JP4854976B2 - Makeup cosmetics - Google Patents

Description

  The present invention relates to a makeup cosmetic, and more particularly to a makeup cosmetic suitable for a foundation or makeup base containing a pearl luster pigment.

  One of the important roles of foundations and makeup bases is to hide or blur skin defects (stains, wrinkles, dullness, pores, etc.). A lot is happening.

  In response to these demands, for example, a method of correcting defects such as pores and dullness while adjusting the blending amount of colored pigments such as titanium oxide and iron oxide, and spherical powder while maintaining a feeling of bare skin and transparency (see Patent Document 1). In this case, there is a problem that the skin quality becomes a so-called “matte” and natural gloss cannot be obtained.

  On the other hand, when a general mica titanium pigment having a pearly luster (average particle size of 20 μm or more) is blended, the reflection interference light of titanium mica is absorbed and scattered by the colored pigment to give brightness. The effect to do is not fully obtained. Conversely, when pearl pigments are blended to such an extent that the brightness of the finish (feel of gloss) can be realized, the difference in brightness depending on the viewing angle of the pearl pigment and the viewing angle increases, resulting in an unnatural finish. There is a problem that unevenness is conspicuous.

Japanese Patent Application No. 08-181581

  An object of the present invention is to provide a cosmetic that corrects defects of the skin as a makeup cosmetic, has a smooth usability and does not have a matte finish and has a natural luster (glossy feeling).

  In order to achieve the above-mentioned object, the present inventor has intensively studied, and as a result, the blending amount of the color pigment is less than 0.5% by mass, in particular, no blending, and by using a specific fine particle pearling agent, It was found that the covering power and natural gloss can be made compatible, and a smoother feeling can be obtained.

That is, in the present invention, 1 to 2 or more types (component (A)) selected from pearl luster pigments having an average particle size of 15 μm or less are blended in an amount of 3 to 15% by mass,
Even if the color pigment (component (B)) is not blended or blended, the total blending amount is less than 0.5% by mass,
When 8 mg / cm ^{2 is} applied to black cowhide leather, the colorimetric values before application (L0 ^* , a0 ^* , b0 ^* ) and the colorimetric values after application specified by the CIE1976L ^* a ^* b ^* color system ( A makeup cosmetic characterized in that a value represented by ΔL ^* (ΔL ^* = L1 ^* −L0 ^* ) obtained from L1 ^* , a1 ^* , b1 ^* ) is 40 to 65.

  The makeup cosmetic of the present invention corrects the defects of the skin, has a smooth usability and has a natural luster (shiny feeling) without a matte finish, has a visual lift-up effect, It can provide foundations and makeup bases that give youthful face impressions.

Details of the present invention will be described below.
(A) Pearly luster pigment The pearly luster pigment having an average particle size of 15 μm or less used for the component (A) of the present invention is a powdery pigment having a pearly luster or metallic appearance. As the pearl pigment, generally, mica titanium, bismuth oxychloride, fish scale foil, and the like are used.
Titanium mica is obtained by coating a layer of titanium dioxide on the surface of mica made of smooth flaky particles. Moreover, it can coat | cover with an iron oxide instead of a titanium dioxide, and can coat | cover a transparent pigment further on the coating layer of a titanium oxide. For example, after the inorganic salt of titanium such as titanyl sulfate or titanium tetrachloride is decomposed by neutralization or hydrolysis in the presence of mica to precipitate hydrous titanium oxide or titanium dioxide, Preferably, it is produced by a method of baking at a temperature of 700 to 900 ° C. (Japanese Patent Publication No. 43-25644). In addition, when making the titanium oxide to coat | cover into a rutile type, it can obtain by coat | covering a titanium oxide, after precipitating a small amount of tin oxide on mica beforehand.

  Here, examples of mica used include muscovite, biotite, phlogopite, and synthetic mica.

  In addition, the pearl luster pigment having an average particle size of 15 μm or less used for the component (A) of the present invention has little dot feeling, good elongation spread on the skin, and is naturally finished while sufficiently hiding the skin. preferable. The average particle diameter is a volume average diameter measured by a laser diffraction / scattering method using a laser diffraction / scattering particle size distribution analyzer (for example, Nikkiso Co., Ltd., Microtrac HRA). (A) The average particle diameter of a component becomes like this. More preferably, it is 0.5-15 micrometers.

  The pearl pigment used in the present invention may be used as it is or may be subjected to a hydrophobic treatment. Moreover, it may be hydrophobized during the cosmetic production process. Hydrophobing treatment includes silicone treatment typified by methylhydrogenpolysiloxane, various organo-modified silicone treatments, dimethylpolysiloxane treatment, fatty acid dextrin treatment, silane coupling treatment typified by octyltriethoxysilane, and stearic acid. Examples include, but are not limited to, fatty acid treatment, metal soap treatment, fluorine treatment represented by perfluoroalkyl phosphate diethanolamine salt, and alkylated amino acid. Specifically, a method of treating powder with methylhydrogenpolysiloxane, (methylhydrogenpolysiloxane / dimethylpolysiloxane) copolymer, dextrin palmitate, n-octyltriethoxysilane, or treatment with tetramethylcyclotetrasiloxane A method of adding tetradecene later is mentioned.

In the present invention, the pearl pigment is preferably titanium oxide-coated mica, and particularly preferably titanium oxide-coated mica that has been hydrophobized. The appearance color is preferably white to light yellow, and the crystal type is preferably a rutile type. Further, a fine type having an average particle diameter of 0.5 to 15 μm is preferable.
Suitable examples of the pearl pigment used in the present invention include a prestige silk series manufactured by ECKART, and a chimiron super silk series manufactured by Merck.

  The compounding quantity of the pearl luster pigment in the makeup cosmetics of this invention is 3-15 mass%, Preferably it is 3-10 mass%. If it is less than 3% by mass, it is difficult to obtain a natural gloss, and if it exceeds 15% by mass, the gloss becomes strong and unnatural.

(B) Colored pigment In the present invention, the colored pigment (B) is an optional blending component, and even when blended, the blending amount is less than 0.5% by mass.
Examples of the color pigment (B) include inorganic white pigments (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigments (eg, iron oxide (Bengara), iron titanate, etc.); inorganic brown pigments (eg, γ- Inorganic yellow pigments (for example, yellow iron oxide, loess); Inorganic black pigments (for example, black iron oxide, low-order titanium oxide); Inorganic purple pigments (for example, manganese violet, cobalt violet) Inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); Inorganic blue pigments (eg, ultramarine blue, bitumen, etc.); Metal powder pigments (eg, aluminum powder, copper powder, etc.); Organic pigments such as zirconium, barium or aluminum lakes (for example, red 201, red 202, red 204, red 205, red 220, red 226) Organic pigments such as red 228, red 405, orange 203, orange 204, yellow 205, yellow 401, and blue 404, red 3, red 104, red 106, red 227, red 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1); natural pigments (eg chlorophyll, β- Carotene and the like).

  The blending amount of the color pigment in the makeup cosmetic of the present invention is less than 0.5% by mass, preferably no blending. By making the prescription only with the fine particle pearl agent, it is possible to achieve both a covering power and a natural gloss, and a smoother feeling of use can be obtained. If the blending amount of the color pigment exceeds 0.5% by mass, the glossiness is lost, which is not preferable.

Regarding the concealability of the resulting makeup cosmetic, when 8 mg / cm ^{2 is} applied to black cowhide leather, the colorimetric values (L0 ^* , a0 ^* , b0 before application) specified by the CIE1976L ^* a ^* b ^* color system ^*) and colorimetric values after application (L1 ^*, a1 ^*, the value represented by b1 ^*) from ^{ΔL * (ΔL * = L1 *} -L0 *) is preferably a 40 to 65.
If it is less than 40, the hiding property is insufficient and the effect of correcting the skin defect is insufficient, and if it exceeds 65, the skin defect can be sufficiently corrected, but the gloss (luster feeling) as makeup skin becomes strong and natural. Is unfavorable because it is damaged.

  About the said measurement, it can measure with the color measuring apparatus (CM series) made from Minolta, for example.

(C) Spherical powder In this invention, it is preferable to mix | blend spherical powder, and spherical resin powder is especially preferable. The spherical resin powder is not particularly limited as long as it can be usually blended into cosmetics and pharmaceuticals. For example, polyamide resin (nylon powder) polyethylene powder, polymethyl methacrylate powder, polyurethane powder, polystyrene powder, polyalkyl acrylate powder, copolymer resin powder of styrene and acrylic acid, silicone powder, cross-linked silicone powder, etc. It is done. More specifically, trimethylsilsesquioxane powder (Tospearl 145A manufactured by Toshiba Silicone), cross-linked silicone powder (Trefyl E-506 manufactured by Toray Dow Corning), polymethacrylate silica (Matsumoto Microsphere M-330) Matsumoto Yushi Co., Ltd.).
Examples of the spherical inorganic powder include silica powder (Sunsphere L-51, manufactured by Dokai Chemical Co., Ltd.).

  The average particle size of the spherical powder used in the present invention is preferably 0.5 to 15 μm, more preferably 1 to 10 μm.

  1-20 mass% is preferable, and, as for the compounding quantity of the spherical powder in the makeup cosmetics of this invention, More preferably, it is 3-15 mass%. By adding the spherical powder, a smooth feeling of use is obtained, and when it is used in excess of 20% by mass, it tends to slip upward, which is not preferable.

The components that can be blended in the present invention are listed below, but are not limited thereto.
Examples of the powder component include inorganic powders (for example, talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, silicic acid. Aluminum, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder Metal soap (for example, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, and the like.

  Examples of liquid oils include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern castor oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.

  Examples of the solid fat include cacao butter, coconut oil, hardened coconut oil, palm oil, palm kernel oil, owl kernel oil, hardened oil, owl, and hardened castor oil.

  Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, Examples include jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, ceresin, and microcrystalline wax.

  Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, squalene, petrolatum and the like.

  Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), and the like. Is mentioned.

  Examples of higher alcohols include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyl decanol, isostearyl alcohol, octyldodecanol and the like.

  Examples of ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, lactic acid Myristyl, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, monoisostearate N-alkyl glycol, neopentyl glycol dicaprate, Diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trime triisostearate Roll propane, tetra-2-ethylhexanoic acid pentaerythritol, tri-2-ethylhexanoic acid glycerin, trioctanoic acid glycerin, triisopalmitic acid glycerin, triisostearic acid trimethylolpropane, cetyl 2-ethylhexanoate, 2-ethylhexyl Palmitate, glyceryl trimyristate, glyceride tri-2-heptylundecanoate, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid 2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyl adipate Decyl, diisopropyl sebacate, 2-ethylhexyl succinate, and triethyl citrate.

  Examples of the silicone oil include linear polysiloxanes (for example, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexyl). And silicone resins that form a three-dimensional network structure, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) It is done.

  Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, Sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate); glycerin polyglycerin fatty acids (eg mono cottonseed oil fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin, monostearin) Glycerin acid, α, α'-oleic acid pyroglutamate glycerin, monostearic acid glycerin malic acid, etc.); propylene glycol fatty acid esters (eg monostearies) Propylene glycolate, etc.); hardened castor oil derivative; glycerin alkyl ether, etc.

  Examples of hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE sorbite fatty acid esters (eg POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, etc.); POE-glycerin fatty acid esters (eg POE-glycerin) Monostearate, POE-glycerol monoisostearate, POE-monooleate such as POE-glycerol triisostearate, etc.); POE-fatty acid esters (for example, POE-distearate, POE-monodiolate, ethylene glycol distearate, etc.); POE-alkyl ethers (eg POE- Uril ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); POE / POP-alkyl ethers (eg POE / POP-cetyl ether) POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether, etc.); POE-castor oil hardened castor oil derivatives (eg, POE-castor) Oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE-hardened castor oil triisostearate, POE-hardened castor oil monopyroglutamic acid monoisostearic acid diester, POE-hardened castor oil maleic acid, etc.) POE-beeswax lanolin derivatives (for example, POE-sorbit beeswax); alkanolamides (for example, coconut oil fatty acid diethanol); Bromide, lauric acid monoethanolamide, fatty acid isopropanol amide and the like); POE- propylene glycol fatty acid esters; POE- alkylamine; POE- fatty amides; sucrose fatty acid esters; trioleyl phosphoric acid and the like.

  Examples of the humectant include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate , Sodium lactate, Bile salt, dl-Pyrrolidone carboxylate, Short chain soluble collagen, Diglycerin (EO) PO adduct, Izayoi rose extract, Achillea millefolium extract, Merilot extract, Trehalose, Erythritol, POE / POP random Examples include copolymer methyl ether.

  Examples of the thickener include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropyl Cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, cellulose dialkyldimethylammonium sulfate, xanthan gum, magnesium aluminum silicate, bentonite, hectorite, AlMg silicate (Beegum), Examples thereof include laponite and silicic anhydride.

Examples of the ultraviolet absorber include the following compounds.
(1) Benzoic acid ultraviolet absorbers For example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester and the like.

(2) Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate.

(3) Salicylic acid ultraviolet absorbers such as amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, and the like.

(4) Cinnamic acid UV absorbers For example, octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4- Diisopropyl cinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxy Ethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl -Diparamethoxycinnamate.

(5) Triazine-based ultraviolet absorber, for example, bisresorcinyl triazine.
More specifically, bis {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) 1,3,5-triazine, 2,4,6-tris { 4- (2-ethylhexyloxycarbonyl) anilino} 1,3,5-triazine and the like.

(6) Other UV absorbers For example, 3- (4'-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor, 2-phenyl-5-methylbenzoxazole, 2,2 '-Hydroxy-5-methylphenylbenzotriazole, 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole, 2- (2'-hydroxy-5'-methylphenylbenzotriazole, dianisoylmethane, 4-methoxy-4'-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one, pyridazine derivatives such as dimorpholinopyridazinone.

  Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate. Sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyl triacetate and the like.

  Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

  Examples of amino acids include alanine, serine, glycine acyl glutamate, glutathione, pyrrolidone carboxylic acid and the like.

  Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Is mentioned.

  Examples of the polymer emulsion include an acrylic resin emulsion, a polyethyl acrylate emulsion, an acrylic resin liquid, a polyacryl alkyl ester emulsion, a polyvinyl acetate resin emulsion, and a natural rubber latex.

  Examples of the pH adjuster include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.

  Examples of vitamins include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.

  Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.

  Examples of the antioxidant assistant include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

  Examples of other components that can be added include preservatives (methyl paraben, ethyl paraben, butyl paraben, phenoxyethanol, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, thiotaurine, hypotaurine, hinokitiol, zinc oxide, allantoin, etc.) Whitening agents (for example, Yukinosita extract, arbutin, tranexamic acid, L-ascorbic acid, L-ascorbic acid phosphate magnesium salt, L-ascorbic acid glucoside, 4-methoxysalicylic acid potassium, etc.); various extracts (for example, Awaku, Auren, Shikon, Peonies, Assemblies, Birch, Sage, Loquat, Carrot, Aloe, Venetian, Iris, Grapes, Yokuinin, Loofah, Lily, Saffron, Senkyu, Ginger, Hypericum Ononisu, garlic, pepper, citrus unshiu peel, angelica, seaweed, etc.), activator (e.g., royal jelly, photosensitizer, cholesterol derivatives, etc.); blood circulation promoter, and the like.

  The makeup cosmetic of the present invention can be prepared by mixing the ingredients usually blended into the makeup cosmetic and the above-mentioned ingredients into a desired dosage form according to a conventional method. As the makeup cosmetic of the present invention, a foundation or a makeup base is suitable.

  Next, the present invention will be described more specifically with reference to examples. The present invention is not limited by these examples. The blending amount is a mass percentage (mass%) based on the total amount unless otherwise specified.

Examples 1-5, Comparative Examples 1-3
(4) to (7) are mixed and pulverized (1) or (2) and (3) are added and stirred, and (8) to (11) are dissolved based on the prescriptions in Tables 1 and 2 What was made to add was mixed and the W / O emulsification foundation was prepared. Next, a predetermined amount was applied to black leather, and after drying, color measurement was performed using a color measuring device manufactured by Minolta. In addition, seven expert panelists evaluated the skin defect correction effect and the sensory effect related to natural glossiness by the following methods.

(1) Measurement of ΔL ^* 8 mg / cm ^{2 of the} obtained foundation was applied to black cowhide leather, and after drying, ΔL ^* was measured with a color measuring device (CM series) manufactured by Minolta.
Measurement is based on colorimetric values before coating (L0 ^* , a0 ^* , b0 ^* ) and colorimetric values after coating (L1 ^* , a1 ^* , b1 ^* ) specified in the CIE1976L ^* a ^* b ^* color system. ΔL ^* (ΔL ^* = L1 ^* −L0 ^* ) was determined. The results are shown in Tables 1 and 2.

(2) Sensory evaluation The following criteria evaluated the defect correction effect on the skin and the natural glossiness. The results are shown in Tables 1 and 2.
[Evaluation criteria]
3 points: very effective 2 points: effective 1 point: somewhat effective 0 point: no effect [overall evaluation]
◎: The average of 7 people is 3 or more and 4 or less ○: The average of 7 people is 2 or more and less than 3 points △: The average of 7 people is 1 or more and less than 2 points ×: The average of 7 people is 0 or more and 1 Less than

  In Examples 1 to 5, the content of (1) which is (A) a pearl pigment is 3 to 15% by mass, and (B) the color pigment is less than 0.5%. Examples 1 to 5 were excellent in the effect of correcting skin defects, and the finish was also good with a natural glossy feeling.

In the following, other examples which have a skin defect correcting effect and exhibit a finish with a natural glossy feeling can be listed. Here, Examples 7, 10, and 11 are reference examples not included in the present invention.

Example 6: Solid foundation α-olefin oligomer 3% by mass
Dimethylpolysiloxane 8
Methyl hydrogen polysiloxane 0.5
Sorbitan sesquiisostearate 1
Calcium hydrogen phosphate 3
Palmitic acid dextrin treated pearl 9
(Pearl pigment, average particle size 5μm)
n-Octyltriethoxysilane treated pearl 5
(Free stage silklet (average particle size 11μm), manufactured by ECKART)
n-Octyltriethoxysilane treated pearl 10
(Fresh stage silk cord (average particle size 11μm), manufactured by ECKART)
Alkyl modified silicone resin coated talc 5
Low temperature calcined zinc oxide 5
Barium sulfate 2
Firing sericite 15
Talc 10
Phlogopite residual spherical polymethylsilsesquioxane powder (spherical resin powder, average particle size 5 μm,
Tospearl 147A manufactured by Toshiba Silicone Co. 3
Cross-linked silicone powder (spherical resin powder, average particle size 5 μm
Trefill E-506) 5
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Thiotaurine 0.1
P-Hydroxybenzoate appropriate amount 2-methoxyhexyl paramethoxycinnamate 3
Silicic anhydride 1

Example 7: Solid makeup base α-olefin oligomer 10% by mass
Microcrystalline wax 0.5
Ceresin 5
Dimethylpolysiloxane 15
Methylphenylpolysiloxane 10
Macadamia nut oil 0.1
Carnauba 0.1
Glyceryl tri-2-ethylhexanoate 7
Cetyl 2-ethylhexanoate 10
Sorbitan sesquiisostearate 1.5
Mica 0.5
Aluminum stearate 1
Cross-linked silicone powder 8
(Spherical resin powder, average particle size 5 μm, Trefil E-506)
N-lauroyl-L-lysine 0.1
D-δ-tocopherol appropriate amount silicone-treated mica pearl 9
(Timiron Supersilk MP-1005 (average particle size 7μm), manufactured by Merck)
Calcium alginate powder 1
Nylon powder Residual spherical silica 1

Example 8: W / O type emulsifying foundation microcrystalline wax 5% by mass
Dimethylpolysiloxane 10
Decamethylcyclopentasiloxane 15
Polyoxyethylene / methylpolysiloxane copolymer 2
Dipropylene glycol 3
Palmitic acid 0.5
Sorbitan sesquiisostearate 1
n-Octyltriethoxysilane treated pearl 8
(Timiron supersilk MP-1005 (average particle size 5μm), Hydrophobized product by Merck)
n-Octyltriethoxysilane treated pearl 5
(Free stage silklet (average particle size 11μm), manufactured by ECKART)
n-Octyltriethoxysilane treated pearl 10
(Fresh stage silk cord (average particle size 11μm), manufactured by ECKART)
Alkyl-modified silicone resin-coated silicic acid anhydride 2
Alkyl-modified silicone resin coated sericite 10
Cross-linked silicone powder 3
(Spherical resin powder, average particle size 5 μm, Trefill E-506)
N-lauroyl-L-lysine 0.1
Tocopherol acetate 0.1
δ-tocopherol 0.1
P-Hydroxybenzoate appropriate amount Merirot extract 2
Purified water residue

Example 9: Oil-based makeup base carnauba wax 1% by mass
Ceresin 6
Decamethylcyclopentasiloxane Residual dodecamethylcyclohexasiloxane 20
Sorbitan sesquiisostearate 2
Bengala coated mica titanium 10
Mica 10
N-lauroyl-L-lysine 0.1
D-δ-tocopherol 0.1
n-Octyltriethoxysilane treated pearl 10
(Timiron supersilk MP-1005 (average particle size 5μm), Hydrophobized product by Merck)
Spherical polyalkyl acrylate powder 10
(Spherical resin powder, average particle size 5 μm)

Example 10: W / O type emulsion foundation dimethylpolysiloxane 15% by mass
Decamethylcyclopentasiloxane 20
Polyoxyethylene / methylpolysiloxane copolymer 5
High molecular weight amino-modified silicone 0.1
Glycerin 5
1,3-butylene glycol 10
Palmitic acid 0.5
Macadamia nut oil fatty acid cholesteryl 0.1
Distearyldimethylammonium chloride 0.2
Palmitic acid dextrin-treated pearl 5
(Pressure stage silklet (average particle size 11μm), hydrophobized by ECKART)
Palmitic acid dextrin-treated pearl 10
(Free stage silk cold (average particle size 11μm), hydrophobized by ECKART)
Alkyl-modified silicone resin coated talc oxide 1.5
Sodium L-glutamate 0.5
DL-α-tocopherol acetate 0.1
P-Hydroxybenzoic acid ester Methyl bis (trimethylsiloxy) trimethoxycinnamate
Silyl isopentyl 0.1
Dimethyl distearyl ammonium hectorite 1.5
Spherical nylon powder (spherical resin powder, average particle size 3 μm) 1
Purified water Residual fragrance Appropriate amount

Example 11: O / W type emulsified cosmetic base microcrystalline wax 1% by mass
Dimethylpolysiloxane 15
Decamethylcyclopentasiloxane 2
1,3-butylene glycol 6
Candelilla Row 3
Isostearic acid 1
Ethylene glycol fatty acid ester 0.1
Lanolin fatty acid octyldodecyl 0.5
2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine 4
Titanium oxide 7.5
Barium sulfate 5
Titanium oxide 7
Talc 3
Silicic anhydride 4
Cross-linked silicone powder 3
(Spherical resin powder, average particle size 1 μm, Trefil E-506)
Sodium metaphosphate 0.1
Hydroxypropyl-β-cyclodextrin 0.1
DL-α-tocopherol acetate 0.1
Hamamelis extract 0.1
Peonies extract 0.1
Sodium chondroitin sulfate 0.1
Sodium hyaluronate 0.1
P-hydroxybenzoic acid ester appropriate amount silicone-treated mica titanium 15
(Timiron supersilk MP-1005 (average particle size 5μm), Hydrophobized product by Merck)
Xanthan gum 0.2
Sodium carboxymethylcellulose 0.2
Merirot extract 2
Purified water residue

Claims (2)

A spherical powder having an average particle size of 3 to 15% by mass and one or more types (component (A)) selected from pearl luster pigments having an average particle size of 15 μm or less and an average particle size of 0.5 to 15 μm. 3 to 15% by mass ,
Without coloring pigment (component (B))
The pearlescent pigments are titanium oxide-coated mica having hydrophobicized with n- octyltriethoxysilane,
When 8 mg / cm ^{2 is} applied to black cowhide leather, the colorimetric values before application (L0 ^* , a0 ^* , b0 ^* ) and the colorimetric values after application specified by the CIE1976L ^* a ^* b ^* color system ( A makeup cosmetic characterized in that the value represented by ΔL ^* (ΔL ^* = L1 ^* −L0 ^* ) obtained from L1 ^* , a1 ^* , b1 ^* ) is 40 to 65.   The makeup cosmetic according to claim 1, wherein the makeup cosmetic is a foundation or a makeup base.