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JP3566162B2 - Hot tool steel with excellent weldability - Google Patents

Hot tool steel with excellent weldability Download PDF

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Publication number
JP3566162B2
JP3566162B2 JP36818199A JP36818199A JP3566162B2 JP 3566162 B2 JP3566162 B2 JP 3566162B2 JP 36818199 A JP36818199 A JP 36818199A JP 36818199 A JP36818199 A JP 36818199A JP 3566162 B2 JP3566162 B2 JP 3566162B2
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Prior art keywords
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weldability
welding
toughness
tool steel
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JP36818199A
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JP2001181782A (en
Inventor
幸生 舘
信博 辻井
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Sanyo Special Steel Co Ltd
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Sanyo Special Steel Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は、熱間加工用金型に用いる溶接性に優れた熱間工具鋼に関するものである。
【0002】
【従来の技術】
従来、熱間鍛造金型、押出しダイス等には、SKD61,SKT4やそれらの改良鋼が使用されている。これらを使用する際、耐摩耗性を付与する目的で、窒化、PVD、CVD等により表面処理を行うことが多い。しかし、表面改質層は硬質ではあるが非常に脆いため割れ・欠けが生じ易く金型の大割れの原因になり、逆に金型寿命を低下させることもある。
【0003】
これに対し、SKD61,SKT4やそれらの改良鋼の金型表面全体または金型の摩耗が激しい部位のみに、耐熱性および耐摩耗性に優れたFe基合金、Co基合金、Ni基合金等の肉盛溶接材および肉盛溶接用粉末材等を肉盛溶接することにより、金型の寿命を改善する手法が用いられているが、これら従来鋼はC含有量が多いために、溶接時の急速加熱および溶接後の急冷により溶接部近傍の型材は一部焼入れ状態となるため、硬化され脆くなり溶接割れを引き起こす。また、溶接による熱影響部(HAZ)に高い残留応力が発生し、鍛造金型として使用中にこれが起因して割れが発生することがある。さらには、金型母材と本来使用したい肉盛材とを冶金的に継ぐ層を形成するため、緩衝材としての下盛り溶接が必要となる。
【0004】
【発明が解決しようとする課題】
上述したような従来の金型鋼では、溶接割れを生じる危険性が高い。さらに、下盛り溶接が必要である分、密着強度が悪く、また溶接工数および溶接費用が高い。また、金型の一部に肉盛溶接を行う場合では、下盛り溶接を行う分だけ余分に金型母材を研削する必要が生じ、加工時間、費用が掛かるという問題がある。
【0005】
【課題を解決するための手段】
上述したような従来の問題を解消するために、本発明者らは、鋭意開発を進めた結果、適正な成分設計を行うことにより、溶接時の金型母材の割れを抑制し、下盛り溶接を必要とせず金型母材に目的とする溶接材を直接肉盛溶接することが可能とする溶接性に優れた工具鋼にある。また、金型として使用する前に予め耐熱性および耐摩耗性または靱性に優れた材質を肉盛溶接することを前提としているため、金型母材には必要以上の硬さ、耐摩耗性は不要であり、金型の割れやヒートチェックの抑制のために靱性を重視した成分設計が成されたものである。
【0006】
その発明の要旨とするところは、
(1)重量%で、C:0.10〜0.30%、Si:0.5%未満、Mn:1.0%以下、Cr:1.0〜3.0%、V:0.2〜0.6%、Nb:0.01〜0.10%、Mo,Wの1種または2種をMo当量(Mo+1/2W)で0.2〜2.0%を含有し、残部Feおよび不可避的不純物からなる鋼を500℃以上で焼戻しを行うことにより、その硬さが36〜42HRCでプリハードンで使用することを特徴とする溶接性に優れた熱間工具鋼。
【0007】
(2)前記(1)に記載の成分組成に、さらにNi:0.3〜1.1%、Co:0.2〜1.0%の1種または2種を添加したことを特徴とする溶接性に優れた熱間工具鋼。
(3)前記(1)〜()に記載の成分組成に、さらに、S:0.10%以下、P:0.030%以下、Pb:0.030〜0.20%、Te:0.010〜0.050%、Ca:0.0003〜0.020%、Bi:0.005〜0.10%、Se:0.010〜0.10%の1種または2種以上を添加したことを特徴とする溶接性に優れた熱間工具鋼。
【0008】
(4)前記(1)〜()に記載の成分組成に、さらにAl:0.05%以下、O:0.0050%以下、N:0.050%以下としたことを特徴とする溶接性に優れた熱間工具鋼にある。
【0009】
【発明の実施の形態】
以下、本発明について詳細に説明する。まず、本発明に係る成分組成の限定理由について説明する。
C:0.10〜0.30%
Cは、焼入れ焼戻しにより十分なマトリックス硬さを与え、金型に必要な強度を付与するための元素である。しかし、0.1%未満では金型として必要な強度が得られず金型の変形を招き、プリハードンにて使用する際の36〜42HRCの硬さが得られず、0.3%を超えると溶接性が低下し溶接時に下盛りが必要になり、プリハードンした際に炭化物生成元素と結合し42HRCを超える硬さとなり型加工が困難となる。ただし、より溶接性を高位水準に保つためには、0.10%以上0.25%未満とするのが望ましい。
【0010】
Si:1.0%以下
Siは脱酸剤として添加されると共に、耐酸化性、焼入性に有効であり、焼戻し過程において炭化物の凝集を抑え二次硬化を促進する。しかし、過剰に添加すると溶接性が低下し、靱性、耐ヒートチェック性も低下するので、1.0%以下、好ましくは0.5%未満とする。
Mn:1.0%以下
MnはSiと同様に、脱酸剤として鋼の清浄度を高め、焼入性を高める元素である。また、Sと結合し、被削性を向上させる。1.0%を超えると溶接性、靱性を低下させる。従って、上限を1.0%以下とした。
【0011】
Cr:1.0〜3.0%
Crはマトリックスに固溶して焼入性を高め、焼戻し時に微細な炭化物を形成し硬さを確保する。しかし、1.0%未満では効果が得られず、2.5%を超えると炭化物が凝集し靱性を低下させる。従って、その範囲を1.0〜3.0%とした。なお、1.0%以上2.6%未満がより好ましい。
【0012】
V:0.2〜0.6%
Vは安定な炭化物を形成し硬さを寄与し焼戻し軟化抵抗性を高め、結晶粒微細化効果が大きく靱性を向上させる。特に、肉盛溶接における熱影響部(HAZ)の結晶粒粗大化を抑制し、HAZの靱性を高位水準に保ち溶接割れを抑制するのに有効である。さらに、金型として使用中にHAZからの割れを抑制するのにも有効である。0.2%未満では上記の硬化が小さく、0.6%を超えると炭化物の凝集により靱性が低下する。なお、好ましくは0.3〜0.6%とする。
【0013】
Mo,Wの1種または2種をMo当量(Mo+1/2W)で0.2〜2.0%Mo,Wは微細な炭化物を形成し、二次硬化に寄与し、軟化抵抗性を改善し、耐ヒートチェック性を向上させる元素であり、その効果はMoがWの2倍ある。Mo当量(Mo+1/2W)で0.2%未満ではその効果が不十分であり、2.0%以上含有すると靱性の低下を招く。従って、その範囲を0.2〜2.0%とした。
【0014】
Nb:0.01〜0.10%
Nbは安定な炭化物を形成し硬さを寄与し焼戻し軟化抵抗性を高め、結晶粒微細化効果が大きく靱性を向上させる。特に、肉盛溶接における熱影響部(HAZ)の結晶粒粗大化を抑制し、HAZの靱性を高位水準に保ち溶接割れを抑制するのに有効である。さらに、金型として使用中にHAZからの割れを抑制するのにも有効である。Vよりもその効果は大きく、0.01%以上の添加が有効であり、0.10%を超えると逆に靱性が低下する。
【0015】
Ni:0.3〜1.1%
Niはマトリックス自体の靱性を高める元素である。しかし、0.3%未満では効果がなく、1.1%を超えて添加しても効果が飽和する。従って、その範囲を0.3〜1.1%とした。
Co:0.2〜1.0%
Coは焼戻しによる炭化物の凝集粗大化を抑制し、軟化抵抗性を高める。これらの効果を得るには0.2%が必要であり、1.0%を超えて添加すると靱性が低下する。従って、その範囲を0.2〜1.0%とした。
【0016】
S:0.10%以下
SはMnと結合して被削性を付与する元素である。必要に応じて添加するが、0.10%を超えて添加すると靱性、熱間加工性および耐ヒートチェック性が低下する。従って、その上限を0.10%とした。
P:0.030%以下
Pは被削性を向上する元素である。しかし、含有量が少ないと効果が得られず、あまり多量に添加すると靱性が低下し、また本発明に重要な溶接性を低下させる。従って、その上限を0.030%とした。
【0017】
Pb:0.030〜0.20%、Te:0.010〜0.050%、Ca:0.0003〜0.020%、Bi:0.005〜0.10%、Se:0.010〜0.10%の1種または2種以上
Pb,Te,Ca,Bi,Seはいずれも被削性を向上する元素である。必要に応じて添加するが、しかし、含有量が少ないと上記の効果が得られず、逆に多量に添加すると靱性および耐ヒートチェック性が低下するとともに地疵の発生を招く。
【0018】
Al:0.05%以下
Alは脱酸剤として添加される。過剰に添加すると靱性が低下するため、上限を0.05%とする。
O:0.0050%以下
Oは鋼中に過剰に存在すると粗大な酸化物を形成し、靱性および被削性を低下させるため、上限を0.0050%とする。
N:0.050%以下
Nは鋼中に過剰に存在すると溶接性を低下させるため、上限を0.0050%とする。
【0019】
【実施例】
以下に、本発明を実施例によって具体的に説明する。
表1に示した本発明鋼を100kg真空誘導溶解炉にて出鋼し、平均径200mmの鋳塊に鋳込み、これを鍛伸して供試材とした。各特性試験としての溶接性試験については、表2に示す溶接条件にて角50mm×100mm長さの試験片の開先部に溶接材料を肉盛溶接し、その後、試験片溶接部の断面を観察した。
また、機械特性としては、機械的特性評価方法とし靱性については、2mm−Uノッチ試験片(試験片硬さが42HRCのもの)によるシャルピー衝撃試験、また、軟化抵抗性については、600℃にて30時間保持、空冷後の硬さ(初期硬さ:42HRC)さらに、被削性については、40HRC材をエンドミルで3m切削した時のエンドミルの逃げ面摩耗幅を求めた。その結果を表3に示す。表3に示すように、供試材A〜の本発明鋼はいずれも溶接性試験において割れがなく、靱性、軟化抵抗性に優れているに対して、比較鋼であるH,Iのいずれも割れの発生し、靱性、軟化抵抗性にも劣ることが判る。また、本発明鋼は、比較鋼と同等以上の被削性を有することが判る。
【0020】
【表1】

Figure 0003566162
【0021】
【表2】
Figure 0003566162
【0022】
【表3】
Figure 0003566162
【0023】
【発明の効果】
以上述べたように、本発明により溶接性に優れ、肉盛溶接工数を削減することによる低コストで高寿命な肉盛補強金型の製造を可能にせしめた金型用鋼を提供することが出来る極めて優れた効果を奏するものである。[0001]
TECHNICAL FIELD OF THE INVENTION
TECHNICAL FIELD The present invention relates to a hot work tool steel having excellent weldability used for a hot working mold.
[0002]
[Prior art]
Conventionally, SKD61, SKT4 and their improved steels have been used for hot forging dies, extrusion dies and the like. When these are used, they are often subjected to surface treatment by nitriding, PVD, CVD or the like for the purpose of imparting wear resistance. However, although the surface modified layer is hard but very brittle, cracking and chipping are likely to occur, causing large cracks in the mold, and conversely, shortening the mold life.
[0003]
On the other hand, Fe-based alloys, Co-based alloys, Ni-based alloys and the like, which are excellent in heat resistance and wear resistance, are provided only on the entire surface of the mold of SKD61, SKT4 or their improved steels or only in the parts where the mold is severely worn. A method has been used to improve the life of the mold by overlay welding of overlay welding material and overlay welding powder material. However, since these conventional steels have a large C content, the conventional steel has a large C content. Due to rapid heating and quenching after welding, the shape near the weld becomes partially quenched, so that it becomes hardened and brittle, causing weld cracking. In addition, a high residual stress is generated in the heat-affected zone (HAZ) by welding, which may cause cracks during use as a forging die. Furthermore, in order to form a metallurgical layer which connects the mold base material and the overlay material to be used originally, it is necessary to perform underlay welding as a cushioning material.
[0004]
[Problems to be solved by the invention]
In the conventional mold steel as described above, there is a high risk of welding cracks. Further, the need for underlay welding results in poor adhesion strength, and high welding man-hours and welding costs. In addition, in the case where overlay welding is performed on a part of the mold, it is necessary to grind the mold base material extra for performing the underlay welding, and there is a problem that processing time and cost are increased.
[0005]
[Means for Solving the Problems]
In order to solve the conventional problems as described above, the present inventors have intensively developed and as a result, by performing appropriate component design, the crack of the mold base material during welding is suppressed, and A tool steel excellent in weldability that enables direct welding of a target welding material to a mold base material without requiring welding. In addition, since it is assumed that a material excellent in heat resistance, wear resistance, or toughness is welded in advance before use as a mold, the mold base material must have excessive hardness and wear resistance. It is unnecessary, and the component design is made with emphasis on toughness to suppress mold cracking and heat check.
[0006]
The gist of the invention is that
(1) By weight%, C: 0.10 to 0.30%, Si: less than 0.5% , Mn: 1.0% or less, Cr: 1.0 to 3.0%, V: 0.2 0.6%, Nb: 0.01 to 0.10% , one or two of Mo and W containing 0.2 to 2.0% by Mo equivalent (Mo + 1 / 2W), and the balance of Fe and A hot work tool steel excellent in weldability, characterized in that steel consisting of unavoidable impurities is tempered at 500 ° C. or higher to have a hardness of 36 to 42 HRC and to be used as a pre-hardened steel.
[0007]
(2) One or two types of Ni: 0.3 to 1.1% and Co: 0.2 to 1.0% are further added to the component composition described in the above (1). Hot tool steel with excellent weldability.
(3) S: 0.10% or less, P: 0.030% or less, Pb: 0.030 to 0.20%, Te: 0 in addition to the component composition described in the above (1) to ( 2 ). One or two or more of 0.010 to 0.050%, Ca: 0.0003 to 0.020%, Bi: 0.005 to 0.10%, Se: 0.010 to 0.10% were added. A hot work tool steel with excellent weldability, characterized in that:
[0008]
(4) Welding wherein the component composition described in (1) to ( 3 ) above is further reduced to Al: 0.05% or less, O: 0.0050% or less, and N: 0.050% or less. In hot work tool steel with excellent heat resistance .
[0009]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in detail. First, the reasons for limiting the component composition according to the present invention will be described.
C: 0.10 to 0.30%
C is an element for imparting sufficient matrix hardness by quenching and tempering and imparting necessary strength to a mold. However, if it is less than 0.1%, the strength required for the mold is not obtained, and the mold is deformed, and the hardness of 36 to 42 HRC when used in pre-hardened cannot be obtained, and exceeds 0.3%. In addition, lower weldability is required during welding, and a lower slab is required at the time of welding. When pre-hardened, it is combined with a carbide-forming element, resulting in a hardness exceeding 42 HRC, which makes molding difficult. However, in order to maintain the weldability at a higher level, it is desirable that the content be 0.10% or more and less than 0.25%.
[0010]
Si: 1.0% or less Si is added as a deoxidizing agent and is effective in oxidation resistance and hardenability, and suppresses agglomeration of carbides during tempering to promote secondary hardening. However, if added excessively, the weldability is reduced, and the toughness and heat check resistance are also reduced. Therefore, the content is set to 1.0% or less, preferably less than 0.5%.
Mn: 1.0% or less Mn, like Si, is an element that increases the cleanliness of steel and enhances hardenability as a deoxidizing agent. In addition, it combines with S to improve machinability. If it exceeds 1.0%, the weldability and toughness are reduced. Therefore, the upper limit is set to 1.0% or less.
[0011]
Cr: 1.0 to 3.0%
Cr forms a solid solution in the matrix to enhance hardenability, and forms fine carbides during tempering to secure hardness. However, if the content is less than 1.0%, no effect can be obtained, and if it exceeds 2.5%, carbides are aggregated and the toughness is reduced. Therefore, the range was set to 1.0 to 3.0%. In addition, 1.0% or more and less than 2.6% are more preferable.
[0012]
V: 0.2-0.6%
V forms stable carbides, contributes to hardness, increases tempering softening resistance, has a large effect of refining crystal grains, and improves toughness. In particular, it is effective in suppressing the coarsening of the crystal grains in the heat-affected zone (HAZ) in overlay welding, maintaining the toughness of the HAZ at a high level, and suppressing welding cracks. Further, it is effective in suppressing cracks from HAZ during use as a mold. If it is less than 0.2%, the above-mentioned hardening is small, and if it exceeds 0.6%, toughness is reduced due to aggregation of carbides. In addition, it is preferably set to 0.3 to 0.6%.
[0013]
One or two of Mo and W are Mo equivalent (Mo + 1 / 2W) at 0.2 to 2.0% Mo and W form fine carbides, contribute to secondary hardening, and improve softening resistance. Mo is an element that improves heat check resistance, and the effect of Mo is twice that of W. If the Mo equivalent (Mo + 1 / 2W) is less than 0.2%, the effect is insufficient, and if the Mo equivalent is 2.0% or more, the toughness is reduced. Therefore, the range is set to 0.2 to 2.0%.
[0014]
Nb: 0.01 to 0.10%
Nb forms stable carbides, contributes to hardness, increases tempering softening resistance, and has a large crystal grain refining effect to improve toughness. In particular, it is effective in suppressing the coarsening of the crystal grains in the heat-affected zone (HAZ) in overlay welding, maintaining the toughness of the HAZ at a high level, and suppressing welding cracks. Further, it is effective in suppressing cracks from HAZ during use as a mold. The effect is larger than that of V, and the addition of 0.01% or more is effective, and when it exceeds 0.10%, the toughness is reduced.
[0015]
Ni: 0.3 to 1.1%
Ni is an element that increases the toughness of the matrix itself. However, if it is less than 0.3%, there is no effect, and if it exceeds 1.1%, the effect is saturated. Therefore, the range was set to 0.3 to 1.1%.
Co: 0.2-1.0%
Co suppresses agglomeration and coarsening of carbides due to tempering and enhances softening resistance. To obtain these effects, 0.2% is required, and if added over 1.0%, toughness is reduced. Therefore, the range is set to 0.2 to 1.0%.
[0016]
S: 0.10% or less S is an element that combines with Mn to impart machinability. It is added as needed, but if added in excess of 0.10%, toughness, hot workability and heat check resistance are reduced. Therefore, the upper limit is set to 0.10%.
P: 0.030% or less P is an element that improves machinability. However, if the content is small, the effect cannot be obtained, and if added in too large a quantity, the toughness is reduced, and the weldability important for the present invention is reduced. Therefore, the upper limit is set to 0.030%.
[0017]
Pb: 0.030 to 0.20%, Te: 0.010 to 0.050%, Ca: 0.0003 to 0.020%, Bi: 0.005 to 0.10%, Se: 0.010 to 10% One or more of 0.10% of Pb, Te, Ca, Bi, and Se are elements that improve machinability. However, if the content is small, the above effects cannot be obtained. Conversely, if the content is large, the toughness and heat check resistance are reduced, and ground flaws are caused.
[0018]
Al: 0.05% or less Al is added as a deoxidizing agent. If added in excess, the toughness decreases, so the upper limit is made 0.05%.
O: 0.0050% or less When O is excessively present in steel, it forms a coarse oxide and lowers toughness and machinability, so the upper limit is made 0.0050%.
N: 0.050% or less If N is excessively present in steel, the weldability is reduced, so the upper limit is made 0.0050%.
[0019]
【Example】
Hereinafter, the present invention will be described specifically with reference to Examples.
The steel of the present invention shown in Table 1 was tapped in a 100 kg vacuum induction melting furnace, cast into an ingot having an average diameter of 200 mm, and forged to obtain a test material. For the weldability test as each characteristic test, the welding material was overlay-welded to the groove of a test piece having a square of 50 mm x 100 mm under the welding conditions shown in Table 2, and then the cross section of the test piece weld was Observed.
As for the mechanical properties, a mechanical property evaluation method was used. For toughness, a Charpy impact test using a 2 mm-U notch test piece (with a test piece hardness of 42 HRC), and for softening resistance, at 600 ° C. Hardness after holding for 30 hours and air cooling (initial hardness: 42 HRC) Further, as for machinability, the flank wear width of the end mill when the 40 HRC material was cut by 3 m with an end mill was determined. Table 3 shows the results. As shown in Table 3, neither the present invention steel test materials A to G had no cracks in the welding test, toughness, relative to have excellent softening resistance, either is H, the I and comparative steels It is also found that cracks occur and the toughness and the softening resistance are inferior. Further, it is understood that the steel of the present invention has machinability equal to or higher than that of the comparative steel.
[0020]
[Table 1]
Figure 0003566162
[0021]
[Table 2]
Figure 0003566162
[0022]
[Table 3]
Figure 0003566162
[0023]
【The invention's effect】
As described above, according to the present invention, it is possible to provide a mold steel excellent in weldability and capable of manufacturing a low-cost, long-life overlay reinforcing mold by reducing the number of overlay welding steps. This is an extremely excellent effect that can be achieved.

Claims (4)

重量%で、
C:0.10〜0.30%、
Si:0.5%未満、
Mn:1.0%以下、
Cr:1.0〜3.0%、
V:0.2〜0.6%、
Nb:0.01〜0.10%
Mo,Wの1種または2種をMo当量(Mo+1/2W)で0.2〜2.0%を含有し、残部Feおよび不可避的不純物からなる鋼を500℃以上で焼戻しを行うことにより、その硬さが36〜42HRCでプリハードンで使用することを特徴とする溶接性に優れた熱間工具鋼。
In weight percent,
C: 0.10 to 0.30%,
Si: less than 0.5%,
Mn: 1.0% or less,
Cr: 1.0 to 3.0%,
V: 0.2-0.6%,
Nb: 0.01 to 0.10%
By tempering a steel containing one or two of Mo and W in a Mo equivalent (Mo + 1 / 2W) of 0.2 to 2.0% and a balance of Fe and unavoidable impurities at 500 ° C. or more, A hot work tool steel excellent in weldability, characterized in that its hardness is 36 to 42 HRC and used in pre-hardened .
請求項1に記載の成分組成に、さらにNi:0.3〜1.1%、Co:0.2〜1.0%の1種または2種を添加したことを特徴とする溶接性に優れた熱間工具鋼。Excellent weldability characterized by further adding one or two types of Ni: 0.3 to 1.1% and Co: 0.2 to 1.0% to the component composition according to claim 1. Hot tool steel. 請求項1〜2に記載の成分組成に、さらに、The component composition according to claim 1 or 2, further comprising:
S:0.10%以下、S: 0.10% or less,
P:0.030%以下、P: 0.030% or less,
Pb:0.030〜0.20%、Pb: 0.030 to 0.20%,
Te:0.010〜0.050%、Te: 0.010 to 0.050%,
Ca:0.0003〜0.020%、Ca: 0.0003-0.020%,
Bi:0.005〜0.10%、Bi: 0.005 to 0.10%,
Se:0.010〜0.10%Se: 0.010 to 0.10%
の1種または2種以上を添加したことを特徴とする溶接性に優れた熱間工具鋼。A hot work tool steel excellent in weldability, characterized by adding one or more of the following.
請求項1〜3に記載の成分組成に、さらにAl:0.05%以下、O:0.0050%以下、N:0.050%以下としたことを特徴とする溶接性に優れた熱間工具鋼。4. A hot weld excellent in weldability, characterized by further comprising Al: 0.05% or less, O: 0.0050% or less, and N: 0.050% or less in the component composition according to claim 1. Tool steel.
JP36818199A 1999-12-24 1999-12-24 Hot tool steel with excellent weldability Expired - Fee Related JP3566162B2 (en)

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