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JP4497952B2 - Multilayer wiring board - Google Patents

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JP4497952B2
JP4497952B2 JP2004047012A JP2004047012A JP4497952B2 JP 4497952 B2 JP4497952 B2 JP 4497952B2 JP 2004047012 A JP2004047012 A JP 2004047012A JP 2004047012 A JP2004047012 A JP 2004047012A JP 4497952 B2 JP4497952 B2 JP 4497952B2
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copper foil
bump
layer
wiring board
diameter
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JP2005236231A (en
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貴史 尾山
克己 見山
勝 小笠原
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クローバー電子工業株式会社
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732Location after the connecting process
    • H01L2224/73251Location after the connecting process on different surfaces
    • H01L2224/73265Layer and wire connectors

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  • Production Of Multi-Layered Print Wiring Board (AREA)
  • Printing Elements For Providing Electric Connections Between Printed Circuits (AREA)
  • Manufacturing Of Printed Wiring (AREA)

Description

本発明は、積層配線基板に関するものである。   The present invention relates to a laminated wiring board.

従来、表面に第1の配線パターンを備えるコア基板上に、プリプレグ等の合成樹脂系シートからなる絶縁体層を介して銅箔等の導電体層を積層し、該導電体層をエッチングすることにより第2の配線パターンを形成した積層配線基板が知られている。前記積層基板では、第1、第2の両配線パターンは層間接続部材により電気的に接続されている。   Conventionally, a conductor layer such as a copper foil is laminated on a core substrate having a first wiring pattern on the surface via an insulator layer made of a synthetic resin-based sheet such as a prepreg, and the conductor layer is etched. A multilayer wiring board having a second wiring pattern formed thereon is known. In the laminated substrate, both the first and second wiring patterns are electrically connected by an interlayer connection member.

また、前記積層基板において、前記導電体層の所定の位置にバンプを形成しておき、該バンプを前記プリプレグ等の絶縁体層に貫通させた後、該バンプの先端を前記コア基板表面の第1の配線パターンに圧着させて、前記層間接続部材としたものが知られている(例えば特許文献1参照)。   In the laminated substrate, a bump is formed at a predetermined position of the conductor layer, and the bump is passed through an insulating layer such as the prepreg. There is known one that is crimped to one wiring pattern to form the interlayer connection member (see, for example, Patent Document 1).

前記バンプは、例えば、前記銅箔上に所定の位置に貫通孔を備えるメタルマスクを積層し、該メタルマスクを介して銀ペースト、銅ペースト等の導電性ペーストをスクリーン印刷して該貫通孔に導電性ペーストを充填した後、該導電性ペーストを乾燥させることにより形成される。前記バンプは、例えば、直径0.20mm、高さ180μmの円錐形状に形成される。   The bump is formed, for example, by laminating a metal mask having a through hole at a predetermined position on the copper foil, and screen printing a conductive paste such as a silver paste or a copper paste through the metal mask. After the conductive paste is filled, the conductive paste is dried. The bump is formed in a conical shape having a diameter of 0.20 mm and a height of 180 μm, for example.

また、前記銅箔は、例えば、厚さ18μmの電解銅箔の表面に、平均粒子径2μmの銅の一次粒子が付着せしめられて平均粒子径20μmの二次粒子を形成している粗化面と、該粗化面を被覆する平均0.30mg/dm2の亜鉛からなる防錆層とを備えるものが用いられる。前記粗化面を備える銅箔は、例えば、前記銅箔の一方の表面を硫酸と硫酸銅とからなる電解液中で交流電解処理した後、陰極電解処理または陰極パルス電解処理して前記銅の一次粒子を付着させることにより形成することができる(例えば特許文献2参照)。 The copper foil is a roughened surface in which, for example, primary particles of copper having an average particle diameter of 2 μm are adhered to the surface of an electrolytic copper foil having a thickness of 18 μm to form secondary particles having an average particle diameter of 20 μm. And a rust preventive layer made of zinc having an average of 0.30 mg / dm 2 covering the roughened surface. The copper foil provided with the roughened surface is, for example, subjected to AC electrolytic treatment on one surface of the copper foil in an electrolytic solution composed of sulfuric acid and copper sulfate, and then subjected to cathodic electrolysis treatment or cathodic pulse electrolysis treatment. It can be formed by adhering primary particles (see, for example, Patent Document 2).

前記銅箔上に前述のようにして形成されるバンプは、該銅箔との間の電気抵抗が平均10mΩとなっている。   The bumps formed on the copper foil as described above have an average electrical resistance of 10 mΩ with the copper foil.

一方、積層配線基板では、電子部品の進歩と共に配線密度を高くする必要があり、配線の幅、間隔、ランド径を小さくすることが行われている。これに伴って、前記バンプもまた直径を小さくすることが望まれる。   On the other hand, in the multilayer wiring board, it is necessary to increase the wiring density with the progress of electronic components, and the width, interval, and land diameter of the wiring are reduced. Accordingly, it is desirable that the bumps also have a small diameter.

しかしながら、前記銅箔上に前記バンプを形成するときに、バンプ径を200μm未満、例えば150μmとすると、該バンプと銅箔との間の電気抵抗が大きくなって発熱し、伝送損失、伝送ノイズが大きくなるという不都合がある。
特開平11−195871号公報 特開平6−350248号公報
However, when the bump is formed on the copper foil, if the bump diameter is less than 200 μm, for example, 150 μm, the electrical resistance between the bump and the copper foil is increased and heat is generated, and transmission loss and transmission noise are reduced. There is an inconvenience of becoming larger.
JP-A-11-195871 JP-A-6-350248

本発明は、かかる不都合を解消して、伝送損失、伝送ノイズを低減することができる積層配線基板を提供することを目的とする。   An object of the present invention is to provide a multilayer wiring board capable of eliminating such disadvantages and reducing transmission loss and transmission noise.

かかる目的を達成するために、本発明は、基板上に形成された第1の配線パターンと、第1の配線パターン上に積層された合成樹脂系シートからなる絶縁体層と、該絶縁体層上に積層された銅箔をエッチングすることにより形成された第2の配線パターンと、該銅箔上の所定の位置に形成されたバンプを該絶縁体層に貫通せしめて両配線パターンを接続する層間接続部材とを備える積層配線基板において、該銅箔は表面に平均粒子径0.5〜1.5μmの銅の一次粒子が付着せしめられて平均粒子径5〜15μmの二次粒子を形成している粗化面と、該粗化面を被覆する0.01〜0.20mg/dm2の亜鉛からなる防錆層とを備え、該バンプは0.20mm未満の直径を備えることを特徴とする。 In order to achieve such an object, the present invention provides a first wiring pattern formed on a substrate, an insulating layer made of a synthetic resin-based sheet laminated on the first wiring pattern, and the insulating layer. The second wiring pattern formed by etching the copper foil laminated thereon and the bump formed at a predetermined position on the copper foil are penetrated through the insulator layer to connect the two wiring patterns. In a multilayer wiring board provided with an interlayer connection member, the copper foil has secondary particles having an average particle diameter of 5 to 15 μm formed by adhering primary particles of copper having an average particle diameter of 0.5 to 1.5 μm to the surface. And a rust preventive layer made of 0.01 to 0.20 mg / dm 2 of zinc covering the roughened surface, and the bump has a diameter of less than 0.20 mm. To do.

本発明の積層配線基板では、前記銅箔に付着せしめる銅の一次粒子の平均粒子径を0.5〜1.5μmの範囲としたので、該一次粒子が凝集して形成される二次粒子の平均粒子径が5〜15μmの範囲となり、従来の銅箔の粗化面よりも細かい二次粒子を備える粗化面が得られる。従って、前記粗化面とバンプの底面との接触面積が大きくなる。   In the multilayer wiring board of the present invention, since the average particle diameter of the primary particles of copper adhered to the copper foil is in the range of 0.5 to 1.5 μm, the secondary particles formed by aggregation of the primary particles An average particle diameter becomes the range of 5-15 micrometers, and the roughening surface provided with a secondary particle finer than the roughening surface of the conventional copper foil is obtained. Accordingly, the contact area between the roughened surface and the bottom surface of the bump is increased.

また、本発明の積層配線基板では、前記粗化面上に形成される防錆層の亜鉛の量が0.01〜0.20mg/dm2の範囲とされ、従来の銅箔の防錆層よりも低減されている。従って、銅よりも電気抵抗値の大きい亜鉛による電気抵抗の増加が抑制される。 In the multilayer wiring board of the present invention, the amount of zinc in the rust prevention layer formed on the roughened surface is in the range of 0.01 to 0.20 mg / dm 2 , and the conventional rust prevention layer of copper foil is used. Has been reduced. Therefore, an increase in electrical resistance due to zinc having a larger electrical resistance value than copper is suppressed.

この結果、前記銅箔上に、0.20mm未満、好ましくは0.15mm以下の直径を備えるバンプを形成した場合にも、該銅箔の粗化面と該バンプの底面との接触面積が大きくなり、しかも該粗化面上に形成されている防錆層の電気抵抗が小さくなる。従って、本発明の積層配線基板によれば、該銅箔と該バンプとの電気抵抗を低減して発熱を低減することができ、伝送損失、伝送ノイズを低減することができる。   As a result, even when a bump having a diameter of less than 0.20 mm, preferably 0.15 mm or less is formed on the copper foil, the contact area between the roughened surface of the copper foil and the bottom surface of the bump is large. In addition, the electric resistance of the rust preventive layer formed on the roughened surface is reduced. Therefore, according to the multilayer wiring board of the present invention, the heat resistance can be reduced by reducing the electrical resistance between the copper foil and the bump, and transmission loss and transmission noise can be reduced.

前記銅の一次粒子の平均粒子径は、0.5μm未満とすることは技術的に難しく、1.5μmを超えると二次粒子の径が大きくなりやすい。また、前記二次粒子の平均粒子径は、5μm未満とすることは技術的に難しく、15μmを超えると、前記粗化面と前記バンプの底面との接触面積を大きくして電気抵抗を低減する効果が得られない。   It is technically difficult to make the average particle diameter of the copper primary particles less than 0.5 μm, and when it exceeds 1.5 μm, the diameter of the secondary particles tends to be large. Further, it is technically difficult to make the average particle diameter of the secondary particles less than 5 μm, and when it exceeds 15 μm, the contact area between the roughened surface and the bottom surface of the bump is increased to reduce the electric resistance. The effect is not obtained.

また、前記銅箔は、前記防錆層上に島状に形成されたシランカップリング剤層を備えることが好ましい。前記銅箔は、前記シランカップリング層を備えることにより、前記絶縁体層を形成する合成樹脂系シートに対する密着性を向上させることができる。尚、前記シランカップリング剤層自体は絶縁体であるが、前記防錆層上に島状に形成されているので、前記銅箔と前記バンプとの電気抵抗を増大させることはない。   Moreover, it is preferable that the said copper foil is equipped with the silane coupling agent layer formed in the island shape on the said antirust layer. The said copper foil can improve the adhesiveness with respect to the synthetic resin type | system | group sheet | seat which forms the said insulator layer by providing the said silane coupling layer. In addition, although the said silane coupling agent layer itself is an insulator, since it is formed in island shape on the said rust preventive layer, the electrical resistance of the said copper foil and the said bump is not increased.

次に、添付の図面を参照しながら本発明の実施の形態についてさらに詳しく説明する。図1は本実施形態の積層配線基板の構成を示す説明的断面図である。   Next, embodiments of the present invention will be described in more detail with reference to the accompanying drawings. FIG. 1 is an explanatory cross-sectional view showing the configuration of the multilayer wiring board of the present embodiment.

図1(a)に示すように、本実施形態の積層配線基板1は、コア基板2上に形成された第1の配線パターン3と、配線パターン3上に積層されたプリプレグ等の合成樹脂製シートからなる絶縁体層4と、絶縁体層4上に形成された第2の配線パターン5とを備えている。そして、配線パターン3,5はバンプ6を層間接続部材として互いに電気的に接続されている。   As shown in FIG. 1A, the laminated wiring board 1 of the present embodiment is made of a first wiring pattern 3 formed on the core substrate 2 and a synthetic resin such as a prepreg laminated on the wiring pattern 3. An insulating layer 4 made of a sheet and a second wiring pattern 5 formed on the insulating layer 4 are provided. The wiring patterns 3 and 5 are electrically connected to each other using the bump 6 as an interlayer connection member.

積層配線基板1は、図1(b)に示すように銅箔7上の所定の位置にバンプ6を形成した後、バンプ6を絶縁体層4に貫通させ、さらに図1(c)に示すようにバンプ6の先端を配線パターン3に圧着させ加熱プレスして、基板2、絶縁体層4、銅箔7を一体化することにより形成される。尚、配線パターン5は、前述のようにして、基板2、絶縁体層4、銅箔7を一体化した後、銅箔7をそれ自体公知の方法によりエッチングすることにより形成することができる。   In the multilayer wiring board 1, bumps 6 are formed at predetermined positions on the copper foil 7 as shown in FIG. 1B, and then the bumps 6 are penetrated through the insulator layer 4, and further, as shown in FIG. In this way, the tip of the bump 6 is crimped to the wiring pattern 3 and heated and pressed to integrate the substrate 2, the insulator layer 4 and the copper foil 7. The wiring pattern 5 can be formed by integrating the substrate 2, the insulator layer 4, and the copper foil 7 as described above, and then etching the copper foil 7 by a method known per se.

バンプ6は、直径0.20mm未満、好ましくは0.15mm以下、高さ150μmの円錐形状を備えている。また、銅箔7は、例えば厚さ9〜35μmの電解銅箔であり、製箔機の表面形状が転写された最大高さ約1μmの凹凸を備える表面に、平均粒子径0.5〜1.5μm、例えば平均粒子径1μmの銅の一次粒子が付着せしめられ、該一次粒子が凝集して形成された平均粒子径5〜15μm、例えば平均粒子径10μmの二次粒子からなる粗化面が備えられている。前記粗化面の上には0.01〜0.20mg/dm2、例えば0.10mg/dm2の亜鉛からなる防錆層が形成されており、該防錆層の上にさらに島状のシランカップリング剤層が形成されている。前記防錆層は1〜100nmの範囲の厚さを備えており、前記シランカップリング剤層は1〜10nmの範囲の厚さを備えている。 The bump 6 has a conical shape with a diameter of less than 0.20 mm, preferably 0.15 mm or less, and a height of 150 μm. Further, the copper foil 7 is, for example, an electrolytic copper foil having a thickness of 9 to 35 μm, and an average particle diameter of 0.5 to 1 is provided on the surface having irregularities with a maximum height of about 1 μm onto which the surface shape of the foil making machine is transferred. A roughened surface composed of secondary particles having an average particle diameter of 5 to 15 μm, for example, an average particle diameter of 10 μm, formed by adhering primary particles of copper having an average particle diameter of 5 μm, for example 1 μm, and agglomerating the primary particles. Is provided. On the roughened surface, a rust preventive layer made of 0.01 to 0.20 mg / dm 2 , for example, 0.10 mg / dm 2 of zinc is formed, and an island-like layer is further formed on the rust preventive layer. A silane coupling agent layer is formed. The rust preventive layer has a thickness in the range of 1 to 100 nm, and the silane coupling agent layer has a thickness in the range of 1 to 10 nm.

前記シランカップリング剤としては、一方の端部にアミノ基、ビニル基、エポキシ基等の有機物と反応できる基を備え、他方の端部に−Si(OR)3(ただし、ORはメトキシ基、エトキシ基等のアルコキシ基)の化学式で表される基を備える化合物である。−Si(OR)3基は加水分解によりシラノール基(−SiOH)を生成することができる。銅箔7は、前記シランカップリング剤からなるシランカップリング剤層を備えることにより、前述のようにして基板2、絶縁体層4と一体化したときに、絶縁体層4との密着性を向上させることができる。 The silane coupling agent includes a group capable of reacting with an organic substance such as an amino group, a vinyl group, or an epoxy group at one end, and -Si (OR) 3 (wherein OR is a methoxy group, It is a compound having a group represented by a chemical formula of an alkoxy group such as an ethoxy group. The —Si (OR) 3 group can generate a silanol group (—SiOH) by hydrolysis. The copper foil 7 is provided with a silane coupling agent layer made of the silane coupling agent, so that when the copper foil 7 is integrated with the substrate 2 and the insulator layer 4 as described above, the adhesion with the insulator layer 4 is improved. Can be improved.

このような銅箔7として、例えば、古河サーキットフォイル株式会社製FCN−MPL箔(商品名)等を用いることができる。   As such a copper foil 7, for example, an FCN-MPL foil (trade name) manufactured by Furukawa Circuit Foil Co., Ltd. can be used.

バンプ6は、銅箔7の上に、所定位置に貫通孔を備えるメタルマスクを積層し、該メタルマスクを介して導電性ペーストをスクリーン印刷した後、該貫通孔に充填された導電性ペーストを乾燥することにより形成される。前記導電性ペーストは、銀、金、銅、半田、ニッケル、カーボン等の導電性粉末または繊維状のフィラーと、バインダー成分と、溶剤とを混合したもの等を用いることができる。   The bump 6 is formed by laminating a metal mask having a through hole at a predetermined position on the copper foil 7, screen-printing a conductive paste through the metal mask, and then applying the conductive paste filled in the through hole. It is formed by drying. As the conductive paste, a mixture of conductive powder such as silver, gold, copper, solder, nickel, carbon or a fibrous filler, a binder component, and a solvent can be used.

本実施形態の積層配線基板1では、バンプ6と銅箔7との間の電気抵抗を電気抵抗を低減して発熱を低減することができるので、伝送損失、伝送ノイズを低減することができる。   In the multilayer wiring board 1 of the present embodiment, the electrical resistance between the bumps 6 and the copper foil 7 can be reduced by reducing the electrical resistance, so that transmission loss and transmission noise can be reduced.

次に、本発明の実施例及び比較例を示す。   Next, examples and comparative examples of the present invention are shown.

本実施例では、表面に平均粒子径1μmの銅の一次粒子が付着せしめられて形成された平均粒子径10μmの二次粒子からなる粗化面と、該粗化面の上に形成された0.10mg/dm2の亜鉛からなる防錆層と、該防錆層の上に形成された島状のシランカップリング剤層とを備える厚さ18μmの銅箔A(古河サーキットフォイル株式会社製FCN−MPL箔(商品名))を用い、該銅箔A上に銀ペーストからなる直径0.15mmのバンプを形成した。前記バンプと前記銅箔Aとの間の電気抵抗を測定したところ、平均10mΩであった。結果を表1に示す。
〔比較例1〕
本比較例では、表面に平均粒子径2μmの銅の一次粒子が付着せしめられて形成された平均粒子径20μmの二次粒子からなる粗化面と、該粗化面の上に形成された0.30mg/dm2の亜鉛からなる防錆層と、該防錆層の上に形成された島状のシランカップリング剤層とを備える厚さ18μmの銅箔B(古河サーキットフォイル株式会社製TCN箔(商品名))を用い、該銅箔B上に銀ペーストからなる直径0.15mmのバンプを形成した。前記バンプと前記銅箔Bとの間の電気抵抗を測定したところ、平均20mΩであった。結果を表1に示す。
〔比較例2〕
本比較例では、直径を0.20mmとした以外は比較例1と全く同一にして前記銅箔B上に銀ペーストからなるバンプを形成した。前記バンプと前記銅箔Bとの間の電気抵抗を測定したところ、平均10mΩであった。結果を表1に示す。
In this example, a roughened surface composed of secondary particles having an average particle diameter of 10 μm formed by adhering primary particles of copper having an average particle diameter of 1 μm to the surface, and 0 formed on the roughened surface. 18 μm thick copper foil A (FCN manufactured by Furukawa Circuit Foil Co., Ltd.) comprising a rust prevention layer made of 10 mg / dm 2 of zinc and an island-shaped silane coupling agent layer formed on the rust prevention layer -MPL foil (trade name)) was used, and a 0.15 mm diameter bump made of a silver paste was formed on the copper foil A. When the electrical resistance between the bump and the copper foil A was measured, it was 10 mΩ on average. The results are shown in Table 1.
[Comparative Example 1]
In this comparative example, a roughened surface composed of secondary particles having an average particle diameter of 20 μm formed by adhering primary particles of copper having an average particle diameter of 2 μm to the surface, and 0 formed on the roughened surface. .18 μm thick copper foil B (TCN manufactured by Furukawa Circuit Foil Co., Ltd.) comprising a rust-proof layer made of 30 mg / dm 2 zinc and an island-shaped silane coupling agent layer formed on the rust-proof layer Using a foil (trade name), a bump having a diameter of 0.15 mm made of a silver paste was formed on the copper foil B. When the electrical resistance between the bump and the copper foil B was measured, the average was 20 mΩ. The results are shown in Table 1.
[Comparative Example 2]
In this comparative example, a bump made of a silver paste was formed on the copper foil B in exactly the same manner as in Comparative Example 1 except that the diameter was 0.20 mm. When the electrical resistance between the bump and the copper foil B was measured, it was 10 mΩ on average. The results are shown in Table 1.

Figure 0004497952
表1から、前記銅箔A上に直径0.15μmのバンプを形成する(実施例)ことにより、前記銅箔B上に同径のバンプを形成する場合(比較例1)よりも電気抵抗が小さくなることが明らかである。また、前記銅箔A上に直径0.15μmのバンプを形成する場合(実施例)には、前記銅箔B上に直径0.20mmのバンプを形成する場合(比較例2)と同等の電気抵抗が得られることが明らかである。
Figure 0004497952
From Table 1, by forming bumps with a diameter of 0.15 μm on the copper foil A (Example), the electrical resistance is higher than when forming bumps with the same diameter on the copper foil B (Comparative Example 1). Obviously, it becomes smaller. Further, when a bump having a diameter of 0.15 μm is formed on the copper foil A (Example), the same electrical property as that when a bump having a diameter of 0.20 mm is formed on the copper foil B (Comparative Example 2). It is clear that resistance is obtained.

本発明の積層配線基板の構成を示す説明的断面図。BRIEF DESCRIPTION OF THE DRAWINGS FIG.

符号の説明Explanation of symbols

1…積層配線基板、 2…基板、 3…第1の配線パターン、 4…絶縁体層、 5…第2の配線パターン、 6…バンプ、 7…銅箔。   DESCRIPTION OF SYMBOLS 1 ... Laminated wiring board, 2 ... Board | substrate, 3 ... 1st wiring pattern, 4 ... Insulator layer, 5 ... 2nd wiring pattern, 6 ... Bump, 7 ... Copper foil.

Claims (3)

基板上に形成された第1の配線パターンと、第1の配線パターン上に積層された合成樹脂系シートからなる絶縁体層と、該絶縁体層上に積層された銅箔をエッチングすることにより形成された第2の配線パターンと、該銅箔上の所定の位置に形成されたバンプを該絶縁体層に貫通せしめて両配線パターンを接続する層間接続部材とを備える積層配線基板において、
該銅箔は表面に平均粒子径0.5〜1.5μmの銅の一次粒子が付着せしめられて平均粒子径5〜15μmの二次粒子を形成している粗化面と、該粗化面を被覆する0.01〜0.20mg/dm2の亜鉛からなる防錆層とを備え、
該バンプは0.20mm未満の直径を備えることを特徴とする積層配線基板。
By etching a first wiring pattern formed on the substrate, an insulator layer made of a synthetic resin sheet laminated on the first wiring pattern, and a copper foil laminated on the insulator layer In a multilayer wiring board comprising: the formed second wiring pattern; and an interlayer connection member that connects the wiring patterns by penetrating bumps formed at predetermined positions on the copper foil through the insulator layer,
The copper foil has a roughened surface on which copper primary particles having an average particle diameter of 0.5 to 1.5 μm are adhered to form secondary particles having an average particle diameter of 5 to 15 μm, and the roughened surface. And 0.01 to 0.20 mg / dm 2 of a rust-preventing layer comprising zinc,
The bump is provided with a diameter of less than 0.20 mm.
前記バンプは0.15mm以下の直径を備えることを特徴とする請求項1記載の積層配線基板。   The laminated wiring board according to claim 1, wherein the bump has a diameter of 0.15 mm or less. 前記銅箔は、前記防錆層上に島状に形成されたシランカップリング剤層を備えることを特徴とする請求項1または請求項2記載の積層配線基板。   The multilayer wiring board according to claim 1, wherein the copper foil includes a silane coupling agent layer formed in an island shape on the rust prevention layer.
JP2004047012A 2004-02-23 2004-02-23 Multilayer wiring board Expired - Fee Related JP4497952B2 (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06350248A (en) * 1993-06-14 1994-12-22 Furukawa Saakitsuto Foil Kk Surface treatment method of copper foil for printed wiring board
JPH07231152A (en) * 1993-12-24 1995-08-29 Mitsui Mining & Smelting Co Ltd Copper foil for printed circuit inner layer and its manufacture
JPH08125331A (en) * 1994-10-19 1996-05-17 Toshiba Corp Manufacture of printed circuit board
JPH08158100A (en) * 1994-10-06 1996-06-18 Furukawa Circuit Foil Kk Roughening of copper foil surface
JPH1079579A (en) * 1996-09-05 1998-03-24 Toshiba Corp Printed circuit board and manufacturing method of printed circuit board
JPH11135947A (en) * 1997-10-28 1999-05-21 Matsushita Electric Works Ltd Printed wiring board and manufacture thereof
JPH11340596A (en) * 1998-05-21 1999-12-10 Furukawa Electric Co Ltd:The Copper foil for printed circuit board and copper foil attached with resin
JP2004006829A (en) * 2002-04-25 2004-01-08 Matsushita Electric Ind Co Ltd Wiring transfer sheet and its manufacturing method, and wiring board and its manufacturing method

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06350248A (en) * 1993-06-14 1994-12-22 Furukawa Saakitsuto Foil Kk Surface treatment method of copper foil for printed wiring board
JPH07231152A (en) * 1993-12-24 1995-08-29 Mitsui Mining & Smelting Co Ltd Copper foil for printed circuit inner layer and its manufacture
JPH08158100A (en) * 1994-10-06 1996-06-18 Furukawa Circuit Foil Kk Roughening of copper foil surface
JPH08125331A (en) * 1994-10-19 1996-05-17 Toshiba Corp Manufacture of printed circuit board
JPH1079579A (en) * 1996-09-05 1998-03-24 Toshiba Corp Printed circuit board and manufacturing method of printed circuit board
JPH11135947A (en) * 1997-10-28 1999-05-21 Matsushita Electric Works Ltd Printed wiring board and manufacture thereof
JPH11340596A (en) * 1998-05-21 1999-12-10 Furukawa Electric Co Ltd:The Copper foil for printed circuit board and copper foil attached with resin
JP2004006829A (en) * 2002-04-25 2004-01-08 Matsushita Electric Ind Co Ltd Wiring transfer sheet and its manufacturing method, and wiring board and its manufacturing method

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