外殻20は、耐圧性を有する。本実施例において、プラスチックとしては、エポキシ樹脂が用いられている。
The
バルブ側口金30は、略円筒状を成し、樹脂ライナ10と外殻20との間に嵌入されて、固定されている。バルブ側口金30の略円柱状の開口が、高圧水素タンク100の開口として機能する。本実施例において、バルブ側口金30は、ステンレスから成るが、アルミニウム等他の金属から成るものであってもよいし、樹脂製でもよい。バルブ50は、円柱状の部分に、雄ねじが形成されており、バルブ側口金30の内側面に形成されている雌ねじに螺合されることにより、バルブ50によって、バルブ側口金30の開口が閉じられる。エンド側口金40は、アルミニウムから成り、一部分が外部に露出した状態で組みつけられ、タンク内部の熱を、外部に導く働きをするものである。
The
図2は、バルブ側ライナ部品10vとエンド側ライナ部品10eの断面構成を概略的に示す断面図である。図2も、図1と同様に、高圧水素タンク100の中心軸に平行で中心軸を通る切断面で切断された断面図を示している。バルブ側ライナ部品10vと、エンド側ライナ部品10eとは、樹脂ライナ10を長手方向に垂直に2分割したような形状を成す。
FIG. 2 is a cross-sectional view schematically showing a cross-sectional configuration of the valve
バルブ側ライナ部品10vは、円筒の一端が縮径した略釣鐘形状を成す。バルブ側ライナ部品10vの縮径した一端には、バルブ側口金30を圧入可能な口金圧入部14vが形成されている。バルブ側ライナ部品10vの他端には、エンド側ライナ部品10eの接合部12e(後述する)と接合される接合部12vが形成されている。
The valve
エンド側ライナ部品10eも、バルブ側ライナ部品10vと同様に、円筒の一端が縮径した略釣鐘形状を成す。エンド側ライナ部品10eの縮径した一端には、エンド側口金40を圧入可能な口金圧入部14eが形成されている。エンド側ライナ部品10eの他端には、バルブ側ライナ部品10vの接合部12vと接合される接合部12eが形成されている。接合部12vと接合部12eとは、図2に拡大して示すように、組み合わせると、互いに嵌合するような形状に形成されている。図2に矢印で示すように、バルブ側ライナ部品10vの接合部12vと、エンド側ライナ部品10eの接合部12eとが接触するように組み合わせて、接触された接合部を、レーザ溶着により接合することにより、樹脂ライナ10が完成する。
Similarly to the valve
バルブ側ライナ部品10vは、レーザ透過性を有するレーザ透過性樹脂部品であり、エンド側ライナ部品10eは、レーザ吸収性を有するレーザ吸収性樹脂部品である。本実施例において、バルブ側ライナ部品10vおよびエンド側ライナ部品10eは、共にナイロン6(PA6)から成る。エンド側ライナ部品10eは、ナイロン6に、黒色の顔料(着色料)を混入することにより、レーザ透過性を低減させて、レーザ吸収性樹脂部品として構成されている。
The valve-
図3は、高圧水素タンク100の製造工程を示すフローチャートである。まず、樹脂ライナ10を製造する(ステップS100)。樹脂ライナ10の製造工程については、後に詳述する。
FIG. 3 is a flowchart showing the manufacturing process of the high-
そして、FW法によって、外殻20を形成する。具体的には、ステップS100によって完成された樹脂ライナ10を、マンドレルとして用い、エポキシ樹脂を含浸させたカーボン繊維を、樹脂ライナ10の周囲に、巻き付ける(ステップS202)。その後、エポキシ樹脂を含浸させたカーボン繊維を、樹脂ライナ10の周囲に巻き付けたものを、加熱炉にて加熱して、エポキシ樹脂を硬化させる(ステップS204)。エポキシ樹脂が硬化すると、CFRPから成る外殻20が形成され、高圧水素タンク100が完成する。なお、外殻20を形成する場合に、加熱炉にて加熱する代わりに、大気中に放置して、エポキシ樹脂を硬化させてもよい。
Then, the
図4、5は、樹脂ライナ10の製造工程を示すフローチャートである。まず、バルブ側ライナ部品10vにバルブ側口金30を組み付け、エンド側ライナ部品10eにエンド側口金40を組み付ける(ステップS102)。各ライナ部品10v、10eの口金圧入部14e、14vに各口金30、40をそれぞれ圧入することによって、組み付けることができる。図4では、エンド側ライナ部品10eにエンド側口金40を組み付ける図を省略している。なお、ステップS102の後に、アニール処理を行なう工程を設けても良い。アニール処理を行うことにより、バルブ側ライナ部品10v、エンド側ライナ部品10eの寸法が安定する。また、アニール処理を行うことにより、バルブ側ライナ部品10v、エンド側ライナ部品10eに含まれる水分が蒸発するため、溶着し易くなり、接着強度が向上する。
4 and 5 are flowcharts showing the manufacturing process of the
そして、口金が組み付けられたバルブ側ライナ部品10vの接合部12vと、エンド側ライナ部品10eの接合部12eとを、図2に示すように嵌合させて、バルブ側ライナ部品10vとエンド側ライナ部品10eとを組み付ける(ステップS104)。以下、バルブ側ライナ部品10vとエンド側ライナ部品10eとを組み付けたものを、「ライナ組立体10b」という。
Then, the
その後、接合部12vと接合部12eとを嵌合させた部分に被せるように、ライナ組立体10bに治具200を取り付ける(ステップS106)。治具200は、バルブ側ライナ部品10vとエンド側ライナ部品10eとの接合部を、外部から押さえて、適度な圧力を加えるための治具である。
Thereafter, the
図6は、治具200の構成を概略的に示す図である。図6には、治具200の構成を説明するために、治具200と共に、ライナ組立体10bを図示している。図6(A)、(C)では、治具200を、ライナ組立体10bに嵌めた状態を、バルブ側ライナ部品10v側から見て示し、図6(B)、(D)では、ライナ組立体10bに嵌めた状態を、10bの側面から見て示す。
FIG. 6 is a diagram schematically showing the configuration of the
図6(A)に示すように、治具200は、四等分された環状を成す分割環202を4つと、各分割環202を接続するためのねじ204を4本、備える。ねじ204によって、分割環202が互いに離間した状態で接続することができる(図6(A))。図6(A)、(B)に示すように、各分割環202が離間して接続された状態で、治具200の内径は、バルブ側ライナ部品10vの外形よりも大きくなるように構成されている。したがって、治具200を各分割環202を離間した状態にして、その輪の中にライナ組立体10b通すことができる(図6(A)、(B))。
As shown in FIG. 6 (A), the
また、ねじ204を締めると、隣り合う分割環202が接触して、全体として環状を成す(図6(C))。分割環202の一方の端には、ねじ204が螺合されるねじ山が形成された孔が形成されている。そして、分割環202の他方の端には、外部から六角レンチ等でねじ204を締めるための貫通孔が形成されている。この貫通孔は、ねじ204のねじ山が嵌合するように形成されている。4つの分割環202の、ねじ山が形成されている一端と、貫通孔が形成されている他端とを、それぞれ向かい合わせて、ねじ204で締め付けることにより、図6(C)に示すように、環状を成す治具200が完成する。
When the
治具200は、環状になったときに(図6(C))、バルブ側ライナ部品10vとエンド側ライナ部品10eとの接合部を外部から適度な圧力で押さえることができるように構成されている(図6(C)、(D))。なお、治具200が環状になったときに、バルブ側ライナ部品10vとエンド側ライナ部品10eとの接合部を、外側から単に保持するように構成してもよい。単に保持するような構成にしても、ライナ組立体10bの内圧によって、バルブ側ライナ部品10vとエンド側ライナ部品10eとの接合部は、押圧される。
The
本実施例において、治具200はガラス製である。ガラスは、レーザ透過性が高いため、治具200の上からレーザ光を照射しても、レーザ光は、治具200を透過して、その下の部品に到達する。したがって、接合部12vと接合部12eとが組み合わされた部分を、覆うように治具200を取り付けて、接合部12v、12eを直接押圧しても、レーザ溶着により、接合部12vと接合部12eとを接合することができる。
In this embodiment, the
治具200がライナ組立体10bに取り付けられると(図4:ステップS106)、ライナ組立体10b内部の圧力(以下、「内圧」ともいう)を、第1の値P1に制御しながら、レーザ溶着を行なう(ステップS108)。図4のステップS108の欄に図示するように、本実施例において、レーザ溶着にて接合部12vと接合部12eとを、接合する場合には、ライナ組立体10bを回転させつつ、レーザ発振装置300によって、レーザ光を照射する。
When the
また、図5に示すように、バルブ側口金30には、配管402が接続され、配管402には、エアポンプ404と、圧力計406とが設けられている。このように、配管402およびエアポンプ404を設けることにより、ライナ組立体10bが密閉される。エアポンプ404によって、ライナ組立体10b内に、空気を送り込むことによって、ライナ組立体10b内の圧力を、ライナ組立体10bの外部の圧力(大気圧)よりも高い、第1の値P1に制御することができる。なお、圧力計406によって、ライナ組立体10bの内圧を確認することができる。ライナ組立体10bの内圧は、人が、圧力計406を視認しながら、エアポンプ404を操作することによって、制御する構成にしてもよいし、圧力計406による検出値に基づいて、コンピュータを用いて自動的に制御する構成にしてもよい。
As shown in FIG. 5, a
また、ライナ組立体10bを回転させるための装置としては、フィラメントワインディング装置を利用することができる。なお、ライナ組立体10bを、フィラメントワインディング装置に設置するときに、回転軸10c方向に、バルブ側ライナ部品10vとエンド側ライナ部品10eとが互いに押し合うような向きに力が加わるように、設置する。このようにすると、接合部12vと接合部12eには、回転軸10c方向に力が加わると共に、ライナ組立体10bの内部圧力と、治具200による外部圧力が加わるため、接合部12vと接合部12eとの嵌合状態が強固に保たれる。
Further, a filament winding apparatus can be used as an apparatus for rotating the
本実施例では、接合部12vと接合部12eとをレーザ溶着により接合するために、ライナ組立体10bを3回転させる。ライナ組立体10bを1回転させる度に、レーザ光の照射位置を変更する。ライナ組立体10bの1回転目のレーザ溶着を「レーザ溶着1」、そのレーザ光照射位置を「照射位置1」、ライナ組立体10bの2回転目のレーザ溶着を「レーザ溶着2」、そのレーザ光照射位置を「照射位置2」、ライナ組立体10bの3回転目のレーザ溶着を「レーザ溶着3」、そのレーザ光照射位置を「照射位置3」という。
In this embodiment, the
図7は、レーザ光照射位置を概略的に示す説明図である。図7(A)は照射位置1、(B)は照射位置2、(C)は照射位置3を示す。図7(A)〜(C)は、それぞれ、図5に示すように、ライナ組立体10bの回転軸10cが水平になるようにライナ組立体10bを配置した場合の、ライナ組立体10bの回転軸10cを通り、回転軸10cに平行な切断面で切断した断面図と、レーザ発振装置300側から見た図を示している。
FIG. 7 is an explanatory diagram schematically showing a laser beam irradiation position. 7A shows the
図7(A)に示すように、治具200は、接合部12vと接合部12eとが接触する部分を、覆って、直接、外側から押圧するように取り付けられている。接合部12vと接合部12eとが接触する接触面は、ライナ組立体10b内に充填された空気によってライナ組立体10bの内部から加えられる圧力と、治具200によって外部から加えられる圧力とによって、密着されている。すなわち、接合部12vと接合部12eと間の隙間は、小さい。
As shown in FIG. 7A, the
なお、後述するように、バルブ側ライナ部品10vとエンド側ライナ部品10eとがレーザ溶着により接合された後、図7(A)に破線で示すように、ライナ組立体10bの外側に突出した部分(以下、「リブ」ともいう。)は、切削される。そのため、接合部12vと接合部12eとの接触面のうち、破線よりもライナ組立体10bの内部よりの部分が溶着されればよい。以下、接合部12vと接合部12eとの接触面のうち、破線よりもライナ組立体10bの内部よりの部分であって、レーザ溶着により溶着される面を、「溶着面12w」という。本実施例において、治具200は、溶着面の大部分を加圧するのに必要な幅に形成されている。しかしながら、治具200は、溶着面の少なくとも一部を加圧可能な幅に形成されていればよく、溶着面全体を加圧可能な幅に形成されていてもよいし、溶着面全体を加圧可能な幅よりも広い幅に形成されていてもよい。なお、本実施例における溶着面12wが、請求項における接触面に相当する。
As will be described later, after the valve-
レーザ溶着1において、レーザ光は、溶着面の、回転軸10c(図5)方向の長さの真ん中辺りに照射される(図7(A))。レーザ溶着2において、レーザ光は、接合部12eの先端近傍に照射される(図7(B))。レーザ溶着3において、レーザ光は、接合部12vの先端近傍に照射される(図7(C))。このように、レーザ光の照射位置をずらすことによって、溶着面の全体が溶着される。
In the
図5に示すように、ステップS108において、レーザ溶着1が終了すると(すなわち、ライナ組立体10bが1回転すると)、ライナ組立体10bの内圧を、第2の値P2に制御しながら、レーザ光の照射位置を照射位置2に変更して、レーザ溶着2を行なう(図5:ステップS110)。第2の値P2は、第1の値P1よりも低く、ライナ組立体10bの外圧(大気圧)よりも高い値である。例えば、第1の値P1=1.0MPa、第2の値P2=0.5MPaとするのが好ましい。ライナ組立体10bの内圧を、低下させることによって、バリの発生を抑制することができる。
As shown in FIG. 5, in step S108, when
ライナ組立体10bが1回転してレーザ溶着2が終了すると、ライナ組立体10bの内圧を、第2の値P2に維持したまま、レーザ溶着3を行なう(ステップS110)。レーザ溶着3が終了すると、リブを切削する(ステップS112)。上記したように、図7(A)に切削面が破線で図示されている。リブを切削することにより、図1に示すように、表面に、ほぼ凸凹のない、樹脂ライナ10が完成する。
When the
本実施例の樹脂ライナの製造方法では、バルブ側ライナ部品10vとエンド側ライナ部品10eとをレーザ溶着する際に、ライナ組立体10b内に空気を充填することによって、ライナ組立体10bの内部に圧力をかけている。それと共に、治具200によって、バルブ側ライナ部品10vとエンド側ライナ部品10eとの接触部(すなわち、接合部12v、12eが接触する部分)に、外部から圧力をかけている。そのため、接合部12vと接合部12eとの接触面の隙間が小さくなる。したがって、レーザ溶着により接合部12vと接合部12eとを接合すると、接着強度が向上される。
In the resin liner manufacturing method of this embodiment, when the valve
また、従来は、レーザ透過性の低い、またはレーザ透過性の無い金属製の治具を用いて、接合部12v、12eに、外部から圧力をかけていた。金属製の治具を用いる場合、接合部12vと接合部12eとを組み付けた部分を覆うように治具を取り付けて、外側から押圧すると、レーザが治具を透過しないため、レーザ溶着をすることができない場合がある。そのため、接合部12v、接合部12eから離れた部分に治具を取り付けて外部から押圧することによって、間接的に、接合部12vと接合部12eとの接触面に外部から圧力を加えていた。
Further, conventionally, pressure is applied to the
治具が、接合部12v、12eから離れて取り付けられていると、接合部12vと接合部12eとの接触面の隙間が大きくなり、レーザ溶着した場合に、充分な接着強度が得られない。これに対して、本実施例では、レーザ透過性の高いガラス製の治具200を用いているため、接合部12vと接合部12eとを組み付けた部分を、覆うように治具200を取り付けても、レーザ溶着をすることが可能になった。そのため、接着強度を向上させることができる。
If the jig is mounted apart from the
上記したように、本実施例では、ライナ組立体10bに内圧をかけつつ、外部から治具200で、押圧することにより、接合部12vと接合部12eとの接触面(特に、溶着面12w)の密着性を向上させている。ライナ組立体10bの内部からも外部からも圧力をかけているため、レーザによって、レーザ吸収性部品であるエンド側ライナ部品10eが溶融すると、ライナ組立体10b内の圧力と、治具200による圧力とによって、溶融した樹脂が押し出され、バリが発生するおそれがある。
As described above, in this embodiment, the inner surface of the
例えば、ライナ組立体10bの内側にバリを有する樹脂ライナ10を用いて、高圧水素タンク100が生成され、使用された場合に、バリがちぎれて、高圧水素タンク100内に存在すると、異音が発生したり、水素経路内にちぎれたバリが詰まることがある。また、高圧水素タンク100は、高圧水素タンク100内の水素量を測定するために、温度センサ(図示しない)を備えているが、ちぎれたバリによって温度センサが損傷するおそれもある。これに対して、本実施例の樹脂ライナの製造方法では、ライナ組立体10bの内圧を、第1の値P1に制御しつつレーザ溶着1を行なった後、ライナ組立体10bの内圧を、第2の値P2に下げて、レーザ溶着2、3を行なう。そのため、接合部12vと接合部12eとの密着性を維持しつつ、バリの発生を抑制することができる。
For example, when the high-
また、本実施例では、接合部12vと接合部12eとの接着強度を向上するために、ライナ組立体10bの内部から圧力をかけつつ、治具200によって、接合部12vと接合部12eとが接触する部分を、直接押圧して、外部から圧力をかけている。したがって、上記した特許文献1に記載されているようなチャンバーを用いなくても、接着強度を向上することができる。したがって、設備を簡素化して、安価に樹脂ライナ10を製造することができる。
Further, in this embodiment, in order to improve the adhesive strength between the
B.変形例:
なお、この発明は上記の実施例や実施形態に限られるものではなく、その要旨を逸脱しない範囲において種々の態様において実施することが可能であり、例えば次のような変形も可能である。
B. Variations:
The present invention is not limited to the above-described examples and embodiments, and can be implemented in various modes without departing from the gist thereof. For example, the following modifications are possible.
(1)バルブ側ライナ部品10vの接合部12vの形状と、エンド側ライナ部品10eの接合部12eの形状は、上記した実施例に限定されず、バルブ側ライナ部品10vとエンド側ライナ部品10eとをレーザ溶着にて接合可能な形状であればよい。図8は、接合部12v、接合部12eの形状の各種の変形例を示す断面図である。接合部12vと接合部12eとは、互いに密着して組み合わせられるような種々の形状に形成可能である。そして、接合部12v、12eを外側から押圧するように治具200を取り付けて、図に破線で示すように、治具200とバルブ側ライナ部品10vを透過して、エンド側ライナ部品10eに到達するように、レーザ光を照射すれば、上記した実施例と同様の効果を得ることができる。
(1) The shape of the
(2)上記した実施例において、流体貯留容器の一例として、高圧水素タンクを例示したが、高圧水素タンクに限定されない。本発明の製造方法は、例えば、窒素、アルゴン、プロパンガス等を貯留する容器や、液体の燃料等を貯留する容器にも用いることができる。 (2) In the above-described embodiment, the high pressure hydrogen tank is illustrated as an example of the fluid storage container, but is not limited to the high pressure hydrogen tank. The production method of the present invention can be used, for example, for a container for storing nitrogen, argon, propane gas or the like, or a container for storing liquid fuel or the like.
(3)上記した実施例において、樹脂ライナ10は、バルブ側ライナ部品10vとエンド側ライナ部品10eとをレーザ溶着により接合することによって形成されているが、2以上の部品をレーザ溶着により接合することによって形成されるものであってもよい。また、上記した実施例において、樹脂ライナ10を、中心軸に垂直な平面で、2分割したような形状の2つの部品を接合して、樹脂ライナ10が形成されるが、例えば、中心軸を通り、中心軸に平行な平面で2分割したような形状の部品を接合してもよい。
(3) In the embodiment described above, the
(4)上記した実施例において、接合部12vと接合部12eとをレーザ溶着により接合する場合に、ライナ組立体10bを回転させることによって、接触面の全周にレーザを照射しているが、ライナ組立体10bは回転させず、レーザ発振装置300がライナ組立体10bの周囲を周る構成にしてもよい。
(4) In the above-described embodiment, when the joining
(5)ライナ組立体10bの内圧を、第1の値P1から第2の値P2に低下させるタイミングは、上記した実施例に限定されない。例えば、予め、実験により、バリの発生が抑制されるタイミング(時間)を計り、レーザ溶着の開始から一定の時間が経過した後に、ライナ組立体10bの内圧を第1の値P1から第2の値P2に低下させるようにしてもよい。このとき、ライナ組立体10bの回転と、ライナ組立体10bの内圧を、第1の値P1から第2の値P2に低下させるタイミングを関連付けてもよいし、関連付けなくてもよい(例えば、1回転する途中で、内圧を低下させてもよい。)。
(5) The timing at which the internal pressure of the
(6)また、上記した実施例では、ガラス製の治具200を用いているが、ガラス製に限定されず、例えば、ポリカーホネートや、ナイロン6等のレーザ透過性の高い材料を用いてもよい。さらに、レーザ透過性の高い治具200に限定されず、レーザ透過性の低い治具や、レーザ透過性のない治具を用いてもよい。例えば、レーザ透過性のない治具を用いる場合には、接合部12v、12eを覆うように治具を取り付けても、治具を回避して、レーザ光が接触面に照射されるように、接合部12v、12eの形状や、レーザ光の照射方向を決定すればよい。このようにしても、接合部の接着強度を向上することができる。
(6) Moreover, in the above-mentioned Example, although the jig |
(7)なお、バルブ側ライナ部品10vとエンド側ライナ部品10eの原料は、上記した実施例に限定されない。バルブ側ライナ部品10vとエンド側ライナ部品10eは、ともに、ガスバリア性を有し、一方がレーザ透過性、他方がレーザ吸収性を有することが好ましい。レーザ吸収性樹脂部品を形成する場合には、必ずしも顔料にて着色する必要はなく、レーザ透過性樹脂部品よりもレーザ透過性の低い樹脂によって形成すればよい。すなわち、バルブ側ライナ部品10vとエンド側ライナ部品10eとの一方がレーザ透過性、他方がレーザ吸収性とするためには、レーザ透過性が異なっていればよい。例えば、エンド側ライナ部品10eとして、ナイロン6よりもレーザ透過性の低い樹脂(例えば、ポリエチレン(PE)やアクリロニトリルブタジエンスチレン(ABS)等)を用いてもよい。また、これらの樹脂に、ガラス繊維等の補強繊維を添加したものを用いてもよい。
(7) The raw materials of the valve
また、バルブ側ライナ部品10v、エンド側ライナ部品10e共に、着色したい場合には、着色料の粒径や、着色料の含有量を調整することによって、レーザ透過性の差を設けるようにしてもよい。
Further, when both the valve
また、本実施例では、バルブ側ライナ部品10vの全体をレーザ透過性樹脂部品、エンド側ライナ部品10eの全体をレーザ吸収性樹脂部品として構成しているが、接合部12v、12eのみをレーザ透過性とレーザ吸収性の組合せになるように構成してもよい。例えば、エンド側ライナ部品10eの接合部12eのみをレーザ吸収性を有するように構成し、他の部分およびバルブ側ライナ部品10vをレーザ透過性として構成してもよい。
In this embodiment, the entire valve
さらに、バルブ側ライナ部品10vとエンド側ライナ部品10eとは、共に、レーザ吸収性樹脂部品であってもよいし、共に、レーザ透過性樹脂部品であってもよい。
Furthermore, both the valve
10…樹脂ライナ
10b…ライナ組立体
10c…回転軸
10e…エンド側ライナ部品
10v…バルブ側ライナ部品
12e、12v…接合部
12w…溶着面
14e、14v…口金圧入部
20…外殻
30…バルブ側口金
40…エンド側口金
50…バルブ
100…高圧水素タンク
200…治具
202…分割環
204…ねじ
300…レーザ発振装置
402…配管
404…エアポンプ
406…圧力計
DESCRIPTION OF
Claims (5)
(a)少なくとも2つの前記ライナ部品の互いの前記接合部を接触させた状態に組み合わせたライナ組立体を生成する工程と、
(b)前記ライナ組立体において、接触された前記接合部の少なくとも一部を、保持具によって、保持する工程と、
(c)前記ライナ組立体の内部の圧力を制御しつつ、レーザ溶着により、接触された前記接合部を接合する工程と、
を備え、
前記工程(c)は、前記圧力の制御において、
(c1)前記ライナ組立体の内部の圧力を前記ライナ組立体の外部の圧力よりも高い、第1の値に制御する工程と、
(c2)前記工程(c1)の後に、前記ライナ組立体の内部の圧力を前記第1の値よりも低く、前記ライナ組立体の外部の圧力よりも高い第2の値に制御する工程と、
を備える、樹脂ライナの製造方法。 A resin liner used for a fluid storage container, wherein the joint portions of a plurality of liner parts are joined to each other.
(A) generating a liner assembly that combines at least two of the liner parts in contact with each other;
(B) in the liner assembly, a step of holding at least a part of the contacted contact portion by a holder;
(C) bonding the contacted joints by laser welding while controlling the pressure inside the liner assembly;
With
In the step (c), in the control of the pressure,
(C1) controlling the pressure inside the liner assembly to a first value higher than the pressure outside the liner assembly;
(C2) after the step (c1), controlling the pressure inside the liner assembly to a second value lower than the first value and higher than the pressure outside the liner assembly;
A method for producing a resin liner.
前記工程(b)において、前記保持具は、互いの前記接合部が接触される接触面であって、前記ライナ組立体の内側から外側に向かう向きと交わる向きの接触面の全体が加圧されるように配置され、
前記保持具は、レーザ透過性の材料より成る、樹脂ライナの製造方法。 In the manufacturing method of the resin liner of Claim 1,
In the step (b), the holder is a contact surface with which the joints are brought into contact with each other, and the entire contact surface in a direction intersecting with the direction from the inner side to the outer side of the liner assembly is pressurized. Arranged so that
The method of manufacturing a resin liner, wherein the holder is made of a laser transmissive material.
前記工程(c)において、前記ライナ組立体が回転されることによって、全周にわたる前記接合部がレーザ溶着により接合される場合に、前記ライナ組立体の回転と関連付けて、前記ライナ組立体の内部の圧力を、前記第1の値から前記第2の値へと減圧するように制御する、樹脂ライナの製造方法。 In the manufacturing method of the resin liner of Claim 1 or 2,
In the step (c), when the liner assembly is rotated so that the joint portion over the entire circumference is joined by laser welding, the inside of the liner assembly is associated with the rotation of the liner assembly. A method for manufacturing a resin liner, wherein the pressure is controlled so as to reduce the pressure from the first value to the second value.
接合される2つの前記ライナ部品は、レーザ透過率の高い第1のライナ部品と、レーザ透過率の低い第2のライナ部品とを含み、
前記レーザ溶着を行う際に、レーザ光は、前記保持具と、前記第1のライナ部品とを透過して、前記第2のライナ部品に到達するように照射される、樹脂ライナの製造方法。 In the manufacturing method of the resin liner of Claim 2 or 3,
The two liner parts to be joined include a first liner part having a high laser transmittance and a second liner part having a low laser transmittance,
When performing the laser welding, the laser beam is irradiated so as to pass through the holder and the first liner part and reach the second liner part.
(a)少なくとも2つの前記ライナ部品の互いの前記接合部を接触させた状態に組み合わせたライナ組立体を生成する工程と、
(b)前記ライナ組立体において、接触された前記接合部の少なくとも一部を、保持具によって、保持する工程と、
(c)前記ライナ組立体の内部の圧力を制御しつつ、レーザ溶着により、接触された前記接合部を接合する工程と、
を備え、
前記工程(c)は、前記圧力の制御において、
(c1)前記ライナ組立体の内部の圧力を前記ライナ組立体の外部の圧力よりも高い、第1の値に制御する工程と、
(c2)前記工程(c1)の後に、前記ライナ組立体の内部の圧力を前記第1の値よりも低く、前記ライナ組立体の外部の圧力よりも高い第2の値に制御する工程と、
を備える、流体貯留容器の製造方法。 A method of manufacturing a fluid storage container, comprising a resin liner formed by joining the joint portions of a plurality of liner parts,
(A) generating a liner assembly that combines at least two of the liner parts in contact with each other;
(B) in the liner assembly, a step of holding at least a part of the contacted contact portion by a holder;
(C) bonding the contacted joints by laser welding while controlling the pressure inside the liner assembly;
With
In the step (c), in the control of the pressure,
(C1) controlling the pressure inside the liner assembly to a first value higher than the pressure outside the liner assembly;
(C2) after the step (c1), controlling the pressure inside the liner assembly to a second value lower than the first value and higher than the pressure outside the liner assembly;
A method for manufacturing a fluid storage container.
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