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JP3671477B2 - Cleaning method for submerged membrane separator - Google Patents

Cleaning method for submerged membrane separator Download PDF

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Publication number
JP3671477B2
JP3671477B2 JP28915095A JP28915095A JP3671477B2 JP 3671477 B2 JP3671477 B2 JP 3671477B2 JP 28915095 A JP28915095 A JP 28915095A JP 28915095 A JP28915095 A JP 28915095A JP 3671477 B2 JP3671477 B2 JP 3671477B2
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JP
Japan
Prior art keywords
membrane
bubbles
membrane element
cleaning
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP28915095A
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Japanese (ja)
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JPH09103661A (en
Inventor
邦博 岩崎
和夫 鈴木
保彦 石井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kurita Water Industries Ltd
Original Assignee
Kurita Water Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to JP28915095A priority Critical patent/JP3671477B2/en
Publication of JPH09103661A publication Critical patent/JPH09103661A/en
Application granted granted Critical
Publication of JP3671477B2 publication Critical patent/JP3671477B2/en
Anticipated expiration legal-status Critical
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Description

【0001】
【発明の属する技術分野】
この発明は、平膜、中空糸膜、管状膜などの膜を本体に取付け、膜を透過する透過水を本体の内部に得る膜エレメントを使用した浸漬型膜分離装置の洗浄方法に関する。
【0002】
【従来の技術】
このような浸漬型膜分離装置として、処理槽内の原水中に、所定の間隔を保って複数の膜エレメントを立て並べ、各膜エレメントの採水口にヘッダー管を介して吸引ポンプを接続し、槽底に微細気泡を噴出する散気管を敷設し、散気管が噴出する微細気泡のエアリフト作用により膜エレメントの間隔に膜に接触して流れる上昇流を生じさせ、前記吸引ポンプの吸引作用で原水中の透過水を各膜エレメントの内部に吸引し、採水口、及びヘッダー管を介して採水するようにしたものは従来から公知である。
【0003】
【発明が解決しようとする課題】
上記従来装置において、散気管から微細気泡を噴出させる目的の1つは、微細気泡の剪断力によって膜の表面に汚染物質が付着するのを防止するためであるが、原水が多量のMLSSを含んでいる場合は、運転の継続により膜の表面に次第に汚染物質が付着し、膜の濾過性能は低下する。そして、濾過性能が或る程度低下したら、膜エレメントを処理槽の外に引出し、薬液で膜の表面を洗浄し、付着している汚染物質を剥離除去する必要があるが、それには非常に手数がかゝる。
【0004】
【課題を解決するための手段】
この発明は、上述した問題点を解消するためのもので、処理槽内の原水中に、所定の間隔を保って複数の膜エレメントを立て並べ、各膜エレメントの採水口と吸引ポンプを接続し、槽底に微細気泡を噴出する微細気泡用散気管を敷設し、該微細気泡用散気管が噴出する微細気泡のエアリフト作用により膜エレメントの間隔に膜に接触して流れる上昇流を生じさせ、前記吸引ポンプの吸引作用で原水中の透過水を各膜エレメントの内部に吸引し、採水口を介して採水する浸漬型膜分離装置の洗浄方法において、各膜エレメントの内部に洗浄薬液を注入し、膜の外に浸出させる洗浄薬液の加圧注入手段と、槽底に粗大気泡を噴出する粗大気泡用散気管を設け、該吸引ポンプの停止中に、該洗浄薬液の加圧注入手段により洗浄薬液を各膜エレメントの内部に加圧注入して膜の外に浸出させると同時に、該粗大気泡用散気管から粗大気泡を噴出させることを特徴とする。
【0005】
図示の実施形態において、1は有機物を含む原水が供給される活性汚泥処理装置の処理槽で、活性汚泥は浮遊する槽内の水中にエアリフト筒2を立設し、このエアリフト筒上に透過水の採水口4を有する複数枚の平膜エレメント3を前後方向に間隔を保って一列に立て並べてある。エアリフト筒の内部下方にはブロアBから供給される空気を微細気泡にして噴出する微細気泡用散気管5と、粗大気泡にして噴出する粗大気泡用散気管6とが弁で切換えて散気するように敷設してある。
【0006】
膜濾過運転を行う際は、微細気泡用散気管5から微細気泡を散気する。これによって原水の有機物を分解する活性汚泥の活性を高め、同時に平膜エレメント3の相対向した膜の間隔に微細気泡のエアリフト作用で膜に接触して流れる上昇流を生じさせ、気泡の剪断作用によって膜の表面にゲル状の汚染物質が付着するのを防止しながら膜を透過する透過水を平膜エレメントの本体の内部に得、この透過水を各平膜エレメントの採水口4に接続したヘッダー管7を介しポンプP1 で吸引して採水する。
【0007】
ヘッダー管7にはタンク8中の洗浄薬液をポンプP2 で加圧して供給する薬注管9が接続してあり、このタンク8、薬注管9、ポンプP2 は洗浄薬液の加圧注入手段10を構成する。薬注管9と、採水用ポンプP1 の上流には弁を設け、膜濾過運転中は注入管の弁を閉にしておく。
【0008】
膜の表面に汚染物質が付着し、膜の濾過性能が低下して来たら、ポンプP1 を停めると共に、ポンプ側の弁を閉じ、薬注管9の弁を開き、ポンプP2 を運転してタンク8内の洗浄薬液を薬注管9、ヘッダー管7を介して各平膜エレメントの本体の内部に加圧して注入する。勿論、水頭差で注入しても良い。使用する洗浄薬液は、次亜塩素酸ナトリウム、水酸化ナトリウム、硫酸、過酸化水素などである。同時に粗大気泡用散気管6から粗大気泡を散気する。
【0009】
これにより、膜エレメントの内部に加圧して注入された洗浄薬液は膜を透過して膜の表面に浸出し、膜の表面に付着した汚染物質と接触して化学変化し、汚染物質の膜に対する付着力を低下させる。そして、膜に接触して上昇する粗大気泡が、その大きな剪断力で、付着力を低下した汚染物質を膜から剥離し、除去する。洗浄薬液による洗浄を所定時間行ったら、ポンプP2 を停め、薬注管の弁を閉じ、ポンプP1 を運転し、微細気泡を微細気泡用散気管5から散気して膜濾過運転を再開する。
【0010】
本発明の実施形態は、平膜エレメントで説明したが、四角形の枠組みに中空糸膜をのれん状に取付けた膜エレメントを立て並べたものでも良く、管状膜を同様に取付けた膜エレメントを立て並べたものでも良い。
又、微細気泡と粗大気泡の散気管を別々としたが両方の機能を兼ね備えた散気管の一種類でも良い。この場合、散気管に供給する空気量を増減することにより対処する。
【0011】
【発明の効果】
以上で明らかなように、本発明によれば膜エレメントの内部に洗浄薬液を加圧注入して膜の表面に付着する汚染物質の付着力を弱め、粗大気泡の大きな剪断力で汚染物質を膜の表面から剥離して除去するので、洗浄が容易に行え、且つ洗浄効果が大である。
【図面の簡単な説明】
【図1】Aは本発明の一実施形態の断面図、Bはその洗浄中の状態の断面図である。
【符号の説明】
1 処理槽
2 エアリフト筒
3 膜エレメント
4 膜エレメントの採水口
5 微細気泡用散気管
6 粗大気泡用散気管
7 ヘッダー管
8 タンク
9 薬注管
10 洗浄薬液の加圧注入手段
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for cleaning an immersion type membrane separation apparatus using a membrane element in which a membrane such as a flat membrane, a hollow fiber membrane, a tubular membrane or the like is attached to a main body and permeate passing through the membrane is obtained inside the main body.
[0002]
[Prior art]
As such a submerged membrane separator, in the raw water in the treatment tank, a plurality of membrane elements are arranged side by side with a predetermined interval, and a suction pump is connected to the water sampling port of each membrane element via a header pipe, A diffuser pipe for ejecting fine bubbles is laid at the bottom of the tank, and an upward flow that flows in contact with the membrane is generated in the space between the membrane elements by the air lift action of the fine bubbles ejected by the diffuser pipe. Conventionally known is a method in which permeated water in water is sucked into each membrane element and collected through a water sampling port and a header pipe.
[0003]
[Problems to be solved by the invention]
In the above conventional apparatus, one of the purposes of ejecting fine bubbles from the air diffuser is to prevent the contaminants from adhering to the membrane surface due to the shear force of the fine bubbles, but the raw water contains a large amount of MLSS. In such a case, contaminants gradually adhere to the surface of the membrane as the operation continues, and the filtration performance of the membrane decreases. When the filtration performance is reduced to some extent, it is necessary to draw the membrane element out of the treatment tank, clean the surface of the membrane with a chemical solution, and peel off and remove the attached contaminants. I'm angry.
[0004]
[Means for Solving the Problems]
This invention is for solving the above-mentioned problems. A plurality of membrane elements are arranged in a row at a predetermined interval in raw water in a treatment tank, and a water sampling port of each membrane element is connected to a suction pump. , laid sparge tube for micro bubbles for ejecting microbubbles in the bottom of the tank, diffusing pipe for the fine air bubbles cause upward flow flowing in contact with the film to the spacing of the membrane element by air lift action of the micro-bubbles ejected, In the cleaning method of the submerged membrane separation device , the permeated water in the raw water is sucked into each membrane element by the suction action of the suction pump, and the cleaning chemical solution is injected into each membrane element in the cleaning method of collecting water through the sampling port. and, a pressure injection means of the cleaning chemical liquid to leach out of the membrane, provided a sparge tube for coarse bubble for ejecting coarse bubbles tank bottom, during the stop of the suction pump, the cleaning chemical liquid pressure injection means By using the cleaning chemical solution for each membrane element Inside at the same time under pressure injected leach out of the membrane, characterized in that for ejecting coarse bubbles from the diffusing pipe for crude large bubbles.
[0005]
In the illustrated embodiment, reference numeral 1 denotes a treatment tank of an activated sludge treatment apparatus to which raw water containing organic matter is supplied. Activated sludge has an air lift cylinder 2 standing in water in a floating tank, and permeate water is placed on the air lift cylinder. A plurality of flat membrane elements 3 each having a water sampling port 4 are arranged in a line at intervals in the front-rear direction. In the lower part of the air lift cylinder, a fine bubble diffusing pipe 5 that blows out air supplied from the blower B as fine bubbles and a coarse bubble diffusing pipe 6 that blows out as coarse bubbles are switched by a valve and diffused. It is laid like this.
[0006]
When performing the membrane filtration operation, fine bubbles are diffused from the fine bubble diffusing tube 5. This enhances the activity of the activated sludge that decomposes the organic matter in the raw water, and at the same time, creates an upward flow that flows in contact with the membrane by the air lift action of the fine bubbles in the space between the opposed membranes of the flat membrane element 3, thereby shearing the bubbles The permeated water that permeates the membrane while preventing gel-like contaminants from adhering to the surface of the membrane is obtained inside the main body of the flat membrane element, and this permeated water is connected to the water sampling port 4 of each flat membrane element. The water is drawn through the header pipe 7 with the pump P1.
[0007]
The header pipe 7 is connected to a chemical injection pipe 9 for supplying the cleaning chemical liquid in the tank 8 by pressurizing it with a pump P2, and the tank 8, the chemical injection pipe 9 and the pump P2 are provided with pressure injection means 10 for the cleaning chemical liquid. Configure. A valve is provided upstream of the drug injection tube 9 and the water sampling pump P1, and the valve of the injection tube is closed during the membrane filtration operation.
[0008]
If contaminants adhere to the surface of the membrane and the filtration performance of the membrane deteriorates, the pump P1 is stopped, the valve on the pump side is closed, the valve of the medicinal tube 9 is opened, and the pump P2 is operated to operate the tank. The cleaning chemical solution in 8 is pressurized and injected into the main body of each flat membrane element through the chemical injection tube 9 and the header tube 7. Of course, you may inject | pour with a water head difference. The cleaning chemicals used are sodium hypochlorite, sodium hydroxide, sulfuric acid, hydrogen peroxide and the like. At the same time, the coarse bubbles are diffused from the coarse bubble diffusion tube 6.
[0009]
As a result, the cleaning chemical injected under pressure inside the membrane element permeates the membrane and leaches out to the surface of the membrane, and comes into contact with the contaminant adhering to the surface of the membrane to chemically change, thereby causing the contaminant to the membrane. Reduce adhesion. Then, the coarse bubbles rising in contact with the film peel off and remove the pollutants whose adhesion has been reduced by the large shearing force. When the cleaning with the cleaning chemical solution is performed for a predetermined time, the pump P2 is stopped, the valve of the chemical injection pipe is closed, the pump P1 is operated, the fine bubbles are diffused from the fine bubble diffusing pipe 5, and the membrane filtration operation is resumed.
[0010]
Although the embodiment of the present invention has been described with respect to the flat membrane element, a membrane element in which hollow fiber membranes are attached in a good shape in a square frame may be arranged side by side. It may be good.
Further, although the fine bubble and coarse bubble diffuser tubes are separated, one type of diffuser tube having both functions may be used. In this case, this is dealt with by increasing or decreasing the amount of air supplied to the air diffuser.
[0011]
【The invention's effect】
As apparent from the above, according to the present invention, the cleaning chemical solution is pressurized and injected into the membrane element to weaken the adhesion of the contaminants adhering to the surface of the membrane, and the contaminants are removed from the membrane by a large shear force of coarse bubbles. Since it is peeled off and removed from the surface, cleaning can be performed easily and the cleaning effect is great.
[Brief description of the drawings]
FIG. 1A is a cross-sectional view of an embodiment of the present invention, and B is a cross-sectional view showing a state during cleaning.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Treatment tank 2 Air lift cylinder 3 Membrane element 4 Membrane element sampling port 5 Air bubble pipe for fine bubbles 6 Air diffuser pipe for coarse bubbles 7 Header pipe 8 Tank 9 Chemical injection pipe 10 Pressure injection means for cleaning chemical liquid

Claims (1)

処理槽内の原水中に、所定の間隔を保って複数の膜エレメントを立て並べ、各膜エレメントの採水口と吸引ポンプを接続し、槽底に微細気泡を噴出する微細気泡用散気管を敷設し、該微細気泡用散気管が噴出する微細気泡のエアリフト作用により膜エレメントの間隔に膜に接触して流れる上昇流を生じさせ、前記吸引ポンプの吸引作用で原水中の透過水を各膜エレメントの内部に吸引し、採水口を介して採水する浸漬型膜分離装置の洗浄方法において、各膜エレメントの内部に洗浄薬液の加圧注入手段と、槽底に粗大気泡を噴出する粗大気泡用散気管を設け、該吸引ポンプの停止中に、該洗浄薬液の加圧注入手段により洗浄薬液を各膜エレメントの内部に加圧注入して膜の外に浸出させると同時に、該粗大気泡用散気管から粗大気泡を噴出させることを特徴とする浸漬型膜分離装置の洗浄方法。 Laying the raw water in the treatment tank, arranged vertically a plurality of membrane elements with a predetermined interval to connect the water inlet and the suction pump adopted for each membrane element, the sparge tube for micro bubbles for ejecting microbubbles into the tank bottom and, the fine bubbles for diffusing tube is caused to rise stream flowing in contact with the film to the spacing of the membrane element by air lift action of the micro-bubbles ejected, the suction pump each membrane element the permeate in the raw water in the suction action of In the cleaning method of the submerged membrane separator that sucks into the inside of the membrane and collects water through the sampling port, for each of the large bubbles that inject the coarse chemical bubbles into the tank bottom and the pressure injection means of the cleaning chemical solution inside each membrane element A diffuser pipe is provided , and while the suction pump is stopped, the cleaning chemical liquid is pressurized and injected into the inside of each membrane element by the pressure injection means of the cleaning chemical liquid. Coarse bubbles are ejected from the air diffuser Method for cleaning a submerged membrane separator, which comprises causing.
JP28915095A 1995-10-12 1995-10-12 Cleaning method for submerged membrane separator Expired - Fee Related JP3671477B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28915095A JP3671477B2 (en) 1995-10-12 1995-10-12 Cleaning method for submerged membrane separator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28915095A JP3671477B2 (en) 1995-10-12 1995-10-12 Cleaning method for submerged membrane separator

Publications (2)

Publication Number Publication Date
JPH09103661A JPH09103661A (en) 1997-04-22
JP3671477B2 true JP3671477B2 (en) 2005-07-13

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