JP3378972B2 - Peeling cosmetics - Google Patents
Peeling cosmeticsInfo
- Publication number
- JP3378972B2 JP3378972B2 JP18626695A JP18626695A JP3378972B2 JP 3378972 B2 JP3378972 B2 JP 3378972B2 JP 18626695 A JP18626695 A JP 18626695A JP 18626695 A JP18626695 A JP 18626695A JP 3378972 B2 JP3378972 B2 JP 3378972B2
- Authority
- JP
- Japan
- Prior art keywords
- powder
- skin
- feeling
- fibrous powder
- fibrous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002537 cosmetic Substances 0.000 title description 24
- 239000000843 powder Substances 0.000 description 84
- 239000000835 fiber Substances 0.000 description 25
- 239000008187 granular material Substances 0.000 description 15
- 239000002245 particle Substances 0.000 description 12
- 238000005201 scrubbing Methods 0.000 description 12
- 239000002699 waste material Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- -1 more specifically Substances 0.000 description 6
- 229920001778 nylon Polymers 0.000 description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 5
- 235000013339 cereals Nutrition 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- 238000003892 spreading Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 229920003169 water-soluble polymer Polymers 0.000 description 3
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- OIKBVOIOVNEVJR-UHFFFAOYSA-N hexadecyl 6-methylheptanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCC(C)C OIKBVOIOVNEVJR-UHFFFAOYSA-N 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 235000011437 Amygdalus communis Nutrition 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KXKPYJOVDUMHGS-OSRGNVMNSA-N chondroitin sulfate Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](OS(O)(=O)=O)[C@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](C(O)=O)O1 KXKPYJOVDUMHGS-OSRGNVMNSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000009725 powder blending Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
【発明の詳細な説明】
【0001】
【産業上の利用分野】本発明は、適度なスクラブ感があ
り、かつ使用感に優れたピーリング化粧料に関する。
【0002】
【従来の技術】一般に、ピーリング化粧料とは、皮膚の
老廃物や付着した汚れを除去することを目的とした化粧
料であり、その具体的除去法としては、物理的に老廃物
等を除去する方法や、化学的に溶解させて除去する方法
が知られている。物理的な方法を用いた化粧料として
は、有機粉末、無機粉末もしくはそれらの複合物を用い
て、その粉末の摩擦作用を利用したものがある。例え
ば、鉱物性粉体を用いたもの(特公昭60−15680
号公報)、米、タピオカ等の植物性粉体を用いたもの
(特開昭61−7208号公報)、セルロース加工物を
用いたもの(特公平5−60446号公報、特開昭63
−238008号公報)、短繊維の凝集体を用いたもの
(特開昭62−238211号公報)等が知られてい
る。また水溶性高分子や肌の老廃物への密着性が高い粉
末等を用いて、その吸着作用を利用したものがある。例
えば、ポリビニルアルコールを用いたもの(特公昭60
−50766号公報)が知られている。化学的な方法を
用いた化粧料としては、例えば、サリチル酸誘導体によ
る角質溶解によるもの(特開昭62−26224号公
報)が知られている。
【0003】
【発明が解決しようとする課題】前記粉末等を配合した
ピーリング化粧料は、使用時の物理的なスクラブ作用ま
たは吸着作用を利用して、皮膚の老廃物や汚れを清浄
し、かつ、その時にかかる力を利用して肌の血行促進等
のマッサージ効果が得られる有用なものであり、このよ
うな観点で作られた製品が従来大部分であった。粉末を
加工、例えば細かくした粉末を用いたものは、清浄効果
は高いが、使用中のスクラブ作用は得られにくかった。
また、短繊維状の粉末を固体油剤等で処理を施した短繊
維の凝集体を用いたものは、ソフトなスクラブ作用は得
られるが、清浄効果はやや不十分であった。また、水溶
性高分子の吸着作用を用いたものは、十分な清浄効果は
得られるが、粘着力が強すぎるため肌への負担が大き
く、肌あれ等を引き起こす原因になる場合もあった。化
学的に角質を溶解する方法についても、肌への負担が大
きく、肌荒れ時や、肌に傷があるときなどには、肌に炎
症を引き起こす場合があった。このように、配合する粉
末等に様々な研究が行われてきたが、粉末の粒径、形
状、性質に着目し、肌への作用を研究したものはみられ
なかった。
【0004】
【課題を解決するための手段】かかる事情において、本
発明者等は鋭意研究を行った結果、上記の問題を解決す
べく、長短二種類の繊維状粉末と、スクラブ作用を高め
るために特定の粒径を有する粉粒体とを、特定割合で特
定量配合すれば一層優れたピーリング化粧料が得られる
ことを見いだし、これらの知見をもって本発明を完成さ
せたのである。
【0005】すなわち、本発明は、(a)成分〜(c)
成分
(a)繊維長が0.8〜1.5mmの短繊維状粉末
(b)繊維長が前記(a)成分の短繊維状粉末の2倍以
上であり、かつ5mm以下である長繊維状粉末
(c)平均粒径が0.5〜1.5mmの粉粒体
を含有し、かつ、繊維状粉末の配合量比率b/aが0.
5〜7であり、繊維状粉末と粉粒体の配合量比率(a+
b)/cが0.5〜10であり、更に、総配合量(a+
b+c)が5〜20重量%であることを特徴とするピー
リング化粧料を提供するものである。
【0006】本発明で使用する(a)成分である繊維長
が0.8〜1.5mmの短繊維状粉末は、例えば、セル
ロース系、ポリエステル系、ポリアミド系、ポリアクリ
ロニトリル系繊維、より具体的には、レーヨン、アセテ
ート、ナイロン、テトロン、アクリル等の合成繊維や、
羊毛、絹繊維等の天然繊維が挙げられる。これらは必要
に応じて一種または二種以上の組み合わせで用いること
ができ、太さは400μm以下のものが好ましく用いら
れる。これら短繊維状粉末は、針状、棒状、円筒状など
その形状を問わない。なお、公知の方法を用いてこれら
短繊維状粉末に表面処理を施しても良い。
【0007】短繊維状粉末の繊維長が0.8mm未満で
ある場合には、肌への密着性が高くなりすぎて、短繊維
状粉末を除去するときに、かなりの力が必要となるとと
もに、また、その時間も必要以上に要するものとなって
しまう。また、短繊維状粉末の繊維長が1.5mmを超
える場合には、逆に肌への密着性が低くなりすぎて、十
分に老廃物を除去することができなくなってしまう。
【0008】本発明で使用する(b)成分である長繊維
状粉末は、繊維長が前記(a)成分の短繊維状粉末の2
倍以上であり、かつ5mm以下である。長繊維状粉末
は、(a)成分と同様に、例えば、セルロース系、ポリ
エステル系、ポリアミド系、ポリアクリロニトリル系繊
維、より具体的には、レーヨン、アセテート、ナイロ
ン、テトロン、アクリル等の合成繊維や、羊毛、絹繊維
等の天然繊維が挙げられる。これらは必要に応じて一種
または二種以上の組み合わせで用いることができ、太さ
は400μm以下のものが好ましく、また長さは5mm
以下で好ましく用いられる。なお、(a)成分と(b)
成分は同質であっても異質であっても同質と異質の混合
であってもかまわない。これら長繊維状粉末は、針状、
棒状、円筒状などその形状を問わない。なお、公知の方
法を用いてこれら長繊維状粉末に表面処理を施しても良
い。
【0009】長繊維状粉末は、短繊維状粉末とともに配
合され、さらに後述する(c)成分である平均粒径が
0.5〜1.5mmの粉粒体との三種の併用により相乗
効果を発揮する。すなわち、肌への密着性の高い短繊維
状粉末と、肌への密着性の低い長繊維状粉末と、スクラ
ブ作用に優れた粉粒体が、短繊維状粉末の肌への密着性
の良さと清浄効果の良さ、及び粉粒体のスクラブ効果の
良さでもって、適度なスクラブ感をもたらしている。更
に、マッサージのスムース性と肌からの離脱性の良好性
を有する長繊維状粉末により、老廃物を除去した短繊維
状粉末が徐々に肌から離脱し、長繊維状粉末を核としな
がら、短繊維状粉末及び粉粒体が徐々に集まって、皮膚
の老廃物や付着した汚れとともに塊として除去される。
長繊維状粉末の繊維長は、短繊維状粉末の繊維長の3倍
以上であればより好ましい効果が発現する。
【0010】長繊維状粉末の繊維長が短繊維状粉末の繊
維長の2倍未満である場合は、短繊維状粉末と長繊維状
粉末との肌への付着性の差異が僅かになり、肌への密着
性が均一になってしまい「マッサージのスムース性と肌
からの離脱性の良好性を有する長繊維状粉末により、老
廃物を除去した短繊維状粉末が徐々に肌から離脱し、長
繊維状粉末を核としながら、短繊維状粉末及び粉粒体が
徐々に集まって、皮膚の老廃物や付着した汚れとともに
塊として除去される」といったことができず、一気に肌
から離脱するようになってしまい、スクラブ作用がスム
ースに得られなかったり、十分に得られない。
【0011】本発明で使用する(c)成分である平均粒
径が0.5〜1.5mmの粉粒体としては、平均粒径が
該範囲内の、ナイロンパウダー、ポリエチレン末、メチ
ルメタアクリレート粉末、ポリスチレンパウダー、ポリ
テトラフルオロエチレンパウダー、シリコーンパウダー
等の合成樹脂粉体;合成樹脂発泡硬質体;合成樹脂焼結
体;マイクロクリスタリンワックス等の固形ワックス;
クルミ殻粒、アンズ殻粒、アーモンド粗粒、モモ殻粒、
トウモロコシ穂軸粒等の植物の葉・根・茎・実等の粉砕
物;アルミニウム等の金属;粘土、珪藻土、シラス等の
無機物質;無機物質発泡体;無機物質焼結体;無機物質
中空体;化粧料用の体質顔料、無機白色顔料、無機着色
顔料、有機顔料、有機粉末、パール剤等を造粒成形した
ものなどを挙げることができる。また、これら粉粒体は
表面被覆処理を施しても良い。
【0012】粉粒体の平均粒径が0.5mm未満では十
分なスクラブ感が得られない。また、粉粒体の平均粒径
が1.5mmを超える場合はスクラブ感が強くなりす
ぎ、場合によっては痛みが感じられることもあり、好ま
しくない。粉粒体の平均粒径は、より好ましくは0.7
〜1.0mmであり、より良好なスクラブ感が得られ
る。
【0013】短繊維状粉末と長繊維状粉末との繊維状粉
末配合量比率b/aは0.5〜7である。また、繊維状
粉末配合量比率b/aはより好ましくは1〜5である。
繊維状粉末配合量比率b/aが0.5未満の場合は、短
繊維状粉末の比率が高すぎ、使用中スムース性が不足
し、マッサージをしている時刺激感を感じる場合もあ
り、また、肌への密着性が高くなってしまい、長繊維状
粉末を核としながら、短繊維状粉末及び粉粒体が徐々に
集まって、皮膚の老廃物や付着した汚れとともに塊とし
て除去されるまでに必要以上に時間がかかるようにな
る。また、繊維状粉末配合量比率b/aが7を超える場
合は、長繊維状粉末の比率が高すぎ、使用中十分なスク
ラブ感が得られないまま、塊ができてしまう。
【0014】本発明においては、繊維状粉末と粉粒体の
配合量比率(a+b)/cが0.5〜10であることが
必要である。また、繊維状粉末と粉粒体の配合量比率
(a+b)/cがより好ましくは1〜7である。繊維状
粉末と粉粒体の配合量比率(a+b)/cが1未満の場
合は、粉粒体の割合が大きくなって、スクラブ作用が強
くなりすぎ、場合によっては刺激感を感じることもあ
り、好ましくない。繊維状粉末と粉粒体の配合量比率
(a+b)/cが10を超える場合は、粉粒体の割合が
小さくなって、良好なスクラブ感が得られない。
【0015】本発明においては、繊維状粉末と粉粒体の
総配合量(a+b+c)が5〜20重量%であることも
必要である。また、総配合量(a+b+c)は、より好
ましくは10〜15重量%である。繊維状粉末と粉粒体
の総配合量(a+b+c)が5重量%未満の場合は、良
好なピーリング作用が得られなくなってしまう。また、
繊維状粉末と粉粒体の総配合量(a+b+c)が20重
量%を超える場合は、伸びが悪く、また、ざらざらする
など使用性・使用感が悪くなる。
【0016】本発明には、上記必須成分の他、エタノー
ル等の低級アルコール、プロピレングリコール、1,3
−ブチレングリコール、グリセリン、ポリエチレングリ
コール、ソルビトール、マルチトール、コンドロイチン
硫酸ナトリウム、ピロリドンカルボン酸ナトリウム、乳
酸ナトリウム等の保湿剤、流動パラフィン、エステル
油、シリコン油等の油剤、水溶性高分子、電解質、界面
活性剤、紫外線吸収剤、香料、防腐剤等を適宜配合する
ことができる。
【0017】本発明は、上記の如く、長短二種類の繊維
状粉末と、特定の粒径を有する粉粒体とを、特定割合で
特定量配合したピーリング化粧料であり、種々の化粧料
の形態に利用できる。例えば、油と水とを乳化した乳化
物、水性又は油性ゲル化剤を主体としたゲル化物、油、
水、他の液体もしくは乳化液に分散した分散物として、
利用できる。
【0018】本発明のピーリング化粧料の形態は、より
好ましくは乳化液への分散物タイプの振蕩型とするのが
よい。乳化液振蕩型とすれば、肌へ伸ばした時の繊維状
粉末の肌への密着性と、粉粒体の肌へのスクラブ感が、
最も望ましいかたちで発揮され、みずみずしい使用感が
得られるとともに、使用後も良好なさっぱり感が得られ
る。
【0019】
【実施例】次いで実施例を挙げて本発明を更に説明する
が、本発明はこれによって何ら限定されるものではな
い。
実施例1:乳化液振蕩型ピーリング化粧料
以下に示す処方及び製法により、乳化液振蕩型ピーリン
グ化粧料を調製した。
【0020】(処方)
【表1】【0021】
【表2】【0022】
【表3】【0023】
【表4】【0024】(製法)
A.成分(13)〜(18)を均一に溶解する。
B.成分(19)にAを加え乳化をする。
C.成分(1)〜(12)を加えて、均一混合し、乳化
液振蕩型ピーリング化粧料を得る。
【0025】得られた乳化液振蕩型ピーリング化粧料に
ついて、女性25名をパネルとする使用テストを行い、
使用中の適度なスクラブ感、肌への密着感、のばしやす
さ、使用後のさっぱり感、すべすべ感、清浄感につい
て、それぞれについて良好とした人数により、以下の基
準に従い評価した。
【0026】
【0027】女性25名をパネルとする使用テストによ
る、使用中の適度なスクラブ感、肌への密着感、のばし
やすさ、使用後のさっぱり感、すべすべ感、清浄感につ
いて、の評価結果についても表1〜表4に示した。表1
〜表4の結果より明らかなように、本発明品1〜12の
乳化液振蕩型ピーリング化粧料は、比較品1〜12に比
較して、使用中の適度なスクラブ感、肌への密着感、の
ばしやすさ、使用後のさっぱり感、すべすべ感、清浄感
について優れたものであった。
【0028】
実施例2:クリーム状ピーリング化粧料
(処方) (重量%)
1.結晶セルロース粉末(繊維長:1mm) 2.0
2.ナイロン繊維(繊維長:3mm) 4.0
3.ポリスチレンパウダー(平均粒径0.7mm) 3.0
4.流動パラフィン 10.0
5.イソオクタン酸セチル 10.0
6.ワセリン 3.0
7.ステアリン酸 1.5
8.セタノール 1.0
9.セスキオレイン酸ソルビタン 0.5
10.モノオレイン酸ポリオキシエチレンソルビタン 0.5
(20E.O.)
11.1,3−ブチレングリコール 10.0
12.カルボキシビニルポリマー 0.1
13.防腐剤 0.1
14.トリエタノールアミン 0.4
15.香料 0.1
16.精製水 残量
【0029】(製法)
A.成分(4)〜(10)を加熱、溶解する。
B.成分(11)〜(16)を加熱、溶解する。
C.AにBを加え乳化をし、その後冷却をする。
D.成分(1)〜(3)を加えて、均一混合し、クリー
ム状ピーリング化粧料を得る。
本発明のクリーム状ピーリング化粧料は、使用中の適度
なスクラブ感、肌への密着感、のばしやすさ、使用後の
さっぱり感、すべすべ感、清浄感について優れたもので
あった。
【0030】
実施例3:ジェル状ピーリング化粧料
(処方) (重量%)
1.ナイロン繊維(繊維長1mm) 2.0
2.ナイロン繊維(繊維長3mm) 4.0
3.ポリエチレン末(平均粒径0.7mm) 3.0
4.メチルフェニルポリシロキサン 3.0
5.イソオクタン酸セチル 5.0
6.ポリオキシアルキレンメチルポリシロキサン 1.0
7.セスキオレイン酸ソルビタン 0.2
8.モノオレイン酸ポリオキシエチレンソルビタン 0.8
(20E.O.)
9.1,3−ブチレングリコール 10.0
10.カルボキシビニルポリマー 0.3
11.防腐剤 0.1
12.トリエタノールアミン 0.3
13.香料 0.1
14.精製水 残量
【0031】(製法)
A.成分(4)〜(8)を加熱、溶解する。
B.成分(9)〜(14)を加熱、溶解する。
C.AにBを加え乳化をし、その後冷却をする。
D.成分(1)〜(3)を加えて、均一混合し、ジェル
状ピーリング化粧料を得る。
本発明のジェル状ピーリング化粧料は、使用中の適度な
スクラブ感、肌への密着感、のばしやすさ、使用後のさ
っぱり感、すべすべ感、清浄感について優れたものであ
った。
【0032】
【発明の効果】本発明のピーリング化粧料は、使用中の
適度なスクラブ感、肌への密着感、のばしやすさ、使用
後のさっぱり感、すべすべ感、清浄感について優れたも
のであった。Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a peeling cosmetic composition having an appropriate scrub feeling and an excellent feeling upon use. [0002] In general, peeling cosmetics are cosmetics intended to remove waste products and adhered dirt from the skin, and specific methods for removing the waste products are physically waste products. And the like, and a method of chemically dissolving and removing. As a cosmetic using a physical method, there is a cosmetic using an organic powder, an inorganic powder, or a composite thereof and utilizing a frictional action of the powder. For example, those using mineral powder (Japanese Patent Publication No. 60-15680)
JP-A-6-7208), those using vegetable powders of rice, tapioca, etc. (JP-A-61-7208), those using a processed cellulose product (JP-B-5-60446, JP-A-63)
Japanese Unexamined Patent Publication (Kokai) No. 238008/1990) and those using aggregates of short fibers (Japanese Unexamined Patent Publication (Kokai) No. 62-238211) are known. In addition, there is a type using a water-soluble polymer or a powder having high adhesion to waste products of the skin and the like, and utilizing its adsorption action. For example, those using polyvinyl alcohol (Japanese Patent Publication No. 60
No. -50766) is known. As a cosmetic using a chemical method, for example, a cosmetic obtained by dissolving keratin with a salicylic acid derivative (JP-A-62-22624) is known. [0003] The peeling cosmetics containing the above-mentioned powders and the like use a physical scrubbing action or an adsorbing action at the time of use to clean skin waste and dirt, and It is useful because a massage effect such as promotion of blood circulation of the skin can be obtained by utilizing the force applied at that time, and most products manufactured from such a viewpoint have been conventionally used. Processed powders, for example, those using a finer powder, have a high cleaning effect, but have a poor scrubbing effect during use.
In the case of using a short fiber aggregate obtained by treating a short fiber powder with a solid oil or the like, a soft scrubbing action was obtained, but the cleaning effect was somewhat insufficient. Further, those using the water-soluble polymer adsorbing action can provide a sufficient cleaning effect, but have too large an adhesive force to put a heavy burden on the skin, which may cause skin roughness and the like. The method of chemically dissolving keratin also imposes a heavy burden on the skin, and may cause skin irritation when the skin becomes rough or when the skin is damaged. As described above, various studies have been conducted on powders to be blended, but no studies have focused on the particle size, shape, and properties of the powder to study the effects on the skin. [0004] Under these circumstances, the present inventors have conducted intensive studies and as a result, in order to solve the above-mentioned problems, two types of long and short fibrous powders and a method for enhancing the scrubbing action. It has been found that a more excellent peeling cosmetic can be obtained by blending a powder having a specific particle size with a specific amount in a specific ratio, and based on these findings, the present invention has been completed. [0005] That is, the present invention relates to the components (a) to (c)
Component (a) a short fibrous powder having a fiber length of 0.8 to 1.5 mm; Powder (c) contains a powder having an average particle diameter of 0.5 to 1.5 mm, and the blending ratio b / a of the fibrous powder is 0.
5 to 7, and the compounding ratio of the fibrous powder and the granular material (a +
b) / c is 0.5 to 10, and the total amount (a +
b + c) is from 5 to 20% by weight. The short fibrous powder having a fiber length of 0.8 to 1.5 mm, which is the component (a) used in the present invention, is, for example, a cellulose-based, polyester-based, polyamide-based or polyacrylonitrile-based fiber, and more specifically, Include synthetic fibers such as rayon, acetate, nylon, tetron, and acrylic,
Natural fibers such as wool and silk fiber are exemplified. These may be used alone or in combination of two or more as necessary, and those having a thickness of 400 μm or less are preferably used. These short fibrous powders may have any shape such as a needle shape, a rod shape, and a cylindrical shape. Note that these short fibrous powders may be subjected to a surface treatment using a known method. If the fiber length of the short fibrous powder is less than 0.8 mm, the adhesiveness to the skin becomes too high, and considerable force is required when removing the short fibrous powder. In addition, the time becomes longer than necessary. On the other hand, when the fiber length of the short fibrous powder exceeds 1.5 mm, the adhesion to the skin becomes too low, and waste products cannot be sufficiently removed. [0008] The long fibrous powder used as the component (b) in the present invention has a fiber length of 2% of the short fibrous powder of the component (a).
It is twice or more and 5 mm or less. Like the component (a), the long-fibrous powder may be, for example, cellulose-based, polyester-based, polyamide-based, polyacrylonitrile-based fibers, more specifically, synthetic fibers such as rayon, acetate, nylon, tetron, and acrylic. And natural fibers such as wool and silk fiber. These can be used singly or in combination of two or more as needed. The thickness is preferably 400 μm or less, and the length is 5 mm.
It is preferably used below. The component (a) and the component (b)
The components may be homogeneous or heterogeneous, or a mixture of homogeneous and heterogeneous. These long fiber powders are acicular,
The shape thereof does not matter, such as a rod shape and a cylindrical shape. In addition, you may perform surface treatment on these long-fibrous powder using a well-known method. The long fibrous powder is compounded together with the short fibrous powder, and has a synergistic effect when used in combination with a powder having an average particle diameter of 0.5 to 1.5 mm, which is the component (c) described later. Demonstrate. That is, short fibrous powder having high adhesion to the skin, long fibrous powder having low adhesion to the skin, and powder having an excellent scrubbing effect are excellent in the adhesion of short fibrous powder to the skin. With a good cleaning effect and a good scrubbing effect of the granular material, a moderate scrub feeling is brought about. Furthermore, the long fibrous powder having the smoothness of massage and good detachability from the skin gradually removes the short fibrous powder from which waste products are removed from the skin. The fibrous powder and granules gradually collect and are removed as lump together with skin waste and attached dirt.
If the fiber length of the long fibrous powder is at least three times the fiber length of the short fibrous powder, more favorable effects will be exhibited. When the fiber length of the long fibrous powder is less than twice the fiber length of the short fibrous powder, the difference in the adhesion between the short fibrous powder and the long fibrous powder to the skin becomes small, Adhesion to the skin becomes uniform and `` the short fibrous powder from which waste products have been removed gradually by the long fibrous powder having the smoothness of massage and good detachability from the skin, While the long fibrous powder is the core, the short fibrous powder and granules gradually gather and are removed as a lump together with skin wastes and attached dirt. " And the scrubbing effect cannot be obtained smoothly or sufficiently. The powder (g) having an average particle size of 0.5 to 1.5 mm, which is the component (c) used in the present invention, includes nylon powder, polyethylene powder, methyl methacrylate having an average particle size within the above range. Powder, synthetic resin powder such as polystyrene powder, polytetrafluoroethylene powder, silicone powder, etc .; synthetic resin foam hard; sintered synthetic resin; solid wax such as microcrystalline wax;
Walnut shell grains, apricot shell grains, almond coarse grains, peach shell grains,
Grinds of plant leaves, roots, stems, fruits, etc., such as corn cob grains; metals, such as aluminum; inorganic substances, such as clay, diatomaceous earth, and shirasu; inorganic substance foams; inorganic substance sintered bodies; A granulated and formed extender for cosmetics, an inorganic white pigment, an inorganic color pigment, an organic pigment, an organic powder, a pearl agent, and the like. These powders may be subjected to a surface coating treatment. If the average particle size of the powder is less than 0.5 mm, a sufficient scrub feeling cannot be obtained. If the average particle size of the powder exceeds 1.5 mm, the scrubbing feeling becomes too strong, and in some cases, pain may be felt, which is not preferable. The average particle size of the powder is more preferably 0.7
1.01.0 mm, and a better scrub feeling can be obtained. The mixing ratio b / a of the fibrous powder of the short fibrous powder to the long fibrous powder is from 0.5 to 7. In addition, the fibrous powder compounding ratio b / a is more preferably 1 to 5.
When the fibrous powder compounding ratio b / a is less than 0.5, the ratio of the short fibrous powder is too high, the smoothness is insufficient during use, and a feeling of irritation may be felt during massage. In addition, the adhesiveness to the skin becomes high, and while the long fiber powder is used as a nucleus, the short fiber powder and the granular material gradually gather and are removed as a lump together with skin waste and attached dirt. Will take longer than necessary. If the fibrous powder blending ratio b / a exceeds 7, the ratio of the long fibrous powder is too high, and a lump is formed without a sufficient scrub feeling during use. In the present invention, it is necessary that the compounding ratio (a + b) / c of the fibrous powder and the granular material is 0.5 to 10. Further, the mixing ratio (a + b) / c of the fibrous powder and the granular material is more preferably 1 to 7. When the blending ratio (a + b) / c of the fibrous powder and the granular material is less than 1, the ratio of the granular material becomes large, the scrubbing action becomes too strong, and in some cases, a feeling of irritation may be felt. Is not preferred. When the compounding ratio (a + b) / c of the fibrous powder and the granular material exceeds 10, the ratio of the granular material becomes small and a good scrub feeling cannot be obtained. In the present invention, it is necessary that the total amount (a + b + c) of the fibrous powder and the granular material is 5 to 20% by weight. The total amount (a + b + c) is more preferably 10 to 15% by weight. If the total blending amount (a + b + c) of the fibrous powder and the granular material is less than 5% by weight, good peeling action cannot be obtained. Also,
When the total amount (a + b + c) of the fibrous powder and the granular material exceeds 20% by weight, the elongation is poor and the usability and feeling of use are poor, such as being rough. In the present invention, in addition to the above essential components, lower alcohols such as ethanol, propylene glycol, 1,3
-Humectants such as butylene glycol, glycerin, polyethylene glycol, sorbitol, maltitol, sodium chondroitin sulfate, sodium pyrrolidone carboxylate, and sodium lactate; oils such as liquid paraffin, ester oil and silicone oil; water-soluble polymers; electrolytes; An activator, an ultraviolet absorber, a fragrance, a preservative, and the like can be appropriately blended. The present invention relates to a peeling cosmetic composition comprising a specific amount of a specific ratio of two types of fibrous powders of a long and short length and a powder having a specific particle size, as described above. Available in any form. For example, an emulsion obtained by emulsifying oil and water, a gelled product mainly containing an aqueous or oily gelling agent, an oil,
As a dispersion in water, other liquids or emulsions,
Available. The form of the peeling cosmetic composition of the present invention is more preferably a shaking type of a dispersion type in an emulsion. If the emulsion is of the shaking type, the adhesion of the fibrous powder to the skin when spread on the skin, and the feeling of scrubbing of the granular material on the skin,
It is exhibited in the most desirable form, providing a fresh feeling of use, and a good refreshing feeling after use. EXAMPLES Next, the present invention will be further described with reference to examples, but the present invention is not limited thereto. Example 1: Emulsion liquid-peeling cosmetic was prepared by the following formulation and manufacturing method. (Prescription) [Table 2] [Table 3] [Table 4] (Production method) A. Components (13) to (18) are uniformly dissolved. B. Add A to component (19) and emulsify. C. The components (1) to (12) are added and uniformly mixed to obtain an emulsion shake-type peeling cosmetic. Using the obtained emulsion shake-type peeling cosmetic, a use test was conducted using 25 women as panels.
Appropriate scrubbing feeling during use, feeling of adhesion to skin, ease of spreading, refreshing feeling after use, smoothness, and cleanliness were evaluated by the number of people who were all good according to the following criteria. [0026] The results of evaluations of a moderate scrub feeling during use, a feeling of close contact with the skin, a smoothness, a refreshing feeling, a smooth feeling, and a clean feeling after use by a use test using 25 women as panels. The results are shown in Tables 1 to 4. Table 1
As is clear from the results shown in Table 4, the emulsion shake type peeling cosmetics of the present invention products 1 to 12 have a moderate scrubbing feeling during use and a feeling of adhesion to the skin as compared with the comparative products 1 to 12. It was excellent in ease of spreading, freshness after use, smoothness and cleanliness. Example 2 Creamy Peeling Cosmetic (Formulation) (% by Weight) 1. Crystalline cellulose powder (fiber length: 1 mm) 2.0 2. Nylon fiber (fiber length: 3 mm) 4.0 3. Polystyrene powder (average particle size 0.7 mm) 3.0 Liquid paraffin 10.0 5. Cetyl isooctanoate 10.0 6. Vaseline 3.0 7. Stearic acid 1.5 8. Cetanol 1.0 9. Sorbitan sesquioleate 0.5 10. Polyoxyethylene sorbitan monooleate 0.5 (20EO) 11.1,3-butylene glycol 10.0 12. Carboxyvinyl polymer 0.1 13. Preservative 0.1 14. Triethanolamine 0.4 15. Fragrance 0.116. Purified water balance (Production method) The components (4) to (10) are heated and dissolved. B. The components (11) to (16) are heated and dissolved. C. Add B to A and emulsify, then cool. D. The components (1) to (3) are added and uniformly mixed to obtain a creamy peeling cosmetic. The creamy peeling cosmetic composition of the present invention was excellent in a moderate scrub feeling during use, a feeling of adhesion to skin, ease of spreading, a refreshing feeling after use, a smooth feeling, and a clean feeling. Example 3: Gel-like peeling cosmetic (formulation) (% by weight) Nylon fiber (fiber length 1 mm) 2.0 2. 2. Nylon fiber (fiber length 3 mm) 4.0 3. Polyethylene powder (average particle size 0.7 mm) 3.0 Methylphenyl polysiloxane 3.0 5. 5. Cetyl isooctanoate 5.0 Polyoxyalkylenemethylpolysiloxane 1.0 7. 7. Sorbitan sesquioleate 0.2 9. Polyoxyethylene sorbitan monooleate 0.8 (20EO) 9.1,3-butylene glycol 10.0 Carboxyvinyl polymer 0.3 11. Preservative 0.1 12. Triethanolamine 0.3 13. Fragrance 0.114. Purified water balance [Production method] A. Heat and dissolve components (4) to (8). B. Components (9) to (14) are heated and dissolved. C. Add B to A and emulsify, then cool. D. The components (1) to (3) are added and uniformly mixed to obtain a gel-like peeling cosmetic. The gel-like peeling cosmetic composition of the present invention was excellent in moderate scrub feeling during use, close contact with the skin, ease of spreading, refreshing feeling after use, smooth feeling, and clean feeling. The peeling cosmetic composition of the present invention is excellent in a moderate scrub feeling during use, a feeling of adhesion to skin, ease of spreading, a refreshing feeling after use, a smooth feeling and a clean feeling. there were.
フロントページの続き (56)参考文献 特開 昭62−238211(JP,A) 特開 昭63−139108(JP,A) 特開 昭63−211206(JP,A) 特開 昭61−171415(JP,A) 特開 昭62−70308(JP,A) (58)調査した分野(Int.Cl.7,DB名) A61K 7/00 - 7/50 Continuation of the front page (56) References JP-A-62-238111 (JP, A) JP-A-63-139108 (JP, A) JP-A-63-211206 (JP, A) JP-A-61-171415 (JP) , A) JP-A-62-70308 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) A61K 7/ 00-7/50
Claims (1)
上であり、かつ5mm以下である長繊維状粉末 (c)平均粒径が0.5〜1.5mmの粉粒体 を含有し、かつ、繊維状粉末の配合量比率b/aが0.
5〜7であり、繊維状粉末と粉粒体の配合量比率(a+
b)/cが0.5〜10であり、更に、総配合量(a+
b+c)が5〜20重量%であることを特徴とするピー
リング化粧料。(57) [Claim 1] (a) Component to (c) Component (a) Short fibrous powder having a fiber length of 0.8 to 1.5 mm (b) Fiber length is defined as (a) )) A long-fibrous powder that is at least twice as long as the short-fibrous powder of the component and no more than 5 mm; Is less than 0.1.
5 to 7, and the compounding ratio of the fibrous powder and the granular material (a +
b) / c is 0.5 to 10, and the total amount (a +
(b + c) is 5 to 20% by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18626695A JP3378972B2 (en) | 1995-06-29 | 1995-06-29 | Peeling cosmetics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18626695A JP3378972B2 (en) | 1995-06-29 | 1995-06-29 | Peeling cosmetics |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0912427A JPH0912427A (en) | 1997-01-14 |
JP3378972B2 true JP3378972B2 (en) | 2003-02-17 |
Family
ID=16185285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18626695A Expired - Fee Related JP3378972B2 (en) | 1995-06-29 | 1995-06-29 | Peeling cosmetics |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3378972B2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1184949C (en) | 2000-01-19 | 2005-01-19 | 花王株式会社 | Detergent compositions |
KR101008703B1 (en) * | 2003-11-17 | 2011-01-19 | 하병조 | Exfoliation cosmetic composition |
-
1995
- 1995-06-29 JP JP18626695A patent/JP3378972B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0912427A (en) | 1997-01-14 |
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