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JP4087800B2 - Method for producing molten Al-Zn plated steel sheet - Google Patents

Method for producing molten Al-Zn plated steel sheet Download PDF

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JP4087800B2
JP4087800B2 JP2004025776A JP2004025776A JP4087800B2 JP 4087800 B2 JP4087800 B2 JP 4087800B2 JP 2004025776 A JP2004025776 A JP 2004025776A JP 2004025776 A JP2004025776 A JP 2004025776A JP 4087800 B2 JP4087800 B2 JP 4087800B2
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祐一 福島
利彦 大居
香樹 橘
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JFE Steel Corp
JFE Galvanizing and Coating Co Ltd
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Description

本発明は、めっき皮膜中のAl含有量が20〜95mass%である溶融Al−Zn系めっき鋼板の製造方法に関する。   The present invention relates to a method for producing a molten Al—Zn-based plated steel sheet having an Al content in a plating film of 20 to 95 mass%.

55%Al−Zn系めっき鋼板に代表される、めっき皮膜中にAlを20〜95mass%含有する溶融Al−Zn系めっき鋼板(以下、「55%Al−Zn系めっき鋼板」を例に説明する)は、特公昭46−7161号に示されるように溶融亜鉛めっき鋼板に較べて優れた耐食性を示すことから、近年、建材分野を中心に需要が増加しつつある。
この55%Al−Zn系めっき鋼板は、酸洗脱スケールした熱延鋼板又はこれをさらに冷間圧延して得られた冷延鋼板を下地鋼板とし、連続式溶融めっき設備において以下のようにして製造される。
A hot-dip Al—Zn plated steel sheet (hereinafter referred to as “55% Al—Zn plated steel sheet”) containing 20 to 95 mass% Al in the plating film, represented by 55% Al—Zn plated steel sheet, will be described as an example. ) Shows excellent corrosion resistance as compared with hot dip galvanized steel sheet as shown in Japanese Examined Patent Publication No. 46-7161, and in recent years, demand is increasing mainly in the building material field.
This 55% Al-Zn-based plated steel sheet is a hot-rolled steel sheet that has been pickled and descaled or a cold-rolled steel sheet obtained by further cold rolling the base steel sheet. Manufactured.

連続式溶融めっき設備では、下地鋼板は還元性雰囲気に保持された焼鈍炉内で所定温度に加熱され、焼鈍と同時に鋼板表面に付着する圧延油等の除去、酸化膜の還元除去が行われた後、下端がめっき浴に浸漬されたスナウト内を通って所定濃度のAlを含有した溶融亜鉛めっき浴中に浸漬される。めっき浴に浸漬された鋼板はシンクロールを経由してめっき浴の上方に引き上げられた後、めっき浴上に配置されたガスワイピングノズルから鋼板の表面に向けて加圧した気体を噴射することによりめっき付着量が調整され、次いで冷却装置により冷却され、所定のめっき皮膜が形成された55%Al−Zn系めっき鋼板が得られる。   In the continuous hot dip plating facility, the base steel sheet was heated to a predetermined temperature in an annealing furnace maintained in a reducing atmosphere, and simultaneously with the annealing, the rolling oil adhered to the steel sheet surface was removed, and the oxide film was reduced and removed. Thereafter, the lower end passes through a snout immersed in the plating bath and is immersed in a hot dip galvanizing bath containing a predetermined concentration of Al. After the steel plate immersed in the plating bath is pulled up above the plating bath via the sink roll, a pressurized gas is sprayed from the gas wiping nozzle arranged on the plating bath toward the surface of the steel plate. The plating adhesion amount is adjusted, and then cooled by a cooling device to obtain a 55% Al—Zn-based plated steel sheet on which a predetermined plating film is formed.

連続式溶融めっき設備における焼鈍炉の熱処理条件及び雰囲気条件、めっき浴組成やめっき後の冷却速度等の操業条件は、所望のめっき品質や材質を確保するために所定の管理範囲で精度よく管理される。
上記のようにして製造された55%Al−Zn系めっき鋼板のめっき皮膜は、主としてZnを過飽和に含有したAlがデンドライト凝固した部分と、残りのデンドライト間隙の部分からなっており、デンドライトはめっき皮膜の膜厚方向に積層している。このような特徴的な皮膜構造により、55%Al−Zn系めっき鋼板は優れた耐食性を示す。
Operating conditions such as annealing furnace heat treatment and atmosphere conditions, plating bath composition and cooling rate after plating in continuous hot dip plating equipment are accurately controlled within a prescribed control range to ensure the desired plating quality and material. The
The plating film of the 55% Al—Zn-plated steel sheet produced as described above mainly consists of a portion where Al containing Zn in supersaturation is dendrite solidified and a portion of the remaining dendrite gap. They are stacked in the film thickness direction. With such a characteristic film structure, the 55% Al—Zn-based plated steel sheet exhibits excellent corrosion resistance.

また、めっき浴には通常1.5mass%程度のSiが添加されているが、このSiの働きにより、55%Al−Zn系めっき鋼板はめっき皮膜/下地鋼板界面の合金相成長が抑えられ、合金相厚さは約1〜2μm程度である。この合金相が薄ければ薄いほど優れた耐食性を示す特徴的な皮膜構造の部分が多くなるので、合金相の成長抑制は耐食性の向上に寄与する。
通常、めっき浴には不可避的不純物、鋼板やめっき浴中の機器等から溶出するFe、合金相抑制のためのSiが含まれるが、それら以外にも何らかの元素が添加されている場合もあり、合金相やめっき皮膜中にはそれら元素が合金或いは単体の形で存在している。
In addition, Si of about 1.5 mass% is usually added to the plating bath, but due to the action of this Si, 55% Al—Zn-based plated steel sheet suppresses alloy phase growth at the plating film / underlying steel sheet interface, The alloy phase thickness is about 1-2 μm. The thinner the alloy phase is, the more portions of the characteristic film structure exhibiting excellent corrosion resistance. Therefore, the suppression of the growth of the alloy phase contributes to the improvement of the corrosion resistance.
Usually, the plating bath contains unavoidable impurities, Fe eluted from the steel plate and equipment in the plating bath, Si for alloy phase suppression, but some elements may be added in addition to them, In the alloy phase and the plating film, these elements exist in the form of an alloy or a simple substance.

上述したように55%Al−Zn系めっき鋼板は優れた耐食性を有する反面、機械的特性、特に伸び特性が他のめっき鋼板、例えばめっき皮膜中にAlを5mass%程度含有する溶融Al−Zn系めっき鋼板(以下、「5%Al−Zn系めっき鋼板」という)に較べて劣る傾向があり、このため厳しい加工を行う用途には使用しにくい難点がある。一方、5%Al−Zn系めっき鋼板は伸び特性に優れているため加工が容易であるものの、55%Al−Zn系めっき鋼板に較べて耐食性に劣っており、このため最近では55%Al−Zn系めっき鋼板への置き替えが行われようになりつつある。   As described above, the 55% Al—Zn-based plated steel sheet has excellent corrosion resistance, while the mechanical properties, in particular the elongation characteristics, are other plated steel plates, for example, a molten Al—Zn-based alloy containing about 5 mass% of Al in the plating film. There is a tendency to be inferior to a plated steel sheet (hereinafter referred to as “5% Al—Zn-based plated steel sheet”), which makes it difficult to use for strict processing. On the other hand, although 5% Al—Zn-based plated steel sheet has excellent elongation characteristics and is easy to process, it is inferior in corrosion resistance to 55% Al—Zn-based plated steel sheet. Replacement to a Zn-based plated steel sheet is being performed.

上述したように55%Al−Zn系めっき鋼板は伸び特性値が小さいために、同程度の加工を行った場合でも同一めっき皮膜厚の5%Al−Zn系めっき鋼板に較べて加工性に劣る傾向がある。そのため折り曲げ等の加工を行うと、加工の程度によっては被加工部のめっき鋼板部分に亀裂が生じ、使用上大きな問題となる場合がある。   As described above, the 55% Al—Zn-based plated steel sheet has a small elongation characteristic value, so that even when the same degree of processing is performed, the workability is inferior compared to the 5% Al—Zn-based plated steel sheet having the same plating film thickness. Tend. For this reason, when processing such as bending is performed, a crack may occur in the plated steel plate portion of the processed portion depending on the degree of processing, which may be a major problem in use.

このような問題に対して、例えば、特許文献1には、55%Al−Zn系めっき鋼板に所定の熱処理を施すことによってその延性を改善する方法が示されている。しかしながら、本発明者らが実験などにより確認したところによれば、このような熱処理をバッチ処理によりめっき鋼板コイルに対して実施した場合、熱処理中にコイル内の鋼板間に焼付き(密着)が発生し、この結果、製品であるめっき鋼板の美麗な表面外観が著しく損なわれるという問題を生じることが判った。   For such a problem, for example, Patent Document 1 discloses a method for improving ductility of a 55% Al—Zn-based plated steel sheet by subjecting it to a predetermined heat treatment. However, according to what the present inventors have confirmed through experiments and the like, when such heat treatment is performed on a plated steel sheet coil by batch processing, seizure (adhesion) is caused between the steel sheets in the coil during the heat treatment. As a result, it has been found that the beautiful surface appearance of the plated steel sheet as a product is significantly impaired.

また、特許文献2には、合金化溶融亜鉛めっき鋼板をバッチ焼鈍によって400〜480℃に加熱する際に、加熱雰囲気を微酸化性にして鋼板間での焼付けを防止する方法が示されているが、55%Al−Zn系めっき鋼板のバッチ加熱を上記温度範囲で実施すると鋼板間での焼付けの発生は避けられない。
特公昭61−28748号公報 特公昭53−9176号公報
Patent Document 2 discloses a method of preventing seizure between steel sheets by making the heating atmosphere slightly oxidizable when heating an alloyed hot-dip galvanized steel sheet to 400 to 480 ° C. by batch annealing. However, if batch heating of the 55% Al—Zn-based plated steel sheet is performed within the above temperature range, the occurrence of baking between the steel sheets is inevitable.
Japanese Patent Publication No. 61-28748 Japanese Patent Publication No.53-9176

したがって本発明の目的は、55%Al−Zn系めっき鋼板に代表される、めっき皮膜中のAl含有量が20〜95mass%である溶融Al−Zn系めっき鋼板であって、伸び特性が優れしかも美麗な表面外観を有するめっき鋼板を安定して製造することができる溶融Al−Zn系めっき鋼板の製造方法を提供することにある。   Therefore, an object of the present invention is a molten Al-Zn-based plated steel sheet represented by 55% Al-Zn-based plated steel sheet, wherein the Al content in the plating film is 20 to 95 mass%, and has excellent elongation characteristics. It is providing the manufacturing method of the fusion | melting Al-Zn type plated steel plate which can manufacture stably the plated steel plate which has a beautiful surface appearance.

上記課題の解決のために、本発明者らは実用製品としての優れためっき表面外観を確保するという観点から、55%Al−Zn系めっき鋼板の伸び特性を向上させ、且つ美麗なめっき表面外観を得るための最適な製造方法について鋭意検討を行った。その結果、55%Al−Zn系めっき鋼板を連続溶融めっきラインで製造する際に、めっき表面粗さRaが0.20μm以上のめっき皮膜を形成させた上で、このめっき鋼板を連続溶融めっきラインの巻取装置の直前で300℃未満の温度に連続加熱し、コイル巻取り張力3.0kg/mm以下で巻き取った後、このコイルをその保有熱により自己保熱するか又は加熱炉において300℃未満の温度に加熱保持することにより、加熱処理による伸び特性の適切な改善が図られるとともに、コイル内でのめっき鋼板間の焼付けが適切に防止され、伸び特性に優れ且つ美麗な表面外観を有する55%Al−Zn系めっき鋼板を製造できることが判った。 In order to solve the above problems, the present inventors have improved the elongation characteristics of 55% Al—Zn-based plated steel sheet and have a beautiful plated surface appearance from the viewpoint of securing an excellent plated surface appearance as a practical product. We have intensively studied the optimum manufacturing method for obtaining the above. As a result, when a 55% Al—Zn-based plated steel sheet was produced on a continuous hot dipping line, a plating film having a plating surface roughness Ra of 0.20 μm or more was formed, and this plated steel sheet was then used as a continuous hot dipping line. The coil is continuously heated to a temperature of less than 300 ° C. immediately before the coiling device and wound at a coil winding tension of 3.0 kg / mm 2 or less. By heating and holding at a temperature of less than 300 ° C., the elongation characteristics can be appropriately improved by the heat treatment, and the seizure between the plated steel sheets in the coil is appropriately prevented, and the surface appearance is excellent in elongation characteristics and beautiful. It was found that a 55% Al—Zn-based plated steel sheet having the following can be produced.

すなわち、本発明の溶融Al−Zn系めっき鋼板の製造方法は以下のような特徴を有する。
[1]めっき皮膜中のAl含有量が20〜95mass%である溶融Al−Zn系めっき鋼板の製造方法であって、めっき金属が凝固した後の溶融Al−Zn系めっき鋼板を加熱処理することにより伸び特性の改善を図る方法において、
めっき表面粗さRaが0.20μm以上2.0μm以下のめっき皮膜が形成された溶融Al−Zn系めっき鋼板を、連続溶融めっきラインの巻取装置の直前で100℃以上300℃未満の温度に連続加熱し、コイル巻取り張力0.3kg/mm 以上3.0kg/mm以下、鋼板加熱温度マイナス10〜20℃(板温)で巻き取った後、該コイルをその保有熱により保熱開始時の板温を100℃以上であって、且つ前記連続加熱での鋼板加熱温度−50℃以上として自己保熱することを特徴とする溶融Al−Zn系めっき鋼板の製造方法。
That is, the manufacturing method of the molten Al—Zn-based plated steel sheet of the present invention has the following characteristics.
[1] A method for producing a molten Al—Zn-based plated steel sheet having an Al content in a plating film of 20 to 95 mass%, wherein the molten Al—Zn-based plated steel sheet is solidified after the plated metal has solidified. In the method of improving the elongation characteristics by
A hot-dip Al-Zn-based plated steel sheet on which a plating film having a plating surface roughness Ra of 0.20 μm or more and 2.0 μm or less is formed at a temperature of 100 ° C. or more and less than 300 ° C. immediately before the winding device of the continuous hot dipping plating line. continuously heating, heat retaining coil winding tension 0.3 kg / mm 2 or more 3.0 kg / mm 2 or less, after winding of a steel plate heating temperature minus 10 to 20 ° C. (sheet temperature), by the potential heat of the coil A method for producing a molten Al—Zn-plated steel sheet, wherein self- heating is carried out at a starting plate temperature of 100 ° C. or higher and a steel plate heating temperature in the continuous heating of −50 ° C. or higher .

[2]めっき皮膜中のAl含有量が20〜95mass%である溶融Al−Zn系めっき鋼板の製造方法であって、めっき金属が凝固した後の溶融Al−Zn系めっき鋼板を加熱処理することにより伸び特性の改善を図る方法において、
めっき表面粗さRaが0.20μm以上2.0μm以下のめっき皮膜が形成された溶融Al−Zn系めっき鋼板を、連続溶融めっきラインの巻取装置の直前で100℃以上300℃未満の温度に連続加熱し、コイル巻取り張力0.3kg/mm 以上3.0kg/mm以下、鋼板加熱温度マイナス10〜20℃(板温)で巻き取った後、該コイルを加熱炉においてコイル最高温度部の板温が100℃以上300℃未満、加熱保持開始時の板温が100℃以上であって、且つ前記連続加熱での鋼板加熱温度−50℃以上になるような条件で加熱保持することを特徴とする溶融Al−Zn系めっき鋼板の製造方法。
[2] A method for producing a molten Al-Zn-based plated steel sheet having an Al content of 20 to 95 mass% in the plating film, wherein the molten Al-Zn-based plated steel sheet after the plating metal has solidified is heat-treated. In the method of improving the elongation characteristics by
A hot-dip Al-Zn-based plated steel sheet on which a plating film having a plating surface roughness Ra of 0.20 μm or more and 2.0 μm or less is formed at a temperature of 100 ° C. or more and less than 300 ° C. immediately before the winding device of the continuous hot dipping plating line. continuously heating, coil winding tension 0.3 kg / mm 2 or more 3.0 kg / mm 2 or less, after winding of a steel plate heating temperature minus 10 to 20 ° C. (sheet temperature), the coil maximum temperature in a heating furnace to the coil Heating and holding under such conditions that the plate temperature of the part is 100 ° C. or higher and lower than 300 ° C., the plate temperature at the start of heating and holding is 100 ° C. or higher, and the steel plate heating temperature in the continuous heating is −50 ° C. or higher. The manufacturing method of the fusion | melting Al-Zn type plated steel plate characterized by these.

本発明法によれば、55%Al−Zn系めっき鋼板に代表される、めっき皮膜中のAl含有量が20〜95mass%である溶融Al−Zn系めっき鋼板であって、伸び特性が優れしかも美麗なめっき表面外観を有するめっき鋼板を安定して製造することができる。   According to the method of the present invention, it is a molten Al-Zn-based plated steel sheet represented by 55% Al-Zn-based plated steel sheet and having an Al content of 20 to 95 mass% in a plating film, and has excellent elongation characteristics. A plated steel sheet having a beautiful plated surface appearance can be stably produced.

本発明が製造の対象とするめっき鋼板は、めっき皮膜中にAlを20〜95mass%含有する溶融Al−Zn系めっき鋼板であり、また、めっき皮膜のより好ましい成分組成は、Al:45〜65mass%、Si:0.7〜2.0mass%、Fe:10mass%未満、残部が不可避的不純物を含む実質的なZnであり、このような組成の場合に特に優れた耐食性を発揮する。
また、溶融Al−Zn系めっき鋼板のめっき付着量は特に限定されないが、一般に片面当たり30〜120g/m程度が適当である。
The plated steel sheet to be manufactured by the present invention is a molten Al—Zn-based plated steel sheet containing 20 to 95 mass% of Al in the plated film, and a more preferable component composition of the plated film is Al: 45 to 65 mass. %, Si: 0.7 to 2.0 mass%, Fe: less than 10 mass%, the balance being substantial Zn containing inevitable impurities, and particularly excellent corrosion resistance is exhibited in such a composition.
Moreover, the amount of plating adhesion of the molten Al—Zn-based plated steel sheet is not particularly limited, but generally about 30 to 120 g / m 2 per side is appropriate.

本発明の第1の方法では、連続溶融めっきラインにおいて、鋼板面にめっき表面粗さRaが0.20μm以上の溶融Al−Zn系めっき皮膜を形成するとともに、この溶融Al−Zn系めっき鋼板を連続溶融めっきラインの巻取装置の直前で300℃未満の温度に連続加熱し、コイル巻取り張力3.0kg/mm以下で巻き取った後、このコイルをその保有熱により保熱処理(自己保熱)する。 In the first method of the present invention, in a continuous hot dipping line, while forming a hot Al—Zn plating film having a plating surface roughness Ra of 0.20 μm or more on the steel plate surface, The coil is continuously heated to a temperature of less than 300 ° C. just before the winding device of the continuous hot dipping line, wound at a coil winding tension of 3.0 kg / mm 2 or less, and then the coil is subjected to a heat treatment (self-maintaining) by its retained heat. heat.

ここで、溶融Al−Zn系めっき鋼板のめっき表面粗さRaを0.20μm以上とするのは、めっき表面粗さRaが0.20μm未満ではめっき鋼板をコイルに巻き取った際にめっき鋼板どうしの接触面積が大きくなり、コイル保熱の際にめっき鋼板間に焼付きが発生し、製品としての使用に耐え得るめっき表面外観が得られなくなるためである。
但し、めっき表面粗さRaの値があまり大きいとめっき表面の凹凸感が大きくなり、めっき表面外観が劣化する傾向がある。このためめっき表面粗さRaは2.0μm以下とすることが好ましい。
Here, the plating surface roughness Ra of the molten Al—Zn-based plated steel sheet is 0.20 μm or more. When the plating surface roughness Ra is less than 0.20 μm, when the plated steel sheet is wound around a coil, the plated steel sheets are separated from each other. This is because the contact area becomes large, seizure occurs between the plated steel sheets during coil heat retention, and a plated surface appearance that can withstand use as a product cannot be obtained.
However, if the value of the plating surface roughness Ra is too large, the surface roughness of the plating surface increases and the appearance of the plating surface tends to deteriorate. Therefore, the plating surface roughness Ra is preferably 2.0 μm or less.

めっき表面粗さRaを支配する要因としては、鋼板のめっき浴中への侵入板温、めっき浴温度、めっき浴組成などの他に、スパングルを形成させるめっき鋼板にあってはめっき後の冷却速度などが、スパングル模様を目立たなくさせるめっき鋼板にあってはめっき後の調質圧延の条件などが挙げられ、したがって、これらを適宜調整することによりめっき表面粗さRaが0.20μm以上のめっき皮膜を得ることができる。   Factors governing the plating surface roughness Ra include the penetration temperature of the steel sheet into the plating bath, the plating bath temperature, the plating bath composition, and the cooling rate after plating for plated steel sheets that form spangles. In the case of a plated steel sheet that makes the spangle pattern inconspicuous, conditions for temper rolling after plating, etc. can be mentioned. Therefore, by appropriately adjusting these, a plating film having a plating surface roughness Ra of 0.20 μm or more Can be obtained.

この方法では、めっき鋼板を加熱処理するために、連続溶融めっきラインの巻取装置の直前のめっき鋼板(当然、このめっき鋼板のめっき金属は凝固している)を300℃未満、好ましくは250℃以下の温度に連続加熱するが、このように連続通板するめっき鋼板を加熱するようにしたのは、コイル状態でのバッチ加熱ではコイル内外やコイルの厚み方向、板幅方向で加熱温度が不均一になりやすく、また加熱時間も長くなるのに対して、通板するめっき鋼板の連続加熱では板長手方向及び幅方向での加熱を均一に行うことができるため、めっき鋼板の加熱温度範囲を狭くすることができるからである。この結果、コイル内での温度のバラツキを低減させて均一な品質の製品を得ることができる。また、加熱昇温時間もバッチ加熱に較べて格段に短くでき、加熱処理時間の短縮化による生産の効率化が可能となる。   In this method, in order to heat-treat the plated steel sheet, the plated steel sheet immediately before the winding device of the continuous hot dipping plating line (of course, the plated metal of the plated steel sheet is solidified) is less than 300 ° C, preferably 250 ° C. Continuously heated to the following temperatures, but the plated steel sheets that are continuously passed through in this way were heated because the heating temperature was low in the coil inside and outside, in the coil thickness direction, and in the plate width direction. While it tends to be uniform and the heating time becomes longer, the continuous heating of the plated steel sheet to be passed allows uniform heating in the plate longitudinal direction and width direction. This is because it can be narrowed. As a result, it is possible to obtain a product of uniform quality by reducing temperature variations in the coil. Further, the heating temperature raising time can be remarkably shortened as compared with batch heating, and the production efficiency can be improved by shortening the heat treatment time.

通板するめっき鋼板の連続加熱の加熱方式には特に制約はなく、ガス加熱方式、電熱ヒーター方式、誘導加熱方式、蒸気加熱方式など適宜な加熱方式を採用することができるが、これらの中でも特に誘導加熱方式が鋼板幅方向の均一加熱を行う上で適している。
この連続溶融めっきラインの巻取装置直前でのめっき鋼板の加熱温度を300℃未満としているのは、加熱温度が300℃以上になるとめっき表面の粘性低下が発生し、コイルへの巻取り後、保熱中にめっき鋼板間で焼付きが発生し、製品としての使用に耐え得るめっき表面外観が得られなくなるためである。また、このような観点から加熱温度は250℃以下がより好ましい。
また、加熱温度の下限については、100℃、好ましくは150℃とすることが適当である。加熱温度が100℃未満では加熱による伸び特性の改善効果が十分に得られない。
There is no particular restriction on the heating method of continuous heating of the plated steel sheet to be passed, and an appropriate heating method such as a gas heating method, an electric heater method, an induction heating method, a steam heating method can be adopted, but among these, The induction heating method is suitable for performing uniform heating in the steel plate width direction.
The heating temperature of the plated steel sheet immediately before the winding device of this continuous hot dipping line is less than 300 ° C., when the heating temperature is 300 ° C. or more, the viscosity of the plating surface decreases, and after winding on the coil, This is because seizure occurs between the plated steel sheets during heat retention, and a plated surface appearance that can withstand use as a product cannot be obtained. From such a viewpoint, the heating temperature is more preferably 250 ° C. or lower.
Moreover, about the minimum of heating temperature, it is appropriate to set it as 100 degreeC, Preferably it is 150 degreeC. If the heating temperature is less than 100 ° C., the effect of improving the elongation characteristics by heating cannot be sufficiently obtained.

また、連続溶融めっきラインにおいてめっき鋼板をコイルに巻取る際に、コイル巻取り張力を3.0kg/mm以下とするのは、巻取り張力が3.0kg/mmを超えるとコイル内でのめっき鋼板間の接触力が大きくなり、コイル保熱時にめっき鋼板間に焼付きが発生し、製品としての使用に耐え得るめっき表面外観が得られなくなるためである。但し、コイル巻取り張力があまり低いとコイル状態に保持する力が弱まり、コイルの変形若しくは潰れが発生しやすい。このためコイル巻取り張力は0.3kg/mm以上とすることが好ましい。 In addition, when winding a plated steel sheet around a coil in a continuous hot dipping line, the coil winding tension is set to 3.0 kg / mm 2 or less when the winding tension exceeds 3.0 kg / mm 2 in the coil. This is because the contact force between the plated steel sheets increases, seizure occurs between the plated steel sheets during coil heat retention, and a plated surface appearance that can withstand use as a product cannot be obtained. However, when the coil winding tension is too low, the force for holding the coil is weakened, and the coil is likely to be deformed or crushed. For this reason, the coil winding tension is preferably 0.3 kg / mm 2 or more.

連続溶融めっきラインから取り出されためっき鋼板のコイルは、直ちにその保有熱により保熱処理される。コイルは保熱容器などに収納することなくそのまま大気下で自己保熱してもよいが、蓋付きの保熱容器などに収納して保熱すれば、保熱時間を確保できるため効率的な自己保熱を行うことができる。
巻取装置の直前で連続加熱されためっき鋼板は、一般に鋼板加熱温度マイナス10〜20℃(板温)で巻き取りを完了した後、直ちに保熱されるが、保熱開始時の板温は100℃以上、好ましくは150℃以上であって、且つ[鋼板加熱温度−50]℃以上とすることが好ましい。保熱開始温度が[鋼板加熱温度−50]℃未満では十分な伸び特性改善効果が得られない。
The coil of the plated steel sheet taken out from the continuous hot dipping line is immediately heat-treated by the retained heat. The coil may be self-heated in the atmosphere without being stored in a heat-retaining container, but if it is stored in a heat-retaining container with a lid and heat-retained, heat retention time can be ensured and efficient self-heating. Heat insulation can be performed.
In general, a plated steel sheet that is continuously heated immediately before the winding device is heated immediately after winding is completed at a steel sheet heating temperature of minus 10 to 20 ° C. (sheet temperature). It is preferable that the temperature is at least 150 ° C., preferably at least 150 ° C., and [steel plate heating temperature−50] ° C. or more. If the heat retention start temperature is less than [steel plate heating temperature−50] ° C., a sufficient effect of improving elongation characteristics cannot be obtained.

この保熱処理は5分以上行うことが好ましい。保熱時間が5分未満では保熱することによる伸び特性の改善効果が十分に得られない。また、通常300℃未満の温度に加熱されたコイルは保熱開始後24時間程度で常温となるので、保熱は24時間程度を限度に実施すればよい。
図1及び図2に、この方法で行う加熱処理の代表的な昇温・保持・冷却温度パターンを示す。このうち図1はコイルを保熱容器に収納することなく大気中で保熱した場合、図2はコイルを蓋付きの保熱容器に収納して保熱した場合の各温度パターンを示している。
This coercive heat treatment is preferably performed for 5 minutes or longer. If the heat retention time is less than 5 minutes, the effect of improving the elongation characteristics due to heat retention cannot be sufficiently obtained. In addition, since the coil heated to a temperature of less than 300 ° C. normally reaches room temperature in about 24 hours after the start of heat retention, the heat retention may be performed for about 24 hours.
FIG. 1 and FIG. 2 show typical temperature rising / holding / cooling temperature patterns of the heat treatment performed by this method. Of these, FIG. 1 shows each temperature pattern when the coil is kept in the atmosphere without being housed in the heat retaining container, and FIG. 2 shows each temperature pattern when the coil is housed in the heat retaining container with a lid and kept warm. .

図4は本発明の上記第1の方法の実施状況を模式的に示したもので、Aは連続溶融めっきライン(焼鈍炉から出側巻取装置までのライン構成)である。この連続溶融めっきラインAにおいて、焼鈍炉1を出た鋼板は溶融めっきポット2内に導かれて溶融めっきされた後、ガスワイピングノズル3によりめっき付着量が調整され、引き続き図示しない冷却帯で冷却されることによりめっき金属が完全に凝固する。このめっき鋼板は必要に応じて調質圧延などが施され、引き続き加熱装置4に導かれて300℃未満の温度に連続加熱された後、直ちに巻取装置5によりコイル巻取り張力3.0kg/mm以下でコイルxに巻き取られる。そして、このコイルxはライン外に取り出され、必要に応じて保熱容器6に入れられて、直ちにその保有熱による保熱処理が行われる。 FIG. 4 schematically shows the state of implementation of the first method of the present invention, and A is a continuous hot dipping line (a line configuration from the annealing furnace to the delivery side winding device). In this continuous hot dip plating line A, the steel plate exiting the annealing furnace 1 is led into the hot dip plating pot 2 and hot dip plated, and then the amount of plating is adjusted by the gas wiping nozzle 3 and subsequently cooled in a cooling zone (not shown). As a result, the plated metal is completely solidified. This plated steel sheet is subjected to temper rolling and the like, if necessary, continuously guided to the heating device 4 and continuously heated to a temperature of less than 300 ° C., and then immediately coiled by the winding device 5 with a coil winding tension of 3.0 kg / It is wound up on the coil x at mm 2 or less. Then, the coil x is taken out of the line, put into the heat insulating container 6 as necessary, and immediately subjected to heat retention by the retained heat.

本発明の第2の方法では、上述した第1の方法がコイルをそれ自体の保有熱により保熱処理するのに対して、コイルを加熱炉で加熱保持するものである。
すなわち、本発明の第2の方法では、連続溶融めっきラインにおいて、鋼板面にめっき表面粗さRaが0.20μm以上の溶融Al−Zn系めっき皮膜を形成するとともに、この溶融Al−Zn系めっき鋼板を連続溶融めっきラインの巻取装置の直前で300℃未満の温度に連続加熱し、コイル巻取り張力3.0kg/mm以下で巻き取った後、このコイルを加熱炉においてコイル最高温度部の板温が300℃未満になるような条件で加熱保持する。
ここで、溶融Al−Zn系めっき鋼板のめっき表面粗さRaを0.20μm以上とする理由及びめっき表面粗さRaの好ましい上限などは、先に述べた第1の方法と同様である。
In the second method of the present invention, the coil is heated and held in a heating furnace, while the first method described above retains the coil by its own retained heat.
That is, in the second method of the present invention, in a continuous hot dipping line, a hot Al—Zn plating film having a plating surface roughness Ra of 0.20 μm or more is formed on the steel plate surface, and this hot Al—Zn plating is performed. The steel sheet is continuously heated to a temperature of less than 300 ° C. just before the winding device of the continuous hot dipping line, and wound at a coil winding tension of 3.0 kg / mm 2 or less. The plate temperature is kept under heating so as to be less than 300 ° C.
Here, the reason why the plating surface roughness Ra of the molten Al—Zn-based plated steel sheet is 0.20 μm or more and the preferable upper limit of the plating surface roughness Ra are the same as in the first method described above.

この方法では、めっき鋼板を加熱処理するために、連続溶融めっきラインの巻取装置の直前のめっき鋼板(当然、このめっき鋼板のめっき金属は凝固している)を300℃未満、好ましくは250℃以下の温度に連続加熱するが、このように連続通板するめっき鋼板を加熱するようにしたのは、コイル状態でのバッチ加熱ではコイル内外やコイルの厚み方向、板幅方向で加熱温度が不均一になりやすく、また加熱時間も長くなるのに対して、通板するめっき鋼板の連続加熱では板長手方向及び幅方向での加熱を均一に行うことができるため、めっき鋼板の加熱温度範囲を狭くすることができるからである。この結果、コイル内での温度のバラツキを低減させて均一な品質の製品を得ることができる。また、加熱昇温時間もバッチ加熱に較べて格段に短くでき、加熱処理時間の短縮化による生産の効率化が可能となる。   In this method, in order to heat-treat the plated steel sheet, the plated steel sheet immediately before the winding device of the continuous hot dipping plating line (of course, the plated metal of the plated steel sheet is solidified) is less than 300 ° C, preferably 250 ° C. Continuously heated to the following temperatures, but the plated steel sheets that are continuously passed through in this way were heated because the heating temperature was low in the coil inside and outside, in the coil thickness direction, and in the plate width direction. While it tends to be uniform and the heating time becomes longer, the continuous heating of the plated steel sheet to be passed allows uniform heating in the plate longitudinal direction and width direction. This is because it can be narrowed. As a result, it is possible to obtain a product of uniform quality by reducing temperature variations in the coil. Further, the heating temperature raising time can be remarkably shortened as compared with batch heating, and the production efficiency can be improved by shortening the heat treatment time.

通板するめっき鋼板の連続加熱の加熱方式には特に制約はなく、ガス加熱方式、電熱ヒーター方式、誘導加熱方式、蒸気加熱方式など適宜な加熱方式を採用することができるが、これらの中でも特に誘導加熱方式が鋼板幅方向の均一加熱を行う上で適している。
この連続溶融めっきラインの巻取装置直前でのめっき鋼板の加熱温度を300℃未満としているのは、加熱温度が300℃以上になるとめっき表面の粘性低下が発生し、コイルへの巻取り後、保熱中にめっき鋼板間で焼付きが発生し、製品としての使用に耐え得るめっき表面外観が得られなくなるためである。また、このような観点から加熱温度は250℃以下がより好ましい。
また、加熱温度の下限については、100℃、好ましくは150℃とすることが適当である。加熱温度が100℃未満では加熱による伸び特性の改善効果が十分に得られない。
There is no particular restriction on the heating method of continuous heating of the plated steel sheet to be passed, and an appropriate heating method such as a gas heating method, an electric heater method, an induction heating method, a steam heating method can be adopted, but among these, The induction heating method is suitable for performing uniform heating in the steel plate width direction.
The heating temperature of the plated steel sheet immediately before the winding device of this continuous hot dipping line is less than 300 ° C., when the heating temperature is 300 ° C. or more, the viscosity of the plating surface decreases, and after winding on the coil, This is because seizure occurs between the plated steel sheets during heat retention, and a plated surface appearance that can withstand use as a product cannot be obtained. From such a viewpoint, the heating temperature is more preferably 250 ° C. or lower.
Moreover, about the minimum of heating temperature, it is appropriate to set it as 100 degreeC, Preferably it is 150 degreeC. If the heating temperature is less than 100 ° C., the effect of improving the elongation characteristics by heating cannot be sufficiently obtained.

また、連続溶融めっきラインにおいてめっき鋼板をコイルに巻取る際に、コイル巻取り張力を3.0kg/mm以下とするのは、巻取り張力が3.0kg/mmを超えるとコイル内でのめっき鋼板間の接触力が大きくなり、コイル保熱時にめっき鋼板間に焼付きが発生し、製品としての使用に耐え得るめっき表面外観が得られなくなるためである。但し、コイル巻取り張力があまり低いとコイル状態に保持する力が弱まり、コイルの変形若しくは潰れが発生しやすい。このためコイル巻取り張力は0.3kg/mm以上とすることが好ましい。 In addition, when winding a plated steel sheet around a coil in a continuous hot dipping line, the coil winding tension is set to 3.0 kg / mm 2 or less when the winding tension exceeds 3.0 kg / mm 2 in the coil. This is because the contact force between the plated steel sheets increases, seizure occurs between the plated steel sheets during coil heat retention, and a plated surface appearance that can withstand use as a product cannot be obtained. However, when the coil winding tension is too low, the force for holding the coil is weakened, and the coil is likely to be deformed or crushed. For this reason, the coil winding tension is preferably 0.3 kg / mm 2 or more.

連続溶融めっきラインからめっき鋼板のコイルを取り出した後、直ちに加熱炉においてコイル最高温度部の板温が300℃未満となるような条件で加熱保持する。先に述べた本発明の第1の方法のようにコイルをそれ自体の保有熱により保熱する方法では、コイル内外周やコイルエッジで温度低下が起こり易く、その部分の加熱が不足するおそれがあるが、この方法によればこのようなコイル内での温度が不均一化を生じることなく、加熱処理を行うことができる。   After the coil of the plated steel sheet is taken out from the continuous hot dipping line, it is immediately heated and maintained in a heating furnace under the condition that the plate temperature of the coil maximum temperature portion is less than 300 ° C. In the method of keeping the coil by its own retained heat as in the first method of the present invention described above, the temperature is likely to decrease at the inner and outer periphery of the coil and the coil edge, and there is a risk that the heating of the portion will be insufficient. However, according to this method, the heat treatment can be performed without causing the temperature in the coil to be non-uniform.

使用する加熱炉としては簡易なものでよく、またその加熱方式にも特に制約はない。したがって、ガス加熱方式、電熱ヒーター方式、誘導加熱方式、蒸気加熱方式など適宜な加熱方法を採用することができる。また、加熱炉は密閉型でも開放型でもよい。
巻取装置の直前で連続加熱されためっき鋼板は、一般に鋼板加熱温度マイナス10〜20℃(板温)で巻き取りを完了した後、直ちに加熱炉に装入されて加熱保持されるが、加熱保持開始時の板温は100℃以上、好ましくは150℃以上であって、且つ[鋼板加熱温度−50]℃以上とすることが好ましい。保熱開始温度が[鋼板加熱温度−50]℃未満では十分な伸び特性改善効果が得られない。
The heating furnace to be used may be simple, and the heating method is not particularly limited. Therefore, an appropriate heating method such as a gas heating method, an electric heater method, an induction heating method, or a steam heating method can be employed. The heating furnace may be a closed type or an open type.
The plated steel sheet that has been continuously heated immediately before the winding device is generally charged in a heating furnace immediately after completion of winding at a steel sheet heating temperature of minus 10 to 20 ° C. (sheet temperature). The plate temperature at the start of holding is 100 ° C. or higher, preferably 150 ° C. or higher, and [steel plate heating temperature−50] ° C. or higher. If the heat retention start temperature is less than [steel plate heating temperature−50] ° C., a sufficient effect of improving elongation characteristics cannot be obtained.

加熱炉内での加熱保持では、コイル最高温度部の板温が300℃未満の範囲内であれば、コイルを昇温させてもよいし、加熱保持開始温度のまま保持してもよい。また、場合によっては緩い温度降下を生じるような加熱保持であってもよい。
この加熱炉内での加熱保持温度をコイル最高温度部の板温で300℃未満としているのは、コイル最高温度部の板温が300℃以上になるとめっき表面の粘性低下が発生し、加熱保持中にめっき鋼板間で焼付きが発生し、製品としての使用に耐え得るめっき表面外観が得られなくなるためである。また、このような観点からコイル最高温度部の板温は250℃以下がより好ましい。
In the heating and holding in the heating furnace, if the plate temperature of the coil maximum temperature portion is within the range of less than 300 ° C., the coil may be heated or may be held at the heating and holding start temperature. Further, in some cases, the heating and holding may cause a gentle temperature drop.
The heating and holding temperature in the heating furnace is set to a temperature lower than 300 ° C. at the coil maximum temperature portion. When the plate temperature at the coil maximum temperature portion is 300 ° C. or more, the viscosity of the plating surface is lowered, and the heating is held. This is because seizure occurs between the plated steel sheets, and a plated surface appearance that can withstand use as a product cannot be obtained. From such a viewpoint, the plate temperature of the coil maximum temperature portion is more preferably 250 ° C. or less.

この加熱保持は5分以上、24時間以内で行うことが好ましい。加熱保持時間が5分未満では十分な伸び特性改善効果が得られず、一方、24時間を超えるとめっき鋼板間の焼付きが発生しやすくなり、また生産性も低下する。
図3に、この方法で行う加熱処理の代表的な昇温・保持・冷却温度パターンを示す。
This heating and holding is preferably performed for 5 minutes or more and within 24 hours. If the heating and holding time is less than 5 minutes, a sufficient effect of improving the elongation characteristics cannot be obtained. On the other hand, if it exceeds 24 hours, seizure between the plated steel sheets tends to occur, and the productivity also decreases.
FIG. 3 shows a typical temperature rise / hold / cooling temperature pattern of the heat treatment performed by this method.

図5は本発明の上記第2の方法の実施状況を模式的に示したものである。この方法では、連続溶融めっきラインAにおいて、焼鈍炉1を出た鋼板は溶融めっきポット2内に導かれて溶融めっきされた後、ガスワイピングノズル3によりめっき付着量が調整され、引き続き図示しない冷却帯で冷却されることによりめっき金属が完全に凝固する。めっき鋼板は必要に応じて調質圧延などが施され、引き続き加熱装置4に導かれて300℃未満の温度に連続加熱された後、直ちに巻取装置5によりコイル巻取り張力3.0kg/mm以下でコイルxに巻き取られる。そして、このコイルxはライン外に取り出されて、加熱炉9に装入され、コイル最高温度部の板温が300℃未満となるような条件で加熱保持が行われる。 FIG. 5 schematically shows the implementation status of the second method of the present invention. In this method, in the continuous hot dipping line A, after the steel plate exiting the annealing furnace 1 is led into the hot dipping pot 2 and hot dipped, the amount of plating is adjusted by the gas wiping nozzle 3, and the cooling not shown is continued. The plated metal is completely solidified by being cooled in the strip. The plated steel sheet is subjected to temper rolling and the like as necessary, and is subsequently guided to the heating device 4 and continuously heated to a temperature of less than 300 ° C., and immediately thereafter, the coil winding tension is 3.0 kg / mm by the winding device 5. It is wound around the coil x at 2 or less. The coil x is taken out of the line and inserted into the heating furnace 9, and is heated and held under such a condition that the plate temperature of the coil maximum temperature portion is less than 300 ° C.

本発明法により製造されるめっき鋼板は、めっき表面にスパングルを形成してもよいし、またスパングル模様を目立たなくさせるようにしてもよい。一般に、めっき表面にスパングルを有するめっき鋼板はその外観性から裸使用する用途に、また、めっき表面のスパングル模様を目立たなくさせためっき鋼板は塗装下地用途に、それぞれ適している。
めっき表面のスパングル模様を目立たなくさせるには、常法に従ってめっき後に調質圧延などを実施すればよい。
In the plated steel sheet produced by the method of the present invention, spangles may be formed on the plating surface, or the spangle pattern may be made inconspicuous. In general, a plated steel sheet having spangles on the plating surface is suitable for a bare use because of its appearance, and a plated steel sheet having a spangle pattern on the plating surface made inconspicuous is suitable for a coating base application.
In order to make the spangle pattern on the plating surface inconspicuous, temper rolling or the like may be performed after plating according to a conventional method.

[実施例1]
常法で製造した冷延鋼板(板厚0.5mm)を連続式溶融めっき設備に通板し、55mass%Al−1.5mass%Si−Znめっき浴を用いて溶融めっきを行い、溶融Al−Zn系めっき鋼板を製造した。連続式溶融めっき設備では、めっき金属が凝固しためっき鋼板を巻取装置直前で加熱装置(誘導加熱方式)により連続加熱した後、コイルに巻き取った。次いで、このコイルを大気中で所定時間保熱処理し、溶融Al−Zn系めっき鋼板の製品とした。
なお、溶融めっきラインのラインスピードは160m/secとし、片面めっき付着量はめっき鋼板間でのバラツキが75〜90g/mの範囲内に収まるようにした。
[Example 1]
A cold-rolled steel sheet (thickness 0.5 mm) manufactured by a conventional method is passed through a continuous hot-dip plating facility, hot-dip plated using a 55 mass% Al-1.5 mass% Si-Zn plating bath, and molten Al- A Zn-based plated steel sheet was produced. In a continuous hot dip plating facility, a plated steel sheet with solidified plating metal was continuously heated by a heating device (induction heating method) immediately before the winding device, and then wound on a coil. Next, this coil was heat-treated in the atmosphere for a predetermined time to obtain a product of a molten Al—Zn-based plated steel sheet.
The line speed of the hot dipping line was 160 m / sec, and the amount of single-sided plating was such that the variation between the plated steel sheets was within the range of 75 to 90 g / m 2 .

得られた製品について、下記の方法に基づいて焼付け発生の有無、めっき表面外観及び伸び特性を評価した。その結果を、溶融めっき条件、保熱条件、めっき皮膜の構成とともに表1及び表2に示す。
なお、表1に示す各実施例(本発明例及び比較例)では、加熱処理前に調質圧延を実施することによりめっき表面のスパングル模様を目立たなくさせためっき鋼板を、また表2に示す各実施例(本発明例及び比較例)でめっき表面にスパングルを有するめっき鋼板を、それぞれ製造した。
(1) 焼付けの発生の有無
加熱処理後のコイル巻き戻し時において、めっき鋼板どうしが剥がれる際に発生する音の有無により、下記の通り焼付け発生の有無を評価した。
無し:コイル巻き戻し時にバリバリという音が発生しない。
発生:コイル巻き戻し時にバリバリという音が発生する。
About the obtained product, the presence or absence of baking, the appearance of the plating surface, and the elongation characteristics were evaluated based on the following methods. The results are shown in Table 1 and Table 2 together with the hot-dip plating conditions, the heat retention conditions, and the structure of the plating film.
In addition, in each Example (invention example and comparative example) shown in Table 1, a plated steel sheet in which the spangle pattern on the plating surface is made inconspicuous by performing temper rolling before the heat treatment is also shown in Table 2. In each example (invention example and comparative example), a plated steel sheet having spangles on the plating surface was produced.
(1) Presence or absence of seizure The presence or absence of seizure was evaluated according to the presence or absence of sound generated when the plated steel sheets peeled off during coil rewinding after heat treatment.
None: No buzzing sound is generated when the coil is rewound.
Generation: A buzzing sound is generated when the coil is rewound.

(2) めっき表面外観
加熱処理後のめっき鋼板の表面外観を目視観察し、下記の通りに評価した。
良い:めっき表面は加熱処理前と変化がなく、美麗なめっき表面外観を有する。
悪い:コイル総面積の1%以上の部分に、めっき鋼板間の焼付けによるめっき剥離又は溶着が発生し、劣悪なめっき表面外観を有する。
(2) Plating surface appearance The surface appearance of the plated steel sheet after the heat treatment was visually observed and evaluated as follows.
Good: The plated surface is the same as before the heat treatment and has a beautiful plated surface appearance.
Poor: Plating peeling or welding due to baking between plated steel sheets occurs in a portion of 1% or more of the total coil area, resulting in a poor plated surface appearance.

(3) 伸び特性
JIS Z 2201(1998)金属材料引張試験片に規定されている5号試験片を用いて、JIS Z 2241(1998)金属材料引張試験方法により試験を行い、破断時全伸びにより評価した。具体的な評価方法としては、加熱処理を行う前の鋼板のめっき破断時全伸びに対する破断時全伸びの増加量(%)で評価を行った。
(3) Elongation characteristics Using the No. 5 test piece defined in JIS Z 2201 (1998) metal material tensile test piece, the test was conducted by JIS Z 2241 (1998) metal material tensile test method, and the total elongation at break evaluated. As a specific evaluation method, evaluation was performed by an increase amount (%) of the total elongation at break relative to the total elongation at the time of plating fracture of the steel plate before the heat treatment.

Figure 0004087800
Figure 0004087800

Figure 0004087800
Figure 0004087800

[実施例2]
常法で製造した冷延鋼板(板厚0.5mm)を連続式溶融めっき設備に通板し、55mass%Al−1.5mass%Si−Znめっき浴を用いて溶融めっきを行い、溶融Al−Zn系めっき鋼板を製造した。連続式溶融めっき設備では、めっき金属が凝固しためっき鋼板を巻取装置直前で加熱装置(誘導加熱方式)により連続加熱した後、コイルに巻き取った。次いで、このコイルを簡易加熱炉(電熱ヒーター方式)で所定時間加熱保持し、溶融Al−Zn系めっき鋼板の製品とした。
なお、溶融めっきラインのラインスピードは160m/secとし、片面めっき付着量はめっき鋼板間でのバラツキが75〜90g/mの範囲内に収まるようにした。
[Example 2]
A cold-rolled steel sheet (thickness 0.5 mm) manufactured by a conventional method is passed through a continuous hot-dip plating facility, hot-dip plated using a 55 mass% Al-1.5 mass% Si-Zn plating bath, and molten Al- A Zn-based plated steel sheet was produced. In a continuous hot dip plating facility, a plated steel sheet with solidified plating metal was continuously heated by a heating device (induction heating method) immediately before the winding device, and then wound on a coil. Next, this coil was heated and held for a predetermined time in a simple heating furnace (electric heater system) to obtain a product of a molten Al—Zn-based plated steel sheet.
The line speed of the hot dipping line was 160 m / sec, and the amount of single-sided plating was such that the variation between the plated steel sheets was within the range of 75 to 90 g / m 2 .

得られた製品について、[実施例1]と同様の方法に基づいて焼き付け発生の有無、表面外観及び伸び特性を評価した。その結果を、溶融めっき条件、タイトコイル加熱処理条件、めっき皮膜の構成とともに表3及び表4に示す。
なお、表3に示す各実施例(本発明例及び比較例)では、加熱処理前に調質圧延を実施することにより、めっき表面のスパングルを目立たなくさせためっき鋼板を、また表4に示す各実施例(本発明例及び比較例)ではめっき表面にスパングルを有するめっき鋼板を、それぞれ製造した。
About the obtained product, the presence or absence of baking, surface appearance, and elongation characteristics were evaluated based on the same method as in [Example 1]. The results are shown in Tables 3 and 4 together with the hot dipping conditions, tight coil heat treatment conditions, and the configuration of the plating film.
In addition, in each Example (invention example and comparative example) shown in Table 3, a plated steel sheet in which spangles on the plating surface are made inconspicuous by performing temper rolling before heat treatment is shown in Table 4. In each example (invention example and comparative example), a plated steel sheet having spangles on the plating surface was produced.

Figure 0004087800
Figure 0004087800

Figure 0004087800
Figure 0004087800

本発明の第1の方法で行う加熱処理の代表的な昇温・保持・冷却温度パターンを示す説明図Explanatory drawing which shows the typical temperature rising / holding / cooling temperature pattern of the heat treatment performed by the first method of the present invention. 本発明の第1の方法で行う加熱処理の代表的な昇温・保持・冷却温度パターンを示す説明図Explanatory drawing which shows the typical temperature rising / holding / cooling temperature pattern of the heat treatment performed by the first method of the present invention. 本発明の第2の方法で行う加熱処理の代表的な昇温・保持・冷却温度パターンを示す説明図Explanatory drawing which shows the typical temperature rising / holding / cooling temperature pattern of the heat treatment performed by the second method of the present invention. 本発明の第1の方法の実施状況を模式的に示す説明図Explanatory drawing which shows typically the implementation condition of the 1st method of this invention 本発明の第2の方法の実施状況を模式的に示す説明図Explanatory drawing which shows typically the implementation condition of the 2nd method of this invention

符号の説明Explanation of symbols

1…焼鈍炉、2…溶融めっきポット、3…ガスワイピングノズル、4…加熱装置、5…巻取装置、6…保熱容器、9…加熱炉、A…連続溶融めっきライン、B…連続処理設備、   DESCRIPTION OF SYMBOLS 1 ... Annealing furnace, 2 ... Hot-dipping pot, 3 ... Gas wiping nozzle, 4 ... Heating device, 5 ... Winding device, 6 ... Thermal insulation container, 9 ... Heating furnace, A ... Continuous hot-dipping line, B ... Continuous treatment Facility,

Claims (2)

めっき皮膜中のAl含有量が20〜95mass%である溶融Al−Zn系めっき鋼板の製造方法であって、めっき金属が凝固した後の溶融Al−Zn系めっき鋼板を加熱処理することにより伸び特性の改善を図る方法において、
めっき表面粗さRaが0.20μm以上2.0μm以下のめっき皮膜が形成された溶融Al−Zn系めっき鋼板を、連続溶融めっきラインの巻取装置の直前で100℃以上300℃未満の温度に連続加熱し、コイル巻取り張力0.3kg/mm 以上3.0kg/mm以下、鋼板加熱温度マイナス10〜20℃(板温)で巻き取った後、該コイルをその保有熱により保熱開始時の板温を100℃以上であって、且つ前記連続加熱での鋼板加熱温度−50℃以上として自己保熱することを特徴とする溶融Al−Zn系めっき鋼板の製造方法。
It is a manufacturing method of the fusion | melting Al-Zn type plated steel plate whose Al content in a plating film is 20-95 mass%, Comprising: Elongation characteristics by heat-processing the molten Al-Zn type plated steel plate after a metal plating solidifies In the method of improving
A hot-dip Al-Zn-based plated steel sheet on which a plating film having a plating surface roughness Ra of 0.20 μm or more and 2.0 μm or less is formed at a temperature of 100 ° C. or more and less than 300 ° C. immediately before the winding device of the continuous hot dipping plating line. continuously heating, heat retaining coil winding tension 0.3 kg / mm 2 or more 3.0 kg / mm 2 or less, after winding of a steel plate heating temperature minus 10 to 20 ° C. (sheet temperature), by the potential heat of the coil A method for producing a molten Al—Zn-plated steel sheet, wherein self- heating is carried out at a starting plate temperature of 100 ° C. or higher and a steel plate heating temperature in the continuous heating of −50 ° C. or higher .
めっき皮膜中のAl含有量が20〜95mass%である溶融Al−Zn系めっき鋼板の製造方法であって、めっき金属が凝固した後の溶融Al−Zn系めっき鋼板を加熱処理することにより伸び特性の改善を図る方法において、
めっき表面粗さRaが0.20μm以上2.0μm以下のめっき皮膜が形成された溶融Al−Zn系めっき鋼板を、連続溶融めっきラインの巻取装置の直前で100℃以上300℃未満の温度に連続加熱し、コイル巻取り張力0.3kg/mm 以上3.0kg/mm以下、鋼板加熱温度マイナス10〜20℃(板温)で巻き取った後、該コイルを加熱炉においてコイル最高温度部の板温が100℃以上300℃未満、加熱保持開始時の板温が100℃以上であって、且つ前記連続加熱での鋼板加熱温度−50℃以上になるような条件で加熱保持することを特徴とする溶融Al−Zn系めっき鋼板の製造方法。
It is a manufacturing method of the fusion | melting Al-Zn type plated steel plate whose Al content in a plating film is 20-95 mass%, Comprising: Elongation characteristics by heat-processing the molten Al-Zn type plated steel plate after a metal plating solidifies In the method of improving
A hot-dip Al-Zn-based plated steel sheet on which a plating film having a plating surface roughness Ra of 0.20 μm or more and 2.0 μm or less is formed at a temperature of 100 ° C. or more and less than 300 ° C. immediately before the winding device of the continuous hot dipping plating line. continuously heating, coil winding tension 0.3 kg / mm 2 or more 3.0 kg / mm 2 or less, after winding of a steel plate heating temperature minus 10 to 20 ° C. (sheet temperature), the coil maximum temperature in a heating furnace to the coil Heating and holding under such conditions that the plate temperature of the part is 100 ° C. or higher and lower than 300 ° C., the plate temperature at the start of heating and holding is 100 ° C. or higher, and the steel plate heating temperature in the continuous heating is −50 ° C. or higher. The manufacturing method of the fusion | melting Al-Zn type plated steel plate characterized by these.
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