JP4589458B2 - Mechanical member belonging to sliding pair and method for manufacturing the mechanical member - Google Patents

Abstract

In a process to run-in a large marine two-stroke diesel engine, the piston rings move up and down in the hard cylinder walls (6) from which they are separated by a metallic soft abrasion agent (7). The metallic abrasion agent is a coating on the piston rings that is softer than the piston rings but no harder than the cylinder lining. The non-wearing structure and abrasion agent are manufactured in a one-stage process.

Description

  The present invention relates to a mechanical member belonging to a sliding pair, which comprises two mechanical members which are movable relative to each other in a large engine, in particular a two-cycle large diesel engine. The mechanical member has a wear-resistant structure comprising particles of a relatively hard material received in a metal matrix and a rough and undulating surface at least in the region of the surface facing the other mechanical member. The machine member is formed as a piston ring or cylinder liner or a piston with at least one piston ring groove, or other sliding member of a large engine.

  German Patent Application No. 102006023396 discloses a mechanical component of a large engine having a wear-resistant structure in the form of a wear protection coating. In this document, the wear protection coating consists of ceramic particles contained in a matrix formed from a nickel alloy. At this time, a thin surface layer made of only a matrix material is provided on the upper side of the coating. However, it has been found from practice that the surface of the surface layer is rough and not smooth, which is not preferable for the running-in process. Therefore, it is necessary to perform processing in the form of a polishing process. Experience has shown that such a polishing process is extremely time consuming and expensive. Furthermore, nickel alloys are inconvenient in the first place due to the hardness of the nickel alloys.

  In view of the foregoing, it is an object of the present invention to improve a structure of the kind described above, thereby reducing manufacturing costs and realizing good behavior during break-in operation. A further object relates to a method for producing the mechanical component according to the invention in a simple and inexpensive manner.

  The first of the above problems is solved as follows. In other words, the wear-resistant structure is coated with a break-in coating for uniforming the undulation and roughness of the upper part of the structure, and the break-in coating is suitable for wear during the break-in process. The break-in operation material is different from the wear-resistant structure material below the break-in operation material and is metallurgically coupled to the wear-resistant structure. The running-in material is softer than the wear-resistant structure and has at most the same wear resistance as the sliding surfaces of the individual opposing mechanical members.

  The aforementioned disadvantages of the known structures are thus completely eliminated. Because the running-in coating is made of a running-in material, good running-in characteristics can be expected. The break-in operation coating makes uniform the roughness and undulation of the wear-resistant structure below the break-in operation coating, and preferably eliminates the need for polishing. Furthermore, it is assured that the hard particles in the upper region of the wear-resistant structure are firmly fixed even if the surface of the structure is exposed at the end of the break-in operation process. Therefore, there is no need to be afraid of falling off the hard particles. An unpolished surface preferably provides a gas tight contact from the outset, which is highly desirable, especially in the sliding pair of piston ring and cylinder liner. A further advantage of the means according to the invention is that the break-in operating film is metallurgically coupled to ensure that the break-in operating film is fixed to the wear-resistant structure below the break-in operating film. Is to ensure that peeling is avoided.

  Advantageous formations of the superior means and further formations suitable for the purpose are set forth in the dependent claims.

  The running-in coating can thus suitably have a hardness of 100 to 200 HV. In that case, particularly good running-in behavior can be expected. In addition, sufficient durability is ensured, thereby ensuring a sufficiently long break-in operation time.

  In a further formation of the superordinate means, the material forming the break-in film has a melting temperature of less than 1050 ° C., preferably from 600 ° C. to 800 ° C. By this means, a break-in coating can be easily produced by a suitable method. At this time, only the material of the running-in coating is melted, and the wear-resistant structural material below the running-in coating remains solidified. This can provide a very thin boundary layer that metallurgically bonds the break-in run coat to the wear resistant structure below the run-in run coat. Thus, the brittleness that is often expected in the boundary layer preferably has a negligible effect on the overall effect.

  The break-in coating is fresh and may have an average thickness of preferably 50 to 300 micrometers (μm). Such a thickness is empirically sufficient for a running-in time of 1000 to 2000 hours, and the wear properties of the opposing sliding surfaces are taken into account by adjusting the thickness. The greater the wear of the opposing sliding surface, the thicker the break-in coating.

  In a further formation of the superordinate means, the break-in coating has a new surface roughness of 1 to 20 Ra. This eliminates the need for finishing and ensures a particularly good seal from the beginning.

In a particularly advantageous formation of the upper means, the break-in material used as the base for the break-in coating is harder than the break-in material, preferably Al ₂ O ₃ and / or CrO and / or Cr _3. particles made of ceramic material, such as C ₂ is included. This increases the durability time of the break-in coating, which can also increase the break-in time. The proportion of particles included may preferably range from 5 to 30 Vol% of the total volume of the break-in coating. This ensures that the contained particles cannot be unacceptably damaging to the running-in behavior.

  The break-in material used as the base material for the break-in coating may suitably contain at least copper (Cu) and / or tin (Sn). This optimizes the desired break-in performance according to the individual case.

  In a particularly preferred configuration at this time, the break-in coating may include approximately 70% copper (Cu) and approximately 30% tin (Sn). Such materials are preferably usable in many cases. It is also conceivable to add an antimony (Sb) component. In this case, a so-called white alloy is produced, and the white alloy is used as a bearing alloy in actual business, and is therefore conveniently available.

  The wear resistant structure that receives the run-in coating may suitably comprise a matrix formed of a nickel alloy. The matrix includes particles of ceramic material, and the volume fraction of the ceramic material may be greater than 60%, preferably 85%, of the total volume of the wear-resistant structure. By such means, load resistance and wear resistance are particularly increased. By adding relatively small amounts of phosphorus (P) and / or silicon (Si), the melting temperature of the matrix is lowered below the melting temperature of cast iron or the like. This facilitates applying the break-in coating to the wear resistant structure and / or applying the break-in coating to the substrate.

  The problem concerning the method is solved by the present invention as follows. That is, a mechanical member having a wear-resistant structure is coated with a break-in operation film covering the wear-resistant structure, and the wear-resistant structure and / or break-in film is formed during the coating process. The material is supplied with energy so that the break-in coating can be metallurgically bonded to the wear-resistant structure as desired. If a thick boundary layer is desired between the wear resistant structure and the break-in coating, energy is supplied so that the break-in coating is eutectic bonded. In contrast, if a thick boundary layer is not desired between the wear-resistant structure and the break-in coating, the energy supply is greatly reduced, thereby causing the break-in coating to be diffusion bonded. At this time, only the material that forms the break-in coating is melted and only the energy is required so that the wear-resistant structure below the material remains solidified. As a result, a relatively thin boundary layer is obtained in such a case. Moreover, the structure bearing the load is not damaged.

  In order to coat the wear-resistant structure, a heating device that is movable relative to the wear-resistant structure and generates a heating spot in the wear-resistant structure is advantageously used. obtain. At this time, the material forming the break-in film is supplied to the heating spot or a region directly adjacent to the heating spot. This allows a simple construction of the coating device and the supply of energy within narrow limits. The material supplied to the heating spot or the area directly adjacent to the heating spot can be supplied in powder form and / or in the form of a line or strip.

  In a wear-resistant structure formed as a coating on a substrate, it is particularly advantageous if the wear-resistant structure and the break-in coating are applied in the same way to the corresponding substrate. The wear resistant structure and the break-in coating can be applied simultaneously or at time intervals. In either case, mechanical engineering costs are slightly reduced.

  Further advantageous configurations and purposeful formations of the superordinate means are described in the remaining dependent claims, and are described in more detail in the following description of embodiments with reference to the drawings.

  The drawings show the following.

It is sectional drawing of the application example in the form of a piston ring provided with the structure which cooperates with a cylinder liner, and bears a load, and the film for a running-in operation provided on the said structure. FIG. 5 is a partial view of a break-in coating with adjacent areas of wear-resistant structures. FIG. 4 is a partial view of a break-in coating that includes ceramic particles. FIG. 2 shows a coating device comprising two laser guns each having a supply device for the material forming the wear-resistant structure and a supply device for the material forming the break-in coating. FIG. 5 is a diagram showing a variation of FIG. 4 with one laser gun and a supply device having two paths.

  The present invention can be advantageously applied wherever a highly durable sliding kinematic pair requires a certain amount of break-in operation, for example, in a metallurgical industry, a milling industry, a food industry machine, an engine, or the like. Particularly preferred applications are large engines, in particular two-cycle large diesel engines, in particular piston rings that cooperate with cylinder liners and corresponding piston ring grooves.

  FIG. 1 schematically shows a part of a cylinder liner 1. A piston 2 that moves up and down is provided in the cylinder liner. The piston is provided with a piston ring groove 3 on the circumferential side, and a corresponding piston ring 4 is accommodated in the piston ring groove with the circumferential surface of the piston ring in contact with the inside of the cylinder liner 1. Has been. FIG. 1 shows only one piston ring groove 3 and one piston ring 4. The piston ring 4 is composed of a base member 5 made of cast steel, and a protective layer applied to the member facing the base member, that is, a region facing the cylinder liner 1 in this figure, on the base member 5 in this figure. As shown, the wear-resistant structure 6 is provided. Of course, it is also conceivable that the wear-resistant structure is already the base material of the base member. On the circumferential side of the wear-resistant structure 6, a break-in operation film 7 is provided to face the sliding surface of the cylinder liner 1.

  As can be seen from FIG. 2, the wear-resistant structure 6 consists of particles 9 made of a hard material contained in a matrix 8. The material may be a ceramic material such as tungsten carbide (WC) having a hardness of 3000 HV to 5000 HV. In order to form the matrix 8, a nickel alloy containing phosphorus (P) and / or silicon (Si) is preferably provided. Since these materials are not toxic, they can also be used in the food field. The nickel alloy contains 1 to 15 Vol%, preferably 3.65 Vol% P, 1 to 6 Vol%, preferably 2.15 Vol% Si, and the balance Ni. The volume fraction of the ceramic particles relative to the entire volume of the wear resistant structure 6 may be greater than 60%, preferably up to 85%. The included ceramic particles 9 preferably have a spherical shape with a diameter of 40 to 160 micrometers (μm). The thickness of the coating formed by the wear-resistant structure 6 can be adapted to the conditions of the individual case. The coating formed by the wear-resistant structure 6 in a piston ring of the kind shown in this figure can have a thickness of 0.2 to 2 mm.

  As can be seen from FIG. 2, the radial surface of the wear-resistant structure 6 is relatively rough and undulated before the break-in coating 7 is provided. That is, there is a raised portion 10, and there is a depression 11 between the raised portions, and this point adversely affects the running-in operation process. Therefore, the running-in coating 7 applied to the wear-resistant structure 6 has a problem that the surface roughness of the wear-resistant structure 6 is made uniform and the recess 11 is filled. Around the end of the running-in process, a surface with no protruding edges or corners, indicated by the broken line 12 in FIG. 2, is obtained. Since the dent 11 is filled, the hard particles 9 that are adjacent to the dent 11 in the lateral direction and protrude upward are also securely embedded in the material surrounding the particles, and thus need to be afraid of dropping off. Disappears. The running-in coating 7 eliminates the need for processing the wear-resistant structure 6. When the break-in coating 7 is manufactured, the surface 13 having a small roughness shown in FIG. 2 is obtained. The surface preferably has 1 to 20 Ra. The roughness allows the piston ring 4 to gas tightly contact the corresponding sliding surface of the cylinder liner 1. At this time, no further processing is required.

  The break-in coating 7 may be composed of any suitable break-in material that is slowly peeled off and disappears during the break-in phase. In large engines such as two-cycle large diesel engines such as those used in marine drive systems, the break-in phase ranges from 1000 to 2000 operating hours. For this purpose, the thickness of the break-in coating 7 is preferably 50 to 300 micrometers (μm). The break-in material used as the base material for the break-in coating 7 is much softer than the wear-resistant structure 6 below the material, and in any case is not harder than the wear-resistant structure. It should be slightly softer than the sliding surface of the cylinder liner 1 in this figure. The break-in coating 7 preferably has a hardness of 100 to 200 HV.

  Metals including copper (Cu) and / or tin (Sn) can be used to form the break-in coating 7. In experiments, good results were obtained when bronze as a Cu.Sn alloy having 70% Cu and 30% Sn was used. It is also conceivable to use a white alloy containing antimony (Sb) and / or zinc (Zn) in addition to copper and tin in a normal ratio in the white alloy. The melting point of such materials is in the range of 600 to 900 ° C., which facilitates the coating process. The lower limit of the melting point of the break-in coating 7 should not be less than 200 ° C.

In order to increase the running-in time, i.e., to increase the durability time of the running-in coating 7, hard particles 14 are embedded in the running-in coating as shown in FIG. The hard particles may suitably be ceramic particles having a diameter of up to 50 micrometers (μm), preferably having a spherical structure. As the ceramic material, Al ₂ O ₃ , CrO, Cr ₃ C ₂ or the like can be used. The proportion of hard particles 14 in the entire volume of the break-in coating 7 may be 5 to 30 Vol% depending on the desired endurance time of the break-in coating 7.

  The coating forming the running-in coating 7 is thus applied onto the wear-resistant structure 6, so that the metallurgical structure between the wear-resistant structure 6 and the running-in coating 7 in the boundary region. Bond occurs. The metallurgical bond appears in the form of a boundary layer 15 shown in FIG. 2 for the boundary region between the wear-resistant structure 6 and the break-in coating 7. The boundary layer is formed from the components of two adjacent layers. In FIG. 1, the boundary layer 15 is indicated only by a broken line. The boundary layer 15 can be formed by forming an alloy or by causing a diffusion process. When an alloy is formed, the break-in coating 7 is in contact with the wear-resistant structure 6 or the wear-resistant structure is in contact with the base member 5 and is eutectic bonded to cause a diffusion process. Are diffusion bonded. The same applies when the coating forming the wear-resistant structure 6 is bonded onto the base member 5. Again, a boundary layer formed as an alloy zone or a diffusion zone is formed, which boundary layer is only indicated by a broken line in FIG. During eutectic bonding, the thickness of the boundary layer 15 is relatively large, thereby ensuring a very good mutual bond. However, very fragile crystals are often formed in the boundary layer, thereby increasing the risk of brittle fracture. The risk of brittle fracture is avoided by forming the boundary layer as a diffusion layer. The diffusion layer only has a thickness that corresponds to the diffusion depth, whereby the volume fraction of fragile crystals is kept within narrow limits while ensuring good metallurgical bonding. Some energy is supplied during the coating process depending on the type of coating desired. During eutectic bonding, both the coating material and the upper region of the material below the coating material are melted, but only the coating material is melted during diffusion bonding. The material below the coating material is heated but remains solidified.

  Ceramic materials as carbides break at relatively high temperatures or change to other carbides with other geometric shapes. As long as the hard particles 9 of the wear-resistant structure 6 are formed by carbide, the break-in coating 7 is preferably applied to protect the carbide, so that the wear-resistant structure 6 is protected from the carbide. It is not heated above the dissociation temperature. The same applies naturally when the wear-resistant structure 6 is applied onto the base member 5. Preferably, the heat transfer to the surface to be coated and the coating material supplied to the surface that occurs to carry out the coating process takes place in a controlled manner, whereby only the coating material is completely melted and the coating The material below the material remains fully solidified, which is diffusion bonded according to the above description.

  The coating process may be performed by spraying the coating material, melting the coating material, or sintering the coating material.

The coating process may be performed by melting the coating material or sintering the coating material. In any case, only processes are envisaged which result in the bonding of the coating material to the substrate, in particular the bonding of the running-in coating 7 to the wear-resistant structure 6. The heat necessary to carry out such a process is supplied in the direction towards the respective substrate, ie towards the wear-resistant structure 6 or the base member.

  The coating and / or break-in coating 7 that forms the wear-resistant structure 6 can be eutectic bonded or diffusion bonded to the substrate provided for each as already described. In order to perform eutectic bonding, a melt is formed that forms a transition region, which contains both the components of the receiving layer and the components to be applied to the receiving layer. For this purpose, both the material to be applied and the area close to the surface of the substrate are heated, thereby causing a transition to the liquid layer. In order to perform diffusion bonding, only the material to be applied individually is transferred to the liquid layer.

The coating and / or break-in coating 7 that forms the wear-resistant structure 6 can be eutectic bonded or diffusion bonded to the substrate provided for each as already described. In order to perform eutectic bonding, a melt is formed that forms a transition region, which contains both the components of the receiving layer and the components to be applied to the receiving layer. For this purpose, both the material to be applied and the area close to the surface of the substrate are heated, thereby causing a transition to the liquid layer. In order to perform diffusion bonding, only the material to be applied individually is transferred to the liquid layer. The substrate is heated, thereby accelerating the diffusion process. Accordingly, in any case, heat is supplied in the direction of the wear-resistant structure so that at least the break-in material supplied at this time is melted.

  In the configuration shown in FIG. 4, two continuously provided energy sources are provided as two continuously provided laser guns 16 and 17, and the laser guns generate laser beams 16 a and 17 a, respectively. Instead of the laser gun, a PTA burner (plasma transfer arc burner) and / or a dielectric coil may be provided. A material supply device 18 or 19 is provided for the energy source or the energy transmission light beam, respectively, and the material supply device has supply ports 18a and 19a, and energy transfer light beams 18b and 19b shown as material transfer jets 18b and 19b. To produce a material supply.

  Individual coating materials can be supplied on the surface to be coated in the form of round or rounded lines, bands or powders. In the example shown in the figure, a powdered material should be processed. Correspondingly, the supply devices 18, 19 are supplied with the corresponding powdered material via the supply ports 18a, 19a, which discharge the material flow 18b or 19b that guides the powdered material. The powder is preferably conveyed by a protective gas that provides protection against oxidation.

  In the example shown in the figure, heating spots are generated on the substrate to be coated by energy transfer rays 16a, 17a, which are represented as laser beams, respectively. At this time, the material transfer jets 18b or 19b provided corresponding to each of them are oriented so that the coating material is supplied directly to the heating spot or to an area directly adjacent to the heating spot. Yes. If the coating material is oriented to be delivered directly to the heated spot, the delivered material will be exposed to the corresponding energy transfer beam, so that the delivered material will each correspond in the melted state. The substrate is heated by the remaining energy. As long as the boundary layer 15 formed of an alloy is desired, the energy source 16 or 17 is adjusted as follows. That is, the energy supplied is sufficient to melt both the coating material and the area close to the underlying surface. When the boundary layer 15 is to be formed only as a diffusion layer, the energy source 16 or 17 is adjusted as follows. That is, only the coating material is completely melted and the corresponding respective substrate remains in a solid state. If a laser gun is used at this time, energy supply can be accurately controlled by a simple method.

  In FIG. 4, energy sources 16 and 17 each having a corresponding material transfer device 18 and 19 are continuously provided with a distance. The distance is such that the wear-resistant structure 6 is already completely solidified before the break-in coating 7 is applied, or when the break-in coating 7 is applied. Is selected such that at least the upper side of the structure 6 is not yet solidified.

  This embodiment having a wear-resistant structure 6 made of a nickel alloy embedded with ceramic particles, applied to a base member 5 containing iron, and a break-in coating 7 formed of bronze containing copper and tin In the example, both the wear-resistant structure 6 and the break-in run coat 7 are bonded to their respective substrates by diffusion. The distance between the energy generators 16, 17 is therefore selected such that the first wear-resistant structure 6 is already completely solidified before the break-in coating 7 is applied. Is done. As already mentioned, the energy transfer is controlled such that only the respective material to be applied is melted and the respective substrate remains solidified.

  In FIG. 4, a third energy transmission light beam 20 that is placed after the second energy transmission light beam 17a is implied. The post-energy transfer light beam 20 is used to smooth the surface of the break-in coating 7 and to transmit enough energy to be suitable for the break-in operation process. Instead of using a unique energy transfer beam 20 provided for smoothing, after coating, the energy transfer beam 16a and / or 17a is used for smoothing without supplying the corresponding material. Is also possible.

  In the example shown in the figure, the energy sources 16 and 17, the material supply devices 18 and 19 disposed in the energy source, and the energy source that generates the energy transmission light beam 20 that is placed behind the material supply device are , Provided in a fixed manner. Accordingly, the base member 5 is moved according to the arrow v in order to produce the desired coating. However, it is also conceivable to move the coating apparatus with the base member 5 fixedly installed. At this time, all the energy generating devices can be integrated with a material supply device arranged in some cases into a coating head which forms a group of members that can be moved uniformly.

  In the configuration shown in FIG. 5, only the energy source 21 is provided as a laser gun, and the laser gun generates an energy transmission light beam 21a. The energy transfer beam is supplied with two material jets to form a first coating that forms a wear-resistant structure 6 and a second coating that forms a break-in coating 7. For this purpose, two material supply devices may be provided, but in the example shown in the figure, only the material supply device 22 is provided, and the material supply device is formed to have two flows. Accordingly, the material supply device 22 is provided with two material supply ports 22a or 22a ′ for the material forming the wear-resistant structure 6 or the material forming the break-in operation film 7. The material supply device 22 also has two material transfer jets 22b, 22b ′, which are respectively placed downstream in the coating direction, for the material forming the wear-resistant structure 6 or the material forming the break-in coating 7. generate.

  The material transfer jets 22b and 22b ′ are arranged as follows. That is, first, the material transfer jet 22b that forms the wear-resistant structure 6 hits the surface of the base member 5 that is not yet coated, and then the material transfer jet 22b ′ that forms the break-in coating 7 is the material transfer jet. It is arranged so as to hit the upper side of the wear-resistant structure 6 already made using 22b. In this case, since the distance between the jets 22b and 22b 'is very small, the layer that forms the wear-resistant structure 6 already applied is the material applied to form the break-in coating 7. Can still release enough energy to melt.

  In order to create a suitable surface that is superior for the purpose of break-in operation, a delayed-acting energy transfer beam 20 can be used, similar to the configuration shown in FIG. The same applies to the configuration method as a unified member group or the movement of the base member 5 or the coating head.

DESCRIPTION OF SYMBOLS 1 Cylinder liner 2 Piston 3 Piston ring groove 4 Piston ring 5 Base member 6 Abrasion-resistant structure 7 Film for running-in operation 8 Metal matrix 9 Particle 10 Raised portion 11 Depression 12 Broken line 13 Surface 14 Particle 15 Boundary layer 16 Energy source ( Laser gun, energy generator, heating device)
16a Energy transmission beam (laser beam)
17 Energy source (laser gun, energy generator, heating device)
17a Energy transmission beam (laser beam)
18 Material supply device (material transfer device)
18a supply port 18b material transfer jet 19 material supply device (material transfer device)
19a Supply port 19b Material transfer jet 20 Energy transfer beam 21 Energy source 21a Energy transfer beam 22 Material supply device 22a Material supply port 22a 'Material supply port 22b Material transfer jet 22b' Material transfer jet

Claims (38)

A mechanical member belonging to a sliding pair having two mechanical members movable with respect to each other of a large diesel engine , wherein the mechanical member is at least in the region of the surface facing the other mechanical member in the metal matrix (8 ) Having a wear-resistant structure (6) comprising particles (9) made of a material harder than the metal matrix (8) and a rough and rough surface, and a piston ring (4 ) Or a cylinder liner (1) or a piston (2) having at least one piston ring groove (3), or a mechanical member formed as a sliding member of a large diesel engine ,
The wear resistant structure (6) is coated with a break-in coating (7) that equalizes the roughness and roughness of the top of the structure, and the break-in coating is applied during the break-in operation step. A break-in material suitable for wear, the break-in material being different from the material of the wear-resistant structure (6) below the break-in material and the wear-resistant structure The material for the break-in operation is softer than the wear-resistant structure (6) and is at most equivalent to the sliding surfaces of the individual opposing mechanical members. The boundary layer between the break-in coating (7) and the wear-resistant structure (6) is provided by the supply of heat to the wear-resistant structure (6). It is formed as a resulting alloy zone or diffusion zone Machine member.   The machine member according to claim 1, wherein the break-in coating (7) has a hardness of 100 to 200 HV.   3. A machine part according to claim 1 or 2, characterized in that the material forming the break-in coating (7) has a melting temperature of at most 1050 ° C.   The machine member according to claim 3, characterized in that the material forming the break-in coating (7) has a melting temperature of 600 ° C to 800 ° C.   Machine according to any one of the preceding claims, characterized in that the break-in coating (7) has a new state and an average thickness of 50 to 300 micrometers (µm). Element.   6. Mechanical member according to any one of the preceding claims, characterized in that the break-in coating (7) has a surface roughness of 1 to 20 Ra in a new state. 7. The break-in operation material of the break-in operation coating (7) includes particles (14) made of a material harder than the operation coating (7). A machine member according to claim 1.   8. Mechanical member according to claim 7, characterized in that the contained particles (14) consist of a ceramic material. Machine member according to claim 8 wherein the inclusion has been that particles (14), characterized in that it consists of _Al 2 _{O 3} and / or CrO and / or _Cr 3 _{C 2.}   Machine according to any one of claims 7 to 9, characterized in that the proportion of particles (14) contained is 5 to 30 Vol% of the total volume of the break-in coating (7). Element.   The machine member according to any one of claims 1 to 10, wherein the break-in operation material used as a base material for the break-in operation film (7) includes at least copper and / or tin.   12. The mechanical member according to claim 11, wherein the break-in material for the break-in operation film (7) is formed as a bronze having 70% Cu and 30% Sn. .   12. The machine member according to claim 11, wherein the break-in operation material of the break-in operation film is formed of a white alloy containing antimony (Sb) in addition to copper and tin.   The wear-resistant structure (6) that receives the break-in coating (7) includes a nickel alloy as a matrix (8), and the matrix includes particles (9) made of a ceramic material. The mechanical member according to any one of claims 1 to 13, wherein the mechanical member is characterized in that: The wear resistance of the structure for receiving the running-in for coating (7) (6) of claim 1, characterized in that it is formed as a coating of the base member (5) comprising metallic or al 14 The machine member according to any one of the above. The mechanical member according to claim 15, wherein the metal is iron. 17. A machine according to claim 14, 15 or 16 , characterized in that the nickel alloy forming the matrix (8) contains 1 to 15 Vol% P, 1 to 6 Vol% Si and the balance Ni. Element. 18. The mechanical member according to claim 17 , wherein the nickel alloy forming the matrix (8) contains 3.65 Vol% P, 2.15 Vol% Si, and the balance Ni. 18. The volume fraction of the ceramic particles (9) with respect to the entire volume of the wear-resistant structure that receives the break-in operation coating is greater than 60 Vol% and not greater than 85 Vol%. The machine member according to any one of the above. Any of the wear resistance of the structure (6) wherein the ceramic particles (9) are at least partially made of tungsten carbide (WC), claims 1 to 19, characterized in that it has a hardness of 5000HV from 3000 The machine member according to one item. Mechanical component according to claim 1, any one of 20 pre-xenon ceramic particles (9) which is a spherical the wear resistance of the structure (6). 22. A mechanical component according to claim 21, wherein the ceramic particles (9) have a diameter of 40 to 160 micrometers ([mu] m). Mechanical components according to any one of claims 7 22, characterized in that the running-in for coating before being included in (7) xenon ceramic particles (14) is spherical. 24. Mechanical member according to claim 23, characterized in that the ceramic particles (14) have a diameter of 20 to 50 micrometers ([mu] m).   The mechanical member according to claim 1, wherein the mechanical member belongs to a slip pair of a two-cycle large diesel engine. 26. Mechanical member according to claim 25 , characterized in that it is formed as a piston ring (4). 26. Mechanical member according to claim 25 , characterized in that it is formed as a cylinder liner (1). 26. Mechanical member according to claim 25 , characterized in that it is formed as a piston (2) having at least one piston ring groove (3). The mechanical member having the wear-resistant structure (6) is coated with a running-in coating (7) covering the wear-resistant structure (6), and the wear-resistant structure (6) is applied during the coating process. ) energy toward supplied to it the run-in coatings for by (7) of any of claims 1 to 28, characterized in that the metallurgically bonded to the wear resistance of the structure (6) A method for manufacturing the mechanical member according to claim 1. 30. Method according to claim 29 , characterized in that the break-in coating (7) is eutectic bonded to the wear-resistant structure (6). The break-in operation film (7) is diffusion bonded to the wear-resistant structure (6), and only the break-in operation material used as a base material for the break-in operation film (7) during the coating process. there were thawed, according to claim 30 the material of the wear resistance of the structure at the bottom of the running-in material (6), characterized in that the energy to remain in the solidified state is supplied Method. Material any one of 31 claims 29, characterized in that it is applied as a solid powder to the wear resistance of the structure (6) during the coating step of forming the running-in for the film (7) The method described in 1. 32. Method according to any one of claims 29 to 31 , characterized in that the break-in coating (7) is melt-plated to the wear-resistant structure (6). In order to coat the wear-resistant structure (6) with the break-in operation film (7), the wear-resistant structure (6) can be moved relative to the wear-resistant structure (6) and the wear-resistant structure. A heating device (17; 21) for generating a heating spot in the structure (6) is used, and the material for forming the break-in coating film (7) is the heating spot or a region directly adjacent to the heating spot. 34. A method according to any one of claims 29 to 33 , characterized in that 35. The method of claim 34 , wherein a laser gun or PTA burner is used to generate the heated spot. 36. A method according to claim 34 or 35 , wherein the material forming the break-in coating (7) is supplied to the heated spot as a powder, wire or strip. In the wear-resistant structure (6) formed as a coating of the base member (5), the wear-resistant structure and the break-in operation coating (7) received in the wear-resistant structure 37. A method according to any one of claims 29 to 36 , characterized in that each is applied to the corresponding substrate in the same way. 38. A method according to claim 37 , characterized in that the wear-resistant structure (6) and the break-in coating (7) are produced in one work step.

Images