JP3605938B2 - Eyelash cosmetics - Google Patents
Eyelash cosmetics Download PDFInfo
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- JP3605938B2 JP3605938B2 JP10409496A JP10409496A JP3605938B2 JP 3605938 B2 JP3605938 B2 JP 3605938B2 JP 10409496 A JP10409496 A JP 10409496A JP 10409496 A JP10409496 A JP 10409496A JP 3605938 B2 JP3605938 B2 JP 3605938B2
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- Prior art keywords
- eyelashes
- effect
- cosmetic
- usability
- film
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- 239000002537 cosmetic Substances 0.000 title claims description 49
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
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- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 239000004204 candelilla wax Substances 0.000 description 2
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Landscapes
- Cosmetics (AREA)
Description
【０００１】
【発明の属する技術分野】
本発明は、睫用化粧料において、睫用化粧料に必要な目元をはっきりさせるという化粧効果及びその持続性に優れ、また使用性が良く、安全性、安定性も良好な睫用化粧料に関する。
【０００２】
【従来の技術】
従来、睫用化粧料は、睫を上にカールする事や睫を太く、長く見せることで、目元をはっきりさせるといった化粧効果をもつものである。一般的に、これらの睫用化粧料は、固形状油分、例えばワックスやロウ類、及び粉体、被膜形成剤を中心として構成されており、化粧品としての快適な使用性、使用感、及び機能性を演出するために、種々の性状、性質をもつワックス類、粉体、被膜形成剤の配合検討が行われてきた。例えば、比較的融点の低いワックスやロウ類においては、配合量を増加させることにより、睫への密着性が高まるため、睫を太く目立たせるといった化粧効果を高めることができる。また、被膜形成剤は、睫に使用されたときに硬い膜を形成することで、化粧持ちを良くしたり、睫を上にカールしたまま固定することで目元をきわだたせるといった化粧効果を高めることができるものである。さらに、これらの系にナイロン等の短繊維を配合することにより、睫を長く見せるといった化粧効果（ロングラッシュ効果）を演出することもできる。
【０００３】
【発明が解決しようとする課題】
しかしながら、低融点のワックスやロウ類を増加させることにより、睫を太くみせるといった化粧効果は得られるものの、睫を上にカールし目元をきわだたせるといった化粧効果については充分な効果が得られず、系が固くなることによる使用性、使用感の悪化といった欠点があった。また、被膜形成剤についても配合量を増加させることにより、睫に硬い膜を形成することができるが、化粧効果の持続性に欠け、使用性の点で睫同士が一本一本離れずに束になってしまい、きれいな化粧ができないといった欠点があった。また、繊維を配合することにより、睫を長く見せる効果（ロングラッシュ効果）を演出することができるが、睫への付着力が低いと化粧効果の持続性に欠け、目の下に粉状に落ちてしまったり、化粧膜の均一性に欠けるため、きれいな化粧が出来ないといった欠点があった。
【０００４】
【課題を解決するための手段】
そこで本発明者らは、上記課題を解決するために鋭意研究した結果、特定量の高融点ワックスと被膜形成性の樹脂、被膜形成性のポリマーエマルション、無水ケイ酸及び繊維を用いることにより、睫をカールし、長く見せ（ロングラッシュ効果）て、目元をきわだたせる化粧効果に優れ、化粧効果の持続性が高く、良好な使用性と均一な化粧膜を付与することができることを見いだし、本発明を完成するに至った。
【０００５】
すなわち、本発明は、次の成分（Ａ）〜（Ｅ）：
（Ａ）融点が７０℃以上で１０５℃以下のエステル系ワックス １〜１０重量％
（Ｂ）ロジン酸系樹脂 ０．１〜５重量％
（Ｃ）ポリ酢酸ビニルポリマーエマルション及び／又はアクリル酸系ポリマーエマルション（固形分として） ４〜２５重量％
（Ｄ）無水ケイ酸 ０．１〜５重量％
（Ｅ）長さが０．１ｍｍ以上５ｍｍ以下、且つ太さが０．１デニール以上８デニール以下である繊維 ０．１〜５重量％
を含有することを特徴とする睫用化粧料に関するものである。
【０００６】
【発明の実施の形態】
本発明に使用される成分（Ａ）の融点が７０℃以上で１０５℃以下のエステル系ワックスとしては、カルナウバワックス、キャンデリラワックス、フラクトオリゴ糖脂肪酸エステル等が用いられる。これらのエステル系ワックスは使用性、官能特性上好ましい。また、これらの高融点エステル系ワックスは必要に応じ、１種又は２種以上を組み合わせて用いられる。
【０００７】
本発明の睫用化粧料に用いられる高融点エステル系ワックスの配合量は、他の成分との関係又は使用性、化粧効果の目的等で決められるが、１〜１０重量％（以下単に％と示す）が必要であり、特に１〜５％が好ましい。配合量が１％より少ないと充分な化粧効果が得られず、１０％を超えると使用性、使用感の面で満足なものが得られない。
【０００８】
本発明に用いられる成分（Ｂ）は、ロジン酸系樹脂である。ロジン酸系樹脂は、使用性、化粧効果の点で好ましい。この樹脂は必要に応じ、１種又は２種以上を組み合わせて用いられる。
【０００９】
本発明の睫用化粧料に用いられるロジン酸系樹脂の配合量は、他の成分との関係、使用性等で決められるが、０．１〜５％が必要であり、特に１〜４％が好ましい。配合量が０．１％より少ないと充分な化粧効果が得られず、５％を超えると使用性、使用感の面で満足なものが得られない。
【００１０】
本発明に用いられる成分（Ｃ）は、ポリ酢酸ビニルポリマーエマルション及び／又はアクリル酸系ポリマーエマルションである。通常のアクリル酸、メタアクリル酸の重合体、共重合体のもの及びアクリル重合体を一部架橋したものも好適に使用できる。例えば、アクリル酸、メタアクリル酸及びそれらのアルキルエステルのホモポリマーエマルション、コポリマーエマルション、アクリルスチレンポリマーエマルション、ポリ酢酸ビニルポリマーエマルションなどがあげられるが、なかでも、アクリル酸系ポリマーエマルション、ポリ酢酸ビニルポリマーエマルションが好ましい。これらのポリマーエマルションは、必要に応じ１種又は２種以上を組み合わせて用いられる。
【００１１】
本発明の睫用化粧料に用いられるポリ酢酸ビニルポリマーエマルション及び／又はアクリル酸系ポリマーエマルションの配合量は、他の成分との関係、使用性等で決められ、固形分濃度によって異なるが、固形分として４〜２５％が必要である。好ましくは６〜２３％含有されたものである。配合量が固形分として４％より少ないと化粧効果の持続性が得られず、２５％を超えると仕上がり膜の均一性が得られない。
【００１２】
本発明に用いられる成分（Ｄ）の無水ケイ酸としては、特に制限されず、化粧品一般に使用されるものであり、無定形構造のもの、疎水化処理したもの、あるいは結晶構造を有するものも好適に使用できる。市販品としては、サイリシア５５０（富士シリシア化学（株）社製）やニップシールＥ−２２０（日本シリカ工業（株）社製）等があげられる。これらの無水ケイ酸は、必要に応じ１種又は２種以上を組み合わせて用いられる。
【００１３】
本発明の睫用化粧料に用いられる無水ケイ酸の配合量は、他の成分との関係、使用性等によって決められるが０．１〜５％が必要であり、好ましくは１〜４％である。配合量が０．１％より少ないと充分な化粧効果が得られず、５％を超えると使用性、使用感の面で満足なものが得られない。
【００１４】
本発明に用いられる成分（Ｅ）の繊維としては特に制限されず、化粧品一般に使用されるものであり、ナイロン、ポリエステル等の合成繊維、レーヨン等の人造繊維、セルロース等の天然繊維、アセテート人絹等の半合成繊維等があげられるが、なかでもナイロン繊維が最も好ましい。
【００１５】
本発明の睫用化粧料に用いられる繊維の長さは、０．１〜５ｍｍであり、好ましくは０．３〜３ｍｍである。繊維の長さが０．１ｍｍ未満では、睫をカールし、長く見せ（ロングラッシュ）る化粧効果に乏しく、５ｍｍを超えると、繊維がマスカラのブラシにまとわりつき、均一な化粧膜ができないため好ましくない。
【００１６】
本発明の睫用化粧料に用いられる繊維の太さは、０．１〜８デニールであり、好ましくは０．３〜７デニール（以下Ｄと示す）である。繊維の太さが０．１Ｄ未満では、睫を長く見せるというロングラッシュ効果やボリューム感に乏しく、８Ｄを超えると、太すぎて睫にきれいにつかず、良好な使用性と均一な化粧膜を得られないため、好ましくない。これらの繊維は材質、太さ、長さにおいて１種又は２種以上を組み合わせて用いることができる。
【００１７】
本発明の睫用化粧料に用いられる繊維の配合量は、他の成分との関係、使用性等で決められるが、０．１〜５％が必要であり、好ましくは０．５〜４％である。配合量が０．１％より少ないと充分な化粧効果が得られず、５％を超えると使用性、使用感、均一な化粧膜の面で満足なものが得られない。
【００１８】
本発明の睫用化粧料には、上記の構成成分に加え、目的に応じて本発明の効果をそこなわない範囲において、化粧効果を付与するための粉体、例えば体質顔料、白色顔料、有色顔料、有機粉末、パール剤等が使用可能である。具体的には、タルク、マイカ、カオリン、炭酸カルシウム、炭酸マグネシウム、酸化チタン、亜鉛華、ベンガラ、黄酸化鉄、黒酸化鉄、ナイロン粉末、シルクパウダー、雲母チタン等があげられ、これらは特に制限されるものではなく、必要に応じ１種又は２種以上を組み合わせて用いられる。また、これらの粉体は本発明の効果を妨げない範囲で一般油剤、シリコーン油、フッ素化合物、界面活性剤等で処理したものも使用することができる。更に、本発明の睫用化粧料には、目的に応じて本発明の効果をそこなわない範囲において、エモリエント効果、モイスチュア効果等を付与するための油脂、エステル油、炭化水素油等の液状油剤や、グリセリン、プロピレングリコール、ジプロピレングリコール、１，３−ブチレングリコール、ポリエチレングリコール等の水性成分、及び界面活性剤、香料、防腐剤、美容剤、増粘剤等、通常化粧品に配合される他の成分を配合することができる。
【００１９】
【実施例】
以下に実施例をあげて本発明を更に説明する。なお、これらは本発明を何ら限定するものではない。
【００２０】
実施例１〜７及び比較例１〜５ マスカラ
表１に示す処方のマスカラを調製し、睫を上にカールし、目元をきわだたせるという化粧効果、及びその化粧効果の持続性、塗布時の化粧のしやすさ（使用性、及び使用感）、及び仕上がり膜の均一性について下記の方法により官能評価を行った。その結果も併せて表１に示す。
【００２１】
【表１】
（製法）
実施例１〜７及び比較例１〜５Ａ．成分（１）〜（１０）を加熱溶解し、成分（１１）を加え、均一に混合する。
Ｂ．成分（１２）〜（２２）を均一に混合する。
Ｃ．ＡにＢを加え、乳化する。
Ｄ．Ｃを容器に充填して製品とする。
【００２３】
（評価方法）
１０名の官能パネルにより、各試料を下記ａ〜ｅについて、（１）絶対評価基準を用いて７段階に評価し、各試料ごとの評点の平均値を（２）４段階評価基準を用いて評価した。
ａ．化粧効果（睫のカール効果）
ｂ．化粧効果（睫のロングラッシュ効果）
ｃ．化粧効果の持続ｄ．化粧のしやすさ
ｅ．仕上がり膜の均一性
（１）絶対評価基準
（評点）：（評価）
６：非常に良い
５：良い
４：やや良い
３：普通
２：やや悪い
１：悪い
０：非常に悪い
（２）４段階評価基準
５点以上 ：非常に良好：◎
３点以上５点未満：良好 ：○
１点以上３点未満：やや不良 ：△
１点未満 ：不良 ：×
【００２４】
表１の結果から明かなように、本発明品である実施例１〜７のマスカラは、比較例１〜５のマスカラに比較し、睫を上にカールし目元をきわだたせるという化粧効果、睫を長く見せ目元をきわだたせるという化粧効果及びその持続性、化粧のしやすさ、仕上がり膜の均一性の全ての面で、はるかに優れた特性を有していることがわかる。特に、本発明のマスカラは、睫を上にカールして長く見せ、目元をきわだたせるという化粧効果に優れ、また睫の一本一本にきれいにつき、仕上がり膜の均一性が高いといった官能特性上、非常に優れたものである。一方、高融点のワックス及び被膜形成性樹脂が多く、繊維の少ない比較例１では、製品系の粘度が高くなりすぎるために化粧のしやすさや仕上がり膜の均一性といった使用性、使用感の面で満足なものが得られず、睫を長く見せるといった化粧効果についても満足のいくものが得られなかった。また被膜形成性のポリマーエマルションの多い比較例２では睫どうしが束になってしまい、仕上がり膜の均一性が得られなかった。また、高融点ワックス量、被膜形成性樹脂量を低減した比較例３、及び被膜形成性のポリマーエマルション、無水ケイ酸を低減した比較例４では、化粧のしやすさ、仕上がり膜の均一性といった使用性、使用感の面では問題ないものの、睫を上にカールし目元をきわだたせるといった化粧効果やその化粧効果の持続の点で満足のいくものが得られなかった。また、繊維の多い比較例５では睫を長く見せるロングラッシュ効果には優れるものの、仕上がりが膜の均一性といった点で満足のいくものが得られなかった。
【００２５】
実施例８ マスカラ
（成分） （％）
（１）ステアリン酸 ２．０
（２）キャンデリラワックス ３．０
（３）ミツロウ ４．５
（４）セタノール ０．１
（５）モノステアリン酸グリセリン ０．９
（６）ショ糖脂肪酸エステル １．５
（７）モノオレイン酸ポリオキシエチレンソルビタン １．３
（８）セスキオレイン酸ソルビタン ０．５
（９）ロジン酸ペンタエリスリット ３．０
（１０）ベンガラ １．４
（１１）黄酸化鉄 ２．６
（１２）タルク ２．０
（１３）マイカ ３．０
（１４）トリエタノールアミン １．１
（１５）１，３−ブチレングリコール ７．０
（１６）ポリアクリル酸ポリマーエマルション(固形分５０％) １０．０
（１７）ポリ酢酸ビニルポリマーエマルション(固形分４０％) ２０．０
（１８）ナイロン繊維（３Ｄ、１ｍｍ） ３．０
（１９）無水ケイ酸 ２．５
（２０）香料 ０．１
（２１）防腐剤 ０．２
（２２）精製水 残量
（製法）
Ａ．成分（１）〜（９）を加熱溶解し、成分（１０）〜（１３）を加え、均一に混合する。
Ｂ．成分（１４）〜（２２）を均一に混合する。
Ｃ．ＡにＢを加え、乳化する。
Ｄ．Ｃを容器に充填して製品とする。
【００２６】
以上のようにして得られたマスカラは、カール効果及びロングラッシュ効果に優れ、睫に一本一本きれいに付着し、化粧膜の均一性も高いものであった。
【００２７】
実施例９ マスカラ
（成分） （％）
（１）ステアリン酸 １．８
（２）フラクトオリゴ糖脂肪酸エステル ６．０
（３）ミツロウ １．０
（４）セタノール ０．１
（５）モノステアリン酸グリセリン ０．９
（６）ショ糖脂肪酸エステル １．５
（７）モノオレイン酸ポリオキシエチレンソルビタン １．３
（８）セスキオレイン酸ソルビタン ０．５
（９）ロジン酸ペンタエリスリット ３．０
（１０）酸化チタン ０．４
（１１）グンジョウ ３．６
（１２）タルク ２．０
（１３）マイカ ３．０
（１４）トリエタノールアミン １．１
（１５）１，３−ブチレングリコール ７．０
（１６）ポリ酢酸ビニルポリマーエマルション（固形分４０％） ３０．０
（１７）レーヨン繊維（２Ｄ、１ｍｍ） ４．０
（１８）無水ケイ酸 ４．０
（１９）香料 ０．１
（２０）防腐剤 ０．２
（２１）精製水 残量
（製法）
Ａ．成分（１）〜（９）を加熱溶解し、成分（１０）〜（１３）を加え、均一に混合する。
Ｂ．成分（１４）〜（２１）を均一に混合する。
Ｃ．ＡにＢを加え、乳化する。
Ｄ．Ｃを容器に充填して製品とする。
【００２８】
以上のようにして得られたマスカラは、カール効果及びロングラッシュ効果に優れ、化粧の持続性、及び使用性、使用感に優れた特性を有するものが得られた。
【００２９】
【発明の効果】
本発明の睫用化粧料は、睫を上にカールし長く見せ、目元をきわだたせるといった化粧効果、及びその化粧持続性に優れ、かつ使用において、化粧がしやすく、経時安定性にも優れるものである。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a cosmetic for eyelashes, which has an excellent cosmetic effect of clarifying the eyes required for the cosmetic for eyelashes and its persistence, and has good usability, safety, and stability. .
[0002]
[Prior art]
2. Description of the Related Art Conventionally, eyelash cosmetics have a cosmetic effect such as curling the eyelashes upward and making the eyelashes thick and long so that the eye area becomes clear. Generally, these eyelash cosmetics are composed mainly of solid oil components, for example, waxes and waxes, powders, and film-forming agents, and have a comfortable usability, a feeling of use, and a function as cosmetics. In order to produce properties, studies have been made on the compounding of waxes, powders, and film-forming agents having various properties and properties. For example, in the case of waxes and waxes having a relatively low melting point, increasing the blending amount increases the adhesion to the eyelashes, so that a cosmetic effect such as making the eyelashes stand out thicker can be enhanced. In addition, the film-forming agent forms a hard film when used for eyelashes, thereby improving the makeup lasting effect, and enhancing the cosmetic effect such that the eyelashes are prominent by fixing the eyelashes while being curled up. Is what you can do. Furthermore, by blending short fibers such as nylon with these systems, a cosmetic effect (long lash effect) such as making the eyelashes long can be produced.
[0003]
[Problems to be solved by the invention]
However, by increasing the amount of low-melting waxes and waxes, a cosmetic effect such as thickening the eyelashes can be obtained, but a sufficient effect cannot be obtained for the cosmetic effect such as curling the eyelashes upward and prominently prominently. However, there are drawbacks such as deterioration of usability and usability due to hardening of the system. In addition, by increasing the amount of the film-forming agent, a hard film can be formed on the eyelashes, but the makeup effect is lacking, and the eyelashes do not separate from each other in terms of usability. There was a drawback that it became a bundle and it was not possible to make beautiful makeup. In addition, by blending fibers, the effect of making the eyelashes look longer (long lash effect) can be produced, but if the adhesion to the eyelashes is low, the makeup effect is not long-lasting and falls into a powdery form under the eyes There is a drawback that the makeup cannot be cleanly made due to the lack of uniformity of the makeup film.
[0004]
[Means for Solving the Problems]
The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, using a specific amount of a high melting point wax, a film-forming resin, a film-forming polymer emulsion, silicic anhydride and fibers, Curls the skin and shows it for a long time (long lash effect), has an excellent makeup effect that stands out the eyes, has a long lasting makeup effect, provides good usability and can provide a uniform makeup film. The invention has been completed.
[0005]
That is, the present invention provides the following components (A) to (E):
(A) 1 to 10% by weight of an ester wax having a melting point of 70 ° C. or more and 105 ° C. or less
(B) rosin acid resin 0.1 to 5% by weight
(C) Polyvinyl acetate polymer emulsion and / or acrylic acid polymer emulsion (as solid content) 4 to 25% by weight
(D) Silicic anhydride 0.1-5% by weight
(E) A fiber having a length of 0.1 mm to 5 mm and a thickness of 0.1 denier to 8 denier 0.1 to 5% by weight
The present invention relates to a cosmetic for eyelashes, comprising:
[0006]
BEST MODE FOR CARRYING OUT THE INVENTION
Examples of the ester wax having a melting point below 105 ° C. at 70 ° C. or more components (A) used in the present invention, carnauba wax, candelilla wax, fructooligosaccharide fatty acid esters and the like are used. These ester-based wax usability, organoleptic properties UeYoshimi preferable. These high-melting ester waxes may be used alone or in combination of two or more, if necessary.
[0007]
The amount of the high-melting ester wax used in the eyelash cosmetic of the present invention is determined depending on the relationship with other components or the usability, the purpose of the cosmetic effect, and the like, but is 1 to 10% by weight (hereinafter simply referred to as%). Is required, and 1 to 5% is particularly preferable. If the amount is less than 1%, a sufficient cosmetic effect cannot be obtained, and if it exceeds 10%, a satisfactory one cannot be obtained in terms of usability and usability.
[0008]
The component (B) used in the present invention is a rosin acid resin. A rosin acid-based resin is preferred in terms of usability and cosmetic effect. This resin is used alone or in combination of two or more as necessary.
[0009]
The amount of the rosin acid-based resin used in the eyelash cosmetic of the present invention is determined depending on the relationship with other components, usability, and the like, but is required to be 0.1 to 5%, and particularly 1 to 4%. Is preferred. If the amount is less than 0.1%, a sufficient cosmetic effect cannot be obtained, and if the amount exceeds 5%, satisfactory useability and usability cannot be obtained.
[0010]
The component (C) used in the present invention is a polyvinyl acetate polymer emulsion and / or an acrylic acid polymer emulsion . Ordinary polymers of acrylic acid and methacrylic acid, copolymers, and partially crosslinked acrylic polymers can also be suitably used. For example, acrylic acid, methacrylic acid and homopolymers emulsion their alkyl esters, copolymer emulsions, acrylic styrene polymer emulsion, although etc. polyvinyl acetate polymer Emar cane emissions are mentioned, among others, acrylic polymer emulsion, poly vinyl acetate polymer emulsion has good preferable. These polymer emulsions are used alone or in combination of two or more as necessary.
[0011]
The amount of the polyvinyl acetate polymer emulsion and / or acrylic acid-based polymer emulsion used in the eyelash cosmetic of the present invention is determined depending on the relationship with other components, usability, and the like. 4 to 25% is required in minutes. Preferably, the content is 6 to 23%. If the amount is less than 4% as a solid content, the persistence of the cosmetic effect cannot be obtained, and if it exceeds 25%, uniformity of the finished film cannot be obtained.
[0012]
The silicic anhydride of the component (D) used in the present invention is not particularly limited, and is generally used in cosmetics, and preferably has an amorphous structure, a hydrophobized material, or a crystal structure. Can be used for Commercially available products include Sylysia 550 (manufactured by Fuji Silysia Chemical Ltd.) and Nip Seal E-220 (manufactured by Nippon Silica Industry Co., Ltd.). These silicic anhydrides are used alone or in combination of two or more as necessary.
[0013]
The compounding amount of the silicic anhydride used in the eyelash cosmetic of the present invention is determined depending on the relationship with other components, usability, and the like, but is required to be 0.1 to 5%, preferably 1 to 4%. is there. If the amount is less than 0.1%, a sufficient cosmetic effect cannot be obtained, and if the amount exceeds 5%, satisfactory useability and usability cannot be obtained.
[0014]
The fiber of the component (E) used in the present invention is not particularly limited, and is generally used in cosmetics. Synthetic fibers such as nylon and polyester; artificial fibers such as rayon; natural fibers such as cellulose; And the like, and among them, nylon fibers are most preferable.
[0015]
The length of the fiber used in the eyelash cosmetic of the present invention is 0.1 to 5 mm, preferably 0.3 to 3 mm. If the length of the fiber is less than 0.1 mm, the eyelashes are curled and the cosmetic effect of making the eye look long (long rush) is poor. .
[0016]
The thickness of the fiber used in the eyelash cosmetic of the present invention is 0.1 to 8 denier, preferably 0.3 to 7 denier (hereinafter, referred to as D). If the thickness of the fiber is less than 0.1D, the long lash effect that makes the eyelashes look long and the volume feeling is poor, and if it exceeds 8D, it is too thick and does not adhere to the eyelashes cleanly, providing good usability and a uniform makeup film. It is not preferable because it cannot be performed. These fibers can be used alone or in combination of two or more in terms of material, thickness, and length.
[0017]
The amount of the fiber used in the eyelash cosmetic of the present invention is determined depending on the relationship with other components, usability, and the like, but is required to be 0.1 to 5%, and preferably 0.5 to 4%. It is. If the amount is less than 0.1%, a sufficient cosmetic effect cannot be obtained, and if it exceeds 5%, a satisfactory product cannot be obtained in terms of usability, usability, and uniform cosmetic film.
[0018]
In the eyelash cosmetic of the present invention, in addition to the above-mentioned components, a powder for imparting a cosmetic effect within a range that does not impair the effects of the present invention depending on the purpose, for example, extender pigment, white pigment, colored Pigments, organic powders, pearling agents and the like can be used. Specific examples include talc, mica, kaolin, calcium carbonate, magnesium carbonate, titanium oxide, zinc white, red iron oxide, black iron oxide, nylon powder, silk powder, titanium mica, and the like. They are not used, and may be used alone or in combination of two or more as needed. These powders may also be those treated with a general oil, silicone oil, fluorine compound, surfactant or the like as long as the effects of the present invention are not impaired. Further, in the eyelash cosmetic of the present invention, liquid oils such as oils and fats, ester oils, hydrocarbon oils and the like for imparting an emollient effect, a moisturizing effect and the like within a range that does not impair the effects of the present invention depending on the purpose. And aqueous components such as glycerin, propylene glycol, dipropylene glycol, 1,3-butylene glycol, and polyethylene glycol, and surfactants, fragrances, preservatives, beauty agents, thickeners, and other ingredients that are usually incorporated in cosmetics. Can be blended.
[0019]
【Example】
Hereinafter, the present invention will be further described with reference to examples. Note that these do not limit the present invention at all.
[0020]
Examples 1 to 7 and Comparative Examples 1 to 5 Mascara Mascara having the formulation shown in Table 1 was prepared, the eyelashes were curled up, the makeup effect of prominent eyes, and the persistence of the makeup effect, the time of application Sensory evaluation was performed on the ease of makeup (usability and feeling) and the uniformity of the finished film by the following method. Table 1 also shows the results.
[0021]
[Table 1]
(Production method)
Examples 1 to 7 and Comparative Examples 1 to 5A. The components (1) to (10) are dissolved by heating, and the component (11) is added and mixed uniformly.
B. The components (12) to (22) are uniformly mixed.
C. Add B to A and emulsify.
D. C is filled into a container to obtain a product.
[0023]
(Evaluation method)
Using a sensory panel of 10 persons, each sample was evaluated for the following a to e in seven steps using (1) absolute evaluation criteria, and the average value of the scores for each sample was evaluated using (2) four-step evaluation criteria. evaluated.
a. Makeup effect (curl effect of eyelashes)
b. Makeup effect (long lash effect of eyelashes)
c. Duration of cosmetic effect d. Ease of makeup e. Uniformity of finished film (1) Absolute evaluation criteria (score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (2) 4-grade evaluation standard 5 or more: Very good: A
3 points or more and less than 5 points: Good: Good
1 point or more and less than 3 points: Somewhat poor: △
Less than 1 point: Bad: ×
[0024]
As is clear from the results in Table 1, the mascaras of Examples 1 to 7 which are the products of the present invention have a cosmetic effect of curling the eyelashes upward and prominently revealing the eyes compared to the mascaras of Comparative Examples 1 to 5, It can be seen that the eyelashes have a far superior characteristic in all aspects of the cosmetic effect of making the eyelashes look long and prominent in the eyes, and their persistence, ease of makeup, and uniformity of the finished film. In particular, the mascara of the present invention has an excellent cosmetic effect such that the eyelashes are curled up and look long, and the eyes are prominent, and the eyelashes are beautifully treated one by one, and the finished film has high uniformity. Above, it is very good. On the other hand, in Comparative Example 1 in which the amount of the high melting point wax and the film-forming resin is large and the number of fibers is small, the viscosity of the product system becomes too high, and the usability and usability such as ease of makeup and uniformity of the finished film are reduced. No satisfactory results were obtained, and no satisfactory cosmetic effects such as prolonged eyelashes were obtained. Further, in Comparative Example 2 having a large number of polymer emulsions capable of forming a film, the eyelashes were bundled, and uniformity of the finished film could not be obtained. In Comparative Example 3 in which the amount of the high melting point wax and the amount of the film-forming resin were reduced, and in Comparative Example 4 in which the amount of the film-forming polymer emulsion and silicic anhydride were reduced, the ease of makeup and the uniformity of the finished film were reduced. Although there was no problem in terms of usability and usability, no satisfactory effect was obtained in terms of the cosmetic effect of curling the eyelashes upward and prominently prominent in the eyes, and the sustainability of the cosmetic effect. In Comparative Example 5 having a large number of fibers, although the long lash effect of making the eyelashes look long was excellent, the finished product was not satisfactory in terms of uniformity of the film.
[0025]
Example 8 Mascara (component) (%)
(1) Stearic acid 2.0
(2) Candelilla wax 3.0
(3) Beeswax 4.5
(4) Cetanol 0.1
(5) Glycerin monostearate 0.9
(6) Sucrose fatty acid ester 1.5
(7) Polyoxyethylene sorbitan monooleate 1.3
(8) Sorbitan sesquioleate 0.5
(9) Pentaerythrosin rosinate 3.0
(10) Bengala 1.4
(11) Yellow iron oxide 2.6
(12) Talc 2.0
(13) Mica 3.0
(14) Triethanolamine 1.1
(15) 1,3-butylene glycol 7.0
(16) Polyacrylic acid polymer emulsion (solid content 50%) 10.0
(17) Polyvinyl acetate polymer emulsion (solid content 40%) 20.0
(18) Nylon fiber (3D, 1 mm) 3.0
(19) Silicic anhydride 2.5
(20) Fragrance 0.1
(21) Preservative 0.2
(22) Remaining purified water (production method)
A. Components (1) to (9) are heated and dissolved, and components (10) to (13) are added and uniformly mixed.
B. The components (14) to (22) are uniformly mixed.
C. Add B to A and emulsify.
D. C is filled into a container to obtain a product.
[0026]
The mascara obtained as described above was excellent in curling effect and long lash effect, adhered to eyelashes one by one, and had high uniformity of the decorative film.
[0027]
Example 9 Mascara (component) (%)
(1) Stearic acid 1.8
(2) Fructooligosaccharide fatty acid ester 6.0
(3) Beeswax 1.0
(4) Cetanol 0.1
(5) Glycerin monostearate 0.9
(6) Sucrose fatty acid ester 1.5
(7) Polyoxyethylene sorbitan monooleate 1.3
(8) Sorbitan sesquioleate 0.5
(9) Pentaerythrosin rosinate 3.0
(10) Titanium oxide 0.4
(11) Gunjo 3.6
(12) Talc 2.0
(13) Mica 3.0
(14) Triethanolamine 1.1
(15) 1,3-butylene glycol 7.0
(16) Polyvinyl acetate polymer emulsion (solid content 40%) 30.0
(17) Rayon fiber (2D, 1 mm) 4.0
(18) Silicic anhydride 4.0
(19) Fragrance 0.1
(20) Preservative 0.2
(21) Remaining purified water (production method)
A. Components (1) to (9) are heated and dissolved, and components (10) to (13) are added and uniformly mixed.
B. The components (14) to (21) are uniformly mixed.
C. Add B to A and emulsify.
D. C is filled into a container to obtain a product.
[0028]
The mascara obtained as described above was excellent in curling effect and long lash effect, and had characteristics of excellent persistence of makeup, usability, and usability.
[0029]
【The invention's effect】
The cosmetic for eyelashes of the present invention is excellent in cosmetic effects such as curling the eyelashes upward and making the eyes look prominent and prominent eyes, as well as in their long-lasting makeup, and in use, is easy to make up and has excellent stability over time. Things.
Claims (3)
（Ａ）融点が７０℃以上で１０５℃以下のエステル系ワックス １〜１０重量％
（Ｂ）ロジン酸系樹脂 ０．１〜５重量％
（Ｃ）ポリ酢酸ビニルポリマーエマルション及び／又はアクリル酸系ポリマーエマルション（固形分として） ４〜２５重量％
（Ｄ）無水ケイ酸 ０．１〜５重量％
（Ｅ）長さが０．１ｍｍ以上５ｍｍ以下、且つ太さが０．１デニール以上８デニール以下である繊維 ０．１〜５重量％
を含有することを特徴とする睫用化粧料。The following components (A) to (E):
(A) 1 to 10% by weight of an ester wax having a melting point of 70 ° C. or more and 105 ° C. or less
(B) rosin acid resin 0.1 to 5% by weight
(C) Polyvinyl acetate polymer emulsion and / or acrylic acid polymer emulsion (as solid content) 4 to 25% by weight
(D) Silicic anhydride 0.1-5% by weight
(E) A fiber having a length of 0.1 mm to 5 mm and a thickness of 0.1 denier to 8 denier 0.1 to 5% by weight
A cosmetic for eyelashes, comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10409496A JP3605938B2 (en) | 1996-03-29 | 1996-03-29 | Eyelash cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10409496A JP3605938B2 (en) | 1996-03-29 | 1996-03-29 | Eyelash cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09263518A JPH09263518A (en) | 1997-10-07 |
| JP3605938B2 true JP3605938B2 (en) | 2004-12-22 |
Family
ID=14371540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10409496A Expired - Fee Related JP3605938B2 (en) | 1996-03-29 | 1996-03-29 | Eyelash cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3605938B2 (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2187833T5 (en) * | 1996-11-27 | 2007-11-01 | THE PROCTER & GAMBLE COMPANY | MASK COMPOSITIONS WITH IMPROVED BENEFITS OF USE AND BEAUTY. |
| JPH11302126A (en) * | 1998-04-24 | 1999-11-02 | Kose Corp | Liquid eye liner cosmetic |
| FR2787318B1 (en) * | 1998-12-21 | 2002-10-11 | Oreal | COMPOSITION FOR COATING KERATIN FIBERS |
| FR2795957B1 (en) | 1999-07-08 | 2001-09-28 | Oreal | MAKEUP COMPOSITION COMPRISING FIBERS |
| FR2795950B1 (en) * | 1999-07-08 | 2003-05-09 | Oreal | MASCARA COMPRISING A POLYURETHANE AND FIBERS |
| FR2815850B1 (en) * | 2000-10-27 | 2003-02-14 | Oreal | FILM-FORMING COSMETIC COMPOSITION |
| FR2815847B1 (en) * | 2000-10-27 | 2002-12-13 | Oreal | COSMETIC COMPOSITION COMPRISING FIBERS AND WAX |
| JP2002234819A (en) * | 2001-02-08 | 2002-08-23 | Kose Corp | Foundation cosmetic for mascara |
| JP4727067B2 (en) * | 2001-05-21 | 2011-07-20 | 株式会社コーセー | Water based cosmetics |
| EP1400234A1 (en) * | 2002-09-20 | 2004-03-24 | L'oreal | Cosmetic composition comprising rigid fibres and a component selected from a filmogenic polymer and/or a wax |
| FR2844708B1 (en) * | 2002-09-20 | 2007-10-26 | Oreal | COSMETIC COMPOSITION COMPRISING RIGID FIBERS AND A FILMOGENEOUS POLYMER |
| US7754196B2 (en) | 2002-09-20 | 2010-07-13 | L'oreal | Cosmetic composition comprising fiber |
| US7875265B2 (en) | 2002-09-26 | 2011-01-25 | L'oreal | Cosmetic composition comprising a sequenced polymer and a plasticizer |
| US6905696B2 (en) * | 2003-01-06 | 2005-06-14 | Color Access, Inc. | Alignment of enhancers in cosmetic compositions |
| US7488472B2 (en) | 2003-06-26 | 2009-02-10 | Kose Corporation | Cosmetic composition for eyelashes |
| JP4757512B2 (en) * | 2004-03-26 | 2011-08-24 | 株式会社コーセー | Cosmetics for water-in-oil coffee |
| JP4866564B2 (en) * | 2004-03-30 | 2012-02-01 | 株式会社コーセー | Cosmetic for salmon |
| US9056053B2 (en) | 2008-01-08 | 2015-06-16 | Avon Products, Inc | Nanoparticle compositions providing enhanced color for cosmetic formulations |
| JP5968044B2 (en) * | 2012-04-24 | 2016-08-10 | 株式会社 資生堂 | Oil-in-water emulsified cosmetic |
| US10507175B1 (en) * | 2019-04-11 | 2019-12-17 | Elc Management Llc | Curling mascara compositions |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57158714A (en) * | 1981-03-26 | 1982-09-30 | Shiseido Co Ltd | Cosmetic for eyelash |
| JPS6112606A (en) * | 1984-06-27 | 1986-01-21 | Kobayashi Kooc:Kk | Eye makeup cosmetic |
| JPH03153613A (en) * | 1989-11-10 | 1991-07-01 | Isehan:Kk | Liquid mascara composition |
| FR2659011B1 (en) * | 1990-03-01 | 1994-09-30 | Oreal | WATER RESISTANT COMPOSITION FOR COATING EYELASHES, AND PREPARATION METHOD THEREOF. |
| FR2680681A1 (en) * | 1991-08-30 | 1993-03-05 | Oreal | COMPOSITION FOR MAKEUP AND CARE OF EYELASHES AND / OR EYEBROWS AND METHOD FOR PREPARING SAME. |
| JP3020738B2 (en) * | 1992-06-24 | 2000-03-15 | 鐘紡株式会社 | mascara |
| JPH06279232A (en) * | 1993-03-30 | 1994-10-04 | Nisshin Chem Ind Co Ltd | Eye makeup cosmetic |
| FR2712805B1 (en) * | 1993-11-24 | 1996-01-19 | Oreal | Cosmetic composition for make-up in the form of a mascara containing at least one wax and one pseudo-latex. |
| JP3410189B2 (en) * | 1993-12-28 | 2003-05-26 | 株式会社コーセー | Eye makeup cosmetics |
| JPH07267828A (en) * | 1994-03-31 | 1995-10-17 | Shiseido Co Ltd | O/w-type cosmetic for eyelash |
| JP3554995B2 (en) * | 1995-03-29 | 2004-08-18 | 株式会社コーセー | Eyelash cosmetics |
-
1996
- 1996-03-29 JP JP10409496A patent/JP3605938B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH09263518A (en) | 1997-10-07 |
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