JP4297382B2 - Method for producing multicolor hologram recording body - Google Patents

Description

The present invention relates to a method for producing a multicolor hologram recording body, and in particular, a multicolor hologram recording body capable of displaying a number of colors larger than the number of recording wavelengths using a volume hologram recorded at two to three wavelengths. It relates to the manufacturing method.

  Conventionally, it is known that a volume hologram of three colors R (red), G (green), and B (blue) is recorded or superimposed to form a multicolor hologram display by additive color mixing. It is also known that R, G, B pixels or halftone dots are juxtaposed and a multicolor hologram display is constructed by additive color mixing based on the area ratio.

  In addition, the present applicant has proposed a method in Patent Document 1 for obtaining a color pattern having different reproduction colors depending on the position from a volume hologram in which uniform interference fringes are recorded using a swelling film. The principle is that, like a photopolymer, a swollen film is prepared by mixing a monomer or oligomer, a photoinitiator, etc. in a binder polymer, and this swollen film is adhered to a photosensitive material with recorded interference fringes such as a photopolymer. Before or after adhesion, the swelling film is irradiated with a predetermined amount of light to polymerize a predetermined ratio of the monomer or oligomer contained in the swelling film to inactivate the amount of the remaining active monomer or oligomer. Adjust the distance between the interference fringes to an arbitrary predetermined amount and adjust the reproduction wavelength to a predetermined one by diffusing and swelling the adjusted amount in the photosensitive material on which the interference fringes have been recorded. There is. After swelling by such a method, the diffused monomer or oligomer can be fixed in the interference fringe by irradiating or heating the photosensitive material on which the interference fringe has been recorded, so that a hologram with excellent reproduction color storage stability can be obtained. . Moreover, a color pattern can be formed on the hologram by providing a spatial distribution to the light to be irradiated.

  This method will be described in a little more detail with reference to the drawings. FIG. 16 shows a case where the swelling film (monomer, oligomer) contained in the swelling film is inactivated by light irradiation after the swelling film is adhered to the photosensitive material, and FIG. It is a figure for demonstrating the principle in the case of inactivating the swelling agent contained in a swelling film by light irradiation, and in the case of FIG. 16, in the same figure (a), from both surfaces of the photosensitive materials 101, such as a photopolymer. When the object beam 102 and the reference beam 103 are applied and interference fringes are recorded therein, a volume hologram 104 as shown in FIG. Next, as shown in FIG. 2C, the swelling film 105 formed by mixing a monomer or oligomer, a photoinitiator, etc. in the binder polymer is adhered, and the diffusivity of the permeable monomer or oligomer in the swelling film 105 is adhered. Before or simultaneously with heating to increase the temperature, light irradiation 106 is performed from the hologram 104 or swollen film 105 side, as shown in FIGS. By this light irradiation 106, a part or all of the active permeable monomer or oligomer in the swelling film 105 is polymerized by a ratio corresponding to the amount of the light irradiation 106 and becomes inactive, and the permeability (diffusibility) is lost. . Therefore, in the case of the figure (d1) in which the amount of the light irradiation 106 is large, the active penetrating monomer or oligomer in the swelling film 105 almost disappears and hardly penetrates into the hologram 104 even when heated next time. Therefore, for example, if the volume hologram 104 is recorded with the blue wavelength in FIG. 9A, the hologram 104 that has undergone the swelling process in FIG. 11D hardly swells and is reproduced by diffracting the blue light. To do. On the other hand, in the case of the figure (d2) in which the amount of the light irradiation 106 is medium, about half of the active permeable monomer or oligomer in the swelling film 105 becomes inactive, and when heated next, the remaining amount About half of the penetrating monomer or oligomer penetrates into the hologram 104 and swells moderately. For this reason, the hologram 104 that has undergone the swelling process of (d2) in the figure is reproduced by diffracting green light longer than the blue wavelength. Further, in the case of the figure (d3) where the light irradiation 106 is not performed, the active permeable monomer or oligomer in the swelling film 105 remains as it is, and when heated, most of the permeable monomer or oligomer penetrates into the hologram 104. And maximum swelling. For this reason, the hologram 104 that has undergone the swelling process of FIG. 3D is reproduced by diffracting red light that is longer than the green wavelength. In this way, by adjusting the amount of the light 106 applied to the swelling film 105 in close contact with the hologram 104, the reproduction color can be arbitrarily controlled between red and blue.

  In the case of FIG. 17, the volume hologram 104 is obtained in FIGS. 16A and 16B in the same manner as FIGS. 16A and 16B. On the other hand, as shown in (c1) to (c3) in the figure, a swelling film 105 prepared by mixing a monomer or oligomer, a photoinitiator, etc. in a binder polymer is prepared, and a predetermined amount of light irradiation 106 is performed thereon. Then, a part or all of the active permeable monomer or oligomer in the ratio corresponding to the amount of the light irradiation 106 becomes inactive, and the permeability (diffusibility) is lost. When the swelling film 105 that has been irradiated with light 106 is in close contact with the hologram 104 and heated in the same manner as in FIG. 16 as shown in FIGS. Since the degree of swelling of 104 changes, by adjusting the amount of light 106 applied to the swelling film 105, the reproduction color can be arbitrarily controlled between red and blue.

The swelling film 105 is obtained by mixing a monomer or oligomer, a photoinitiator, etc. in a binder polymer, and is the same as a photopolymer for hologram recording. Therefore, a photopolymer for hologram recording can be used as the swelling film 105 without special production.
JP-A-6-332355

  However, in the method of color-recording intermediate colors by multiply recording or superimposing volume holograms of R, G, and B colors, the recording intensity of each color hologram must be adjusted. This is a problem in producing a large amount of images with high reproducibility and stability.

  On the other hand, the method of arranging R, G, B pixels or halftone dots in parallel and generating a neutral color according to the area ratio is a simple method that only adjusts the area of the halftone dots, but the R, G, B3 colors. The halftone dots must be aligned with an accuracy below the dimensional level, and this point has been a difficulty in producing a multicolor hologram display body in large quantities with good reproducibility and stability.

  In addition, the above-mentioned method for producing a color pattern proposed by the present applicant adjusts the amount of light applied to the swollen film before or after closely adhering to the photosensitive material on which interference fringes have been recorded. By adjusting the amount of the monomer or oligomer, the swelling ratio of interference fringes (distance between interference fringes) was adjusted, and the reproduction wavelength was adjusted to a predetermined value. That is, the reproduction color is adjusted by the amount of irradiation light. Hereinafter, in this specification, the method for adjusting the reproduction wavelength of the volume hologram is referred to as “color tuning”, and the swelling film used for the difference is referred to as “color tuning film”.

  However, it is not always easy to accurately adjust the amount of light in order to develop a predetermined color, and there may be a problem that the reproducibility of reproduced colors is not stable.

  The present invention has been made in view of such problems of the prior art, and its purpose is to combine three or more colors such as R, G, and B by combining volume holograms recorded at two wavelengths and color tuning. The object is to provide a multicolor hologram recording body capable of displaying colors or intermediate colors, or a multicolor hologram recording body which appears substantially white when the entire surface is viewed.

The method for producing a multicolor hologram recording body of the present invention that achieves the above object is to produce a multicolor hologram recording body from a volume hologram formed by multiplex recording of holograms that diffract light having reflected light of at least two different wavelengths. In the way to
A color tuning film containing a penetrating monomer or oligomer that can diffuse from the surface to the outside on the volume hologram, and a color tuning film in which the penetrating monomer or oligomer is inactivated according to a predetermined revocation pattern is overlaid,
What is the portion corresponding to the revocation pattern by diffusing the active penetrating monomer or oligomer from the color tuning film into the volume hologram and swelling the portion corresponding to the outside of the revocation pattern of the volume hologram? Diffract light of different wavelengths,
From the portion corresponding to the outside of the revocation pattern of the volume hologram, light of at least two different wavelengths different from the multiplex recorded wavelength is mixed and diffracted, and corresponds to the revocation pattern of the volume hologram. From the portion, it is a method characterized in that multi-color display is possible by mixing and diffracting light of at least two different wavelengths that are multiplexed and recorded.

In this case, the holographically recorded hologram is recorded on the entire effective area, and the revocation pattern can be composed of halftone dots. It can also be used for a hologram reflection / scattering plate for a liquid crystal display device. It is also possible to include regions having different area ratios of halftone dots.

  Further, each of the volume holograms that are recorded in multiple recordings can be recorded in different pattern areas. In that case, a region swollen by the color tuning film and a region not swollen constitute a halftone dot that can reproduce three colors of R (red), G (green), and B (blue). Can do. And the area | region where the area ratios of a halftone dot differ can be included.

  When a color tuning film is used, the color tuning film may be provided integrally.

  In the method for producing a multicolor hologram recording body of the present invention, it is possible to reproduce a color different from the recorded color only by color tuning a partial area of the volume hologram that has been multiplexed and recorded using the color tuning film, Arbitrary color patterns can be created in large quantities with good reproducibility by the additive color mixture of the recorded color and the color-tuned color. Further, it is possible to easily obtain a hologram reflection / scattering plate whose entire surface is substantially white.

  Examples of the multicolor hologram recording body of the present invention will be described below. First, an example of the first multicolor hologram recording body will be described.

  As shown in FIG. 1, in a colorless and transparent background, a flower pattern composed of a red petal region 1, a yellow-green petal region 2, a yellow petal region 3, an orange petal region 4, and a green stem region 5 It is assumed that a hologram display body 10 that displays a pattern consisting of a red diffractive volume hologram and a green diffractive volume hologram is created.

  For this purpose, two volume hologram recording photosensitive materials 11 and 12 made of photopolymer or the like are prepared. As shown in FIG. 4A, one recording photosensitive material 11 has a red color as shown in FIG. The mask pattern 21 is superposed, and the ultraviolet ray 6 for exposing the recording sensitive material 11 is irradiated from the mask pattern 21 side. Here, in the mask pattern 21, pattern areas 41, 43, and 44 corresponding to the red petal area 1, the yellow petal area 3, and the orange petal area 4 of the hologram display body 10 are opaque to the ultraviolet rays 6. The pattern area 42 corresponding to the yellow-green petal area 2 of the hologram display body 10 is a halftone dot area, and the halftone dot portion is opaque to the ultraviolet rays 6. Accordingly, the portions corresponding to the pattern areas 41, 43, and 44 of the recording material 11 are not exposed to the ultraviolet rays 6 and remain photosensitive, and the portion corresponding to the pattern area 42 is 50% in terms of the sum of the areas. The portion corresponding to the halftone dot occupying the area remains photosensitive, and the portion corresponding to outside the pattern regions 41 to 44 and the portion other than the halftone dot occupying the remaining 50% of the area of the pattern region 42 Corresponding parts are exposed to ultraviolet rays 6 and have expired.

  Further, a green mask pattern 22 as shown in FIG. 3 is superimposed on the other recording sensitive material 12 and, as shown in FIG. 4B, ultraviolet rays 6 are applied to sensitize the recording sensitive material 12 from the mask pattern 22 side. To do. Here, in the mask pattern 22, the pattern areas 52, 53, and 55 corresponding to the yellow-green petal area 2, the yellow petal area 3, and the green stem area 5 of the hologram display body 10 are opaque to the ultraviolet rays 6. Thus, the pattern area 54 corresponding to the orange petal area 4 of the hologram display body 10 is a halftone dot area, and the halftone dot portion is opaque to the ultraviolet rays 6. Accordingly, the entire surface of the recording material 12 corresponding to the pattern areas 52, 53, and 55 is not exposed to the ultraviolet rays 6 and remains photosensitive, and the area corresponding to the pattern area 54 is 50% in total area. The portion corresponding to the halftone dot occupying the area remains photosensitive, and the portion corresponding to outside the pattern regions 52 to 55 and the portion other than the halftone dot occupying the remaining 50% of the area of the pattern region 54 Corresponding parts are exposed to ultraviolet rays 6 and have expired.

  Next, light of red wavelength is respectively applied to the non-deactivated area (photosensitive area) of the recording photosensitive materials 11 and 12 in which a part of the area is deactivated through the red mask pattern 21 and the green mask pattern 22 as described above. A red diffractive volume hologram and a green diffractive volume hologram that reflect and diffract light (for example, wavelength 647 nm) and green light (for example, wavelength 532 nm) are recorded. For this purpose, as shown in FIGS. 5 (a) and 5 (b), the reflection / scattering plate 23 is separated by a predetermined distance d from the back side of the recording material 11 and 12 in which a part of the area is invalidated as described above. , The red wavelength light 24 and the green wavelength light 26 are made incident at a predetermined incident angle from the recording sensitive materials 11 and 12 side, respectively, and transmitted through the recording sensitive materials 11 and 12. Red diffracted volume hologram for reflecting and diffracting red wavelength light by reflecting and scattering light 25 and 27 and incident light 24 and 26 in the photosensitive region, and reflecting and diffracting green wavelength light. A green diffractive volume hologram is recorded. Here, the distance d is set depending on a desired reflection / scattering characteristic of the volume hologram to be recorded. Of course, the contact may be d≈0.

  Then, when the films 11 ′ and 12 ′ on which the red diffractive volume hologram and the green diffractive volume hologram are recorded are aligned and overlapped in the non-deactivated region in this way, a hologram display body 10 as shown in FIG. 1 is obtained. Further, as shown in FIG. 6, another volume hologram recording sensitive material 28 is overlaid, and from the recording sensitive material 28 side, red wavelength light (for example, wavelength 647 nm) and green wavelength light (for example, When the illumination light 29 including the wavelength 532 nm is incident, the incident light 29, the light 30 (light having a red wavelength) diffracted from the hologram region of the film 11 ′, and the hologram region of the film 12 ′ are diffracted. The light 31 (light having a green wavelength) interferes in the recording material 28 and is multiplexed and recorded, so that the hologram display body 10 shown in FIG. 1 is obtained.

  7A to 7E show the states of the regions 1 to 5 of the hologram display body 10, respectively. In order from the easy-to-understand region, the region 1 has red reflection as shown in FIG. Only scattering holograms (with a left-down hatch in the figure) are recorded and appear red under white illumination light. As shown in FIG. 7 (e), only the green reflection / scattering hologram (indicated by a downward-sloping hatch in the figure) is recorded in the area 5, and it becomes green under white illumination light. appear. In the region 3, as shown in FIG. 7C, a red reflection / scattering hologram and a green reflection / scattering hologram are superimposed and recorded, and both wavelengths (for example, wavelengths 647 nm and 532 nm) (see FIG. 7). 8) is diffracted and appears yellow due to additive color mixing.

  In the area 2, as shown in FIG. 7B, a minute halftone dot 7 having an area ratio of 50% is present in the background 8, and the halftone dot 7 is red-reflected as in the area 3. The scattering hologram and the green reflection / scattering hologram are superimposed and recorded in yellow, and only the green reflection / scattering hologram is recorded in the background 8 portion, which is green. Therefore, this halftone dot 7 exists in the background 8, and appears yellowish green as shown in FIG. 8 due to an additive color mixture of the yellow of the halftone dot 7 and the green of the background 8 in a ratio of 50:50.

  Then, in the region 4, as shown in FIG. 7D, a minute halftone dot 7 having an area ratio of 50% is present in the background 8, and the portion of the halftone dot 7 is the same as in the region 3, A red reflection / scattering hologram and a green reflection / scattering hologram are superimposed and recorded in yellow, and in this case, only the red reflection / scattering hologram is recorded in the background 8 portion, which is red. . Therefore, this halftone dot 7 exists in the background 8 and appears orange as shown in FIG. 8 due to the additive color mixture of yellow of the halftone dot 7 and red of the background 8 in a 50:50 ratio.

  The above is the 50% halftone dot region for the regions 2 and 4, but the area ratio of the halftone dots can be set arbitrarily, so that the intermediate color is also an arbitrary one between green and yellow, yellow and red Can develop color.

  In the above, the hologram display body 10 is composed of a multiple recording body or a laminate of two color holograms, a red diffractive volume hologram and a green diffractive volume hologram. A hologram can be added to form a multi-recorded or laminated body of three color holograms. In this case, the creation method can be easily expanded by adding a mask pattern, a recording material, and a recording wavelength for another color in the above-described production process, and thus a detailed description is omitted.

  Next, another multicolor hologram recording body of the present invention combining a volume hologram recorded at two wavelengths and color tuning will be described.

First, as shown in FIG. 9, two types of recording materials 61 and 62 for volume holograms are prepared, as shown in FIG. 9, and one recording feeling is prepared as shown in FIG. The reflection / scattering plate 23 is disposed on the back surface side of the material 61 by a predetermined distance d, and light 65 having a wavelength λ _B in the blue region is incident on the entire effective region from the recording material 61 side at an incident angle θ ₁ . Blue diffraction in which light 66 transmitted through the material 61 and reflected and scattered by the reflection / scattering plate 23 interferes with the incident light 65 in the photosensitive region to uniformly reflect and diffract light having a blue wavelength from the entire effective region. A volume hologram 61 ′ is recorded. Similarly, as shown in FIG. 2B, the reflection / scattering plate 23 is arranged on the back side of the recording material 62 by a predetermined distance d, and the green light region at the same incident angle θ ₁ from the recording material 62 side. The light 67 having the wavelength λ _G is incident on the entire effective area, transmitted through the recording material 62, and the light 68 reflected and scattered by the reflection / scattering plate 23 interferes with the incident light 67 in the photosensitive area, so that the entire effective area A green diffraction volume hologram 62 ′ that records and diffracts light of a green wavelength uniformly is recorded. Here, the distance d is set depending on the desired reflection / scattering characteristic of the volume hologram to be recorded. Of course, the contact may be d≈0.

Thereafter, as shown in FIG. 9C, the blue diffractive volume hologram 61 ′ and the green diffractive volume hologram 62 ′ are overlapped, and another volume hologram recording sensitive material 63 is brought into close contact with the laminate. When the uniform duplication illumination light 69 including the wavelengths of λ _B and λ _G is incident at an incident angle θ ₁ from the recording material 63 side, the illumination light 69 and the volume type are overlapped. Reflected and scattered diffracted light 70 consisting of light of wavelength λ _B diffracted by hologram 61 ′ and light of wavelength λ _G diffracted by volume hologram 62 ′ interferes in recording sensitive material 63, and the entire effective area Thus, a hologram 63 ′ in which a blue diffractive volume hologram for reflecting and diffracting blue wavelength light and a green diffractive volume hologram for reflecting and diffracting green wavelength light is multiplexed is reproduced. It should be noted that by performing exposure as shown in FIGS. 9A and 9B sequentially or simultaneously on one sheet of the photosensitive material 63 without being duplicated in this way, the blue color is uniformly distributed from the entire effective area. A hologram 63 ′ in which a blue diffractive volume hologram that reflects and diffracts light having a wavelength and a green diffractive volume hologram that reflects and diffracts light having a green wavelength may be produced.

  Next, as shown in FIG. 10 (a), on the hologram 63 ′ thus prepared, monomers or oligomers in the binder polymer, photoinitiation, as described with reference to FIGS. 16 and 17, are used. A swelling film (hereinafter referred to as a color tuning film) 71 formed by mixing an agent or the like is superposed, and a mask 72 provided with a repeating pattern of transparent openings such as halftone dots is placed thereon, and a mask is placed. The transparent opening of the mask 72 is irradiated with a sufficient amount of light 73 such as ultraviolet rays to polymerize and inactivate almost all of the active penetrable monomer or oligomer in the color tuning film 71 through 72. The portion of the color tuning film 71 corresponding to the portion is substantially invalidated. After such irradiation, if heat treatment is performed at a temperature and for a time sufficient to diffuse the active penetrating monomer or oligomer in the color tuning film 71 into the hologram 63 ′, the light 73 shown in FIG. In the portion b of the hologram 63 ′ corresponding to the position where there was not, the distance between the interference fringes of the blue diffractive volume hologram swells to become a green diffractive volume hologram that reflects and diffracts light of the green wavelength, and the same part Similarly, the distance between the interference fringes of the green diffractive volume hologram in b also swells to become a red diffractive volume hologram that reflects and diffracts light of the red wavelength. On the other hand, in the portion a of the hologram 63 ′ corresponding to the position where the portion of the color tuning film 71 is substantially invalidated by the light 73, both the blue diffractive volume hologram and the green diffractive volume hologram remain substantially the same. There is almost no change.

Accordingly, as shown in FIG. 10 (c), 'a wavelength in the blue region lambda _B, the wavelength in the green region λ _G, λ _G' hologram 63 subjected to color tuning as described above, the wavelength of the red region lambda _R Is irradiated with an incident angle θ ₁ at the time of hologram recording, light 75 having wavelengths of λ _B and λ _G is reflected and diffracted from the portion a of the hologram 63 ′, and the portion of the hologram 63 ′ From b, light 75 'having wavelengths of λ _G ' and λ _R is reflected and scattered. Light 75 appears cyan and light 75 ′ appears yellow.

FIGS. 11A and 11B are curves showing specific examples of the diffraction efficiency distribution of the volume holograms of the portions a and b of the hologram 63 ′ of FIG. 10C. However, each vertical axis does not directly indicate the diffraction efficiency, but indicates the 0th-order light transmittance that is complementary to the diffraction efficiency. In this specific example, Omnidex 706 (manufactured by DuPont) was used as the photopolymer of the recording material 63, and CTF75 (manufactured by DuPont) was used as the color tuning film 71. The heat treatment for diffusion of the active permeable monomer or the like was performed at 120 ° C. for 2 hours. From the specific example in FIG. 11, from the portion a where color tuning has not been performed, the light of the wavelength λ _{B in the} blue region and the wavelength λ _{G in} the green region is reflected and diffracted (FIG. 11A), and the hologram is colored From the tuned portion b, it is well understood that the light having the wavelength λ _G ′ in the green region and the wavelength λ _{R in} the red region is reflected and diffracted.

  If the parts a and b are fine, the entire hologram 63 ′ appears to be an additive color mixture of cyan and yellow, but the area of the transparent portion of the mask 72 (corresponding to the area of the part a) and the area of the opaque part (part b) Of the transparent portion such as the halftone dots of the mask 72 or the irradiation light quantity of the light 73, the intensity ratio of the B (blue) and G (green) laser light, and the heat treatment conditions As a result of this adjustment, the color mixture ratio changes depending on the area gradation or density gradation, so that an intermediate color can be reproduced. Further, by configuring the mask 72 so that the area gradation or density gradation changes according to the position of the mask 72, the hologram 63 'can be a multicolor hologram display.

  Further, by the same adjustment, a hologram reflection / scattering plate can be obtained in which the entire hologram 63 'appears to be substantially white or greenish white due to the additive color mixture of cyan and yellow. Such a hologram reflection / scattering plate can be used as a bright reflection / scattering plate of a liquid crystal liquid crystal display device.

  Here, a liquid crystal liquid crystal display device using such a hologram reflection / scattering plate will be briefly described. The white hologram reflection / scattering plate according to the present invention is a hologram that diffuses and reflects light incident from a specific direction (direction of illumination light 74 in FIG. 10C) only in a direction determined as an observation area. In the liquid crystal display device using the white hologram reflection / scattering plate 76 of the present invention, the white hologram reflection / scattering plate 76 is disposed on the opposite side to the observation side of the liquid crystal display element 80 as shown in a cross section in FIG. Thus, the illumination light 77 incident from the display side of the liquid crystal display element 80 is diffused and reflected as diffused light 78 only in an angle range θ matching the observation area of the liquid crystal display device, and a self-luminous backlight in a bright place. It is possible to display without using. Here, the liquid crystal display element 80 includes, for example, a twisted nematic liquid crystal layer 85 sandwiched between two glass substrates 81 and 82, and a uniform transparent counter electrode is formed on the inner surface of one glass substrate 82. 84, and a transparent display electrode 83 and a black matrix (not shown) are provided on the inner surface of the other glass substrate 81 independently for each pixel. In the case of a color display device, a transparent display electrode 83, a color filter, and a black matrix are provided on the inner surface of the other glass substrate 81 independently for each of the liquid crystal cells R, G, and B. In addition, an alignment layer (not shown) is also provided on the liquid crystal layer 85 side of the electrodes 83 and 84. Further, a polarizing plate 86 is provided on the outer surface of the observation side glass substrate 81, and a glass substrate 82 on the opposite side to the observation side. Polarizing plates 87 are respectively attached to the outer surfaces, and for example, their transmission axes are arranged so as to be orthogonal to each other. By controlling the voltage applied between the transparent display electrode and the transparent counter electrode of the liquid crystal display element 80 to change the transmission state, it is possible to selectively display numbers, characters, symbols, pictures, and the like. .

  In the case of FIG. 9, a blue diffractive volume hologram and a green diffractive volume hologram are recorded on the entire effective area of each of the recording light-sensitive materials 61 and 62, but desired at the stage of FIGS. 9 (a) and 9 (b). Consider recording a volume hologram only in the pattern area. Two volume hologram recording sensitive materials 91 and 92 are prepared, and a blue mask pattern is superimposed on the recording sensitive material 91 for recording a blue diffraction volume hologram in the same manner as in FIG. The pattern sensitive region 91 of the recording photosensitive material 91 is exposed and expired as shown in FIG. 13A by irradiating ultraviolet rays for exposing the recording photosensitive material 91 from the pattern side. Further, the recording sensitive material 92 for recording the green diffractive volume hologram is overlaid with a green mask pattern and irradiated with ultraviolet rays for exposing the recording sensitive material 92 from the mask pattern side, as shown in FIG. As described above, the pattern area 95 of the recording material 92 is exposed to light and expired.

Thereafter, as shown in FIGS. 13A and 13B, the recording material 91 and 92 have an undestructed area in blue as in FIGS. 9A and 9B. A blue diffractive volume hologram 91 ′ that reflects and diffracts light of a wavelength of blue and a green diffractive volume hologram 92 ′ that reflects and diffracts light of a green wavelength from only the undeactivated region are recorded. Thereafter, as shown in FIG. 13C, in the same manner as in FIG. 9C, the blue diffractive volume hologram 91 ′ and the green diffractive volume hologram 92 ′ are overlaid and another volume type is formed on the laminate. When the hologram recording photosensitive material 93 is brought into close contact with each other or slightly overlapped, and uniform illumination light 69 including wavelengths λ _B and λ _G is incident at an incident angle θ ₁ from the recording photosensitive material 93 side. The recording light-sensitive material 93 is composed of the illumination light 69 and the reflected and scattered diffracted light 70 composed of the light having the wavelength λ _B diffracted by the volume hologram 91 ′ and the light having the wavelength λ _G diffracted by the volume hologram 92 ′. A blue diffractive volume hologram that reflects and diffracts blue wavelength light and a green diffractive volume hologram that reflects and diffracts green wavelength light are recorded in multiple layers by interfering with each other and patterned separately. The hologram 93 ' The Instead of such duplication, the exposure is performed sequentially or simultaneously on one sheet of recording material 93 as shown in FIG. 13A and FIG. Alternatively, a hologram 93 ′ in which a blue diffractive volume hologram that reflects and diffracts light of a certain wavelength and a green diffractive volume hologram that reflects and diffracts light of a green wavelength are recorded in a multiplexed manner may be produced.

  The hologram 93 ′ thus duplicated or multiplex-recorded has a blue diffractive volume hologram area G and a green diffractive volume hologram area B alternately as illustrated in FIGS. 14 (a) and 15 (a). Although not shown, the blue diffractive volume hologram region G and the green diffractive volume hologram region B partially overlap, and in some cases, the blue diffractive volume hologram region B, the green diffractive volume hologram region There is an area where G is not recorded. 14 (a) and 15 (a) are cases where the blue diffractive volume hologram region B and the green diffractive volume hologram region G are alternately arranged adjacent to each other, but FIG. ) Is an example in which the region G is twice as wide as the region B, and FIG. 15A is an example in which the region B is twice as wide as the region G. Thus, the hologram 93 ′ in which the blue diffractive volume hologram region G and the green diffractive volume hologram region B are multiplex-recorded is a blue diffractive volume of a predetermined region in the same manner as in FIGS. 10 (a) and 10 (b). One or both of the holographic hologram and the green diffractive volume hologram is color tuned by the color tuning film 71, and the distance between the interference fringes of the blue diffractive volume hologram swells to reflect and diffract light of the green wavelength. It becomes a volume hologram, and the distance between the interference fringes of the green diffraction volume hologram similarly swells and becomes a red diffraction volume hologram that reflects and diffracts light of red wavelength.

  In the case of FIG. 14B, the area c of the color tuning film 71 is expired and color tuning is not performed, the area d is valid and color tuning is performed, and half of the green diffractive volume hologram area G of the hologram 93 ′ is red. It is converted into a diffractive volume hologram R. In the case of FIG. 15B, the area e of the color tuning film 71 is expired and color tuning is not performed, the area f is valid and color tuning is performed, and half of the blue diffractive volume hologram area B of the hologram 93 ′ is green. The diffractive volume hologram region G is converted, and the green diffractive volume hologram region G is converted into a red diffractive volume hologram region R. In any case, the three regions that are substantially equal in size and are adjacent to each other become a blue diffraction volume hologram region B, a green diffraction volume hologram region G, and a red diffraction volume hologram region R. The recording light-sensitive materials 61 and 62 are invalidated so that an arbitrary color can be expressed at an arbitrary position by an additive color mixture of RGB by an area gradation or density gradation of the pixel or a combination thereof. By selecting the mask pattern and transmittance at the time, and the mask pattern and transmittance when the color tuning film 71 is expired, an arbitrary color pattern can be displayed.

  In the holograms 63 ′ and 93 ′ partially color tuned with the above color tuning film 71, the color tuning film 71 may be peeled off from the final hologram recording body, but it remains as a single unit. Also good.

  As described above, the multicolor hologram recording body of the present invention has been described based on the embodiment. However, the present invention is not limited to this embodiment, and various modifications are possible. The hologram in the present invention is not limited to a reflection / scattering volume hologram, but may be a transmission / scattering volume hologram or a volume hologram capable of reproducing a pattern such as a stereoscopic image. The halftone dot in the present invention includes not only a collection of figures such as a minute circle and a rectangle but also a collection of fine stripes.

  As is clear from the above description, according to the multicolor hologram display of the present invention, the intermediate color pattern region based on the halftone dot area ratio is a halftone dot of another color hologram in the background color hologram recorded on the entire surface. Since the portions are overlapped, the alignment accuracy between the hologram originals of different colors is greatly relaxed as compared with the case where alignment of halftone dots is required. In addition, since the intermediate color depends on the halftone dot area ratio, not the hologram recording intensity, it can be stably colored with high reproducibility, and a multicolor hologram display can be stably produced in large quantities with good reproducibility. .

  In addition, according to another multicolor hologram recording material of the present invention, a color different from the recorded color can be reproduced only by color tuning a partial area of the volume hologram recorded in multiple using a color tuning film. An arbitrary color pattern can be produced in a large amount with good reproducibility by the additive color mixture of the recorded color and the color-tuned color. Further, it is possible to easily obtain a hologram reflection / scattering plate whose entire surface is substantially white.

It is a top view of the multicolor hologram display body of one Example of this invention. It is a top view of one mask pattern used in the multicolor hologram display body production process of FIG. It is a top view of the other mask pattern used in the multicolor hologram display body preparation process of FIG. It is a figure for demonstrating the process of canceling one part of the recording sensitive material in the multicolor hologram display body preparation process of FIG. It is a figure for demonstrating the process of recording a hologram on a recording sensitive material in the multicolor hologram display body preparation process of FIG. It is a figure for demonstrating the process of replicating the multicolor hologram display body of FIG. 1 from an original. It is a figure which shows the mode of each area | region of the multicolor hologram display body of FIG. It is a figure for demonstrating the coloring principle of the intermediate color of the multicolor hologram display body of FIG. It is a figure which shows a part of recording process of the multicolor hologram recording body of another Example of this invention. It is a figure which shows the remaining part of the recording process of the multicolor hologram recording body of another Example of this invention. It is a figure which shows the specific example of the diffraction efficiency distribution of the multicolor hologram recording body by FIG. 9, FIG. It is sectional drawing of the liquid crystal display device using the white hologram reflection scattering plate based on this invention. It is a figure which shows a part of recording process of the multicolor hologram recording body of the modification of FIG. 9, FIG. It is a figure which shows the remaining part of the recording process of the multicolor hologram recording body of the modification of FIG. 9, FIG. It is a figure which shows another form of the remaining part of the recording process of the multicolor hologram recording body of the modification of FIG. 9, FIG. It is a figure for demonstrating one of the preparation methods of the conventional hologram color display body. It is a figure for demonstrating another thing of the preparation methods of the conventional hologram color display body.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 ... Red petal area 2 ... Yellow-green petal area 3 ... Yellow petal area 4 ... Orange petal area 5 ... Green stem area 6 ... Ultraviolet light 7 ... Halftone dot 8 ... Background 10 ... Hologram display bodies 11 and 12, 28 ... Volume-sensitive hologram recording material 11 '... Red diffractive volume hologram recording film 12' ... Green diffractive volume hologram recording film 21 ... Red mask pattern 22 ... Green mask pattern 23 ... Reflection scattering plate 24: Red wavelength light 25, 27: Reflected scattered light 26 ... Green wavelength light 29 ... Illumination light 30 including red wavelength light and green wavelength light 30, 31 ... Diffracted light 41-45 ... Pattern region 51 to 55 Pattern regions 61, 62, 63 Volume sensitive recording material 61 'Blue diffraction volume hologram 62' Green diffraction volume hologram 63 'Multiple recording hologram 65 The wavelength of the light 66 ... reflected scattered light 67 ... wavelength of light 68 ... reflected scattered light 69 ... duplication illumination light 70 ... reflected scattered diffracted light 71 ... swelling film in the green region of the blue region (color tuning film)
72 ... Mask 73 ... Light 74 such as ultraviolet rays ... Illumination light 75, 75 '... Reflection / scattering diffraction 76 ... White hologram reflection / scattering plate 77 ... Illumination light 78 ... Diffused light 80 ... Liquid crystal display element 81, 82 ... Glass substrate 83 ... Transparent Display electrode 84 ... Transparent counter electrode 85 ... Liquid crystal layers 86, 87 ... Polarizing plates 91, 92, 93 ... Volume hologram recording material 94, 95 ... Deactivated pattern region 91 '... Blue diffraction volume hologram 92' ... Green diffraction Volume hologram 93 '... Multiple recording hologram

Claims (8)

In a method for producing a multicolor hologram recording body from a volume hologram formed by multiplex recording of a hologram that diffracts light of at least two different wavelengths as reflected scattered light ,
A color tuning film containing a penetrating monomer or oligomer that can diffuse from the surface to the outside on the volume hologram, and a color tuning film in which the penetrating monomer or oligomer is inactivated according to a predetermined revocation pattern is overlaid,
What is the portion corresponding to the revocation pattern by diffusing the active penetrating monomer or oligomer from the color tuning film into the volume hologram and swelling the portion corresponding to the outside of the revocation pattern of the volume hologram? Diffract light of different wavelengths ,
From a portion corresponding to the outside of the revocation pattern of the volume hologram, light of at least two different wavelengths different from the multiplex-recorded wavelength is mixed and diffracted to correspond to the revocation pattern of the volume hologram. A method for producing a multicolor hologram recording body, characterized in that multicolor display can be performed by mixing and diffracting light of at least two different wavelengths that are multiplexed and recorded from the portion . 2. The method for producing a multicolor hologram recording body according to claim 1, wherein the multiple recorded holograms are recorded on the entire effective area, and the revocation pattern is formed of halftone dots. 3. The method for producing a multicolor hologram recording body according to claim 2, wherein the multicolor hologram recording body is used for a hologram reflection / scattering plate for a liquid crystal display device. The method for producing a multicolor hologram recording body according to claim 2, wherein the halftone dot portion includes regions having different area ratios. 2. The method for manufacturing a multicolor hologram recording body according to claim 1, wherein each of the multiple recorded holograms is recorded in different pattern areas. In Claim 5, the area | region swollen by the said color tuning film and the area | region which is not swollen comprise the halftone dot which can reproduce three colors of R (red), G (green), and B (blue). A method for producing a multi-color hologram recording body characterized in that: The method for producing a multicolor hologram recording body according to claim 6, wherein the halftone dot area ratio is different. 8. The method for producing a multicolor hologram recording body according to any one of claims 1 to 7, wherein the color tuning film is provided integrally with the multicolor hologram recording body.

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