JP3254837B2 - Manufacturing method of decorative sheet - Google Patents
Manufacturing method of decorative sheetInfo
- Publication number
- JP3254837B2 JP3254837B2 JP21025093A JP21025093A JP3254837B2 JP 3254837 B2 JP3254837 B2 JP 3254837B2 JP 21025093 A JP21025093 A JP 21025093A JP 21025093 A JP21025093 A JP 21025093A JP 3254837 B2 JP3254837 B2 JP 3254837B2
- Authority
- JP
- Japan
- Prior art keywords
- decorative sheet
- electron beam
- fine powder
- inorganic fine
- release agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000000843 powder Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 238000010894 electron beam technology Methods 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 6
- 230000001678 irradiating effect Effects 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 239000006082 mold release agent Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 238000009816 wet lamination Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- QWYSJTTWCUXHQO-UHFFFAOYSA-N [F].OC(=O)C=C Chemical compound [F].OC(=O)C=C QWYSJTTWCUXHQO-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Decoration By Transfer Pictures (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は家具、器物の表面や、建
築物の内装材の表面等に使用する化粧シートの製造方法
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a decorative sheet for use on surfaces of furniture and objects, surfaces of interior materials of buildings, and the like.
【０００２】[0002]
【従来の技術】従来、前記のような目的に用いられる化
粧シートは、必要に応じてべたインキ層、絵柄インキ層
を設けてなる化粧シート基材の上に、電子線硬化型樹脂
に無機微粉末及び離型剤を混ぜたものを塗布し、その後
電子線を照射して硬化させたものであった。2. Description of the Related Art Conventionally, a decorative sheet used for the above-mentioned purpose is provided on a decorative sheet base material provided with a solid ink layer and a picture ink layer as necessary, by applying an inorganic fine particle to an electron beam-curable resin. A mixture of a powder and a release agent was applied, and then cured by irradiation with an electron beam.
【０００３】この、電子線硬化型樹脂に無機微粉末及び
離型剤を混ぜて塗布する方法は、塗布した樹脂中の無機
微粉末及び離型剤の分布が均一となるため、無機微粉末
及び離型剤が大量に必要とされる。電子線硬化型樹脂に
無機微粉末を入れる事により耐摩耗性、スクラッチ性の
表面物性が良くなるが、無機微粉末を含む電子線硬化型
樹脂を塗布した化粧シートの表面は意匠性が良くなく、
無機微粉末の大量使用は電子線硬化型樹脂の硬化阻害に
影響する。[0003] In this method of applying an inorganic fine powder and a release agent to an electron beam-curable resin, the inorganic fine powder and the release agent are uniformly distributed in the applied resin. Large quantities of release agents are required. By adding inorganic fine powder to the electron beam-curable resin, the abrasion resistance and scratch properties of the surface properties are improved, but the surface of the decorative sheet coated with the electron beam-curable resin containing the inorganic fine powder has poor design. ,
Use of a large amount of the inorganic fine powder affects the curing inhibition of the electron beam-curable resin.
【０００４】[0004]
【発明が解決しようとする課題】本発明はこのような問
題点を解決するためになされたものであり、その課題と
するところは、少量の無機微粉末及び離型剤で従来以上
の耐摩耗性、スクラッチ性、テープ離型性等の表面物性
の向上及び意匠性の良い化粧シート及びその製造方法を
提供することにある。DISCLOSURE OF THE INVENTION The present invention has been made to solve such problems, and it is an object of the present invention to use a small amount of inorganic fine powder and a release agent to achieve a higher abrasion resistance than before. It is an object of the present invention to provide a decorative sheet having improved surface properties such as removability, scratching property, and tape releasability, and good design, and a method for producing the same.
【０００５】[0005]
【課題を解決するための手段】本発明はこの課題を解決
するため、転写フィルム基材の表面に無機微粉末を含む
離型剤を塗布し、化粧シート基材の上に無機微粉末及び
離型剤を含まない電子線硬化型樹脂を塗布し、両塗布面
を圧着して電子線を照射して電子線硬化型樹脂を硬化さ
せることを特徴とする化粧シートの製造方法を提供す
る。In order to solve this problem, the present invention applies a release agent containing inorganic fine powder to the surface of a transfer film substrate, and applies the inorganic fine powder and
Provided is a method for producing a decorative sheet, characterized by applying an electron beam-curable resin containing no release agent, compressing both application surfaces, and irradiating an electron beam to cure the electron beam-curable resin.
【０００６】以下、本発明を詳細に説明する。本発明に
係る化粧シート基材としては、紙、各種フィルム、不織
布等が使用できる。Hereinafter, the present invention will be described in detail. Paper, various films, nonwoven fabrics, and the like can be used as the decorative sheet substrate according to the present invention.
【０００７】また、前記化粧シート基材の上には、任意
に、必要に応じてベタインキ層か又は絵柄インキ層を設
ける。これらの層を設ける方法としては、グラビア印
刷、グラビアオフセット印刷等がある。[0007] Further, a solid ink layer or a picture ink layer is optionally provided on the decorative sheet substrate as required. Methods for providing these layers include gravure printing and gravure offset printing.
【０００８】本発明に係る電子線硬化型樹脂としては、
ウレタンアクリレート、ポリエステルアクリレート、エ
ポキシアクリレート等が使用できる。塗布方法として
は、ロールコーター、グラビアコーター、リバースコー
ター、ナイフコーター等がある。塗布量は７〜１００ｇ
／ｍ2 が好適である。The electron beam-curable resin according to the present invention includes:
Urethane acrylate, polyester acrylate, epoxy acrylate and the like can be used. Examples of the coating method include a roll coater, a gravure coater, a reverse coater, and a knife coater. Application amount is 7-100g
/ M 2 is preferred.
【０００９】本発明に係る無機微粉末としては酸化アル
ミニウム、酸化ケイ素、カーボランダム、コランダム、
ダイヤモンド等が使用でき、微粉末の粒径は５μｍ以下
が好適である。The inorganic fine powder according to the present invention includes aluminum oxide, silicon oxide, carborundum, corundum,
Diamond or the like can be used, and the particle size of the fine powder is preferably 5 μm or less.
【００１０】本発明に係る離型剤としては、シリコンア
クリレート、フッ素アクリレート、シリコン樹脂、フッ
素樹脂等が使用でき、その塗布するフィルムとしては、
ポリエチレンテレフタレートフィルム、ポリプロピレン
フィルム等が使用できる。また塗布方法としては、グラ
ビアコーター、マイクログラビアコーター、スプレーコ
ーター等がある。塗布量は０．５〜２ｇ／ｍ2 が好適で
ある。As the release agent according to the present invention, silicone acrylate, fluorine acrylate, silicone resin, fluorine resin and the like can be used.
A polyethylene terephthalate film, a polypropylene film or the like can be used. Examples of the coating method include a gravure coater, a microgravure coater, and a spray coater. The coating amount is preferably 0.5 to 2 g / m 2 .
【００１１】本発明の製造方法における、両フィルムの
塗布面を圧着する方法としては、ウエットラミネートを
使用する。その速度は、３０〜１００ｍ／ｓｅｃ、圧力
は１．０〜６．０Ｋｇｆ／ｃｍ2 が好適である。In the manufacturing method of the present invention, a wet lamination is used as a method of pressing the coated surfaces of both films. The speed is preferably 30 to 100 m / sec, and the pressure is preferably 1.0 to 6.0 kgf / cm 2 .
【００１２】本発明の製造方法の工程における、電子線
の照射、電子線硬化型樹脂の硬化については、２５０Ｋ
ｖ、３〜５Ｍｒａｄの電子線照射が好適である。The irradiation of the electron beam and the curing of the electron beam-curable resin in the steps of the production method of the present invention are carried out at 250K.
v, electron beam irradiation of 3 to 5 Mrad is preferable.
【００１３】[0013]
【作用】以上に示したように、本発明の化粧シートの製
造方法により表面に無機微粉末を含む離型剤が集中的に
存在するようになり、樹脂に混ぜるよりも少量でスリッ
プ効果があがり、耐摩耗性、耐スクラッチ性等の物性が
向上する。また、ウエットラミネートで転写することで
フィルムによる表面の平滑性がでる。更に、電子線照射
時に電子線硬化型樹脂の表面を無機微粉末を含む離型剤
を塗布したフィルムで覆っているため、表面の保護の効
果も有する。As described above, according to the method for producing a decorative sheet of the present invention, the release agent containing the inorganic fine powder is intensively present on the surface, and the slip effect is increased with a smaller amount than when mixed with the resin. And physical properties such as wear resistance and scratch resistance are improved. In addition, the surface is smoothed by the film by transferring with wet lamination. Furthermore, since the surface of the electron beam-curable resin is covered with a film coated with a release agent containing inorganic fine powder at the time of electron beam irradiation, it also has an effect of protecting the surface.
【００１４】[0014]
【実施例】坪量３０ｇ／ｍ2 の薄葉紙にベタインキ、木
目絵柄インキを印刷し、この表面にポリエステルアクリ
レート樹脂をロールコーターにより７ｇ／ｍ2 塗布し
た。また厚さ１２μのＰＥＴフィルムに０．３μｍアル
ミナ微粉末を離型剤に添加したものを０．３ｇ／ｍ2 塗
布した。直ちにこれらを圧着させ、２００ＫｅＶ、３Ｍ
ｒａｄの電子線を照射して硬化させた。こうして得られ
た化粧シートはＰＥＴフィルムを剥がすことにより薄葉
紙側のポリエステルアクリレートの表面にアルミナ微粉
末を含む離型剤が転写された。この化粧シートはスリッ
プ性、耐摩耗性、スクラッチ性等に優れ、表面の平滑性
が良好であった。EXAMPLE A solid ink and a wood pattern ink were printed on thin paper having a basis weight of 30 g / m 2 , and a polyester acrylate resin was applied to the surface of the thin paper with a roll coater at 7 g / m 2 . Further, 0.3 g / m 2 of 0.3 μm alumina fine powder added to a release agent was applied to a 12 μm thick PET film. Immediately press them together, 200 KeV, 3M
Irradiation of rad was performed to cure. By releasing the PET film from the decorative sheet thus obtained, the release agent containing alumina fine powder was transferred to the surface of the polyester acrylate on the tissue paper side. This decorative sheet was excellent in slip property, abrasion resistance, scratch property and the like, and had good surface smoothness.
【００１５】[0015]
【発明の効果】本発明の化粧シートは表面に無機微粉末
を含む離型剤が集中的に存在することにより、化粧シー
ト基材に塗布する電子線硬化型樹脂に混ぜるよりも少量
でスリップ性、耐摩耗性、スクラッチ性の物性において
良好な結果を示し、表面の平滑性も良好である。また製
造方法においてフィルムを剥がす作業は必ずしもインラ
イン上で行われなくても良く、後工程で剥がすことも可
能であるため、フィルムによる表面の保護効果がある。EFFECT OF THE INVENTION The decorative sheet of the present invention has a slip property smaller than that mixed with the electron beam- curable resin applied to the decorative sheet substrate due to the concentrated presence of the release agent containing the inorganic fine powder on the surface. It shows good results in physical properties such as wear resistance and scratch resistance, and also has good surface smoothness. In the manufacturing method, the operation of peeling off the film is not necessarily performed in-line, and the film can be peeled off in a subsequent step, so that the film has an effect of protecting the surface.
【００１６】[0016]
【図１】従来の化粧シートの一例の断面の構造を示す説
明図である。FIG. 1 is an explanatory diagram showing a cross-sectional structure of an example of a conventional decorative sheet.
【図２】本発明の製造方法により得られる化粧シートの
一例の断面の構造を示す説明図である。FIG. 2 is an explanatory diagram showing a cross-sectional structure of an example of a decorative sheet obtained by the production method of the present invention.
【図３】本発明の化粧シートの製造方法の一実施例の工
程を示す説明図である。FIG. 3 is an explanatory view showing the steps of one embodiment of the method for producing a decorative sheet according to the present invention.
１…基材 ２…ベタインキ層 ３…絵柄インキ層 ４…電子線硬化型樹脂 ５…離型剤、無機微粉末 ６…転写フィルム基材 ７…電子線照射機 ８…化粧シート DESCRIPTION OF SYMBOLS 1 ... Base material 2 ... Solid ink layer 3 ... Picture ink layer 4 ... Electron beam curable resin 5 ... Release agent, inorganic fine powder 6 ... Transfer film base material 7 ... Electron beam irradiation machine 8 ... Decorative sheet
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭61−205197（ＪＰ，Ａ) 特開 平４−239687（ＪＰ，Ａ) 実開 昭61−105193（ＪＰ，Ｕ) (58)調査した分野(Int.Cl.7，ＤＢ名) B44C 1/165 - 1/17 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-61-205197 (JP, A) JP-A-4-239687 (JP, A) Jpn. Field (Int.Cl. 7 , DB name) B44C 1/165-1/17
Claims (1)
む離型剤を塗布し、化粧シート基材の上に無機微粉末及
び離型剤を含まない電子線硬化型樹脂を塗布し、両塗布
面を圧着して電子線を照射して電子線硬化型樹脂を硬化
させることを特徴とする化粧シートの製造方法。1. A transfer film a release agent containing inorganic fine powder coated on the surface of the substrate, the inorganic fine powder及 on the decorative sheet substrate
A method for producing a decorative sheet, comprising applying an electron beam-curable resin containing no mold release agent , applying pressure on both application surfaces, and irradiating an electron beam to cure the electron beam-curable resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21025093A JP3254837B2 (en) | 1993-08-25 | 1993-08-25 | Manufacturing method of decorative sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21025093A JP3254837B2 (en) | 1993-08-25 | 1993-08-25 | Manufacturing method of decorative sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0761196A JPH0761196A (en) | 1995-03-07 |
| JP3254837B2 true JP3254837B2 (en) | 2002-02-12 |
Family
ID=16586270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21025093A Expired - Fee Related JP3254837B2 (en) | 1993-08-25 | 1993-08-25 | Manufacturing method of decorative sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3254837B2 (en) |
-
1993
- 1993-08-25 JP JP21025093A patent/JP3254837B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0761196A (en) | 1995-03-07 |
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