JP4669385B2 - Steel strip cleaning method in pickling line - Google Patents

Description

  The present invention relates to a method for cleaning a steel strip in a pickling line that improves the cleanliness and appearance quality of the steel strip in a pickling line for pickling the surface of the steel strip after hot rolling.

For example, in a line for producing a pickled hot rolled steel strip using a hot rolled coil as a starting material or a hot dip galvanizing line, the surface of the steel strip after hot rolling is pickled using hydrochloric acid water or the like.
Various methods for cleaning steel strips in this pickling line have hitherto been proposed. For example, JP 61-195983 (Patent Document 1) and JP 64-15386 ( Patent Document 2) and Japanese Patent Application Laid-Open No. 1-246384 (Patent Document 3) describe a chelating agent for a steel strip that has been pickled from a pickling tank when the pickling line is stopped or slowly moved and the pickling solution is squeezed with a ringer roll. A method for preventing discoloration of a steel strip that stipulates washing with water after spraying is described.
However, the above Patent Documents 1 to 3 are intended to remove hydrochloric acid and FeCl2 adhering to the surface of the steel strip, and remove foreign substances consisting of residues including C and Si adhering to the surface of the steel strip as in the present invention. Therefore, there was no technical idea of spraying high-pressure water spray or regulating the pressure.
Japanese Utility Model Publication No. 3-78050 (Patent Document 4) discloses a compact and inexpensive hot dip galvanizing that can easily produce hot dip galvanized steel strip coils and pickled steel strip coils using hot rolled coils as starting materials. Lines are listed.
However, this Patent Document 4 does not discuss the improvement in the cleanliness of the steel strip after pickling in a line where pickling is performed as a pretreatment in the production line of hot dip galvanized steel strip or pickled steel strip. There has been no suggestion of the technical idea of the present invention to spray a high-pressure water spray or to regulate the pressure in order to remove foreign substances composed of residues containing C and Si adhering to the steel strip surface.
Japanese Patent Laid-Open No. 61-195983 JP-A-64-15386 JP-A-1-246384 Japanese Utility Model Publication No. 3-78050

  The present invention solves the problems of the prior art as described above, improves the appearance quality of the pickled steel strip, and in the line where pickling is performed as a pretreatment in the production line of the hot dip galvanized steel strip, It is an object of the present invention to provide a method for cleaning a steel strip in a pickling line that can improve the plating failure of a galvanized steel strip.

In order to solve the above-mentioned problems, the present invention sprays high-pressure water spray on the surface of the steel strip that has been removed from the pickling tank and squeezed the pickling solution with a ringer roll, thereby adhering to the surface of the steel strip. The foreign substance consisting of the residue containing Si is removed, and the gist thereof is the following contents as described in the claims.
(1) In the pickling line for pickling a steel strip surface after hot rolling, for the out of the pickling tank is narrowed to the pickling solution in wringer roll steel strip surface, immediately after the wringer roll steel A nozzle provided in a spray header extending in a direction perpendicular to the traveling direction of the steel strip above the surface of the strip, the nozzle height H (mm) from the steel strip surface being 50 to 100 (mm) A high pressure water spray having a constant discharge pressure of 50 to 80 (Kg / cm ² ) sprayed from adjacent nozzles and rotated by θ (°) with respect to the traveling direction of the steel strip. With a nozzle pitch L (mm) that spreads over and avoids interference between high-pressure water sprays sprayed from adjacent nozzles and wraps the uniform spray range of each nozzle by 1/2 in the width direction of the steel strip Multiple high-pressure water spray nozzles arranged A method for cleaning a steel strip in a pickling line, wherein the surface of the steel strip is cleaned by spraying a high-pressure water spray.
(2) The method of cleaning a steel strip in a pickling line as described in (1), wherein the collision energy of the high-pressure water spray to the steel strip is 0.006 J / mm ² or more.
(3) The steel in the pickling line according to (1) or (2), wherein the steel strip surface is cleaned as a pretreatment for applying Ni pre-plating and hot-dip galvanizing to the steel strip surface. How to clean the belt.

According to the present invention, by removing the deposits on the surface of the steel strip by spraying high-pressure water spray onto the surface of the steel strip which has been pickled out of the pickling tank and squeezed with the pickling solution by the Ringer roll, The appearance quality of the steel strip can be improved.
In addition, in a production line for hot-dip galvanized steel strip, a line where pickling is performed as a pretreatment, a spray of high-pressure water is sprayed on the surface of the steel strip that has been pickled from the pickling tank and pickled with a ringer roll. With this, it is possible to significantly improve the plating defects of the hot dip galvanized steel strip.

The best mode for carrying out the present invention will be described in detail with reference to FIGS.
FIG. 1 is a diagram illustrating a production line for a hot-dip galvanized steel strip to which the steel strip cleaning method of the present invention is applied.
In FIG. 1, 1 is a pay-off reel for delivering a hot-rolled coil manufactured in a continuous hot rolling line, 2 is a coil tip end welding apparatus, 3 is a bridle roll, 4 is a deflector roll, and 5 is an entry side looper. , 6 and 7 are deflector rolls, 9 is a bridle roll, 11 is a pickling tank, 12 is a rinsing tank, 13 is a catenary roll disposed in the tanks 11 and 12, 14 is a dryer, 15 is a bridle roll, and 16 is a support. Roll, 17 is a nickel plating device for plating nickel on a pickled steel strip 0.07 to 1.2 g / m ² , 18 is a rinse, 19 is a dryer, 20 is a 30-50 ° C nickel-coated steel strip heated to 400-500 ° C Heating device, 21 is a molten zinc pot containing a molten zinc bath 22 of 390 to 480 ° C. with an aluminum concentration of 0.1 to 5.0%, 23 is a sink roll, and 24 is the amount of molten zinc attached. Adjusting device, 25 is a cooling device for cooling the hot-dip galvanized steel strip to 400 to 420 ° C, 26 is a zero spangle device, 27 is a cooling device for cooling the steel strip to 250 to 300 ° C or less, 28 and 29 are top rolls, 30 is a cooling device for cooling the steel strip to 60 ° C. or less, 31 is a deflector roll, 32 is a shape leveling device such as a tension leveler or roller leveler for correcting the shape of a hot dip galvanized steel strip, 33 is a dryer, and 34 is zinc attached 35, 36, 37, 38 and 39 are deflector rolls, 40 is a chemical conversion treatment device, 41 is a dryer, 42 is a bridle roll, 43 and 44 are deflector rolls, 45 is an exit looper, and 46 and 47 are deflector rolls. 48 is a bridle roll, 49 is a side trimmer, 50 is a bridle roll, 51 is a shear, and 52 is a tension reel. As shown in FIG. 1, the entry-side bridle roll 15 of the nickel plating apparatus 17 and the entry-side bridle roll 42 of the exit-side looper 45 are arranged close to each other.

FIG. 1 shows the state of sheet passing during the production of hot-dip galvanized hot-rolled steel strip coil. The line switching from hot-dip galvanized hot-rolled steel strip coil production to pickling hot-rolled coil production By cutting the steel strip on the exit side of the bridle roll 15, cutting the steel strip on the exit side of the bridle roll 42, and welding the cut end on the bridle roll 15 side and the cut end on the exit looper 45 side Can be done.
At this time, since the bridle roll 15 and the bridle roll 42 are arranged close to each other, the end connection can be performed without almost pulling out the steel strip wound around the bridle roll 15 for the end connection. The steel strip from the entry side of the nickel plating apparatus 17 to the exit side of the bridle roll 42 is left as it is.
Conversely, the line switching from the production of the pickling hot rolled coil to the production of the hot dip galvanized hot rolled steel strip coil is performed by cutting the steel strip on the exit side of the bridle roll 15 and cutting the steel strip on the bridle roll 15 side. And the rear end of the steel strip remaining from the entry side of the nickel plating device 17 to the exit side of the bridle roll 42 are welded together and the steel strip cutting end on the exit looper 45 side and the nickel plating device This can be done by welding the steel strip remaining from the entry side 17 to the exit side of the bridle roll 42.

In this pickling line, there are problems such as poor appearance quality such as poor color tone on the surface of the steel strip and poor plating such as non-uniform hot dip galvanizing.
In order to determine these causes, the present inventors conducted a component analysis of the defective portion of the hot dip galvanizing, and as a result, foreign matter containing about 1% C or 3-4% Si adhered to the surface of the steel strip. This phenomenon is prominent in steel types containing 0.1 to 0.15% Cu as a trump element in the steel strip components, and therefore foreign matter is generated due to Cu contained in the steel strip. It was estimated that.
In addition, it was estimated that foreign matter was brought from the pickling tank because Cl was detected at about 0.5% in the defective plating portion.
Therefore, in the pickling line for pickling the steel strip surface after hot rolling, the present invention adheres to the steel strip surface by spraying high-pressure water spray on the steel strip surface that comes out of the pickling tank. The present inventors have found a method for removing the foreign matter composed of residues containing C and Si and cleaning the surface of the steel strip, and an embodiment thereof will be described below.

FIG. 2 is a diagram illustrating an embodiment of a steel strip cleaning method in the pickling line of the present invention.
In FIG. 2, 61 is a steel strip, 62 is a pickling tank, 63 is a ringer roll, 64 is a high-pressure spray nozzle, 65 is a water spray nozzle (low-pressure nozzle of 2.0 kg / cm ² or less), 66 is a cold rinse tank, 67 Is a deflector roll, 68 is a ringer roll, 69 is a hot rinse tank, 70 is a deflector roll, 71 is a water spray nozzle (low pressure nozzle of about 0.5 kg / cm ² ), and 72 is a ringer roll.
As shown in FIG. 2, the steel strip 61 from the pickling tank 62 and squeezed with the pickling solution by the Ringer roll 63 is sprayed with high-pressure water on the surface by a high-pressure spray nozzle 64 provided immediately after that. After the foreign matter including C and Si adhering to the surface of the belt 61 is removed while it is wet and easily removed, it enters the cold rinse tank 66 and the hot rinse tank 69 to remove the pickling solution.
In the present invention, the steel strip 61 that has come out of the pickling tank 62 and is squeezed with the pickling solution by the Ringer roll 63 is sprayed with high-pressure water on the surface by the high-pressure spray nozzle 64 provided immediately after that. The appearance quality of the pickled steel strip can be remarkably improved by removing foreign matters including C and Si adhering to the surface of the steel in a wet and easy-to-remove state. Defects can be greatly improved.

Furthermore, the present inventors show the results of experiments on the relationship between the collision energy and the steel plate surface quality when the high-pressure water sprayed by the high-pressure spray nozzle collides with the steel plate.
The horizontal axis in FIG. 3 represents the collision energy (J / mm 2) when high-pressure water collides with the steel sheet surface, and the vertical axis represents the ΔL value, which is an increase in the L value indicating the color tone of the steel sheet surface.
As shown in Fig. 3, the ΔL value is 1.7 or more when the impact energy to the steel sheet is 0.006 (J / mm ² ) or more, and the effect is constant when it exceeds 0.01 (J / mm ² ). In addition, the equipment cost required for high pressure spraying is high.
Therefore, the collision energy when the high-pressure water collides with the steel sheet surface is preferably 0.006 (J / mm ² ) or more and 0.01 (J / mm ² ) or less.
The high-pressure water used in the present invention may be room temperature water, but the cleaning effect can be further increased by using warm water of about several tens of degrees Celsius.
The present invention can improve the appearance quality by applying it to a pickled steel strip that is not plated on the surface of the steel strip. In particular, Ni pre-plating is applied to the surface of the steel strip, and hot dip zinc is applied thereon. By applying it as a pretreatment when plating, the amount of Ni pre-plating used as a base treatment for galvanization can be made uniform, and as a result, plating defects in hot dip galvanization can be significantly reduced. .

FIG. 4 is a diagram showing a comparison of plating defect occurrence ratios before and after spraying of the high-pressure water spray used in the present invention (when the pre-improvement is 100%).
As shown in the bar graph on the right side of FIG. 4, by using the cleaning method of the present invention, it was possible to reduce the incidence of defective plating of hot dip galvanizing to 30% or less compared to the conventional case.
5 to 7 are views showing a preferable discharge pressure and nozzle arrangement of the high-pressure spray nozzle used in the present invention.
The horizontal axis of FIG. 5 (a) indicates the discharge pressure (kg / cm ² ) of the high-pressure spray nozzle, and the vertical axis indicates the ΔL value, which is an increase in the L value indicating the color tone of the steel sheet surface.
As shown in Fig. 5 (a), when the discharge pressure of the high-pressure spray nozzle is 50 (kg / cm ² ) or more, the ΔL value is 1.7 or more, which is remarkably improved, so 50 (kg / cm ² ) or more is preferable. The preferable range is 80 (kg / cm ² ) or less at which is constant.
The horizontal axis in FIG. 5 (b) indicates the nozzle height H (mm), which is the distance from the tip of the high-pressure spray nozzle to the steel strip surface, and the vertical axis indicates the ΔL value, which is an increase in L value indicating the color tone of the steel sheet surface. Indicates.
As shown in FIG. 5B, since the ΔL value becomes 1.7 or more when the nozzle height H of the high-pressure spray nozzle is 100 (mm) or less and is remarkably improved, 100 (mm) or less is a preferable range.
Further, the smaller the nozzle height H is, the larger the ΔL value is, but 50 (mm) or more is necessary to secure the nozzle installation space.

FIG. 6 is a view showing the nozzle arrangement of the high-pressure spray nozzle used in the present invention.
In FIG. 6, L represents the nozzle pitch (mm), H represents the nozzle height (mm), and θ represents the nozzle rotation angle (°).
As shown in FIG. 6, the high-pressure water spray sprayed from adjacent nozzles sprays so as to spread in an elliptical shape rotated by θ (°) with respect to the traveling direction of the steel strip, and is sprayed from adjacent nozzles. By avoiding interference between water sprays and wrapping the uniform spray range of each nozzle by 1/2 in the width direction of the steel strip, it is possible to spray uniformly in the width direction of the steel strip, and 1 The spray header can double the cleaning effect.
FIG. 7 is a diagram illustrating a preferred nozzle arrangement of the high-pressure water spray used in the present invention.
As shown in FIG. 7, the nozzle pitch L (mm) and the nozzle rotation angle θ (°) are set within the range of the optimum values indicated by ○, for example, L = 100 (mm) and θ = 20 (°). Thus, the lap allowance (overlap allowance) target value of spray sprayed from adjacent nozzles can be set to 75 (mm), and uniform spraying can be performed in the width direction of the steel strip. The spray header can double the cleaning effect.

It is a figure which illustrates the production line of the hot dip galvanized steel strip which applies the cleaning method of the steel strip of this invention. It is a figure which illustrates embodiment of the cleaning method of the steel strip in the pickling line of this invention. It is a figure which shows the relationship between the collision energy of the high pressure water spray used for this invention, and the improvement degree of a steel strip color tone. It is a figure which shows the comparison of the plating defect generation ratio before and after spraying of the high-pressure water spray used in the present invention (when pre-improvement is 100%). It is a figure which shows the relationship between the spray pressure of the high pressure water spray used for this invention, distance, and a color tone. It is a figure which illustrates nozzle arrangement | positioning of the high pressure water spray used for this invention. It is a figure which illustrates the preferable nozzle arrangement | positioning of the high pressure water spray used for this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Payoff reel 2 Coil tip end welding apparatus 3 Bridle roll 4 Deflector roll 5 Entrance side looper 6,7 Deflector roll 9 Bridle roll 11 Pickling tank 12 Rinse tank 13 Catenary roll 14 Dryer 15 Bridle roll 16 Support roll 17 Nickel plating apparatus 18 Rinse 19 Dryer 20 Heating device 21 Molten zinc pot 22 Molten zinc bath 23 Sink roll 24 Molten zinc adhesion amount adjusting device 25 Cooling device 26 Zero spangle device 27 Cooling devices 28, 29 Top roll 30 Cooling device 31 Deflector roll 32 Shape correction device 33 Dryer 34 Zinc adhesion meter 35, 36, 37, 38, 39 Deflector roll 40 Chemical conversion device 41 Dryer 42 Bridle roll 43, 44 Deflector roll 45 Outgoing loop -46, 47 Deflector roll 48 Bridle roll 49 Side trimmer 50 Bridle roll 51 Shear 52 Tension reel 61 Steel strip 62 Pickling tank 63 Ringer roll 64 High pressure spray nozzle 65 Water spray nozzle 66 Cold drain tank 67 Deflector roll 68 Ringer roll 69 Hot Rinse tank 70 Deflector roll 71 Water spray nozzle 72 Ringer roll

Claims (3)

In pickling line for pickling a steel strip surface after hot rolling, for the out of the pickling tank is narrowed to the pickling solution in wringer roll steel strip surface, immediately after the wringer roll of steel strip surface A nozzle provided on a spray header extending in a direction perpendicular to the traveling direction of the steel strip above, the nozzle height H (mm) from the steel strip surface being a constant value of 50 to 100 (mm) Then, a high pressure water spray having a constant discharge pressure of 50 to 80 (Kg / cm ² ) sprayed from adjacent nozzles spreads in an elliptical shape rotated by θ (°) with respect to the traveling direction of the steel strip, A plurality of nozzles arranged at a nozzle pitch L (mm) that avoids interference between high-pressure water sprays sprayed from adjacent nozzles and wraps the uniform spray range of each nozzle by 1/2 in the width direction of the steel strip From the high pressure water spray nozzle A method for cleaning a steel strip in a pickling line, wherein the surface of the steel strip is cleaned by spraying high-pressure water spray. The method of cleaning a steel strip in a pickling line according to claim 1, wherein the energy of collision of the high-pressure water spray with the steel strip is 0.006 J / mm ² or more. The steel strip surface in the pickling line according to claim 1 or 2, wherein the steel strip surface is cleaned as a pretreatment for applying Ni pre-plating and hot-dip galvanizing to the steel strip surface. Method.

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