JP4927224B2 - Light emitting device - Google Patents

Description

The present invention includes an anode, a cathode, and a layer containing an organic compound capable of emitting light by applying an electric field (
Hereinafter, the present invention relates to an organic light-emitting element having “electroluminescent layer” and a light-emitting device using the same. The present invention also relates to an electronic device in which a light emitting device having an organic light emitting element is mounted as a component.

In recent years, research on a light-emitting device having an EL element as a self-luminous light-emitting element has been activated.
This light emitting device is also called an organic EL display or an organic light emitting diode. These light-emitting devices have features such as fast response speed, low voltage, and low power consumption driving suitable for moving image display, so next-generation displays such as new-generation mobile phones and personal digital assistants (PDAs) It is attracting a lot of attention.

The light-emitting element has an electroluminescent layer sandwiched between a pair of electrodes (anode and cathode), and the light-emitting mechanism includes holes injected from the anode when an electric field is applied between both electrodes, and a cathode The electrons injected from the recombination in the electroluminescent layer recombine at the luminescent center in the electroluminescent layer to form molecular excitons, and release energy when the molecular excitons return to the ground state. Is said to emit light.

Unlike a liquid crystal display device that requires a backlight, an organic EL display having a light-emitting element is self-luminous and has no viewing angle problem. That is, as a display used outdoors, it is more suitable than a liquid crystal display, and use in various forms has been proposed.

The driving method of the organic EL display is roughly divided into a direct current drive and an alternating current drive.

In addition, the present applicant describes in Japanese Patent Application Laid-Open No. H11-228707 that alternating current driving is used for an active matrix display device having an EL element. An EL element for AC driving is disclosed in Patent Document 2.
Is disclosed.

JP 2001-222255 A JP 2004-95546 A

In the case of AC driving, an AC signal (a signal whose polarity is inverted every certain period) is applied between the pair of electrodes of the EL element. When the EL element has a simple structure including a stack of a first electrode, a second electrode, and a layer containing an organic compound sandwiched between the pair of electrodes,
Due to the rectifying action, when an AC signal is applied, it emits light only for a half period. Therefore, in order to obtain the same amount of light emission as that in the case of DC driving where a DC voltage is applied, power consumption increases.

An object of the present invention is to provide an EL element having a novel structure suitable for AC driving.

Therefore, the present invention provides a material layer (current value on the horizontal axis and voltage value between the first electrode and the layer containing the organic compound and between the layer containing the organic compound and the second electrode. It is characterized by a light-emitting element having a novel structure suitable for alternating current drive, provided with a material layer having substantially point-symmetric current-voltage characteristics centered on zero in the graph display taken along the vertical axis.

The above-described material layer having current-voltage characteristics has both hole injection (or hole transport) characteristics and electron injection (or electron transport) characteristics. The characteristics are demonstrated.

In the AC signal to be applied, as shown in an example of the waveform in FIG. 13, the absolute value of the voltage is positive and negative, and therefore, the luminance of the EL element in a half cycle to which the positive voltage is applied and the negative voltage are applied. Further, it is necessary to make the luminance of the EL element of the half cycle the same. Accordingly, in the present invention, a positive signal and a negative signal are obtained by using a material layer having a current-voltage characteristic that is substantially point-symmetric about zero in a graph display in which the current value is taken on the horizontal axis and the voltage value is taken on the vertical axis. The EL element can be caused to emit light by both of the above signals, and a light emission amount equivalent to that obtained by direct current driving by applying a direct current voltage can be obtained without increasing power consumption.

The structure of the invention disclosed in this specification is a light-emitting device including a plurality of light-emitting elements. The light-emitting element has a current value on the horizontal axis and a voltage value on the first electrode and the first electrode. A first material layer having substantially point-symmetric current-voltage characteristics centered on zero in a graphical representation taken along the vertical axis;
A layer containing an organic compound on the first material layer, a second material layer having the same current-voltage characteristics as the first material layer on the layer containing the organic compound, and the second material A light-emitting device including a second electrode over the layer.

In the above structure, the first material layer and the second material layer are a composite layer of an organic compound and an inorganic compound that can exchange electrons with the organic compound. It is a composite layer containing an oxide and an organic compound.

In the above structure, the metal oxide is one or more selected from the group consisting of molybdenum oxide, tungsten oxide, and rhenium oxide.

Further, the first material layer and the second material layer described above can obtain excellent conductivity in addition to effects (such as improvement in heat resistance) that are considered to be obtained by mixing inorganic compounds. . These effects cannot be obtained by simply mixing an organic compound and an inorganic compound that do not have an electronic interaction with each other as in a conventional hole transport layer.

In addition, since the first material layer and the second material layer described above can increase the thickness of the material layer without causing an increase in driving voltage, a short circuit of the element due to dust or the like in the EL element formation process. Can be suppressed, and the yield is improved.

Needless to say, the first material layer and the second material layer described above do not have to have the same composition as long as they have the above-described current-voltage characteristics. The first mentioned above
The material layer and the second material layer need not have the same film thickness.

In addition, the material layer having the current-voltage characteristics described above has both the hole injection (or hole transport) characteristics and the electron injection (or electron transport) characteristics, so that the structure of the EL element is simple. It can be. For example, it is not necessary to have a complicated structure in which a plurality of layers for emitting light every half cycle in accordance with an AC signal is provided between a pair of electrodes, and the manufacturing process can be simplified.

In the above structure, the light-emitting device includes a drive circuit that applies an AC signal between the first electrode and the second electrode. Note that if an image signal whose polarity is inverted every predetermined period is applied between the first electrode and the second electrode of the light emitting device, an image can be displayed as an organic EL display. Note that the constant period here means every vertical synchronizing signal or horizontal synchronizing signal of the video signal. For example, the fixed period is 1/60 seconds or longer than 1/60 seconds. Further, if the fixed period is shorter than 1/60 seconds, it can be more suitable for moving image display.

Note that a light-emitting device in this specification refers to an image display device, a light-emitting device, or a light source (including a lighting device). Also, a connector such as an FPC (Flexible prin
ted circuit) or TAB (Tape Automated Bonding) tape or TCP (Tape Carrie)
r Package), TAB tape, a module with a printed wiring board at the end of TCP, or a module in which an IC (integrated circuit) is directly mounted on a light emitting element by the COG (Chip On Glass) method It shall be included in the light emitting device.

According to the present invention, a light-emitting device suitable for AC driving can be realized without a complicated element structure.

4A and 4B illustrate an example of a structure of a light-emitting element of the present invention. It is explanatory drawing which shows the operation mechanism of the light emitting element of this invention. It is explanatory drawing which shows the operation mechanism of the light emitting element of this invention. The graph which shows the current-voltage characteristic of the material layer of this invention. It is a figure which shows the upper surface structure and cross-sectional structure of a passive type display apparatus. It is a figure which shows a perspective view. It is a top view which shows the external appearance of a light emitting module. It is a figure which shows the top view of a light emitting module. It is a figure which shows sectional drawing of a light emitting module. It is a figure which shows another example of cross-sectional structure. FIG. 14 illustrates an example of an electronic device. FIG. 14 illustrates an example of an electronic device. It is a figure which shows an alternating current signal. (A) is a graph which shows the current-voltage characteristic in an organic compound single layer, (B) is a graph which shows the current-voltage characteristic in a molybdenum oxide single layer. (Comparative example)

  Embodiments of the present invention will be described below. An example of the laminated structure of the present invention is shown in FIG.

FIG. 1 illustrates a first electrode 11, a first material layer 12, a layer 13 containing an organic compound, a second material layer 14, and a second electrode 15 over a substrate 10 having an insulating surface. The structure which laminated | stacked one by one is shown. Note that an AC power supply 16 is connected to the first electrode 11 and the second electrode 15, and the layer 13 containing an organic compound emits light.

The first electrode 11 and the second electrode 15 are both or one of which is a light-transmitting conductive film. As the light-transmitting conductive film, ITO, IZO, or ITSO may be used.
The film thicknesses of the first electrode 11 and the second electrode 15 are in the range of 10 nm to 500 nm. When the film thickness of the first electrode 11 and the second electrode 15 is 10 nm or less, the conductivity is remarkably lowered, so that it does not function as an electrode, and when it is thicker than 500 nm, the translucency is lowered.

When a metal film is used as the first electrode 11 or the second electrode 15, Ag,
Al, Ta, or the like can be used.

Further, the first material layer 12 and the second material layer 14 have substantially point-symmetric current-voltage characteristics centered on zero in a graph display in which the current value is taken on the horizontal axis and the voltage value is taken on the vertical axis. Use materials. Specifically, the first material layer 12 and the second material layer 14 are formed using a metal oxide (molybdenum oxide, tungsten oxide, rhenium oxide, or the like) and an organic compound (a material having a hole transporting property (for example, 4, 4 ′). -Bis [N- (3-methylphenyl) -N-phenylamino]
Biphenyl (abbreviation: TPD), 4,4′-bis [N- (1-naphthyl) -N-phenylamino] biphenyl (abbreviation: α-NPD), 4,4′-bis {N- [4- (N , N-di-m
-Tolylamino) phenyl] -N-phenylamino} biphenyl (abbreviation: DNTPD, etc.))).

The film thicknesses of the first material layer 12 and the second material layer 14 are in the range of 3 nm to 1000 nm. If the film thickness is less than 3 nm, it cannot be formed as a film on one side.
If it is thicker than nm, the translucency is significantly reduced.

Further, the layer 13 containing an organic compound may be a single layer or a laminate, and the thickness of one layer is 5 nm to
Set to 500 nm. In the structure of the light emitting element of FIG. 1, when a single layer is used, the simplest laminated structure is obtained.

The material used for the layer 13 containing an organic compound is, for example, tris (8-quinolinolato).
Aluminum (abbreviation: Alq ₃ ), tris (4-methyl-8-quinolinolato) aluminum (abbreviation: Almq ₃ ), α-NPD, or the like can be used. The layer 13 containing an organic compound may contain a dopant material. For example, N, N′-dimethylquinacridone (abbreviation: DMQd), coumarin 6, rubrene, or the like can be used.

The layer 13 containing an organic compound has a highest occupied orbit (HOMO) and a lowest empty orbit (LUMO).
It is preferable to use one having a level within the band gap of the metal oxide contained in the first material layer 12 and the second material layer 14.

In addition, the first electrode 11 and the second electrode 15 have a work function of material that is the first material layer 12.
In addition, the band gap of the metal oxide contained in the second material layer 14 is preferable.

Description will be made using an operation mechanism in which an AC signal is applied from the AC power supply 16 to the light emitting element shown in FIG. 1 and light emission is performed using the energy levels shown in FIGS. 2 and 3, the same reference numerals are used for portions corresponding to those in FIG.

FIG. 2 shows an example of energy levels in which the first electrode 11 of the light emitting element is ITO and the second electrode 15 is Al.

When a voltage is applied between the first electrode 11 and the second electrode 15, charges are generated in the first material layer 12 and the second material layer 14. In the first material layer 12 in contact with the first electrode 11, among the generated charges, electrons move to the first electrode 11, and holes are injected into the layer 13 containing an organic compound.

On the other hand, in the second material layer 14 in contact with the second electrode 15, among the generated charges, electrons are injected into the layer 13 containing an organic compound, and holes move to the second electrode 15.

In this way, holes injected from the first material layer 12 and electrons injected from the second material layer 14 are recombined to emit light in the layer 13 containing an organic compound.

FIG. 3 shows the state of energy levels when a signal having a polarity opposite to that of the signal shown in FIG. 2 is applied. Even when a signal having a reverse polarity is applied, light is emitted from the layer 13 containing an organic compound in the same manner because of the same element structure.

As described above, when an AC signal is applied to the light-emitting element of the present invention, light emission can be performed not only by a half cycle in which a voltage having a certain polarity is applied but also by applying a voltage having a reverse polarity.

  Moreover, the experiment shown below was conducted and the obtained result is shown in FIG.

Sample 1 in which an ITSO film, a composite film in which three molybdenum oxides, DNTPD, and rubrene are vapor-deposited at an arbitrary ratio simultaneously with an aluminum film, and an aluminum film, and an ITSO film and a molybdenum oxide film are laminated on a glass substrate. Sample 2 was prepared by laminating a composite film in which three, BBPB, and rubrene were simultaneously vapor-deposited at an arbitrary ratio and an aluminum film.

Then, current and voltage were applied to Sample 1 and Sample 2, and the current value was plotted on the horizontal axis, and the voltage value was plotted on the vertical axis, and displayed in a graph.

As shown in FIG. 4, it can be seen that the material sandwiched between the pair of electrodes (ITSO film and aluminum film) of Sample 1 is a material layer having current-voltage characteristics that are substantially point-symmetric with respect to zero. Similarly, the sample 2 is a material layer having current-voltage characteristics that are substantially point-symmetric about zero.

As Comparative Example 1, FIG. 14A shows the result of measuring current-voltage characteristics by stacking an ITSO film, a DNTPD film, and an aluminum film over a glass substrate. Comparative Example 1
FIG. 14A also shows the results of measuring current-voltage characteristics by stacking an ITSO film, a BBPB film, and an aluminum film over a glass substrate. As shown in FIG. 14A, when an organic compound film is sandwiched between a pair of electrodes as a single layer, current flows only when a positive voltage is applied.

As Comparative Example 3, FIG. 14B shows the results of measuring current-voltage characteristics by stacking an ITSO film, a molybdenum oxide film, and an aluminum film over a glass substrate. FIG. 14 (B
), When a molybdenum oxide film is sandwiched between a pair of electrodes as a single layer, a symmetric current-voltage characteristic is not exhibited.

The present invention having the above-described configuration will be described in more detail with the following examples.

In this embodiment, an example in which the structure of the light-emitting element of the present invention is used as a light-emitting element of a passive display device is shown in FIGS.

FIG. 5A is a diagram illustrating a top view of the pixel portion before sealing, and is a chain line A in FIG.
5B is a cross-sectional view taken along the line -A ′, and FIG. 5C is a cross-sectional view taken along the chain line BB ′.
).

On the first substrate 110, a plurality of first electrodes 113 are arranged in stripes at equal intervals. A partition 114 having an opening corresponding to each pixel is provided over the first electrode 113, and the partition 114 having the opening is formed using a photosensitive or non-photosensitive organic material (polyimide,
Acrylic, polyamide, polyimide amide, resist or benzocyclobutene), or SOG film (for example, an SiOx film containing an alkyl group)). Note that the opening corresponding to each pixel is a light emitting region 121.

A plurality of reverse-tapered partition walls 122 that are parallel to each other and intersect with the first electrode 113 are provided over the partition wall 114 having an opening. The reverse-tapered partition 122 is formed by using a positive photosensitive resin as a pattern in the unexposed portion and adjusting the exposure amount or the development time so that the lower part of the pattern is etched more in accordance with the photolithography method.

FIG. 6 shows a perspective view immediately after forming a plurality of parallel reverse-tapered partition walls 122. In addition, the same code | symbol is used for the same part as FIG. 5 (A)-FIG.5 (C).

The height of the inversely tapered partition wall 122 is set larger than the film thickness of the film containing the organic compound and the conductive film. When a film containing an organic compound and a conductive film are stacked on the first substrate having the structure shown in FIG. 6, the organic compound is separated into a plurality of electrically independent regions as shown in FIG. The included layers 115R, 115G, and 115B and the second electrode 116 are formed. The second electrode 116 is a striped electrode parallel to each other and extending in a direction intersecting the first electrode 113. Note that a film containing an organic compound and a conductive film are also formed over the reverse-tapered partition wall 122, but the layers 115R, 115G, and 115B containing the organic compound and the second electrode 116 are separated from each other.

In this embodiment, a first composite layer containing a metal oxide and an organic compound, a layer containing an organic compound, and a second composite layer containing a metal oxide and an organic compound are formed on the first electrode. Stack 115R, 1
In this example, 15G and 115B are selectively formed, and a light emitting device capable of full color display capable of obtaining three types of light emission (red, green, and blue) is shown. Lamination 115R, 115G, 115
Each B is formed in a stripe pattern parallel to each other. Here, although the stacking is the same pattern, the first composite layer and the second composite layer are common to each light-emitting element, and only the layer containing an organic compound to be the light-emitting layer is selected using a vapor deposition mask. Alternatively, vapor deposition may be performed.

An example of forming a first composite layer containing a metal oxide and an organic compound is shown. First, NPB and molybdenum oxide are housed in separate resistance-heating evaporation sources, and are deposited on a substrate having a first electrode installed in a vacuum-deposited deposition apparatus. At the time of deposition, NPB is 0.4 nm
Evaporation is performed at a film formation rate of / s, and molybdenum oxide evaporates an amount (weight ratio) of 1/4 with respect to NPB. In this case, the molar ratio is NPB: molybdenum oxide = 1: 1. The thickness of the first composite layer including the metal oxide and the organic compound is 50 nm.

Next, on the first composite layer, a PPD in which CBP (4,4′-bis (N-carbazolyl) -biphenyl) is added as a blue light-emitting layer to a region where a blue light-emitting element is to be formed is added.
4,4′-bis (N- (9-phenanthryl) -N-phenylamino) biphenyl) is deposited with a film thickness of 30 nm.

In addition, Alq ₃ to which DCM is added as a red light emitting layer is formed to a thickness of 40 nm in a region where a red light emitting element is to be formed.

In addition, Alq ₃ to which DMQD is added as a green light emitting layer is formed to a thickness of 40 nm in a region where a green light emitting element is to be formed.

Then, a second composite layer including a metal oxide and an organic compound is formed over the blue light-emitting layer, the red light-emitting layer, and the green light-emitting layer. The second composite layer is NPB in the same manner as the first composite layer.
And molybdenum oxide are vapor-deposited. The film thickness of the second composite layer is also 50 nm. Note that the light emission efficiency may be improved by appropriately changing the film thickness of the first composite layer or the second composite layer for each emission color.

Alternatively, a light emitting device capable of full color display capable of obtaining four types of light emission (red, green, blue, and white) may be formed. Further, a light emitting device capable of full color display capable of obtaining four types of light emission (red, green, blue, and emerald green) may be formed. Further, a light emitting device capable of full color display capable of obtaining five types of light emission (red, green, blue, white, and emerald green) may be formed. Further, a light emitting device capable of full color display capable of obtaining five types of light emission (red, green, blue, emerald green, and vermilion yellow) may be formed.

Alternatively, a single layer of light emitting element may be provided over the entire surface, and a light emitting device capable of monochrome display or a light emitting device capable of area color display may be used. Alternatively, a light-emitting device that can emit white light may be a light-emitting device capable of full-color display by being combined with a color filter.

In addition, the light-emitting element is sealed by bonding the second substrate with a sealant. If necessary, a protective film covering the second electrode 116 may be formed. Note that the second substrate is preferably a substrate having a high barrier property against moisture. Further, if necessary, a desiccant may be disposed in a region surrounded by the sealing material.

In the case where the first electrode 113 is a light-reflective conductive material and the second electrode 116 is a light-transmitting conductive material, light emitted from the light-emitting element is allowed to pass through the second substrate. A top emission type light emitting device can be obtained. When an aluminum alloy (Al (C + Ni)) film containing carbon and nickel is used as the first electrode 113 for a single layer or a lower layer of a transparent conductive film, contact with ITO or ITSO even after energization or heat treatment This is preferable because it is a material that does not vary greatly in resistance value.

In the case where the first electrode 113 is a light-transmitting conductive material and the second electrode 116 is a light-reflecting conductive material, light emitted from the light-emitting element is allowed to pass through the first substrate 110. Thus, a bottom emission type light emitting device can be obtained.

In the case where both the first electrode 113 and the second electrode 116 are light-transmitting conductive materials, light emission from the light-emitting element is allowed to pass through the second substrate, and light emission from the light-emitting element is performed. A light-emitting device capable of both passing through the first substrate can be obtained.

  Further, FIG. 7 shows a top view of a light emitting module on which an FPC or the like is mounted after sealing.

The first substrate 301 and the second substrate 310 are attached with a sealant 311 so as to face each other. A photo-curing resin may be used as the sealing material 311, and a material with low degassing and low hygroscopicity is preferable. Further, the sealant 311 may be added with a filler (a rod-like or fiber-like spacer) or a spherical spacer in order to keep the substrate interval constant. The second substrate 310 is preferably made of a material having the same thermal expansion coefficient as that of the first substrate 401.
Glass (including quartz glass) or plastic can be used.

As shown in FIG. 7, the pixel portions constituting the image display intersect so that the scanning line group and the data line group are orthogonal to each other.

The first electrode 113 in FIG. 5B corresponds to the scanning line 302 in FIG.
6 corresponds to the data line 303, and the reverse-tapered partition 122 corresponds to the partition 304. A stack including an organic compound is sandwiched between the data line 302 and the scan line 303, and an intersection indicated by 305 corresponds to one pixel.

Note that the scanning line 303 is electrically connected to the connection wiring 308 at a wiring end, and the connection wiring 308 is connected to the FPC 309 b through the input terminal 307. The data line is input terminal 306.
To the FPC 309a.

Further, if necessary, an optical film such as a polarizing plate or a circular polarizing plate (including an elliptical polarizing plate), a retardation plate (λ / 4 plate, λ / 2 plate), a color filter, or the like is appropriately provided on the exit surface. Also good. Further, an antireflection film may be provided on the polarizing plate or the circularly polarizing plate. For example, anti-glare treatment can be performed that diffuses reflected light due to surface irregularities and reduces reflection. Moreover, you may perform the anti-reflection process which heat-processes to a polarizing plate or a circularly-polarizing plate. Thereafter, in order to protect from external impact, a hard coat treatment may be performed. However, when a polarizing plate or a circularly polarizing plate is used, the light extraction efficiency decreases due to the polarizing plate or the circularly polarizing plate. In addition, the cost of the polarizing plate or the circularly polarizing plate itself is high and easily deteriorates.

The light emitting module shown in FIG. 7 thus obtained is AC driven. Even if the light emitting device of the present invention is driven by alternating current, the light emitting device can emit light with both positive and negative signals, and further when the direct current drive is applied to apply a direct current voltage without increasing the power consumption. Can be obtained.

  This embodiment can be freely combined with the best mode.

In this embodiment, an example of manufacturing a light-emitting module on which an IC chip is mounted is shown below.

First, on a first substrate 401 having an insulating surface, a data line (anode) 402 having a laminated structure in which a lower layer is a reflective metal film and an upper layer is a transparent oxide conductive film is formed. At the same time, connection wirings 408, 409a, 409b and input terminals are also formed.

Next, a partition wall having an opening corresponding to each pixel 405 is provided. Next, a plurality of reverse-tapered partitions 404 that are parallel to each other and intersect the data lines 402 are provided on the partitions having openings.

  FIG. 8A shows a top view at the stage where the steps described above are completed.

Next, a first composite layer containing a metal oxide and an organic compound, a film containing an organic compound, a second composite layer containing a metal oxide and an organic compound, and a transparent conductive film are sequentially stacked. , A layer containing an organic compound that is separated into a plurality of electrically independent regions as shown in FIG.
A scanning line 403 made of a transparent conductive film is formed. The scanning line 403 made of a transparent conductive film is
These are stripe-shaped electrodes extending in parallel to the data line 402 and parallel to each other.

Next, a second substrate 414 having a light-transmitting property is attached with a sealant 413.
Next, the data line side IC 406 and the scanning line side IC 407 in which a driving circuit for transmitting each signal to the pixel portion is formed in the peripheral (outside) region of the pixel portion are mounted by a COG method. C
You may mount using TCP and a wire bonding system as mounting techniques other than OG system. TCP is an IC mounted on a TAB tape, and the IC is mounted by connecting the TAB tape to a wiring on an element formation substrate. The data line side IC 406 and the scanning line side IC 407 are
A silicon substrate may be used, or a driving circuit may be formed with a TFT on a glass substrate, a quartz substrate, or a plastic substrate. In addition, although an example in which one IC is provided on one side is shown, it may be divided into a plurality of parts on one side.

Note that the scanning line 403 is electrically connected to the connection wiring 408 at the wiring end, and the connection wiring 408 is connected to the scanning line side IC 407. This is because the scanning line side IC 407 is reverse-tapered partition 404.
This is because it is difficult to set up.

The data line side IC 406 provided in the above configuration is connected to the FPC 411 through the connection wiring 409 a and the input terminal 410. The scanning line side IC 407 is connected to the connection wiring 40.
9b and the input terminal are connected to the FPC.

Further, an IC chip 412 (memory chip, CPU chip, power supply circuit chip, etc.) is mounted for integration.

FIG. 9 illustrates an example of a cross-sectional structure cut along a chain line CD in FIG.

A base insulating film 511 is provided on the substrate 510, and a data line made of a stack is formed thereon. The lower layer 512 is a reflective metal film, and the upper layer 513 is a transparent oxide conductive film. The upper layer 513 is preferably a conductive film having a high work function. In addition to indium tin oxide (ITO), for example, indium tin oxide containing Si element (ITSO) or indium oxide with 2 to 20% zinc oxide ( IZO (Indium Zinc) mixed with ZnO)
A film containing a transparent conductive material such as Oxide) or a combination of these materials can be used. In particular, ITSO does not crystallize like ITO even when baked and remains in an amorphous state. Therefore, ITSO has higher flatness than ITO, and even if the stack containing the organic compound is thin, short-circuiting with the cathode hardly occurs, and it is suitable as an anode of a light-emitting element.

The lower layer 512 uses an Ag, Al, or Al (C + Ni) alloy film. Above all, A
An l (C + Ni) film (aluminum alloy film containing carbon and nickel (1 to 20 wt%)) is preferable because it is a material that does not change greatly in contact resistance with ITO or ITSO even after energization or heat treatment.

The partition wall 514 is a resin for insulating adjacent data lines, and different colored layers (
It is overlapped with a boundary or a gap between the sealing substrate and the sealing substrate. A region surrounded by the partition walls has the same area corresponding to the light emitting region.

The layer 515 containing an organic compound is laminated in the order of the first composite layer, the EML (light emitting layer), and the second composite layer from the data line (anode) side.

The first composite layer and the second composite layer are composite layers containing a metal oxide and an organic compound,
In this embodiment, a composite layer of tungsten oxide and TPD is used. The EML (light emitting layer) is formed using a light emitting substance. At this time, the light-emitting layer may be formed so that the light-emitting substance is dispersed and included in a layer made of a substance having an energy gap larger than that of the light-emitting substance. By dispersing the light emitting substance, quenching due to concentration can be prevented. Here, there is no particular limitation on the light-emitting substance, and when red light emission is desired, for example, 4-dicyanomethylene-2-isopropyl-6- [2- (1,1,7
, 7-Tetramethyljulolidin-9-yl) ethenyl] -4H-pyran (abbreviation: DCJ
TI), 4-dicyanomethylene-2-methyl-6- [2- (1,1,7,7-tetramethyljulolidin-9-yl) ethenyl] -4H-pyran (abbreviation: DCJT), 4-dicyano Methylene-2-tert-butyl-6- [2- (1,1,7,7-tetramethyljulolidin-9-yl) ethenyl] -4H-pyran (abbreviation: DCJTB), periflanthene,
Emission spectrum peaks from 600 nm to 680 nm, such as 2,5-dicyano-1,4-bis [2- (10-methoxy-1,1,7,7-tetramethyljulolidin-9-yl) ethenyl] benzene. A substance that exhibits light emission may be used as the light-emitting substance. When green light emission is desired, N, N′-dimethylquinacridone (abbreviation: DMQd), coumarin 6 or coumarin 545T, tris (8-quinolinolato) aluminum (abbreviation: Alq ₃ )
For example, a substance that emits light having a peak of an emission spectrum from 500 nm to 550 nm may be used as the light-emitting substance. When it is desired to obtain blue light emission, 9,10-bis (2-
Naphthyl) -tert-butylanthracene (abbreviation: t-BuDNA), 9,9′-bianthryl, 9,10-diphenylanthracene (abbreviation: DPA), 9,10-bis (2-
Naphthyl) anthracene (abbreviation: DNA), bis (2-methyl-8-quinolinolato) -4
-Phenylphenolato-gallium (abbreviation: BGaq), bis (2-methyl-8-quinolinolato) -4-phenylphenolato-aluminum (abbreviation: BAlq), etc., emit light having an emission spectrum peak from 420 nm to 500 nm. A substance may be used as a light-emitting substance. There is no particular limitation on a substance used with the luminescent substance to disperse the luminescent substance. For example, anthracene such as 9,10-di (2-naphthyl) -2-tert-butylanthracene (abbreviation: t-BuDNA) is used. In addition to derivatives or carbazole derivatives such as 4,4′-bis (N-carbazolyl) biphenyl (abbreviation: CBP), bis [2- (2-hydroxyphenyl) pyridinato] zinc (abbreviation: Znpp ₂ ), bis [2 A metal complex such as-(2-hydroxyphenyl) benzoxazolate] zinc (abbreviation: ZnBOX) can be used.

The EML can take a laminated structure or a mixed structure in addition to a single layer structure.

The scanning line 516 (cathode) is formed so as to intersect the data line (anode). Scan line 5
16 (cathode) uses a transparent conductive film such as ITO, indium tin oxide containing Si element (ITSO), or IZO in which 2 to 20% zinc oxide (ZnO) is mixed with indium oxide. In this embodiment, since it is an example of a top emission type light emitting device in which light emission passes through the sealing substrate 520, it is important that the scanning line 516 is transparent.

In addition, a transparent protective film that covers the scan line 516 may be provided in order to protect the light-emitting element from damage due to moisture or degassing. As a transparent protective film, a dense inorganic insulating film (SiN, SiNO film, etc.) by PCVD method, or a dense inorganic insulating film (SiN, SiNO film) by sputtering method is used.
It is preferable to use a thin film containing carbon as a main component (DLC film, CN film, amorphous carbon film), metal oxide film (WO ₂ , CaF ₂ , Al ₂ O _3, etc.). What is transparency?
It indicates that the visible light transmittance is 80 to 100%.

In addition, the pixel portion including the light-emitting element is sealed with a sealant 519 and a sealing substrate 520 so that the enclosed space is hermetically sealed.

As the sealing material 519, ultraviolet curable resin, thermosetting resin, silicone resin, epoxy resin, acrylic resin, polyimide resin, phenol resin, PVC (polyvinyl chloride),
PVB (polyvinyl butyral) or EVA (ethylene vinyl acetate) can be used. Further, the sealing material may be a filler added with a filler (bar-shaped or fiber-shaped spacer) or a spherical spacer.

Further, a glass substrate or a plastic substrate is used as the sealing substrate 520. As the plastic substrate, polyimide, polyamide, acrylic resin, epoxy resin, PES (polyethylene sulfide), PC (polycarbonate), PET (polyethylene terephthalate) or PEN (polyethylene naphthalate) may be used in the form of a plate or film. it can.

The sealed space 518 is filled with a dry inert gas. A small amount of moisture is removed from the inner sealed space 518 surrounded by the sealant 519 with the desiccant 517, and is sufficiently dried. As the desiccant 517, a substance that absorbs moisture by chemical adsorption such as an oxide of an alkaline earth metal such as calcium oxide or barium oxide can be used. As another desiccant, a substance that adsorbs moisture by physical adsorption, such as zeolite or silica gel, may be used.

On the other hand, a terminal electrode is formed at the end of the substrate 510, and an FP connected to an external circuit at this portion.
C (flexible printed wiring board) 532 is bonded together. The terminal electrode includes a stacked layer of a reflective metal film 530, a transparent oxide conductive film 529, and an oxide conductive film extending from the second electrode, but is not particularly limited.

As a method for mounting the FPC 532, a connection method using an anisotropic conductive material or a metal bump, or a wire bonding method can be adopted. In FIG. 9, the anisotropic conductive adhesive 531
Is used for connection.

Further, around the pixel portion, an IC chip 523 in which a driving circuit for transmitting each signal to the pixel portion is formed is electrically connected by anisotropic conductive materials 524 and 525. In order to form a pixel portion corresponding to color display, the number of data lines is 3072 in the XGA class, and 768 scanning lines are required. The data lines and scanning lines formed in such numbers are divided into several blocks at the end of the pixel portion to form lead lines, which are collected according to the pitch of the output terminals of the IC.

  This embodiment can be freely combined with the best mode or embodiment 1.

In this example, an example in which an optical film is provided will be described with reference to FIG.

An optical film 621 is provided over a second substrate 620 provided to face the first substrate 610. In this embodiment, an example in which light is emitted in the direction indicated by an arrow in FIG. 10A, that is, an example in which light emitted from the light emitting element passes through the second substrate 620 and then passes through the optical film 621 is shown. However, there is no particular limitation, and an optical film may be provided on the first substrate side, and light emitted from the light-emitting element may pass through the second substrate 620 after passing through the optical film 621.

The optical film 621 includes a polarizing plate, a circular polarizing plate (including an elliptical polarizing plate), a retardation plate (λ /
4 plates, λ / 2 plates), and optical films such as color filters.

The light-emitting elements in the pixels of the passive matrix light-emitting device are the same as in the first embodiment.
12 is a reflective metal film, the upper layer 613 is a transparent oxide conductive film, a data line (anode) having a laminated structure, a first material layer 615a, a layer 615b containing an organic compound, a second material The layer 615c and the scanning line 616 made of a transparent conductive film are included. In addition, the partition wall 614
Is made of a resin material.

Note that the first material layer 615a and the second material layer 615c are formed using a metal oxide (such as molybdenum oxide, tungsten oxide, or rhenium oxide) and an organic compound (a material having a hole transporting property).
It is a composite layer. With such a stacked structure of light emitting elements, a light emitting element suitable for AC driving is obtained.

When a circularly polarizing plate is used as the optical film 621, it is possible to prevent external light from being reflected on the lower layer 612 and the visibility of the image from being lowered. Specifically, the circularly polarizing plate means λ / 4, λ /
Refers to a circularly polarizing plate (including an elliptically polarizing plate) composed of a combination of a retardation plate, retardation film, or retardation film having a retardation characteristic of 4 + λ / 2 and a polarizing plate, a polarizing film, or a linear polarizing film. ing. The broadband λ / 4 plate here gives a constant phase difference (90 degrees) in the visible light range. Specifically, a circularly polarizing plate is set so that the angle formed by the transmission axis of the polarizing plate and the slow axis of the retardation film is 45 °. In this specification,
The circularly polarizing plate includes a circularly polarizing film.

Further, when the light emitting element is a white light emitting element and a color filter is used as the optical film 621, full color display can be realized.

  A plurality of types of optical films may be appropriately combined.

In addition, this embodiment can be freely combined with the best mode, embodiment 1, or embodiment 2.

In this embodiment, an example of a bottom emission light-emitting device will be described with reference to FIG.

The light-emitting element in this example has a data line (anode) 713 formed of a transparent oxide conductive film, a first material layer 715a, a layer 715b containing an organic compound, a second material layer 715c, and reflectivity. And a scanning line 716 made of a conductive film. Further, the partition 714 is made of a resin material as in the third embodiment.

Note that the first material layer 715a and the second material layer 715c are formed using a metal oxide (such as molybdenum oxide, tungsten oxide, or rhenium oxide) and an organic compound (a material having hole transporting properties).
It is a composite layer. With such a stacked structure of light emitting elements, a light emitting element suitable for AC driving is obtained.

Light emitted from the light-emitting element is extracted in a direction indicated by an arrow in FIG. 6B, that is, a direction passing through the first substrate 710. Therefore, the second substrate 721 does not need to have a light transmitting property and may be a metal plate. Further, a thick protective film 717 is provided to improve the reliability of the light emitting element.
Even if formed, it is preferable because the light extraction efficiency does not decrease.

This embodiment can be freely combined with the best mode, embodiment 1, embodiment 2, or embodiment 3. For example, in the case where an optical film is provided in combination with the present example and Example 3, an optical film may be provided on the first substrate 710.

In this example, an example in which the light-emitting device is different from those in Example 1, Example 2, Example 3, and Example 4 will be described with reference to FIG.

The light-emitting element in this example includes a data line (anode) 813 made of a transparent oxide conductive film, a first material layer 815a, a layer 815b containing an organic compound, a second material layer 815c, and a transparent oxide. The scanning line 816 is made of a material conductive film. The partition wall 814 is the same as that of the first embodiment.
It is comprised with the resin material similarly to.

Note that the first material layer 815a and the second material layer 815c are formed using a metal oxide (such as molybdenum oxide, tungsten oxide, or rhenium oxide) and an organic compound (a material having a hole transporting property).
It is a composite layer. With such a stacked structure of light emitting elements, a light emitting element suitable for AC driving is obtained.

Light emitted from the light-emitting element is extracted in both the direction indicated by the arrow in FIG. 10C, that is, the direction passing through the first substrate 810 and the direction passing through the second substrate 820. Therefore, the first
As the substrate 810 and the second substrate 820, substrates having optical transparency are used.

This embodiment can be freely combined with the best mode, embodiment 1, embodiment 2, or embodiment 3. For example, in the case where an optical film is provided in combination with this example and Example 3, the optical film may be provided on both the first substrate 810 and the second substrate 820.

As a light emitting device and an electronic device of the present invention, a video camera, a digital camera, a navigation system, an audio playback device (car audio, audio component, etc.), a notebook computer, a game device, a portable information terminal (mobile computer, mobile phone, mobile phone) Type game machine or electronic book), and an image playback device (specifically, Digital Versatile Disc) provided with a recording medium
(A device provided with a display capable of reproducing a recording medium such as (DVD) and displaying the image). Specific examples of these electronic devices are shown in FIGS.

A mobile phone shown in FIG. 11 includes a main body (A) 901 provided with operation switches 904, a microphone 905, and the like, a main body (A) 908, a display panel (B) 909, a speaker 906, and the like ( B) 902 is connected with a hinge 910 so that it can be opened and closed. The display panel (A) 908 and the display panel (B) 909 include a main body (
B) Housed in a housing 903 of 902. Display panel (A) 908 and display panel (B
) The pixel portion 909 is arranged so as to be visible from an opening window formed in the housing 903.

In the display panel (A) 908 and the display panel (B) 909, specifications such as the number of pixels can be set as appropriate in accordance with the function of the mobile phone 900. For example, display panel (A) 908
Can be combined as a main screen and the display panel (B) 909 can be combined as a sub-screen.

A display panel (A) 908 has the configuration capable of AC driving described in any one of Embodiments 1 to 5. According to the present invention, even when the display panel (A) 908 is AC driven, the total power consumption of the mobile phone can be suppressed without causing an increase in driving voltage. Similarly, the display panel (B) 909 may also be AC driven, and the total power consumption of the mobile phone can be suppressed without causing an increase in driving voltage.

The mobile phone according to the present embodiment can be transformed into various modes according to the function and application.
For example, a mobile phone with a camera may be obtained by incorporating an image sensor at the hinge 910. Further, even when the operation switches 904, the display panel (A) 908, and the display panel (B) 909 are housed in one housing and integrated, the above-described effects can be obtained. Further, even when the configuration of the present embodiment is applied to an information display terminal having a plurality of display units, the same effect can be obtained.

FIG. 12A illustrates a television, which includes a housing 2001, a support base 2002, a display portion 2003, a speaker portion 2004, a video input terminal 2005, and the like. The present invention can realize a television with reduced power consumption by using a display portion 2003 incorporated in the television as an AC drive. Note that all information display televisions such as personal computers, TV broadcast reception, and advertisement display are included.

FIG. 12B illustrates a digital camera, which includes a main body 2101, a display portion 2102, and an image receiving portion 210.
3, an operation key 2104, an external connection port 2105, a shutter 2106, and the like. The present invention can provide a digital camera with reduced power consumption by alternating current driving the display unit 2102 incorporated in the digital camera.

FIG. 12C illustrates a personal computer, which includes a main body 2201, a housing 2202, a display portion 2203, a keyboard 2204, an external connection port 2205, and a pointing mouse 220.
6 etc. are included. The present invention can be applied to the display portion 2203 incorporated in the personal computer, and a personal computer with reduced power consumption can be realized by using the display portion as an AC drive.

FIG. 12D illustrates an electronic book, which includes a main body 2301, a display portion 2302, a switch 2303,
An operation key 2304, an infrared port 2305, and the like are included. The present invention can realize an electronic book with reduced power consumption by using an AC drive for a display portion 2302 incorporated in the electronic book.

FIG. 12E shows a portable image reproducing device (specifically, a DVD reproducing device) provided with a recording medium.
A main body 2401, a housing 2402, a display portion A 2403, a display portion B 2404, a recording medium (DVD or the like) reading portion 2405, operation keys 2406, a speaker portion 2407, and the like.
A display portion A2403 mainly displays image information, and a display portion B2404 mainly displays character information. The present invention relates to a display portion A2403 and a display portion B2404 built in the image reproduction apparatus.
Can be realized with an AC drive, and an image reproducing apparatus with reduced power consumption can be realized.

FIG. 12F illustrates a portable game machine, which includes a main body 2501 and display portions 2503 and 2505.
Operation switch 2504 and the like. A portable game device with reduced power consumption can be realized by alternating current driving a semiconductor integrated circuit (memory, CPU, or the like) incorporated in the game device and the display portions 2503 and 2505.

FIG. 12G illustrates a video camera, which includes a main body 2601, a display portion 2602, a housing 2603,
External connection port 2604, remote control receiving unit 2605, image receiving unit 2606, battery 260
7, voice input unit 2608, operation key 2609, and the like. The present invention can realize a video camera with reduced power consumption by using a semiconductor integrated circuit (a memory, a CPU, and the like) incorporated in the video camera and a display portion 2602 as AC drive.

Further, this embodiment can be freely combined with Embodiment Mode, Embodiment 1, Embodiment 2, Embodiment 3, Embodiment 4, or Embodiment 5.

According to the present invention, the structure of an EL element using an AC driving method can be simplified, and the manufacturing process can be simplified. Further, according to the present invention, since the thickness between the pair of electrodes can be increased without causing an increase in driving voltage, it is possible to suppress a short circuit of the element due to dust in the EL element forming process, Yield is improved.

10: substrate having an insulating surface 11: first electrode 12: first material layer 13: layer containing an organic compound 14: second material layer 15: second electrode 16: AC power supply

Claims (5)

A light emitting device having a plurality of light emitting elements, wherein the light emitting elements are:
A first electrode;
A first composite comprising a film in which molybdenum oxide, DNTPD, and rubrene are simultaneously vapor-deposited on the first electrode in an arbitrary ratio, or a film in which molybdenum oxide, BBPB, and rubrene are simultaneously vapor-deposited in an arbitrary ratio. A membrane,
A layer containing an organic compound on the first composite film;
A second film comprising a film in which molybdenum oxide, DNTPD, and rubrene are simultaneously vapor-deposited in an arbitrary ratio on the layer containing the organic compound, or a film in which molybdenum oxide, BBPB, and rubrene are simultaneously vapor-deposited in an arbitrary ratio. A composite membrane;
The light emitting device characterized by having a second electrode on the second composite film. Oite to claim 1, wherein the first composite film, the light emitting device characterized by comprising a different material than said second composite film. Oite to claim 1, wherein the first composite film, the light emitting device characterized by comprising the same material as the second composite film. A light emitting device having a plurality of light emitting elements, wherein the light emitting elements are:
A first electrode;
A first composite film containing molybdenum oxide and NPB on the first electrode;
A layer containing an organic compound on the first composite film;
A second composite film containing molybdenum oxide and NPB on the layer containing the organic compound;
A light emitting device comprising: a second electrode on the second composite film. A light emitting device having a plurality of light emitting elements, wherein the light emitting elements are:
A first electrode;
A first composite film comprising tungsten oxide and TPD on the first electrode;
A layer containing an organic compound on the first composite film;
A second composite film containing tungsten oxide and TPD on the organic compound-containing layer;
A light emitting device comprising: a second electrode on the second composite film.

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