JP4688455B2 - 掃除用具 - Google Patents
掃除用具 Download PDFInfo
- Publication number
- JP4688455B2 JP4688455B2 JP2004262897A JP2004262897A JP4688455B2 JP 4688455 B2 JP4688455 B2 JP 4688455B2 JP 2004262897 A JP2004262897 A JP 2004262897A JP 2004262897 A JP2004262897 A JP 2004262897A JP 4688455 B2 JP4688455 B2 JP 4688455B2
- Authority
- JP
- Japan
- Prior art keywords
- antigenicity
- cleaning tool
- oil
- reducing
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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Images
Classifications
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- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
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- A47L13/17—Cloths; Pads; Sponges containing cleaning agents
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
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- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
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- A—HUMAN NECESSITIES
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- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/20—Mops
- A47L13/24—Frames for mops; Mop heads
- A47L13/254—Plate frames
- A47L13/256—Plate frames for mops made of cloth
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- A—HUMAN NECESSITIES
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- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/38—Other dusting implements
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- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
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- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T442/2525—Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/659—Including an additional nonwoven fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/659—Including an additional nonwoven fabric
- Y10T442/671—Multiple nonwoven fabric layers composed of the same polymeric strand or fiber material
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- Emergency Medicine (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Printers Or Recording Devices Using Electromagnetic And Radiation Means (AREA)
- Sampling And Sample Adjustment (AREA)
- Valve Device For Special Equipments (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明の清掃用具に付与される抗原性低減化組成物は、(a)アレルギーを引き起こす物質の抗原性を低減化する抗原性低減化成分と、(b)油剤と、(c)界面活性剤と、を含んでいる。以下、それぞれの構成成分について説明する。
本発明で用いられる「抗原性低減化成分」は、アレルギーを引き起こす物質の抗原性を低減化してアレルギー症状を抑制するものであり、植物由来の成分である。ここで、アレルギーを引き起こす物質(アレルゲン)とは、例えば、ダニ、ハウスダスト、動物、真菌(カビ)、昆虫等の吸入性アレルゲンや、スギ、イネ科花粉等である。
本発明で用いられる「油剤」は、塵埃やダストの吸着保持能力を高めるために添加される。このような油剤としては特に限定されないが、鉱物油、合成油、シリコーン油、植物油のうち少なくとも1種以上含むことが好ましい。鉱物油としてはパラフィン系炭化水素、ナフテン系炭化水素、芳香族炭化水素等が例示できる。これらの油剤は、単独で用いてもよく、2種以上を混合して用いてもよい。
本発明で用いられる「界面活性剤」は、掃除用具への付与を容易にし、また、組成物を均一化するために添加される。界面活性剤の種類としては、非イオン性界面活性剤を用いることが好ましい。このような非イオン活性剤としては特に限定されないが、ポリオキシエチレンアルキルエーテルとしては、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンステアリルエーテルなどが好ましい。ソルビタンエステルとしてはソルビタンラウリン酸モノエステル、ソルビタンパルチミン酸モノエステル、ソルビタンステアリン酸モノエステル、ソルビタンオレイン酸モノエステルなどが好ましい。グリセリン脂肪酸エステルとしては、モノミリスチン酸グリセリル、モノステアリン酸グリセリル、モノオレイン酸グリセリル、モノイソステアリン酸グリセリル、ジオレイン酸グリセリルなどが好ましい。植物油としては、ホホバ油、アボカド油、オリーブ油、杏仁油、グレープシード油、サフラワー油、ヒマワリ油などが好ましい。ソルビタントリオレエートとしては、ソルビタンステアリン酸トリエステル、ソルビタンオレイン酸トリエステルなどが好ましい。ヒマシ油もしくは硬化ヒマシ油のEO付加物としては、ポリオキシエチレン硬化ヒマシ油、ラウリン酸ポリオキシエチレン硬化ヒマシ油、モノイソステアリン酸ポリオキシエチレン硬化ヒマシ油などが好ましい。これらの界面活性剤は、単独で用いてもよく、2種以上を混合して用いてもよい。
本発明に用いられる抗原性低減化組成物には、その性状を大きく変動させない範囲内において、上記の植物由来の抗原性低減化成分、油剤、界面活性剤以外の各種の成分が配合されていてもよい。
上記の各成分は、従来公知の方法で混合・攪拌され、抗原性低減化組成物とすることができる。ここで、上記の必須3成分である抗原性低減化成分、油剤、界面活性剤の配合割合としては、抗原性低減化組成物全体に対し、抗原性低減化成分を0.01〜10質量%、油剤を50〜95質量%、界面活性剤を1〜50質量%含有することが好ましい。より好ましくは、抗原性低減化成分が0.02〜1質量%、油剤が60〜80質量%、界面活性剤が20〜40質量%である。
次に、上記の抗原性低減化組成物を付与する掃除用具について説明する。掃除用具は、実質的に水分を含有しない繊維状基材を有する室内用の清掃用具、いわゆるドライタイプの清掃用具であれば特に限定されない。例えば、シート状であってもよく、シートを切断した短冊状であってもよく、モップのように多数の紐状体で構成されていてもよく、トウファイバー(繊維の集合体)で形成されていてもよい。繊維状基材の種類も特に限定されず、天然繊維、合成繊維、半合成繊維のいずれでもよい。また、繊維形態は織物、編物、不織布のいずれであってもよく特に限定されない。
図1、2には、このような掃除用具の一例が示されている。図1は掃除用具の斜視図、図2は図1における掃除用シートの分解斜視図である。図1に示すように、この掃除用具10はいわゆるハンディタイプであり、本発明における繊維状基材に相当する掃除用シート11と、把持具12とから構成されている。なお、把持具12は適宜交換可能であり、例えば、図3に示すような把持具22を装着することで、図1の掃除用具では手の届かない高所や狭い場所においても使用することができる。
図4には、掃除用具の他の例として、床面を掃除するのに好適なフロアタイプの掃除用具30が示されている。図4に示すように、この掃除用具30では、本発明における繊維状基材に相当する掃除用シート31を、把持具32の先端部32aに巻きつけて使用する。なお、掃除用シート31の表裏にはトウからなる凸部33が形成されており、溝部分など、平面状のものでは掃除しにくい箇所の掃除が行ない易くなっている。この掃除用具30で床面などに触れさせるだけで、掃除用シート31によって埃などが捕集できる。このようなフロアタイプの掃除用具30においては、掃除用シート31の全体に抗原性低減化組成物を付与することが好ましい。
上記の掃除用具に抗原性低減化組成物を付与する方法としては、繊維状基材に抗原性低減化組成物を噴霧法やローラーコート法、浸漬法などにより付与する方法が挙げられるがこれに限定されない。
(タンニン酸)
タンニン酸(和光純薬製)を水およびエタノールに溶解し、タンニン酸15%になるよう調整した液である。
タンニン酸を抗原性低減化成分とする抗原性低減化剤を用い、表1に示す配合割合で、製造例1〜3の抗原性低減化組成物を得た。
注2)ポリオキシエチレンアルキルエーテルのEO付加モル数は5モル、構成するアルキル基の炭素数12〜14。
注3)30℃での粘度は50mm2/s。
注4)ポリオキシエチレン硬化ヒマシ油のEO付加モル数は60モル。
注5)ポリオキシエチレンアルキルエーテルのEO付加モル数は3モル、構成するアルキル基の炭素数12〜14。
次に、上記の製造例1、2の抗原性低減化組成物、及び製造例3の組成物を、図1に示すような掃除用具(以下ハンディタイプという)、及び、図4に示すような掃除用具(以下フロアタイプという)にスプレーで付与し、それぞれのタイプについて、実施例1、2(製造例1、2を付与したもの)、及び比較例1(製造例3を付与したもの)の掃除用具を得た。
〔試験例1:抗原性低減化性能の評価〕
実施例1、3、及び比較例1の掃除用具について、以下の手順で、スギ花粉及びヒョウヒダニ類に対する抗原性低減化の評価を行った。その結果をまとめて表2、3に示す。なお、表中の「低減化率」は、100−100×(抗原性低減化剤を付与した掃除用具のELISAによるアレルゲン量)/(抗原性低減化剤を付与しない掃除用具のELISAによるアレルゲン量)によって求めた値であり、表中の記号は下記の低減化率を示す。
○・・・良好 低減化率 50%以上
△・・・劣る 低減化率 10〜50%
×・・・不良 低減化率 0〜10%
加温試験:実施例2の掃除用具の繊維状基材のみを、ハンディタイプの掃除用具は紙容器に収容して包装し、フロアタイプの掃除用具はフィルムでピロー包装した。この包装体を、室内の日陰、40℃恒温槽、50℃恒温槽にそれぞれ放置した。そして、放置直後、1ヶ月経過後に、上記の試験例1と同様の方法でアレルゲンを測定した。
光照射試験:ハンディタイプ、フロアタイプの掃除用具の繊維状基材ともに包装せず、シートのまま放置した。キセノンランプウェザーメーターにて太陽光1ヶ月相当、6ヶ月相当を照射し、上記の試験例1と同様の方法でアレルゲンを測定した。
2 基材シート
3 繊維束(刷毛部)
3a 第1の繊維束
3b 第2の繊維束
3c 第3の繊維束
3d 第4の繊維束
5 短冊シート
6 全層接合線
7 接合線
10、20、30 掃除用具
11、31 掃除用シート(繊維状基材)
12、22、32 把持具
13 保持空間
32a 先端部
33 凸部
Claims (6)
- 保持シートと、前記保持シートとの間で把持具を挿入するための保持空間が形成される基材シートと、トウファイバーからなる繊維束と、が順に積層された繊維状基材を有する室内用の清掃拭き取り具であって、
前記繊維状基材の前記繊維束にのみ、アレルギーを引き起こす物質の抗原性を低減化する、抗原性低減化成分が付与され、主成分が流動パラフィンである油剤と、界面活性剤と、水と、を含む抗原性低減化組成物が付与されており、
前記抗原性低減化組成物に含まれる前記油剤と水分の重量比率において、前記水分量が5.0%以下であり、前記油剤に前記水分が可溶化しているドライタイプの掃除用具。 - 前記界面活性剤は、非イオン系界面活性剤である請求項1記載の掃除用具。
- 前記油剤は、着塵油剤である請求項1又は2記載の掃除用具。
- 前記油剤は、鉱物油である請求項1から3いずれか記載の掃除用具。
- 前記鉱物油は、30℃における粘度が10〜200mm2/sである請求項4記載の掃除用具。
- 前記抗原性低減化組成物全体に対し、前記抗原性低減化成分を0.01〜10質量%、前記油剤を50〜95質量%、前記界面活性剤を1〜50質量%含有する請求項1から5記載の掃除用具。
Priority Applications (18)
Application Number | Priority Date | Filing Date | Title |
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JP2004262897A JP4688455B2 (ja) | 2004-09-09 | 2004-09-09 | 掃除用具 |
US11/039,059 US7786030B2 (en) | 2004-09-09 | 2005-01-18 | Cleaning tool |
CA 2578489 CA2578489C (en) | 2004-09-09 | 2005-08-10 | Cleaning tool |
PCT/JP2005/014626 WO2006027927A1 (ja) | 2004-09-09 | 2005-08-10 | 掃除用具 |
KR1020077007324A KR101176680B1 (ko) | 2004-09-09 | 2005-08-10 | 청소 용구 |
PL05770342T PL1785082T3 (pl) | 2004-09-09 | 2005-08-10 | Narzędzie czyszczące |
AT05770342T ATE481027T1 (de) | 2004-09-09 | 2005-08-10 | Reinigungswerkzeug |
MX2007002730A MX2007002730A (es) | 2004-09-09 | 2005-08-10 | Herramienta de limpieza. |
EP20050770342 EP1785082B1 (en) | 2004-09-09 | 2005-08-10 | Cleaning tool |
CN2005800298043A CN101010023B (zh) | 2004-09-09 | 2005-08-10 | 清洁用具 |
TW094127199A TW200614962A (en) | 2004-09-09 | 2005-08-10 | Cleaning appliance |
DE200560023627 DE602005023627D1 (de) | 2004-09-09 | 2005-08-10 | Reinigungswerkzeug |
ES05770342T ES2351609T3 (es) | 2004-09-09 | 2005-08-10 | Utensilio de limpieza. |
MYPI20053743A MY146706A (en) | 2004-09-09 | 2005-08-11 | Cleaning tool |
CN200580029970.3A CN101014695B (zh) | 2004-09-09 | 2005-09-08 | 清洁工具 |
PCT/JP2005/016997 WO2006028280A1 (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
CN200580029969.0A CN101014694B (zh) | 2004-09-09 | 2005-09-08 | 清洁工具 |
PCT/JP2005/016988 WO2006028273A1 (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
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JP2004262897A JP4688455B2 (ja) | 2004-09-09 | 2004-09-09 | 掃除用具 |
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JP2010247791A Division JP5281065B2 (ja) | 2010-11-04 | 2010-11-04 | 掃除用具 |
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JP4688455B2 true JP4688455B2 (ja) | 2011-05-25 |
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JP2004262897A Expired - Fee Related JP4688455B2 (ja) | 2004-09-09 | 2004-09-09 | 掃除用具 |
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US (1) | US7786030B2 (ja) |
EP (1) | EP1785082B1 (ja) |
JP (1) | JP4688455B2 (ja) |
KR (1) | KR101176680B1 (ja) |
CN (1) | CN101010023B (ja) |
AT (1) | ATE481027T1 (ja) |
CA (1) | CA2578489C (ja) |
DE (1) | DE602005023627D1 (ja) |
ES (1) | ES2351609T3 (ja) |
MX (1) | MX2007002730A (ja) |
MY (1) | MY146706A (ja) |
PL (1) | PL1785082T3 (ja) |
TW (1) | TW200614962A (ja) |
WO (1) | WO2006027927A1 (ja) |
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JP2004081840A (ja) * | 2002-07-03 | 2004-03-18 | Kao Corp | 拭き取りシート |
Also Published As
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PL1785082T3 (pl) | 2011-01-31 |
CN101010023B (zh) | 2010-11-03 |
US20060048325A1 (en) | 2006-03-09 |
MX2007002730A (es) | 2007-05-16 |
EP1785082A4 (en) | 2007-09-05 |
CN101010023A (zh) | 2007-08-01 |
EP1785082B1 (en) | 2010-09-15 |
WO2006027927A1 (ja) | 2006-03-16 |
KR101176680B1 (ko) | 2012-08-23 |
ATE481027T1 (de) | 2010-10-15 |
TWI305141B (ja) | 2009-01-11 |
US7786030B2 (en) | 2010-08-31 |
DE602005023627D1 (de) | 2010-10-28 |
JP2006075361A (ja) | 2006-03-23 |
ES2351609T3 (es) | 2011-02-08 |
KR20070053794A (ko) | 2007-05-25 |
CA2578489A1 (en) | 2006-03-16 |
CA2578489C (en) | 2009-12-29 |
EP1785082A1 (en) | 2007-05-16 |
MY146706A (en) | 2012-09-14 |
TW200614962A (en) | 2006-05-16 |
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