JP4703176B2 - Oil gel cosmetics - Google Patents
Oil gel cosmetics Download PDFInfo
- Publication number
- JP4703176B2 JP4703176B2 JP2004352281A JP2004352281A JP4703176B2 JP 4703176 B2 JP4703176 B2 JP 4703176B2 JP 2004352281 A JP2004352281 A JP 2004352281A JP 2004352281 A JP2004352281 A JP 2004352281A JP 4703176 B2 JP4703176 B2 JP 4703176B2
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic
- concealer
- oil
- titanium dioxide
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002537 cosmetic Substances 0.000 title claims description 56
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 51
- -1 polyethylene Polymers 0.000 claims description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- 239000004408 titanium dioxide Substances 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 239000011787 zinc oxide Substances 0.000 claims description 7
- 239000003921 oil Substances 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 12
- 239000000499 gel Substances 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 230000006750 UV protection Effects 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 8
- 239000004359 castor oil Substances 0.000 description 7
- 235000019438 castor oil Nutrition 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000006096 absorbing agent Substances 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000004166 Lanolin Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 235000019388 lanolin Nutrition 0.000 description 4
- 229940039717 lanolin Drugs 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 206010042496 Sunburn Diseases 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 150000003722 vitamin derivatives Chemical class 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004386 Erythritol Substances 0.000 description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229930003316 Vitamin D Natural products 0.000 description 2
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 229930016911 cinnamic acid Natural products 0.000 description 2
- 235000013985 cinnamic acid Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 2
- 235000019414 erythritol Nutrition 0.000 description 2
- 229940009714 erythritol Drugs 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229920002674 hyaluronan Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- ZUFQODAHGAHPFQ-UHFFFAOYSA-N pyridoxine hydrochloride Chemical compound Cl.CC1=NC=C(CO)C(CO)=C1O ZUFQODAHGAHPFQ-UHFFFAOYSA-N 0.000 description 2
- MMXZSJMASHPLLR-UHFFFAOYSA-N pyrroloquinoline quinone Chemical compound C12=C(C(O)=O)C=C(C(O)=O)N=C2C(=O)C(=O)C2=C1NC(C(=O)O)=C2 MMXZSJMASHPLLR-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
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- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
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- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 2
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- ZQTHOIGMSJMBLM-BUJSFMDZSA-N pangamic acid Chemical compound CN(C)CC(=O)OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O ZQTHOIGMSJMBLM-BUJSFMDZSA-N 0.000 description 1
- 108700024047 pangamic acid Proteins 0.000 description 1
- 229940055726 pantothenic acid Drugs 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 239000011713 pantothenic acid Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 229940116985 potassium lauryl sulfate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 229940095050 propylene Drugs 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- RADKZDMFGJYCBB-UHFFFAOYSA-N pyridoxal hydrochloride Natural products CC1=NC=C(CO)C(C=O)=C1O RADKZDMFGJYCBB-UHFFFAOYSA-N 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 235000019163 vitamin B12 Nutrition 0.000 description 1
- 239000011715 vitamin B12 Substances 0.000 description 1
- 235000019164 vitamin B2 Nutrition 0.000 description 1
- 239000011716 vitamin B2 Substances 0.000 description 1
- 235000019158 vitamin B6 Nutrition 0.000 description 1
- 239000011726 vitamin B6 Substances 0.000 description 1
- 235000011912 vitamin B7 Nutrition 0.000 description 1
- 239000011735 vitamin B7 Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、オイルゲル化粧料に関し、更に詳細には、コンシーラーに好適なオイルゲル化粧料に関する。 The present invention relates to an oil gel cosmetic, and more particularly to an oil gel cosmetic suitable for a concealer.
コンシーラーは、シミなどを目立たなくさせる化粧料であり、このものの隠蔽効果が減じると、忽ち、シミが目立ってしまうため、化粧崩れを防ぐ必要が存する。この為、カルナウバワックスなどの高融点ワックスとヒマシ油などの高粘度油剤とを組み合わせたオイルゲル、アクリル樹脂ポリマーエマルジョンなどの粘着性高分子と粉体とを組み合わせた系などがコンシーラーの剤形として用いられている（例えば、特許文献１、特許文献２、特許文献３、特許文献４、特許文献５、特許文献６を参照）。近年、シミと紫外線の関係において、シミに紫外線が照射することによる、シミの悪化の懸念が問いただされるようになり、コンシーラーに於ける紫外線防護機能が望まれるようになってきている。元々コンシーラーが視覚的にシミを隠すことを目的としている化粧料であることから、コンシーラーとしての機能と紫外線防護機能には噛み合わない部分が存する。特に、隠蔽粉体として使用している二酸化チタンの、紫外線吸収後の励起エネルギーの放出形態であるラジカル発生は一つの問題となっている。その意味で、紫外線防護効果の存するコンシーラー化粧料の開発が望まれている。 Concealer is a cosmetic that makes spots and the like inconspicuous. If the concealing effect of the concealer is reduced, the spots will become noticeable, and it is necessary to prevent the makeup from collapsing. Therefore, oil gels that combine high-melting waxes such as carnauba wax and high-viscosity oils such as castor oil, and systems that combine adhesive polymers such as acrylic resin polymer emulsions and powders are concealer dosage forms. that has been used (for example, see Patent Document 1, Patent Document 2, Patent Document 3, Patent Document 4, Patent Document 5, Patent Document 6). Recently, the relationship between the stain and UV due to the fact that ultraviolet light stain is irradiated, is as concerns stain deterioration is queried, UV protection function has come to be desired that put the concealer. Since the concealer is originally a cosmetic intended to hide the stain visually, there is a part that does not mesh with the concealer function and the UV protection function. In particular, the generation of radicals, which is the emission form of excitation energy after ultraviolet absorption of titanium dioxide used as a concealing powder, is a problem. In that sense, development of concealer cosmetics that have UV protection effects is desired.
一方、ポリエチレンは、オイルゲル化粧料では、オイルゲル構造を作る炭化水素系構造形成剤として汎用の原料である。少なくともシリカとアルミナで被覆された二酸化チタン（以下、単にシリカ・アルミナ被覆二酸化チタンと称する場合がある）は、透明感のある隠蔽剤として化粧料分野で汎用されている（例えば、特許文献７、特許文献８、特許文献９を参照）。微粒子二酸化チタンも、紫外線防護力を有しながら、透明感を有する隠蔽性粉体として化粧料分野で汎用されている原料である（例えば、特許文献１０、特許文献１１を参照）。しかしながら、オイルゲル化粧料であって、１）ポリエチレン３〜１０質量％と２）シリカ・アルミナ被覆二酸化チタン１０〜２５質量％とを含有する化粧料は全く知られていないし、かかる構成の化粧料が、コンシーラーとしての特性を有しながら、且つ、優れた紫外線防護作用を有することは全く知られていなかった。 On the other hand, polyethylene is a general-purpose raw material as a hydrocarbon-based structure forming agent that forms an oil gel structure in oil gel cosmetics. At least silica and alumina coated titanium dioxide (hereinafter, simply referred to as silica-alumina-coated titanium dioxide) is that is commonly used in the cosmetic field as a masking agent with a clarity (e.g., Patent Document 7, (See Patent Document 8 and Patent Document 9) . Fine particles of titanium dioxide also while having UV protection force, Ru raw der widely used in the cosmetic field as a hiding property powder having a transparency (for example, see Patent Document 10, Patent Document 11). However, there is no known oil gel cosmetic that contains 1) 3 to 10% by mass of polyethylene and 2) 10 to 25% by mass of silica / alumina-coated titanium dioxide. However, it has not been known at all that it has excellent UV protection while having the characteristics of a concealer.
ところで、ＳＰＦとは、Ｓｕｎ Ｐｒｏｔｅｃｔｉｏｎ Ｆａｃｔｏｒの略であり、日本化粧品工業会（ＪＣＩＡ）が平成４年１月に定めたＳＰＦ 測定法基準（ＪＣＩＡ法）の試験条件で測定した値である。サンバーン（主としてＵＶＢによる日焼けで皮膚が赤くなること）防止効果を示す値（サンバーン防止効果指数）を意味し、この数値は次式から算出することが出来る。この値は化粧料の当業者では共通基盤に立った数値である（例えば、特許文献１２、特許文献１３、特許文献１４を参照）。通常、この値の上限値は４０〜４５であると言われている。
（式１）
ＳＰＦ＝被験物質を塗布したときの最少紅斑量（ＭＥＤ）／素肌のＭＥＤ
By the way, SPF is an abbreviation for Sun Protection Factor, and is a value measured under the test conditions of the SPF measurement method standard (JCIA method) established in January 1992 by the Japan Cosmetic Industry Association (JCIA). It means a value (sunburn prevention effect index) indicating the effect of preventing sunburn (mainly red skin caused by UVB sunburn), and this value can be calculated from the following equation. This value Ru numerical der stood to common ground in those skilled in cosmetics (e.g., refer to Patent Document 12, Patent Document 13, Patent Document 14). Usually, it is said that the upper limit of this value is 40-45.
(Formula 1)
SPF = minimum erythema amount (MED) / medium of bare skin when test substance is applied
本発明は、この様な状況下為されたものであり、コンシーラーとしての特性を有しながら、且つ、優れた紫外線防護作用を有する化粧料を提供することを課題とする。 The present invention has been made under such circumstances, and it is an object of the present invention to provide a cosmetic material having an excellent ultraviolet protective effect while having characteristics as a concealer.
この様な状況に鑑みて、本発明者らは、コンシーラーとしての特性を有しながら、且つ、優れた紫外線防護作用を有する化粧料を求めて、鋭意研究努力を重ねた結果、１）ポリエチレン３〜１０質量％と２）シリカ・アルミナ被覆二酸化チタン１０〜２５質量％と３）二酸化チタンと酸化亜鉛の焼結粉体を１０〜２５質量％とを含有する化粧料がこの様な特性を有していることを見出し、発明を完成させるに至った。即ち、本発明は、以下に示す技術に関するものである。
（１）オイルゲル化粧料であって、１）ポリエチレン３〜１０質量％と２）少なくともシリカとアルミナで被覆された二酸化チタン１０〜２５質量％と３）二酸化チタンと酸化亜鉛の焼結粉体を１〜５質量％とを含有するコンシーラーであることを特徴とする化粧料。
（２）ペンシルタイプであることを特徴とする、（１）に記載の化粧料。
（３）ＳＰＦ値が５０以上であることを特徴とする、（１）又は（２）に記載の化粧料。
（４）シミを目立たなくカバーするとともに、該シミが紫外線の照射によって悪化する
のを防ぐ目的の化粧料であることを特徴とする、（１）〜（３）何れか１項に記載の化粧料。
In view of such a situation, the present inventors have intensively researched for cosmetics having characteristics as a concealer and having an excellent UV protection effect. 1) Polyethylene 3 10% by mass, 2) 10-25% by mass of silica / alumina coated titanium dioxide, and 3) 10-25% by mass of sintered powder of titanium dioxide and zinc oxide have such properties. I found out that I was doing it and came to complete the invention. That is, this invention relates to the technique shown below.
(1) Oil gel cosmetics, 1) 3 to 10% by mass of polyethylene, 2) 10 to 25% by mass of titanium dioxide coated with at least silica and alumina, and 3) a sintered powder of titanium dioxide and zinc oxide. A cosmetic comprising a concealer containing 1 to 5% by mass.
( 2 ) The cosmetic according to (1), which is a pencil type.
( 3 ) SPF value is 50 or more, Cosmetics as described in (1) or (2) .
( 4 ) The cosmetic composition according to any one of (1) to (3) , wherein the cosmetic composition is a cosmetic for the purpose of covering the stain inconspicuously and preventing the stain from being deteriorated by irradiation with ultraviolet rays. Fee.
この様な状況下為されたものであり、コンシーラーとしての特性を有しながら、且つ、優れた紫外線防護作用を有する化粧料を提供することができる。 Under such circumstances, it is possible to provide a cosmetic having an excellent UV protection effect while having characteristics as a concealer.
（１）本発明の化粧料の必須成分であるポリエチレン
本発明の化粧料は、オイルゲル化粧料であって、必須成分としてポリエチレンを３〜１０質量％、より好ましくは４〜７質量％含有することを特徴とする。本発明の化粧料に於いて、かかるポリエチレンは、オイルゲルの構造を作るワックス分としての働きを有する。この様な構造形成用の成分としては、平均分子量が大きすぎると、他のオイル分に相溶しにくくなるので、適正な範囲に保たれていることが好ましい。この様な平均分子量の値としては、３００〜１０００が好ましく、４００〜７００がより好ましい。この様な形態で含有することにより、構造維持性と付着性の高いオイルゲル構造を作ることが出来、これにより、適正なＳＰＦ値を示す程度の塗布厚で化粧料を塗布することが出来るようになる。
(1) Polyethylene which is an essential component of the cosmetic of the present invention The cosmetic of the present invention is an oil gel cosmetic and contains 3 to 10% by mass, more preferably 4 to 7% by mass of polyethylene as an essential component. It is characterized by. In the cosmetic of the present invention, such polyethylene functions as a wax component that forms an oil gel structure. As such a component for forming a structure, if the average molecular weight is too large, it becomes difficult to be compatible with other oil components, and therefore it is preferably kept in an appropriate range. As such a value of average molecular weight, 300 to 1000 are preferable, and 400 to 700 are more preferable. By containing in such a form, it is possible to make an oil gel structure with high structure maintainability and adhesion, so that cosmetics can be applied with an application thickness that shows an appropriate SPF value. Become.
（２）本発明の化粧料の必須成分であるシリカ・アルミナ被覆二酸化チタン
本発明の化粧料は、オイルゲル化粧料であって、少なくともシリカ及び／又はアルミナで被覆された二酸化チタンを１０〜２５質量％、より好ましくは１１〜２４質量％含有することを特徴とする。ここで、少なくともシリカ及び／又はアルミナで被覆された二酸化チタンとは、二酸化チタンを主成分とする金属酸化物であって、主として表面に第二、第三の成分としてアルミナ或いはシリカを含有し、アルミナ、シリカ以外の金属酸化物の含有、例えば、ジルコニアや酸化鉄などの含有も許容するとの意味であり、前記主成分としては二酸化チタンの５０質量％以上の含有を意味する。この様な粉体は、市販の二酸化チタンに水酸化アルミニウムやケイ酸を積層し、５００〜１２００℃で１０〜３０時間焼成することにより、製造することも出来るが、既にこの要件を充足している市販の原料を購入して利用することも出来る。市販の原料としては、シリカ・アルミナ・ジルコニア被覆の「タイペークＴＴＯ−Ｆ１」、「タイペークＴＴＯ−Ｆ２」或いはシリカ・アルミナ被覆の「タイペークＴＴＯ−Ｆ６」（いずれも石原産業株式会社製）、酸化アルミニウム水和物・ケイ酸処理酸化チタンである「酸化チタンＪＲ８００」（テイカ株式会社製）などが好ましく例示でき、「タイペークＴＴＯ−Ｆ６」及び／又は「酸化チタンＪＲ８００」を用いることが特に好ましい。かかる成分は、二酸化チタンとともに用いた場合、二酸化チタンが紫外線を吸収したことにより、発生させるラジカルを消去する作用を有する。この成分が多くなりすぎても、少なくなりすぎてもＳＰＦ値が損なわれる場合が存する。
(2) Silica / alumina-coated titanium dioxide which is an essential component of the cosmetic of the present invention The cosmetic of the present invention is an oil gel cosmetic, and 10 to 25 mass of titanium dioxide coated with at least silica and / or alumina. %, More preferably 11 to 24% by mass. Here, the titanium dioxide coated with at least silica and / or alumina, two a metal oxide containing titanium oxide as a main component, mainly secondary to the surface, containing alumina or silica as a third component In addition, the inclusion of metal oxides other than alumina and silica, for example, the inclusion of zirconia, iron oxide, and the like is also permitted, and the main component means the inclusion of 50% by mass or more of titanium dioxide. Such a powder can be produced by laminating commercially available titanium dioxide with aluminum hydroxide or silicic acid and firing at 500 to 1200 ° C. for 10 to 30 hours. You can also purchase and use commercially available raw materials. Commercially available raw materials include silica-alumina-zirconia-coated “Taipaque TTO-F1”, “Taipaque TTO-F2” or silica-alumina-coated “Taipaque TTO-F6” (all manufactured by Ishihara Sangyo Co., Ltd.), aluminum oxide “Titanium oxide JR800” (manufactured by Teika Co., Ltd.), which is a hydrate / silicic acid-treated titanium oxide, can be preferably exemplified, and “Taipaque TTO-F6” and / or “titanium oxide JR800” is particularly preferable. Such a component, when used together with titanium dioxide, has an action of eliminating radicals generated when titanium dioxide absorbs ultraviolet rays. Assistant engineer that to be a lot this component also exists if the SPF value be too small may be impaired.
（３）本発明の化粧料
本発明の化粧料は、前記必須成分を含有し、オイルゲル化粧料であることを特徴とする。本発明の化粧料としては、特段の限定はないが、メークアップ化粧料や紫外線防護化粧料が好ましく例示できる。特に好ましいものはコンシーラーである。コンシーラーとは、目立つシミ等の部分にスポット的に塗布して、隠蔽する化粧料である。コンシーラーとしては、クリーム様の練り化粧料やスティック状の化粧料等が通常使用されるが、本発明では、その硬度などの物理的特性から、ペンシル状のものが特に好ましい。ペンシル状とは、直径１〜８ｍｍの芯状に化粧料を加工して、木軸に包埋したり、ホルダー等に保持させた形態のものを意味する。この様な形態では、微小なシミなどをカバーすることが出来る点でも有利である。本発明の化粧料では、かかる成分以外に通常化粧料で使用される任意の成分を含有することも出来る。この様な任意成分としては、例えば、マカデミアナッツ油、アボガド油、トウモロコシ油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、サフラワー油、綿実油、ホホバ油、ヤシ油、パーム油、液状ラノリン、硬化ヤシ油、硬化油、モクロウ、硬化ヒマシ油、ミツロウ、キャンデリラロウ、カルナウバロウ、イボタロウ、ラノリン、還元ラノリン、硬質ラノリン、ホホバロウ等のオイル、ワックス類、流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックス等の炭化水素類、オレイン酸、イソステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、ウンデシレン酸等の高級脂肪酸類、セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、ミリスチルアルコール、セトステアリルアルコール等の高級アルコール等、イソオクタン酸セチル、ミリスチン酸イソプロピル、イソステアリン酸ヘキシルデシル、アジピン酸ジイソプロピル、セバチン酸ジ−２−エチルヘキシル、乳酸セチル、リンゴ酸ジイソステアリル、ジ−２−エチルヘキサン酸エチレングリコール、ジカプリン酸ネオペンチルグリコール、ジ−２−ヘプチルウンデカン酸グリセリン、トリ−２−エチルヘキサン酸グリセリン、トリ−２−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ−２−エチルヘキサン酸ペンタンエリトリット等の合成エステル油類、ジメチルポリシロキサン、メチルフェニルポリシロキサン、ジフェニルポリシロキサン等の鎖状ポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサンシロキサン等の環状ポリシロキサン、アミノ変性ポリシロキサン、ポリエーテル変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等の変性ポリシロキサン等のシリコーン油等の油剤類、脂肪酸セッケン（ラウリン酸ナトリウム、パルミチン酸ナトリウム等）、ラウリル硫酸カリウム、アルキル硫酸トリエタノールアミンエーテル等のアニオン界面活性剤類、塩化ステアリルトリメチルアンモニウム、塩化ベンザルコニウム、ラウリルアミンオキサイド等のカチオン界面活性剤類、イミダゾリン系両性界面活性剤（２−ココイル−２−イミダゾリニウムヒドロキサイド−１−カルボキシエチロキシ２ナトリウム塩等）、ベタイン系界面活性剤（アルキルベタイン、アミドベタイン、スルホベタイン等）、アシルメチルタウリン等の両性界面活性剤類、ソルビタン脂肪酸エステル類（ソルビタンモノステアレート、セスキオレイン酸ソルビタン等）、グリセリン脂肪酸類（モノステアリン酸グリセリン等）、プロピレングリコール脂肪酸エステル類（モノステアリン酸プロピレングリコール等）、硬化ヒマシ油誘導体、グリセリンアルキルエーテル、ＰＯＥソルビタン脂肪酸エステル類（ＰＯＥソルビタンモノオレエート、モノステアリン酸ポリオキエチレンソルビタン等）、ＰＯＥソルビット脂肪酸エステル類（ＰＯＥ−ソルビットモノラウレート等）、ＰＯＥグリセリン脂肪酸エステル類（ＰＯＥ−グリセリンモノイソステアレート等）、ＰＯＥ脂肪酸エステル類（ポリエチレングリコールモノオレート、ＰＯＥジステアレート等）、ＰＯＥアルキルエーテル類（ＰＯＥ２−オクチルドデシルエーテル等）、ＰＯＥアルキルフェニルエーテル類（ＰＯＥノニルフェニルエーテル等）、プルロニック型類、ＰＯＥ・ＰＯＰアルキルエーテル類（ＰＯＥ・ＰＯＰ２−デシルテトラデシルエーテル等）、テトロニック類、ＰＯＥヒマシ油・硬化ヒマシ油誘導体（ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油等）、ショ糖脂肪酸エステル、アルキルグルコシド等の非イオン界面活性剤類、ポリエチレングリコール、グリセリン、１，３−ブチレングリコール、エリスリトール、ソルビトール、キシリトール、マルチトール、プロピレングリコール、ジプロピレングリコール、ジグリセリン、イソプレングリコール、１，２−ペンタンジオール、２，４−ヘキシレングリコール、１，２−ヘキサンジオール、１，２−オクタンジオール等の多価アルコール類、ピロリドンカルボン酸ナトリウム、乳酸、乳酸ナトリウム等の保湿成分類、グアガム、クインスシード、カラギーナン、ガラクタン、アラビアガム、ペクチン、マンナン、デンプン、キサンタンガム、カードラン、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、メチルヒドロキシプロピルセルロース、コンドロイチン硫酸、デルマタン硫酸、グリコーゲン、ヘパラン硫酸、ヒアルロン酸、ヒアルロン酸ナトリウム、トラガントガム、ケラタン硫酸、コンドロイチン、ムコイチン硫酸、ヒドロキシエチルグアガム、カルボキシメチルグアガム、デキストラン、ケラト硫酸，ローカストビーンガム，サクシノグルカン，カロニン酸，キチン，キトサン、カルボキシメチルキチン、寒天、ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー、ポリアクリル酸ナトリウム、ポリエチレングリコール、ベントナイト等の増粘剤、表面を処理されていても良い、マイカ、タルク、カオリン、合成雲母、炭酸カルシウム、炭酸マグネシウム、無水ケイ酸（シリカ）、酸化アルミニウム、硫酸バリウム等の粉体類、表面を処理されていても良い、ベンガラ、黄酸化鉄、黒酸化鉄、酸化コバルト、群青、紺青等の必須成分に属さない無機顔料類、表面を処理されていても良い、雲母チタン、魚燐箔、オキシ塩化ビスマス等のパール剤類、レーキ化されていても良い赤色２０２号、赤色２２８号、赤色２２６号、黄色４号、青色４０４号、黄色５号、赤色５０５号、赤色２３０号、赤色２２３号、橙色２０１号、赤色２１３号、黄色２０４号、黄色２０３号、青色１号、緑色２０１号、紫色２０１号、赤色２０４号等の有機色素類、ポリエチレン末、ポリメタクリル酸メチル、ナイロン粉末、オルガノポリシロキサンエラストマー等の有機粉体類、パラアミノ安息香酸系紫外線吸収剤、アントラニル酸系紫外線吸収剤、サリチル酸系紫外線吸収剤、桂皮酸系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤、糖系紫外線吸収剤、２−（２’−ヒドロキシ−５’−ｔ−オクチルフェニル)ベンゾトリアゾール、４−メトキシ−４’−ｔ−ブチルジベンゾイルメタン等の紫外線吸収剤類、エタノール、イソプロパノール等の低級アルコール類、ビタミンＡ又はその誘導体、ビタミンＢ6塩酸塩，ビタミンＢ6トリパルミテート，ビタミンＢ6ジオクタノエート，ビタミンＢ2又はその誘導体，ビタミンＢ12，ビタミンＢ15又はその誘導体等のビタミンＢ類、α−トコフェロール，β−トコフェロール，γ−トコフェロール，ビタミンＥアセテート等のビタミンＥ類、ビタミンＤ類、ビタミンＨ、パントテン酸、パンテチン、ピロロキノリンキノン等のビタミン類などが好ましく例示できる。特に好ましいものは、二酸化チタンと酸化亜鉛の焼結粉体（チタン酸亜鉛）が例示できる。この様な焼結体に於ける、二酸化チタンと酸化亜鉛の質量比は、７：３〜９：１が好ましい。かかる成分を１〜５質量％、より好ましくは、２〜４質量％含有させることにより、ＳＰＦ値を更に向上せしめ、あわせて、紫外線Ａに対する防護効果を向上させることも出来る。この様な、二酸化チタンと酸化亜鉛の焼結粉体は、二酸化チタンと酸化亜鉛とを８００〜１２００℃で１０〜３０時間焼成することにより製造することが出来る。又、この様な粉体には市販品も存し、かかる市販品を購入して利用することも出来る。好ましい市販品としては、「エアリーフィット・パウダー」（日興リカ株式会社製）等が好適に例示できる。本発明の化粧料は、この様な必須成分と任意成分とを常法に従って処理することにより製造できる。かくして得られた、本発明の化粧料は、優れた紫外線防護効果を奏する。ＳＰＦ値に表せば、ベンゾフェノンや桂皮酸エステルなどの紫外線吸収剤を用いることなく、５０以上の数値をとる。
(3) Cosmetics of this invention The cosmetics of this invention contain the said essential component, It is an oil gel cosmetics, It is characterized by the above-mentioned. Although there is no special limitation as cosmetics of this invention, Makeup cosmetics and ultraviolet protection cosmetics can be illustrated preferably. Particularly preferred is a concealer. A concealer is a cosmetic that is applied in a spot manner to a conspicuous spot or the like to conceal it. As the concealer, cream-like kneaded cosmetics, stick-like cosmetics and the like are usually used, but in the present invention, a pencil-like one is particularly preferred because of its physical properties such as hardness. The pencil shape means that the cosmetic is processed into a core shape having a diameter of 1 to 8 mm and embedded in a wooden shaft or held in a holder or the like. Such a configuration is advantageous in that it can cover minute stains and the like. The cosmetic of the present invention may contain any component that is usually used in cosmetics in addition to such components. Examples of such optional ingredients include macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, and hardened coconut oil. Oil, wax, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, oil, wax, liquid wax, liquid paraffin, squalane, bean wax, candelilla wax, carnauba wax, ibotarou, lanolin, reduced lanolin, hard lanolin , Hydrocarbons such as microcrystalline wax, higher fatty acids such as oleic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, cetyl alcohol, stearyl alcohol, isostearyl Alcohol, behenyl alcohol, octyldodecanol, higher alcohol such as myristyl alcohol, cetostearyl alcohol, etc., cetyl isooctanoate, isopropyl myristate, hexyldecyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, malic acid Diisostearyl, di-2-ethylhexanoic acid ethylene glycol, dicaprate neopentyl glycol, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, tri Synthetic ester oils such as trimethylolpropane isostearate and pentane erythritol tetra-2-ethylhexanoate, dimethylpolysiloxane, methylphenylpoly Loxane, linear polysiloxane such as diphenylpolysiloxane, cyclic polysiloxane such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexanesiloxane, amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, Oil agents such as silicone oil such as modified polysiloxane such as fluorine-modified polysiloxane, anionic surfactants such as fatty acid soap (sodium laurate, sodium palmitate, etc.), potassium lauryl sulfate, triethanolamine ether of alkyl sulfate, chloride Cationic surfactants such as stearyltrimethylammonium, benzalkonium chloride, laurylamine oxide, imidazoline-based amphoteric surfactants (2-cocoyl-2-imida Zolinium hydroxide-1-carboxyethyloxy disodium salt, etc.), betaine surfactants (alkyl betaine, amide betaine, sulfobetaine, etc.), amphoteric surfactants such as acylmethyltaurine, sorbitan fatty acid esters (sorbitan) Monostearate, sorbitan sesquioleate, etc.), glycerin fatty acids (eg, glyceryl monostearate), propylene glycol fatty acid esters (eg, propylene glycol monostearate), hardened castor oil derivatives, glycerin alkyl ethers, POE sorbitan fatty acid esters (POE sorbitan monooleate, polyoxyethylene sorbitan monostearate, etc.), POE sorbite fatty acid esters (POE-sorbitol monolaurate, etc.), POE glycerin fatty acid ester Tells (POE-glycerol monoisostearate, etc.), POE fatty acid esters (polyethylene glycol monooleate, POE distearate, etc.), POE alkyl ethers (POE2-octyldodecyl ether, etc.), POE alkylphenyl ethers (POE nonylphenyl) Ethers, etc.), Pluronic types, POE / POP alkyl ethers (POE / POP2-decyltetradecyl ether, etc.), Tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE hardened castor oil, etc.), Nonionic surfactants such as sucrose fatty acid ester and alkyl glucoside, polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, propylene Polyols such as recall, dipropylene glycol, diglycerin, isoprene glycol, 1,2-pentanediol, 2,4-hexylene glycol, 1,2-hexanediol, 1,2-octanediol, pyrrolidone carboxylic acid Moisturizing ingredients such as sodium, lactic acid, sodium lactate, guar gum, quince seed, carrageenan, galactan, gum arabic, pectin, mannan, starch, xanthan gum, curdlan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, chondroitin sulfate , Dermatan sulfate, glycogen, heparan sulfate, hyaluronic acid, sodium hyaluronate, tragacanth gum, keratan sulfate, chondroitin, mucoitin sulfate, hyaluronan Droxyethyl guar gum, carboxymethyl guar gum, dextran, keratosulfuric acid, locust bean gum, succinoglucan, caronic acid, chitin, chitosan, carboxymethylchitin, agar, polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, sodium polyacrylate, Thickeners such as polyethylene glycol and bentonite, surface may be treated, powder such as mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, silicic anhydride (silica), aluminum oxide, barium sulfate The surface may be treated, inorganic pigments that do not belong to essential components such as bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, and bitumen, the surface may be treated, mica titanium, Fish phosphorus foil, bismuth oxychloride, etc. Pearls, which may be raked Red 202, Red 228, Red 226, Yellow 4, Blue 404, Yellow 5, Red 505, Red 230, Red 223, Orange 201 Organic dyes such as red 213, yellow 204, yellow 203, blue 1, green 201, purple 201, red 204, polyethylene powder, polymethyl methacrylate, nylon powder, organopolysiloxane elastomer, etc. Organic powders, paraaminobenzoic acid UV absorbers, anthranilic acid UV absorbers, salicylic acid UV absorbers, cinnamic acid UV absorbers, benzophenone UV absorbers, sugar UV absorbers, 2- (2 UV light such as'-hydroxy-5'-t-octylphenyl) benzotriazole, 4-methoxy-4'-t-butyldibenzoylmethane Collectors, lower alcohols such as ethanol and isopropanol, vitamin A or derivatives thereof, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 or derivatives thereof, vitamin B12, vitamin B15 or derivatives thereof, etc. Vitamin E such as vitamin B, α-tocopherol, β-tocopherol, γ-tocopherol and vitamin E acetate, vitamin D such as vitamin D, vitamin H, pantothenic acid, panthetin, pyrroloquinoline quinone and the like can be preferably exemplified. Particularly preferred is a sintered powder (zinc titanate) of titanium dioxide and zinc oxide. The mass ratio of titanium dioxide and zinc oxide in such a sintered body is preferably 7: 3 to 9: 1. By containing 1 to 5% by mass of such a component, more preferably 2 to 4% by mass, the SPF value can be further improved, and the protective effect against ultraviolet A can be improved. Such a sintered powder of titanium dioxide and zinc oxide can be produced by firing titanium dioxide and zinc oxide at 800 to 1200 ° C. for 10 to 30 hours. In addition, such powders also have commercial products, and such commercial products can be purchased and used. Preferable examples of commercially available products include “Airy Fit Powder” (manufactured by Nikko Rica Corporation). The cosmetic of the present invention can be produced by treating such essential components and optional components according to a conventional method. The cosmetic of the present invention thus obtained has an excellent ultraviolet protective effect. In terms of the SPF value, a numerical value of 50 or more is taken without using an ultraviolet absorber such as benzophenone or cinnamic acid ester.
以下に、実施例を挙げて、本発明について更に詳細に説明を加えるが、本発明がかかる実施例に限定されないのは言うまでもない。 Hereinafter, the present invention will be described in more detail with reference to examples, but it goes without saying that the present invention is not limited to such examples.
以下に示す処方に従って、本発明の化粧料であるコンシーラーを製造した。即ち、イの成分をボールミルで分散した後、ロの成分を加えて、処方成分を９５℃に加熱して溶解させ、これを金型に流し込み、冷却、固化させて、５ｍｍφ×７ｃｍの芯の形態に加工したコンシーラー用の芯を作成し、これをホルダーにセットして、本発明の化粧料であるコンシーラー１を得た。 A concealer, which is a cosmetic of the present invention, was produced according to the formulation shown below. That is, after the component (a) is dispersed with a ball mill, the component (b) is added, the prescription component is heated to 95 ° C. to dissolve, poured into a mold, cooled and solidified, and the core of 5 mmφ × 7 cm is formed. A concealer core processed into a form was prepared and set in a holder to obtain a concealer 1 which is a cosmetic of the present invention.
＜試験例１＞
上記のコンシーラー１、コンシーラー１のタイペークＴＴＯ−Ｆ６と酸化チタンＪＲ−８００とを通常の二酸化チタンに置換した比較例１、コンシーラー１のポリエチレン（平均分子量５００）をマイクロクリスタリンワックスに置換した比較例２を作成し、ＪＣＩＡ法に従ってＳＰＦ値を測定した。結果を表２に示す。これより、本発明の化粧料は優れたＳＰＦ値を示すことが判る。
<Test Example 1>
Concealer 1, Comparative Example 1 in which Typeke TTO-F6 of Concealer 1 and titanium oxide JR-800 were replaced with ordinary titanium dioxide, Comparative Example 2 in which polyethylene (average molecular weight of 500) in Concealer 1 was replaced with microcrystalline wax And the SPF value was measured according to the JCIA method. The results are shown in Table 2. From this, it can be seen that the cosmetic of the present invention exhibits an excellent SPF value.
表１の処方に従って化粧料組成物を作成し、金型に流し込み長径３．５ｃｍ、短径２．５ｃｍの楕円の断面を有する柱状に加工し、本発明のコンシーラー２とした。このもののＳＰＦ値は５１であり、本発明の化粧料としては、ペンシル状であることが好ましいことが判った。 A cosmetic composition was prepared according to the formulation of Table 1, poured into a mold and processed into a columnar shape having an elliptical cross section with a major axis of 3.5 cm and a minor axis of 2.5 cm, thereby obtaining a concealer 2 of the present invention. The SPF value of this product was 51, and it was found that the cosmetic of the present invention preferably has a pencil shape.
実施例１と同様に、下記の処方に従ってペンシル状のコンシーラーを作成した。このもののＳＰＦ値は５３であった。 As in Example 1, a pencil-shaped concealer was prepared according to the following formulation. The SPF value of this product was 53.
実施例１と同様に、下記の処方に従ってペンシル状のコンシーラーを作成した。このもののＳＰＦ値は５２であった。 As in Example 1, a pencil-shaped concealer was prepared according to the following formulation. The SPF value of this product was 52.
本発明は、紫外線防護効果を有するコンシーラーに応用出来る。 The present invention can be applied to a concealer having an ultraviolet protection effect.
Claims (4)
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| JP2004352281A JP4703176B2 (en) | 2004-12-06 | 2004-12-06 | Oil gel cosmetics |
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| JP2006160638A5 JP2006160638A5 (en) | 2007-12-27 |
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| EP2066291A2 (en) * | 2006-09-28 | 2009-06-10 | The Procter and Gamble Company | Cosmetic product |
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| JP2000226315A (en) * | 1999-02-01 | 2000-08-15 | Pola Chem Ind Inc | Cosmetic containing powder |
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| JPS63265819A (en) * | 1987-04-20 | 1988-11-02 | Titan Kogyo Kk | Manufacture of zinc dititanate finely devided grain powder for protection from ultraviolet ray |
| GB8712752D0 (en) * | 1987-05-30 | 1987-07-01 | Tioxide Group Plc | Particulate material |
| JP2739253B2 (en) * | 1990-08-22 | 1998-04-15 | 花王株式会社 | Cosmetics |
| JPH05222317A (en) * | 1991-09-18 | 1993-08-31 | Mitsui Mining & Smelting Co Ltd | Multicomponent oxide for intercepting ultraviolet ray and its production |
| JP3819575B2 (en) * | 1997-12-26 | 2006-09-13 | 花王株式会社 | Cerium phosphate UV absorber and method for producing the same |
| JPH11217315A (en) * | 1998-01-27 | 1999-08-10 | Pola Chem Ind Inc | Makeup cosmetic showing natural appearance |
| JPH11217219A (en) * | 1998-01-28 | 1999-08-10 | Nonogawa Shoji Kk | Composite pigment and cosmetic containing the same |
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| JP3940501B2 (en) * | 1998-05-29 | 2007-07-04 | ポーラ化成工業株式会社 | Makeup cosmetics suitable for use under shooting light source conditions |
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|---|---|---|---|---|
| JP2000072621A (en) * | 1998-08-27 | 2000-03-07 | Pola Chem Ind Inc | Powder for summer cosmetic |
| JP2000226315A (en) * | 1999-02-01 | 2000-08-15 | Pola Chem Ind Inc | Cosmetic containing powder |
| JP2000327532A (en) * | 1999-05-17 | 2000-11-28 | Pola Chem Ind Inc | Concealer |
| JP2001226223A (en) * | 2000-02-18 | 2001-08-21 | Tokiwa Corp | Stick-like cosmetic |
| JP2002154915A (en) * | 2000-09-11 | 2002-05-28 | Showa Denko Kk | Cosmetic |
| JP2003171124A (en) * | 2001-12-05 | 2003-06-17 | Pola Chem Ind Inc | Titanium dioxide cerium oxide composite, method for manufacturing the same and composition containing the same |
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