JP5010632B2 - Photodegradation odor masking agent for dairy products, dairy products containing the masking agent, and a method for masking photodegradation odors using the masking agent - Google Patents
Photodegradation odor masking agent for dairy products, dairy products containing the masking agent, and a method for masking photodegradation odors using the masking agent Download PDFInfo
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- JP5010632B2 JP5010632B2 JP2009047520A JP2009047520A JP5010632B2 JP 5010632 B2 JP5010632 B2 JP 5010632B2 JP 2009047520 A JP2009047520 A JP 2009047520A JP 2009047520 A JP2009047520 A JP 2009047520A JP 5010632 B2 JP5010632 B2 JP 5010632B2
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- masking agent
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- odor
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Landscapes
- Dairy Products (AREA)
Description
本発明は、乳製品の光劣化臭マスキング剤、該マスキング剤を含有する乳製品並びに該マスキング剤を利用する光劣化臭のマスキング方法に関するものである。 The present invention relates to a photodegradation odor masking agent for dairy products, a dairy product containing the masking agent, and a method for masking a photodegradation odor using the masking agent.
牛乳や発酵乳等に代表される乳製品は、タンパク質、脂肪、ビタミン、ミネラル等を含有し、栄養学的にバランスがよく、更にその良好な嗜好性から広く消費されている。また、近年、これらの乳製品に様々な機能性成分を配合した商品の開発も盛んに行われており、例えば、貧血等の原因となる鉄分不足を補うための鉄分強化乳製品(特許文献1)等を例示することができる。 Dairy products represented by milk and fermented milk contain proteins, fats, vitamins, minerals and the like, are well balanced nutritionally, and are widely consumed due to their good palatability. In addition, in recent years, products in which various functional ingredients are blended with these dairy products have been actively developed. For example, an iron-enriched dairy product for compensating for an iron deficiency causing anemia or the like (Patent Document 1). ) And the like.
これらの乳製品の多くは、一般に、小売店等でショーケースに陳列され、光照射下で販売されているが、光透過性容器に充填された乳製品の場合は、長時間強い光に曝されることにより、乳中に含有しているリボフラビンが光の照射により励起され、それに伴い、メチオニン、システインなどの含硫化合物の酸化が連鎖的に促されて、漬物臭様のオフフレーバー(以下、光劣化臭という)が発生し、風味が著しく劣化するという問題があった。 Many of these dairy products are generally displayed in showcases at retail stores and sold under light irradiation, but dairy products filled in light-transmitting containers are exposed to strong light for a long time. As a result, the riboflavin contained in the milk is excited by light irradiation, and along with this, the oxidation of sulfur-containing compounds such as methionine and cysteine is promoted in a chained manner, and the pickled odor-like off-flavor , Light-degraded odor), and the flavor is significantly deteriorated.
そこで、この光劣化臭の発生を抑制するための方法として、乳製品に0.1wt%以下のアスコルビン酸を添加して混合する方法(特許文献2)や、乳含有酸性飲料にルチン、モリン又はケルセチンのうち1種あるいは2種以上を添加する方法(特許文献3)が提案されている。 Therefore, as a method for suppressing the occurrence of this photodegradation odor, a method of adding and mixing 0.1 wt% or less ascorbic acid to a dairy product (Patent Document 2), or rutin, morin or a milk-containing acidic beverage A method of adding one or more of quercetin (Patent Document 3) has been proposed.
ところが、近年、多様化する乳製品においては、従前の方法では光劣化臭を抑制する効果が十分に得られない場合が生じており、また、栄養成分の一つである鉄分を強化した乳製品においては、ルチン等のポリフェノール系抗酸化剤を使用した場合に、色調が変化(黒色を帯びる)して商品価値を損なうという別途の問題も生じ、光劣化臭の抑制に有効な新たな手段の確立が求められていた。 However, in recent years, in diversified dairy products, there are cases where the effect of suppressing light-degraded odor cannot be sufficiently obtained by the conventional method, and dairy products in which iron, which is one of the nutritional components, is fortified. In the case of using a polyphenolic antioxidant such as rutin, there is another problem that the color tone changes (it takes on a black color) and impairs the product value. Establishment was required.
従って、本発明の課題は、多様化する乳製品においても、光照射により生じる光劣化臭を抑制することができる新規な光劣化臭マスキング手段を提供することである。更に詳細に言えば、本発明は、鉄分を強化した乳製品においても、色調変化を伴うことなく光照射により生じる光劣化臭を抑制することができる新規な光劣化臭マスキング剤や光劣化臭マスキング方法を提供することをその目的とするものである。 Accordingly, an object of the present invention is to provide a novel photodegradation odor masking means capable of suppressing a photodegradation odor caused by light irradiation even in diversified dairy products. More specifically, the present invention provides a novel photodegradation odor masking agent and photodegradation odor masking that can suppress the photodegradation odor caused by light irradiation without changing the color tone even in a dairy product reinforced with iron. Its purpose is to provide a method.
本発明者らは上記課題を解決するため、乳製品における光劣化臭をマスキングし得る化合物について鋭意検索を行ったところ、1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンよりなる群から選ばれる化合物が、優れた光劣化臭のマスキング効果を有することを見出した。 In order to solve the above-mentioned problems, the present inventors have conducted an extensive search for compounds capable of masking the photodegradation odor in dairy products. As a result, 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxy It has been found that a compound selected from the group consisting of furanones has an excellent masking effect on photodegradation odor.
そして、これらの化合物は、鉄分を強化した乳製品に配合しても、色調変化を伴うことなく、光劣化臭がマスキングできることを確認した。 And even if it mix | blended with the dairy products which strengthened iron content, these compounds confirmed that the photodegradation odor could be masked without accompanying a color change.
すなわち、本発明の要旨は、以下の(1)〜(7)である。
(1)1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンよりなる群から選ばれる化合物の1種以上を有効成分として含有することを特徴とする乳製品の光劣化臭マスキング剤。
(2)乳製品が鉄含有乳製品である(1)に記載の光劣化臭マスキング剤。
(3)乳製品又は鉄含有乳製品が光透過性容器に充填されたものである(1)又は(2)の何れかに記載の光劣化臭マスキング剤。
(4)(1)乃至(3)の何れかに記載の光劣化臭マスキング剤を含有せしめたことを特徴とする乳製品。
(5)1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンよりなる群から選ばれる1種以上の化合物各々の乳製品中における濃度が、0.000001〜10ppmとなるように、(1)乃至(3)の何れかに記載の光劣化臭マスキング剤を含有せしめたことを特徴とする(4)に記載の乳製品。
(6)(1)乃至(3)の何れかに記載の光劣化臭マスキング剤を乳製品に配合することを特徴とする光劣化臭のマスキング方法。
(7)光劣化臭マスキング剤を、1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンよりなる群から選ばれる1種以上の化合物の濃度として、0.000001〜10ppmとなるよう乳製品に配合することを特徴とする(6)に記載の劣化臭のマスキング方法。
That is, the gist of the present invention is the following (1) to (7).
(1) Photodegradation of a dairy product comprising at least one compound selected from the group consisting of 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxyfuranone as an active ingredient Odor masking agent.
(2) The photodegradation odor masking agent according to (1), wherein the dairy product is an iron-containing dairy product.
(3) The photodegradation odor masking agent according to any one of (1) and (2), wherein a dairy product or an iron-containing dairy product is filled in a light transmissive container.
(4) A dairy product comprising the photodegradation odor masking agent according to any one of (1) to (3).
(5) The concentration in the dairy product of each of one or more compounds selected from the group consisting of 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxyfuranone is 0.000001 to 10 ppm. As described above, the dairy product according to (4), wherein the photodegradation odor masking agent according to any one of (1) to (3) is contained.
(6) A photodegraded odor masking method comprising blending the photodegraded odor masking agent according to any one of (1) to (3) into a dairy product.
(7) As a concentration of one or more compounds selected from the group consisting of 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxyfuranone, 0.000001-10 ppm The deterioration odor masking method according to (6), which is blended in a dairy product so that
本発明のマスキング剤は、乳製品における光劣化臭に対し、優れたマスキング効果を有し、特に、鉄含有乳製品に配合した場合であっても、色調変化を伴うことなく、光劣化臭をマスキングすることができる。 The masking agent of the present invention has an excellent masking effect on the photodegradation odor in dairy products, and in particular, even when blended with iron-containing dairy products, the photodegradation odor is not accompanied by color change. Can be masked.
以下に、本発明を実施の形態に即して詳細に説明する。 Hereinafter, the present invention will be described in detail according to embodiments.
本発明の乳製品の光劣化臭マスキング剤(以下、「マスキング剤」ということがある)は、乳製品に配合することにより、光劣化臭をマスキングするものである。本発明の光劣化臭とは、乳製品が光照射されることにより発生する漬物臭様のオフフレーバーのことをいう。 The photodegradation odor masking agent (hereinafter sometimes referred to as “masking agent”) of the dairy product of the present invention masks the photodegradation odor by blending into the dairy product. The photodegradation odor of the present invention refers to a pickled odor-like off-flavor generated when a dairy product is irradiated with light.
本発明のマスキング剤は、1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンから選ばれる化合物の1種以上を有効成分とするものである。 The masking agent of the present invention comprises at least one compound selected from 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxyfuranone as an active ingredient.
ここで、1,3−オクタンジオールは、ほぼ無臭の化合物であり、リンゴやペアー等に含有しているものである。また、5−オクテン−1,3−ジオールは、お茶のような渋い香りを有する無色の化合物であり、リンゴやペアー等に含有しているものである。更に、ジメチルメトキシフラノンは、ドライフルーツやリキュールのような熟成された甘い香りを有する無色の化合物であり、リンゴ、ペアー、マンゴーフルーツ等に含有しているものである。 Here, 1,3-octanediol is an almost odorless compound and is contained in apples, pears and the like. Further, 5-octene-1,3-diol is a colorless compound having a bitter aroma like tea and contained in apples, pears and the like. Further, dimethylmethoxyfuranone is a colorless compound having a sweet aroma such as dried fruit and liqueur, and is contained in apples, pears, mango fruits and the like.
本発明のマスキング剤の有効成分である1,3−オクタンジオール、5−オクテン−1,3−ジオール又はジメチルメトキシフラノンは、何れも食品衛生法により食品への添加が認められているものであるが(厚生労働省食監発第0520002号の別添及び食安基発第0814001号の別添参照)、何れの化合物も乳製品に添加した場合における光劣化臭のマスキング作用は知られていない。 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxyfuranone, which are active ingredients of the masking agent of the present invention, are all approved to be added to food by the Food Sanitation Law. However, the masking action of the photodegradation odor when any compound is added to the dairy product is not known (see the attachment of the Ministry of Health, Labor and Welfare Food Supervision No. 05220002 and the attachment of the Food Safety Foundation No. 0881001).
本発明のマスキング剤の有効成分である1,3−オクタンジオール、5−オクテン−1,3−ジオール又はジメチルメトキシフラノンは、天然物からの抽出・精製、或いは、化学合成により得ることができ、いずれの方法で得られたものでも好適に使用することができる。 The active ingredient of the masking agent of the present invention, 1,3-octanediol, 5-octene-1,3-diol or dimethylmethoxyfuranone can be obtained by extraction / purification from natural products, or chemical synthesis, What was obtained by any method can be used conveniently.
例えば、天然物から抽出・精製して得る場合には、天然物を原料として、常法により抽出・精製すればよい。ここで原料として用いることができる天然物としては、1,3−オクタンジオール、5−オクテン−1,3−ジオール又はジメチルメトキシフラノンが含まれているものであればよく、特に制限されない。例えば、リンゴ、ペアー、マンゴーフルーツ等を挙げることができる。また、前記天然物からの抽出方法としては、例えば、未乾燥又は乾燥した前記天然物をそのまま又は粉砕し、水性溶媒に浸漬等して抽出する方法を挙げることができる。このとき用いる水性溶媒としては、食品に使用することができるものであれば、特に限定されず、例えば、エタノール、プロピレングリコール、グリセリン等を挙げることができる。更に、前記の方法により得られる抽出液から精製する方法としては、例えばカラムクロマト法を挙げることができる。 For example, when it is obtained by extraction and purification from a natural product, it may be extracted and purified by a conventional method using the natural product as a raw material. Here, the natural product that can be used as a raw material is not particularly limited as long as it contains 1,3-octanediol, 5-octene-1,3-diol, or dimethylmethoxyfuranone. For example, an apple, a pair, a mango fruit, etc. can be mentioned. Examples of the extraction method from the natural product include a method in which the natural product which has not been dried or dried is directly or pulverized and immersed in an aqueous solvent for extraction. The aqueous solvent used at this time is not particularly limited as long as it can be used for food, and examples thereof include ethanol, propylene glycol, and glycerin. Furthermore, as a method of purifying from the extract obtained by the above method, for example, column chromatography can be mentioned.
前記の方法に代表される常法により抽出・精製された1,3−オクタンジオール、5−オクテン−1,3−ジオール又はジメチルメトキシフラノンは、これをそのまま本発明のマスキング剤の有効成分として用いることができるが、前記の抽出物も、1,3−オクタンジオール、5−オクテン−1,3−ジオール又はジメチルメトキシフラノンを含むものであり、これをそのまま本発明のマスキング剤として用いることもできる。更に、この抽出物を加熱揮散して得られる濃縮物や乾燥物等をそのまま本発明のマスキング剤として使用することもできる。 1,3-octanediol, 5-octene-1,3-diol or dimethylmethoxyfuranone extracted and purified by a conventional method typified by the above method is directly used as an active ingredient of the masking agent of the present invention. However, the extract also contains 1,3-octanediol, 5-octene-1,3-diol, or dimethylmethoxyfuranone, and can be used as it is as a masking agent of the present invention. . Furthermore, a concentrate or a dried product obtained by heating and evaporating the extract can be used as it is as a masking agent of the present invention.
また、化学合成により得る場合は、これら化合物を得るための通常の方法を用いればよく、例えば、特許文献4記載の方法を挙げることができる。 Moreover, what is necessary is just to use the normal method for obtaining these compounds, when obtaining by chemical synthesis, For example, the method of patent document 4 can be mentioned.
天然物からの抽出・精製、或いは化学合成により得られた1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンは、何れも常温で液体の物質であり、そのまま本発明のマスキング剤として使用することができる。更に、これら化合物をエタノール、プロピレングリコール、グリセリン等の溶媒中に溶解した製剤も本発明のマスキング剤として用いることができる。 1,3-octanediol, 5-octene-1,3-diol, and dimethylmethoxyfuranone obtained by extraction / purification from natural products or chemical synthesis are all substances that are liquid at room temperature, and thus are used in the present invention. It can be used as a masking agent. Furthermore, a preparation prepared by dissolving these compounds in a solvent such as ethanol, propylene glycol, glycerin and the like can also be used as the masking agent of the present invention.
このようにして得られる本発明のマスキング剤は、乳製品における光劣化臭に対して優れたマスキング効果を有するものである。乳製品に配合される本発明のマスキング剤の量は特に制限されるものではないが、光劣化臭のマスキング効果の点から、1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンから選ばれる1種以上の化合物各々の乳製品に対する濃度が、0.000001〜10ppmとなるように配合することが好ましい。 The masking agent of the present invention thus obtained has an excellent masking effect against the photodegradation odor in dairy products. The amount of the masking agent of the present invention to be blended with the dairy product is not particularly limited, but 1,3-octanediol, 5-octene-1,3-diol and It is preferable to blend so that the concentration of each of the one or more compounds selected from dimethylmethoxyfuranone with respect to the dairy product is 0.000001 to 10 ppm.
更に、1,3−オクタンジオールを本発明のマスキング剤の有効成分として用いる場合には、光劣化臭のマスキング効果の点から、1,3−オクタンジオールの乳製品に対する濃度が0.00001〜10ppm、更に0.001〜10ppmとなるように本発明のマスキング剤を乳製品に配合することが好ましく、光劣化臭のマスキング効果と乳製品の嗜好性の点から、特に0.001〜0.1ppmとなるように配合することがより好ましい。 Further, when 1,3-octanediol is used as an active ingredient of the masking agent of the present invention, the concentration of 1,3-octanediol with respect to the dairy product is 0.00001 to 10 ppm from the viewpoint of the masking effect of the photodegradation odor. Furthermore, it is preferable to add the masking agent of the present invention to the dairy product so as to be 0.001 to 10 ppm, and particularly from the viewpoint of the masking effect of the light deterioration odor and the palatability of the dairy product, 0.001 to 0.1 ppm. It is more preferable to mix | blend so that it may become.
また更に、5−オクテン−1,3−ジオールを本発明のマスキング剤の有効成分として用いる場合には、光劣化臭のマスキング効果の点から、5−オクテン−1,3−ジオールの乳製品に対する濃度が0.000001〜1ppm、更に0.001〜1ppmとなるように本発明のマスキング剤を乳製品に配合することが好ましく、光劣化臭のマスキング効果と乳製品の嗜好性の点から、特に0.001〜0.01ppmとなるように配合することがより好ましい。 Furthermore, when 5-octene-1,3-diol is used as an active ingredient of the masking agent of the present invention, from the viewpoint of the masking effect of photodegradation odor, 5-octene-1,3-diol can be used for dairy products. It is preferable to mix the masking agent of the present invention into the dairy product so that the concentration is 0.000001 to 1 ppm, and further 0.001 to 1 ppm, particularly from the viewpoint of the masking effect of the photodegradation odor and the palatability of the dairy product. It is more preferable to mix | blend so that it may become 0.001-0.01 ppm.
更にまた、ジメチルメトキシフラノンを本発明のマスキング剤の有効成分として用いる場合には、光劣化臭のマスキング効果の点から、ジメチルメトキシフラノンの乳製品に対する濃度が0.000001〜1ppm、更に0.0001〜1ppmとなるように本発明のマスキング剤を乳製品に配合することが好ましく、光劣化臭のマスキング効果と乳製品の嗜好性の点から、特に0.0001〜0.01ppmとなるように配合することがより好ましい。 Furthermore, when dimethylmethoxyfuranone is used as an active ingredient of the masking agent of the present invention, the concentration of dimethylmethoxyfuranone with respect to the dairy product is 0.000001 to 1 ppm, more preferably 0.0001, from the viewpoint of the masking effect of the photodegradation odor. It is preferable to mix the masking agent of the present invention into dairy products so as to be ˜1 ppm, and in particular from 0.0001 to 0.01 ppm from the viewpoint of masking effect of light deterioration odor and palatability of dairy products More preferably.
本発明のマスキング剤は、その有効成分である1,3−オクタンジオール、5−オクテン−1,3−ジオール又はジメチルメトキシフラノンを、それぞれ単独で、若しくは2種以上を組み合わせて使用することにより、乳製品の光劣化臭をマスキングすることができるが、光劣化臭のマスキング効果の点から、前記3種の有効成分を全て組み合わせて使用することが好ましい。 The masking agent of the present invention uses 1,3-octanediol, 5-octene-1,3-diol, or dimethylmethoxyfuranone, which are the active ingredients, alone or in combination of two or more. Although the photodegradation odor of a dairy product can be masked, it is preferable to use it combining all the said 3 types of active ingredients from the point of the masking effect of a photodegradation odor.
本発明のマスキング剤を乳製品に配合する時期及びその方法は特に限定されず、乳製品製造時の任意段階で配合すればよく、配合は、マスキング剤を直接乳製品に添加して行ってもよく、本発明のマスキング剤を含む香料製剤を調製して、該香料製剤を乳製品に添加して行ってもよい。このマスキング剤を含む香料製剤に添加することができる食品用香料成分としては、例えば、アルデヒド類、脂肪酸類、脂肪酸高級アルコール類、フェノール類等を挙げることができる。 The timing and method for blending the masking agent of the present invention into the dairy product are not particularly limited, and may be blended at any stage during the production of the dairy product. The masking agent may be added directly to the dairy product. It is also possible to prepare a fragrance preparation containing the masking agent of the present invention and add the fragrance preparation to the dairy product. Examples of the fragrance ingredient for food that can be added to the fragrance preparation containing this masking agent include aldehydes, fatty acids, fatty acid higher alcohols, phenols and the like.
ここで、本発明のマスキング剤が配合される乳製品とは、乳そのもの若しくは乳を原料として製造されるもののことをいい、そのようなものであれば特に制限されるものではなく、例えば、(1)牛乳、山羊乳、羊乳、豆乳等の液状乳;(2)脱脂粉乳、全粉乳等の粉乳類を水で溶解した還元乳;(3)前記液状乳若しくは還元乳(以下、「原料乳」という)をそのまま或いは水で希釈して、乳酸菌やビフィズス菌等を用いて発酵処理して得られる発酵乳飲料;(4)前記発酵乳飲料にゼラチン、寒天等を配合したハードタイプのヨーグルト(5)前記発酵乳飲料を含有し、殺菌処理を施された乳性飲料;(6)原料乳に有機酸等の酸成分を加えて酸性にした酸性乳を挙げることができる。 Here, the dairy product in which the masking agent of the present invention is blended refers to milk itself or a product produced from milk as a raw material, and is not particularly limited as long as it is, for example, ( 1) Liquid milk such as cow's milk, goat's milk, sheep milk and soy milk; (2) Reduced milk obtained by dissolving powdered milk such as skim milk powder and whole milk powder in water; (3) Liquid milk or reduced milk (hereinafter referred to as “raw material”) Fermented milk beverage obtained by fermentation with lactic acid bacteria, bifidobacteria, etc. (4) Hard yogurt containing gelatin, agar, etc. in the fermented milk drink; (5) Milk beverage containing the fermented milk beverage and sterilized; (6) Acid milk made acidic by adding an acid component such as organic acid to raw milk.
本発明のマスキング剤が配合される乳製品である発酵乳飲料を製造する場合は、原料乳に微生物を接種し、発酵すればよい。その製造に用いられる微生物としては、通常、食品の製造に使用される乳酸菌やビフィズス菌であれば特に限定されず、例えば、ラクトバチルス・カゼイ、ラクトバチルス・マリ、ラクトバチルス・アシドフィルス、ラクトバチルス・デルブルッキィ サブスピーシーズ ブルガリカス、ラクトバチルス・ヘルベティカス等のラクトバチルス属細菌;ストレプトコッカス・サーモフィルス等のストレプトコッカス属細菌;ラクトコッカス・ラクチス サブスピーシーズ クレモリス等のラクトコッカス属細菌;エンテロコッカス・フェカーリス等のエンテロコッカス属細菌などの乳酸菌、あるいは、ビフィドバクテリウム・ブレーベ、ビフィドバクテリウム・ビフィダム、ビフィドバクテリウム・ロンガム等のビフィドバクテリウム属細菌などのビフィズス菌を挙げることができる。これらの微生物の中でも、ラクトバチルス・カゼイ、ラクトバチルス・アシドフィルス、ラクトバチルス・デルブルッキィ サブスピーシーズ ブルガリカス又はストレプトコッカス・サーモフィルスを使用すると本発明のマスキング剤が配合される乳製品の風味が良好であるため好ましい。これらの微生物は、1種単独で用いることもできるし、2種以上を組み合わせて用いることもできる。 When producing a fermented milk beverage that is a dairy product in which the masking agent of the present invention is blended, the raw material milk may be inoculated with microorganisms and fermented. The microorganism used for the production is not particularly limited as long as it is usually a lactic acid bacterium or bifidobacteria used for food production. For example, Lactobacillus casei, Lactobacillus mari, Lactobacillus acidophilus, Lactobacillus Delbrucchi subspices Lactobacillus bacteria such as Bulgaricus, Lactobacillus helveticus; Streptococcus bacteria such as Streptococcus thermophilus; Lactococcus bacteria such as Lactococcus lactis; Lactic acid bacteria, or Bifidobacterium breve, Bifidobacterium bifidum, Bifidobacterium longum, etc. Mention may be made of bifidobacteria. Among these microorganisms, when using Lactobacillus casei, Lactobacillus acidophilus, Lactobacillus delbrukki subspecies Bulgaricus or Streptococcus thermophilus, the flavor of the milk product containing the masking agent of the present invention is good. preferable. These microorganisms can be used individually by 1 type, and can also be used in combination of 2 or more type.
上記微生物を原料乳に接種し、発酵する条件や方法としては、通常の発酵乳の製造に使用される条件及び方法を適用すればよく、特に限定されない。例えば、30〜40℃の温度で、pHが3.0〜5.0となるまで発酵させればよく、その方法も、静置発酵、攪拌発酵、振とう発酵、通気発酵等から適宜選択して発酵に用いる微生物に適した方法を用いればよい。 Conditions and methods for inoculating raw milk with the above microorganisms and fermenting may be the conditions and methods used for the production of ordinary fermented milk, and are not particularly limited. For example, it may be fermented at a temperature of 30 to 40 ° C. until the pH becomes 3.0 to 5.0, and the method is also appropriately selected from stationary fermentation, stirring fermentation, shaking fermentation, aeration fermentation and the like. Thus, a method suitable for the microorganism used for fermentation may be used.
本発明のマスキング剤が配合される乳製品である酸性乳を製造する場合は、原料乳に各種酸成分を添加してpHが酸性になるように調製すればよい。ここで使用することができる酸成分としては、食品に使用することができるものであれば特に限定されるものではなく、例えば、乳酸、クエン酸、酒石酸、リンゴ酸、酢酸等の有機酸、リン酸等の無機酸を挙げることができる。 When producing acidic milk that is a dairy product in which the masking agent of the present invention is blended, various acid components may be added to the raw milk so that the pH becomes acidic. The acid component that can be used here is not particularly limited as long as it can be used in foods. For example, organic acids such as lactic acid, citric acid, tartaric acid, malic acid, and acetic acid, phosphorus Mention may be made of inorganic acids such as acids.
また、本発明のマスキング剤は、鉄含有乳製品に対して特に好適に使用することができる。ここで、鉄含有乳製品とは、前記の乳製品に鉄分を配合したものをいう。ここで使用することができる鉄分としては、例えば、塩化第2鉄、クエン酸鉄、クエン酸鉄アンモニウム、クエン酸第1鉄ナトリウム、乳酸鉄、ピロリン酸第1鉄、ピロリン酸第2鉄、及びピロリン酸第2鉄を特定の乳化成分で被覆したピロリン酸第2鉄乳化剤被覆組成物(特許文献1)を例示することができ、乳製品への鉄分の添加量は特に制限されるものではない。 Moreover, the masking agent of this invention can be used especially suitably with respect to iron containing dairy products. Here, the iron-containing dairy product refers to the above-described dairy product containing iron. Examples of iron that can be used here include ferric chloride, iron citrate, ammonium iron citrate, sodium ferrous citrate, iron lactate, ferrous pyrophosphate, ferric pyrophosphate, and A ferric pyrophosphate emulsifier coating composition (Patent Document 1) in which ferric pyrophosphate is coated with a specific emulsifying component can be exemplified, and the amount of iron added to the dairy product is not particularly limited. .
更に、本発明のマスキング剤は、光透過性の容器に充填された乳製品に対しても使用することができる。この光透過性容器とは、積分球式光線透過率測定装置(「JISハンドブック11プラスチック」(財団法人日本規格協会、1987年4月20日発行)の第253頁〜第255頁)を用い、光源から出た光が試験片(容器)を通過し、透過後の光を受光機で検出・測定することができるものをいい、例えば、ガラスや合成樹脂、より具体的には、ポリスチレン、ポリエチレン、塩化ビニル、ポリエチレンテレフタラートからなる容器を挙げることができる。また、前記方法により測定される光透過性容器の光透過率は特に限定されるものではない。 Furthermore, the masking agent of the present invention can also be used for dairy products filled in light transmissive containers. With this light transmissive container, an integrating sphere type light transmittance measuring device ("JIS Handbook 11 Plastic" (Japan Standards Association, issued on April 20, 1987), pages 253 to 255), The light emitted from the light source passes through the test piece (container), and the light after transmission can be detected and measured by the light receiver. For example, glass, synthetic resin, more specifically, polystyrene, polyethylene And containers made of vinyl chloride and polyethylene terephthalate. Moreover, the light transmittance of the light transmissive container measured by the above method is not particularly limited.
なお、本発明のマスキング剤は、通常の乳製品に用いられる各種食品素材を配合する乳製品に対しても使用することができる。ここで、用いられる食品素材としては、例えば、糖質、甘味料、増粘剤、乳化剤、ビタミン類、果汁、フレーバー等を挙げることができ、具体的には、ショ糖、グルコース、フルクトース、パラチノース、キシロース、麦芽糖等の糖質;ソルビトール、キシリトール、エリスリトール、パラチニット、還元水飴等の糖アルコール;アスパルテーム、ソーマチン、スクラロース、アセスルファムK、ステビア等の高甘味度甘味料;寒天、ゼラチン、カラギーナン、グアーガム、キサンタンガム、ペクチン、ローカストビーンガム、ジェランガム等の増粘剤;ショ糖脂肪酸エステル、グリセリン脂肪酸エステル、グリセリン脂肪酸エステル、レシチン等の乳化剤;ビタミンA、ビタミンB類、ビタミンC、ビタミンE等のビタミン類;ストロベリー果汁、ブルーベリー果汁、グレープ果汁、白ぶどう果汁等の果汁;ストロベリーフレーバー、ブルーベリーフレーバー、グレープフレーバー、マスカットフレーバー等のフレーバーを例示することができる。 In addition, the masking agent of this invention can be used also with respect to the dairy product which mix | blends various food materials used for normal dairy products. Here, examples of food materials used include sugars, sweeteners, thickeners, emulsifiers, vitamins, fruit juices, flavors, and the like. Specifically, sucrose, glucose, fructose, palatinose Carbohydrates such as xylose and maltose; sugar alcohols such as sorbitol, xylitol, erythritol, palatinit, reduced starch syrup; high-intensity sweeteners such as aspartame, thaumatin, sucralose, acesulfame K, stevia; agar, gelatin, carrageenan, guar gum, Thickeners such as xanthan gum, pectin, locust bean gum, gellan gum; emulsifiers such as sucrose fatty acid ester, glycerin fatty acid ester, glycerin fatty acid ester, lecithin; vitamins such as vitamin A, vitamin B, vitamin C, vitamin E; Strawberry It can be exemplified strawberry flavor, blueberry flavor, grape flavor, the flavor of such Muscat flavor; juice, blueberry juice, grape juice, fruit juice such as white grape juice.
以下、試験例及び実施例を挙げて本発明を詳細に説明するが、本発明はこれらに何ら制約されるものではない。 EXAMPLES Hereinafter, although a test example and an Example are given and this invention is demonstrated in detail, this invention is not restrict | limited at all by these.
試 験 例 1
抗酸化剤が、鉄含有発酵乳における光劣化臭のマスキングとその嗜好性に対して与える影響について検討した。まず、発酵乳ベース、シロップ及びピロリン酸第2鉄乳化剤被覆組成物を混合し、鉄含有発酵乳(比較品1)を調製した。また、表1に記載の添加物(抗酸化剤)を比較品1に添加し、比較品2〜4を調製した。比較品の調製には、発酵乳ベースとして、殺菌された20%脱脂粉乳溶液にストレプトコッカス・サーモフィルス(YIT2001株)のシードスターターを0.2%となるように接種し、更に、ラクトバチルス・カゼイ(YIT9029株)のシードスターターを0.1%となるように接種して34℃でpH4.2まで培養し、均質化機を用いて15MPaで均質化したものを用いた。
Test example 1
We investigated the effects of antioxidants on the masking of photo-degraded odor and fertility in fermented milk containing iron. First, fermented milk base, syrup and ferric pyrophosphate emulsifier coating composition were mixed to prepare fermented milk containing iron (Comparative Product 1). Moreover, the additive (antioxidant) of Table 1 was added to the comparative product 1, and the comparative products 2-4 were prepared. For the preparation of the comparative product, as a fermented milk base, a sterilized 20% nonfat dry milk solution was inoculated with a seed starter of Streptococcus thermophilus (YIT2001 strain) at 0.2%, and further, Lactobacillus casei (YIT9029 strain) seed starter was inoculated to 0.1%, cultured at 34 ° C. to pH 4.2, and homogenized at 15 MPa using a homogenizer.
また、シロップとしては、水に白ぶどう果汁9g、マルチトール18g、アスパルテーム0.18g及びペクチン3gを溶解し、全量を600gとした後110℃で3秒間殺菌したものを用いた。 As syrup, 9 g of white grape juice, 18 g of maltitol, 0.18 g of aspartame and 3 g of pectin were dissolved in water to make a total amount of 600 g and then sterilized at 110 ° C. for 3 seconds.
各比較品の調製方法は次の通りである。
発酵乳ベース400g、シロップ600g及びピロリン酸第2鉄乳化剤被覆組成物2.5gを混合したものを比較品1;比較品1に、アスコルビン酸を濃度が0.1%となるように配合したものを比較品2;比較品1に、ザクロ由来ポリフェノールを含む製剤を濃度が0.2%となるように配合したものを比較品3;比較品1に、ルチンを濃度が0.02%となるように配合したものを比較品4とした。
The preparation method of each comparative product is as follows.
A mixture of 400 g of fermented milk base, 600 g of syrup and 2.5 g of ferric pyrophosphate emulsifier coating composition, comparative product 1; mixed with ascorbic acid at a concentration of 0.1% in comparative product 1 Comparison product 2; Comparison product 3 containing a formulation containing a pomegranate-derived polyphenol mixed at a concentration of 0.2% Comparison product 3; Comparison product 1 with a rutin concentration of 0.02% The product thus formulated was designated as Comparative Product 4.
以上のようにして調製した比較品1〜4の鉄含有発酵乳をポリスチレン製光透過性容器(光透過率約75%)に充填して、光劣化臭の程度及び嗜好性を次の方法により評価した。 The iron-containing fermented milk of Comparative products 1 to 4 prepared as described above is filled in a polystyrene light-transmitting container (light transmittance of about 75%), and the degree and preference of light-deteriorating odor is determined by the following method. evaluated.
[ 光劣化臭 ]
比較品1〜4を1200Luxの光を照射しながら10℃にて120時間保存後、その光劣化臭について、比較品1の光劣化臭の程度を1点とし、暗所にて10℃、120時間保存した比較品1(以下、対照品1という)の光劣化臭の程度、即ち、光劣化臭が全くない状態を7点とした7段階でパネル10名により評価した。
[Light odor]
After the comparison products 1 to 4 were stored at 10 ° C. for 120 hours while irradiating 1200 Lux light, the light degradation odor of the comparison product 1 was defined as one point, and 10 ° C. and 120 ° C. in the dark. Evaluation was performed by 10 panelists in 7 stages, with the degree of photodegradation odor of the comparative product 1 (hereinafter referred to as the control product 1) stored for a period of time, that is, 7 points with no photodegradation odor.
[ 嗜好性 ]
光劣化臭について評価したものとは別の比較品1〜4を用い、これらを暗所にて10℃、120時間保存後、ポリフェノールやアスコルビン酸そのものが鉄含有発酵乳の風味に与える影響を、風味が非常に悪いという評価を1点とし、風味が非常によいという評価を7点とした7段階でパネル10名により評価した。この嗜好性評価では、暗所にて保存した比較品を用いることで、光劣化臭が風味に与える影響を排除した。
[Preferences]
Using comparative products 1 to 4 different from those evaluated for the photodegradation odor, and after storing them at 10 ° C. for 120 hours in the dark, the effect of polyphenol and ascorbic acid itself on the flavor of the fermented milk containing iron Evaluation was made by 10 panelists in 7 stages, with an evaluation that the flavor was very bad as 1 point and an evaluation that the flavor was very good as 7 points. In this preference evaluation, by using a comparative product stored in a dark place, the influence of the light deterioration odor on the flavor was eliminated.
表1の結果から、鉄含有発酵乳に光を照射することにより、光劣化臭が生じることがわかった。また、本試験例の鉄含有発酵乳においては、抗酸化剤であるアスコルビン酸、ザクロ由来ポリフェノール又はルチンを添加することにより、光劣化臭が抑制されることがわかった。 From the results shown in Table 1, it was found that a light-deteriorating odor was produced by irradiating the iron-containing fermented milk with light. Moreover, in the iron containing fermented milk of this test example, it turned out that a photodegradation odor is suppressed by adding ascorbic acid which is an antioxidant, a pomegranate origin polyphenol, or rutin.
試 験 例 2
次に、ポリフェノール系抗酸化剤が、鉄含有発酵乳の外観に与える影響について検討した。試験例1で調製した比較品1、3及び4を暗所にて10℃、120時間保存後、その外観について自由描写した。その結果を表2に示す。なお、試験例1と同様に、比較品1を暗所にて10℃、120時間保存したものを対照品1とした。
Test example 2
Next, the effect of polyphenol antioxidants on the appearance of fermented milk containing iron was examined. Comparative products 1, 3 and 4 prepared in Test Example 1 were stored in the dark at 10 ° C. for 120 hours, and the appearance was freely described. The results are shown in Table 2. As in Test Example 1, the comparative product 1 was stored in the dark at 10 ° C. for 120 hours as the control product 1.
表2の結果から、鉄含有発酵乳にポリフェノール系抗酸化剤であるザクロ由来ポリフェノール又はルチンを添加した場合は、鉄含有発酵乳中の鉄とポリフェノール系抗酸化剤が反応することにより鉄含有発酵乳の外観が青黒い色味を帯びた白色、又は赤黒い色味を帯びた白色となることがわかった。このように黒味を帯びた鉄含有発酵乳は、その商品価値が著しく損なわれたものであった。 From the results of Table 2, when iron-containing fermented milk is added with polyphenol-based antioxidant pomegranate-derived polyphenol or rutin, iron in the iron-containing fermented milk reacts with the polyphenol-based antioxidant to cause iron-containing fermentation. It was found that the appearance of the milk was white with a bluish tinge or white with a reddish tinge. Thus, the iron-containing fermented milk with a blackish taste has been significantly impaired in commercial value.
実 施 例 1
20%脱脂粉乳溶液を120℃で3秒間殺菌し、ストレプトコッカス・サーモフィルス(YIT2001株)のシードスターターを0.2%となるように接種し、更に、ラクトバチルス・カゼイ(YIT9029株)のシードスターターを0.1%となるように接種して34℃でpH4.2まで培養し、均質化機を用いて15MPaで均質化することにより発酵乳ベースを調製した。
Example 1
A 20% non-fat dry milk solution is sterilized at 120 ° C. for 3 seconds, a Streptococcus thermophilus (YIT2001 strain) seed starter is inoculated to 0.2%, and a Lactobacillus casei (YIT9029 strain) seed starter. Was fermented to a pH of 4.2 at 34 ° C. and homogenized at 15 MPa using a homogenizer to prepare a fermented milk base.
一方、水に白ぶどう果汁9g、マルチトール18g、アスパルテーム0.18g、ペクチン3gを溶解し、全量を600gとした後110℃で3秒間殺菌し、シロップを調製した。得られたシロップ600gを、発酵乳ベース400g及びピロリン酸第2鉄乳化剤被覆組成物2.5gと混合することにより比較品1を調製した。更に、比較品1に下表2に示す通りに1,3−オクタンジオール、5−オクテン−1,3−ジオール又はジメチルメトキシフラノンを配合し、実施品1〜3を得た。 On the other hand, 9 g of white grape juice, 18 g of maltitol, 0.18 g of aspartame and 3 g of pectin were dissolved in water to make a total amount of 600 g, and then sterilized at 110 ° C. for 3 seconds to prepare a syrup. Comparative product 1 was prepared by mixing 600 g of the resulting syrup with 400 g of fermented milk base and 2.5 g of ferric pyrophosphate emulsifier coating composition. Further, as shown in Table 2 below, 1,3-octanediol, 5-octene-1,3-diol or dimethylmethoxyfuranone was blended into Comparative Product 1 to obtain Working Products 1-3.
比較品1及び実施品1〜3をポリスチレン製光透過性容器(光透過率約75%)に充填して、試験例1と同様にして光照射後の光劣化臭と暗所保存後の嗜好性を評価した。また、暗所にて10℃、120時間保存後の比較品1及び実施品1〜3の外観について自由描写した。これらの結果を表3に示す。 Comparison product 1 and execution products 1 to 3 were filled in a polystyrene light-transmitting container (light transmittance of about 75%), and in the same manner as in Test Example 1, photodegradation odor after light irradiation and preference after storage in the dark Sex was evaluated. In addition, the appearances of Comparative Product 1 and Examples 1 to 3 after storage at 10 ° C. for 120 hours in a dark place were freely depicted. These results are shown in Table 3.
化合物b:5−オクテン−1,3−ジオール
化合物c:ジメチルメトキシフラノン
Compound b: 5-octene-1,3-diol
Compound c: Dimethylmethoxyfuranone
表3の結果から、鉄含有発酵乳に1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンから選ばれる何れか1種類を0.0001ppm配合することにより、鉄含有発酵乳の風味に悪影響を及ぼすことなく、光劣化臭をマスキングできることがわかった。更に、鉄含有発酵乳の外観は、1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンから選ばれる何れか1種類を0.0001ppm添加した場合でも、黒味を帯びた色に劣化しないことがわかった。 From the results shown in Table 3, iron-containing fermented milk is mixed with 0.0001 ppm of any one selected from 1,3-octanediol, 5-octene-1,3-diol, and dimethylmethoxyfuranone. It was found that the photodegradation odor could be masked without adversely affecting the flavor of milk. Furthermore, the iron-containing fermented milk has a black appearance even when 0.0001 ppm of any one selected from 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxyfuranone is added. It was found that the color did not deteriorate.
実 施 例 2
前記実施例1で調製した比較品1に、1,3−オクタンジオールを最終製品あたり0.00001〜10ppmとなるように配合し、実施品4〜10の鉄含有発酵乳を調製した。
Example 2
In Comparative Product 1 prepared in Example 1, 1,3-octanediol was blended so as to be 0.0001 to 10 ppm per final product to prepare iron-containing fermented milk of Examples 4 to 10.
比較品1及び実施品4〜10をポリスチレン製光透過性容器(光透過率約75%)に充填して、試験例1と同様にして光照射後の光劣化臭と暗所保存後の嗜好性を評価した。この結果を表4に示す。 The comparative product 1 and the practical products 4 to 10 were filled in a polystyrene light-transmitting container (light transmittance of about 75%), and in the same manner as in Test Example 1, the photodegraded odor after light irradiation and the preference after storage in the dark Sex was evaluated. The results are shown in Table 4.
表4の結果から、鉄含有発酵乳に1,3−オクタンジオールを0.00001〜10ppm配合することにより、光劣化臭をマスキングできることがわかった。また、0.001〜10ppm配合した場合に光劣化臭のマスキング効果がより高く、特に0.001〜0.1ppm配合した場合に光劣化臭のマスキング効果と嗜好性がどちらも最も好ましいものとなることがわかった。 From the results shown in Table 4, it was found that the photodegradation odor can be masked by adding 0.00001 to 10 ppm of 1,3-octanediol to the fermented milk containing iron. Further, when 0.001 to 10 ppm is blended, the masking effect of the photodegradation odor is higher, and particularly when 0.001 to 0.1 ppm is blended, both the masking effect of the photodegradation odor and the palatability are most preferable. I understood it.
実 施 例 3
前記実施例1で調製した比較品1に、5−オクテン−1,3−ジオールを最終製品あたり0.000001〜1ppmとなるように配合し、実施品11〜17を調製した。
Example 3
The comparative product 1 prepared in Example 1 was blended with 5-octene-1,3-diol so that the final product had a concentration of 0.000001 to 1 ppm to prepare the practical products 11 to 17.
比較品1及び実施品11〜17をポリスチレン製光透過性容器(光透過率約75%)に充填して、試験例1と同様にして光照射後の光劣化臭と暗所保存後の嗜好性を評価した。この結果を表5に示す。 Comparative product 1 and Examples 11 to 17 were filled in a polystyrene light-transmitting container (light transmittance of about 75%), and in the same manner as in Test Example 1, the photodegraded odor after light irradiation and the preference after storage in the dark Sex was evaluated. The results are shown in Table 5.
表5の結果から、鉄含有発酵乳に5−オクテン−1,3−ジオールを0.000001〜1ppm配合することにより、光劣化臭をマスキングできることがわかった。また、0.001〜1ppm配合した場合に光劣化臭のマスキング効果がより高く、特に0.001〜0.01ppm配合した場合に光劣化臭のマスキング効果と嗜好性がどちらも最も好ましいものとなることがわかった。 From the results of Table 5, it was found that the photodegradation odor can be masked by adding 0.000001 to 1 ppm of 5-octene-1,3-diol to the fermented milk containing iron. Further, when 0.001 to 1 ppm is blended, the masking effect of the photodegradation odor is higher, and particularly when 0.001 to 0.01 ppm is blended, both the masking effect and preference of the photodegradation odor are most preferable. I understood it.
実 施 例 4
前記実施例1で調製した比較品1に、ジメチルメトキシフラノンを最終製品あたり0.000001〜1ppmとなるように配合し、実施品18〜24を調製した。
Example 4
The comparative product 1 prepared in Example 1 was blended with dimethylmethoxyfuranone so as to be 0.000001 to 1 ppm per final product to prepare practical products 18 to 24.
比較品1及び実施品18〜24をポリスチレン製光透過性容器(光透過率約75%)に充填して、試験例1と同様にして光照射後の光劣化臭と暗所保存後の嗜好性を評価した。この結果を表6に示す。 The comparative product 1 and the practical products 18 to 24 are filled in a polystyrene light transmissive container (light transmittance of about 75%), and the light deterioration odor after light irradiation and the taste after storage in the dark are the same as in Test Example 1. Sex was evaluated. The results are shown in Table 6.
表6の結果から、鉄含有発酵乳にジメチルメトキシフラノンを0.000001〜1ppm配合することにより、光劣化臭をマスキングできることがわかった。また、0.0001〜1ppm配合した場合に光劣化臭のマスキング効果がより高く、特に0.0001〜0.01ppm配合した場合に光劣化臭のマスキング効果と嗜好性がどちらも最も好ましいものとなることがわかった。 From the result of Table 6, it turned out that a photodegradation odor can be masked by mix | blending 0.0001-1 ppm of dimethylmethoxy furanone with fermented milk containing iron. Further, when 0.0001 to 1 ppm is blended, the masking effect of the photodegradation odor is higher, and particularly when 0.0001 to 0.01 ppm is blended, both the masking effect and preference of the photodegradation odor are most preferable. I understood it.
実 施 例 5
前記実施例1で調製した比較品1に、1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンから選ばれる2種又は3種を表7のとおりに配合し、実施品25〜28を調製した。
Example 5
Two or three kinds selected from 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxyfuranone were blended in Comparative Product 1 prepared in Example 1 as shown in Table 7, and carried out. Articles 25-28 were prepared.
比較品1及び実施品25〜28をポリスチレン製光透過性容器(光透過率約75%)に充填して、試験例1と同様にして光照射後の光劣化臭と暗所保存後の嗜好性を評価した。また、暗所にて10℃、120時間保存後の比較品1及び実施品25〜28の外観について自由描写した。これらの結果を表7に示す。 The comparative product 1 and the practical products 25 to 28 are filled in a polystyrene light-transmitting container (light transmittance of about 75%), and in the same manner as in Test Example 1, the light deterioration odor after light irradiation and the preference after storage in the dark place Sex was evaluated. In addition, the appearances of the comparative product 1 and the working products 25 to 28 after storage at 10 ° C. for 120 hours in a dark place were freely depicted. These results are shown in Table 7.
化合物b:5−オクテン−1,3−ジオール
化合物c:ジメチルメトキシフラノン
表7の結果から、1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンから選ばれる2種又は3種を組み合わせて、鉄含有発酵乳に配合することにより、鉄含有発酵乳の風味に悪影響を与えることなく、光劣化臭をマスキングできることがわかった。また、前記化合物のいずれか2種を添加した場合に比べ、3種添加した場合の方が、光劣化臭のマスキング効果が高いことがわかった。更に、鉄含有発酵乳の外観は、1,3−オクタンジオール、5−オクテン−1,3−ジオール及びジメチルメトキシフラノンから選ばれる2種又は3種を配合した場合でも、黒味を帯びた色に劣化しないことがわかった。 From the results of Table 7, iron content is obtained by combining two or three kinds selected from 1,3-octanediol, 5-octene-1,3-diol, and dimethylmethoxyfuranone, and blending into fermented milk containing iron. It was found that the photodegradation odor could be masked without adversely affecting the flavor of fermented milk. Moreover, it turned out that the masking effect of a photodegradation odor is high when three kinds are added compared with the case where any two kinds of the said compounds are added. Furthermore, the appearance of the fermented milk containing iron is blackish even when two or three selected from 1,3-octanediol, 5-octene-1,3-diol and dimethylmethoxyfuranone are blended. It turned out not to deteriorate.
本発明のマスキング剤は、乳製品が光照射を受けることにより生じる光劣化臭を有効にマスキングできるものである。また、本発明のマスキング剤は、鉄含有乳製品に配合した場合でも、その外観を黒味を帯びた色に劣化させないものである。 The masking agent of the present invention can effectively mask a photodegradation odor caused by light irradiation of a dairy product. In addition, the masking agent of the present invention does not deteriorate the appearance of the masking agent into a blackish color even when blended in an iron-containing dairy product.
従って、このマスキング剤は、各種の乳製品、特にポリフェノール系の抗酸化剤が配合できない鉄含有乳製品において有利に利用しうるものであり、得られた乳製品は、高い商品価値を有するものである。
以 上
Therefore, this masking agent can be advantageously used in various dairy products, particularly iron-containing dairy products that cannot contain polyphenol antioxidants, and the obtained dairy products have high commercial value. is there.
that's all
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