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JP3569439B2 - Continuous hot-dip plating method and apparatus - Google Patents

Continuous hot-dip plating method and apparatus Download PDF

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Publication number
JP3569439B2
JP3569439B2 JP08837198A JP8837198A JP3569439B2 JP 3569439 B2 JP3569439 B2 JP 3569439B2 JP 08837198 A JP08837198 A JP 08837198A JP 8837198 A JP8837198 A JP 8837198A JP 3569439 B2 JP3569439 B2 JP 3569439B2
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Japan
Prior art keywords
snout
steel strip
annealing furnace
continuous
temperature
Prior art date
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JP08837198A
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Japanese (ja)
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JPH11286762A (en
Inventor
義広 末宗
宏幸 森本
久芳 小松
聖人 山崎
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Nippon Steel Corp
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Nippon Steel Corp
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Publication of JPH11286762A publication Critical patent/JPH11286762A/en
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  • Heat Treatment Of Strip Materials And Filament Materials (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、溶融メッキ工程においてスナウト内で発生する亜鉛ヒューム量を抑制するための連続溶融めっき方法及びその装置に関するものである。
【0002】
【従来の技術】
近年、自動車・家電用の表面処理鋼板として、耐食性の優れる溶融亜鉛メッキ鋼板の適用が増大している。この溶融亜鉛メッキ鋼板は、鋼帯を還元雰囲気炉内で焼鈍した後に冷却され焼鈍炉とメッキ浴を結ぶスナウトと呼ばれる炉内を通過して、溶融亜鉛浴に侵漬される。更に、その後ワイピングノズルで適正なメッキ付着量に調整される。溶融亜鉛メッキ工程においては、従来よりスナウト内部の亜鉛浴面からヒュームが発生し、該ヒュームがスナウト壁に付着堆積し、これが一部剥離落下して、直接メッキ前の鋼板に付着したり、亜鉛浴面に落下し、亜鉛浴面上を浮遊しながら、鋼帯に付着し、その結果メッキ後の鋼板外観を損ねることが知られている。
【0003】
この対策として、例えば特開平6−339346号公報に開示されているように、スナウト内の亜鉛浴表面から発生するヒュームに対し、スナウト壁の温度分布をつけ、自然対流を生じさせ、連続炉側のスナウト取付け部より上流側に強制的に移送し、スナウト内壁への付着・成長を抑制させること、またターンダウンロール室に低温部を設けることによって、金属ヒュームを析出させる方法、更にスナウト内に自然対流を生じさせるためにスナウト外壁に電熱ヒータを複数に区画設置する方案が提示されている。
【0004】
【発明が解決しようとする課題】
しかし、スナウト内部に自然対流を発生させると、スナウト浴表面での亜鉛ヒューム濃度勾配が大きくなり、却ってヒューム発生量が促進される。この結果、スナウト内部のヒューム濃度は自然対流を発生させない場合とほとんど変わらず、更にターンダウンロール室の低温部で堆積するヒューム量が増大するために、ラインの生産を止めて炉開放を行い、清掃を行う必要が生じてくる。
【0005】
【課題を解決するための手段】
本発明は、上記問題点に鑑みてなされたもので、鋼帯を連続焼鈍炉での還元性雰囲気下で加熱、焼鈍し、該連続焼鈍炉から周囲雰囲気から区画されたターンダウンロール室およびスナウトを介して溶融金属めっき浴へ導入してめっきを行なう連続溶融めっき方法において、前記スナウト内と前記焼鈍炉内との間をシールし、スナウト内の温度偏差を50℃以内とした。
【0006】
また、鋼帯を還元性雰囲気下で加熱、焼鈍する連続焼鈍炉と、該連焼鈍炉から溶融金属めっき浴へ導入する鋼帯を周囲雰囲気から区画するスナウトを具備した連続溶融めっき装置において、ターンダウンロールの上流側あるいは/および下流側に、前記鋼帯の上下に、鋼帯との間隔を30mm以下となるように仕切り板を設けることにより、スナウト内の温度偏差を50℃以内となるようにスナウト内と前記焼鈍炉内との間をシールした。
更に、スナウト及びその上部に配置するターンダウンロール室の鉄皮に加熱装置を複数に区画して設置し、且つ、該加熱装置の外側に断熱材を施工し、スナウト及びターンダウンロール室の各部に温度検出器を設け、該温度検出器から入力される測温結果に基づいて複数に区画した加熱装置への印加電圧を制御する温度制御部を設けた。
【0007】
【発明の実施の形態】
本発明に係る装置の概要図を図1に示す。図1(a)は全体概要図であり、図1(b)はターンダウンロールの上下に仕切り板を設置した場合であり、また、図1(c)はターンダウンロール部の上流に仕切り板を設置した図である。鋼帯1は焼鈍炉加熱帯2で焼鈍され、溶融亜鉛メッキ浴5と鋼帯1温度をほぼ同一とするため、冷却帯3で冷却され、その後ターンダウンロール6を介してスナウト4を通り、亜鉛浴7へ漬される。ターンダウンロール6より連続焼鈍炉側には鋼帯1の上下両面ともに接触するロール8を取り付け、ロール8と炉体の間には隙間が5mm以下の仕切り板9を設置している。スナウト4の壁には電熱ヒータが設置され、亜鉛浴との温度差を50℃以内としている。電熱ヒータの外は断熱材10で覆われ、更に断熱材10の外側をステンレス板11で覆っている。
【0008】
また、スナウト4と連続炉側をシールする方法として、図1(b)に示すように、ターンダウンロール6の上方、下方にそれぞれターンダウンロール6との距離が30mm以下とする仕切り板を設置した方法や、図1(c)に示すように、ターンダウンロール部6の上流または下流に鋼板との距離を30mm以下とする仕切り板を設置した場合もある。
本装置において、スナウト内の温度差を50℃以内としたのは、スナウト内対流を生じさせないようにしたためであり、実験でスナウト壁温度を変えていった場合、スナウト内温度差が50℃より大きくなるとになると自然対流が強く生じはじめ、その時、連続炉側に漏洩する亜鉛蒸気の量が多くなった。
【0009】
これは、スナウト内での亜鉛蒸気が飽和状態になっていたのを自然対流を発生させることによって、亜鉛浴表面での気液平衡を崩し、その結果、亜鉛蒸気発生量が増大したためと考えられる。操業中スナウトを加熱しない場合、スナウト炉体上下面の板道部は鋼板保有熱の輻射により板道から外れた部位よりも約100℃高温となった。このため、複数に区画した加熱帯で調整し、スナウト壁温度を均一とした。
また、請求項において切り板9と鋼帯1との隙間を30mm以下としたのは、スナウト内部の亜鉛蒸気を極力飽和に近づけるためであり、鋼帯1と仕切り板9またはターンダウンロール6と仕切り板9が実操業上接触トラブルを起こさない範囲として30mm以下とした。
【0010】
【実施例】
図2は本発明に係る装置のターンダウンロール部を示す概要図である。この図2に示すような装置で連続溶融亜鉛メッキのスナウト4において、スナウト壁に温度分布を付与させた場合のターンダウンロール部より連続炉側へ移動するヒューム量を測定した。ヒューム発生量の測定は、ターンダウンロールより上流側の炉体に測定口13を取付け、炉内ガスをポンプ14で吸引し濾紙12でヒュームを捕集し、その重量を測定した。その際、炉体から濾紙12までの配管は亜鉛ヒュームが結露しないように加熱した。その結果、スナウト壁の温度差を付けるとともにヒューム発生量が増大した。また、ターンダウンロール部に鋼帯との隙間を10mmとしたシール装置を設置した場合、シール装置より連続炉側で発生するヒューム量が減少し、スナウト壁との温度差を50℃以内とした場合のヒューム量はシール装置がない場合の1/10まで減少した。
また、スナウト壁を電熱ヒータで加熱した場合に、ターンダウンロール部に設置した鋼帯との仕切り板距離を変えた場合の連続炉側へのヒューム漏洩量を調査した。ヒューム漏洩量は鋼帯と仕切り板との距離に比例して多くなった。
【0011】
【発明の効果】
本発明により、スナウト内亜鉛浴面より発生する亜鉛蒸気量が減少し、連続溶融亜鉛メッキラインの生産を止めなくても、表面外観の良好な亜鉛メッキ鋼板を製造することができるようになった。
【図面の簡単な説明】
【図1】本発明に係る装置の概要図である。
【図2】本発明に係る装置のターンダウンロール部を示す概要図である。
【符号の説明】
1 鋼帯
2 焼鈍炉加熱帯
3 冷却帯
4 スナウト
5 電熱ヒーター
6 ターンダウンロール
7 亜鉛浴
8 ロール
9 仕切り板
10 断熱材
11 ステンレス板
12 濾紙
13 測定口
14 ポンプ
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a continuous hot-dip plating method and apparatus for suppressing the amount of zinc fume generated in a snout in a hot-dip plating process.
[0002]
[Prior art]
In recent years, hot-dip galvanized steel sheets having excellent corrosion resistance have been increasingly used as surface-treated steel sheets for automobiles and home appliances. After the steel strip is annealed in a reducing atmosphere furnace, the steel strip is cooled, passed through a furnace called a snout connecting the annealing furnace and the plating bath, and immersed in the molten zinc bath. Further, thereafter, the wiping nozzle is adjusted to an appropriate plating adhesion amount. In the hot-dip galvanizing process, fumes have been generated from the zinc bath surface inside the snout, and the fume adheres and accumulates on the snout wall, partially peels and falls, and directly adheres to the steel plate before plating, It is known that the steel sheet falls to the bath surface and adheres to the steel strip while floating on the zinc bath surface, thereby impairing the appearance of the steel plate after plating.
[0003]
As a countermeasure, for example, as disclosed in JP-A-6-339346, the temperature distribution of the snout wall is applied to fumes generated from the surface of the zinc bath in the snout to generate natural convection, and the continuous furnace side is used. Forcibly transport to the upstream side from the snout mounting part, to suppress adhesion and growth on the inner wall of the snout, and to provide a low-temperature part in the turndown roll chamber to precipitate metal fume, furthermore, in the snout There has been proposed a method in which a plurality of electric heaters are sectioned on an outer wall of a snout to generate natural convection.
[0004]
[Problems to be solved by the invention]
However, when natural convection is generated inside the snout, the zinc fume concentration gradient on the surface of the snout bath increases, and the amount of generated fume is accelerated. As a result, the fume concentration inside the snout is almost the same as when natural convection does not occur, and since the amount of fume deposited in the low temperature part of the turndown roll chamber further increases, the production of the line is stopped and the furnace is opened, It becomes necessary to perform cleaning.
[0005]
[Means for Solving the Problems]
The present invention has been made in view of the above problems, and a steel strip is heated and annealed under a reducing atmosphere in a continuous annealing furnace, and a turndown roll chamber and a snout are separated from the surrounding atmosphere from the continuous annealing furnace. In the continuous hot-dip plating method of performing plating by introducing into a hot-dip metal plating bath through the above, the space between the inside of the snout and the inside of the annealing furnace was sealed, and the temperature deviation in the snout was set to 50 ° C. or less.
[0006]
Also, heating the steel strip in a reducing atmosphere, a continuous annealing furnace for annealing, in a continuous hot dipping apparatus comprising a snout for partitioning from the ambient atmosphere of the steel strip introduced from該連connection annealing furnace into the molten metal plating bath, on the upstream side or / and downstream side of the turndown roll, above and below the steel strip, by Rukoto provided a partition plate so that the distance between the steel strip and 30mm or less, and within 50 ° C. the temperature deviation in the snout Thus, the space between the snout and the inside of the annealing furnace was sealed.
Furthermore, a heating device is divided into a plurality of sections and installed on a steel shell of the snout and a turn-down roll chamber disposed above the snout, and a heat insulating material is installed outside the heating apparatus. Provided with a temperature detector, and a temperature controller for controlling an applied voltage to a plurality of divided heating devices based on a temperature measurement result input from the temperature detector.
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
FIG. 1 shows a schematic diagram of an apparatus according to the present invention. FIG. 1A is an overall schematic view, FIG. 1B shows a case where partition plates are installed above and below a turndown roll, and FIG. 1C shows a partition plate upstream of a turndown roll portion. FIG. The steel strip 1 is annealed in an annealing furnace heating zone 2 and cooled in a cooling zone 3 to make the temperature of the hot dip galvanizing bath 5 and the steel strip 1 almost the same, and then passes through a snout 4 via a turndown roll 6. , it is immersed into the zinc bath 7. On the continuous annealing furnace side from the turndown rolls 6, a roll 8 that is in contact with both the upper and lower surfaces of the steel strip 1 is attached, and a partition plate 9 having a gap of 5 mm or less is provided between the roll 8 and the furnace body. An electric heater 5 is installed on the wall of the snout 4 so that the temperature difference from the zinc bath is within 50 ° C. The outside of the electric heater 5 is covered with a heat insulating material 10, and the outside of the heat insulating material 10 is further covered with a stainless steel plate 11.
[0008]
In addition, as a method for sealing the snout 4 and the continuous furnace side, as shown in FIG. 1B, a partition plate having a distance of 30 mm or less from the turndown roll 6 is installed above and below the turndown roll 6. In some cases, as shown in FIG. 1C, a partition plate having a distance of 30 mm or less from the steel plate is provided upstream or downstream of the turndown roll unit 6.
In the present apparatus, the reason why the temperature difference in the snout was set to 50 ° C. or less was to prevent convection in the snout, and when the snout wall temperature was changed in the experiment, the temperature difference in the snout exceeded 50 ° C. As it became larger, natural convection began to occur strongly, at which time the amount of zinc vapor leaking to the continuous furnace side increased.
[0009]
This is thought to be due to the fact that the zinc vapor in the snout was saturated, causing natural convection, which disrupted the vapor-liquid equilibrium on the surface of the zinc bath, resulting in an increase in the amount of zinc vapor generated. . In the case where the snout was not heated during the operation, the plate path portions on the upper and lower surfaces of the snout furnace body were heated to about 100 ° C. higher than the portion deviated from the plate path due to the radiation of the steel sheet holding heat. For this reason, it adjusted by the heating zone divided into several and made the snout wall temperature uniform.
Further, the gap between the cutting plate 9 and the steel strip 1 specification in claims 2 was 30mm below are to approximate as much as possible saturated zinc vapor inside the snout, the strip 1 and the partition plate 9 or turndown roll The thickness was set to 30 mm or less as a range where the contact trouble 6 and the partition plate 9 did not cause a contact trouble in actual operation.
[0010]
【Example】
FIG. 2 is a schematic diagram showing a turndown roll section of the device according to the present invention. The amount of fume moving from the turndown roll to the continuous furnace side when the temperature distribution was applied to the snout wall was measured in the snout 4 of the continuous hot-dip galvanizing with the apparatus as shown in FIG. For the measurement of the amount of fume generation, a measurement port 13 was attached to the furnace body on the upstream side of the turndown roll, the gas in the furnace was suctioned by the pump 14, the fume was collected by the filter paper 12, and the weight was measured. At that time, the piping from the furnace body to the filter paper 12 was heated so that the zinc fume did not dew. As a result, the temperature difference of the snout wall was added, and the fume generation increased. In addition, when a seal device having a gap of 10 mm with the steel strip is installed in the turndown roll, the amount of fume generated on the continuous furnace side from the seal device is reduced, and the temperature difference between the steel plate and the snout wall is set to 50 ° C or less. The fume volume in the case was reduced to 1/10 that of the case without the sealing device.
In addition, when the snout wall was heated by an electric heater, the amount of fume leakage to the continuous furnace side when the distance of the partition plate from the steel strip installed on the turndown roll was changed was investigated. The amount of fume leakage increased in proportion to the distance between the steel strip and the partition.
[0011]
【The invention's effect】
According to the present invention, the amount of zinc vapor generated from the zinc bath surface in the snout decreases, and a galvanized steel sheet having a good surface appearance can be manufactured without stopping production of a continuous hot-dip galvanizing line. .
[Brief description of the drawings]
FIG. 1 is a schematic diagram of an apparatus according to the present invention.
FIG. 2 is a schematic diagram showing a turndown roll section of the device according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Steel strip 2 Annealing furnace heating zone 3 Cooling zone 4 Snout 5 Electric heater 6 Turndown roll 7 Zinc bath 8 Roll 9 Partition plate 10 Insulation material 11 Stainless steel plate 12 Filter paper 13 Measurement port 14 Pump

Claims (3)

鋼帯を連続焼鈍炉での還元性雰囲気下で加熱、焼鈍し、該連続焼鈍炉から周囲雰囲気から区画されたターンダウンロール室およびスナウトを介して溶融金属めっき浴へ導入してめっきを行なう連続溶融めっき方法において、前記スナウト内と前記焼鈍炉内との間をシールし、スナウト内の温度偏差を50℃以内としたことを特徴とする連続溶融めっき方法。The steel strip is heated and annealed in a reducing atmosphere in a continuous annealing furnace, and is continuously introduced from the continuous annealing furnace into a molten metal plating bath through a turndown roll chamber and a snout partitioned from an ambient atmosphere to perform plating. A continuous hot-dip plating method, wherein the inside of the snout and the inside of the annealing furnace are sealed, and the temperature deviation in the snout is set to 50 ° C. or less . 鋼帯を還元性雰囲気下で加熱、焼鈍する連続焼鈍炉と、該連続焼鈍炉から溶融金属めっき浴へ導入する鋼帯を周囲雰囲気から区画するスナウトとを具備した連続溶融めっき装置において、ターンダウンロールの上流側あるいは下流側に、前記鋼帯の上下に、鋼帯との間隔を30mm以下となるように仕切り板を設けることにより、スナウト内の温度偏差を50℃以内となるようにスナウト内と前記焼鈍炉内との間をシールしたことを特徴とする連続溶融めっき装置。In a continuous hot-dip plating apparatus having a continuous annealing furnace for heating and annealing a steel strip under a reducing atmosphere, and a snout for separating a steel strip introduced from the continuous annealing furnace into a molten metal plating bath from an ambient atmosphere, on the upstream side or downstream side of the roll, snout above and below the steel strip, by Rukoto provided a partition plate so that the distance between the steel strip becomes 30mm or less, the temperature deviation within the snout to be within 50 ° C. A continuous hot-dip galvanizing apparatus characterized by sealing between the inside and the inside of the annealing furnace. スナウト及びその上部に配置するターンダウンロール室の鉄皮に加熱装置を複数に区画して設置し、且つ、該加熱装置の外側に断熱材を施工し、スナウト及びターンダウンロール室の各部に温度検出器を設け、該温度検出器から入力される測温結果に基づいて複数に区画した加熱装置への印加電圧を制御する温度制御部を設けたことを特徴とする請求項2に記載の連続溶融めっき装置。A heating device is divided into a plurality of sections and placed on the skin of the snout and the turndown roll chamber disposed above the snout, and a heat insulating material is installed outside the heating apparatus. 3. The continuity according to claim 2, further comprising a detector, and a temperature controller configured to control an applied voltage to a plurality of divided heating devices based on a temperature measurement result input from the temperature detector. 4. Hot-dip plating equipment.
JP08837198A 1998-04-01 1998-04-01 Continuous hot-dip plating method and apparatus Expired - Lifetime JP3569439B2 (en)

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