JP4633587B2 - Mirror for vehicle with heater and method for manufacturing the same - Google Patents

Description

  The present invention relates to a vehicle mirror with a heater using a PTC (Positive Temperature Coefficient) heating element and a method for manufacturing the same.

  In the vehicle mirror with a heater, a heater is provided on the mirror plate of the vehicle mirror, and the mirror plate is heated by energizing the heater to remove water droplets attached to the mirror surface. Heaters used for vehicle mirrors with heaters use PTC heating elements in addition to those using heating wires. According to the one using the PTC heating element, since the temperature is self-adjusted, there is an advantage that a separate part such as a thermostat for temperature adjustment becomes unnecessary.

  As a conventional vehicle mirror with a heater using a PTC planar heating element, there are those described in Patent Documents 1 to 4 below. The vehicle mirror with a heater described in Patent Document 1 is configured by forming a pair of electrodes made of metal foil in a comb shape on a substrate such as a polyester film and covering the sheet-like PTC sheet heating element thereon. The heating element is bonded to the back surface of the mirror plate. When a voltage is applied between the pair of electrodes, the PTC planar heating element generates heat.

  In the vehicle mirror with heater described in Patent Document 2, an insulating film is formed on the reflective film on the back surface of the mirror plate, and a pair of conductive film patterns constituting electrodes are formed on the insulating film in a comb shape by screen printing. Then, a carbon paste is applied thereon by screen printing to form a PTC sheet heating element, and an insulating film is placed thereon. When a voltage is applied between the pair of conductive films, the PTC planar heating element generates heat.

  In the vehicle mirror with a heater described in Patent Document 3, an insulating resin film is pasted on the reflective film on the back surface of the mirror plate, and a meandering PTC sheet heating element is formed on the resin film. Is covered with a resin film for insulation. By applying a voltage between both ends of the meandering PTC sheet heating element, the PTC sheet heating element generates heat.

  The vehicle mirror with a heater described in Patent Document 4 is a mirror substrate in which a reflective film-cum-electrode, a PTC sheet heating element, and a power feeding electrode are sequentially stacked. When a voltage is applied between the reflective film and electrode and the feeding electrode, the PTC planar heating element generates heat.

Japanese Utility Model Publication No. 5-45987 (FIG. 1) JP-A-9-207723 (FIG. 4) Japanese Patent Laid-Open No. 11-20624 (FIG. 3) JP 2001-171490 A (FIG. 2)

  According to the vehicle mirror with a heater described in Patent Documents 1 and 2, it is necessary to pattern the electrodes in a comb shape. According to the vehicle mirror with a heater described in Patent Document 3, it is necessary to pattern the PTC heating element in a meandering shape. According to the vehicle mirror with a heater described in Patent Document 4, the feeding electrode needs to be formed by screen printing on a PTC planar heating element using a copper paste or the like.

  The present invention has been made in view of the above points, and it is not necessary to pattern the electrodes in a comb shape or to form a PTC heating element in a meandering shape, and the feeding electrode is made of a copper paste on the PTC planar heating element. It is an object of the present invention to provide a vehicle mirror with a heater that does not need to be formed by screen printing using the above.

A vehicle mirror with a heater according to the present invention includes a first substrate having a transparent and non-conductive member and a metal reflection film and a first electrode film formed on the back surface, and a non-conductive member and a second electrode on the front surface. A second substrate on which a film is formed, and the metal reflective film-cum-first electrode film and the second electrode film are sandwiched between the first substrate and the second substrate so as to face each other, A PTC planar heating element layer integrated with one substrate and the second substrate, and whose front and back surfaces are electrically connected to the metal reflective film and first electrode film and the second electrode film, respectively. And a driving voltage for the PTC planar heating element layer is applied in the film thickness direction of the PTC planar heating element layer between the metal reflective film / first electrode film and the second electrode film. The front surface side of the first substrate is used as the mirror front surface side.

  According to the vehicle mirror with a heater of the present invention, unlike the vehicle mirror with a heater described in Patent Documents 1 to 3, a voltage is applied in the film thickness direction of the PTC planar heating element layer, so that the electrodes are comb-like. There is no need to pattern or form a PTC heating element in a meandering shape. Further, according to the present invention, since two substrates each having electrodes are used and a PTC heating element is sandwiched between both substrates to form a vehicle mirror with a heater, Can be prepared. Therefore, unlike the vehicle mirror with heater described in Patent Document 4, it is not necessary to form the power supply electrode on the PTC planar heating element by screen printing using copper paste or the like.

  The mirror for a vehicle with a heater according to the present invention can be formed by integrally bonding the first substrate, the PTC planar heating element layer, and the second substrate by the adhesive force of the PTC planar heating element layer. .

  Since the vehicle mirror with a heater according to the present invention uses two substrates each having an electrode, the clip electrodes are fitted and mounted on the substrates, so that the electrodes are connected to the lead wires via the clip electrodes. Can be easily connected to.

  In the vehicle mirror with a heater according to the present invention, the PTC planar heating element layer can be formed using, for example, a conductive paste having PTC characteristics. In this case, if non-conductive particles for controlling the film thickness having a uniform particle size larger than the conductive particles contained in the conductive paste are dispersed in the conductive paste, the PTC planar heat generation The thickness of the body layer can be set to a uniform thickness defined by the particle size of the non-conductive particles for thickness control.

  In the vehicle mirror with a heater according to the present invention, the PTC planar heating element layer may be configured using a sheet-like PTC planar heating element having a uniform thickness.

  In the method of manufacturing a mirror for a vehicle with a heater according to the present invention, a material constituting the PTC planar heating element layer is sandwiched between the first substrate and the second substrate, and the first substrate and the second substrate are The PTC planar heating element layer is formed by heating and pressing each other, and the first substrate, the PTC planar heating element layer, and the second substrate are integrated by the adhesive force of the PTC planar heating element layer. It is a thing.

(Embodiment 1)
Embodiment 1 of the vehicle mirror with heater according to the present invention is shown in a perspective view of FIG. Moreover, the AA cross section of FIG. 2 is shown in FIG. The mirror 10 is a part that constitutes a mirror plate of a vehicle outer mirror device such as a door mirror or a fender mirror. The mirror 10 includes a first substrate 14, a second substrate 18, and a PTC sheet heating element layer 20 composed of a conductive paste 20a having PTC characteristics sandwiched between the first substrate 14 and the second substrate 18. The heating element layer 20 is integrally formed by bonding to each other with the adhesive force of the heating element layer 20. The first substrate 14 is made of a transparent non-conductive member such as a transparent glass plate, and a metal reflection film / first electrode film 12 such as Cr (chromium) is formed on the entire back surface. The second substrate 18 is made of a non-conductive member (not necessarily transparent) such as a glass plate, and the second electrode film 16 such as Cr is formed on the entire front surface. The PTC planar heating element layer 20 is configured by dispersing conductive particles such as carbon particles in a resin. A clip electrode 22 is fitted and attached to the lower edge portion of the first substrate 14 so as to be electrically connected to the metal reflection film / first electrode film 12. A lead wire 26 is connected to the clip electrode 22 with a bonding material 30 such as solder or conductive adhesive. A clip electrode 24 is fitted and attached to the upper edge of the second substrate 18 so as to be electrically connected to the second electrode film 16. A lead wire 28 is connected to the clip electrode 24 with a bonding material 32 such as solder or conductive adhesive. The clip electrodes 22 and 24 are not in direct contact with the PTC planar heating element layer 20.

  The mirror 10 is used with the front surface side of the first substrate 14 as the mirror front surface side, and the driver can view the image behind the vehicle reflected by the metal reflection film / first electrode film 12 from the viewpoint 34. Visually check. A DC voltage for driving the PTC planar heating element layer 20 is supplied between the lead wires 26 and 28. This voltage is applied between the metal reflection film / first electrode film 12 and the second electrode film 16 via the clip electrodes 22 and 24. Thereby, the voltage is applied to the PTC planar heating element layer 20 in the film thickness direction to generate heat. When the temperature is low, the PTC planar heating element layer 20 has a reduced resistance because the number of electric paths formed by connecting conductive particles dispersed in the resin to each other increases. As a result, the current value increases. , The temperature rises. Further, when the temperature is increased, the resin expands and the connection between the conductive particles dispersed in the resin is partially broken, so that the electric circuit is reduced and the resistance value is increased. As a result, the current value is increased. Decreases and temperature decreases. With such a mechanism, the current value of the PTC planar heating element layer 20 is automatically adjusted according to the temperature during energization, and is maintained at a predetermined temperature.

  An example of a manufacturing process of the mirror 10 according to the first embodiment will be described. A transparent glass substrate having a curvature R = 1000 mm is prepared as the first substrate 14. On the back surface (concave surface) of the transparent glass substrate 14, a Cr film is formed as a metal reflective film and first electrode film 12 to a thickness of 80 nm by sputtering. Similarly, a transparent glass substrate having a curvature R = 1000 mm is prepared as the second substrate 18. On the surface (convex surface) of the transparent glass substrate 18, a Cr film is formed as a second electrode film 16 to a thickness of 80 nm by a sputtering method. The metal reflecting film / first electrode film 12 and the second electrode film 16 can be formed by a vapor deposition method, an ion plating method or the like in addition to the sputtering method.

  Next, as shown in FIG. 3, a conductive paste having PTC characteristics, which is a material of the PTC planar heating element layer 20, at the center of the surface of the metal reflecting film / first electrode film 12 on the concave surface of the first substrate 14. 20a is discharged by an appropriate paste discharge device (dispenser). The conductive paste 20a having PTC characteristics can be configured by dispersing conductive particles such as carbon particles in a resin. More specifically, the conductive paste 20a having PTC characteristics can be composed of, for example, a mixture of a polymer, a conductivity imparting agent, an insulating filler, a plasticizer, a dispersant, and the like. In this case, the main operating temperature can be set according to the type of polymer. Further, the resistance value and the secondary operating temperature can be set by the conductivity imparting agent, the insulating filler, the plasticizer, and the dispersing agent. In order to bond and integrate with the first substrate 14 and the second substrate using the adhesive force of the PTC planar heating element layer 20 itself, a hot melt type or adhesive type polymer can be used. As the hot melt type polymer, an ethylene-vinyl acetate copolymer, an olefin type, a thermoplastic elastomer, a polyester type, or a mixture thereof can be used. As the adhesive polymer, rubber-based, acrylic-based, urethane-based, vinyl ether, silicone-based, or a mixture thereof can be used. As the conductivity imparting agent, conductive particles such as ketjen black (registered trademark), carbon black, metal fine particles, and surface-treated fine particles having a metal thin film formed on the surface can be used. As the insulating filler, metal oxide, talc, silica, mica and the like can be used.

A blending example of the conductive paste 20a having PTC characteristics is shown below. The polymer is also blended to serve as an adhesive.

(Formulation example of conductive paste 20a having PTC characteristics)
・ Main polymer: Saturated polyester resin 45%
-Secondary polymer: 27% acrylic rubber
・ Carbon black: 23%
・ Mica: 4%
・ Dispersant: 1%

  When the conductive paste 20a is discharged to the central portion of the concave surface of the first substrate 14, the first substrate 14 and the second substrate 18 are shifted from each other by the amount of the clip electrodes 22 and 24 (see FIG. 1). The outer surfaces of the first substrate 14 and the second substrate 16 are formed on the outer surfaces of the first substrate 14 and the outer surface of the second substrate 16 (the concave outer surface shape for the convex outer surface of the first substrate 14 and the concave outer surface of the second substrate 18). A heated jig (not shown) having a convex outer surface shape is pressed against each other to heat and press each other, so that the conductive paste 20a is opposed to the metal reflecting film / first electrode film 12 and the second electrode film 16. It extends in layers over the entire surface. In this case, since the conductive paste 20a is uniformly spread in all directions from the center of the substrates 14 and 18, air is prevented from being taken into the layer of the conductive paste 20a. As a result, the PTC planar heating element layer 20 without a hole is formed, and the first substrate 14 and the second substrate 18 are bonded to each other using the PTC planar heating element layer 20 as an adhesive and integrated. Since the first substrate 14 and the second substrate 18 have the same curvature, the thickness of the PTC planar heating element layer 20 is uniform. Thereafter, when the bonded body returns to room temperature, the PTC planar heating element layer 20 is stabilized and the integrated state is stably maintained. Note that the operating temperature of the PTC planar heating element layer 20 varies depending on the film thickness and the resistance value between the metal reflective film / first electrode film 12 and the second electrode film 16 varies, Therefore, the film thickness (for example, 0.15 mm or other appropriate value) at which a desired operating temperature is obtained is set.

  Thereafter, the clip electrode 22 is fitted and attached to the lower edge portion of the first substrate 14 so as to be electrically connected to the metal reflection film / first electrode film 12, and is electrically connected to the second electrode film 16 on the upper edge portion of the second substrate 18. The clip electrode 24 is fitted and attached as shown. Further, the lead wire 26 is connected to the clip electrode 22 with a bonding material 30 such as solder or conductive adhesive, and the lead wire 28 is connected to the clip electrode 24 with a bonding material 32 such as solder or conductive adhesive. The mirror 10 is completed.

  When a driving voltage is applied between the lead wires 26 and 28 of the mirror 10 manufactured as described above, the PTC sheet heating element layer 20 generates heat by applying the voltage in the film thickness direction. In this case, even if the PTC planar heating element layer 20 is continuously energized, the temperature of the PTC planar heating element layer 20 is maintained at a constant value by the self-temperature adjusting function of the PTC planar heating element layer 20. Further, since the thickness of the PTC planar heating element layer 20 is constant, the area resistance of the PTC planar heating element layer 20 is constant regardless of the position, and the entire surface is heated to a substantially uniform temperature.

  FIG. 4 shows an example of the relationship between the environmental temperature of the mirror 10 and the resistance value between the lead wires 26 and 28. According to this, the resistance value increases rapidly as the temperature rises. FIG. 5 shows the relationship between the time (based on the start of application) and the mirror surface temperature when a voltage of 13.5 V is applied between the lead wires 26 and 28 of the mirror 10 (the temperature before voltage application is about 20). An example is shown. According to this, the mirror surface temperature rises with time, and when it reaches a certain temperature, it is maintained at that temperature by the self-temperature adjustment function.

(Embodiment 2)
Embodiment 2 of the vehicle mirror with heater according to the present invention is shown in FIG. 6 in a sectional view (a sectional view at a position corresponding to the section AA in FIG. 2 relating to Embodiment 1). The same reference numerals are used for portions common to those in FIG. The mirror 36, instead of the conductive paste 20a has been PTC planar heating element layer 20 composed of the first embodiment, composed of a conductive paste 20a that are dispersed film thickness control for non-conductive particles 38 The PTC sheet heating element layer 40 is disposed. The non-conductive particles 38 for controlling the film thickness are made of non-conductive materials such as plastic beads and non-conductive metal oxides having a uniform particle size. The film thickness control non-conductive particles 38 have a larger particle size than the conductive particles contained in the PTC planar heating element layer 40 and can obtain desired heating characteristics of the PTC planar heating element layer 40. It is set to a value equal to the thickness (for example, 0.15 mm or other appropriate value).

  The mirror 36 is used with the front surface side of the first substrate 14 as the mirror front surface side, and the driver can view an image of the rear of the vehicle reflected by the metal reflection film / first electrode film 12 from the viewpoint 34. Visually check. A DC voltage for driving the PTC planar heating element layer 40 is supplied between the lead wires 26 and 28. This voltage is applied between the metal reflection film / first electrode film 12 and the second electrode film 16 via the clip electrodes 22 and 24. As a result, the PTC planar heating element layer 40 generates heat when a voltage is applied in the film thickness direction. When the temperature is low, the PTC planar heating element layer 40 has a reduced resistance because the number of electric paths formed by connecting conductive particles dispersed in the resin to each other increases. As a result, the current value increases. , The temperature rises. Further, when the temperature is increased, the resin expands and the connection between the conductive particles dispersed in the resin is partially broken, so that the electric circuit is reduced and the resistance value is increased. As a result, the current value is increased. Decreases and temperature decreases. With such a mechanism, the current value of the PTC planar heating element layer 40 is automatically adjusted according to the temperature during energization, and is maintained at a predetermined temperature.

  An example of the manufacturing process of the mirror 36 according to the second embodiment will be described. A transparent glass substrate having a curvature R = 1000 mm is prepared as the first substrate 14. On the back surface (concave surface) of the transparent glass substrate 14, a Cr film is formed as a metal reflective film and first electrode film 12 to a thickness of 80 nm by sputtering. Similarly, a transparent glass substrate having a curvature R = 1000 mm is prepared as the second substrate 18. On the surface (convex surface) of the transparent glass substrate 18, a Cr film is formed as a second electrode film 16 to a thickness of 80 nm by a sputtering method. The metal reflecting film / first electrode film 12 and the second electrode film 16 can be formed by a vapor deposition method, an ion plating method or the like in addition to the sputtering method.

  Next, as shown in FIG. 7, a conductive paste having PTC characteristics, which is a material of the PTC planar heating element layer 40, at the center of the surface of the metal reflective film / first electrode film 12 on the concave surface of the first substrate 14. A material in which the non-conductive particles 38 for controlling the film thickness are dispersed in 20a is discharged by an appropriate paste discharge device. For the conductive paste 20a having PTC characteristics, the same material as that described in the first embodiment can be used.

  Further, the first substrate 14 and the second substrate 18 are shifted from each other (see FIG. 6) to the extent that the clip electrodes 22 and 24 are attached, and are aligned on the outer surfaces of the first substrate 14 and the second substrate 16. A heated jig (not shown) having an outer surface shape following each outer surface is pressed against each other and heated and pressed to be regulated by the non-conductive particles 38 for film thickness control (that is, film thickness control). Non-conductive particles 38 are pressed against the metal reflective film / first electrode film 12 and the second electrode film 16 so that the metal reflective film / first electrode film 12 and the second electrode film 16 cannot be further approached. The conductive paste 20a is extended in a layered manner over the entire area of the opposing surfaces of the metal reflective film / first electrode film 12 and the second electrode film 16. As a result, the PTC planar heating element layer 40 is formed, and the first substrate 14 and the second substrate 18 are bonded and integrated with each other using the PTC planar heating element layer 40 as an adhesive. Since the first substrate 14 and the second substrate 18 have the same curvature, the film thickness of the PTC planar heating element layer 40 is a uniform film thickness determined by the particle diameter of the film-controlling non-conductive particles 38 (for example, 0.15 mm). Other appropriate values). Thereafter, when the bonded body returns to room temperature, the PTC planar heating element layer 40 is stabilized and the integrated state is stably maintained.

  Thereafter, the clip electrode 22 is fitted and attached to the lower edge portion of the first substrate 14 so as to be electrically connected to the metal reflection film / first electrode film 12, and is electrically connected to the second electrode film 16 on the upper edge portion of the second substrate 18. The clip electrode 24 is fitted and attached as shown. Furthermore, the lead wire 26 is connected to the clip electrode 22 with a bonding material 30 such as solder or conductive adhesive, and the lead wire 28 is connected to the clip electrode 24 with a bonding material 32 such as solder or conductive adhesive. The mirror 36 is completed.

(Embodiment 3)
A third embodiment of the vehicle mirror with heater according to the present invention is shown in FIG. 8 as a cross-sectional view (a cross-sectional view at a position corresponding to the AA cross section in FIG. 2 relating to the first embodiment). The same reference numerals are used for portions common to those in FIG. In this mirror 42, a PTC sheet heating element layer 46 composed of a sheet-like PTC sheet heating element 44 is disposed instead of the PTC sheet heating element layer 20 composed of the conductive paste 20a of the first embodiment. It is a thing. The sheet-like PTC sheet heating element 44 can be configured, for example, by impregnating a non-woven fabric with a conductive paste having PTC characteristics. The film thickness of the sheet-like PTC planar heating element 44 is set to a film thickness (for example, 0.15 mm or other appropriate value) that provides desired heat generation characteristics.

  The mirror 42 is used with the front surface side of the first substrate 14 as the mirror front surface side, and the driver can view an image behind the vehicle reflected by the metal reflective film / first electrode film 12 from the viewpoint 34. Visually check. A DC voltage for driving the PTC planar heating element layer 46 is supplied between the lead wires 26 and 28. This voltage is applied between the metal reflection film / first electrode film 12 and the second electrode film 16 via the clip electrodes 22 and 24. Thereby, the voltage is applied to the PTC planar heating element layer 46 in the film thickness direction to generate heat. When the temperature of the PTC planar heating element layer 46 is low, the resistance value decreases because the number of electric paths formed by interconnecting conductive particles dispersed in the resin increases, and as a result, the current value increases. , The temperature rises. Further, when the temperature is increased, the resin expands and the connection between the conductive particles dispersed in the resin is partially broken, so that the electric circuit is reduced and the resistance value is increased. As a result, the current value is increased. Decreases and temperature decreases. With such a mechanism, the current value of the PTC planar heating element layer 46 is automatically adjusted according to the temperature during energization, and is maintained at a predetermined temperature.

  An example of the manufacturing process of the mirror 42 according to the third embodiment will be described. A transparent glass substrate having a curvature R = 1000 mm is prepared as the first substrate 14. On the back surface (concave surface) of the transparent glass substrate 14, a Cr film is formed as a metal reflective film and first electrode film 12 to a thickness of 80 nm by sputtering. Similarly, a transparent glass substrate having a curvature R = 1000 mm is prepared as the second substrate 18. On the surface (convex surface) of the transparent glass substrate 18, a Cr film is formed as a second electrode film 16 to a thickness of 80 nm by a sputtering method. The metal reflecting film / first electrode film 12 and the second electrode film 16 can be formed by a vapor deposition method, an ion plating method or the like in addition to the sputtering method.

  Next, as shown in FIG. 9, the PTC planar heating element layer 46 is interposed between the first substrate 14 and the second substrate 18 with the metal reflective film / first electrode film 12 and the second electrode film 16 facing each other. The sheet-like PTC planar heating element 44 constituting the above is disposed. Then, the first substrate 14 and the second substrate 18 are displaced from each other (see FIG. 8) by the amount corresponding to the clip electrodes 22 and 24 (see FIG. 8), and the first substrate 14, the sheet-like PTC sheet heating element 44, The second substrate 18 is overlaid. In this state, the first substrate 14 and the second substrate 16 are pressed against each outer surface of the first substrate 14 and the second substrate 16 with a heated jig (not shown) having an outer surface shape following these outer surfaces. 18 are mutually heated and pressed, and the first substrate 14 and the second substrate 18 are bonded to each other using the sheet-like PTC planar heating element 44 as an adhesive to be integrated. Since the first substrate 14 and the second substrate 18 have the same curvature, one surface of the sheet-like PTC planar heating element 44 is bonded to the metal reflective film / first electrode film 12 over the entire surface, and the other surface is The entire surface is bonded to the second electrode film 16. Then, if this bonded body returns to normal temperature, the integrated state is stably maintained.

  Thereafter, the clip electrode 22 is fitted and attached to the lower edge portion of the first substrate 14 so as to be electrically connected to the metal reflection film / first electrode film 12, and is electrically connected to the second electrode film 16 on the upper edge portion of the second substrate 18. The clip electrode 24 is fitted and attached as shown. Further, the lead wire 26 is connected to the clip electrode 22 with a bonding material 30 such as solder or conductive adhesive, and the lead wire 28 is connected to the clip electrode 24 with a bonding material 32 such as solder or conductive adhesive. The mirror 42 is completed.

It is a figure which shows Embodiment 1 of the mirror for vehicles with heaters of this invention, and is AA sectional drawing of FIG. It is the perspective view which looked at the mirror for vehicles with a heater of Drawing 1 from the back side. It is the perspective view seen from the mirror back surface side which shows a part of manufacturing process of the mirror 10 for vehicles with a heater of FIG. FIG. 3 is a diagram illustrating an example of a relationship between an environmental temperature of a mirror 10 in FIG. 1 and a resistance value between lead wires 26 and 28. FIG. 2 is a diagram showing an example of the relationship between time and mirror surface temperature when a voltage of 13.5 V is applied between the lead wires 26 and 28 of the mirror 10 of FIG. It is sectional drawing which shows Embodiment 2 of the mirror for vehicles with a heater of this invention. It is the perspective view seen from the mirror back side which shows a part of manufacturing process of the mirror 36 for vehicles with a heater of FIG. It is sectional drawing which shows Embodiment 3 of the mirror for vehicles with heaters of this invention. It is the perspective view seen from the mirror back side which shows a part of manufacturing process of the mirror 42 for vehicles with a heater of FIG.

Explanation of symbols

  DESCRIPTION OF SYMBOLS 10, 36, 42 ... Vehicle mirror with a heater, 12 ... Metal reflective film and 1st electrode film, 14 ... 1st board | substrate comprised with the transparent nonelectroconductive member, 16 ... 2nd electrode film, 18 ... Nonelectroconductive member Second substrate 20, 40, 46 ... PTC planar heating element layer, 20 a ... conductive paste, 38 ... non-conductive particles for film thickness control, 44 ... sheet-like PTC planar heating element.

Claims (8)

A first substrate composed of a transparent non-conductive member and having a metal reflective film and first electrode film formed on the back surface;
A second substrate formed of a non-conductive member and having a second electrode film formed on the front surface;
The metal reflective film / first electrode film and the second electrode film are sandwiched between the first substrate and the second substrate so that the first electrode film and the second substrate are opposed to each other. And the PTC sheet heating element layer, each of which is integrated and electrically connected to the metal reflection film / first electrode film and the second electrode film,
A driving voltage for the PTC planar heating element layer is applied between the metal reflective film / first electrode film and the second electrode film in the thickness direction of the PTC planar heating element layer, and the first substrate A vehicle mirror with a heater that is used with the front side as the mirror front side. A clip electrode connected to the metal reflection film and the first electrode film is fitted and attached to the peripheral edge of the first substrate,
A clip electrode conducting to the second electrode film is fitted and attached to the peripheral edge of the second substrate,
2. The vehicle with a heater according to claim 1, wherein a driving voltage for the PTC planar heating element layer is applied between the metal reflection film / first electrode film and the second electrode film via the two clip electrodes. mirror. The mirror for vehicles with heater according to claim 1 or 2 with which said PTC sheet heating element layer is constituted using conductive paste which has a PTC characteristic. In the conductive paste having the PTC characteristic, non-conductive particles for film thickness control having a uniform particle size larger than the conductive particles contained in the conductive paste having the PTC characteristic are dispersed. Item 4. A vehicle mirror with a heater according to Item 3 . The conductive paste having the PTC characteristic includes a polymer serving as an adhesive, and the first substrate, the PTC planar heating element layer, and the second substrate are mutually bonded by the adhesive force of the PTC planar heating element layer. The vehicle mirror with a heater according to claim 3 or 4 , wherein the mirror is attached to and integrated with the heater. A method for manufacturing a vehicle mirror with a heater according to claim 5 ,
A material constituting the PTC planar heating element layer is sandwiched between the first substrate and the second substrate, and the PTC planar heating element is heated and pressed against each other. A method of manufacturing a mirror for a vehicle with a heater, in which a first layer, a PTC planar heating element layer, and a second substrate are integrated by forming an adhesive layer and bonding the PTC planar heating element layer. The mirror for a vehicle with a heater according to claim 1 or 2, wherein the PTC planar heating element layer is configured by using a sheet-like PTC planar heating element having a uniform thickness.   The mirror for a vehicle with a heater according to claim 7, wherein the sheet-like PTC sheet heating element is configured by impregnating a nonwoven fabric with a conductive paste having PTC characteristics.

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